JP3769879B2 - Gas concentration measuring device - Google Patents

Gas concentration measuring device Download PDF

Info

Publication number
JP3769879B2
JP3769879B2 JP15574397A JP15574397A JP3769879B2 JP 3769879 B2 JP3769879 B2 JP 3769879B2 JP 15574397 A JP15574397 A JP 15574397A JP 15574397 A JP15574397 A JP 15574397A JP 3769879 B2 JP3769879 B2 JP 3769879B2
Authority
JP
Japan
Prior art keywords
value
measurement
nox
average value
gas concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP15574397A
Other languages
Japanese (ja)
Other versions
JPH10332617A (en
Inventor
浩明 松久
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimadzu Corp
Original Assignee
Shimadzu Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shimadzu Corp filed Critical Shimadzu Corp
Priority to JP15574397A priority Critical patent/JP3769879B2/en
Publication of JPH10332617A publication Critical patent/JPH10332617A/en
Application granted granted Critical
Publication of JP3769879B2 publication Critical patent/JP3769879B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Description

【0001】
【発明の属する技術分野】
試料ガス中の目的成分(NOx、SO2、CO、O2等)の濃度を測定するガス濃度測定装置、特に、燃焼機関の排ガス中の目的成分の濃度を測定する排ガス濃度測定装置に関するものである。
【0002】
【従来の技術】
大気汚染防止法により排出規制される酸化物濃度の測定値は、NOxを例として説明すると、次式(1)により基準残存酸素濃度状態に換算された値として求めることが定められている。
C=(21−On)・Cs/(21−Os) (1)
ただし、Cは換算後のNOx濃度(ppm)、Csは排ガス中のNOx濃度測定値(ppm)、Onは基準残存酸素濃度(vol%)、Osは排ガス中の酸素濃度測定値(vol%)、数値21は大気中の酸素濃度(vol%)である。
測定対象設備が、例えばボイラの場合、ボイラ運転中の排ガス中に含まれるNOxとO2を複数回測定し、それぞれの測定時のNOxとO2からNOxの換算値を算出し、それらの平均値が大気汚染防止法により定められた排出規準値以内であるかどうかをみる。
【0003】
測定対象設備によっては、運転・休止が短時間で繰り返される。乾式(赤外線式分析計等)のガス濃度測定装置により測定する場合は、通常は測定対象設備の運転・休止にあわせて測定を断続することはせず、連続して測定を行ない、測定終了後、測定対象設備の運転時のデータのみを抜き出して平均値を算出することを行なっている。
また、測定対象設備の運転・休止にあわせて測定又は測定値の記憶を断続するときは、オペレータが操作したり、運転・休止に対応した信号を出力する手段を測定対象設備に備え、その信号を入力する手段を測定装置に備えている。
【0004】
【発明が解決しようとする課題】
連続測定した場合、測定対象設備の運転時のデータのみ抜き出して平均値を算出するには、その作業に手間がかかるという問題があった。
また、測定を断続しようとした場合、手動の場合、オペレータの操作が煩雑になり、自動の場合、測定対象設備に運転・休止に対応した信号を出力する手段、及び測定対象設備からの休止信号を入力する手段を測定装置に備えるためにコストがかかるという問題があった。
そこで、本発明は、ガス測定装置の、平均値の算出の自動化、操作の簡便化、及びコスト低減化を目的とするものである。
【0005】
【課題を解決するための手段】
本発明は、燃焼機関の排ガス中の特定酸化物ガス濃度を測定し、ある時間内の平均値を求める演算部を備えたガス濃度測定装置において、酸化物ガス濃度測定値及び他の成分ガス測定値を予め設定されたしきい値と比較し、その比較結果に基づいて燃焼機関の運転・休止を判断し、かつ、休止中のデータを省いて平均値を算出する判断・演算部を備えるガス濃度測定装置である。
例えば、大気汚染防止法により排出規制される排ガス中に含まれる酸化物及びO2の濃度を検出部により常時測定し、酸化物とO2の両方の測定値と記憶部に予め記憶されたしきい値とを判断・演算部で比較することにより、測定対象設備が運転中のデータか、休止中のデータかを自動で判断する。休止中のデータを自動的に省いて、ある時間内の測定値の平均値を算出する。
【0006】
【実施例】
本発明の一実施例として検出部にNOx検出器とO2検出器を用いたNOx測定装置の一例について説明する。図1に、一実施例のNOx測定装置の構成ブロック図を示す。
このNOx測定装置は、排ガス中に含まれるNOxを検出するNOx検出部1、O2を検出するO2検出部2、平均値算出開始信号及び終了信号を入力する入力部3、しきい値や測定値を記憶する記憶部4、検出信号の濃度計算、その換算値又は平均値を算出し、しきい値と比較して測定対象設備の運転・休止を判断する判断・演算部5、並びに測定データを出力する出力部6から構成されている。
【0007】
NOx検出部1にはNOx検出器が備えられており、排ガス中に含まれるNOxを測定し、その検出信号を判断・演算部5に出力する。O2検出部2にはO2検出器が備えてられており、排ガス中に含まれるO2を測定し、その検出信号を判断・演算部5に出力する。
図1における判断・演算部5、記憶部4、入力部3及び出力部6は、測定装置の動作を制御しデータを処理する専用の制御・データ処理装置を利用してもよく、又は汎用のコンピュータにより実現してもよい。
【0008】
図2に測定対象設備が休止中のデータを含むNOx濃度測定の測定データ例を示す。x軸は時間、y軸は濃度(%F.S.)を示す。
測定対象設備が休止中の場合、大気を測定していることになるので、O2≒21vol%、NOx≒0ppmとなり、そこから算出される換算値は小さくなる。
一方、測定対象設備が運転中の場合、大気下で燃焼させた時、O2≪21vol%、NOx≫0ppmとなり、そこから算出される換算値≫0ppmとなる。
【0009】
図3は、同実施例の動作を示すフローチャート図であり、その動作を図2、3を参照にして説明する。
NOx検出部1、O2検出部2から出力された信号があるサンプリング間隔で判断・演算部5に取り込まれ、NOx、O2濃度値がそれぞれ算出される。それらの測定値からステップST1で(1)式により換算値が算出される。
入力部3から測定開始又は平均値算出開始の信号が入力されていればステップST2でイエスと判断される。
【0010】
ステップST3で記憶部4に記憶されたNOxしきい値又はO2しきい値とNOx測定値又はO2測定値とがそれぞれ比較される。NOx値を比較する代わりに、換算値のしきい値と換算値とを比較してもよい。
その結果、NOx測定値>NOxしきい値、又はO2測定値<O2しきい値となり、イエスと判断された場合、すなわち、測定対象設備が運転中と判断された場合、ステップST4でそれぞれの値は平均値算出用のデータとして記憶部4に記憶される。
ステップST5で、それぞれの値は測定データとして出力部6から出力される。
【0011】
ステップST3でノーと判断された場合、すなわち、測定対象設備が休止中であると判断した場合は、測定値及び換算値は記憶されず、ステップST5で、測定データとして出力部6から出力される。
ステップST6で平均値算出終了信号が入力されていないことが検知され、ノーと判断された場合、平均値算出終了信号が入力されるまではステップST1からステップST6の動作が繰り返される。ステップST6でイエスと判断された場合、すなわち、平均値算出終了信号が入力された場合、平均値算出開始信号の入力から平均値算出終了信号の入力までの間の時間に運転中のデータとして記憶部4に記憶された複数の換算値の平均値を自動的に算出する。
記憶部4に予め記憶されているそれぞれのしきい値は、NOxしきい値は0ppmに近い値、O2しきい値は21vol%に近い値、換算値のしきい値は0ppmに近い値とする。
【0012】
ステップST3の条件は、NOx値とO2値の両方で判断する。
実施例ではNOx測定装置に適用した一例を示したが、本発明装置はSO2又はCO測定装置にも適用することができる。
測定対象設備の運転・休止を判断できるので、用紙などの保守品の使用時間を減らして交換周期を伸ばすために、休止中は記録計等をストップさせることが好ましい。
【0013】
【発明の効果】
自動で測定対象設備の運転時のデータのみを抜き出して平均値を算出するので、手動でその作業を行なう手間を省くことができる。
測定対象設備の運転・休止にあわせて、測定を断続する必要がないので、オペレータによる操作を簡便にすることができる。
測定対象設備に運転・休止に対応した信号を出力する手段、及び、測定装置に測定対象設備からの運転休止信号を入力する手段を備える必要がないので、コストが低減できる。
よって、ガス測定装置の、換算値の平均値の算出の自動化、操作の簡便化、及びコスト低減化を実施することができる。
【図面の簡単な説明】
【図1】 本発明を適用した一実施例としてのNOx測定装置を示す構成ブロック図である。
【図2】 測定対象設備が休止中のデータを含むNOx濃度測定の測定データ例を示す図である。
【図3】 同実施例の動作を示すフローチャート図である。
【符号の説明】
1 NOx検出部
2 O2検出部
3 入力部
4 記憶部
5 判断・記憶部
6 出力部
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a gas concentration measuring device that measures the concentration of a target component (NOx, SO 2 , CO, O 2, etc.) in a sample gas, and more particularly to an exhaust gas concentration measuring device that measures the concentration of a target component in the exhaust gas of a combustion engine. is there.
[0002]
[Prior art]
The measured value of the oxide concentration that is regulated by the Air Pollution Control Law is determined to be obtained as a value converted into a reference residual oxygen concentration state by the following equation (1) when NOx is taken as an example.
C = (21−On) · Cs / (21−Os) (1)
However, C is the converted NOx concentration (ppm), Cs is the measured NOx concentration value (ppm) in the exhaust gas, On is the reference residual oxygen concentration (vol%), and Os is the measured oxygen concentration value (vol%) in the exhaust gas. Numerical value 21 is the oxygen concentration (vol%) in the atmosphere.
For example, when the equipment to be measured is a boiler, NOx and O 2 contained in the exhaust gas during boiler operation are measured a plurality of times, and the converted value of NOx is calculated from NOx and O 2 at the time of each measurement, and the average of them is calculated. Check if the value is within the emission standards set by the Air Pollution Control Law.
[0003]
Depending on the equipment to be measured, operation and suspension are repeated in a short time. When measuring with a dry type (infrared analyzer, etc.) gas concentration measurement device, the measurement is usually not performed intermittently according to the operation of the equipment to be measured. The average value is calculated by extracting only the data at the time of operation of the measurement target equipment.
In addition, when measurement or measurement value storage is interrupted according to the operation / pause of the measurement target equipment, the measurement target equipment is provided with means for operating the operator or outputting a signal corresponding to the operation / pause. Is provided in the measuring apparatus.
[0004]
[Problems to be solved by the invention]
In the case of continuous measurement, there is a problem that it takes time and labor to extract only the data at the time of operation of the measurement target equipment and calculate the average value.
In addition, when the measurement is to be interrupted, the manual operation becomes complicated in the case of manual operation, and in the case of automatic, means for outputting a signal corresponding to operation / pause to the measurement target equipment, and the pause signal from the measurement target equipment There is a problem that it is expensive to provide the measuring device with a means for inputting.
Therefore, the present invention aims to automate the calculation of the average value, simplify the operation, and reduce the cost of the gas measuring device.
[0005]
[Means for Solving the Problems]
The present invention relates to a gas concentration measuring apparatus having a calculation unit that measures a specific oxide gas concentration in exhaust gas of a combustion engine and obtains an average value within a certain time, and measures an oxide gas concentration measurement value and other component gas measurements. Gas comprising a judgment / calculation unit that compares a value with a preset threshold value, judges operation / stop of the combustion engine based on the comparison result, and calculates an average value by omitting data during the stop It is a concentration measuring device.
For example, the concentration of oxide and O 2 contained in the exhaust gas regulated by the Air Pollution Control Law is always measured by the detector, and the measured values of both oxide and O 2 are stored in advance in the storage. By comparing the threshold value with the judgment / calculation unit, it is automatically judged whether the measurement target equipment is operating data or inactive data. The average value of the measured values within a certain time is calculated by automatically omitting the data during the pause.
[0006]
【Example】
As an embodiment of the present invention, an example of a NOx measuring device using a NOx detector and an O 2 detector as a detection unit will be described. FIG. 1 is a block diagram showing the configuration of a NOx measuring apparatus according to one embodiment.
The NOx measuring device, NOx detector 1 for detecting the NOx contained in exhaust gas, O 2 detects the O 2 detector 2, the average value calculation start signal and the input unit 3 for inputting an end signal, the threshold value Ya Storage unit 4 for storing measurement values, detection signal concentration calculation, conversion value or average value thereof, judgment / arithmetic unit 5 for determining operation / pause of measurement target equipment by comparing with threshold value, and measurement It is comprised from the output part 6 which outputs data.
[0007]
The NOx detector 1 is provided with a NOx detector, measures NOx contained in the exhaust gas, and outputs a detection signal to the determination / calculation unit 5. The O 2 detector 2 is provided with an O 2 detector, measures O 2 contained in the exhaust gas, and outputs a detection signal to the determination / calculation unit 5.
The determination / calculation unit 5, the storage unit 4, the input unit 3, and the output unit 6 in FIG. 1 may use a dedicated control / data processing device that controls the operation of the measurement device and processes data, or a general-purpose device. It may be realized by a computer.
[0008]
FIG. 2 shows an example of measurement data for NOx concentration measurement including data when the measurement target equipment is not operating. The x-axis indicates time, and the y-axis indicates concentration (% FS).
When the measurement target facility is not operating, the atmosphere is being measured, so that O 2 ≈21 vol% and NOx≈0 ppm, and the conversion value calculated therefrom becomes small.
On the other hand, when the measurement target equipment is in operation, when it is burned in the atmosphere, O 2 << 21 vol%, NOx >> 0 ppm, and the conversion value calculated therefrom is 0 ppm.
[0009]
FIG. 3 is a flowchart showing the operation of the embodiment, and the operation will be described with reference to FIGS.
The signals output from the NOx detection unit 1 and the O 2 detection unit 2 are taken into the determination / calculation unit 5 at a certain sampling interval, and the NOx and O 2 concentration values are respectively calculated. A converted value is calculated from these measured values according to equation (1) in step ST1.
If a measurement start or average value calculation start signal is input from the input unit 3, the determination at step ST2 is YES.
[0010]
In step ST3, the NOx threshold value or O 2 threshold value stored in the storage unit 4 is compared with the NOx measurement value or O 2 measurement value. Instead of comparing the NOx value, the threshold value of the converted value and the converted value may be compared.
As a result, NOx measurement value> NOx threshold value, or O 2 measurement value <O 2 threshold value, and when it is determined to be yes, that is, when it is determined that the measurement target equipment is in operation, each at step ST4 Is stored in the storage unit 4 as average value calculation data.
In step ST5, each value is output from the output unit 6 as measurement data.
[0011]
When it is determined NO in step ST3, that is, when it is determined that the measurement target facility is not operating, the measurement value and the converted value are not stored, and are output from the output unit 6 as measurement data in step ST5. .
If it is detected in step ST6 that the average value calculation end signal has not been input and it is determined no, the operations from step ST1 to step ST6 are repeated until the average value calculation end signal is input. If it is determined as YES in step ST6, that is, if an average value calculation end signal is input, it is stored as data during operation at the time between the input of the average value calculation start signal and the input of the average value calculation end signal. An average value of a plurality of converted values stored in the unit 4 is automatically calculated.
The respective threshold values stored in advance in the storage unit 4 are a NOx threshold value close to 0 ppm, an O 2 threshold value close to 21 vol%, and a converted value threshold value close to 0 ppm. To do.
[0012]
The condition of step ST3 is determined by both the NOx value and the O 2 value.
In the embodiment, an example is shown in which the present invention is applied to a NOx measuring apparatus, but the present invention apparatus can also be applied to an SO 2 or CO measuring apparatus.
Since it is possible to determine whether the measurement target facility is in operation or not, it is preferable to stop the recorder or the like during the stop in order to reduce the use time of maintenance items such as paper and extend the replacement cycle.
[0013]
【The invention's effect】
Since only the data at the time of operation of the measurement target equipment is automatically extracted and the average value is calculated, it is possible to save the trouble of manually performing the work.
Since it is not necessary to interrupt the measurement in accordance with the operation / rest of the measurement target facility, the operation by the operator can be simplified.
Costs can be reduced because there is no need to provide means for outputting a signal corresponding to operation / pause to the measurement target facility and means for inputting an operation stop signal from the measurement target facility to the measurement apparatus.
Therefore, automation of calculation of the average value of the conversion value, simplification of operation, and cost reduction of the gas measuring device can be performed.
[Brief description of the drawings]
FIG. 1 is a block diagram showing a configuration of an NOx measuring apparatus as an embodiment to which the present invention is applied.
FIG. 2 is a diagram showing an example of measurement data of NOx concentration measurement including data when the measurement target equipment is not operating.
FIG. 3 is a flowchart showing the operation of the embodiment.
[Explanation of symbols]
1 NOx detection unit 2 O 2 detection unit 3 input unit 4 storage unit 5 judgment / storage unit 6 output unit

Claims (1)

燃焼機関の排ガス中の特定酸化物ガス濃度を測定し、ある時間内の平均値を求めるガス濃度測定装置において、
前記酸化物ガス濃度測定値及び他の成分ガス測定値を予め設定されたしきい値と比較し、該比較結果に基づいて前記燃焼機関の運転・休止を判断し、かつ、休止中のデータを省いて前記平均値を算出する判断・演算部を備えたことを特徴とするガス濃度測定装置。
In the gas concentration measuring device that measures the specific oxide gas concentration in the exhaust gas of the combustion engine and calculates the average value within a certain time,
The oxide gas concentration measurement value and other component gas measurement values are compared with a preset threshold value, and the operation / stop of the combustion engine is determined based on the comparison result, and the data during the stop is A gas concentration measuring apparatus comprising a determination / calculation unit that omits the average value and calculates the average value.
JP15574397A 1997-05-28 1997-05-28 Gas concentration measuring device Expired - Fee Related JP3769879B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15574397A JP3769879B2 (en) 1997-05-28 1997-05-28 Gas concentration measuring device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15574397A JP3769879B2 (en) 1997-05-28 1997-05-28 Gas concentration measuring device

Publications (2)

Publication Number Publication Date
JPH10332617A JPH10332617A (en) 1998-12-18
JP3769879B2 true JP3769879B2 (en) 2006-04-26

Family

ID=15612471

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15574397A Expired - Fee Related JP3769879B2 (en) 1997-05-28 1997-05-28 Gas concentration measuring device

Country Status (1)

Country Link
JP (1) JP3769879B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101673947B1 (en) * 2015-03-02 2016-11-08 주식회사 포스코 Apparatus and method for treating gas

Also Published As

Publication number Publication date
JPH10332617A (en) 1998-12-18

Similar Documents

Publication Publication Date Title
CN1141569C (en) Method and apparatus for remote measurement of exhaust gas
EP1106983A3 (en) Exhaust gas analyzing system
US10309889B2 (en) Exhaust gas analysis system, recording medium recorded with program for exhaust gas analysis system, and exhaust gas analyzing method
SG148843A1 (en) System and method for determining and controlling contamination
JP2021107829A5 (en)
JP3769879B2 (en) Gas concentration measuring device
EP0890789A4 (en) Combustion equipment for flue gas exhausting plants
CN201251547Y (en) Synchronous online monitor device of flue dust and special gas
EP2674752A1 (en) Hydrogen flame ionization type exhaust gas analyzer
CN205301014U (en) Boiler flue gas composition short -term test sampling system
EP1710569A1 (en) Gas analyzer and method for controlling hydrogen flame ionization detector
CN113189269A (en) Method and system for automatically testing smoke dust
JPH09250971A (en) Method and device for inspecting abnormality
JP3617261B2 (en) Continuous particulate measuring device
WO2022113603A1 (en) Gas analysis device, gas analysis method, and program for gas analysis device
JP2002189019A5 (en)
NO960367L (en) Method and apparatus for detecting and / or measuring at least one geophysical parameter from a core sample
JPH11352058A (en) Water quality analyzer
CA1106207A (en) Flow indicator for gas sampling system
KR960002729B1 (en) Circuit for testing buzzer
KR830000415Y1 (en) Alarm monitor device
JP2927041B2 (en) Gas in oil detector
CN1352386A (en) Alarm controller of electronic nose
CN112611879A (en) Analysis method of control system applied to material element analysis of internal combustion engine parts
JPS635001Y2 (en)

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040401

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050527

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20050607

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20051018

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20051215

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060117

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060130

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees