JP3525556B2 - Polyolefin-based splittable conjugate fiber and nonwoven fabric - Google Patents

Polyolefin-based splittable conjugate fiber and nonwoven fabric

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Publication number
JP3525556B2
JP3525556B2 JP13862395A JP13862395A JP3525556B2 JP 3525556 B2 JP3525556 B2 JP 3525556B2 JP 13862395 A JP13862395 A JP 13862395A JP 13862395 A JP13862395 A JP 13862395A JP 3525556 B2 JP3525556 B2 JP 3525556B2
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JP
Japan
Prior art keywords
fiber
component
splittable conjugate
polyolefin
conjugate fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP13862395A
Other languages
Japanese (ja)
Other versions
JPH08311717A (en
Inventor
賢 西島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JNC Corp
Original Assignee
Chisso Corp
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Filing date
Publication date
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Priority to JP13862395A priority Critical patent/JP3525556B2/en
Publication of JPH08311717A publication Critical patent/JPH08311717A/en
Application granted granted Critical
Publication of JP3525556B2 publication Critical patent/JP3525556B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Multicomponent Fibers (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0010】[0010]

【産業上の利用分野】 本発明は、ポリオレフィン系分
割型複合繊維に関する。更に詳しくはカ−ド工程中の静
電気発生を抑制し、かつ極めて優れた分割性を有するポ
リオレフィン系分割型複合繊維、およびその分割型複合
繊維を用いて得られる親水性、柔軟性、拭き取り性の良
好な極細繊維不織布に関する。
TECHNICAL FIELD The present invention relates to a polyolefin-based splittable conjugate fiber. More specifically, it suppresses the generation of static electricity during the carding process, and has a very excellent splittability, and is a polyolefin-based splittable conjugate fiber, and hydrophilicity, flexibility, and wipeability obtained by using the splittable conjugate fiber. It relates to a good ultrafine fiber nonwoven fabric.

【0011】[0011]

【従来技術】 近年、優れた柔軟性および触感、拭き取
り性並びに不織布強度の高さから極細繊維を用いた織
布、または不織布が広く用いられている。例えば、溶解
性の異なる2種類以上の樹脂から製造された多芯型の複
合繊維で、いわゆる海島型複合繊維と呼ばれる繊維を織
製加工で織布とした後、海成分を除去することで極細繊
維の織布を得る方法(特公昭43−7411号公報)、
また別の方法として互いに相溶性の小さい2種類以上の
成分が接合された複合繊維、いわゆる分割型複合繊維で
あって、乾式法または湿式法でウエブとした後、高圧水
流等の機械的衝撃により繊維を分割及び交絡させて極細
繊維不織布を得る方法(特公昭48−28005号公
報、特開平5−321018号公報、特公平6−361
29号公報)が一般的に行われている。
2. Description of the Related Art In recent years, woven fabrics or non-woven fabrics using ultrafine fibers have been widely used because of their excellent flexibility, touch, wiping properties, and high strength of non-woven fabrics. For example, a multi-core type composite fiber manufactured from two or more kinds of resins with different solubilities, a so-called sea-island type composite fiber is woven into a woven fabric, and then the sea component is removed to obtain an ultrafine fiber. A method for obtaining a woven fabric of fibers (Japanese Patent Publication No. 43-7411),
As another method, a composite fiber in which two or more kinds of components having low compatibility with each other are joined, that is, a so-called split type composite fiber, which is formed into a web by a dry method or a wet method and then subjected to mechanical impact such as high pressure water flow A method of dividing and entangled fibers to obtain an ultrafine fiber nonwoven fabric (Japanese Patent Publication No. 48-28005, Japanese Patent Application Laid-Open No. 5-321018, Japanese Patent Publication No. 6-361).
No. 29) is generally performed.

【0012】 しかしながら、海島型複合繊維を用いる
方法は、織製工程、繊維の溶解除去工程等があり、製造
工程が複雑になるという問題がある。一方、分割型複合
繊維を用いる方法は、カ−ド法等で得られたウエブを、
高圧水流にて繊維の分割及び交絡を同時に行う事で、比
較的容易に極細繊維不織布が得られる。しかしながら、
分割型複合繊維を構成する樹脂は、機械的衝撃で容易に
分割する必要があり一般的に組み合わされるものとして
相溶性の互いに少ないポリアミド系樹脂、ポリエステル
系樹脂およびポリプロピレン系樹脂、ポリエチレン系樹
脂の内から選ばれるため、乾式法に於いてカ−ド法等の
工程を経てウエブを形成する場合、工程半ばで分割部分
が発生したり、分割不充分である。通常一般的な合成繊
維は、加工工程中の静電気の発生を抑える目的で繊維表
面に界面活性剤等を付着させているが、前記分割部分の
発生により繊維の表面積が増大し、静電気が発生するた
めカ−ド通過性が著しく悪化する。また静電気の発生を
抑えるために、繊維仕上剤をカ−ド工程中に追加付着し
た場合もカ−ド機の汚染、ウエブ強力の低下等の問題が
発生する。
However, the method using the sea-island type composite fiber has a problem that the manufacturing process is complicated because it includes a weaving process, a fiber dissolving and removing process, and the like. On the other hand, the method using the splittable conjugate fiber is a web obtained by the card method,
By simultaneously dividing and entanglement the fibers with a high-pressure water stream, an ultrafine fiber nonwoven fabric can be obtained relatively easily. However,
The resin that constitutes the splittable conjugate fiber must be easily split by mechanical impact and is generally combined as a combination of polyamide resins, polyester resins and polypropylene resins, and polyethylene resins that are less compatible with each other. Therefore, when the web is formed through the steps such as the card method in the dry method, a divided portion is generated in the middle of the step or the division is insufficient. Usually, synthetic fibers have a surface-active agent attached to the surface of the fibers in order to suppress the generation of static electricity during the processing process, but the surface area of the fibers increases due to the generation of the above-mentioned divided parts, and static electricity is generated. Therefore, the card passage property is significantly deteriorated. Further, in order to suppress the generation of static electricity, even when a fiber finishing agent is additionally attached during the carding process, problems such as contamination of the carding machine and reduction of web strength occur.

【0013】 従来のポリオレフィン系分割型複合繊維
は、高圧水流による不織布化工程で、繊維仕上剤として
繊維表面に付着していた親水性界面活性剤が急速に洗い
流される。しかしながらポリプロピレン、ポリエチレン
に代表されるポリオレフィン樹脂は公定水分率が0%と
極めて強い疎水性であるために、高圧水流による不織布
化工程の初期の段階で繊維が高圧水流を避ける事とな
り、水の衝撃エネルギ−を均一に受ける事が出来ない。
そのため高圧水流の段数を増加しなければ十分均一に分
割した極細繊維不織布は得られない。
In the conventional polyolefin-based splittable conjugate fiber, the hydrophilic surfactant attached to the surface of the fiber as a fiber finishing agent is rapidly washed away in the process of forming a nonwoven fabric by high-pressure water flow. However, polyolefin resins typified by polypropylene and polyethylene have extremely strong hydrophobicity with an official moisture regain of 0%, so the fibers avoid high-pressure water flow at the initial stage of the nonwoven fabric formation process due to high-pressure water flow, and the impact of water Energy cannot be received uniformly.
Therefore, unless the number of high-pressure water streams is increased, a sufficiently uniformly divided ultrafine fiber nonwoven fabric cannot be obtained.

【0014】[0014]

【発明が解決しようとする課題】 本発明の目的は、上
記従来技術の課題である分割型複合繊維のカ−ド工程中
の静電気の発生を抑制すると共に、優れた拭き取り性、
柔軟性及び親水性を有する、極細不織布を提供すること
にある。
The object of the present invention is to suppress the generation of static electricity during the carding process of the splittable conjugate fiber, which is the problem of the above-mentioned prior art, and to have an excellent wiping property.
It is to provide an ultrafine non-woven fabric having flexibility and hydrophilicity.

【0015】[0015]

【課題を解決するための手段】 本発明者らは、上記課
題を解決すべく鋭意研究を重ねた結果、分割型複合繊維
を構成するポリオレフィン系樹脂の少なくとも1成分に
親水成分を練り込み添加する事により上記課題を解決出
来得る事を知った。即ちポリオレフィン系分割型複合繊
維の分割する界面部分に親水成分を析出させる事により
所期の目的が達成されることを知り、本発明を完成する
に至った。
Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors knead and add a hydrophilic component to at least one component of a polyolefin resin that constitutes a splittable conjugate fiber. I knew that I could solve the above problems. That is, the inventors have found that the intended purpose can be achieved by precipitating a hydrophilic component on the interfacial portion where the polyolefin-based splittable conjugate fiber divides, and have completed the present invention.

【0016】 本発明は、次の構成を有する。 (1) 主としてポリオレフィン系樹脂からなる分割型
複合繊維であって、ポリオレフィン系樹脂の少なくとも
1成分に、脂肪酸グリセライド、アルコキシ化アルキル
フェノール、ポリオキシアルキレン脂肪酸エステルの群
から選ばれた少なくとも1種である親水成分が1.0〜
7.0重量%練り込み添加されたポリオレフィン系分割
型複合繊維。 () 上記1に記載のポリオレフィン系分割型複合繊
維を分割して得られる繊度0.5デニール以下であり、
かつ異形断面形状である極細繊維からなる不織布。
The present invention has the following configurations. (1) A splittable conjugate fiber mainly composed of a polyolefin resin, wherein at least one component of the polyolefin resin contains a fatty acid glyceride and an alkoxylated alkyl.
Group of phenol, polyoxyalkylene fatty acid ester
At least one hydrophilic component selected from 1.0 to
A polyolefin-based splittable conjugate fiber kneaded and added at 7.0% by weight. ( 2 ) The fineness obtained by splitting the polyolefin-based splittable conjugate fiber according to 1 above is 0.5 denier or less,
Also, a non-woven fabric made of ultrafine fibers having a modified cross-sectional shape.

【0017】 以下、本発明を詳細に説明する。本発明
のポリオレフィン系分割型複合繊維に用いられるポリオ
レフィン系樹脂とは、エチレン、プロピレンの単独重合
体、及び他のα−オレフィンとの共重合体のことであ
り、またはこれらの混合物である。α−オレフィン共重
合体としては、プロピレンを主体とするオレフィン系の
二元共重合体または三元共重合体がある。これら共重合
体の具体例としては、プロピレンを主体として、これに
エチレンまたはブテン−1あるいは4−メチルペンテン
−1などの共重合物が例示できる。また、用途によって
はポリエステル系樹脂もしくはポリアミド系樹脂とポリ
オレフィン系樹脂との組合せまたは混合物を適宜選択し
ても何等差し支えない。これらのポリオレフィン系樹脂
のうち、互いに相溶性の小さい少なくとも2種の樹脂を
図1〜図5に例示されるように、放射状または平行ある
いは並列に複合紡糸することにより本発明のポリオレフ
ィン系分割型複合繊維が得られる。また、それらのポリ
オレフィン系分割型複合繊維は、本発明の目的を達する
範囲内で繊維内に他の機能性を付与する添加剤を配合す
ることが可能であり、用途に合わせて選択し、適宜配合
することができる。
The present invention will be described in detail below. The polyolefin resin used for the polyolefin splittable conjugate fiber of the present invention is a homopolymer of ethylene and propylene, and a copolymer with other α-olefin, or a mixture thereof. As the α-olefin copolymer, there is an olefin-based binary copolymer or terpolymer mainly containing propylene. Specific examples of these copolymers include propylene as a main component and a copolymer such as ethylene or butene-1 or 4-methylpentene-1. In addition, depending on the application, a combination or mixture of polyester resin or polyamide resin and polyolefin resin may be appropriately selected without any problem. Of these polyolefin-based resins, at least two resins having a low compatibility with each other are radially or parallelly or parallelly composite-spun as shown in FIGS. Fibers are obtained. Further, those polyolefin-based splittable conjugate fibers can be blended with an additive that imparts other functionality to the fiber within a range that achieves the object of the present invention, and can be selected according to the application and appropriately selected. It can be blended.

【0018】 本発明のポリオレフィン系分割型複合繊
維の単糸繊度は、0.5デニ−ル〜6.0デニ−ルのも
のが好ましい。より好ましくは1.0〜4.0デニ−ル
のものである。単糸繊度が0.5デニ−ル未満の場合、
不織布加工時のカ−ド工程によるウエブ形成時にネップ
の発生、シリンダ−への沈み等が起こる傾向になる。ま
た、別方式である湿式法つまり繊維の水中分散によるウ
エブ形成法では0.5デニ−ル未満のものは、分散性不
良となる場合が多い。一方、6.0デニ−ルを越える場
合、分割後の繊度が太くなるため拭き取り性能が劣り好
ましくない。分割後に得られる分割極細繊維の繊度は
0.02〜0.50デニ−ルのものが好ましい。より好
ましくは0.30デニ−ル以下のものが拭き取り性、柔
軟性に優れた不織布が得られる。
The polyolefin-based splittable conjugate fiber of the present invention preferably has a single yarn fineness of 0.5 denier to 6.0 denier. It is more preferably 1.0 to 4.0 denier. When the single yarn fineness is less than 0.5 denier,
When a web is formed by the carding process at the time of processing a non-woven fabric, there is a tendency that a nep is generated, a sink in a cylinder or the like occurs. In another method, that is, a wet method, that is, a web forming method by dispersing fibers in water, a method of less than 0.5 denier often causes poor dispersibility. On the other hand, if it exceeds 6.0 denier, the fineness after division becomes thicker and the wiping performance is poor, which is not preferable. The fineness of the divided ultrafine fibers obtained after the division is preferably 0.02 to 0.50 denier. More preferably, a non-woven fabric having a denier of 0.30 or less can provide a non-woven fabric having excellent wiping properties and flexibility.

【0019】 本発明で練り込み添加される親水成分
は、脂肪酸グリセライド、アルコキシ化アルキルフェノ
−ル、ポリオキシアルキレン脂肪酸エステル、脂肪酸ア
ミド等の非イオン界面活性剤の群から適宜に選択して単
独であるいは混合物として使用することが出来る。その
うち紡糸時の熱安定性及びポリオレフィン系樹脂への親
水性付与能力等に基き評価された好ましい親水成分の例
として、 一般式 (I) CH2(OR1)CH(OR2)CH
2(OR3) (式中、OR1,OR2,OR3は独立してヒドロキシ基
または脂肪酸エステル基を示す。但し、少なくとも1個
は脂肪酸エステル基である。) (II) R−Ph−O−(CH2CH2O)n−CH2CH
2OH (式中、Rは1〜20個の炭素原子を有するアルキル基
であり、Phはフェニル基を示し、nは10〜55の数
値である。) (III) R−(CH2CH2O)n−CH2CH2OH (式中、Rは飽和または不飽和の脂肪酸エステル基であ
り、nは10〜55の数値である。)が挙げられる。
The hydrophilic component to be kneaded and added in the present invention is appropriately selected alone from the group of nonionic surfactants such as fatty acid glyceride, alkoxylated alkylphenol, polyoxyalkylene fatty acid ester, and fatty acid amide. Alternatively, it can be used as a mixture. Among them, examples of preferable hydrophilic components evaluated on the basis of thermal stability during spinning, hydrophilicity imparting ability to polyolefin resin, and the like include general formula (I) CH 2 (OR 1 ) CH (OR 2 ) CH
2 (OR 3 ) (In the formula, OR 1 , OR 2 , and OR 3 independently represent a hydroxy group or a fatty acid ester group, provided that at least one is a fatty acid ester group.) (II) R-Ph- O- (CH 2 CH 2 O) n -CH 2 CH
2 OH (In the formula, R is an alkyl group having 1 to 20 carbon atoms, Ph is a phenyl group, and n is a numerical value of 10 to 55.) (III) R- (CH 2 CH 2 O) n —CH 2 CH 2 OH (wherein R is a saturated or unsaturated fatty acid ester group, and n is a numerical value of 10 to 55).

【0020】 本発明のポリオレフィン系分割型複合繊
維は、少なくとも1成分に親水成分が練り込まれ、多成
分にすべて親水成分が練り込み添加されてもよい。本発
明の目的を達成する親水成分の練り込み添加量は、1成
分中1.0〜7.0重量%であり、特に2.0〜6.0
重量%のものが好ましい。親水成分の添加量が1.0重
量%未満の場合、カ−ド工程中の剥離分割により繊維の
表面積が増大した場合に十分な効果が得られず静電気が
発生し好ましくない。また7.0重量%を超える場合、
溶融紡糸工程で曳糸性が不安定になり好ましくない。親
水成分が練り込まれた第1成分と第2成分との比率は、
等量が好ましいがこれに特定するものではなく、親水成
分が練り込まれた第1成分の分割型複合繊維の比率は、
10〜90重量%が好ましく、更に好ましくは30〜7
0重量%である。
In the polyolefin-based splittable conjugate fiber of the present invention, at least one component may be kneaded with a hydrophilic component, and multicomponents may be kneaded with all hydrophilic components. The kneading addition amount of the hydrophilic component for achieving the object of the present invention is 1.0 to 7.0% by weight in one component, and particularly 2.0 to 6.0.
Weight% is preferable. When the amount of the hydrophilic component added is less than 1.0% by weight, a sufficient effect cannot be obtained when the surface area of the fiber is increased due to separation and division during the carding step, and static electricity is generated, which is not preferable. Further, when it exceeds 7.0% by weight,
In the melt spinning process, the spinnability becomes unstable, which is not preferable. The ratio of the first component and the second component in which the hydrophilic component is kneaded is
An equal amount is preferable, but not limited to this. The ratio of the splittable conjugate fiber of the first component in which the hydrophilic component is kneaded is:
10 to 90% by weight is preferable, more preferably 30 to 7
It is 0% by weight.

【0021】 本発明の不織布は、分割型複合繊維を分
割して得られる繊度0.5デニ−ル以下で、かつ異形断
面形状である。分割型複合繊維を開繊機などを用いウエ
状にし、ニードルパンチ、ウオーターニードルなどを
用い分割して得られる。さらに本発明の不織布は、坪量
20〜200g/m が好ましく、より好ましくは4
0〜150g/m である。上記の範囲を逸脱する
と、不織布の強度不足、不均一性、分割不足等の結果を
招き好ましくない。また本発明の極細繊維不織布は用途
に適用する範囲であれば本発明のポリオレフィン系分割
型複合繊維と他のポリオレフィン系繊維の混綿不織布で
も差し支えない。本発明のポリオレフィン系分割型複合
繊維は、高圧水流により分割する。本発明の目的から、
その分割率が80%以上であることが好ましい。特に8
5%以上であると、柔軟性、拭き取り性の点から好まし
い。その分割状態及び分割率は高圧水流の水圧、ライン
速度、段数、噴出孔とウエブの距離等により変化する。
従って上記80%以上の分割率を得るためには、水圧と
して60kg/cm 以上で行うことができる。より
好ましくは80kg/cm 以上でできる。
The nonwoven fabric of the present invention has a fineness of 0.5 denier or less obtained by splitting splittable conjugate fibers, and has a modified cross-sectional shape. Use the split type composite fiber to
The blanking shape, needle punch, obtained by dividing the like water needle. Furthermore, the nonwoven fabric of the present invention preferably has a basis weight of 20 to 200 g / m 2 , and more preferably 4
It is 0 to 150 g / m 2 . If it deviates from the above range, the strength of the non-woven fabric may be insufficient, the non-uniformity may be insufficient, or the division may be insufficient. The ultrafine fiber nonwoven fabric of the present invention may be a mixed cotton nonwoven fabric of the polyolefin-based splittable conjugate fiber of the present invention and other polyolefin fibers as long as it is applicable to the intended use. The polyolefin-based splittable conjugate fiber of the present invention is split by a high-pressure water stream. For the purposes of the present invention,
The division ratio is preferably 80% or more. Especially 8
It is preferable that it is 5% or more from the viewpoint of flexibility and wiping property. The division state and the division ratio change depending on the water pressure of the high-pressure water stream, the line speed, the number of stages, the distance between the ejection hole and the web, and the like.
Therefore, in order to obtain the above-mentioned division ratio of 80% or more, the water pressure may be 60 kg / cm 2 or more. It is more preferably 80 kg / cm 2 or more.

【0022】 本発明の0.5デニ−ル以下で異形断面
の極細繊維からなる極細繊維不織布は、親水成分が繊維
自体に練り込み添加されているために、最終的に親水性
を必要とする用途でも後処理として親水成分の付着等の
親水化処理をする必要がなく、また全てがポリオレフィ
ン系樹脂で構成される場合は、耐酸性、耐アルカリ性に
優れるので一層汎用に富んでいる。本発明の極細繊維不
織布は、上記構成により、医療用及び工業用ワイピング
クロス、マスク、手術衣、包装布、フィルタ−、衛生用
品の表面材、建築構造体補強繊維、液体輸送膜等に使用
できる。
The ultrafine fiber nonwoven fabric made of ultrafine fibers having a modified cross section of 0.5 denier or less of the present invention finally needs hydrophilicity because the hydrophilic component is kneaded and added into the fibers themselves. In applications, there is no need to perform a hydrophilic treatment such as adhesion of a hydrophilic component as a post-treatment, and when all are made of a polyolefin-based resin, they are excellent in acid resistance and alkali resistance, and therefore more versatile. The ultrafine fiber nonwoven fabric of the present invention can be used for medical and industrial wiping cloths, masks, surgical gowns, packaging cloths, filters, surface materials for sanitary goods, building structure reinforcing fibers, liquid transport membranes, etc. .

【0023】 以下本発明を実施例にて更に詳細に説明
するが本発明の要旨を越えない限り以下の実施例、比較
例に限定されるものではない。なお、各例において繊維
の物性の評価並びに、不織布性能等の評価は以下に示す
方法で行った。 (1)糸の強伸度:JIS L 1069の方法によ
る。試長20mm,引張速度20mm/分の条件でテス
トし、強度(g/d),伸度(%)を求めた。 (2)カ−ド通過性:各工程を目視により評価した。 ○:静電気の発生及びネップの発生もなく良好。 ×:静電気が発生し通過性不良。 (3)分割率:試料をワックスに包埋し、ミクロト−ム
で繊維軸に対しほぼ直角に切断し試料片を得る。これを
顕微鏡で観察し、得られた断面像から画像処理にて、分
割した分割極細繊維の総断面積(A)と未分割の分割型
複合繊維の総断面積(B)を測定し、以下の式で算出し
た。 分割率%=A/(A+B)×100
Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the following Examples and Comparative Examples as long as the gist of the present invention is not exceeded. In addition, in each example, the evaluation of the physical properties of the fiber and the evaluation of the nonwoven fabric performance and the like were performed by the following methods. (1) Strength / elongation of yarn: According to the method of JIS L 1069. The test was conducted under the conditions of a test length of 20 mm and a pulling speed of 20 mm / min, and the strength (g / d) and the elongation (%) were obtained. (2) Card passability: Each step was visually evaluated. ◯: Good with no generation of static electricity and no nep. ×: Static electricity is generated and the passability is poor. (3) Dividing ratio: The sample is embedded in wax and cut with a microtome at a right angle to the fiber axis to obtain a sample piece. This is observed with a microscope, and the total cross-sectional area (A) of the divided ultrafine fibers divided and the total cross-sectional area (B) of the undivided splittable conjugate fiber (B) are measured by image processing from the obtained cross-sectional image. It was calculated by the formula. Split rate% = A / (A + B) × 100

【0024】 (4)風合い:触感により評価した。 ○:非常に良い。 ×:やや悪い。 (5)親水性:極細繊維不織布を80±5℃の恒温装置
内で5時間放置した後、デシケ−タ内で室温まで冷却
し、恒温水槽中で23±2℃に調整した蒸留水をピペッ
トにて不織布上1cmの高さより1滴ずつ位置をずらし
ながら計20点滴下し以下の式で算出した。 親水性%=〔滴下後30秒以内に吸水された水滴数/総
滴下数(;20点)〕×100 (6)拭き取り性:平面な硝子板に油脂及び蒸留水を一
定量塗布し、拭き取り試験を行った。拭き取り後、目視
により硝子表面の曇りを観察した。油脂及び水がきれい
に拭き取れた物を拭き取り性が良い(○)。硝子表面の
油脂または水のどちらかが残り、曇りが取れない物を拭
き取り性が不良(×)として評価した。それらの結果
は、表1に示した。 (7)繊度 分割前繊度は、カットする前の繊維束を6cmにカットし
150本を秤量し、試験回数5回として求めた。分割後
繊度は、使用した分割型複合繊維紡糸用口金の分割数か
ら計算で求めた。
(4) Texture: Evaluation was made by touch. ○: Very good. X: Somewhat bad. (5) Hydrophilicity: After leaving the ultrafine fiber non-woven fabric in an incubator at 80 ± 5 ° C for 5 hours, it was cooled to room temperature in a desiccator, and distilled water adjusted to 23 ± 2 ° C in a thermostat water pipette. Then, a total of 20 points were dropped while shifting the position of each drop from the height of 1 cm on the non-woven fabric, and the calculation was performed by the following formula. Hydrophilicity = [Number of water drops absorbed within 30 seconds after dropping / total number of drops (; 20 points)] x 100 (6) Wipeability: A certain amount of oil and distilled water was applied to a flat glass plate and wiped off. The test was conducted. After wiping, the cloudiness of the glass surface was visually observed. Good for wiping off things that have been cleanly wiped of oils and fats (○). One in which oil or water on the glass surface remained and the cloudiness could not be removed was evaluated as poor wiping property (x). The results are shown in Table 1. (7) Fineness The fineness before division was obtained by cutting the fiber bundle before cutting into 6 cm, weighing 150 pieces, and conducting the test 5 times. The fineness after division was calculated from the number of divisions of the division type composite fiber spinning die used.

【0025】実施例1 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンにエトキシ化アルキルフェノ−ル
及び混合グリセライド(ICI製、商品名アトマ−68
5)を1重量%練り込み添加した樹脂を第2成分とし
て、分割型複合繊維紡糸用口金を用いて、第1成分と第
2成分の体積比が5対5である図1の断面を有する分割
型複合繊維を得た。この分割型複合繊維を、延伸倍率
6.0倍で延伸後、クリンパ−で捲縮数約17山/吋に
捲縮加工を施し繊維仕上剤としてアルキルフォスフェ−
トK塩を0.3重量%付着した後カットした。単糸繊度
2.0デニ−ル、繊維長45mmで強度4.2g/d、
伸度38%のステ−プルファイバ−を得た。得られたス
テ−プルファイバ−を、カ−ド工程にてウエブを形成し
た後、80kg/cm2の高水圧にて不織布加工を施し
た。評価結果は表1に示した。
Example 1 Polypropylene of MFR30 (g / 10 minutes, 230 ° C.) was used as the first component, and MFR25 (g / 10 minutes, 190 ° C.)
High-density polyethylene with ethoxylated alkylphenol and mixed glycerides (ICI, trade name Atoma-68
5) is added to the resin as a second component, and a splitting type composite fiber spinning die is used, and the volume ratio of the first component to the second component is 5: 5. A splittable conjugate fiber was obtained. The splittable conjugate fiber was drawn at a draw ratio of 6.0 times and then crimped with a crimper to a crimping number of about 17 threads / inch to give an alkyl phosphate as a fiber finishing agent.
Tok K salt was attached at 0.3% by weight and then cut. Single yarn fineness 2.0 denier, fiber length 45 mm, strength 4.2 g / d,
A staple fiber having an elongation of 38% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0026】実施例2 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR20(g/10分、190℃)
の直鎖状低密度ポリエチレンに実施例1で添加した親水
成分と同様の成分を2重量%練り込み添加した物を第2
成分とし、分割型複合繊維紡糸用口金を用いて、第1成
分と第2成分の体積比が5対5である図1の断面を有す
る分割型複合繊維を得た。この分割型複合繊維を、延伸
倍率4.0倍で延伸後、クリンパ−で捲縮数約17山/
吋に捲縮加工を施し繊維仕上剤としてアルキルフォスフ
ェ−トK塩を0.3重量%付着した後カットした。単糸
繊度1.3デニ−ル、繊維長45mmで強度3.5g/
d、伸度38%のステ−プルファイバ−を得た。得られ
たステ−プルファイバ−を、カ−ド工程にてウエブを形
成した後、80kg/cm2の高水圧にて不織布加工を
施した。評価結果は表1に示した。
Example 2 Polypropylene of MFR30 (g / 10 minutes, 230 ° C.) was used as the first component, and MFR20 (g / 10 minutes, 190 ° C.)
2% by weight of the same linear hydrophilic low density polyethylene as the hydrophilic component added in Example 1 was kneaded and added to
Using a splittable conjugate fiber spinning die as a component, a splittable conjugate fiber having a cross section of FIG. 1 in which the volume ratio of the first component to the second component was 5: 5 was obtained. This splittable conjugate fiber was drawn at a draw ratio of 4.0 times and then crimped to a crimp number of about 17 peaks /
The bowl was crimped, and 0.3% by weight of an alkyl phosphate K salt as a fiber finishing agent was adhered thereto and then cut. Single yarn fineness 1.3 denier, fiber length 45 mm, strength 3.5 g /
A staple fiber having d and an elongation of 38% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0027】実施例3 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンに実施例1で添加した親水成分と
同様の成分を6重量%練り込み添加した物を第2成分と
し、分割型複合繊維紡糸用口金を用いて、第1成分と第
2成分の体積比が5対5である図1の断面を有する分割
型複合繊維を得た。この分割型複合繊維を、延伸倍率
6.0倍で延伸後、クリンパ−で捲縮数約17山/吋に
捲縮加工を施し繊維仕上剤としてアルキルフォスフェ−
トK塩を0.3重量%付着した後カットした。単糸繊度
2.0デニ−ル、繊維長45mmで強度3.8g/d、
伸度45%のステ−プルファイバ−を得た。得られたス
テ−プルファイバ−を、カ−ド工程にてウエブを形成し
た後、80kg/cm2の高水圧にて不織布加工を施し
た。評価結果は表1に示した。
Example 3 Polypropylene of MFR30 (g / 10 minutes, 230 ° C) was used as the first component, and MFR25 (g / 10 minutes, 190 ° C).
The second component is obtained by kneading and adding 6% by weight of a component similar to the hydrophilic component added in Example 1 to the high-density polyethylene of Example 1 and using a splitting type composite fiber spinning die. A splittable conjugate fiber having a cross-section of FIG. 1 having a volume ratio of 5: 5 was obtained. The splittable conjugate fiber was drawn at a draw ratio of 6.0 times and then crimped with a crimper to a crimping number of about 17 threads / inch to give an alkyl phosphate as a fiber finishing agent.
Tok K salt was attached at 0.3% by weight and then cut. Single yarn fineness 2.0 denier, fiber length 45 mm, strength 3.8 g / d,
A staple fiber having an elongation of 45% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0028】実施例4 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンに実施例1で添加した親水成分と
同様の成分を6重量%練り込み添加した物を第2成分と
し、分割型複合繊維紡糸用口金を用いて、第1成分と第
2成分の体積比が5対5である図1の断面を有する分割
型複合繊維を得た。この分割型複合繊維を、延伸倍率
6.0倍で延伸後、クリンパ−で捲縮数約17山/吋に
捲縮加工を施し繊維仕上剤としてアルキルフォスフェ−
トK塩を0.3重量%付着した後カットした。単糸繊度
6.0デニ−ル、繊維長51mmで強度3.5g/d、
伸度55%のステ−プルファイバ−を得た。得られたス
テ−プルファイバ−を、カ−ド工程にてウエブを形成し
た後、80kg/cm2の高水圧にて不織布加工を施し
た。評価結果は表1に示した。
Example 4 MFR30 (g / 10 min, 230 ° C.) polypropylene was used as the first component, and MFR25 (g / 10 min, 190 ° C.)
The second component is obtained by kneading and adding 6% by weight of a component similar to the hydrophilic component added in Example 1 to the high-density polyethylene of Example 1 and using a splitting type composite fiber spinning die. A splittable conjugate fiber having a cross-section of FIG. 1 having a volume ratio of 5: 5 was obtained. The splittable conjugate fiber was drawn at a draw ratio of 6.0 times and then crimped with a crimper to a crimping number of about 17 threads / inch to give an alkyl phosphate as a fiber finishing agent.
Tok K salt was attached at 0.3% by weight and then cut. Single yarn fineness 6.0 denier, fiber length 51 mm, strength 3.5 g / d,
A staple fiber having an elongation of 55% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0029】実施例5 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンに実施例1で添加した親水成分と
同様の成分を7重量%練り込み添加した物を第2成分と
し、分割型複合繊維紡糸用口金を用いて、第1成分と第
2成分の体積比が5対5である図1の断面を有する分割
型複合繊維を得た。この分割型複合繊維を、延伸倍率
6.0倍で延伸後、クリンパ−で捲縮数約17山/吋に
捲縮加工を施し繊維仕上剤としてアルキルフォスフェ−
トK塩を0.3重量%付着した後カットした。単糸繊度
2.0デニ−ル、繊維長45mmで強度3.6g/d、
伸度32%のステ−プルファイバ−を得た。得られたス
テ−プルファイバ−を、カ−ド工程にてウエブを形成し
た後、80kg/cm2の高水圧にて不織布加工を施し
た。評価結果は表1に示した。
Example 5 Polypropylene of MFR30 (g / 10 minutes, 230 ° C) was used as the first component, and MFR25 (g / 10 minutes, 190 ° C).
The second component is obtained by kneading 7% by weight of a component similar to the hydrophilic component added in Example 1 to the high-density polyethylene of Example 1 and using a splitting type composite fiber spinning die as a first component and a second component. A splittable conjugate fiber having a cross-section of FIG. 1 having a volume ratio of 5: 5 was obtained. The splittable conjugate fiber was drawn at a draw ratio of 6.0 times and then crimped with a crimper to a crimping number of about 17 threads / inch to give an alkyl phosphate as a fiber finishing agent.
Tok K salt was attached at 0.3% by weight and then cut. Single yarn fineness 2.0 denier, fiber length 45 mm, strength 3.6 g / d,
A staple fiber having an elongation of 32% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0030】実施例6 MFR30(g/10分、230℃)のポリプロピレン
に実施例1で添加した親水成分と同様の成分を3重量%
練り込み添加した物を第1成分とし、MFR25(g/
10分、190℃)の高密度ポリエチレンに実施例1で
添加した親水成分と同様の成分を3重量%練り込み添加
した物を第2成分とし、分割型複合繊維紡糸用口金を用
いて、第1成分と第2成分の体積比が5対5である図1
の断面を有する分割型複合繊維を得た。この分割型複合
繊維を、延伸倍率5.0倍で延伸後、クリンパ−で捲縮
数約17山/吋に捲縮加工を施し繊維仕上剤としてアル
キルフォスフェ−トK塩を0.3重量%付着した後カッ
トした。単糸繊度2.0デニ−ル、繊維長51mmで強
度3.5g/d、伸度45%のステ−プルファイバ−を
得た。得られたステ−プルファイバ−を、カ−ド工程に
てウエブを形成した後、80kg/cm2の高水圧にて
不織布加工を施した。評価結果は表1に示した。
Example 6 3% by weight of the same component as the hydrophilic component added in Example 1 was added to polypropylene of MFR30 (g / 10 minutes, 230 ° C.).
The kneaded and added product is used as the first component, and MFR25 (g / g
(10 minutes, 190 ° C.) High-density polyethylene (3% by weight) similar to the hydrophilic component added in Example 1 was kneaded and added as the second component, and the split type composite fiber spinning die was used to The volume ratio of the first component to the second component is 5: 5 in FIG.
A splittable conjugate fiber having a cross section of was obtained. The splittable conjugate fiber was drawn at a draw ratio of 5.0 times and then crimped with a crimper to a crimping number of about 17 threads / inch, and 0.3 weight of an alkyl phosphate K salt was used as a fiber finishing agent. % After adhering, cut. A staple fiber having a single yarn fineness of 2.0 denier, a fiber length of 51 mm, a strength of 3.5 g / d and an elongation of 45% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0031】実施例7,8 実施例3で得られたウエブを加工水圧80kg/cm
で加工段数をそれぞれ2段、3段と変更し不織布加工
を施した。評価結果は表1に示した。
Examples 7 and 8 The web obtained in Example 3 was processed into water having a pressure of 80 kg / cm 2.
The number of processing steps was changed to 2 steps and 3 steps respectively, and non-woven fabric processing was performed. The evaluation results are shown in Table 1.

【0032】比較例1 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンを第2成分とし、分割型複合繊維
紡糸用口金を用いて、第1成分と第2成分の体積比が5
対5である図1の断面を有する分割型複合繊維を得た。
この分割型複合繊維を、延伸倍率6.0倍で延伸後、ク
リンパ−で捲縮数約17山/吋に捲縮加工を施し繊維仕
上剤としてアルキルフォスフェ−トK塩を0.3重量%
付着した後カットした。単糸繊度2.0デニ−ル、繊維
長51mmで強度4.3g/d、伸度30%のステ−プ
ルファイバ−を得た。得られたステ−プルファイバ−
を、カ−ド工程にてウエブを形成した後、80kg/c
2の高水圧にて不織布加工を施した。評価結果は表1
に示した。
Comparative Example 1 MFR30 (g / 10 minutes, 230 ° C.) polypropylene was used as the first component, and MFR25 (g / 10 minutes, 190 ° C.).
The high-density polyethylene as the second component is used as the second component, and the volume ratio of the first component and the second component is 5 by using the split type composite fiber spinning die.
A splittable conjugate fiber having a cross section of FIG.
The splittable conjugate fiber was drawn at a draw ratio of 6.0 times and then crimped with a crimper to a crimp number of about 17 threads / inch, and 0.3 weight of an alkyl phosphate K salt was used as a fiber finishing agent. %
It cut after adhering. A staple fiber having a single yarn fineness of 2.0 denier, a fiber length of 51 mm, a strength of 4.3 g / d and an elongation of 30% was obtained. Obtained staple fiber
After forming the web in the carding process, 80 kg / c
The nonwoven fabric was processed under a high water pressure of m 2 . Table 1 shows the evaluation results.
It was shown to.

【0033】比較例2 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンに実施例1で添加した親水成分と
同様の成分を0.5重量%練り込み添加した物を第2成
分とし、分割型複合繊維紡糸用口金を用いて、第1成分
と第2成分の体積比が5対5である図1の断面を有する
分割型複合繊維を得た。この分割型複合繊維を、延伸倍
率6.0倍で延伸後、クリンパ−で捲縮数約17山/吋
に捲縮加工を施し繊維仕上剤としてアルキルフォスフェ
−トK塩を0.3重量%付着した後カットした。単糸繊
度2.0デニ−ル、繊維長45mmで強度4.0g/
d、伸度32%のステ−プルファイバ−を得た。得られ
たステ−プルファイバ−を、カ−ド工程にてウエブを形
成した後、80kg/cm2の高水圧にて不織布加工を
施した。評価結果は表1に示した。
Comparative Example 2 MFR30 (g / 10 minutes, 230 ° C.) polypropylene was used as the first component, and MFR25 (g / 10 minutes, 190 ° C.).
The second component is obtained by kneading 0.5% by weight of the same component as the hydrophilic component added in Example 1 into the second high density polyethylene, and using the split type composite fiber spinning die as a first component, A splittable conjugate fiber having a cross section of FIG. 1 in which the volume ratio of the two components was 5: 5 was obtained. The splittable conjugate fiber was drawn at a draw ratio of 6.0 times and then crimped with a crimper to a crimp number of about 17 threads / inch, and 0.3 weight of an alkyl phosphate K salt was used as a fiber finishing agent. % After adhering, cut. Single yarn fineness 2.0 denier, fiber length 45 mm, strength 4.0 g /
d, a staple fiber having an elongation of 32% was obtained. The staple fiber thus obtained was subjected to a carding process to form a web, and then a nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0034】比較例3 MFR30(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンに実施例1で添加した親水成分と
同様の成分を9重量%練り込み添加した物を第2成分と
し、分割型複合繊維紡糸用口金を用いて紡糸したが、曳
糸性が安定せず。サンプルが得られなかった。
Comparative Example 3 MFR30 (g / 10 minutes, 230 ° C.) polypropylene was used as the first component, and MFR25 (g / 10 minutes, 190 ° C.).
The second component was prepared by kneading 9% by weight of a component similar to the hydrophilic component added in Example 1 to the high-density polyethylene described above, and was spun using a splitting type composite fiber spinning die. Not stable. No sample was obtained.

【0035】比較例4 MFR10(g/10分、230℃)のポリプロピレン
を第1成分とし、MFR25(g/10分、190℃)
の高密度ポリエチレンに実施例1で添加した親水成分と
同様の成分を6重量%練り込み添加した物を第2成分と
し、鞘芯型複合繊維紡糸用口金を用いて、第1成分と第
2成分の体積比が5対5である鞘芯型の断面を有する鞘
芯型複合繊維を得た。この複合繊維を、延伸倍率4.0
倍で延伸後、クリンパ−で捲縮数約17山/吋に捲縮加
工を施し繊維仕上剤としてアルキルフォスフェ−トK塩
を0.3重量%付着した後カットした。単糸繊度2.0
デニ−ル、繊維長45mmで強度3.2g/d、伸度7
7%のステ−プルファイバ−を得た。得られたステ−プ
ルファイバ−を、カ−ド工程にてウエブを形成した後、
80kg/cm2の高水圧にて不織布加工を施した。評
価結果は表1に示した。
Comparative Example 4 MFR10 (g / 10 min, 230 ° C.) polypropylene was used as the first component, and MFR25 (g / 10 min, 190 ° C.)
The second component is prepared by kneading and adding 6 wt% of the same component as the hydrophilic component added in Example 1 to the high-density polyethylene described above, and the sheath-core type composite fiber spinning die is used to prepare the first component and the second component. A sheath-core type composite fiber having a sheath-core type cross section in which the volume ratio of the components was 5: 5 was obtained. This composite fiber is stretched at a draw ratio of 4.0.
After stretching at twice, crimping was applied to about 17 ridges / inch with a crimper, 0.3% by weight of alkyl phosphate K salt as a fiber finishing agent was adhered thereto, and then cut. Single yarn fineness 2.0
Denier, fiber length 45 mm, strength 3.2 g / d, elongation 7
7% staple fiber was obtained. After forming a web in the carding process of the obtained staple fiber,
The nonwoven fabric was processed at a high water pressure of 80 kg / cm 2 . The evaluation results are shown in Table 1.

【0036】比較例5 比較例1で得られたステ−プルファイバ−を、カ−ド工
程にてウエブを形成した後、80kg/cm2の高水圧
にて加工段数を2段に変更し不織布加工を施した。評価
結果は表1に示した。
Comparative Example 5 The staple fiber obtained in Comparative Example 1 was subjected to a carding process to form a web, and the number of processing steps was changed to 2 by a high water pressure of 80 kg / cm 2 to obtain a nonwoven fabric. Processed. The evaluation results are shown in Table 1.

【0037】[0037]

【発明の効果】 本発明のポリオレフィン系分割型複合
繊維は、親水成 分の練り込まれた成分を有し親水効果
を持続するので、カ−ド処理中に分割、剥離が少なくカ
−ド作業性は良好であった。本発明のポリオレフィン系
分割型複合繊維は、カ−ド処理中に例え分割、剥離が多
少起き分割、剥離面が発生しても、練り込まれた親水成
分をブリードアウトし、静電気の発生を抑え、ネップの
発生もなくカ−ド通過性を改善した。本発明のポリオレ
フィン系分割型複合繊維は、繊維自体に親水成分が練り
込み添加されているために繊維仕上剤として繊維表面に
付着していた親水性界面活性剤が洗い流された場合でも
繊維表面に親水成分が現れた。本発明のポリオレフィン
系分割型複合繊維は、カ−ド処理中には、分割、剥離が
少なく、高圧水流による加工、いわゆるウオーターニド
ル加工に於いても親水効果を持続するので、水するこ
となく嵩高になることなく加工前処理の水濡れ状態を維
持し、高圧水流による加工に於いて分割率が著しく向上
した。また更に本発明のポリオレフィン系分割型複合繊
維は、剥離分割した界面にも親水成分が現れるので、湿
潤性が向上し、高圧水流による不織布化加工を繰り返し
た場合でも繊維が水流を避ける事なく、水の衝撃エネル
ギ−を均等に受け易くなり、少ない段数で十分均一に分
割した極細繊維不織布が得られた。
EFFECTS OF THE INVENTION The polyolefin-based splittable conjugate fiber of the present invention has a kneaded component of a hydrophilic component and maintains the hydrophilic effect. The sex was good. The polyolefin-based splittable conjugate fiber of the present invention suppresses the generation of static electricity by bleeding out the kneaded hydrophilic component even if splitting or peeling occurs to some extent during the card treatment and splitting occurs. The card passage property was improved without the occurrence of nep. The polyolefin-based splittable conjugate fiber of the present invention has a hydrophilic component kneaded and added to the fiber itself, so that even if the hydrophilic surfactant adhering to the fiber surface as a fiber finishing agent is washed off, A hydrophilic component appeared. Polyolefin splittable conjugate fiber of the present invention, Ca - in de processing, splitting, peeling less, processed by the high-pressure water stream, since sustain the hydrophilic effect at the so-called water two dollars processing, be water repellent Maintaining the wet condition of the pretreatment before processing without becoming bulky, the splitting rate was significantly improved in processing by high pressure water flow. Furthermore, the polyolefin-based splittable conjugate fiber of the present invention has a hydrophilic component that appears at the separated and separated interface, so that the wettability is improved, and the fiber does not avoid the flow of water even when the non-woven fabric is repeatedly processed by high-pressure water flow. It became easier to receive the impact energy of water evenly, and an ultrafine fiber nonwoven fabric was obtained which was sufficiently evenly divided with a small number of steps.

【0038】 本発明のポリオレフィン系分割型複合繊
維は、カ−ド通過性を改善した上、高圧水流による加
工、いわゆるウオーターニドル加工に於いても親水効果
を持続するので、水することなく嵩高になることなく
加工前処理の水濡れ状態を維持し、高圧水流による加工
に於いて分割率が著しく向上した。本発明の極細繊維か
らなる不織布は、未分割複合繊維が少なく、極細繊維が
均一に分散し且つ相互に交絡し、かつ親水性を練り込ま
れており、柔軟であり、親水性を有していた。本発明の
極細繊維からなる不織布は、親水成分を練り込まれポリ
オレフィン系樹脂からなる異形断面の極細繊維なので、
油脂汚れの拭き取りと同時に水成分汚れの拭き取り性が
良かった。
The polyolefin splittable conjugate fiber of the present invention, Ca - after having improved de passing property, processing by high-pressure water, since sustain the hydrophilic effect at the so-called water two dollars processed without water repellent The wettability of the pretreatment before processing was maintained without becoming bulky, and the splitting rate was significantly improved during processing by high-pressure water flow. The nonwoven fabric composed of the ultrafine fibers of the present invention has a small amount of undivided composite fibers, the ultrafine fibers are uniformly dispersed and entangled with each other, and the hydrophilicity is kneaded into the nonwoven fabric, which is soft and hydrophilic. It was The non-woven fabric made of the ultrafine fibers of the present invention is an ultrafine fiber having a modified cross section made of a polyolefin-based resin in which a hydrophilic component is kneaded,
At the same time as wiping off greasy dirt, it was easy to wipe off water component dirt.

【0039】[0039]

【表1】 [Table 1]

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の分割型複合繊維の断面図である。FIG. 1 is a cross-sectional view of a splittable conjugate fiber of the present invention.

【図2】本発明の分割型複合繊維の断面図である。FIG. 2 is a cross-sectional view of the splittable conjugate fiber of the present invention.

【図3】本発明の分割型複合繊維の断面図である。FIG. 3 is a cross-sectional view of the splittable conjugate fiber of the present invention.

【図4】本発明の分割型複合繊維の断面図である。FIG. 4 is a cross-sectional view of the splittable conjugate fiber of the present invention.

【図5】本発明の分割型複合繊維の断面図である。FIG. 5 is a cross-sectional view of the splittable conjugate fiber of the present invention.

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 主としてポリオレフィン系樹脂からなる
分割型複合繊維であって、ポリオレフィン系樹脂の少な
くとも1成分に、脂肪酸グリセライド、アルコキシ化ア
ルキルフェノール、ポリオキシアルキレン脂肪酸エステ
ルの群から選ばれた少なくとも1種である親水成分が
1.0〜7.0重量%練り込み添加されたポリオレフィ
ン系分割型複合繊維。
1. A splittable conjugate fiber mainly comprising a polyolefin resin, wherein at least one component of the polyolefin resin comprises a fatty acid glyceride and an alkoxylated resin.
Ruquilphenol, polyoxyalkylene fatty acid ester
Polyolefin-based splittable conjugate fiber in which 1.0 to 7.0% by weight of a hydrophilic component, which is at least one selected from the group of the above-mentioned group, is kneaded and added.
【請求項2】 請求項1に記載のポリオレフィン系分割
型複合繊維を分割して得られる繊度0.5デニール以下
であり、かつ異形断面形状である極細繊維からなる不織
布。
2. A non-woven fabric made of ultrafine fibers having a fineness of 0.5 denier or less, which is obtained by dividing the polyolefin-based splittable conjugate fiber according to claim 1 .
JP13862395A 1995-05-12 1995-05-12 Polyolefin-based splittable conjugate fiber and nonwoven fabric Expired - Fee Related JP3525556B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13862395A JP3525556B2 (en) 1995-05-12 1995-05-12 Polyolefin-based splittable conjugate fiber and nonwoven fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13862395A JP3525556B2 (en) 1995-05-12 1995-05-12 Polyolefin-based splittable conjugate fiber and nonwoven fabric

Publications (2)

Publication Number Publication Date
JPH08311717A JPH08311717A (en) 1996-11-26
JP3525556B2 true JP3525556B2 (en) 2004-05-10

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Country Link
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK1149424T3 (en) 1999-01-08 2007-04-30 Ahlstrom Mount Holly Springs L Durable hydrophilic non-woven mat for rechargeable alkaline batteries
CN102822399B (en) 2010-03-30 2015-04-29 大和纺控股株式会社 Polyolefin-based split-type conjugate fibre, fibrous mass and cell separator using same, and production method for same

Also Published As

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