JP3596272B2 - Discharge surface treatment apparatus and discharge surface treatment method using the same - Google Patents

Discharge surface treatment apparatus and discharge surface treatment method using the same Download PDF

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JP3596272B2
JP3596272B2 JP3318298A JP3318298A JP3596272B2 JP 3596272 B2 JP3596272 B2 JP 3596272B2 JP 3318298 A JP3318298 A JP 3318298A JP 3318298 A JP3318298 A JP 3318298A JP 3596272 B2 JP3596272 B2 JP 3596272B2
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discharge
surface treatment
electrode
treatment layer
treatment
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JPH11229159A (en
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祥人 今井
英孝 三宅
昭弘 後藤
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Mitsubishi Electric Corp
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Mitsubishi Electric Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、例えば金属またはセラミック等に、放電表面処理により表面処理層を形成する放電表面処理装置およびこれを用いた放電表面処理方法に関するものである。
【0002】
【従来の技術】
図8は例えば特開平7―70761号公報に記載されている液中放電による表面処理装置を説明するための説明図で、液中放電によって例えばアルミニウムまたはアルミニウム合金等の金属材料の被処理材表面をコーティングして、耐食性や耐磨耗性を与えるものである。
図8において6は被処理材、8は加工液で例えばケロシン等の油を用い、14は圧粉体電極、15は被処理材6に形成された表面処理層である。
例えば、被処理材6の表面にTi系の被膜を形成する場合、まず、TiH(水素化チタン)系の圧粉体電極14により、ケロシン等放電により炭素を発生する加工液中8において放電を発生させる。
この放電により電極14が消耗し、その成分であるTiが極間に放出される。このTiが放電により熱分解された加工液の成分である炭素と反応してTiCとなり、被処理材6の表面に表面処理層15が形成できる。
【0003】
【発明が解決しようとする課題】
しかしながら、例えば、上記のようにして、TiH(水素化チタン)の圧粉体電極によりアルミ合金への表面処理を行った場合には、アルミ合金とTiC被膜の硬度差が大きすぎるために、すぐに被膜が剥離してしまうという課題があった。
また、圧粉体電極の材料成分もしくは粒径、電極長さ、電極面積または電極製作時の成形圧などが異なる場合や、電極が傾斜的特性を有する場合には、圧粉体電極の部分により電気伝導度や熱伝導度が異なるため、表面処理中の放電エネルギーが一定の場合、電極消耗状況が異なるので、面性状が悪化し、密着性や耐摩耗性に劣る表面処理層が形成されるという課題があった。
即ち、従来の放電表面処理装置を用いた表面処理方法では、被処理材に要求仕様を満たす表面処理層を形成することができなかった。
【0004】
本発明は、かかる課題を解決するためになされたもので、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができる放電表面処理装置およびこれを用いた放電表面処理方法を得ることを目的とする。
【0005】
【課題を解決するための手段】
本発明に係る第1の放電表面処理装置は、表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電を発生させることにより上記被処理材の表面に表面処理層を形成する放電処理手段、上記表面処理層の要求仕様を記憶する要求仕様記憶部、上記圧粉体電極の放電処理に関連する特性を記憶する電極の特徴記憶部、上記放電処理手段で放電が正常に行われているか否かを放電処理中に検出する放電状態検出部、並びに上記電極の特徴記憶部からの出力結果と上記要求仕様記憶部の要求仕様と上記放電状態検出部からの検出結果とから上記放電処理手段の放電処理条件を制御する放電処理条件制御部を備えたものである。
【0006】
本発明に係る第2の放電表面処理装置は、上記第1の放電表面処理装置において、被処理材に形成された表面処理層の性状が正常であるか否かを放電処理中に検出する表面処理層の性状検出部を備え、放電処理条件制御部が上記表面処理層の性状検出部の検出結果から放電処理手段の放電処理条件を制御するものである。
【0007】
本発明に係る第3の放電表面処理装置は、上記第1の放電表面処理装置において、放電処理条件が放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧のものである。
【0008】
本発明に係る第4の放電表面処理装置は、上記第1の放電表面処理装置において、放電処理に関連する電極の特性が、電極材料成分、電極材料の粒径、電極長さ、電極面積または電極成型圧であるものである。
【0009】
本発明に係る第1の放電表面処理方法は、表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電処理することにより上記被処理材の表面に表面処理層を形成する放電表面処理方法において、上記表面処理層の要求仕様と、上記圧粉体電極の放電処理に関連する特性と、放電処理中の放電処理状態とにより上記放電処理条件を制御する方法である。
【0010】
本発明に係る第2の放電表面処理方法は、上記第1の放電表面処理方法において、放電処理条件の制御を放電処理中の表面処理層の性状によりおこなう方法である。
【0011】
本発明に係る第3の放電表面処理方法は、上記第1または第2の放電表面処理方法において、放電処理条件が放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧の方法である。
【0012】
本発明に係る第4の放電表面処理方法は、上記第1または第2の放電表面処理方法において、放電処理に関連する電極の特性が、電極材料成分、電極材料の粒径、電極長さ、電極面積または電極成型圧の方法である。
【0014】
【発明の実施の形態】
実施の形態1.
図1は本発明の実施の形態の放電表面処理装置において、要求仕様に対して最初に設定した放電条件に基づいて行う放電処理に係わる構成を示す説明図であり、図2はこの放電表面処理の処理過程を示すフローチャートである。
図において、1は表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電を発生させることにより上記被処理材の表面に表面処理層を形成する放電処理手段、2は圧粉体電極の放電に関連する電極の特性を記憶する電極の特徴記憶部、3は被処理材に形成される表面処理材の要求仕様を記憶する要求仕様記憶部、4は電極の特徴記憶部2からの出力結果と上記要求仕様記憶部の要求仕様とから上記放電処理手段1の放電処理条件を制御する放電処理条件制御部である。
【0015】
まず、ステップ1で被処理材に形成する表面処理層の硬度、耐摩耗性、密着性、膜厚または面あらさなどの要求仕様を要求仕様記憶部3に記憶し、ステップ2で圧粉体電極の放電に関連した特性、例えば電極材料成分もしくは粒径、電極長さ、電極面積、電極製作時の成形圧または電極の傾斜的上記特性等を記憶する。
次に、ステップ3で電極の特徴記憶部2と要求仕様記憶部3とから、放電処理に適した放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧等の放電処理条件を放電処理条件制御部4により設定し、それに基づきステップ4で放電処理手段1により放電処理をおこない、ステップ5で表面処理層が要求仕様に達した時点で放電処理を終了する。なお、ステップ1とステップ2は前後してもよい。
【0016】
実施の形態2.
実施の形態1において、被処理材に硬度変化がなめらかである表面処理層(表面処理層の要求仕様)を形成する場合について説明する。
図3は上記実施の形態1における被処理材の放電処理を説明する説明図である。図において、6は被処理材、8は加工液でケロシン等の油、5は圧粉体電極、7は表面処理層である。
また、圧粉体電極5としては、TiH2の粉体量とNiの粉体量を徐々に変化させ組成に傾斜性をもたせたもの(電極の特徴)を用いた。即ち、被処理材6側は比較的柔らかい金属であるNi粉体の量を、比較的硬い金属であるTiを含むTiH2粉体の量より多くなるように徐々に変化させている。
次に、上記電極を用いて上記表面処理層を被処理材に形成するための放電処理条件として、電極と被処理材間に一定の放電エネルギーで放電を発生させると設定し、ケロシン等放電により炭素を発生する加工液中8において放電処理し、図に示すように成分に傾斜性を有する表面処理層7を得ることができた。
即ち、被処理材6と表面処理層7との接触部分にはNi量が多く、表面処理層7の上面部に向かってNi量が減少し、それにつれて従来と同様にして得られたTiCの量が増加するので、TiC単独で形成されているより硬度変化がなめらかとなり、高硬度な表面処理層被膜の形成と同時にその剥離を抑制することができた。
【0017】
なお、本実施の形態で用いた圧粉体電極5は、粒径10μm程度の粉体を用い、Ni粉体量:TiH粉体量=7:3〜0:10(体積%)で連続的に変化させたものを用い傾斜性をもたせた。なお、上記電極は例えば混合比率の異なる粉体を電極型内に積層させた後、加圧成形することにより製作した。
【0018】
また、図4のように、圧粉体電極5のワーク6側を比較的柔らかい金属であるNiの粉体で形成し、他を比較的硬い金属であるTiを含むTiH2の粉体で形成することにより上記と同様の効果を得ることができる。
図4は本実施の形態で用いることができる圧粉体電極の説明図で、図において、9は圧粉体電極、10はNiの粉体で形成された部分、11はTiH2の粉体で形成された部分である。
【0019】
また、本圧粉体電極の傾斜性を電極材料成分にもたせたが、圧粉体電極の傾斜性を粒径(例えば2〜20μm)または電極材料と粒径の両方にもたせることでもよい。
また、Ti以外にもV(バナジウム)、Nb(ニオブ)、Ta(タンタル)、Cr(クロム)、Mo(モリブデン)またはW(タングステン)等を使用しても、さらにこれらに他の金属やセラミックス等を混合したものを使用しても同様の効果を得ることができる。
【0020】
実施の形態3.
実施の形態1において、被処理材に面性状に優れた表面処理層(表面処理層の要求仕様)を形成する場合について説明する。
図5は実施の形態1における放電処理条件制御部の動作を説明するための説明図で、異なる粒径からなる圧粉体電極(電極の特徴)を用いた場合の放電処理エネルギー(放電処理条件)による面性状の関係を示す特性図{図5(a)}と、放電処理エネルギーと表面処理層の膜厚との関係を示す特性図{図5(b)}を示す。
図において放電処理エネルギーとはピーク電流とパルスオン時間の積である。粒径が5μmの場合(図中△)には、図5(a)に示すように面性状の点から放電処理エネルギーはE1〜E2から選らばれ、図5(b)に示すように膜厚の点から最適な放電処理エネルギーを決定すればよい。一方、粒径が1μmの場合(図中)には、粒径が5μmの場合に使用した放電処理エネルギーでは、膜厚が厚くなるものの面性状が悪化するため、放電処理エネルギーはE0〜E1から選ぶことにより良質な被膜を形成することができる。
【0021】
実施の形態4.
図6は本発明の実施の形態の放電表面処理装置の構成を示す説明図であり、図7はこの放電表面処理装置を用いた放電表面処理の処理過程を示すフローチャートである。
図において、1〜4は図1と同様であり、12は放電処理手段1で放電が正常に行われているか(例えば短絡が生じているか)否かを検出する放電処理状態検出部、13は表面処理層の性状が正常であるか否かを検出する表面処理層の性状検出部である。
つまり、実施の形態1では図1に示すように、最初に設定する放電処理条件は外乱の影響がないものと想定しているが、実際は処理くずの排出状態等により上記条件では対応できない状態が発生する。これを例えば短絡状態で、連続して放電が発生しているか否かを検出する。
また、例えば最初に設定した放電処理条件が不適切であるか、または放電の進行に伴い放電処理条件が不適切になると、面粗さが悪くなり、被膜の厚さが不均一になり表面処理層の性状が悪くなることから、表面層の性状から放電処理状態を検出することができる。
【0022】
まず、図7において、ステップ4までは図2と同様にして放電処理手段1により放電処理をおこなう。
処理時間が長くなると放電処理中に圧粉体電極の特徴が変化するが、その変化に対応することにより、より要求仕様に沿った表面処理層を得ることができる。
即ち、図7において、ステップ6、7で放電処理中、放電処理状態が正常であるか否かを判断し、異常であれば放電処理条件制御部4で放電処理条件を修正し正常ならステップ8、9で、被処理材に形成された表面処理層の性状が正常であるか否かを判断し、異常であれば放電処理条件制御部4で放電処理条件を修正し正常ならステップ5で表面処理層が要求仕様に達した時点で放電処理を終了する。
なお、ステップ1とステップ2およびステップ6、7とステップ8、9は前後してもよく、ステップ6、7とステップ8、9は実行回数を最初から決めていても良い。
【0023】
実施の形態1の図1に示すように、放電処理条件制御部による放電処理条件の決定は、表面処理前に一度実行するが、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜(20μm程度)であっても、本発明の実施の形態の放電表面処理装置を用いた放電表面処理方法では、放電処理条件制御部により放電条件の決定を実行して修正するので良質な表面処理層を得ることができる。
【0024】
【発明の効果】
本発明の第1の放電表面処理装置によれば、表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電を発生させることにより上記被処理材の表面に表面処理層を形成する放電処理手段、上記表面処理層の要求仕様を記憶する要求仕様記憶部、上記圧粉体電極の放電処理に関連する特性を記憶する電極の特徴記憶部、上記放電処理手段で放電が正常に行われているか否かを放電処理中に検出する放電状態検出部、並びに上記電極の特徴記憶部からの出力結果と上記要求仕様記憶部の要求仕様と上記放電状態検出部からの検出結果とから上記放電処理手段の放電処理条件を制御する放電処理条件制御部を備えたものであり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができるという効果がある。
【0025】
本発明の第2の放電表面処理装置によれば、上記第1の放電表面処理装置において、被処理材に形成された表面処理層の性状が正常であるか否かを放電処理中に検出する表面処理層の性状検出部を備え、放電処理条件制御部が上記表面処理層の性状検出部の検出結果から放電処理手段の放電処理条件を制御するものであり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができるという効果がある。
【0026】
本発明の第3の放電表面処理装置によれば、上記第1の放電表面処理装置において、放電処理条件が放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧のものであり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができるという効果がある。
【0027】
本発明の第4の放電表面処理装置によれば、上記第1の放電表面処理装置において、放電処理に関連する電極の特性が、電極材料成分、電極材料の粒径、電極長さ、電極面積または電極成型圧であるものであり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができるという効果がある。
【0028】
本発明の第1の放電表面処理方法は、表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電処理することにより上記被処理材の表面に表面処理層を形成する放電表面処理方法において、上記表面処理層の要求仕様と、上記圧粉体電極の放電処理に関連する特性と、放電処理中の放電処理状態とにより上記放電処理条件を制御する方法であり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができるという効果がある。
【0029】
本発明の第2の放電表面処理方法は、上記第1の放電表面処理装置において、放電処理条件の制御を放電処理中の表面処理層の性状によりおこなう方法であり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様をさらに満たす表面処理層を形成することができるという効果がある。
【0030】
本発明の第3の放電表面処理方法は、上記第1または第2の放電表面処理方法において、放電処理条件が放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧であり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材により十分に要求仕様を満たす表面処理層を形成することができるという効果がある。
【0031】
本発明の第4の放電表面処理方法は、上記第1または第2の放電表面処理方法において、放電処理に関連する電極の特性が、電極材料成分、電極材料の粒径、電極長さ、電極面積または電極成型圧の方法であり、処理中に圧粉体電極等の特徴が変化したり、または形成する表面処理層が厚膜であっても、被処理材に要求仕様を満たす表面処理層を形成することができるという効果がある。
【図面の簡単な説明】
【図1】本発明に係わる放電表面処理装置の構成を示す説明図である。
【図2】本発明に係わる放電表面処理装置を用いた放電表面処理の処理過程を示すフローチャートである。
【図3】本発明に係わる放電表面処理装置による被処理材の放電処理を説明する説明図である。
【図4】本発明に係わる圧粉体電極の説明図である。
【図5】本発明に係わる放電表面処理装置における放電処理条件制御部の動作を説明するための説明図である。
【図6】本発明に係わる放電表面処理装置の構成を示す説明図である。
【図7】本発明に係わる放電表面処理装置を用いた放電表面処理の処理過程を示すフローチャートである。
【図8】従来の放電表面処理装置による被処理材の放電処理を説明する説明図である。
【符号の説明】
5 圧粉体電極、7 表面処理層。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a discharge surface treatment apparatus for forming a surface treatment layer on a metal or ceramic by discharge surface treatment and a discharge surface treatment method using the same.
[0002]
[Prior art]
FIG. 8 is an explanatory view for explaining a surface treatment apparatus using submerged discharge described in, for example, Japanese Patent Application Laid-Open No. 7-70761. The surface of a material to be processed is made of a metal material such as aluminum or an aluminum alloy by submerged discharge. To impart corrosion resistance and abrasion resistance.
In FIG. 8, reference numeral 6 denotes a material to be processed, 8 denotes a working liquid, for example, using oil such as kerosene, 14 denotes a green compact electrode, and 15 denotes a surface treatment layer formed on the material 6 to be processed.
For example, when a Ti-based film is formed on the surface of the material 6 to be processed, first, a TiH 2 (titanium hydride) -based green compact electrode 14 discharges in a machining fluid 8 that generates carbon by electric discharge such as kerosene. Generate.
This discharge consumes the electrode 14 and releases its component Ti between the electrodes. The Ti reacts with carbon, which is a component of the working fluid thermally decomposed by the electric discharge, to become TiC, and the surface treatment layer 15 can be formed on the surface of the material 6 to be treated.
[0003]
[Problems to be solved by the invention]
However, for example, when a surface treatment is performed on an aluminum alloy using a compact electrode of TiH 2 (titanium hydride) as described above, the hardness difference between the aluminum alloy and the TiC coating is too large. There was a problem that the coating was immediately peeled off.
Further, when the material component or particle diameter of the green compact electrode, the electrode length, the electrode area or the molding pressure at the time of manufacturing the electrode are different, or when the electrode has a gradient characteristic, depending on the part of the green compact electrode. Since the electric conductivity and the thermal conductivity are different, when the discharge energy during the surface treatment is constant, the electrode wear conditions are different, so the surface properties are deteriorated, and a surface treatment layer having poor adhesion and abrasion resistance is formed. There was a problem.
That is, in the surface treatment method using the conventional discharge surface treatment apparatus, it was not possible to form a surface treatment layer satisfying the required specifications on the material to be treated.
[0004]
The present invention has been made in order to solve such a problem, and even if the characteristics of a green compact electrode or the like are changed during processing, or even if the surface treatment layer to be formed is a thick film, it is necessary to provide a material to be processed. An object of the present invention is to provide a discharge surface treatment apparatus capable of forming a surface treatment layer satisfying specifications and a discharge surface treatment method using the same.
[0005]
[Means for Solving the Problems]
The first discharge surface treatment apparatus according to the present invention generates a discharge by applying a voltage between a green compact electrode made of a surface treatment material or a material that is a source of the surface treatment material and a material to be treated. Discharge treatment means for forming a surface treatment layer on the surface of the material to be treated, a required specification storage unit for storing required specifications of the surface treatment layer, and characteristics of an electrode for storing characteristics relating to the discharge treatment of the green compact electrode A storage unit, a discharge state detection unit that detects whether or not discharge is normally performed by the discharge processing unit during the discharge process, and an output result from the characteristic storage unit of the electrode and a required specification of the required specification storage unit. A discharge processing condition control unit for controlling a discharge processing condition of the discharge processing unit based on a detection result from the discharge state detection unit .
[0006]
A second discharge surface treatment apparatus according to the present invention is the first discharge surface treatment apparatus according to the first discharge surface treatment apparatus, which detects whether or not a property of a surface treatment layer formed on the workpiece is normal during the discharge treatment. The apparatus further includes a treatment layer property detection unit, and the discharge treatment condition control unit controls the discharge treatment condition of the discharge treatment unit based on the detection result of the surface treatment layer property detection unit .
[0007]
A third discharge surface treatment apparatus according to the present invention, in the first discharge surface treatment apparatus, wherein discharge treatment conditions are those of a discharge pulse polarity, a peak current, an open voltage, a pulse on time, a pulse off time, or a servo voltage. .
[0008]
A fourth discharge surface treatment apparatus according to the present invention, in the first discharge surface treatment apparatus, wherein the characteristics of the electrodes related to the discharge treatment are: electrode material component, particle diameter of the electrode material, electrode length, electrode area or This is the electrode molding pressure .
[0009]
The first discharge surface treatment method according to the present invention is characterized in that the discharge treatment is performed by applying a voltage between a green compact electrode made of a surface treatment material or a material that is a source of the surface treatment material and a material to be treated. In the discharge surface treatment method of forming a surface treatment layer on the surface of the material to be treated, the required specifications of the surface treatment layer, the characteristics related to the discharge treatment of the green compact electrode, and the discharge treatment state during the discharge treatment This is a method for controlling the above discharge processing conditions.
[0010]
A second discharge surface treatment method according to the present invention is a method according to the first discharge surface treatment method, wherein the discharge treatment conditions are controlled by the properties of the surface treatment layer during the discharge treatment .
[0011]
A third discharge surface treatment method according to the present invention, in the first or second discharge surface treatment method, wherein the discharge treatment conditions include discharge pulse polarity, peak current, open voltage, pulse on time, pulse off time, or servo voltage. Is the way.
[0012]
In a fourth discharge surface treatment method according to the present invention, in the first or second discharge surface treatment method, the characteristics of the electrode related to the discharge treatment include an electrode material component , a particle diameter of the electrode material, an electrode length, It is a method of electrode area or electrode molding pressure .
[0014]
BEST MODE FOR CARRYING OUT THE INVENTION
Embodiment 1 FIG.
In Figure 1 the discharge surface treatment apparatus of the embodiment of the present onset Ming embodiment is an explanatory view showing a configuration related to the first based on the set discharge conditions performs discharge processing for the required specifications, Figure 2 is the discharge surface It is a flowchart which shows the process of a process.
In the drawing, reference numeral 1 denotes a surface of the material to be treated by applying a voltage between a green compact electrode made of a surface treatment material or a material that is a source of the surface treatment material and a material to be treated to generate a discharge. Discharge treatment means for forming a treatment layer, 2 is an electrode characteristic storage unit for storing the characteristics of the electrodes related to the discharge of the green compact electrode, and 3 is the required specification of the surface treatment material formed on the material to be treated. The required specification storage unit 4 is a discharge processing condition control unit that controls the discharge processing conditions of the discharge processing unit 1 based on the output result from the electrode characteristic storage unit 2 and the required specifications in the required specification storage unit.
[0015]
First, in step 1, required specifications such as hardness, abrasion resistance, adhesion, film thickness or surface roughness of a surface treatment layer formed on a material to be processed are stored in a required specification storage unit 3, and in step 2, a green compact electrode is formed. For example, the characteristics related to the discharge, such as the electrode material component or particle size, the electrode length, the electrode area, the molding pressure at the time of manufacturing the electrode, or the above-mentioned characteristic of the electrode inclination are stored.
Next, in step 3, from the electrode characteristic storage unit 2 and the required specification storage unit 3, discharge processing conditions such as the polarity, peak current, open voltage, pulse on time, pulse off time, or servo voltage of the discharge pulse suitable for the discharge processing. Is set by the discharge processing condition control unit 4, and based on that, the discharge processing is performed by the discharge processing means 1 in step 4, and the discharge processing ends when the surface treatment layer reaches the required specification in step 5. Step 1 and step 2 may be performed before and after.
[0016]
Embodiment 2 FIG.
In the first embodiment, it will be described the case of forming a surface treatment layer hardness change in the material to be treated is smooth (required specifications for surface treatment layer).
FIG. 3 is an explanatory diagram for explaining the discharge processing of the material to be processed in the first embodiment. In the figure, 6 is a material to be treated, 8 is a working fluid, such as oil such as kerosene, 5 is a green compact electrode, and 7 is a surface treatment layer.
Further, as the green compact electrode 5, an electrode having a gradient in composition by gradually changing the amount of TiH 2 powder and the amount of Ni powder (characteristic of the electrode) was used. That is, the amount of the Ni powder, which is a relatively soft metal, is gradually changed on the side of the workpiece 6 so as to be larger than the amount of the TiH 2 powder containing Ti, which is a relatively hard metal.
Next, as a discharge treatment condition for forming the surface treatment layer on the material to be treated using the electrode, it is set that a discharge is generated with a constant discharge energy between the electrode and the material to be treated, and the discharge is performed by a discharge such as kerosene. Discharge treatment was performed in the working fluid 8 that generates carbon, and as shown in the figure, a surface treatment layer 7 having a gradient in components could be obtained.
That is, the amount of Ni is large in the contact portion between the material to be treated 6 and the surface treatment layer 7, and the amount of Ni decreases toward the upper surface of the surface treatment layer 7. Since the amount increased, the change in hardness became smoother than that made of TiC alone, and the peeling of the surface treatment layer film having high hardness could be suppressed at the same time.
[0017]
The green compact electrode 5 used in the present embodiment uses a powder having a particle size of about 10 μm, and has a continuous Ni powder amount: TiH 2 powder amount = 7: 3 to 0:10 (vol%). It was made to have a gradient by using a material which was changed in the end. The electrodes were manufactured by, for example, laminating powders having different mixing ratios in an electrode mold, followed by pressure molding.
[0018]
Further, as shown in FIG. 4, the work 6 side of the green compact electrode 5 is formed of a relatively soft metal Ni powder, and the other is formed of a relatively hard metal Ti containing TiH 2 powder. By doing so, the same effect as described above can be obtained.
FIG. 4 is an explanatory view of a green compact electrode that can be used in the present embodiment . In the figure, 9 is a green compact electrode, 10 is a portion formed of Ni powder, and 11 is a TiH 2 powder. It is a part formed by.
[0019]
Further, although the gradient of the present green compact electrode is given to the electrode material component, the gradient of the green compact electrode may be given to the particle size (for example, 2 to 20 μm) or both the electrode material and the particle size.
Also, other than Ti, V (vanadium), Nb (niobium), Ta (tantalum), Cr (chromium), Mo (molybdenum), W (tungsten), or the like may be used. The same effect can be obtained by using a mixture of these.
[0020]
Embodiment 3 FIG.
Oite to the first embodiment will be described the case of forming an excellent surface treatment layer on the surface properties on the treated material (the required specifications of the surface treatment layer).
FIG. 5 is an explanatory diagram for explaining the operation of the discharge processing condition control unit according to the first embodiment. The discharge processing energy (discharge processing conditions) when using compacted electrodes (characteristics of electrodes) having different particle sizes is used. 5) shows a characteristic diagram {FIG. 5 (a)} showing the relationship of the surface properties according to the present invention, and FIG. 5 (b)} shows a characteristic diagram showing the relationship between the discharge treatment energy and the film thickness of the surface treatment layer.
In the figure, the discharge processing energy is the product of the peak current and the pulse on time. When the particle size is 5 μm ( in the figure), the discharge treatment energy is selected from E1 and E2 in terms of the surface properties as shown in FIG. 5 (a), and the film thickness is as shown in FIG. 5 (b). From this point, the optimum discharge treatment energy may be determined. On the other hand, when the particle diameter is 1 μm ( ○ in the figure), the discharge treatment energy used when the particle diameter is 5 μm increases the film thickness but deteriorates the surface properties. By selecting from among these, a good quality film can be formed.
[0021]
Embodiment 4 FIG.
Figure 6 is an explanatory diagram showing a configuration of a discharge surface treatment apparatus of the embodiment of the present onset Ming embodiment, FIG. 7 is a flowchart of the operation of the discharge surface treatment using the discharge surface treatment apparatus.
In the figure, reference numerals 1 to 4 are the same as those in FIG. 1, reference numeral 12 is a discharge processing state detection unit for detecting whether or not discharge is normally performed by the discharge processing unit 1 (for example, whether or not a short circuit has occurred). It is a property detection unit of the surface treatment layer that detects whether the property of the surface treatment layer is normal.
That is, in the first embodiment, as shown in FIG. 1, it is assumed that the initially set discharge processing conditions are not affected by disturbance, but there are actually states in which the above conditions cannot cope with the discharge state of the processing waste. appear. This is detected, for example, in a short-circuit state to determine whether or not discharge has occurred continuously.
Further, for example, if the initially set discharge processing conditions are inappropriate, or if the discharge processing conditions become inappropriate as the discharge proceeds, the surface roughness deteriorates, the thickness of the coating becomes uneven, and the surface treatment is performed. Since the properties of the layer deteriorate, the state of the discharge treatment can be detected from the properties of the surface layer.
[0022]
First, in FIG. 7, the discharge processing is performed by the discharge processing means 1 up to step 4 in the same manner as in FIG.
When the treatment time is prolonged, the characteristics of the green compact electrode change during the discharge treatment. By responding to the change, a surface treatment layer more in accordance with the required specifications can be obtained.
That is, in FIG. 7, during the discharge processing, it is determined whether or not the discharge processing state is normal during the discharge processing. If abnormal, the discharge processing condition control unit 4 corrects the discharge processing condition. In step 9, it is determined whether or not the properties of the surface treatment layer formed on the material to be treated are normal. If abnormal, the discharge treatment conditions are corrected by the discharge treatment condition control unit 4. When the processing layer reaches the required specification, the discharge processing is completed.
Steps 1 and 2 and steps 6 and 7 and steps 8 and 9 may be performed before and after, and steps 6 and 7 and steps 8 and 9 may determine the number of executions from the beginning.
[0023]
As shown in FIG. 1 of the first embodiment, the determination of the discharge processing condition by the discharge processing condition control unit is performed once before the surface treatment, but the characteristics of the green compact electrode and the like change during the treatment , or Even if the surface treatment layer to be formed is a thick film ( about 20 μm), in the discharge surface treatment method using the discharge surface treatment apparatus according to the embodiment of the present invention, the discharge condition is determined by the discharge condition control unit. As a result, a high-quality surface treatment layer can be obtained.
[0024]
【The invention's effect】
According to the first discharge surface treatment apparatus of the present invention, a discharge is generated by applying a voltage between a green compact electrode made of a surface treatment material or a material serving as a surface treatment material and a material to be treated. A discharge processing means for forming a surface treatment layer on the surface of the material to be processed, a required specification storage unit for storing required specifications of the surface treatment layer, and an electrode for storing characteristics relating to discharge processing of the green compact electrode. A characteristic storage unit, a discharge state detection unit that detects whether or not discharge is normally performed by the discharge processing unit during the discharge processing, and an output result from the characteristic storage unit of the electrode and a request from the required specification storage unit. It has a discharge processing condition control unit that controls the discharge processing conditions of the discharge processing unit from the specifications and the detection results from the discharge state detection unit , and the characteristics of the green compact electrode and the like change during processing. Or forming surface treatment There is also a thick film, there is an effect that it is possible to form the surface treatment layer satisfying the required specifications in the treated material.
[0025]
According to the second discharge surface treatment device of the present invention, in the first discharge surface treatment device, it is detected during the discharge treatment whether or not the property of the surface treatment layer formed on the material to be treated is normal. includes a property detecting unit of the surface treatment layer, discharging treatment condition control unit is for controlling the discharge process condition of a discharge processing unit from the detection result of the property detection portion of the surface treatment layer, a green compact electrode and the like during processing Even if the characteristics of the above-mentioned are changed, or the surface treatment layer to be formed is a thick film, there is an effect that a surface treatment layer satisfying required specifications can be formed on the material to be treated.
[0026]
According to the third discharge surface treatment device of the present invention, in the first discharge surface treatment device, the discharge treatment condition is such that the discharge pulse has a polarity, a peak current, an open voltage, a pulse on time, a pulse off time, or a servo voltage . Yes, even if the characteristics of the green compact electrode change during processing, or even if the surface treatment layer to be formed is a thick film, the surface treatment layer that meets the required specifications can be formed on the material to be treated. There is.
[0027]
According to the fourth discharge surface treatment apparatus of the present invention, in the first discharge surface treatment apparatus, the characteristics of the electrodes related to the discharge treatment include the electrode material component, the particle diameter of the electrode material, the electrode length, and the electrode area. Or, it is the electrode molding pressure, and even if the characteristics of the green compact electrode change during processing, or the surface treatment layer to be formed is a thick film, the surface treatment layer that meets the required specifications for the material to be treated Can be formed.
[0028]
In the first discharge surface treatment method of the present invention, the discharge treatment is performed by applying a voltage between a green compact electrode made of a surface treatment material or a material that is a base material of the surface treatment material and a material to be treated. in the discharge surface treatment method of forming a surface treatment layer on the surface of the treated material, more and required specifications for the surface treatment layer, and characteristics associated with the discharge processing of the green compact electrode, and the discharge processing state during the discharge process This is a method for controlling the above-mentioned discharge treatment conditions. Even if the characteristics of the green compact electrode change during the treatment, or the surface treatment layer to be formed is a thick film, the surface treatment satisfying the required specifications for the material to be treated. There is an effect that a layer can be formed.
[0029]
Second discharge surface treatment method of the present invention, in the above-mentioned first discharge surface treatment apparatus, and the control of the discharge process conditions a method performed by the properties of the surface treatment layer during the discharge process, the green compact electrode during processing Even if the characteristics such as change or the surface treatment layer to be formed is a thick film, there is an effect that the surface treatment layer which further satisfies the required specifications can be formed on the material to be treated.
[0030]
In a third discharge surface treatment method of the present invention, in the first or second discharge surface treatment method, the discharge treatment condition is a polarity of a discharge pulse, a peak current, an open voltage, a pulse on time, a pulse off time or a servo voltage. Even if the characteristics of the green compact electrode change during processing, or even if the surface treatment layer to be formed is a thick film, it is possible to form a surface treatment layer that sufficiently satisfies the required specifications depending on the material to be treated. effective.
[0031]
In a fourth discharge surface treatment method of the present invention, in the first or second discharge surface treatment method, the characteristics of the electrode related to the discharge treatment include an electrode material component , a particle diameter of the electrode material, an electrode length, and an electrode. This is a method of area or electrode molding pressure , and the surface treatment layer that meets the required specifications for the material to be treated , even if the characteristics of the green compact electrode etc. change during processing or the surface treatment layer to be formed is a thick film Can be formed.
[Brief description of the drawings]
FIG. 1 is an explanatory diagram showing a configuration of a discharge surface treatment apparatus according to the present invention.
FIG. 2 is a flowchart showing a process of a discharge surface treatment using the discharge surface treatment apparatus according to the present invention.
FIG. 3 is an explanatory diagram illustrating a discharge process of a material to be processed by a discharge surface treatment apparatus according to the present invention.
FIG. 4 is an explanatory view of a green compact electrode according to the present invention.
FIG. 5 is an explanatory diagram for explaining an operation of a discharge processing condition control unit in the discharge surface treatment apparatus according to the present invention.
FIG. 6 is an explanatory diagram showing a configuration of a discharge surface treatment apparatus according to the present invention.
FIG. 7 is a flowchart showing a process of a discharge surface treatment using the discharge surface treatment apparatus according to the present invention.
FIG. 8 is an explanatory diagram illustrating a discharge process of a material to be processed by a conventional discharge surface treatment apparatus.
[Explanation of symbols]
5 green compact electrode, 7 surface treatment layer.

Claims (8)

表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電を発生させることにより上記被処理材の表面に表面処理層を形成する放電処理手段、上記表面処理層の要求仕様を記憶する要求仕様記憶部、上記圧粉体電極の放電処理に関連する特性を記憶する電極の特徴記憶部、上記放電処理手段で放電が正常に行われているか否かを放電処理中に検出する放電状態検出部、並びに上記電極の特徴記憶部からの出力結果と上記要求仕様記憶部の要求仕様と上記放電状態検出部からの検出結果とから上記放電処理手段の放電処理条件を制御する放電処理条件制御部を備えた放電表面処理装置。Forming a surface treatment layer on the surface of the material to be treated by applying a voltage between the surface treatment material or a green compact electrode composed of a material that is a source of the surface treatment material and the material to be treated to generate a discharge. Discharge processing means, a required specification storage section for storing required specifications of the surface treatment layer, an electrode characteristic storage section for storing characteristics relating to the discharge processing of the green compact electrode, and normal discharge by the discharge processing means. A discharge state detection unit for detecting whether or not the discharge is performed during the discharge process, and the output result from the electrode characteristic storage unit, the required specification in the required specification storage unit, and the detection result from the discharge state detection unit. A discharge surface treatment apparatus comprising a discharge treatment condition control unit for controlling a discharge treatment condition of a discharge treatment means. 被処理材に形成された表面処理層の性状が正常であるか否かを放電処理中に検出する表面処理層の性状検出部を備え、放電処理条件制御部が上記表面処理層の性状検出部の検出結果から放電処理手段の放電処理条件を制御することを特徴とする請求項1に記載の放電表面処理装置。 A surface treatment layer property detection unit that detects whether the property of the surface treatment layer formed on the material to be processed is normal during the discharge treatment, and the discharge treatment condition control unit controls the property detection unit of the surface treatment layer. The discharge surface treatment apparatus according to claim 1, wherein the discharge processing conditions of the discharge processing means are controlled based on the detection result of (1) . 放電処理条件が放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧であることを特徴とする請求項1に記載の放電表面処理装置。The discharge surface treatment apparatus according to claim 1, wherein the discharge processing condition is a polarity of a discharge pulse, a peak current, an open voltage, a pulse on time, a pulse off time, or a servo voltage. 放電処理に関連する電極の特性が、電極材料成分、電極材料の粒径、電極長さ、電極面積または電極成型圧であることを特徴とする請求項1に記載の放電表面処理装置。The discharge surface treatment apparatus according to claim 1, wherein the characteristics of the electrode related to the discharge treatment are an electrode material component , a particle size of the electrode material, an electrode length, an electrode area, or an electrode molding pressure . 表面処理材料または表面処理材料の元となる材料からなる圧粉体電極と被処理材との間に電圧を印加して放電処理することにより上記被処理材の表面に表面処理層を形成する放電表面処理方法において、上記表面処理層の要求仕様と、上記圧粉体電極の放電処理に関連する特性と、放電処理中の放電処理状態とにより上記放電表面処理方法。A discharge for forming a surface treatment layer on the surface of the material to be treated by applying a voltage between the surface treatment material or a green compact electrode made of a material of the surface treatment material and the material to be treated to perform a discharge treatment; in the surface treatment method, the required specifications for the surface treatment layer, characteristics and, more the discharge surface treatment method in the discharge processing state during the discharge process associated with the discharge treatment of the green compact electrode. 放電処理条件の制御を放電処理中の表面処理層の性状によりおこなうことを特徴とする請求項5に記載の放電表面処理方法。The discharge surface treatment method according to claim 5, wherein the control of the discharge treatment conditions is performed by the properties of the surface treatment layer during the discharge treatment . 放電処理条件が放電パルスの極性、ピーク電流、オープン電圧、パルスオン時間、パルスオフ時間またはサーボ電圧であることを特徴とする請求項5または請求項6に記載の放電表面処理方法。7. The discharge surface treatment method according to claim 5, wherein the discharge treatment conditions are a polarity of a discharge pulse, a peak current, an open voltage, a pulse on time, a pulse off time, or a servo voltage. 放電処理に関連する電極の特性が、電極材料成分、電極材料の粒径、電極長さ、電極面積または電極成型圧であることを特徴とする請求項5または請求項6に記載の放電表面処理方法。The discharge surface treatment according to claim 5 or 6, wherein the characteristics of the electrode related to the discharge treatment are an electrode material component , a particle diameter of the electrode material, an electrode length, an electrode area, or an electrode molding pressure. Method.
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