JP3550833B2 - Resin coloring composition for liquid bleach containers - Google Patents
Resin coloring composition for liquid bleach containers Download PDFInfo
- Publication number
- JP3550833B2 JP3550833B2 JP29387695A JP29387695A JP3550833B2 JP 3550833 B2 JP3550833 B2 JP 3550833B2 JP 29387695 A JP29387695 A JP 29387695A JP 29387695 A JP29387695 A JP 29387695A JP 3550833 B2 JP3550833 B2 JP 3550833B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- acid
- weight
- coloring composition
- titanium dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 title claims description 24
- 239000011347 resin Substances 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 10
- 238000004040 coloring Methods 0.000 title claims description 8
- 239000007844 bleaching agent Substances 0.000 title claims description 6
- 239000007788 liquid Substances 0.000 title claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000004408 titanium dioxide Substances 0.000 claims description 15
- 229920005672 polyolefin resin Polymers 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 20
- 239000000178 monomer Substances 0.000 description 13
- -1 polyethylene Polymers 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- SPURMHFLEKVAAS-UHFFFAOYSA-N 1-docosene Chemical compound CCCCCCCCCCCCCCCCCCCCC=C SPURMHFLEKVAAS-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OOKDYUQHMDBHMB-UHFFFAOYSA-N 3,6-dichloro-2-methoxybenzoic acid;2-(2,4-dichlorophenoxy)acetic acid;n-methylmethanamine Chemical compound CNC.CNC.COC1=C(Cl)C=CC(Cl)=C1C(O)=O.OC(=O)COC1=CC=C(Cl)C=C1Cl OOKDYUQHMDBHMB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- ZDLBWMYNYNATIW-UHFFFAOYSA-N tetracos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCC=C ZDLBWMYNYNATIW-UHFFFAOYSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
- 229940106006 1-eicosene Drugs 0.000 description 1
- FIKTURVKRGQNQD-UHFFFAOYSA-N 1-eicosene Natural products CCCCCCCCCCCCCCCCCC=CC(O)=O FIKTURVKRGQNQD-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- SYIUWAVTBADRJG-UHFFFAOYSA-N 2H-pyran-2,6(3H)-dione Chemical compound O=C1CC=CC(=O)O1 SYIUWAVTBADRJG-UHFFFAOYSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- WMZHDICSCDKPFS-UHFFFAOYSA-N triacont-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCC=C WMZHDICSCDKPFS-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】
【発明の属する技術分野】
本発明は、過酸化水素水を含有する液体漂白剤の容器として適した樹脂着色組成物に関する。
【０００２】
【従来の技術】
従来より衣料の漂白には、過酸化水素水が用いられている。この過酸化水素水は通常、密封性の高いポリエチレン等のプラスチック容器に充填され家庭用液体漂白剤として市販されている。
また、このプラスチック容器は内容物保護、デザイン性などのために、顔料によって着色されている。
【０００３】
【発明が解決しようとする課題】
過酸化水素水は、アルカリ、粉状白金、二酸化マンガンその他の微細な粉末、粗雑な面をもつ固体など、種々のものが触媒となって容易に分解し、酸素を放つことが知られている。
この為、過酸化水素水系液体漂白剤を入れたプラスチック容器を二酸化チタン等で着色すると、過酸化水素水が分解し酸素ガスが発生し、過酸化水素水の漂白能力が著しく低下したり、発生したガスによって、容器が変形したりするという問題があった。
この問題に対し、過酸化水素水を入れる容器としては、内側に未着色樹脂の層を有する多層構造の容器が用いられている。しかし、多層構造の容器は製造工程が複雑になり、コストアップになるという問題が生じた。
【０００４】
【課題を解決するための手段】
本発明者らは、上記の問題を解決すべく鋭意検討した結果、酸変性樹脂にて表面をコーティングした二酸化チタンを着色剤として用いると、二酸化チタンによる過酸化水素水の分解が抑制されることを発見し、本発明に至った。
すなわち、本発明は、ポリオレフィン樹脂２０〜９９．９５重量％と酸変性樹脂でコーティングした二酸化チタン顔料０．０５〜８０重量％を含有することを特徴とする液体漂白剤容器用樹脂着色組成物である。
【０００５】
【発明の実施の形態】
以下本発明を更に詳細に説明する。
本発明で使用するポリオレフィン樹脂としては、ポリエチレン、ポリプロピレン等が挙げられ、ポリエチレンとしては低密度、中密度、高密度のポリエチレンが、またポリプロピレンとしてはホモ、ブロック、ランダムポリプロピレンが挙げられ、高密度のポリエチレンがが好ましい。
【０００６】
本発明で使用する酸変性樹脂としては、不飽和二重結合を有するモノマーと、不飽和二重結合および極性基を有するモノマーとを共重合せしめたものや、ポリオレフィン樹脂に不飽和二重結合および極性基を有するモノマーをグラフトせしめたもの等が挙げられ、顔料表面をコーティングするということから、低分子量の方が好ましい。
【０００７】
不飽和二重結合を有するモノマーとしては、例えばα−オレフィン、アリルモノマー、Ｎ−ビニルモノマー、ビニルエーテル、（メタ）アクリル酸エステルモノマー等が挙げられる。
α−オレフィンとしては、エチレン、プロピレン、ブチレン、イソブチレン、ペンテン、１−ヘキセン、１−ヘプテン、１−オクテン、１−ノネン、１−デセン、１−ドデセン、１−テトラドデセン、１−ヘキサドデセン、１−オクタデセン、１−エイコセン、１−ドコセン、１−テトラコセン、１−ヘキサコセン、１−オクタコセン、１−トリアコンテンが挙げられる。市販品としては、ダイアレン２０８（Ｃ２０〜２８）、ダイアレン３０（Ｃ３０以上）（三菱化成（株））、ＶＹＢＡＲ＃２６０（Ｃ３０以上）、ＶＹＢＡＲ＃６０４（Ｃ３０以上）（ペトライト（株））等が挙げられる。
【０００８】
上記のような不飽和二重結合を有するモノマーと共重合せしめる、不飽和二重結合および極性基を有するモノマーとしては、カルボキシル基を有するモノマーが好ましく、例えばアクリル酸、メタクリル酸、マレイン酸、フマル酸、イタコン酸、シトラコン酸、グルタコン酸、クロトン酸、テロラヒドロフタール酸、無水マレイン酸、無水イタコン酸、無水シトラコン酸、無水グルタコン酸、無水テロラヒドロフタール酸が挙げられ、マレイン酸、無水マレイン酸、アクリル酸が好ましい。
【０００９】
上記不飽和二重結合および極性基を有するモノマーは、不飽和二重結合を有するモノマーと共重合せしめる他、ポリオレフィン樹脂にグラフト反応せしめても良い。酸変性樹脂の製造に用いられるポリオレフィン樹脂としては前記したポリオレフィン樹脂が挙げられる。
【００１０】
また、本発明において用いられる酸変性樹脂は、上記の極性基を有する共重合体やグラフト体中の極性基の一部または全てを金属塩によって中和した、いわゆるアイオノマーであっても良い。
中和に用いられる金属塩としては、水酸化ナトリウム、水酸化カリウム、炭酸カルシウム、炭酸マグネシウム等が挙げられる。
【００１１】
酸変性樹脂との配合量としては、二酸化チタン１００重量部に対して、０．０５〜１００重量部が好ましく、１０〜５０重量部がさらに好ましい。酸変性樹脂との配合量が０．０５よりも少ないと、過酸化水素水の分解抑制しにくくなり、逆に１００重量部を越えると成形性や物性に悪影響を及ぼしやすい。
【００１２】
本発明で使用する二酸化チタンとしては、粒度分布０．０５〜０．４５μｍ、平均粒径０．２０〜０．３０μｍであることが好ましく、ルチル型、アナターゼ型いずれであってもよい。
【００１３】
本発明において、二酸化チタンは酸変性樹脂でコーティングしてなるものであり、バンバリーミキサー、３本ロール等によって二酸化チタンと酸変性樹脂を混練するなどして予め酸変性樹脂でコーティングしてなる二酸化チタンを得、係る二酸化チタンを用いて本発明の樹脂着色組成物を製造する。
【００１４】
本発明の樹脂着色組成物は、ポリオレフィン樹脂２０〜９９．９５重量％と、詳述した酸変性樹脂をコーティングした二酸化チタン顔料０．０５〜８０重量％を含有するものであり、好ましくはポリオレフィン樹脂６０〜９９．９５重量％と、酸変性樹脂をコーティングした二酸化チタン顔料０．０５〜４０重量％含有するものである。相対的にポリオレフィン樹脂が少なくなると、成形しにくくなり、逆に相対的にポリオレフィン樹脂が多くなると色が薄くなってしまう。
【００１５】
なお、本発明においては、上記の樹脂着色組成物に必要に応じて、他の成分を種々添加することが出来る。例えば、紫外線吸収剤、滑剤、帯電防止剤、その他の公知のポリマー用添加剤を必要量添加することが出来る。
【００１６】
【実施例】
以下、実施例により本発明を具体的に説明する。
実施例１
エチレン−アクリル酸共重合体を炭酸カルシウムで中和したアイオノマー２０重量部と二酸化チタン２０重量部を配合し、３本ロールにて予備混練を行った。さらに、高密度ポリエチレン（比重０．９５７、ＭＦＲ６．０ｇ／１０ｍｉｎ．）６０重量部を加えて押出機にて溶融混練して、樹脂着色成形物を得た。
【００１７】
実施例２
エチレン−無水マレイン酸共重合体１０重量部、二酸化チタン２０重量部およびポリエチレンワックス（分子量 ４３００ 、比重 ０．９２４）１０重量部を配合し、３本ロールにて予備混練を行う。さらに、高密度ポリエチレン６０重量部を加えて押出機出溶融混練して、樹脂着色成形物を得た。
【００１８】
実施例３〜４、比較例１
表１の組成に従って、実施例１と同様にして、樹脂着色成形物を得た。
【００１９】
評価方法
実施例、比較例で得た樹脂着色成形物３０ｇを２００ｍｌ三角フラスコに入れ、過酸化水素水５％水溶液１００ｍｌを注入し、温度４０℃の条件でウォーターバス中で加温し、分解発生するガスを補集した。
過酸化水素水５％水溶液１００ｍｌのみの三角フラスコからのガス発生量を測定し、これをブランクとして、ガスの発生量を経時的に測定した。
その結果を表１に示す。
【００２０】
【表１】
【発明の効果】
本発明の樹脂着色組成物は、過酸化水素溶液と接触した状態においても、過酸化水素の分解を抑制・防止し、ガスの発生を抑制・防止できる。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a resin coloring composition suitable as a container for a liquid bleach containing hydrogen peroxide solution.
[0002]
[Prior art]
Conventionally, aqueous hydrogen peroxide has been used for bleaching clothing. This aqueous hydrogen peroxide is usually filled in a plastic container made of polyethylene or the like having a high sealing property, and is commercially available as a liquid bleach for household use.
The plastic container is colored with a pigment for protection of contents and design.
[0003]
[Problems to be solved by the invention]
Hydrogen peroxide water is known to easily decompose and release oxygen by various catalysts such as alkali, powdered platinum, manganese dioxide and other fine powders, and solids with rough surfaces. .
For this reason, if a plastic container containing a hydrogen peroxide-based liquid bleach is colored with titanium dioxide or the like, the hydrogen peroxide solution is decomposed and oxygen gas is generated, and the bleaching ability of the hydrogen peroxide solution is significantly reduced or generated. There is a problem that the container is deformed due to the generated gas.
To solve this problem, a container having a multilayer structure having an uncolored resin layer inside is used as a container for storing the hydrogen peroxide solution. However, the multi-layered container has a problem that the manufacturing process is complicated and the cost is increased.
[0004]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to solve the above-described problems, and as a result, when titanium dioxide coated on the surface with an acid-modified resin is used as a coloring agent, decomposition of hydrogen peroxide by titanium dioxide is suppressed. Have been found, and the present invention has been achieved.
That is, the present invention relates to a resin coloring composition for a liquid bleach container, comprising 20 to 99.95% by weight of a polyolefin resin and 0.05 to 80% by weight of a titanium dioxide pigment coated with an acid-modified resin. is there.
[0005]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in more detail.
Examples of the polyolefin resin used in the present invention include polyethylene, polypropylene, and the like.Polyethylene includes low-density, medium-density, high-density polyethylene, and polypropylene includes homo, block, and random polypropylene. Polyethylene is preferred.
[0006]
As the acid-modified resin used in the present invention, a monomer obtained by copolymerizing a monomer having an unsaturated double bond with a monomer having an unsaturated double bond and a polar group, or a polyolefin resin having an unsaturated double bond and Examples thereof include those obtained by grafting a monomer having a polar group, and the lower molecular weight is more preferable since the pigment surface is coated.
[0007]
Examples of the monomer having an unsaturated double bond include α-olefins, allyl monomers, N-vinyl monomers, vinyl ethers, (meth) acrylate monomers, and the like.
Examples of the α-olefin include ethylene, propylene, butylene, isobutylene, pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-dodecene, 1-tetradodecene, 1-hexadedecene, Octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacocene, 1-octacocene, and 1-triaconten. Commercial products include Dialen 208 (C20-28), Dialen 30 (C30 or more) (Mitsubishi Kasei), VYBAR # 260 (C30 or more), VYBAR # 604 (C30 or more) (Petrite Co., Ltd.) and the like. No.
[0008]
As the monomer having an unsaturated double bond and a polar group to be copolymerized with the monomer having an unsaturated double bond as described above, a monomer having a carboxyl group is preferable, such as acrylic acid, methacrylic acid, maleic acid, and fumaric acid. Acids, itaconic acid, citraconic acid, glutaconic acid, crotonic acid, terolahydrophthalic acid, maleic anhydride, itaconic anhydride, citraconic anhydride, glutaconic anhydride, terolahydrophthalic anhydride, maleic acid, anhydride Maleic acid and acrylic acid are preferred.
[0009]
The monomer having an unsaturated double bond and a polar group may be copolymerized with a monomer having an unsaturated double bond, or may be subjected to a graft reaction to a polyolefin resin. Examples of the polyolefin resin used for producing the acid-modified resin include the above-described polyolefin resins.
[0010]
Further, the acid-modified resin used in the present invention may be a so-called ionomer in which a part or all of the polar group in the copolymer or the graft having the polar group is neutralized with a metal salt.
Examples of the metal salt used for neutralization include sodium hydroxide, potassium hydroxide, calcium carbonate, magnesium carbonate and the like.
[0011]
The compounding amount with the acid-modified resin is preferably from 0.05 to 100 parts by weight, more preferably from 10 to 50 parts by weight, based on 100 parts by weight of titanium dioxide. When the compounding amount with the acid-modified resin is less than 0.05, it is difficult to suppress the decomposition of the hydrogen peroxide solution, and when it exceeds 100 parts by weight, moldability and physical properties are easily adversely affected.
[0012]
The titanium dioxide used in the present invention preferably has a particle size distribution of 0.05 to 0.45 μm and an average particle size of 0.20 to 0.30 μm, and may be any of rutile type and anatase type.
[0013]
In the present invention, the titanium dioxide is coated with an acid-modified resin, and the titanium dioxide is previously coated with the acid-modified resin by kneading the titanium dioxide and the acid-modified resin by using a Banbury mixer, three rolls or the like. And the resin coloring composition of the present invention is produced using the titanium dioxide.
[0014]
The resin coloring composition of the present invention contains 20 to 99.95% by weight of a polyolefin resin and 0.05 to 80% by weight of a titanium dioxide pigment coated with an acid-modified resin described in detail, and is preferably a polyolefin resin. It contains 60 to 99.95% by weight and 0.05 to 40% by weight of a titanium dioxide pigment coated with an acid-modified resin. If the polyolefin resin is relatively small, molding becomes difficult, and if the polyolefin resin is relatively large, the color becomes light.
[0015]
In the present invention, various other components can be added to the above-mentioned resin coloring composition as needed. For example, UV absorbers, lubricants, antistatic agents, and other known additives for polymers can be added in required amounts.
[0016]
【Example】
Hereinafter, the present invention will be specifically described with reference to examples.
Example 1
20 parts by weight of an ionomer obtained by neutralizing an ethylene-acrylic acid copolymer with calcium carbonate and 20 parts by weight of titanium dioxide were blended, and preliminarily kneaded with a three-roll mill. Further, 60 parts by weight of high-density polyethylene (specific gravity: 0.957, MFR: 6.0 g / 10 min.) Was added and melt-kneaded by an extruder to obtain a resin colored molded product.
[0017]
Example 2
10 parts by weight of an ethylene-maleic anhydride copolymer, 20 parts by weight of titanium dioxide, and 10 parts by weight of a polyethylene wax (molecular weight: 4300, specific gravity: 0.924) are blended and pre-kneaded with a three-roll mill. Further, 60 parts by weight of high-density polyethylene was added and melt-kneaded out of an extruder to obtain a resin-colored molded product.
[0018]
Examples 3 and 4, Comparative Example 1
According to the composition of Table 1, in the same manner as in Example 1, a resin colored molded product was obtained.
[0019]
Evaluation method 30 g of the resin-colored molded product obtained in Examples and Comparative Examples was placed in a 200-ml Erlenmeyer flask, 100 ml of a 5% aqueous solution of hydrogen peroxide was injected, and the mixture was heated in a water bath at a temperature of 40 ° C. to cause decomposition. Gas was collected.
The amount of gas generated from an Erlenmeyer flask containing only 100 ml of a 5% aqueous solution of hydrogen peroxide was measured, and this was used as a blank to measure the amount of gas generated over time.
Table 1 shows the results.
[0020]
[Table 1]
【The invention's effect】
The resin coloring composition of the present invention can suppress and prevent the decomposition of hydrogen peroxide and can suppress and prevent the generation of gas even in the state of being in contact with the hydrogen peroxide solution.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29387695A JP3550833B2 (en) | 1995-11-13 | 1995-11-13 | Resin coloring composition for liquid bleach containers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29387695A JP3550833B2 (en) | 1995-11-13 | 1995-11-13 | Resin coloring composition for liquid bleach containers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09137003A JPH09137003A (en) | 1997-05-27 |
| JP3550833B2 true JP3550833B2 (en) | 2004-08-04 |
Family
ID=17800305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29387695A Expired - Lifetime JP3550833B2 (en) | 1995-11-13 | 1995-11-13 | Resin coloring composition for liquid bleach containers |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3550833B2 (en) |
-
1995
- 1995-11-13 JP JP29387695A patent/JP3550833B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09137003A (en) | 1997-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2011177992A (en) | Laminate and packaging material using the same | |
| JP3550833B2 (en) | Resin coloring composition for liquid bleach containers | |
| JPH05156028A (en) | Production of aqueous dispersion of olefinic polymer composition | |
| JPH0362803A (en) | Method for preparing antibacterial polymer and its use | |
| JPH0372542A (en) | Resin composition and multilayer structure made by using it | |
| US5891539A (en) | Colorant resin composition | |
| KR20120105466A (en) | Colored resin composition and molded product | |
| JPH0827332A (en) | Resin composition and multilayer structure | |
| JP3012340B2 (en) | Liquid bleach in multi-layer container | |
| JP2006096369A (en) | Draw-molded multilayer container | |
| JPS58108240A (en) | Resin composiion and its preparation | |
| JP3133410B2 (en) | Easy tear multilayer film | |
| JPH0345744B2 (en) | ||
| JP2787024B2 (en) | Molding method | |
| JP2006096902A (en) | Ethylene resin powder coating material for powder coating and coated product coated with this powder coating material | |
| JP2581757B2 (en) | Heat resistant foam sheet and container | |
| JPH0372541A (en) | Resin composition and multilayer structure | |
| JPS5974106A (en) | Deodorized polyethylene composition | |
| JP3219866B2 (en) | Liquid bleaching resin coloring composition for single-layer containers | |
| JPH09137004A (en) | Colored resin composition for liquid bleaching agent container | |
| JP2006096901A (en) | Ethylene resin powder coating material for powder coating and coated product coated with this powder coating material | |
| CN118019627A (en) | Injection molded closure article comprising a blend of at least one substantially linear polyolefin elastomer component and at least one partially neutralized ethylene acid copolymer resin component | |
| JPH07125150A (en) | Multilayer package | |
| JPH01148551A (en) | Plastic sheet molding vessel | |
| JPH09137005A (en) | Colored resin composition for liquid bleaching agent container |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20040325 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20040330 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20040412 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110514 Year of fee payment: 7 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120514 Year of fee payment: 8 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130514 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140514 Year of fee payment: 10 |
|
| EXPY | Cancellation because of completion of term |