JP3806942B2 - ポリスチレン樹脂の臭素化方法 - Google Patents
ポリスチレン樹脂の臭素化方法 Download PDFInfo
- Publication number
- JP3806942B2 JP3806942B2 JP51565998A JP51565998A JP3806942B2 JP 3806942 B2 JP3806942 B2 JP 3806942B2 JP 51565998 A JP51565998 A JP 51565998A JP 51565998 A JP51565998 A JP 51565998A JP 3806942 B2 JP3806942 B2 JP 3806942B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- bromination
- mixture
- catalyst
- styrene polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/727,341 US5677390A (en) | 1996-09-26 | 1996-09-26 | Process for brominating polystyrenic resins |
| US08/727,341 | 1996-09-26 | ||
| PCT/US1997/015624 WO1998013397A1 (en) | 1996-09-26 | 1997-09-05 | Process for brominating polystyrenic resins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002512641A JP2002512641A (ja) | 2002-04-23 |
| JP2002512641A5 JP2002512641A5 (enExample) | 2005-02-10 |
| JP3806942B2 true JP3806942B2 (ja) | 2006-08-09 |
Family
ID=24922284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51565998A Expired - Lifetime JP3806942B2 (ja) | 1996-09-26 | 1997-09-05 | ポリスチレン樹脂の臭素化方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5677390A (enExample) |
| EP (1) | EP0928299B1 (enExample) |
| JP (1) | JP3806942B2 (enExample) |
| CA (1) | CA2265785C (enExample) |
| DE (1) | DE69701996T2 (enExample) |
| IL (1) | IL129115A (enExample) |
| WO (1) | WO1998013397A1 (enExample) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6518368B2 (en) | 1996-06-14 | 2003-02-11 | Albemarle Corporation | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
| US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
| US6235831B1 (en) * | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
| US6326439B1 (en) | 1996-09-26 | 2001-12-04 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US6133381A (en) * | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
| DE69701997T2 (de) | 1996-09-26 | 2000-11-09 | Albemarle Corp., Baton Rouge | Verfahren zur bromierung von styrolpolymeren |
| US6232408B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
| US6235844B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
| US6521714B2 (en) | 1996-09-26 | 2003-02-18 | Albemarle Corporation | Brominated polystyrenic resins |
| US6232393B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
| US6146555A (en) * | 1998-01-19 | 2000-11-14 | Ferro Corporation | Brominated copolymer flame retardant additives having improved color characteristics and related method |
| WO2000014125A1 (en) * | 1998-09-10 | 2000-03-16 | Albemarle Corporation | Improved brominated polystyrenic resins, and their use |
| IL160929A0 (en) | 2001-12-21 | 2004-08-31 | Pabu Services Inc | Method and apparatus for producing decabromodiphenyl alkanes |
| US20040072929A1 (en) * | 2002-06-27 | 2004-04-15 | De Schryver Daniel A. | Flame retardant compositions |
| US6657028B1 (en) | 2002-08-01 | 2003-12-02 | Albemarle Corporation | Anionic polymerization process |
| US7666944B2 (en) * | 2004-01-21 | 2010-02-23 | Albemarle Corporation | Flame retarded fibers and filaments and process of production therefor |
| US20050159552A1 (en) * | 2004-01-21 | 2005-07-21 | Reed Jon S. | Flame retarded fibers and filaments and process of production therefor |
| US7585443B2 (en) * | 2004-05-20 | 2009-09-08 | Albemarle Corporation | Pelletized brominated anionic styrenic polymers and their preparation and use |
| ATE453671T1 (de) | 2004-09-30 | 2010-01-15 | Chemtura Corp | Verbesserte bromstyrol-polymere mit kontrolliertem molekülgewicht |
| PL1896512T3 (pl) * | 2005-06-30 | 2017-05-31 | Albemarle Corporation | Bromowane polimery styrenowe i ich wytwarzanie |
| CN101341175B (zh) * | 2005-12-21 | 2011-03-30 | 雅宝公司 | 溴化的苯乙烯系聚合物或树脂的制备 |
| WO2007076369A1 (en) * | 2005-12-21 | 2007-07-05 | Albemarle Corporation | Brominated anionic styrenic polymers and their preparation |
| EP2044133B1 (en) * | 2006-07-20 | 2015-01-28 | Albemarle Corporation | Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles |
| EP2054446B1 (en) * | 2006-08-16 | 2019-07-24 | Dow Global Technologies LLC | Process for brominating butadiene/vinyl aromatic copolymers |
| JP5536451B2 (ja) * | 2006-08-16 | 2014-07-02 | ダウ グローバル テクノロジーズ エルエルシー | ブタジエン/ビニル芳香族コポリマーを臭素化する方法 |
| TW200817447A (en) * | 2006-08-22 | 2008-04-16 | Albemarle Corp | Terminating bromination of styrenic polymer in a bromination reaction mixture |
| KR20090093962A (ko) * | 2006-11-28 | 2009-09-02 | 알베마를 코포레이션 | 브롬화 음이온성 스티렌계 중합체를 저장, 수송, 및 사용하기 위해 경질이고 큰 형태로 전환하는 방법 |
| US8435636B2 (en) * | 2007-03-29 | 2013-05-07 | Akron Polymer Systems, Inc. | Optical compensation films of brominated styrenic polymers and related methods |
| US8889043B2 (en) | 2007-03-29 | 2014-11-18 | Akron Polymer Systems, Inc. | Optical films cast from styrenic fluoropolymer solutions |
| US9011992B2 (en) | 2007-03-29 | 2015-04-21 | Akron Polymer Systems | Optical compensation films based on stretched polymer films |
| US8802238B2 (en) * | 2007-03-29 | 2014-08-12 | Akron Polymer Systems, Inc. | Optical compensation films based on fluoropolymers |
| ES2708852T3 (es) | 2007-06-07 | 2019-04-11 | Albemarle Corp | Aductos, aductos y oligómeros, o aductos, oligómeros y polímeros de bajo peso molecular, y su preparación |
| US8193287B2 (en) * | 2008-03-06 | 2012-06-05 | Dow Global Technologies Llc | Process for brominating butadiene copolymers by the addition of water or certain solvents |
| WO2009126531A1 (en) * | 2008-04-07 | 2009-10-15 | Dow Global Technologies, Inc. | Process for brominating butadiene/vinyl aromatic copolymers |
| JP5508397B2 (ja) * | 2008-05-01 | 2014-05-28 | ダウ グローバル テクノロジーズ エルエルシー | ブタジエン共重合体を臭素化する2段階方法 |
| JP5498486B2 (ja) | 2008-06-06 | 2014-05-21 | アルベマール・コーポレーシヨン | 低分子量臭素化ポリマー、それらの製作プロセス、および熱可塑性配合物におけるそれらの使用 |
| US8993684B2 (en) * | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
| WO2010065462A2 (en) * | 2008-12-02 | 2010-06-10 | Albemarle Corporation | Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom |
| JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
| CN102272176A (zh) * | 2008-12-02 | 2011-12-07 | 雅宝公司 | 支化和星形支化的苯乙烯聚合物、调聚物和加合物,其合成、其溴化及其用途 |
| CA2743025A1 (en) * | 2008-12-02 | 2010-06-10 | Albemarle Corporation | Bromination of telomer mixtures derived from toluene and styrene |
| KR20120088535A (ko) | 2009-05-01 | 2012-08-08 | 알베마를 코포레이션 | 펠렛화된 저분자량 브롬화 방향족 고분자 조성물 |
| JO3059B1 (ar) | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
| CN101701047B (zh) * | 2009-10-22 | 2011-09-07 | 国家海洋局天津海水淡化与综合利用研究所 | 喷雾干燥溴化聚苯乙烯制备方法 |
| US9457496B2 (en) | 2011-03-23 | 2016-10-04 | Akron Polymer Systems, Inc. | Aromatic polyamide films for transparent flexible substrates |
| US9856376B2 (en) | 2011-07-05 | 2018-01-02 | Akron Polymer Systems, Inc. | Aromatic polyamide films for solvent resistant flexible substrates |
| US11084906B2 (en) | 2011-08-19 | 2021-08-10 | Akron Polymer Systems, Inc. | Thermally stable, low birefringent copolyimide films |
| US8871882B2 (en) | 2012-02-14 | 2014-10-28 | Akron Polymer Systems, Inc. | Method for the preparation of styrenic fluoropolymers |
| EP4259668A4 (en) * | 2020-12-11 | 2024-12-18 | Arlanxeo Singapore Pte. Ltd. | HALOGEN RECOVERY WITH K-CONTAINING OXIDANT IN A PROCESS FOR HALOGENATION OF AN UNSATURATED ISOOLEFIN COPOLYMER |
Family Cites Families (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1890772A (en) * | 1930-01-28 | 1932-12-13 | Du Pont | Chlorination of meta styrene |
| US2199026A (en) * | 1937-04-01 | 1940-04-30 | Du Pont | Chlorinated aromatic resins |
| US2823201A (en) * | 1952-03-10 | 1958-02-11 | Dow Chemical Co | Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same |
| US3009906A (en) * | 1957-05-09 | 1961-11-21 | Dow Chemical Co | Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens |
| US3050476A (en) * | 1958-12-08 | 1962-08-21 | Koppers Co Inc | Method of making a self extinguishing expandable polymer of styrene by bromination |
| US3039977A (en) * | 1959-12-03 | 1962-06-19 | Koppers Co Inc | Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension |
| US3132045A (en) * | 1961-10-26 | 1964-05-05 | Dow Chemical Co | Method of impregnating film materials with ammonium bromide |
| NL128916C (enExample) * | 1965-02-18 | 1900-01-01 | ||
| US3506741A (en) * | 1966-01-10 | 1970-04-14 | Phillips Petroleum Co | Halogenated polymers and block copolymers produced therefrom |
| US3534012A (en) * | 1969-05-01 | 1970-10-13 | Dow Chemical Co | Anionic polymerization of nuclear halogenated styrenes |
| CH584731A5 (enExample) * | 1973-12-17 | 1977-02-15 | Ciba Geigy Ag | |
| US3959398A (en) * | 1974-06-03 | 1976-05-25 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
| US4028486A (en) * | 1974-06-03 | 1977-06-07 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
| US3932542A (en) * | 1974-08-26 | 1976-01-13 | Great Lakes Chemical Corporation | Process for preparation of 2,5-dibromo-p-xylene |
| US4178327A (en) * | 1974-12-19 | 1979-12-11 | The Dow Chemical Company | Ar-halo-ar(t-alkyl)styrenes and polymers thereof |
| CA1054161A (en) * | 1975-08-22 | 1979-05-08 | Herbert Naarmann | Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds |
| DE2645711C3 (de) * | 1976-10-09 | 1979-06-07 | Basf Ag, 6700 Ludwigshafen | Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| CA1050754A (en) * | 1977-01-02 | 1979-03-20 | Louis Scodeller | Earth planer |
| DE2703419B1 (de) * | 1977-01-28 | 1978-02-02 | Basf Ag | Flammwidrig ausgeruestete polyamid- formmassen |
| FR2413409A1 (fr) * | 1978-01-02 | 1979-07-27 | Huels Chemische Werke Ag | Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau |
| DE3006448A1 (de) * | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen |
| US4352909A (en) * | 1980-08-20 | 1982-10-05 | Ferro Corporation | Process for the bromination of polystyrenes |
| US4389517A (en) * | 1982-04-02 | 1983-06-21 | The Dow Chemical Company | Hydrogenation of phenylacetylene prior to styrene polymerization |
| US4554326A (en) * | 1983-04-01 | 1985-11-19 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4501859A (en) * | 1983-04-01 | 1985-02-26 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4548995A (en) * | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4513116A (en) * | 1983-04-01 | 1985-04-23 | Exxon Research And Engineering Co. | Process for the manufacture of halogenated polymers |
| EP0150332A3 (en) * | 1983-12-26 | 1987-08-19 | Mitsubishi Kasei Corporation | Process for producing a chloromethylated polymer |
| JPS6134723A (ja) * | 1984-07-26 | 1986-02-19 | Teijin Ltd | 磁気記録媒体及びその製造法 |
| US4650832A (en) * | 1984-09-17 | 1987-03-17 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| EP0201411A3 (en) * | 1985-05-03 | 1989-02-08 | The Dow Chemical Company | Brominated polymers of alkenyl aromatic compounds |
| US4879353A (en) * | 1987-01-28 | 1989-11-07 | Great Lakes Chemical Corporation | Bromination of polystyrene using bromine as the reaction solvent |
| US4835222A (en) * | 1987-02-19 | 1989-05-30 | The Dow Chemical Company | Alkylation of vinyl aromatic polymer |
| US4832873A (en) * | 1987-10-09 | 1989-05-23 | Great Lakes Chemical Corporation | Process for producing polybrominated higher alkylbenzenes |
| JPH0760235B2 (ja) * | 1988-09-29 | 1995-06-28 | 株式会社三協精機製作所 | エレクトロクロミック表示装置 |
| JPH02215807A (ja) * | 1989-02-17 | 1990-08-28 | Nippon Kayaku Co Ltd | 臭素化ポリスチレンの製造方法 |
| US5112897A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
| US5112896A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High-impact polystyrene containing low molecular weight brominated polystyrene |
| US5112898A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
| US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
| DE69129533T2 (de) * | 1990-03-16 | 1998-10-29 | Great Lakes Chemical Corp | Verfahren zur reinigung von bromiertem polystyrol |
| US5194482A (en) * | 1990-08-23 | 1993-03-16 | Ferro Corporation | Flame retardant resin composition containing styrenic polymers |
| US5235000A (en) * | 1990-12-10 | 1993-08-10 | Ethyl Corporation | Preparation, storage, and usage of bromine chloride |
| US5326837A (en) * | 1992-11-20 | 1994-07-05 | Mobil Oil Corporation | Catalyst systems for syndiospecific polymerization of styrenes |
| US5304618A (en) * | 1993-07-22 | 1994-04-19 | Great Lakes Chemical Corporation | Polymers of brominated styrene |
| US5532322B1 (en) * | 1995-09-26 | 1999-12-07 | Manac Inc | Process for preparing brominated polystyrene |
-
1996
- 1996-09-26 US US08/727,341 patent/US5677390A/en not_active Expired - Lifetime
-
1997
- 1997-06-11 US US08/872,985 patent/US5852132A/en not_active Expired - Lifetime
- 1997-09-05 IL IL12911597A patent/IL129115A/en not_active IP Right Cessation
- 1997-09-05 DE DE69701996T patent/DE69701996T2/de not_active Expired - Lifetime
- 1997-09-05 JP JP51565998A patent/JP3806942B2/ja not_active Expired - Lifetime
- 1997-09-05 EP EP97939809A patent/EP0928299B1/en not_active Expired - Lifetime
- 1997-09-05 CA CA002265785A patent/CA2265785C/en not_active Expired - Lifetime
- 1997-09-05 WO PCT/US1997/015624 patent/WO1998013397A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE69701996T2 (de) | 2000-11-09 |
| DE69701996D1 (de) | 2000-06-15 |
| JP2002512641A (ja) | 2002-04-23 |
| WO1998013397A1 (en) | 1998-04-02 |
| US5677390A (en) | 1997-10-14 |
| CA2265785A1 (en) | 1998-04-02 |
| US5852132A (en) | 1998-12-22 |
| CA2265785C (en) | 2005-04-19 |
| IL129115A0 (en) | 2000-02-17 |
| EP0928299A1 (en) | 1999-07-14 |
| EP0928299B1 (en) | 2000-05-10 |
| IL129115A (en) | 2002-08-14 |
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| JP3806942B2 (ja) | ポリスチレン樹脂の臭素化方法 | |
| JP4969605B2 (ja) | 難燃性が与えられた熱可塑材 | |
| JP4328388B2 (ja) | スチレン重合体の臭素化方法 | |
| JP5066043B2 (ja) | ポリスチレン樹脂の臭素化方法 | |
| US6326439B1 (en) | Process for brominating polystyrenic resins | |
| EP1293518B1 (en) | Process for brominating polystyrenic resins | |
| TWI405780B (zh) | 溴化苯乙烯聚合物或樹脂之製備 |
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