JP3167105B2 - Freeze-resistant tofu and method for producing the same - Google Patents

Freeze-resistant tofu and method for producing the same

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Publication number
JP3167105B2
JP3167105B2 JP06366496A JP6366496A JP3167105B2 JP 3167105 B2 JP3167105 B2 JP 3167105B2 JP 06366496 A JP06366496 A JP 06366496A JP 6366496 A JP6366496 A JP 6366496A JP 3167105 B2 JP3167105 B2 JP 3167105B2
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Japan
Prior art keywords
starch
tofu
parts
weight
texture
Prior art date
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Expired - Fee Related
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JP06366496A
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Japanese (ja)
Other versions
JPH09215479A (en
Inventor
尚幸 家郷
有紀子 枡本
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Nippon Starch Chemical Co Ltd
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Nippon Starch Chemical Co Ltd
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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、冷凍保存しても豆
腐特有の性状を良好に保持できる、冷凍耐性を特徴とす
る豆腐の製造方法に関する。即ち、各種の食品(例え
ば、みそ汁、すき焼き、マーボー豆腐等の冷凍食品)の
具材となる好適な食感と冷凍耐性を併せ持った豆腐の製
造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing tofu characterized by freezing resistance, which can maintain good properties of tofu even when stored frozen. That is, the present invention relates to a method for producing tofu having suitable texture and freezing resistance to be used as ingredients for various foods (for example, frozen foods such as miso soup, sukiyaki, and marbo tofu).

【0002】[0002]

【従来の技術】豆腐を冷凍すると、解凍時に離水が激し
く、組織が破壊されるため豆腐本来のテクスチャーを保
持することができなかった。従って、従来では、生豆腐
を凍結乾燥することにより「凍豆腐」という全く異なる
食品として扱われてきた。
2. Description of the Related Art When tofu is frozen, water separation is severe at the time of thawing and tissue is destroyed, so that the original texture of tofu cannot be maintained. Therefore, conventionally, by freeze-drying raw tofu, it has been treated as a completely different food product called “frozen tofu”.

【0003】この改善方法として、ゲル化剤並びに糖類
系処理剤を添加する方法(特開平5−316984号)
が提案されており、糖類系処理剤として、可溶性デンプ
ンやシクロデキストリンが好ましいとしている。この方
法では、凍結解凍後の離水は若干改善されるが、凍結前
に比べ硬く、弾力性などの点で好ましくない。
[0003] As a method of improving this, a method of adding a gelling agent and a saccharide-based treating agent (Japanese Patent Laid-Open No. 5-316984).
And disclose that soluble starch and cyclodextrin are preferable as the saccharide-based treating agent. In this method, water separation after freezing and thawing is slightly improved, but is harder than before freezing and is not preferable in terms of elasticity and the like.

【0004】また、油脂、澱粉、増粘剤等の添加(特開
平5−336916号)が提案されるが、澱粉として
は、食品に利用できるものであればどれでもよいとして
いる。この方法では、豆腐の組織破壊は若干改善される
が、凍結解凍後の離水が激しく、凍結前に比べ硬く、バ
サバサした感じになる。
Further, addition of fats and oils, starch, thickeners and the like has been proposed (Japanese Patent Application Laid-Open No. 5-336916), but any starch that can be used in foods is mentioned. With this method, the tissue destruction of the tofu is slightly improved, but the water separation after freezing and thawing is severe, and the tofu has a harder and rougher feel than before freezing.

【0005】[0005]

【発明が解決しようとする課題】これらの諸問題即ち、
豆腐に冷凍耐性を与え、しかも好適なゲル強度を保持す
るという課題を克服し、解凍しても、保水性にすぐれ、
豆腐の滑らかさ、弾力性に富む、食感の良い豆腐を提供
することにある。
SUMMARY OF THE INVENTION These problems, namely,
Overcoming the problem of imparting tofu with freezing resistance and maintaining a suitable gel strength, even when thawed, it has excellent water retention,
An object of the present invention is to provide a tofu that is rich in smoothness and elasticity and has a good texture.

【0006】[0006]

【課題を解決するための手段】本発明者等は検討を重ね
た結果、上記の提案に残る問題、即ち豆腐に冷凍耐性を
与え、しかも好適なゲル強度を保持するという問題を、
タピオカ澱粉、馬鈴薯澱粉又はワキシコーンスターチを
原料とする置換度が0.04〜0.2の範囲であるエー
テル化澱粉を使用することで著しく改善出来ることを見
いだし、本発明を完成した。
As a result of repeated studies by the present inventors, the problem remaining in the above proposal, that is, the problem of imparting freezing resistance to tofu and maintaining a suitable gel strength, was solved.
The present inventors have found that the use of tapioca starch, potato starch or waxy corn starch as a raw material and the use of etherified starch having a substitution degree in the range of 0.04 to 0.2 can significantly improve the present invention, and completed the present invention.

【0007】[0007]

【発明の実施の形態】本発明に於ける化工澱粉に施した
エーテル化としては、ヒドロキシプロピル化、ヒドロキ
シルエチル化、カルボキシルメチル化などのエーテル化
を示すことができ、この化工は、通常よく知られる薬剤
を使用して常法に従って反応することにより容易に達成
される。例えば反応薬剤としては、ヒドロキシプロピル
化の場合は酸化プロピレンを例示できる。また、本発明
のエーテル化による物性を損ねない程度に軽度の酸化、
酸処理または漂白処理、架橋処理を行ってもよい。
BEST MODE FOR CARRYING OUT THE INVENTION The etherification applied to the modified starch in the present invention may be etherification such as hydroxypropylation, hydroxylethylation, carboxymethylation, etc., and these modifications are generally well known. This can be easily achieved by reacting according to a conventional method using a given drug. For example, in the case of hydroxypropylation, propylene oxide can be exemplified as a reactive agent. Further, mild oxidation to the extent that the physical properties of the etherification of the present invention are not impaired,
An acid treatment, a bleaching treatment, and a crosslinking treatment may be performed.

【0008】本発明に於けるエーテル化の置換度(D.
S.)とは無水グルコース残基1個当たりの置換水酸基
の平均値を言い、D.S.0.04〜0.2の範囲であ
るタピオカ澱粉、馬鈴薯澱粉又はワキシコーンスターチ
を使用するのが好ましく、置換度0.04以下では冷凍
耐性が不充分で、やや離水が多くなり良くない。又0.
2以上の置換度になると豆腐に粘性が生じ、豆腐本来の
食感が失われる。
In the present invention, the degree of substitution of etherification (D.
S. ) Means the average value of substituted hydroxyl groups per anhydroglucose residue. S. It is preferable to use tapioca starch, potato starch or waxy corn starch having a range of 0.04 to 0.2. When the substitution degree is 0.04 or less, the freezing resistance is insufficient, and the water separation is slightly increased, which is not good. Also 0.
When the degree of substitution is 2 or more, the tofu becomes viscous, and the original texture of the tofu is lost.

【0009】本発明の実施例に用いる離水率とは、製造
後の豆腐重量と凍結解凍後の豆腐重量の差を製造後の豆
腐重量で除した値である。
The water separation rate used in the examples of the present invention is a value obtained by dividing the difference between the weight of tofu after production and the weight of tofu after freezing and thawing by the weight of tofu after production.

【0010】本発明の実施例に用いる破断強度とは、厚
さ3cmの測定用豆腐試料片をレオメーター(不動工業
(株)製)を使用して、10mm径球形プランジャー
で、破断したときの強度を3回測定した平均値とした。
尚、テーブル上昇速度は6cm/minとした。
[0010] The breaking strength used in the examples of the present invention means that a 3 cm-thick tofu sample for measurement is broken with a 10 mm diameter spherical plunger using a rheometer (manufactured by Fudo Industry Co., Ltd.). Was taken as an average value measured three times.
The table rising speed was 6 cm / min.

【0011】本発明に使用する化工澱粉の添加量は置換
度の種類、置換度により若干の違いがあるが、豆乳10
00重量部に対し5〜40重量部である。5重量部以下
では、冷凍耐性が不充分で効果が少ない。又、40重量
部以上では豆腐の食感が失われ好ましくない。
The amount of the modified starch used in the present invention varies slightly depending on the type of substitution degree and the substitution degree.
It is 5 to 40 parts by weight with respect to 00 parts by weight. If the amount is less than 5 parts by weight, the freezing resistance is insufficient and the effect is small. If the amount is more than 40 parts by weight, the texture of the tofu is lost, which is not preferable.

【0012】本発明に使用する凝固剤は、にがり、硫酸
カルシウム、グルコノデルタラクトン等が用いられ、豆
乳1000重量部に対し、3〜4重量部使用される。
The coagulant used in the present invention includes bittern, calcium sulfate, glucono delta lactone and the like, and is used in an amount of 3 to 4 parts by weight based on 1,000 parts by weight of soymilk.

【0013】本発明澱粉の使用方法は、従来から知られ
る一般的な澱粉の添加方法により、その効果は得られ
る。一例として、あらかじめ水に凝固剤を溶解させた中
に本発明澱粉を攪拌分散させた後、これを豆乳に加えて
攪拌分散させ、加熱して豆腐を固める方法を挙げること
が出来る。
The effect of the starch of the present invention can be obtained by a conventionally known general method of adding starch. As an example, there can be mentioned a method in which the starch of the present invention is stirred and dispersed in a coagulant previously dissolved in water, then added to soymilk, stirred and dispersed, and heated to solidify the tofu.

【0014】上に述べた如く、製造した豆腐は凍結解凍
した後も殆ど離水せず、豆腐の滑らかさ、弾力性に富む
食感の良い豆腐を提供することが可能である。
As described above, the produced tofu hardly separates from water even after being frozen and thawed, and it is possible to provide a tofu having a smooth and elastic tofu and a good texture.

【0015】以下に本発明について、実施例をもって具
体的に示すが、これらの例に於ける部はすべて重量部と
して表す。
Hereinafter, the present invention will be described specifically with reference to Examples, in which all parts are expressed as parts by weight.

【0016】[0016]

【実施例】【Example】

実施例1 水1200部に硫酸ナトリウム300部及び
水酸化ナトリウム10部を溶解した溶液を表1に示す試
料番号毎に用意し、原料澱粉1000部、エーテル化剤
として酸化プロピレンを表1の通り添加して、40℃で
20時間反応した後、塩酸で中和、水洗、脱水、乾燥し
てヒドロキシプロピルスターチを得た。その置換度を表
1に示す。
Example 1 A solution prepared by dissolving 300 parts of sodium sulfate and 10 parts of sodium hydroxide in 1200 parts of water was prepared for each sample number shown in Table 1, and 1000 parts of raw starch and propylene oxide as an etherifying agent were added as shown in Table 1. After reacting at 40 ° C. for 20 hours, the mixture was neutralized with hydrochloric acid, washed with water, dehydrated and dried to obtain hydroxypropyl starch. Table 1 shows the substitution degree.

【表1】 表中のT澱粉はタピオカ澱粉、P澱粉は馬鈴薯澱粉、W
澱粉はワキシコーンスターチ、C澱粉はコーンスター
チ、H澱粉はハイアミロースコーンスターチを示す。
[Table 1] In the table, T starch is tapioca starch, P starch is potato starch, W starch.
Starch indicates waxy corn starch, C starch indicates corn starch, and H starch indicates high amylose corn starch.

【0017】実施例2 対照例として澱粉を添加しない
物及び未化工の原料澱粉8部添加した物及び実施例1で
調製したすべての試料番号の化工澱粉を各々各8部を添
加して、次に示すように調製して豆腐を製造した。水2
0部に塩化マグネシウム1.4部を溶解させた中に、澱
粉8部攪拌分散させた後、これを豆乳400部に加えて
攪拌分散させ、85℃まで加熱し、凝固させた。得られ
た豆腐を冷水に浸漬して豆腐成分をゲル化固定した。こ
れをテスト用豆腐片に切り、冷凍庫で1週間凍結後解凍
して、離水率及び破断強度を測定し、処理前の状態と比
較してゲルの状態を調べた。その結果を表2及び表3に
示す。
Example 2 As a control, 8 parts each of a substance without added starch and a substance to which 8 parts of unmodified raw starch was added and 8 parts of modified starch of all sample numbers prepared in Example 1 were added. Was prepared as shown in Table 1 to produce tofu. Water 2
In 1.4 parts of magnesium chloride dissolved in 0 parts, 8 parts of starch was stirred and dispersed, and then added to 400 parts of soymilk, stirred and dispersed, heated to 85 ° C., and coagulated. The tofu obtained was immersed in cold water to gelify and fix the tofu component. This was cut into test tofu pieces, frozen in a freezer for one week, and then thawed. The water separation rate and the breaking strength were measured, and the gel state was examined in comparison with the state before the treatment. The results are shown in Tables 2 and 3.

【表2】 [Table 2]

【表3】 表中のT澱粉はタピオカ澱粉、P澱粉は馬鈴薯澱粉、W
澱粉はワキシコーンスターチ、C澱粉はコーンスター
チ、H澱粉はハイアミロースコーンスターチを示す。
尚、表2及び表3の評価は以下の基準により評価した。 ◎:離水が無く、ゲル強度も適度であり、組織が良好
で、豆腐の食感がある。 ○:組織が良好で、豆腐の食感であるが、少し離水があ
る。 ×:離水が多く、組織破壊があり、処理後の物性に大き
な変化が認められる。或いは、離水が少なく、組織破壊
もないが、べたつき、粘りがあり、豆腐の食感がなくな
る。
[Table 3] In the table, T starch is tapioca starch, P starch is potato starch, W starch.
Starch indicates waxy corn starch, C starch indicates corn starch, and H starch indicates high amylose corn starch.
The evaluations in Tables 2 and 3 were based on the following criteria. ◎: No water separation, moderate gel strength, good texture, and tofu texture. :: The texture is good and the texture of the tofu is good, but there is some water separation. X: There is much water separation, there is tissue destruction, and a large change in physical properties after treatment is observed. Alternatively, there is little water separation and no tissue destruction, but there is stickiness and stickiness, and the texture of tofu disappears.

【0018】実施例3 実施例1で調製した試料番号
2、3及び4の化工澱粉を各々各1、2、4、8、1
6、24部を添加して、次に示すように調製して豆腐を
製造した。水20部に塩化マグネシウム1.4部を溶解
させた中に澱粉を攪拌分散させた後、これを豆乳400
部に加えて攪拌分散させ、85℃まで加熱し、凝固させ
た。得られた豆腐を冷水に浸漬して豆腐成分をゲル化固
定した。これをテスト用豆腐片に切り冷凍庫で1週間凍
結後解凍して、離水率及び破断強度を測定し、処理前の
状態と比較してゲルの状態を調べた。その結果を表4に
示す。
Example 3 The modified starches of Sample Nos. 2, 3 and 4 prepared in Example 1 were respectively 1, 2, 4, 8, 1
6, 24 parts were added and prepared as shown below to produce tofu. After stirring and dispersing the starch in a solution of 1.4 parts of magnesium chloride in 20 parts of water, the starch was mixed with 400 parts of soy milk.
Then, the mixture was stirred and dispersed, heated to 85 ° C., and solidified. The obtained tofu was immersed in cold water to gelify and fix the tofu component. This was cut into test tofu pieces, frozen in a freezer for one week and thawed. The water separation rate and the breaking strength were measured, and the state of the gel was examined in comparison with the state before the treatment. Table 4 shows the results.

【表4】 尚、表4の評価は以下の基準により評価した。 ◎:離水が無く、ゲル強度も適度であり、組織が良好
で、豆腐の食感である。 ○:組織が良好で、豆腐の食感であるが、少し離水があ
る。 ×:離水が多く、組織破壊がある。或いは、離水が少な
く、組織破壊もないが、べたつき、粘りがあり、豆腐の
食感がなくなる。
[Table 4] The evaluations in Table 4 were based on the following criteria. ◎: No water separation, moderate gel strength, good texture, and tofu texture. :: The texture is good and the texture of the tofu is good, but there is some water separation. X: There is much water separation, and there is tissue destruction. Alternatively, there is little water separation and no tissue destruction, but there is stickiness and stickiness, and the texture of tofu disappears.

【0019】実施例4 実施例1で調整した試料番号4
の化工澱粉8部を添加して、次に示すように調整して豆
腐を製造した。水20部に塩化マグネシウム1.4部を
溶解させた中に澱粉を攪拌分散させた後、これを豆乳4
00部に加えて攪拌分散させ、85℃まで加熱し、凝固
させた。得られた豆腐を冷水に浸漬して豆腐成分をゲル
化固定した。これを適当な大きさに型切りし、凍結後、
真空乾燥を行い凍結乾燥豆腐を製造した。得られた凍結
乾燥豆腐を水戻しした結果、口当たりの滑らかな良好な
豆腐であった。
Example 4 Sample No. 4 prepared in Example 1
8 parts of modified starch was added and adjusted as follows to produce tofu. The starch was stirred and dispersed in 1.4 parts of magnesium chloride dissolved in 20 parts of water.
The resulting mixture was stirred and dispersed, heated to 85 ° C., and solidified. The obtained tofu was immersed in cold water to gelify and fix the tofu component. Cut this into a suitable size, freeze it,
Vacuum drying was performed to produce freeze-dried tofu. The obtained freeze-dried tofu was rehydrated, and as a result, the tofu was smooth and good.

【0020】以上の実施例からわかるように、置換度が
0.04〜0.2の範囲にエーテル化した化工タピオカ
澱粉、化工馬鈴薯澱粉又は化工ワキシコーンスターチを
添加した冷凍豆腐は他の原料澱粉からの化工澱粉より、
離水や物性変化も少なく優れていることは明白である。
従って、これを使用した冷凍豆腐は、冷凍食品、或い
は、その具材として有用かつ優れている。
As can be seen from the above Examples, the frozen tofu to which a modified tapioca starch, a modified potato starch or a modified waxy corn starch etherified to a substitution degree in the range of 0.04 to 0.2 is added to other raw starch. From modified starch from
It is clear that water separation and changes in physical properties are small and excellent.
Therefore, the frozen tofu using this is useful and excellent as a frozen food or an ingredient thereof.

【0021】[0021]

【発明の効果】本発明澱粉を使用し製造された冷凍豆腐
は凍結による、組織の破壊がなく、物性の変化も殆ど無
く、好適なゲル強度を保ち、更に離水も殆どない好まし
い物となる。
The frozen tofu produced by using the starch of the present invention is a preferred product which is free from destruction of tissue due to freezing, has almost no change in physical properties, maintains a suitable gel strength, and has almost no water separation.

フロントページの続き (56)参考文献 特開 平6−269257(JP,A) 特開 平5−336916(JP,A) 特開 平5−316984(JP,A) 特開 平3−30646(JP,A) 特開 昭57−16670(JP,A) (58)調査した分野(Int.Cl.7,DB名) A23L 1/20 - 1/201 A23L 1/211 Continuation of the front page (56) References JP-A-6-269257 (JP, A) JP-A-5-336916 (JP, A) JP-A-5-316984 (JP, A) JP-A-3-30646 (JP) , A) JP-A-57-16670 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) A23L 1/20-1/201 A23L 1/211

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 豆乳1000重量部にタピオカ澱粉、馬
鈴薯澱粉又はワキシコーンスターチを原料とする置換度
が、0.04〜0.2の範囲であるエーテル化澱粉を5
〜40重量部及び凝固剤3〜4重量部を添加した、冷凍
耐性を特徴とする豆腐。
1. A method in which 1,000 parts by weight of soymilk is mixed with 5 parts of etherified starch having a substitution degree of 0.04 to 0.2 using tapioca starch, potato starch or waxy corn starch as a raw material.
A tofu characterized by freezing resistance, containing 40 parts by weight and 3-4 parts by weight of a coagulant.
【請求項2】 豆乳1000重量部にタピオカ澱粉、馬
鈴薯澱粉又はワキシコーンスターチを原料とする置換度
が、0.04〜0.2の範囲であるエーテル化澱粉を5
〜40重量部及び凝固剤3〜4重量部添加した、冷凍耐
性を特徴とする豆腐の製造方法。
2. 1,000 parts by weight of soy milk are mixed with 5 parts of etherified starch having a substitution degree of 0.04 to 0.2 using tapioca starch, potato starch or waxy corn starch as a raw material.
A method for producing tofu characterized by freezing resistance, in which-40 parts by weight and 3-4 parts by weight of a coagulant are added.
JP06366496A 1996-02-13 1996-02-13 Freeze-resistant tofu and method for producing the same Expired - Fee Related JP3167105B2 (en)

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JP06366496A JP3167105B2 (en) 1996-02-13 1996-02-13 Freeze-resistant tofu and method for producing the same

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Application Number Priority Date Filing Date Title
JP06366496A JP3167105B2 (en) 1996-02-13 1996-02-13 Freeze-resistant tofu and method for producing the same

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JPH09215479A JPH09215479A (en) 1997-08-19
JP3167105B2 true JP3167105B2 (en) 2001-05-21

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4424205B2 (en) * 2002-10-18 2010-03-03 不二製油株式会社 Nugget food manufacturing method
KR101303213B1 (en) * 2011-05-06 2013-09-04 씨제이제일제당 (주) A dry bean curd
KR101315267B1 (en) * 2011-05-06 2013-10-14 씨제이제일제당 (주) A method containing starch gelatinization for manufacturing bean curd and the bean curd
KR101303214B1 (en) * 2011-05-06 2013-09-04 씨제이제일제당 (주) A vacuum freeze drying method for manufacturing dry bean curd and the dry bean curd
KR101431004B1 (en) * 2011-05-06 2014-08-18 씨제이제일제당(주) Stirring method of soy milk, water and starch
KR101337416B1 (en) * 2011-05-06 2013-12-06 씨제이제일제당 (주) A bean curd manufactured by process containing starch gelatinization
WO2013108697A1 (en) * 2012-01-19 2013-07-25 不二製油株式会社 Granulated soybean curd and process for production thereof

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