JP3650202B2 - Rice cake-like food and its manufacturing method - Google Patents
Rice cake-like food and its manufacturing method Download PDFInfo
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- JP3650202B2 JP3650202B2 JP01816296A JP1816296A JP3650202B2 JP 3650202 B2 JP3650202 B2 JP 3650202B2 JP 01816296 A JP01816296 A JP 01816296A JP 1816296 A JP1816296 A JP 1816296A JP 3650202 B2 JP3650202 B2 JP 3650202B2
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Description
【0001】
【発明の属する技術分野】
この発明は、ぜんざい等のレトルト食品として有用な餅様食品とその製造方法に関する。
【0002】
【従来の技術】
近年、ぜんざい、あんみつ、雑煮等の餅入りレトルト食品が商品化され、市販されている。餅入りレトルト食品の保存性を高め、食に供する際につきたての餅に近い食感を出すようにすることは、簡単ではない。特に、レトルト殺菌時の加熱で餅が型くずれすること、長期保存により餅が老化すること、食する際の加熱により型くずれがすること、等が大きな問題になる。
【0003】
レトルト殺菌時の加熱条件下での餅の型くずれを防止する技術として、餅にLMペクチン及び/又はアルギン酸ナトリウムを含有させ、餅を包む外液中にカルシウム塩を含ませて、餅と外液の浸透圧をほぼ等しくする方法が提案されている(特公平4−40979号公報)。この方法は、餅に含ませたLMペクチン又はアルギン酸ナトリウムと外液中のカルシウム塩の反応により餅の保型性を改善しようとするものである。
【0004】
【発明が解決しようとする課題】
しかし、上記従来の方法では、レトルト殺菌時の型くずれはある程度改善されるものの、その後の保存による餅の老化はそれほど避けられず、冷たいまま食すると固く、また食する際に加熱すると型くずれ(ダレ)が生じて、本来の餅の食感が得られない。更に、餅の外側部分でのアルギン酸ナトリウムとカルシウム塩との反応に起因するざらついた食感が残るという問題がある。
【0005】
この発明は、上記事情を考慮してなされたもので、化工澱粉を主剤として用いて、加熱時の型くずれがなく、老化も少なく、保存後の食感も優れた餅様食品及びその製造方法を提供することを目的としている。
【0006】
【課題を解決するための手段】
この発明に係る餅様食品は、化工澱粉を主剤とし、均一分散させたカルシウムにより不溶化したアルギン酸を含んでゲル化させてなることを特徴とする。
この発明において用いられる化工澱粉は、タピオカ澱粉、馬鈴薯澱粉、ワキシコーン澱粉、米澱粉、甘藷澱粉、小麦澱粉の中から選ばれた少なくとも1種を化工したものとする。
この発明において用いられる化工澱粉はまた、エステル化澱粉、アセチル化澱粉、エーテル化澱粉の中から選ばれた少なくとも1種とする。
【0007】
この発明による餅様食品の製造方法は、化工澱粉を主原料とし、これに可溶化させたアルギン酸と共にカルシウム塩を配合し、加水加熱して凝固させることを特徴とする。
【0008】
この発明による餅様食品は、化工澱粉を主剤として、可溶化されたアルギン酸をカルシウム塩と反応させて均一にゲル化させたものであり、初期においては実際の餅に比べてゲル状感があるものの、保型性に優れ、レトルト殺菌時やその後の加熱によっても型くずれが少なく、餅様の柔らかさを保ってしかもベトつかない優れた食感が得られる。また化工澱粉を用いるため餅に比べて老化が少ない。またこの発明においては、カルシウム塩を食品全体に均一に分散された状態でゲル化させるため、従来技術のように、餅に添加したアルギン酸を餅の外側でのみカルシウム塩と反応させる方法と異なり、全体としてカルシウム塩の成分比を小さくして、ざらざら感のない優れた食感を得ることができる。
【0009】
この発明において、主剤とする化工澱粉の含有量は、餅食感を得るに必要な量として、10〜40%の範囲で選択される。化工澱粉の量がこの範囲を外れると、餅食感が固くなったり、糊状感が出たりする。また主剤とともに砂糖等の糖分を必要に応じて加えることができる。アルギン酸の含有量は、0.01〜2%の範囲、より好ましくは、0.1〜0.4%の範囲で使用される。アルギン酸の含有量がこの範囲より少ないと、レトルトによりダレてしまい、多いと食感が固くなりすぎて餅食感からずれてしまう。
【0010】
【発明の実施の形態】
以下、この発明の実施例を説明する。
この発明において用いられる化工澱粉の原料となる澱粉としては、タピオカ澱粉、馬鈴薯澱粉、ワキシコーン澱粉、米澱粉、その他甘藷澱粉、小麦澱粉、サゴヤシ澱粉等が用いられる。これらの澱粉は、種々の無機酸、有機酸とエステルを作り、もともとの澱粉にない耐老化性や膨潤性、凝固性等の性質を化工澱粉とすることができる。
具体的にこれらの原料澱粉から作られ、この発明において用いられる化工澱粉とては、エステル化澱粉、アセチル化澱粉、エーテル化澱粉等がある。
【0011】
エステル化澱粉としては、正リン酸塩やトリポリリン酸塩等のリン酸塩によるモノエステル型リン酸澱粉、ヘキサメタリン酸塩やトリメタリン酸塩等のリン酸によるジエステル型リン酸澱粉が使用される。これらのリン酸架橋澱粉のエステル化度は、置換度DS(Degree of Substitution)により表され、この発明においては、DS=0.3以下、より好ましくは、DS=0.02〜0.1のものを用いることで、アルギン酸を用いてゲル化したときに餅様の食感を得ることができる。
【0012】
アセチル化澱粉は、上述の原料澱粉から選ばれた澱粉に、無水酢酸や酢酸等のアセチル基を導入して得られる。
エーテル化澱粉は、上述の原料澱粉から選ばれた澱粉に、酸化プロピレンを用いてヒドロキシプロピル基を導入することにより得られる。
これらの化工澱粉の場合も、DS=0.2以下でやはり、アルギン酸を用いてゲル化して餅様の食感を得ることができる。
【0013】
この発明における餅様食品は、上述した化工澱粉を主原料として、これに可溶化されたアルギン酸、及び難溶性カルシウム塩を混合して作られる。具体的には例えば、これらの原料粉体を混合し、加水して混練加熱する。場合によっては、温湯で加水混合した原料を餅つき機でついたり、ミキシングにより混練してつくることもできる。但し精製されたアルギン酸は水に不溶であるから、炭酸ナトリウム等のアルカリ塩と併用とすることにより、加熱溶解の過程で可溶化する。
【0014】
上述の混練加熱により、アルギン酸は炭酸ナトリウムと反応して可溶化し、やがてカルシウム塩と反応して、不溶性のゲルを作ることになる。加水加熱により化工澱粉等の澱粉質がα化する段階で同時にアルギン酸の可溶化が進むことで、粘性が一気に上がりすぎることが防止されるため、混練加熱の作業性は高いものとなる。また均一に分散させた難溶性のカルシウム塩は、アルギン酸溶液が一気に反応して不均一な凝固を起こすことを防ぐ働きをし、この結果均一な凝固を得ることができる。
【0015】
可溶化されたアルギン酸として、予め炭酸ナトリウムと反応させたアルギン酸ナトリウムの乾燥粉末を用いることもできる。但しこれを用いると、加熱溶解の際に、アルギン酸を用いた場合に比べて粘性が速く出てしまうので、混練加熱の作業性に難点がある。しかし、難溶性カルシウム塩を若干多めに加える等の工夫により、粘性の上昇を緩くして、均一なゲル化を実現することが可能である。
【0016】
なお、難溶性のカルシウム塩としては、クエン酸カルシウム、グリセロリン酸カルシウム、リン酸カルシウム(オルト、メタ、パラを含む)、炭酸カルシウム等が用いられる。
また、これらの難溶性カルシウム塩と別に、可溶性カルシウム塩を用いることもできる。可溶性カルシウム塩を用いる場合には、カルシウム塩を除く原料粉体を加水し混練加熱した後に、カルシウム塩の水溶液を加える方法を採る。但しこの方法は、難溶性カルシウム塩を他の原料と同時に混合する方法に比べて、不均一な凝固を生じ易い。
【0017】
またこの発明において、上述した原料に更に、糯粉、粳粉、糯澱粉、粳澱粉、タピオカ澱粉、ワキシコーン澱粉、馬鈴薯澱粉等を適宜補助的に加えることができる。
【0018】
【実施例】
具体的に、次表1のような配合で餅様食品を作った。
【0019】
【表1】
【0020】
上の原料のうち先ず粉体原料を全て混合し、これに加水して混練加熱し、約30分練り上げた。十分に練り上げた後、これを薄く拡げて冷却凝固させた。その後、餅の切断と同様に、一口大(約2cm角)にカットして、餅様食品とした。
【0021】
得られた餅様ゲル化食品を、▲1▼レトルト殺菌前、▲2▼レトルト殺菌後15℃まで冷却した状態、▲3▼更にこれを100℃で加熱し70℃まで下げた状態で、それぞれゼリー強度、型くずれの様子、食感テスト等を行った。その結果を比較例と共に下表2に示す。
なお比較例1,2はそれぞれ、特公平4−40979号明細書における実施例16(LMペクチン含有)、実施例17(アルギン酸ナトリウム含有)に相当する試作品である。食感テストは、本来の餅の食感に対するパネラーによる10点法での採点である。
【0022】
【表2】
【0023】
以上の結果から、比較例1,2は共に、レトルト殺菌、更にその後の加熱によってゼリー強度が大きく低下しているのに対して、この実施例のものはゼリー強度の低下は小さく、型くずれは殆どない。
食感については、比較例1は再加熱後はダレて餅本来の食感が殆どなくなっている。比較例2は比較例1に比べるとダレが少ないが、レトルト殺菌後や再加熱後にざらついた食感となっている。この実施例のものは、初期の段階で餅粉主体の比較例1,2に比べて若干のゲル状感があるものの、レトルト殺菌後、更にその後の加熱後も大きな変化はなく、良好な食感を示す。
【0024】
【発明の効果】
以上述べたようにこの発明によれば、化工澱粉を主剤として、可溶化されたアルギン酸をカルシウム塩と反応させて均一にゲル化させることにより、保型性に優れ、レトルト殺菌時やその後の加熱によっても型くずれが少なく、老化も少なく、餅様の柔らかさを保ってしかもベトつかない優れた食感が得られる餅様食品を得ることができる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a koji-like food useful as a retort food such as zenzai and a method for producing the same.
[0002]
[Prior art]
In recent years, retort foods with rice cakes such as zenzai, anmitsu and simmered noodles have been commercialized and marketed. It is not easy to improve the preservability of retort-containing foods with a koji and give a texture close to that of fresh koji. In particular, there are major problems such as losing mold due to heating during retort sterilization, aging of cocoons due to long-term storage, and losing mold due to heating during eating.
[0003]
As a technique for preventing the deformation of the cocoon under heating conditions during retort sterilization, the cocoon contains LM pectin and / or sodium alginate, and the external liquid that wraps the cocoon contains a calcium salt. A method for making the osmotic pressure substantially equal has been proposed (Japanese Patent Publication No. 4-40979). This method is intended to improve the shape retention of the cocoon by the reaction of LM pectin or sodium alginate contained in the cocoon and the calcium salt in the external solution.
[0004]
[Problems to be solved by the invention]
However, in the above conventional method, although the shape loss at the time of retort sterilization is improved to some extent, aging of the cocoon due to subsequent storage is unavoidable, and it is hard to eat while it is cold, and when it is heated, it loses shape (sag) Occurs, and the texture of the original candy cannot be obtained. Furthermore, there is a problem that a rough texture due to the reaction between sodium alginate and calcium salt in the outer part of the cocoon remains.
[0005]
This invention has been made in view of the above circumstances, and uses a modified starch as a main ingredient, a mold-like food with no aging, little aging, and excellent texture after storage, and a method for producing the same It is intended to provide.
[0006]
[Means for Solving the Problems]
The koji-like food according to the present invention is characterized in that it contains alginic acid insolubilized by calcium, which is uniformly dispersed, with a modified starch as a main ingredient.
The modified starch used in the present invention is obtained by modifying at least one selected from tapioca starch, potato starch, waxy corn starch, rice starch, sweet potato starch and wheat starch.
The modified starch used in the present invention is at least one selected from esterified starch, acetylated starch, and etherified starch.
[0007]
The method for producing a koji-like food according to the present invention is characterized in that a modified starch is used as a main raw material, a calcium salt is blended with alginic acid solubilized therein, and the mixture is heated and coagulated.
[0008]
The rice cake-like food according to the present invention is obtained by uniformizing gelatinized by reacting solubilized alginic acid with a calcium salt using a modified starch as a main ingredient, and initially has a gel-like feeling as compared with an actual rice cake. However, it is excellent in shape retention, has little shape loss even during retort sterilization and subsequent heating, and has an excellent texture that is not sticky while maintaining its softness. In addition, the use of modified starch reduces aging compared to koji. In this invention, in order to gel the calcium salt in a state of being uniformly dispersed throughout the food, unlike the conventional technique, the alginic acid added to the koji is reacted with the calcium salt only outside the koji, As a whole, the component ratio of the calcium salt can be reduced to obtain an excellent texture without rough feeling.
[0009]
In the present invention, the content of the modified starch as the main agent is selected in the range of 10 to 40% as an amount necessary for obtaining a gluttonous feeling. When the amount of the modified starch is out of this range, the gluttony feeling becomes hard or a paste-like feeling appears. Moreover, sugars, such as sugar, can be added with a main ingredient as needed. The content of alginic acid is used in the range of 0.01 to 2%, more preferably in the range of 0.1 to 0.4%. If the content of alginic acid is less than this range, it will sag due to retort, and if it is too much, the texture becomes too hard and deviates from the engorged texture.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Examples of the present invention will be described below.
As starch used as a raw material for the modified starch used in the present invention, tapioca starch, potato starch, waxy corn starch, rice starch, other sweet potato starch, wheat starch, sago palm starch and the like are used. These starches can produce various inorganic acids and organic acids and esters, and can be made into modified starches with properties such as aging resistance, swelling property, and coagulation property that are not found in the original starch.
Specifically, the modified starch made from these raw material starches and used in the present invention includes esterified starch, acetylated starch, etherified starch and the like.
[0011]
As the esterified starch, monoester phosphate starch using phosphate such as normal phosphate or tripolyphosphate, or diester phosphate starch using phosphoric acid such as hexametaphosphate or trimetaphosphate is used. The esterification degree of these phosphoric acid crosslinked starches is represented by a substitution degree DS (Degree of Substitution). In the present invention, DS = 0.3 or less, more preferably DS = 0.02 to 0.1. By using a thing, when it gelatinizes using alginic acid, a candy-like food texture can be obtained.
[0012]
The acetylated starch is obtained by introducing an acetyl group such as acetic anhydride or acetic acid into starch selected from the above-mentioned raw material starch.
The etherified starch is obtained by introducing a hydroxypropyl group into the starch selected from the above-mentioned raw material starch using propylene oxide.
In the case of these modified starches, DS = 0.2 or less can be gelled with alginic acid to obtain a candy-like texture.
[0013]
The koji-like food in this invention is made by mixing the above-mentioned modified starch as a main raw material with alginic acid solubilized therein and a sparingly soluble calcium salt. Specifically, for example, these raw material powders are mixed, added and kneaded and heated. In some cases, the raw material mixed with warm water can be prepared with a kneader or kneaded by mixing. However, since purified alginic acid is insoluble in water, it is solubilized in the process of heating and dissolving by using it together with an alkali salt such as sodium carbonate.
[0014]
By the kneading and heating described above, alginic acid reacts with sodium carbonate to solubilize, and eventually reacts with calcium salt to form an insoluble gel. Since the solubilization of alginic acid proceeds at the same time as the starch quality such as modified starch becomes α by hydrothermal heating, the viscosity is prevented from excessively rising, so that the workability of the kneading heating becomes high. Further, the poorly soluble calcium salt uniformly dispersed serves to prevent the alginic acid solution from reacting at once and causing non-uniform solidification, and as a result, uniform solidification can be obtained.
[0015]
As the solubilized alginic acid, a dry powder of sodium alginate previously reacted with sodium carbonate can also be used. However, if this is used, the viscosity of the kneading and heating work will be difficult since the viscosity will be higher when heated and dissolved than when alginic acid is used. However, it is possible to achieve uniform gelation by loosening the increase in viscosity by means such as adding a slightly more insoluble calcium salt.
[0016]
In addition, as the hardly soluble calcium salt, calcium citrate, calcium glycerophosphate, calcium phosphate (including ortho, meta, para), calcium carbonate and the like are used.
In addition to these poorly soluble calcium salts, soluble calcium salts can also be used. When a soluble calcium salt is used, a method of adding an aqueous solution of calcium salt after adding and kneading and heating the raw material powder excluding the calcium salt is employed. However, this method tends to cause non-uniform solidification as compared with a method in which a hardly soluble calcium salt is mixed simultaneously with other raw materials.
[0017]
In the present invention, koji powder, koji powder, koji starch, koji starch, tapioca starch, waxy corn starch, potato starch, and the like can be added as appropriate to the above-described raw materials.
[0018]
【Example】
Specifically, a candy-like food was prepared with the formulation shown in Table 1 below.
[0019]
[Table 1]
[0020]
First of all, the powder raw materials of the above raw materials were mixed, added to this, kneaded and heated, and kneaded for about 30 minutes. After fully kneaded, it was spread thinly and allowed to cool and solidify. Then, like the cutting of the koji, it was cut into bite-sized (about 2 cm square) to make a koji-like food.
[0021]
(1) Before retort sterilization, (2) In a state cooled to 15 ° C. after retort sterilization, and (3) In a state further heated at 100 ° C. and lowered to 70 ° C. Jelly strength, deformation of the mold, texture test, etc. were performed. The results are shown in Table 2 below together with comparative examples.
Comparative Examples 1 and 2 are prototypes corresponding to Example 16 (containing LM pectin) and Example 17 (containing sodium alginate) in JP-B-4-40979, respectively. The texture test is a 10-point scoring by a panelist with respect to the actual texture of the salmon.
[0022]
[Table 2]
[0023]
From the above results, in both Comparative Examples 1 and 2, the jelly strength was greatly reduced by retort sterilization and further heating, whereas in this example, the decrease in jelly strength was small, and there was almost no mold loss. Absent.
Regarding the texture, Comparative Example 1 sagged after reheating, and the original texture of the koji was almost lost. Comparative Example 2 has less sagging than Comparative Example 1, but has a rough texture after retort sterilization and after reheating. Although this example has a slight gel-like feeling in comparison with Comparative Examples 1 and 2 mainly composed of starch at the initial stage, it does not change greatly after retort sterilization and further after heating. Show a feeling.
[0024]
【The invention's effect】
As described above, according to the present invention, by using a modified starch as a main ingredient, solubilized alginic acid is reacted with a calcium salt to be uniformly gelled, thereby providing excellent shape retention and heating during retort sterilization or subsequent heating. According to the above, it is possible to obtain a candy-like food that has less mold loss, little aging, has a candy-like softness, and has an excellent texture that is not sticky.
Claims (4)
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JP01816296A JP3650202B2 (en) | 1996-01-08 | 1996-01-08 | Rice cake-like food and its manufacturing method |
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JP01816296A JP3650202B2 (en) | 1996-01-08 | 1996-01-08 | Rice cake-like food and its manufacturing method |
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JP3650202B2 true JP3650202B2 (en) | 2005-05-18 |
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JP6092831B2 (en) * | 2014-10-10 | 2017-03-08 | 株式会社エルビー | Process for producing rice cake processed food and method for producing beverage containing rice cake processed food |
JP6512519B2 (en) * | 2016-08-18 | 2019-05-15 | 長岡香料株式会社 | Moldy food |
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CN111567741A (en) * | 2020-04-20 | 2020-08-25 | 安徽粮悦大吃兄食品科技有限公司 | Chocolate rice crust and preparation method thereof |
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1996
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