JP3889008B6 - Method for producing tin or tin alloy plated copper alloy for multipolar terminals - Google Patents

Description

The present invention is a multi-electrode terminal for tin or tin alloy-plated copper alloy, in particular, relating to the manufacturing method of the multi-electrode terminal for tin-plated copper alloy for a motor vehicle.

  Tin plated copper alloys are used for automobile terminals and connectors. The purpose of tin plating is generally to obtain good electrical contacts, impart corrosion resistance, and improve solderability. In Patent Documents 1 and 2 below, for the purpose of suppressing the diffusion of Cu and Ni into the tin plating layer and keeping the solder wettability of the tin plating material good over a long period of time, A technique is disclosed in which an intermetallic compound layer is provided, thereby suppressing diffusion of elements into tin and keeping the tin plating layer for a long period of time.

JP-A-4-235292 JP-A-4-329891

  On the other hand, the number of poles of a multipolar connector formed by assembling terminals, that is, the number of terminals, is increasing with the recent trend toward the electrification of automobiles. When the number of poles increases in this way, the insertion force when fitting the connector increases, which causes the fatigue of the worker when assembling the automobile and the workability.

As a means to solve the above problems due to the large insertion force, measures on the terminal design side such as reducing the contact pressure of the female terminal or increasing the tab clearance can be considered. There is a risk of impairing the stability of the electrical contact that is the original purpose.
SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to solve the above problems by reducing the insertion force of a terminal without impairing the reliability of electrical contacts.

The present inventors have conceived that the insertion force of the terminal can be reduced without impairing the reliability of the contact if the friction coefficient of tin or tin alloy-plated copper alloy forming the terminal is lowered. A tin or tin alloy plated copper alloy that requires a low friction coefficient and a small terminal insertion force by forming a high hardness intermetallic compound comprising a copper and tin intermetallic compound under the tin or tin alloy plating layer Found that you can get.

The present invention has been made based on this finding. The manufacturing method of the tin or tin alloy plating copper alloy for multipolar terminals which concerns on this invention performed the copper plating of 0.05-0.2 micrometer on the copper alloy, and also gave the tin or tin alloy plating on it Later, by performing a reflow process, all the copper plating is changed to an intermetallic compound of copper and tin, and a first layer made of an intermetallic compound of copper and tin having a thickness of 0.1 to 0.4 μm, and Furthermore, a tin or tin alloy plated copper alloy having a tin or tin alloy plating layer of 0.1 to 1.2 μm and a dynamic friction coefficient between the same materials of 0.3 or less is obtained. And
In addition, it is preferable that the Knoop hardness (Hk25gf) is 95-220 in the tin or tin alloy plating copper alloy for multipolar terminals manufactured by this invention.
This copper alloy is usually supplied in the form of a plate or strip and formed into a terminal by pressing.

The friction coefficient of the tin or tin alloy plated copper alloy material, and hence the insertion force of the tin or tin alloy plated terminal, is determined by the deformation resistance and shear resistance of the plating film. In the present invention, it is considered that by having a high-hardness intermetallic compound layer under a soft layer such as a tin-plated layer, the soft tin-plated layer produces a lubricating action and the friction coefficient becomes small. The thinner the tin plating layer, the smaller the coefficient of friction.
That is, the present invention provides a dynamic friction coefficient of a material that affects the insertion force of the terminal by forming an intermetallic compound layer under the tin or tin alloy plating layer and simultaneously limiting the thickness of the tin or tin alloy plating layer. Is intended to obtain an excellent tin or tin alloy-plated copper alloy for multipolar terminals.

By the way, the electrical properties of the terminal contacts must be sufficiently stable during use of the automobile in which they are mounted. It is already known that the tin plating layer is a high-speed diffusion medium of Cu or Ni, and these elements diffuse into the tin plating layer even at a temperature near room temperature to form an intermetallic compound. And, for example, a tin or tin alloy plating layer that is thick enough that the electrical properties of the contacts are not compromised even if these elements diffuse into the tin plating layer for 10 years is required. .
However, if the tin or tin alloy plating layer is thickened, the friction coefficient increases, and even if the stability of the contact can be ensured, it is difficult to manufacture a multipolar terminal with low insertion force during mounting and excellent workability. It becomes. Therefore, in the present invention, an intermetallic compound layer having an appropriate thickness for suppressing diffusion into the tin plating layer is provided on the base so that reliability is not lowered even if the plating thickness is made thinner than the conventional one.

Conventionally, it has been considered that the thickness of the tin or tin alloy plating film should be thick in order to maintain good solder wettability. However, in recent automobile terminals, from the viewpoint of reliability and the like, a wire connection method by caulking is used instead of soldering. When using such a connection method, There is no need to increase the thickness of the plating film from the viewpoint of solder wettability. Rather, in the present invention, contrary to the prior art, the friction coefficient is controlled to be low by reducing the tin or tin alloy plating film to a certain thickness or less, and the terminal insertion force is reduced.
Therefore, it can be said that the present invention is particularly suitable for a multipolar terminal which does not perform soldering and wants to keep the insertion force low. However, the present invention is not limited to only multipolar terminals that are not soldered.

In addition, for the purpose of suppressing the diffusion of Cu and Ni into the tin plating layer and maintaining good solder wettability etc. of the tin plating material over a long period of time, an intermetallic compound layer is provided below the tin plating layer, A technique for suppressing the diffusion of elements into tin and keeping the tin plating layer for a long time is already disclosed in Patent Documents 1 and 2.
On the other hand, as described above, the present invention limits the thickness of the tin or tin alloy plating layer on the intermetallic compound layer, thereby reducing the dynamic friction coefficient of the material that affects the insertion force of the terminal. It is intended to obtain a tin or tin alloy-plated copper alloy that suppresses the value low and is excellent particularly for multipolar terminals.

  According to the present invention, it is possible to obtain a tin-plated or tin-alloy plated copper alloy strip having a lower coefficient of friction than conventional ones, and a terminal using the plated material can have a low insertion force. Suitable for pinned automotive multipolar connectors.

Here, the reason why the thickness of the intermetallic compound layer of copper and tin is 0.1 to 0.4 μm will be described. The reason why the thickness is set to 0.1 μm or more is that a thickness of at least 0.1 μm or more is necessary to suppress the diffusion of elements from the copper alloy to the tin plating layer. On the other hand, the upper limit of the thickness of the intermetallic compound layer is set to 0.4 μm or less because if the thickness exceeds this, the plating film cracks during the molding process of the terminal, which reduces corrosion resistance or causes cracking. This is because there is an adverse effect of increasing the amount of waste during press working.

  As for the thickness of the tin or tin alloy plating, the thinner, the lower the friction coefficient and the smaller the insertion force. However, if it is less than 0.1 μm, even if an intermetallic compound layer that suppresses diffusion is provided on the ground due to defects in the plating film or diffusion of copper element from the base material into the plating film, the life of the automobile is exceeded. This is because it is difficult to ensure the stability of contact resistance required for the contact. Accordingly, the plating thickness needs to be 0.1 μm or more. On the other hand, the upper limit of the plating thickness was 1.2 μm. This is because the friction coefficient increases when the thickness exceeds this. Within the above range, 0.3 to 0.8 μm is preferable for long-term stabilization of the terminal insertion force and the contact resistance value.

  Regarding Knoop hardness, the larger this is, the smaller the friction coefficient of the plating material tends to be, and the insertion force tends to be smaller. Therefore, the value of Hk25gf is desirably 95 or more, and the upper limit is desirably 220 or less from the viewpoint of preventing surface cracks during processing. This Knoop hardness condition can be obtained in the range of tin or tin alloy plating thickness of 0.3 to 0.8 μm.

In the method of the present invention , a copper plating of 0.05 to 0.2 μm is performed on the copper alloy, and after tin or tin alloy plating is performed thereon, a reflow treatment for melting the plating layer is performed, and the copper plating layer is formed. In order to obtain an intermetallic compound layer having a thickness of 0.1 to 0.4 μm, the copper plating layer needs to have a thickness of 0.05 to 0.2 μm.
The tin or tin alloy plating may be either electrolytic or electroless, and it may be difficult to control the thickness of the plating layer, but may be formed by hot tin plating.
Examples of the tin alloy plating include alloys such as tin-lead (solder), tin-zinc, and tin-nickel.

A phosphor bronze plate made of 0.25 mm Cu-6 wt% Sn-0.045 wt% P was plated under the plating conditions shown in Table 1, and an intermetallic compound layer was formed by reflow treatment. The results are summarized in Table 2.
In Table 2 , the initial Cu plating and initial Sn plating thicknesses before reflow treatment were both directly plated on the surface of phosphor bronze under the same conditions as in the examples. Thus, the plating thickness is obtained, and this is used as the plating thickness of each example. Further, the thickness of the intermetallic compound layer and the thickness of the Sn plating (after the reflow treatment) are obtained from the SEM image after cutting the cross section of the plating layer with a microtome.

The friction coefficient was measured using an autograph so that the prepared test materials (the same tin-plated phosphor bronze plate) were in contact with each other with a certain area. That is, as schematically shown in FIG. 1, a test material 1 having an area of 1 cm ² is attached to a block 2 having a load (N) of 1 kgf so that its center of gravity is matched with the test material 1, and this is attached to the surface of the other test material 3. Was slid at a moving speed of 0.38 mm / sec and the dynamic friction coefficient (μ) was calculated from the force (F) applied in the horizontal direction by the following equation.
μ = F / N
In FIG. 1, 4 is a wire for pulling the test material (less elastic), 5 is a pulley, and 6 is a load cell. Also, no lubricating oil or the like is applied to the friction surface of the tin plating material.

The contact resistance value is obtained by applying a waterproof coating to the end face, and using a tin plating material left in an atmosphere of a temperature of 40 ° C. and a humidity of 85% for 24 hours. It is a measured value.
W bending workability was evaluated by bending a test piece having a width of 10 mm with a bending radius of 0.5 mm and a linear pressure of 100 kgf / mm, and then observing the bent portion with a stereomicroscope by magnifying it 40 times.

  As shown in Table 2, no. When the initial copper plating thickness of 1 to 8 was 0.05 to 0.2 μm, the thickness of the intermetallic compound layer after the reflow treatment was 0.1 to 0.4 μm. The thickness of the intermetallic compound layer is 0.1 to 0.4 μm, and the thickness of the tin plating layer is in the range of 0.1 to 1.2 μm. In the case of 1 to 8, the friction coefficient is 0.3 or less, and the contact resistance value after the wet test is maintained at a low value of 2.2 mΩ or less. On the other hand, the thickness of the intermetallic compound layer exceeds 0.4 μm. In 9, the dynamic friction coefficient and the contact resistance value are good, but the plating layer cracks after bending. In addition, a tin plating layer of 2.2 μm No. At 10, the coefficient of friction increases to 0.35.

It is the figure which represented typically the measuring method of the friction coefficient in this invention.

Explanation of symbols

1, 3 Tin plating test material 2 Load block

Claims (1)

After copper plating of 0.05 to 0.2 μm is performed on the copper alloy, and further, tin or tin alloy plating is performed thereon, and then reflow treatment is performed, so that the copper plating is entirely an intermetallic compound of copper and tin. A first layer made of an intermetallic compound of copper and tin having a thickness of 0.1 to 0.4 μm, and a tin or tin alloy plating layer having a thickness of 0.1 to 1.2 μm on the first layer. And the manufacturing method of the tin or tin alloy plating copper alloy for multipolar terminals which obtains the tin or tin alloy plating copper alloy whose dynamic friction coefficient between the same materials is 0.3 or less is obtained.

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