JP3636748B2 - Structure reinforcement method - Google Patents

Structure reinforcement method Download PDF

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Publication number
JP3636748B2
JP3636748B2 JP29816794A JP29816794A JP3636748B2 JP 3636748 B2 JP3636748 B2 JP 3636748B2 JP 29816794 A JP29816794 A JP 29816794A JP 29816794 A JP29816794 A JP 29816794A JP 3636748 B2 JP3636748 B2 JP 3636748B2
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Japan
Prior art keywords
resin
prepreg
reinforcing
matrix resin
matrix
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JP29816794A
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JPH08158664A (en
Inventor
和也 後藤
孟 後藤
忠 横地
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Mitsubishi Chemical Corp
Mitsubishi Rayon Co Ltd
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Mitsubishi Chemical Corp
Mitsubishi Rayon Co Ltd
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Description

【0001】
【産業上の利用分野】
本発明はコンクリート構築物等の大型の構造物を繊維強化プラスチックで補強する方法の改良に関するものである。
【0002】
【従来の技術】
構造物を繊維強化プラスチックで補強するための材料として種々な材料が提案されている。
これら材料の代表的なものは、ガラス繊維、炭素繊維、アラミド繊維等の高強度繊維から成る織物或いは一方向材料であり、従来の補強技術はこれらの材料に施工現場に於いてポリエステル或いはエポキシ樹脂等の常温で硬化する樹脂を含浸しながら補強材を構造物に貼付ける施工方法、即ち現場含浸施工法であった。
【0003】
【発明が解決しょうとする課題】
しかしながら、上記従来の現場含浸施工法では、補強材に樹脂を含浸するのに長時間を要すること、施工に際して上向作業を行う場合が多く含浸作業が困難であること、作業環境が劣悪であること、及び多額の費用を要すること等の問題があった。
本発明はかかる従来の問題点を解消し、短時間で容易に且つ安価に構造物の補強を行うことのできる方法を提供するものである。
【0004】
【課題を解決するための手段】
本発明は、構造物に、マトリックス樹脂Aを含浸したプリプレグAと、マトリックス樹脂Aと接触して硬化するマトリックス樹脂Bを含浸したプリプレグBとを、双方が互いに重なるように貼り付けて補強層を形成することを特徴とする構造物の補強方法を第1番目の発明の要旨とし、
【0005】
構造物に、常温において単独で硬化するプライマー樹脂Cを塗布した後、マトリックス樹脂Aを含浸したプリプレグAと、マトリックス樹脂Aと接触して硬化するマトリックス樹脂Bを含浸したプリプレグBとを、双方が互いに重なるように貼り付けて補強層を形成することを特徴とする構造物の補強方法を第2番目の発明の要旨とし、
【0006】
前記発明において、補強層の最外層表面に室温で硬化する樹脂を塗布することが好ましい。
【0007】
本発明を図面に基づいて説明すると、図1は、本発明の補強方法の一例を示す説明図で、同図において(1)は構造物例えばコンクリート構築物であり、この表面にマトリックス樹脂Aを補強用繊維シートに含浸したプリプレグA(2)を貼り付け、次いでその上にマトリックス樹脂Aと接触して硬化するマトリックス樹脂Bを補強用繊維シートに含浸したプリプレグB(3)を貼り付けることにより、プリプレグAとプリプレグBとの界面からマトリックス樹脂A及びBの硬化が開始され、硬化したマトリックス樹脂により構造物(1)と補強材料(プリプレグA及びB)を一体化するのである。尚、本発明に於いてプリプレグA及びBの貼り付け枚数に制限はない。
【0008】
図1に示された補強構造に於いて、構造物(1)とプリプレグA(2)との界面は補強と云う観点から考えると最も重要な界面であり、またマトリックス樹脂A(2)の硬化により始めて接着力が発生するため上向貼付の場合、プリプレグA(2)及びB(3)の積層量によっては施工時に脱落が生ずる虞がある。このような場合は、図2に示すように構造物(1)とプリプレグA(2)との間にプライマー樹脂C(4)を介在させて、構造物(1)とプリプレグA(2)との接着力を高めることが好ましい。更に補強層の最外層表面は、硬化の始まる界面からは最も遠く、その表面が硬化するまでにはかなりの時間がかかることがあるが、そのような場合には、最外層表面に常温で硬化可能な樹脂Dを塗布すると、表面のべたつきが短時間でなくなる。
【0009】
次に、上記補強構造物に於いて用いられる補強用繊維シート、マトリックス樹脂AおよびB、並びにプライマー樹脂Cについて詳細に説明する。
マトリックス樹脂A、Bが含浸される補強用繊維シートはガラス繊維、炭素繊維、アラミド繊維等の高強度繊維から成る織物或いは一方向シート材料であるが、本発明ではそれ等の繊維の種類、シートの構成を特に限定するものではない。
また、例えば補強レベルがプリプレグAを構成する補強繊維の量で十分な場合にはプリプレグBを構成する繊維材料は補強に寄与しない材料(例えば多孔質の紙或いは繊維マット等)で単にマトリックス樹脂Bを担持する材料であってもよく、またマトリックス樹脂Bの塗布だけでもよい。
【0010】
本発明において用いるマトリックス樹脂A及びBは、互いに接触することによって硬化する樹脂である。このような樹脂としては触媒硬化型の樹脂系が好ましく、更に反応速度の面からはラジカル重合系が好ましい。具体的なマトリックス樹脂A及びBの組み合わせとしては、不飽和ポリエステルまたはビニルエステル樹脂等を主剤として過酸化物等の硬化触媒を加えた樹脂と同主剤にナフテン酸コバルト等の促進剤を加えたものの組合わせ、或いは市販されている2液混合型の接着剤例えば電気化学工業(株)製のハードロック等が例示される。
【0011】
プライマー樹脂Cは、マトリックス樹脂との接触により硬化するか、或いはマトリックス樹脂と関係なく、常温において単独で硬化する樹脂が用いられる。
プライマー樹脂Cがマトリックス樹脂との接触により硬化する樹脂である場合は、プライマー樹脂Cは構造物に直接塗布するか又は十分に薄い繊維シートに担持されたプリプレグシートとして使用することが出来る。プライマー樹脂Cが常温において単独で硬化する樹脂である場合は、構造物に直接塗布して施工を行うが、マトリックス樹脂の硬化を阻害するものであってはならない。このような条件を満足するプライマー樹脂Cはマトリックス樹脂と同一の樹脂でもよく、また常温で硬化するポリエステル系或いはエポキシ系の樹脂でもよい。
【0012】
また、補強層の最外層に塗布する樹脂は、常温で硬化する樹脂であれば特に制限はなく、全プリプレグを積層後の最外層表面に直接塗布して施工を行うが、マトリックス樹脂A、あるいはBの硬化を阻害するものであってはならない。
【0013】
【実施例】
以下、実施例により本発明をさらに具体的に説明する。
【0014】
[実施例1]
1m当り0.8gの炭素繊維を引揃え且つ緯方向にガラス繊維で部分的に固定した300g/m2 の一方向シートに樹脂含有率50%の割合でハードロックE−510K(電気化学工業株式会社製)のA剤を含浸したプリプレグA、及び同B剤を含浸せしめたプリプレグBを作製した。構造物として、コンクリートモルタル板を用い、その表面を平滑にした後、次の2種の補強施工を行った。
(1)先づプリプレグAをモルタル板に貼付け、次いでプリプレグB、さらにプリプレグAを貼り付けた後、ナイロンフィルムで全体をシールしかつ脱気を行った。
(2)ハードロックE−510KのB剤(プライマー樹脂Cに該当)をスポンジローラーによりモルタル板に塗布し、次いでプリプレグAを貼り付け、上記(1)と同様に脱気を行った。
これらの施工において貼り付け作業は短時間に完了し、施工性は従来の現場含浸施工法に比べてはるかに優れていた。また、プリプレグの積層界面はおよそ10分程度で硬化の開始が認められ、4日間で全体が硬化した。
【0015】
[実施例2]
実施例1で用いた炭素繊維一方向シートに、エポキシアクリレートに過酸化物を混合したマトリックス樹脂Aを樹脂含有率50%で含浸して得たプリプレグA、及びエポキシアクリレートにナフテン酸コバルトを加えたマトリックス樹脂Bを樹脂含有率50%で含浸して得たプリプレグBを作製した。構造物としてコンクリートモルタル板を用い、その表面を平滑にした後、次の2種の補強施工を行った。
(1)チバガイギー社製のアラルダイトLY5052/HY5052=100/38に混合した常温において単独で硬化する樹脂(プライマー樹脂Cに該当)をスポンジローラーによりモルタル板に塗布し、次いでプリプレグA、プリプレグB、プリプレグAの順に3枚貼り付けた。
(2)マトリックス樹脂A/マトリックス樹脂B=1/1に混合した樹脂(プライマー樹脂Cに該当)をスポンジローラーによりモルタル板に塗布し、次いでプリプレグA、プリプレグB、プリプレグAの順に3枚貼り付けた。
上記2種の施工を行った後、各々表面をナイロンフィルムで被覆、脱気し、樹脂の硬化を行った。本実施例に於いても従来の施工法に比べて作業性が格段に優れており、5日間で全体が硬化した。
【0016】
【実施例3】
実施例2の(1)と同様の補強施工を行った後、補強層の最外層表面にプライマー樹脂Cとして用いた樹脂と同様の樹脂を樹脂Dとして塗布したところ、最外層表面は1時間以内にべとつかなくなった。
【0017】
【発明の効果】
上述の如く構成された本発明によれば、短時間で容易に且つ安価に構造物の補強を行うことができるという優れた効果を奏する。
【図面の簡単な説明】
【図1】本発明の補強方法の一例を示す説明図である。
【図2】図1の補強方法において、構造物の表面にプライマー樹脂Cを塗布した例を示す説明図である。
【図3】図2の補強方法において、補強層の最外層表面に常温で硬化する樹脂Dを塗布した例を示す説明図である。
【符号の説明】
1 構造物
2 プリプレグA
3 プリプレグB
4 プライマー樹脂C
5 樹脂D
[0001]
[Industrial application fields]
The present invention relates to an improvement in a method for reinforcing a large structure such as a concrete structure with a fiber reinforced plastic.
[0002]
[Prior art]
Various materials have been proposed as materials for reinforcing structures with fiber reinforced plastics.
Typical examples of these materials are woven fabrics or unidirectional materials made of high-strength fibers such as glass fibers, carbon fibers, and aramid fibers, and conventional reinforcing techniques are applied to these materials at the construction site using polyester or epoxy resin. This was a construction method in which a reinforcing material was applied to a structure while impregnating a resin that hardens at room temperature, such as an on-site impregnation construction method.
[0003]
[Problems to be solved by the invention]
However, in the conventional on-site impregnation method, it takes a long time to impregnate the reinforcing material with the resin, the upward work is often performed during construction, the impregnation work is difficult, and the working environment is poor. And there was a problem of requiring a large amount of expenses.
The present invention provides a method capable of solving such a conventional problem and reinforcing a structure easily and inexpensively in a short time.
[0004]
[Means for Solving the Problems]
In the present invention, a prepreg A impregnated with a matrix resin A and a prepreg B impregnated with a matrix resin B that is cured by contact with the matrix resin A are attached to a structure so that both layers overlap each other. A method for reinforcing a structure characterized by forming a gist of the first invention,
[0005]
After applying primer resin C that is cured alone at room temperature to the structure, both prepreg A impregnated with matrix resin A and prepreg B impregnated with matrix resin B that comes into contact with matrix resin A to cure The reinforcing method of the structure, which is characterized in that the reinforcing layer is formed by pasting so as to overlap each other, the gist of the second invention,
[0006]
In the said invention, it is preferable to apply | coat resin hardened | cured at room temperature to the outermost layer surface of a reinforcement layer.
[0007]
The present invention will be described with reference to the drawings. FIG. 1 is an explanatory view showing an example of the reinforcing method of the present invention. In FIG. 1, (1) is a structure such as a concrete structure, and the matrix resin A is reinforced on the surface. Affixing the prepreg A (2) impregnated on the fiber sheet, and then affixing the prepreg B (3) impregnated on the reinforcing fiber sheet with the matrix resin B, which is cured by contact with the matrix resin A, Curing of the matrix resins A and B is started from the interface between the prepreg A and the prepreg B, and the structure (1) and the reinforcing material (prepregs A and B) are integrated by the cured matrix resin. In the present invention, the number of prepregs A and B to be attached is not limited.
[0008]
In the reinforcing structure shown in FIG. 1, the interface between the structure (1) and the prepreg A (2) is the most important interface from the viewpoint of reinforcement, and the hardening of the matrix resin A (2). In the case of upward sticking, depending on the amount of the prepregs A (2) and B (3) stacked, there is a risk of dropping during construction. In such a case, as shown in FIG. 2, a primer resin C (4) is interposed between the structure (1) and the prepreg A (2), and the structure (1) and the prepreg A (2) It is preferable to increase the adhesive strength. Furthermore, the outermost layer surface of the reinforcing layer is farthest from the interface where curing begins, and it may take a considerable amount of time for the surface to cure. In such a case, the outermost layer surface is cured at room temperature. When the possible resin D is applied, the stickiness of the surface is eliminated in a short time.
[0009]
Next, the reinforcing fiber sheet, matrix resins A and B, and primer resin C used in the reinforcing structure will be described in detail.
The reinforcing fiber sheet impregnated with the matrix resins A and B is a woven fabric or a unidirectional sheet material made of high-strength fibers such as glass fibers, carbon fibers, and aramid fibers. The configuration is not particularly limited.
Further, for example, when the reinforcing level is sufficient for the amount of reinforcing fibers constituting the prepreg A, the fiber material constituting the prepreg B is a material that does not contribute to reinforcement (for example, porous paper or fiber mat) and is simply a matrix resin B. It may be a material that supports or may be applied only by applying the matrix resin B.
[0010]
The matrix resins A and B used in the present invention are resins that are cured by contact with each other. As such a resin, a catalyst curable resin system is preferable, and a radical polymerization system is preferable from the viewpoint of reaction rate. As a specific combination of matrix resins A and B, a resin obtained by adding an accelerator such as cobalt naphthenate to a resin obtained by adding an unsaturated polyester or vinyl ester resin or the like and a curing catalyst such as peroxide to the same main agent. Examples thereof include combinations or commercially available two-component mixed adhesives such as Hard Rock manufactured by Denki Kagaku Kogyo Co., Ltd.
[0011]
As the primer resin C, a resin that is cured by contact with the matrix resin or a resin that is cured alone at room temperature regardless of the matrix resin is used.
When the primer resin C is a resin that is cured by contact with the matrix resin, the primer resin C can be applied directly to the structure or used as a prepreg sheet supported on a sufficiently thin fiber sheet. In the case where the primer resin C is a resin that is curable alone at normal temperature, the primer resin C is applied directly to the structure and applied, but it should not inhibit the curing of the matrix resin. The primer resin C satisfying such conditions may be the same resin as the matrix resin, or may be a polyester or epoxy resin that cures at room temperature.
[0012]
In addition, the resin applied to the outermost layer of the reinforcing layer is not particularly limited as long as it is a resin that cures at room temperature, and is applied by directly applying the entire prepreg to the surface of the outermost layer after lamination. It must not inhibit the hardening of B.
[0013]
【Example】
Hereinafter, the present invention will be described more specifically with reference to examples.
[0014]
[Example 1]
Hard Rock E-510K (Electrochemical Industry Co., Ltd.) with a resin content of 50% on a unidirectional sheet of 300 g / m 2 in which 0.8 g of carbon fiber per meter is aligned and partially fixed with glass fiber in the weft direction. Prepreg A impregnated with agent A) and prepreg B impregnated with agent B were prepared. A concrete mortar board was used as the structure, and after smoothing the surface, the following two types of reinforcement work were performed.
(1) First, prepreg A was pasted on a mortar plate, then prepreg B and further prepreg A were pasted, and then the whole was sealed with a nylon film and deaerated.
(2) Hardlock E-510K B agent (corresponding to primer resin C) was applied to the mortar plate with a sponge roller, prepreg A was then applied, and deaeration was performed in the same manner as in (1) above.
In these constructions, the pasting work was completed in a short time, and the workability was far superior to the conventional on-site impregnation method. Moreover, the start of hardening was recognized by the lamination | stacking interface of the prepreg in about 10 minutes, and the whole hardened | cured in 4 days.
[0015]
[Example 2]
The carbon fiber unidirectional sheet used in Example 1 was added with prepreg A obtained by impregnating a matrix resin A in which a peroxide was mixed with epoxy acrylate at a resin content of 50%, and cobalt naphthenate was added to the epoxy acrylate. A prepreg B obtained by impregnating the matrix resin B with a resin content of 50% was produced. After using a concrete mortar board as a structure and smoothing the surface, the following two types of reinforcement work were performed.
(1) A resin (corresponding to the primer resin C) that is singly cured at room temperature mixed with Araldite LY5052 / HY5052 = 100/38 manufactured by Ciba Geigy Co., Ltd. is applied to the mortar plate with a sponge roller, and then prepreg A, prepreg B, prepreg Three sheets were pasted in the order of A.
(2) Apply a resin mixed in matrix resin A / matrix resin B = 1/1 (corresponding to primer resin C) to the mortar plate with a sponge roller, and then paste three prepreg A, prepreg B, and prepreg A in this order. It was.
After performing the above two types of construction, the surface was covered with a nylon film, degassed, and the resin was cured. Also in this example, workability was remarkably superior to the conventional construction method, and the whole was cured in 5 days.
[0016]
[Example 3]
After performing the same reinforcement work as in Example 2 (1), when the same resin as the resin used as the primer resin C was applied as the resin D to the outermost surface of the reinforcing layer, the outermost surface was within 1 hour. I'm not sticky.
[0017]
【The invention's effect】
According to the present invention configured as described above, there is an excellent effect that the structure can be reinforced easily and inexpensively in a short time.
[Brief description of the drawings]
FIG. 1 is an explanatory view showing an example of a reinforcing method of the present invention.
2 is an explanatory view showing an example in which a primer resin C is applied to the surface of a structure in the reinforcing method of FIG. 1;
3 is an explanatory view showing an example in which a resin D that cures at room temperature is applied to the outermost surface of a reinforcing layer in the reinforcing method of FIG. 2; FIG.
[Explanation of symbols]
1 Structure 2 Prepreg A
3 Prepreg B
4 Primer resin C
5 Resin D

Claims (3)

構造物に、マトリックス樹脂Aを含浸したプリプレグAと、マトリックス樹脂Aと接触して硬化するマトリックス樹脂Bを含浸したプリプレグBとを、双方が重なるように貼り付けて補強層を形成することを特徴とする構造物の補強方法。  A prepreg A impregnated with a matrix resin A and a prepreg B impregnated with a matrix resin B that comes into contact with the matrix resin A and are bonded to the structure so as to overlap each other to form a reinforcing layer. Reinforcing method of structure. 構造物に、常温において単独で硬化するプライマー樹脂Cを塗布した後、マトリックス樹脂Aを含浸したプリプレグAと、マトリックス樹脂Aと接触して硬化するマトリックス樹脂Bを含浸したプリプレグBとを、双方が重なるように貼り付けて補強層を形成することを特徴とする構造物の補強方法。  After applying primer resin C that is cured alone at room temperature to the structure, both prepreg A impregnated with matrix resin A and prepreg B impregnated with matrix resin B that comes into contact with matrix resin A to cure A method for reinforcing a structure, characterized in that the reinforcing layer is formed by being attached so as to overlap. 補強層の最外層表面に室温で硬化する樹脂を塗布する請求項1又は2記載の構造物の補強方法。The method for reinforcing a structure according to claim 1 or 2, wherein a resin that cures at room temperature is applied to the outermost surface of the reinforcing layer.
JP29816794A 1994-10-03 1994-12-01 Structure reinforcement method Expired - Lifetime JP3636748B2 (en)

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KR100271227B1 (en) * 1997-08-29 2000-11-01 한만엽 Structure reinforment method by adhesion of reinforment member in stages
JP6508719B2 (en) * 2015-08-06 2019-05-08 株式会社Akitec Reinforcement structure and method of concrete structure

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