JP3686186B2 - Mold for resin molding and molding method using the same - Google Patents

Mold for resin molding and molding method using the same Download PDF

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JP3686186B2
JP3686186B2 JP27849696A JP27849696A JP3686186B2 JP 3686186 B2 JP3686186 B2 JP 3686186B2 JP 27849696 A JP27849696 A JP 27849696A JP 27849696 A JP27849696 A JP 27849696A JP 3686186 B2 JP3686186 B2 JP 3686186B2
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mold
resin
shape
molding
thin plate
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JPH10119095A (en
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修司 保科
信行 細沼
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Asahi Kasei Chemicals Corp
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Asahi Kasei Chemicals Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、各種熱可塑性樹脂を用いた射出成形に於いて、表面に微細な凹凸形状を付与させるための金型及び該金型を用いた成形方法に関する。特に、面照明装置用導光板の射出成形に適する。
【0002】
【従来の技術】
射出成形は、複雑な形状の成形品を一度の成形で得る事に最大の長所があり、この長所を利用すれば、あらゆる種類の表面形状を付与させる事が可能である。
【0003】
表面に微細な凹凸形状を有する成形品の例として、凹凸形状が規則的に配列したシボパターンにより光散乱を起こさせ、均一に発光する様に工夫された面照明光源用導光板がある。このような面照明光源用導光板に於いては、シボパターンの種類、即ち凹凸部の配列の規則性や形状、大きさを変化させる事により面照明光源の性能を調整する事ができるため非常に有効である。
【0004】
これらのシボパターンを射出成形時に付与させる事により、表面に凹凸状の光散乱部が形成された面照明光源用導光板を得る方法として、例えば特開平4−355409号公報には形状パターンを有する転写シートを成形用金型内に挟み込んで射出成形を行い、得られた成形品から該シートを剥離する事により表面形状を付与した導光板成形品を得る方法、特開平7−159623号公報には面積が任意に変化しかつ底面が粗された凹部を多数形成した金型を用いて導光板成形品を得る方法が開示されている。
【0005】
【発明が解決しようとする課題】
特開平4−355409号公報の方法によれば、凹凸形状を付与させる転写シートの熱的特性及び固定方法についての記載が無く、成形時に転写シートが熱劣化或いは位置ずれを起こし所望の凹凸形状が付与された成形品を効率よく得る事ができない可能性がある。また、凹凸形状が付与された一体成形品を得るために転写シートを剥離する工程が必要である。従って、工業的に安定に生産する方法とは言えない。
【0006】
特開平7−159623号公報の方法によれば、面照明光源に対する各種の要求特性を満足するために発光面の輝度分布を制御するには、凹凸形状のパターンを変化させた金型を随時準備する必要があり、多くの時間と費用を要するため工業的に安定に生産する方法として適当ではない。
【0007】
上記の従来技術に於ける共通の問題点は、微細な凹凸形状を表面に転写させた一体成形品を、要求に応じて凹凸形状のパターンを任意に変更しても工業的に安定に生産できる方法ではないという事である。
【0008】
薄い金属板材料に切削又はエッチング等の方法で表面に凹凸形状を形成させ、該金属板を金型キャビティ内部に固定して射出成形する方法を採用すれば、一回の射出成形工程に於いて凹凸形状を表面に転写させた一体成形品を効率良く得る事ができる。また、薄い金属板材料を用いるため任意の凹凸形状パターンを容易に形成させる事ができ、かつ短時間で低い費用で実施できる。更に、所望の凹凸形状パターンにより該金属薄板を任意に交換する事が可能となり、上記の問題点を解決できる。
【0009】
以上の方法を用いて得られる成形品に於いて微細な凹凸形状の転写性を安定に保つためには、通常は射出圧力や保圧を高く、或いは金型温度を高くする等の条件が用いられる。射出圧力や保圧を高めていくと成形品への凹凸形状の転写性は向上するが、該凹凸形状が微細になる程成形品の金属薄板面への密着力が高まり、離型時に金属薄板が変形し良好な成形品が得られなくなるという新たな問題が生じる。また、安定した転写効果が得られる程度に金型温度を高くすると、表面に凹凸形状を有する金属薄板材質とそれを保持する母型材質との熱膨張率の差によって金属薄板と母型間に隙間が生じ、逆に凹凸形状の転写性が著しく低下するという問題が生じる。
【0010】
本発明の目的は、金型キャビティを形成する面に微細な凹凸形状が施された金属薄板を固定した金型を用いて、該凹凸形状のパターンを要求に応じて任意に変更する事が可能で、かつ該凹凸形状を効果的に転写させた各種熱可塑性樹脂成形品を工業的に安定して生産する方法、およびその成形品を提供する事にある。
【0011】
【課題を解決するための手段】
本発明者らは、上記課題を解決するため鋭意検討した結果、微細な凹凸形状が施された金属薄板が吸引孔を有する入れ子表面に設置され、かつ該金属薄板の特定の位置を枠体で挟み込んだ構造より成る金型を用いる事により、各種熱可塑性樹脂に於いて表面の凹凸形状の転写性に優れた成形品を工業的に安定して得る射出成形方法を見出した。
【0012】
即ち本発明第一は、吸引孔を有する入れ子の表面に、金型キャビティを形成する面に微細な凹凸形状が施された金属薄板を設け、かつ該金属薄板の樹脂ゲート部側の外周部を枠体で挟み込む様にし、他端の樹脂流動末端部側を可動できるような構造にして入れ子の表面に金属薄板を設置して成ることを特徴とする樹脂成形用金型である。
【0013】
本発明第一の金型に於いては、上記の入れ子に於ける吸引孔の直径aと上記金属薄板の厚さtとの比a/tが0.05〜5の範囲にあるのが好ましい。
【0014】
また本発明第二は、上記の金型を用いて射出成形する熱可塑性樹脂の成形方法である。
【0016】
【発明の実施の形態】
以下、本発明を詳細に説明する。
【0017】
本発明に於いて、微細な凹凸形状が施された金属薄板の吸引は、吸引孔を一般の油回転式真空ポンプ等に接続して排気する事により行う事ができる。
【0018】
吸引孔の形状は、吸引側の直径aと排気側の直径bが異なる様な形状である場合、排気時に真空ポンプにかかる負荷を抑制し、各々の吸引孔に於いて均等に吸引させる事ができるため好ましい。例えば、図1(A)に示される様な直径aと直径bが階段状に不連続に変化する形状、図1(B)に示される様な直線又は曲線状に連続して変化する形状等が一例として挙げられる。特に、図1(A)に示される直径aと直径bが階段状に不連続に変化する形状に於いては、直径aの孔の深さLaと直径bの孔の深さLbとの比La/Lbを変える事により吸引時に排気側ポンプにかかる抵抗を低下させる事ができ、同時に加工も容易である点で好ましい。La/Lbの値は0.01〜2の範囲内であれば吸引時の抵抗が小さいため好ましい。また、La/Lbの値がこの範囲内にあれば、各々の吸引孔の形状は製品面領域内の位置によって任意に変化しても良い。
【0019】
吸引孔の個数は特に限定はなく、理論的には1個以上であれば良いが、吸引孔と金属薄板との接触面の粗さの状態や、排気流路に於ける漏れの度合いによって必要となる吸引孔の個数は異なるため、通常は5個以上の吸引孔がある事が好ましい。
【0020】
吸引孔の配置は、金属薄板面上に於ける金型キャビティ内への樹脂の射出側の領域、すなわち樹脂ゲート部(以下、「ゲート部」と記す。)側の領域で多く、それ以外の領域では少ないといった偏った配置である場合は特に好ましい。かかるゲート部は、通常、製品面内ではなく製品面外周部に配置される。
【0021】
図2(A)は、投影図が正方形である製品をゲート部GAから樹脂を充填して得る場合の一例を示しており、金属薄板11は、ゲート部GA側の外周部YAで枠体22により挟み込まれて固定されており、樹脂流動末端部側の外周部ZAは可動できるようになっている。
【0022】
図2(A)に示した例では、ゲート部GA側の外周部YAと樹脂流動末端部側の外周部ZAとの区切りは、ゲート部GAを中心として、ゲート部GAから樹脂流動末端部(図中のPA1及びPA2)までの2分の1になる距離を半径として描いた弧XAで行っている。
【0023】
また図2(B)では、投影図が長方形である製品をゲート部GB1とGB2から樹脂を充填して得る場合の一例を示しており、金属薄板11は、2点のゲート部側の外周部YBで枠体22により挟み込まれて固定されており、樹脂流動末端部側の外周部ZBは可動できるようになっている。
【0024】
図2(B)に示した例では、ゲート部側の外周部YAと樹脂流動末端部側の外周部ZAとの区切りは、各ゲート部を中心として、ゲート部から樹脂流動末端部(図中のPB1及びPB2)までの2分の1になる距離を半径として描いた弧XBで行っている。
【0025】
本発明に於いて、金属薄板外周部の固定領域及び自由領域の設定は上記2例に限定されるものではなく、製品の平面形状やゲート部の位置によって適宜設定することができ、微細な凹凸形状が施された金属薄板はゲート部側の外周部では枠体で挟み込まれて完全に固定され、それ以外の樹脂流動末端部側の外周部では該金属薄板が熱膨張又は熱収縮しても樹脂の流動方向と平行な方向に可動できるようにする。
【0026】
金属薄板の樹脂流動末端部側の外周部を樹脂の流動方向と平行な方向に可動できるようにするには、金属薄板と枠体との間に隙間を設ける事で実現できる。具体的には、枠体と金属薄板面との垂直方向の隙間は0.02〜0.05mm、枠体と金属薄板面と平行方向の隙間は0.05〜0.5mmの間隔を設ける事が好ましい。
【0027】
枠体と金属薄板面との隙間が前記範囲内であれば、金属薄板が可動できかつ成形品のバリ等を生じない点で好ましい。金型キャビティ内へ樹脂が充填されると溶融した樹脂が持つ熱によって該金属薄板が熱膨張し、樹脂の固化温度まで冷却されると収縮するというような変形サイクルを繰り返す。金属薄板の外周全てを完全に固定した場合は、金属薄板表面に於いて熱変形による皺状の外観不良が生じ、一方外周全てを可動できるようにした場合は金属薄板の位置ずれ等が生じ、何れの場合に於いても成形品表面の凹凸形状の転写不良や外観不良を招き好ましくない。
【0028】
尚、前記の図2(A)に示した例では、金属薄板11の外周部分YAでは枠体22で隙間無く挟み込まれ、それ以外の外周部分ZAでは枠体と金属薄板面との垂直方向の隙間として0.04mmの間隔を持たせてキャビティ部21を設けている。図中Dは枠体と金属薄板面と平行方向の隙間である。また図2(B)に示した例では、金属薄板11の外周部分YBで枠体22により隙間無く挟み込まれ、それ以外の外周部分ZBでは枠体と金属薄板面との垂直方向の隙間として0.05mmの間隔が設けられている。
【0029】
また本発明に於いては、微細な凹凸形状が施された金属薄板の厚さtと吸引孔の直径aとの比a/tが0.05〜5の範囲にある事が好ましい。a/tの値がこの範囲にあれば、溶融した樹脂の充填圧力に対する吸引孔の位置上の金属薄板のたわみは無視でき、成形品の外観不良を生じる事がない点で好ましい。
【0030】
本発明に用いる金属薄板表面の微細な凹凸形状は、市販の光学顕微鏡又は電子顕微鏡により観察する事ができる。得られる観察像から、微細な凹凸形状は、凹凸形状単位の規則的な配列によって構成されているか、不均一に表面が粗されているのかが判断できる。
【0031】
凹凸形状単位が規則的に配列して微細凹凸形状が構成されている場合、その構成単位は立方体状、直方体状、円筒状、楕円筒状、プリズム形状、球面状、非球面状の形状等がその一例として挙げられる。これらの形状の配列は、例えばドット状、直線状、曲線状の配列が一例として挙げられる。
【0032】
凹凸形状の高さと配列されている間隔は、縦又は横方向で任意に変化しても良い。その高さと間隔は、光学顕微鏡又は電子顕微鏡の観察像から視覚的に測定する事ができる。
【0033】
また、微細な凹凸形状面が梨地状である場合も好ましく、JIS B0601−1994法により表面粗さの最大高さ(Ry)を測定した時に1〜100μmの範囲にある事が好ましい。梨地状面の表面粗さは、市販の表面粗さ計を用いて測定する事ができる。
【0034】
本発明に用いる微細な凹凸形状が施された金属薄板を得るには、金属薄板材料を用いたエッチング加工法、切削加工法、放電加工法、又は電鋳加工法や鋳造加工法等、従来の公知の技術を使用する事ができる。
【0035】
エッチング加工法は、予め写真フィルム等に凹凸形状を形成しておき、金属薄板面上にフォトレジスト法で凹凸形状に対応したマスクを形成し、その後金属薄板を化学薬品によりエッチングする方法である。
【0036】
電鋳加工法は、先ず鋼鉄、アルミニウム又は黄銅の等の金属材料の表面に所望の凹凸形状を有するマスターをかぶせエッチングにより凹凸形状を形成する方法、あるいは熱可塑性樹脂を成形した平滑な板の面状を切削して所望の凹凸形状を形成する方法により電鋳用の電型を作成し、次にこの電型を電着槽に浸して表面に金属メッキを0.1〜1mmの厚さ範囲で積層させる。その後電着槽から電型を取り出し、積層されたメッキ部分を電型から剥離する事により電型表面の凹凸形状が転写された積層メッキ部分が得られ、これを凹凸形状が施された金属薄板として用いる方法である。
【0037】
本発明第二は、以上の金型を用いて射出成形する熱可塑性樹脂の成形方法であり、かかる成形方法によって得られる成形品の形状、厚みは特に限定されないが、厚みが0.1〜10mm、更に好ましくは0.5〜5mmの範囲内にある板状の成形品が好ましい。この厚み範囲内であれば、厚みが変化する偏肉形状であっても良い。
【0038】
上記成形方法により得られる少なくとも一方の面に微細な凹凸形状が付与された成形品としては、具体的には例えば面照明光源用導光板が挙げられる。液晶表示装置等に用いられる面照明光源装置は特に明るさに対する要求が高く、使用される導光板についても微細凹凸形状の転写性が高い事が望まれている。導光板の少なくとも一方の表面に金属薄板に施した微細凹凸形状を転写する事により導光板表面の発光効率を高める事ができ、また微細凹凸形状パターンを最適化する事により面照明光源装置の輝度が低下せず均一にする事ができる。本発明によれば、要求に応じて凹凸形状のパターンを任意に変更させた面照明光源用導光板を、該凹凸形状の転写性を高めた成形条件下でも工業的に安定して生産する事ができる。
【0039】
本発明に用いられる熱可塑性樹脂は、具体的にはメタクリル樹脂、ポリカーボネート樹脂、ポリスチレン、ゴム補強ポリスチレン、アクリロニトリル−ブタジエン−スチレン共重合体、スチレン−メチルメタクリレート共重合樹脂、スチレン−ブタジエン共重合樹脂、ポリエチレン、ポリプロピレン、非晶質ポリオレフィン樹脂ナイロン6、ナイロン66、変性ポリフェニレンエーテル等が挙げられる。好ましく採用されるものは、メタクリル樹脂又はポリカーボネイト樹脂である。特に好ましく採用されるものはメタクリル樹脂である。
【0040】
メタクリル樹脂は、メタクリル酸メチルを主体とする樹脂が挙げられ、これにはメチルメタクリレートの単独重合体、又はメチルメタクリレートとメチルアクリレート、エチルアクリレート、n−プロピルアクリレート、イソプロピルアクリレート、ブチルアクリレート、アクリロニトリル、アクリル酸、メタクリル酸、ビニルピリジン、ビニルモルホリン、ビニルピリドンテトラヒドロフルフリルアクリレート、N,N−ジメチルアミノエチルアクリレート、N,N−ジメチルアクリルアミド、2−ヒドロキシアクリレート、エチレングリコールモノアクリレート、グリセリンモノアクリレート、無水マレイン酸、スチレン、もしくはα−メチルスチレンなどの共重合可能なモノマーのいずれか一つ以上との共重合体、及び耐熱性アクリル樹脂、低吸湿性アクリル樹脂などが含まれる。これらは単独で用いてもよいしブレンドしてもよい。透明性を維持して耐衝撃性を同時に持たせるためには耐衝撃性アクリル樹脂が用いられ、そのゴム弾性体は特開昭53−58554号公報、同55−94917号公報、同61−32346号公報等に開示されている。簡単に説明すると、アクリル系重合体芯材料のまわりに弾性層及び非弾性層を交互に生成させる多段階逐次重合法により製造される多段重合体である。
【0041】
【実施例】
以下、実施例及び比較例により本発明を具体的に説明する。なお、各実施例及び比較例で用いた金型、成形条件、成形品の評価及び試験方法は次の通りである。
【0042】
(1)微細凹凸形状を有する金属薄板を固定した金型の作製
表面に凹凸形状を施した金属薄板として、0.3mm及び0.05mmの2種類の厚みで直方体状の形状単位をドット状に配列したもの、プリズム形状単位を直線状に配列したもの合計4種類を準備した。図3(A)で示す様に、金属薄板の形状は208×158mmの長方形である。図中P1とP2を結んだ直線上の断面図(図3(B))で示した様に、金属薄板11の裏面に吸引孔を形成した入れ子23を設置し、該金属薄板11の外周4mm幅の部分を枠体22で挟み込む。枠体22は、金属薄板が樹脂の流動末端部で流動方向に可動できるような形状のものと、金属薄板の全外周を隙間なく完全に固定する形状のものを2種類準備した。図中R1で示した外周部分では金属薄板11との隙間が無く、R2で示した外周部分では金属薄板11の面と垂直方向に0.05mmの間隔が設けられた形状になっている。図3に示した枠体22は、図中R1で示した外周部分で金属薄板11との隙間が無く、R2で示した外周部分では金属薄板11の面と垂直方向に0.05mmの間隔が設けられた形状になっており、樹脂が充填されると流動末端部で金属薄板11が流動方向に可動できる構造になっている。また、枠体と金属薄板面と平行方向の間には0.1mmの隙間を設けてある。金属薄板11を吸引するための入れ子23は、吸引孔の直径aが0.3mmのもの、及び1.0mmのものの2種類を準備し、これらは随時交換が可能となるように等しいサイズにした。吸引孔の形状は図4(A)に示す様な階段状、排気側の直径bは3mm、直径aの孔深さLaは3mmとし、直径bの孔深さLbはLaとLbの比La/Lbが0.1〜0.4の範囲内に入る様に吸引孔の位置によって変化させた。また、吸引孔の配置は図4(B)の様にし、排気側面では全ての吸引孔間を1mmの深さの溝で結合させ排気系流路42を作り、これを真空ポンプに接続して0.02Torrの真空度を保ちながら排気した。以上の様にして得られた金型に於いて、表面に金属板の凹凸形状が転写された板状偏肉成形品(投影面は200×150mmの長方形)を得る事ができる。
【0043】
(2)表面に微細凹凸形状を有する射出成形品の成形条件
上記(1)で得た金型を射出成形機(住友重機械工業社製SG−100型)に取り付け、メタクリル樹脂(旭化成工業製、商品名デルペット80NH)を用いて射出成形を行った。成形温度は240℃、金型温度は70℃、射出圧力は175MPa、保圧力は85MPaに設定した。
【0044】
(3)成形品の外観の評価
上記(2)の方法で得られた成形品を目視で観察し、表面凹凸形状の転写性を観察した。転写の不均一に伴う表面ムラが観察される場合は×、転写が均一にされ表面ムラが観察されない場合は○と判定した。
【0045】
(4)面照明光源としての輝度分布測定
上記(2)の方法で得られた板状偏肉成形品36に於いて、図5に示す様に凹凸形状が転写された面に反射フィルム51、反対側の面に拡散フィルム52を貼り付け、成形品の肉厚側端面に冷陰極管53(直径3mm、長さ220mm)を配置しインバーターに接続して面光源照明装置を作成した。冷陰極管を点灯後30分間放置して明るさを安定させた後、発光面を縦横に25分割し各々の位置での輝度を輝度計54(ミノルタカメラ社製CA−1000型)で測定した。得られた各々の輝度値を分布として表現し、輝度最大値、及び輝度均斉度(輝度最小値を輝度最大値で除した値)を導出した。
【0046】
[実施例1〜4、比較例1〜2]
金属薄板の凹凸形状と厚み、及び金属薄板の設置条件を表1に示す通りとして、上記(1)、(2)の方法で金型を得て射出成形を50ショット行った。成形中に於いて成形品の離型状態を観察し、成形終了後には金属薄板の固定状態を確認した。また、成形品の離型や金属薄板の剥離等が生じず安定して成形を行う事ができた成形ショット数を計測した。
【0047】
実施例1、3では、全ショットに於いて成形品は良好に離型し、成形終了後も金属薄板は完全に元の固定状態のままであり、成形前の状態から変化していない。また、安定して成形を行う事ができたと判断される成形ショット数は50ショットであり、非常に好ましい結果であった。
【0048】
実施例2では、金属薄板面上の吸引孔の位置に窪みが生じるが、成形品は45ショットまで良好に離型し、比較的安定に成形できたと判断した。
【0049】
実施例4では、実施例2と同様に金属薄板面上の吸引孔の位置に窪みが生じるが、成形品は40ショットまで良好に離型し、比較的安定に成形できたと判断した。
【0050】
比較例1では、最初の2ショットまで良好に離型するが、その後流動末端部付近で金属薄板の熱膨張により母型から浮き上がってしまい、成形品が良好に離型できない結果となった。安定した成形と判断される成形ショット数はわずかに2ショットであり、好ましくない結果となった。
【0051】
比較例2では、最初のショットに於いて流動末端部付近で金属薄板の熱膨張により母型から浮き上がって皺が生じてしまい、成形品が良好に離型できず安定した成形を行う事ができず、好ましくない結果となった。
【0052】
【表1】

Figure 0003686186
【0053】
[実施例5〜6、比較例3〜4]
実施例1、3及び比較例1、2で得られた成形品を試験片として上記(3)の評価を行った。
【0054】
実施例5、6では、それぞれ実施例1、3で得られた成形品を試験片とした。何れの試験片に於いても、成形品表面全体に渡って凹凸形状が均一に転写されており、外観状態の判定は○であり非常に好ましい結果であった。
【0055】
比較例3では、比較例1で安定して得られた成形品を試験片とした。離型不良を伴わず安定して成形が行えたにもかかわらず、凹凸形状の転写が充分でないため不均一な光散乱に因る模様が生じ、外観状態は×と判定した。
【0056】
比較例4では、比較例2で得られた成形品を試験片とした。金属薄板の熱膨張に伴う皺模様が転写されており、また凹凸形状はほとんど転写されておらず、外観状態の判定は×とした。
【0057】
[実施例7、比較例5]
実施例7では実施例1で得られた成形品を試験片とし、比較例5では比較例1で得られた成形品を試験片として上記(4)の評価を行い、表2に示す結果を得た。
【0058】
実施例7では、輝度最大値は750nt、輝度均斉度は0.72と何れも高い値を示し、均一で明るい面照明光源装置を得る事ができ非常に好ましい結果となった。
【0059】
比較例5では、輝度最大値は340nt、輝度均斉度は0.35と何れも低い値を示し、面照明光源装置として充分な性能が得られず好ましくない結果となった。
【0060】
【表2】
Figure 0003686186
【0061】
【発明の効果】
本発明の金型を用いる事により、微細な凹凸形状のパターンを要求に応じて任意に変更する事が可能で、かつ該凹凸形状を効果的に転写させた各種熱可塑性樹脂成形品を工業的に安定して生産する事ができる。
【図面の簡単な説明】
【図1】本発明に於ける金型を構成する吸引孔の形状の一例を示す断面図である。
【図2】本発明に於ける金型の概念図の一例である。
【図3】本発明の実施例に用いた金型の構成図である。
【図4】本発明の実施例に用いた金型に於ける吸引孔の形状及び配置の説明図である。
【図5】本発明の実施例に用いた面照明光源の輝度分布測定方法の概念図である。
【符号の説明】
11 金属薄板
21 キャビティ部
22 枠体
23 吸引孔を有する入れ子
34 ゲート位置
35 パーティング面
36 板状偏肉成形品
42 排気系流路
51 反射フィルム
52 拡散フィルム
53 冷陰極管
54 輝度計[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a mold for imparting a fine uneven shape to the surface and a molding method using the mold in injection molding using various thermoplastic resins. In particular, it is suitable for injection molding of a light guide plate for a surface illumination device.
[0002]
[Prior art]
Injection molding has the greatest advantage in obtaining a molded product having a complicated shape in a single molding, and by using this advantage, it is possible to give all kinds of surface shapes.
[0003]
As an example of a molded product having a fine concavo-convex shape on the surface, there is a light guide plate for a surface illumination light source that is devised so as to cause light scattering by a texture pattern in which the concavo-convex shape is regularly arranged to emit light uniformly. In such a light guide plate for a surface illumination light source, the performance of the surface illumination light source can be adjusted by changing the type of the embossed pattern, that is, the regularity, shape, and size of the arrangement of the uneven portions. It is effective for.
[0004]
As a method for obtaining a light guide plate for a surface illumination light source in which a concavo-convex light scattering portion is formed on the surface by applying these texture patterns at the time of injection molding, for example, JP-A-4-355409 has a shape pattern. Japanese Patent Application Laid-Open No. 7-159623 discloses a method of obtaining a light guide plate molded product having a surface shape by sandwiching a transfer sheet in a molding die and performing injection molding and peeling the sheet from the obtained molded product. Discloses a method for obtaining a light guide plate molded product using a mold in which a large number of recesses having an arbitrarily changed area and a roughened bottom surface are formed.
[0005]
[Problems to be solved by the invention]
According to the method of Japanese Patent Laid-Open No. 4-355409, there is no description about the thermal characteristics and fixing method of a transfer sheet that gives an uneven shape, and the transfer sheet undergoes thermal deterioration or misalignment during molding, resulting in a desired uneven shape. There is a possibility that the assigned molded product cannot be obtained efficiently. In addition, a process of peeling the transfer sheet is necessary to obtain an integrally molded product with an uneven shape. Therefore, it cannot be said that it is an industrially stable production method.
[0006]
According to the method disclosed in Japanese Patent Laid-Open No. 7-159623, in order to control the luminance distribution of the light emitting surface in order to satisfy various required characteristics for the surface illumination light source, a mold having a concavo-convex pattern is prepared as needed. This requires a lot of time and cost, and is not suitable as an industrially stable production method.
[0007]
A common problem in the above-described prior art is that an integrally molded product in which a fine uneven shape is transferred to the surface can be produced industrially stably even if the uneven shape pattern is arbitrarily changed as required. It is not a method.
[0008]
If a thin metal plate material is formed with irregularities on the surface by a method such as cutting or etching, and the metal plate is fixed inside the mold cavity and injection molding is adopted, in one injection molding process It is possible to efficiently obtain an integrally molded product in which the uneven shape is transferred to the surface. In addition, since a thin metal plate material is used, an arbitrary concavo-convex pattern can be easily formed and can be carried out in a short time and at a low cost. Further, the metal thin plate can be arbitrarily replaced with a desired uneven shape pattern, and the above problems can be solved.
[0009]
In order to stably maintain the transferability of the fine unevenness in the molded product obtained by using the above method, conditions such as high injection pressure and holding pressure or high mold temperature are usually used. It is done. Increasing the injection pressure and holding pressure improves the transferability of the concavo-convex shape to the molded product. However, as the concavo-convex shape becomes finer, the adhesion of the molded product to the metal thin plate surface increases, and the metal thin plate is released during mold release. Deforms and a new problem arises that a good molded product cannot be obtained. Also, if the mold temperature is increased to such a degree that a stable transfer effect can be obtained, the difference between the thermal expansion coefficient between the metal sheet material having a concavo-convex shape on the surface and the matrix material holding it will cause a gap between the metal sheet and the mold. There arises a problem that gaps are generated and conversely the transferability of the uneven shape is remarkably lowered.
[0010]
The object of the present invention is to use a mold in which a thin metal plate having a fine uneven shape is fixed on the surface on which the mold cavity is formed, and the uneven pattern can be arbitrarily changed as required. In addition, an object of the present invention is to provide a method for industrially and stably producing various thermoplastic resin molded products to which the uneven shape is effectively transferred, and the molded products thereof.
[0011]
[Means for Solving the Problems]
As a result of intensive studies to solve the above-described problems, the present inventors have found that a thin metal plate having a fine uneven shape is installed on a nesting surface having suction holes, and a specific position of the thin metal plate is defined by a frame. The present inventors have found an injection molding method for industrially stably obtaining a molded product having excellent surface unevenness transferability in various thermoplastic resins by using a mold having a sandwiched structure.
[0012]
That is, according to the first aspect of the present invention, a thin metal plate having a fine concavo-convex shape on the surface forming the mold cavity is provided on the surface of the nest having suction holes, and the outer peripheral portion of the thin metal plate on the resin gate side is provided. A mold for resin molding characterized in that a metal thin plate is installed on the surface of a nest so that the resin flow end portion side at the other end can be moved so as to be sandwiched between frames.
[0013]
In the first mold of the present invention, the ratio a / t between the suction hole diameter a and the metal sheet thickness t in the nesting is preferably in the range of 0.05 to 5. .
[0014]
The second aspect of the present invention is a method for molding a thermoplastic resin that is injection-molded using the above mold.
[0016]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail.
[0017]
In the present invention, suction of a thin metal plate having a fine uneven shape can be performed by connecting the suction hole to a general oil rotary vacuum pump or the like and exhausting it.
[0018]
When the suction hole has a shape in which the suction-side diameter a and the exhaust-side diameter b are different, the load applied to the vacuum pump during evacuation can be suppressed, and suction can be performed uniformly in each suction hole. This is preferable because it is possible. For example, a shape in which the diameter a and the diameter b change discontinuously as shown in FIG. 1A, a shape that changes continuously in a straight line or a curve as shown in FIG. Is given as an example. In particular, in the shape in which the diameter a and the diameter b change discontinuously in a step shape shown in FIG. 1A, the ratio of the depth La of the diameter a to the depth Lb of the hole of diameter b. Changing La / Lb is preferable in that the resistance applied to the exhaust pump during suction can be reduced, and at the same time, processing is easy. A value of La / Lb is preferably in the range of 0.01 to 2 because the resistance during suction is small. If the value of La / Lb is within this range, the shape of each suction hole may be arbitrarily changed depending on the position in the product surface area.
[0019]
There is no particular limitation on the number of suction holes. Theoretically, the number should be one or more, but it is necessary depending on the roughness of the contact surface between the suction holes and the thin metal plate and the degree of leakage in the exhaust passage. Since the number of suction holes to be different is different, it is usually preferable to have five or more suction holes.
[0020]
The arrangement of the suction holes is large in the region of the resin injection side into the mold cavity on the metal thin plate surface, that is, the region on the resin gate portion (hereinafter referred to as “gate portion”) side. It is particularly preferable when the arrangement is uneven such that there is little in the region. Such a gate portion is usually arranged not on the product surface but on the outer periphery of the product surface.
[0021]
FIG. 2A shows an example in which a product having a square projection view is obtained by filling a resin from the gate portion GA, and the metal thin plate 11 has a frame 22 at the outer peripheral portion YA on the gate portion GA side. The outer peripheral portion ZA on the resin flow end portion side is movable.
[0022]
In the example shown in FIG. 2A, the separation between the outer peripheral portion YA on the gate portion GA side and the outer peripheral portion ZA on the resin flow end portion side is from the gate portion GA to the resin flow end portion ( This is performed with an arc XA in which the distance that is half the distance to PA1 and PA2) in the figure is drawn as a radius.
[0023]
FIG. 2B shows an example in which a product whose projection is rectangular is obtained by filling the resin from the gate parts GB1 and GB2, and the metal thin plate 11 has two outer peripheral parts on the gate part side. The outer peripheral portion ZB on the resin flow end side is movable by being sandwiched and fixed by the frame body 22 at YB.
[0024]
In the example shown in FIG. 2B, the separation between the outer peripheral portion YA on the gate portion side and the outer peripheral portion ZA on the resin flow end portion side is centered on each gate portion from the gate portion to the resin flow end portion (in the figure). PB1 and PB2) in the arc XB drawn with a radius as a half distance.
[0025]
In the present invention, the setting of the fixed region and the free region on the outer peripheral portion of the metal thin plate is not limited to the above two examples, and can be appropriately set according to the planar shape of the product and the position of the gate portion, The shaped thin metal plate is sandwiched and fixed completely by the frame at the outer peripheral portion on the gate portion side, and even if the thin metal plate is thermally expanded or contracted at the other outer peripheral portion on the resin flow end portion side It should be movable in a direction parallel to the resin flow direction.
[0026]
In order to be able to move the outer peripheral portion of the metal thin plate on the resin flow end portion side in a direction parallel to the resin flow direction, it can be realized by providing a gap between the metal thin plate and the frame. Specifically, the vertical gap between the frame and the metal sheet surface is 0.02 to 0.05 mm, and the parallel gap between the frame and the metal sheet surface is 0.05 to 0.5 mm. Is preferred.
[0027]
If the gap between the frame and the metal thin plate surface is within the above range, it is preferable in that the metal thin plate can move and does not cause burrs or the like in the molded product. When the resin is filled into the mold cavity, the metal thin plate is thermally expanded by the heat of the molten resin, and is repeatedly deformed such that the metal sheet contracts when cooled to the solidification temperature of the resin. When the entire outer periphery of the metal thin plate is completely fixed, a saddle-like appearance defect due to thermal deformation occurs on the surface of the metal thin plate, while when the entire outer periphery can be moved, the displacement of the metal thin plate occurs, In either case, it is not preferable because it causes a transfer defect or an appearance defect of the uneven shape on the surface of the molded product.
[0028]
In the example shown in FIG. 2A, the outer peripheral portion YA of the thin metal plate 11 is sandwiched by the frame 22 without a gap, and the other outer peripheral portion ZA is perpendicular to the frame and the thin metal plate surface. The cavity portion 21 is provided with a gap of 0.04 mm as a gap. In the figure, D is a gap in the direction parallel to the frame and the thin metal plate surface. In the example shown in FIG. 2B, the outer peripheral portion YB of the thin metal plate 11 is sandwiched by the frame 22 without any gap, and the other outer peripheral portion ZB is 0 as the vertical gap between the frame and the thin metal plate surface. .05 mm spacing is provided.
[0029]
In the present invention, it is preferable that the ratio a / t between the thickness t of the thin metal plate having fine irregularities and the diameter a of the suction hole is in the range of 0.05 to 5. If the value of a / t is within this range, the deflection of the thin metal plate at the position of the suction hole with respect to the filling pressure of the molten resin can be ignored, which is preferable in that the appearance defect of the molded product does not occur.
[0030]
The fine uneven shape on the surface of the thin metal plate used in the present invention can be observed with a commercially available optical microscope or electron microscope. From the obtained observation image, it can be determined whether the fine concavo-convex shape is constituted by a regular arrangement of concavo-convex shape units or the surface is unevenly uneven.
[0031]
When the concave / convex shape units are regularly arranged to form a fine concave / convex shape, the structural unit may be a cubic shape, a rectangular parallelepiped shape, a cylindrical shape, an elliptical cylindrical shape, a prism shape, a spherical shape, an aspherical shape, or the like. An example is given. Examples of the arrangement of these shapes include dot-like, linear, and curved arrangements, for example.
[0032]
The height of the concavo-convex shape and the arrangement interval may be arbitrarily changed in the vertical or horizontal direction. The height and interval can be visually measured from an observation image of an optical microscope or an electron microscope.
[0033]
Moreover, it is also preferable that the fine uneven surface is a satin-like surface, and it is preferable that it is in the range of 1 to 100 μm when the maximum height (Ry) of the surface roughness is measured by JIS B0601-1994 method. The surface roughness of the textured surface can be measured using a commercially available surface roughness meter.
[0034]
In order to obtain a metal thin plate with a fine uneven shape used in the present invention, an etching method, a cutting method, an electric discharge method, or an electroforming method or a casting method using a metal thin plate material are used. Known techniques can be used.
[0035]
The etching method is a method in which a concavo-convex shape is formed in advance on a photographic film or the like, a mask corresponding to the concavo-convex shape is formed on a metal thin plate surface by a photoresist method, and then the metal thin plate is etched with a chemical.
[0036]
The electroforming method is a method of first forming a concavo-convex shape by etching with a master having a desired concavo-convex shape on the surface of a metal material such as steel, aluminum or brass, or a surface of a smooth plate formed of a thermoplastic resin. An electroforming mold for electroforming is prepared by a method of cutting a shape to form a desired concavo-convex shape. Next, the electroplating is immersed in an electrodeposition bath, and a metal plating is formed on the surface in a thickness range of 0.1 to 1 mm. Laminate with. After that, the electric mold is taken out from the electrodeposition tank, and the laminated plating portion is peeled off from the electric mold to obtain a laminated plating portion on which the uneven shape of the surface of the electric mold is transferred. It is the method used as.
[0037]
The second aspect of the present invention is a method of molding a thermoplastic resin that is injection-molded using the above-mentioned mold, and the shape and thickness of a molded product obtained by such a molding method are not particularly limited, but the thickness is 0.1 to 10 mm. More preferably, a plate-shaped molded product within a range of 0.5 to 5 mm is preferable. If it is within this thickness range, it may be an uneven shape in which the thickness changes.
[0038]
Specific examples of the molded product having a fine uneven shape on at least one surface obtained by the molding method include a light guide plate for a surface illumination light source. A surface illumination light source device used for a liquid crystal display device or the like has a particularly high demand for brightness, and the light guide plate used is also required to have a high transferability of a fine uneven shape. The light emission efficiency on the surface of the light guide plate can be increased by transferring the fine uneven shape on the thin metal plate to at least one surface of the light guide plate, and the brightness of the surface illumination light source device can be improved by optimizing the fine uneven shape pattern. Can be made uniform without decreasing. According to the present invention, a light guide plate for a surface illumination light source having an irregular pattern arbitrarily changed according to demand can be produced industrially and stably even under molding conditions in which the irregular shape is transferred. Can do.
[0039]
The thermoplastic resin used in the present invention is specifically methacrylic resin, polycarbonate resin, polystyrene, rubber reinforced polystyrene, acrylonitrile-butadiene-styrene copolymer, styrene-methyl methacrylate copolymer resin, styrene-butadiene copolymer resin, Examples include polyethylene, polypropylene, amorphous polyolefin resin nylon 6, nylon 66, and modified polyphenylene ether. Those preferably employed are methacrylic resin or polycarbonate resin. Particularly preferred is methacrylic resin.
[0040]
Examples of the methacrylic resin include resins mainly composed of methyl methacrylate, which include a homopolymer of methyl methacrylate, or methyl methacrylate and methyl acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate, butyl acrylate, acrylonitrile, acrylic Acid, methacrylic acid, vinyl pyridine, vinyl morpholine, vinyl pyridone tetrahydrofurfuryl acrylate, N, N-dimethylaminoethyl acrylate, N, N-dimethylacrylamide, 2-hydroxy acrylate, ethylene glycol monoacrylate, glycerin monoacrylate, maleic anhydride A copolymer with at least one of copolymerizable monomers such as acid, styrene, or α-methylstyrene, and heat-resistant acrylic Butter, and the like low hygroscopicity acrylic resin. These may be used alone or in a blend. In order to maintain transparency and have impact resistance at the same time, an impact-resistant acrylic resin is used, and rubber elastic bodies thereof are disclosed in JP-A-53-58554, JP-A-55-94917, and JP-A-61-32346. No. gazette and the like. Briefly, it is a multistage polymer produced by a multistage sequential polymerization method in which an elastic layer and an inelastic layer are alternately formed around an acrylic polymer core material.
[0041]
【Example】
Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. In addition, the metal mold | die used by each Example and the comparative example, molding conditions, evaluation of a molded article, and a test method are as follows.
[0042]
(1) Fabrication of a mold in which a metal thin plate having a fine concavo-convex shape is fixed. As a metal thin plate having a concavo-convex shape on the surface, a rectangular parallelepiped shape unit is formed in two different thicknesses of 0.3 mm and 0.05 mm. There were prepared a total of four types of arrangements and prism arrangement units arranged in a straight line. As shown in FIG. 3A, the shape of the metal thin plate is a rectangle of 208 × 158 mm. As shown in the cross-sectional view on the straight line connecting P1 and P2 in the drawing (FIG. 3B), a nesting 23 having a suction hole is provided on the back surface of the thin metal plate 11, and the outer circumference of the thin metal plate 11 is 4 mm. The width portion is sandwiched between the frame bodies 22. Two types of frame 22 were prepared, one having a shape in which the metal thin plate can be moved in the flow direction at the flow end portion of the resin, and the other having a shape in which the entire outer periphery of the metal thin plate is completely fixed without a gap. In the drawing, there is no gap between the outer peripheral portion indicated by R1 and the thin metal plate 11, and the outer peripheral portion indicated by R2 has a shape in which an interval of 0.05 mm is provided in the direction perpendicular to the surface of the thin metal plate 11. The frame body 22 shown in FIG. 3 has no gap with the thin metal plate 11 at the outer peripheral portion indicated by R1 in the drawing, and the outer peripheral portion indicated by R2 has an interval of 0.05 mm in the direction perpendicular to the surface of the thin metal plate 11. It has a provided shape, and when the resin is filled, the metal thin plate 11 can move in the flow direction at the flow end portion. In addition, a gap of 0.1 mm is provided between the frame body and the metal thin plate surface in the parallel direction. Two types of inserts 23 for sucking the metal thin plate 11 were prepared, one having a suction hole diameter a of 0.3 mm and one having a diameter of 1.0 mm, and these were made the same size so that they could be exchanged at any time. . The shape of the suction hole is stepped as shown in FIG. 4A, the diameter b on the exhaust side is 3 mm, the hole depth La of the diameter a is 3 mm, and the hole depth Lb of the diameter b is the ratio La of La and Lb. / Lb was changed depending on the position of the suction hole so that it was within the range of 0.1 to 0.4. In addition, the suction holes are arranged as shown in FIG. 4B, and on the exhaust side, all the suction holes are joined by a groove having a depth of 1 mm to form an exhaust system flow path 42, which is connected to a vacuum pump. The air was exhausted while maintaining a degree of vacuum of 0.02 Torr. In the mold obtained as described above, it is possible to obtain a plate-shaped uneven-thickness molded product (projection surface is a rectangle of 200 × 150 mm) in which the uneven shape of the metal plate is transferred to the surface.
[0043]
(2) Molding conditions for an injection molded product having fine irregularities on the surface The mold obtained in (1) above is attached to an injection molding machine (SG-100 manufactured by Sumitomo Heavy Industries, Ltd.), and methacrylic resin (manufactured by Asahi Kasei Kogyo) And injection molding was performed using a trade name Delpet 80NH). The molding temperature was 240 ° C., the mold temperature was 70 ° C., the injection pressure was 175 MPa, and the holding pressure was 85 MPa.
[0044]
(3) Evaluation of appearance of molded product The molded product obtained by the above method (2) was visually observed to observe the transferability of the surface uneven shape. When surface unevenness due to non-uniform transfer was observed, it was judged as x, and when transfer was made uniform and surface unevenness was not observed, it was judged as ◯.
[0045]
(4) Luminance distribution measurement as a surface illumination light source In the plate-shaped uneven thickness molded product 36 obtained by the method of (2) above, as shown in FIG. A diffusion film 52 was affixed to the opposite surface, a cold cathode tube 53 (diameter 3 mm, length 220 mm) was placed on the thick-side end surface of the molded product, and connected to an inverter to produce a surface light source illumination device. After the cold-cathode tube was lighted for 30 minutes to stabilize the brightness, the light-emitting surface was divided into 25 vertical and horizontal, and the luminance at each position was measured with a luminance meter 54 (CA-1000 type manufactured by Minolta Camera Co., Ltd.). . Each luminance value obtained was expressed as a distribution, and a luminance maximum value and luminance uniformity (a value obtained by dividing the luminance minimum value by the luminance maximum value) were derived.
[0046]
[Examples 1-4, Comparative Examples 1-2]
With the uneven shape and thickness of the metal thin plate and the installation conditions of the metal thin plate as shown in Table 1, a mold was obtained by the above methods (1) and (2), and injection molding was performed for 50 shots. During molding, the release state of the molded product was observed, and after the molding, the fixed state of the metal thin plate was confirmed. Further, the number of molding shots that could be stably molded without causing release of the molded product or peeling of the metal thin plate was measured.
[0047]
In Examples 1 and 3, the molded product was released satisfactorily in all shots, and the metal thin plate remained completely in the original fixed state even after the completion of molding, and did not change from the state before molding. Further, the number of molding shots judged to have been stably molded was 50 shots, which was a very favorable result.
[0048]
In Example 2, although a depression was generated at the position of the suction hole on the surface of the metal thin plate, it was judged that the molded product was released well up to 45 shots and could be molded relatively stably.
[0049]
In Example 4, although a dent was generated at the position of the suction hole on the metal thin plate surface as in Example 2, it was determined that the molded product was satisfactorily released up to 40 shots and could be molded relatively stably.
[0050]
In Comparative Example 1, the molds were released satisfactorily until the first two shots, but after that, they floated up from the matrix due to the thermal expansion of the metal thin plate in the vicinity of the flow end, and the molded product could not be released satisfactorily. The number of molding shots judged to be stable molding was only 2 shots, which was not preferable.
[0051]
In Comparative Example 2, in the first shot, the metal sheet floats up near the flow end portion due to the thermal expansion, causing wrinkles, and the molded product cannot be released properly and stable molding can be performed. The result was unfavorable.
[0052]
[Table 1]
Figure 0003686186
[0053]
[Examples 5-6, Comparative Examples 3-4]
The evaluation of the above (3) was performed using the molded products obtained in Examples 1 and 3 and Comparative Examples 1 and 2 as test pieces.
[0054]
In Examples 5 and 6, the molded products obtained in Examples 1 and 3 were used as test pieces, respectively. In any of the test pieces, the uneven shape was uniformly transferred over the entire surface of the molded product, and the appearance state was judged as ◯, which was a very preferable result.
[0055]
In Comparative Example 3, the molded product stably obtained in Comparative Example 1 was used as a test piece. In spite of the fact that the molding could be performed stably without any defective mold release, the uneven shape was not sufficiently transferred, so that a pattern due to non-uniform light scattering occurred, and the appearance state was judged as x.
[0056]
In Comparative Example 4, the molded product obtained in Comparative Example 2 was used as a test piece. The wrinkle pattern accompanying the thermal expansion of the metal thin plate was transferred, and the uneven shape was hardly transferred, and the appearance state was judged as x.
[0057]
[Example 7, Comparative Example 5]
In Example 7, the molded article obtained in Example 1 was used as a test piece, and in Comparative Example 5, the molded article obtained in Comparative Example 1 was used as a test piece to evaluate the above (4), and the results shown in Table 2 were obtained. Obtained.
[0058]
In Example 7, the luminance maximum value was 750 nt, and the luminance uniformity was 0.72, which was a high value, and a uniform and bright surface illumination light source device could be obtained.
[0059]
In Comparative Example 5, the maximum luminance value was 340 nt, and the luminance uniformity was 0.35, both of which were low values. As a result, it was not possible to obtain sufficient performance as a surface illumination light source device.
[0060]
[Table 2]
Figure 0003686186
[0061]
【The invention's effect】
By using the mold of the present invention, it is possible to arbitrarily change the pattern of fine uneven shapes as required, and industrially produce various thermoplastic resin molded products in which the uneven shapes are effectively transferred. Can be produced stably.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing an example of a shape of a suction hole constituting a mold in the present invention.
FIG. 2 is an example of a conceptual diagram of a mold in the present invention.
FIG. 3 is a configuration diagram of a mold used in an embodiment of the present invention.
FIG. 4 is an explanatory diagram of the shape and arrangement of suction holes in a mold used in an embodiment of the present invention.
FIG. 5 is a conceptual diagram of a luminance distribution measuring method of a surface illumination light source used in an example of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 11 Metal thin plate 21 Cavity part 22 Frame 23 Nest 34 which has a suction hole Gate position 35 Parting surface 36 Plate-shaped uneven thickness molded article 42 Exhaust system flow path 51 Reflective film 52 Diffusion film 53 Cold cathode tube 54 Luminance meter

Claims (3)

吸引孔を有する入れ子の表面に、金型キャビティを形成する面に微細な凹凸形状が施された金属薄板を設け、かつ該金属薄板の樹脂ゲート部側の外周部を枠体で挟み込む様にし、他端の樹脂流動末端部側を可動できるような構造にして入れ子の表面に金属薄板を設置して成ることを特徴とする樹脂成形用金型。  On the surface of the nesting having the suction holes, a metal thin plate having a fine uneven shape is provided on the surface forming the mold cavity, and the outer peripheral portion on the resin gate portion side of the metal thin plate is sandwiched between frames, A mold for resin molding characterized by having a structure in which the resin flow end side of the other end can be moved, and a thin metal plate is installed on the surface of the insert. 上記の入れ子に於ける吸引孔の直径aと上記金属薄板の厚さtとの比a/tが0.05〜5の範囲にあることを特徴とする、請求項1に記載の樹脂成形用金型。  2. The resin molding according to claim 1, wherein a ratio a / t between a diameter a of the suction hole in the nesting and a thickness t of the metal thin plate is in a range of 0.05 to 5. 5. Mold. 請求項1又は2に記載の金型を用いて射出成形することを特徴とする熱可塑性樹脂の成形方法。  A method for molding a thermoplastic resin, wherein injection molding is performed using the mold according to claim 1.
JP27849696A 1996-10-22 1996-10-22 Mold for resin molding and molding method using the same Expired - Fee Related JP3686186B2 (en)

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JP2004050685A (en) * 2002-07-22 2004-02-19 Asahi Kasei Chemicals Corp Metal plate for manufacturing light guide plate, method for manufacturing light guide plate using the same and light guide plate
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JP2006315240A (en) * 2005-05-11 2006-11-24 Dainippon Toryo Co Ltd In-mold coat molding method for coated molding excellent in designability
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