JP3521235B2 - Dyeing aid - Google Patents
Dyeing aidInfo
- Publication number
- JP3521235B2 JP3521235B2 JP34620092A JP34620092A JP3521235B2 JP 3521235 B2 JP3521235 B2 JP 3521235B2 JP 34620092 A JP34620092 A JP 34620092A JP 34620092 A JP34620092 A JP 34620092A JP 3521235 B2 JP3521235 B2 JP 3521235B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- dyeing
- dye
- group
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Description
【０００１】[0001]
【産業上の利用分野】本発明は、染色補助剤及びこの染
色補助剤を含有する毛髪染料組成物に関する。FIELD OF THE INVENTION The present invention relates to a dyeing auxiliary agent and a hair dye composition containing the dyeing auxiliary agent.
【０００２】[0002]
【従来の技術およびその課題】染毛剤用の染料として、
従来パラフェニレンジアミン、パラアミノフェノールな
どの酸化染料が主として用いられている。この染毛剤
は、上記酸化染料を毛髪などに適用した後、過酸化水素
等の過酸化物を用いて該染料を酸化重合させて染料を毛
髪に固定し、持続的な染色を行うものである。そして、
過酸化物の分解を促進し、染毛をより円滑に行うために
アンモニアやモノエタノールアミンなどの塩基性化合物
が通常添加されている。2. Description of the Related Art As a dye for a hair dye,
Conventionally, oxidation dyes such as para-phenylenediamine and para-aminophenol have been mainly used. This hair dye is one in which the above-mentioned oxidation dye is applied to hair and the like, and then the dye is oxidatively polymerized by using peroxide such as hydrogen peroxide to fix the dye to the hair for continuous dyeing. is there. And
A basic compound such as ammonia or monoethanolamine is usually added in order to accelerate the decomposition of peroxide and to make hair dyeing smoother.
【０００３】しかしながら、過酸化物を用いた酸化染料
の重合反応はかなり激しい反応であるため、毛髪や皮膚
に存在するタンパク質などの生体成分に対しても同時に
反応し、また、塩基性化合物などの添加剤の影響もあ
り、毛髪や皮膚が傷みやすく、かぶれ等の皮膚炎を起こ
すこともあった。また、酸化重合のような激しい反応は
制御が難しいため、染色むらが生じやすい問題もあっ
た。染料の酸化重合の条件を緩和すれば、これらの欠点
は軽減されるが、毛髪の染色性や染色堅牢性も同時に低
下するため、均一に且つ十分な濃さで染毛を行いつつか
ぶれなどの副作用の発生を抑えることは困難であった。However, since the polymerization reaction of an oxidative dye using a peroxide is a very vigorous reaction, it also simultaneously reacts with biological components such as proteins present in hair and skin, and also with basic compounds such as basic compounds. Due to the effects of additives, hair and skin were easily damaged, and dermatitis such as rashes sometimes occurred. Further, since it is difficult to control a violent reaction such as oxidative polymerization, there is a problem that uneven dyeing is likely to occur. If the conditions for the oxidative polymerization of the dye are alleviated, these drawbacks are alleviated, but the dyeing properties and dyeing fastness of the hair are also reduced at the same time, so that hair is uniformly and sufficiently thickened while causing rashes and the like. It was difficult to suppress the occurrence of side effects.
【０００４】また、リンスやシャンプーなどの製品に吸
着染料を混合し、該染料を毛髪に吸着させて染色する試
みも行われている。この方法によれば、皮膚や毛髪の組
織に対する影響はほとんどないが、吸着染料は毛髪を水
洗い等する際に毛髪から脱着し易く、十分な染色効果を
得るのが困難であった。Attempts have also been made to mix adsorbing dyes with products such as rinses and shampoos, and to adsorb the dyes on hair to dye them. According to this method, there is almost no effect on the tissues of the skin or hair, but the adsorbent dye is easily desorbed from the hair when the hair is washed with water, and it is difficult to obtain a sufficient dyeing effect.
【０００５】本発明は、染料の染色むらを抑制し、濃染
性および染色堅牢性などを向上させて、より緩和な条件
で染色を行うことのできる染色補助剤および該染色補助
剤を用いた持続的または一時的毛髪染料組成物を提供す
ることを目的とする。The present invention uses a dyeing auxiliary agent and a dyeing auxiliary agent capable of suppressing uneven dyeing, improving the deep dyeing property and dyeing fastness, and performing dyeing under milder conditions. The aim is to provide a permanent or temporary hair dye composition.
【０００６】[0006]
【課題を解決するための手段】本発明者は、上記の染色
剤の欠点を解消するため鋭意検討を重ねた結果、特定構
造のアルキルグリコシド類が毛髪の染色補助剤として優
れていることを見出した。即ち、本発明は、一般式
（１）：Means for Solving the Problems As a result of intensive studies to solve the above drawbacks of the dyeing agent, the present inventor has found that alkyl glycosides having a specific structure are excellent as hair dyeing auxiliary agents. It was That is, the present invention provides the general formula (1):
【０００７】[0007]
【化４】 [Chemical 4]
【０００８】〔式中、Ｒは炭素数１〜１８の直鎖または
分枝状のアルキル基を示し、ＸおよびＹは同一または異
なって−ＣＨ2 ＣＨ2 Ｏ−、−ＣＨ（ＣＨ3 ）ＣＨ2 Ｏ
−または−ＣＨ2 ＣＨ（ＣＨ3 ）Ｏ−を示し、Ｇは同一
または異なって炭素数５または６の糖残基を示し、ｎお
よびｎ´は、平均値が０≦ｎ≦１０および０≦ｎ´≦１
０を示し、ｎ''は平均値が０≦ｎ''≦３ｘ＋１を示し、
ｘは平均値が１≦ｘ≦１０を示す〕で表されるアルキル
グリコシド類の少なくとも１種からなる毛髪染色補助剤
を提供するものである。[In the formula, R represents a linear or branched alkyl group having 1 to 18 carbon atoms, and X and Y are the same or different and are -CH 2 CH 2 O-, -CH (CH 3 ) CH. 2 O
- or -CH 2 CH (CH 3) O- are shown, G are the same or different represents a sugar residue of 5 or 6 carbon atoms, n and n'has an average value of 0 ≦ n ≦ 10 and 0 ≦ n'≤1
0, n ″ has an average value of 0 ≦ n ″ ≦ 3x + 1,
x represents an average value of 1 ≦ x ≦ 10], and provides a hair dyeing auxiliary agent comprising at least one kind of alkyl glycosides.
【０００９】また、本発明は、酸化染料０．１〜２０重
量％、過酸化物０．０５〜２０重量％および一般式
（１）：The present invention also provides an oxidative dye of 0.1 to 20% by weight, a peroxide of 0.05 to 20% by weight and a general formula (1):
【００１０】[0010]
【化５】 [Chemical 5]
【００１１】〔式中、Ｒ、Ｘ、Ｙ、Ｇ、ｎ、ｎ´、ｎ''
およびｘは前記に同じ〕で表されるアルキルグリコシド
０．０１〜２０重量％を含む持続的毛髪染料組成物を提
供するものである。[Wherein R, X, Y, G, n, n ', n "
And x are the same as described above] to provide a continuous hair dye composition containing 0.01 to 20% by weight of an alkyl glycoside.
【００１２】さらに、本発明は、吸着染料０．１〜２０
重量％および一般式（１）：Further, the present invention provides an adsorption dye of 0.1 to 20.
Weight% and general formula (1):
【００１３】[0013]
【化６】 [Chemical 6]
【００１４】〔式中、Ｒ、Ｘ、Ｙ、Ｇ、ｎ、ｎ´、ｎ''
およびｘは前記に同じ〕で表されるアルキルグリコシド
０．０１〜２０重量％を含む一時的毛髪染料組成物を提
供するものである。[Wherein R, X, Y, G, n, n ', n "
And x are the same as those defined above] to provide a temporary hair dye composition containing 0.01 to 20% by weight of an alkyl glycoside.
【００１５】なお、上記のアルキルグリコシド、酸化染
料、過酸化物および吸着染料は、各々溶媒等を含んだ組
成物全量に対する割合を重量％で示したものである。The above-mentioned alkyl glycosides, oxidation dyes, peroxides and adsorption dyes are shown by weight% in proportion to the total amount of the composition containing a solvent and the like.
【００１６】なお、持続的毛髪染料組成物において、組
成物が液状の場合、各成分が均一に溶解ないし乳濁する
必要があるため、酸化染料および過酸化物の含有量はあ
る程度制限される。組成物が半固形状（例えばゲル状）
の場合には、基剤を適宜選択することにより各成分を容
易に均一に混合することができるので、より多くの量の
酸化染料および過酸化物を用いることができる。In the continuous hair dye composition, when the composition is in a liquid state, it is necessary that each component be uniformly dissolved or emulsified, so that the content of the oxidative dye and the peroxide is limited to some extent. The composition is semi-solid (eg gel)
In this case, each component can be easily and uniformly mixed by appropriately selecting the base material, so that a larger amount of the oxidation dye and the peroxide can be used.
【００１７】同様の理由により、一時的毛髪染料組成物
においても、組成物がスプレー原料を含めて液状ないし
乳濁する場合、吸着染料の量はやや少なめにする必要が
あり、組成物が半固形状の場合には、より多くの量の吸
着染料を用いることができる。For the same reason, also in a temporary hair dye composition, when the composition is liquid or emulsified including the spray raw material, the amount of the adsorbing dye needs to be slightly small and the composition is semi-solid. In the case of shapes, higher amounts of adsorptive dye can be used.
【００１８】本発明において、持続的毛髪染料組成物と
は、染料が共有結合等により強固に毛髪に結合し、洗髪
などにより色が落ちない組成物を示し、例えば、酸化染
毛料、鉱物性染毛料、溶剤型染毛料などが挙げられる。In the present invention, the continuous hair dye composition refers to a composition in which the dye is firmly bound to the hair by covalent bonding or the like and the color is not lost by washing the hair, and examples thereof include oxidative hair dye and mineral dye. Examples include hair dyes and solvent-type hair dyes.
【００１９】本発明において、一時的毛髪染料組成物と
は、染料が非共有結合的に毛髪に吸着し、洗髪などによ
り色落ちが起こり得る組成物を示し、例えば、カラーリ
ンス、カラーシャンプー、カラートリートメント、ヘア
カラースチック、カラークレヨン、カラースプレーなど
が挙げられる。In the present invention, the temporary hair dye composition refers to a composition in which the dye is non-covalently adsorbed to the hair to cause discoloration by washing the hair, and examples thereof include color rinse, color shampoo, and color. Treatments, hair color sticks, color crayons, color sprays, etc.
【００２０】本発明において、吸着染料とは、水素結
合、静電的相互作用、疎水性相互作用などのメカニズム
により非共有結合的に吸着する染料を示し、毛髪の染色
用途に従来公知の染料が広く使用できる。例えば、赤色
２２７号、橙２０５号、紫色４０１号、黒色４０１号な
どのタール系染料、カーボンブラックなどが挙げられ
る。In the present invention, the adsorptive dye means a dye which is non-covalently adsorbed by a mechanism such as hydrogen bond, electrostatic interaction, hydrophobic interaction, etc. Can be widely used. For example, tar-based dyes such as red No. 227, orange No. 205, purple No. 401, and black No. 401, carbon black and the like can be mentioned.
【００２１】本発明において、Ｒで表されるアルキル基
としては、メチル基、エチル基、ｎ−プロピル基、イソ
プロピル基、ｎ−ブチル基、イソブチル基、ｓｅｃ−ブ
チル基、ｔ−ブチル基、ペンチル基、ヘキシル基、ヘプ
チル基、オクチル基、ノニル基、デシル基、ウンデシル
基、ドデシル基、トリデシル基、テトラデシル基、ペン
タデシル基、ヘキサデシル基、ヘプタデシル基、オクタ
デシル基などの直鎖または分枝を有する炭素数１〜１８
のアルキル基が挙げられ、好ましくは炭素数１〜１２の
直鎖または分枝を有するアルキル基が挙げられる。In the present invention, examples of the alkyl group represented by R include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, t-butyl group, pentyl. Group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group and other straight or branched carbon Number 1-18
And an alkyl group having a straight or branched chain having 1 to 12 carbon atoms is preferable.
【００２２】本発明において、ＸまたはＹで表される基
としては、−ＣＨ2 ＣＨ2 Ｏ−、−ＣＨ（ＣＨ3 ）ＣＨ
2 Ｏ−および−ＣＨ2 ＣＨ（ＣＨ3 ）Ｏ−が挙げられ
る。In the present invention, the group represented by X or Y includes --CH 2 CH 2 O-- and --CH (CH 3 ) CH.
2 O- and -CH 2 CH (CH 3) O- and the like.
【００２３】本発明において、Ｇで表される炭素数５ま
たは６の糖残基としては、アノマー炭素に水酸基を有す
るものとして例示すると、リボース、アラビノース、キ
シロース、リキソースなどの５炭糖及びグルコース、ガ
ラクトース、マンノース、フルクトース、アルトロー
ス、イドース、タロースなどの６炭糖が挙げられ、好ま
しい糖残基としては、グルコースが挙げられる。（Ｇ）
x（ｘ≧２）で表される基の例としては、マルトース、
ラクトース、マルトトリオース、などが挙げられる。In the present invention, the sugar residue having 5 or 6 carbon atoms represented by G is exemplified by those having a hydroxyl group on the anomeric carbon, and 5-carbon sugars such as ribose, arabinose, xylose and lyxose and glucose, Examples include hexoses such as galactose, mannose, fructose, altrose, idose, and talose, and preferable sugar residues include glucose. (G)
Examples of the group represented by x (x ≧ 2) include maltose and
Lactose, maltotriose, etc. are mentioned.
【００２４】本発明において、ｎおよびｎ´は平均値が
各々０≦ｎ≦１０および０≦ｎ´≦１０を示し、ｎ''お
よびｘは平均値が各々０≦ｎ''≦３ｘ＋１および１≦ｘ
≦１０を示し、ｘは好ましくは１≦ｘ≦５である。In the present invention, n and n'represent average values of 0≤n≤10 and 0≤n'≤10, and n "and x have average values of 0≤n" ≤3x + 1 and 1 respectively. ≤ x
≦ 10 is shown, and x is preferably 1 ≦ x ≦ 5.
【００２５】本発明において、好ましいアルキルグリコ
シド類としてはメチルグリコシド、エチルグリコシド、
ブチルグリコシド、オクチルグリコシドおよびドデシル
グリコシド等が挙げられる。In the present invention, preferred alkyl glycosides are methyl glycoside, ethyl glycoside,
Examples thereof include butyl glycoside, octyl glycoside and dodecyl glycoside.
【００２６】本発明のアルキルグリコシド類は単独で、
または２種以上を混合して用いることができる。２種以
上の成分を含む場合、その比率は任意である。The alkyl glycosides of the present invention alone
Alternatively, two or more kinds can be mixed and used. When two or more kinds of components are contained, the ratio is arbitrary.
【００２７】本発明のアルキルグリコシド類は、いずれ
も公知の化合物であり、公知の製造方法、例えば特開平
１−２８３２９４号に記載の方法により製造することが
できる。The alkyl glycosides of the present invention are all known compounds and can be produced by a known production method, for example, the method described in JP-A-1-283294.
【００２８】本発明の染色補助剤は、ヘアケア製品、例
えばカラーリンス、ヘアダイ、カラーシャンプー、カラ
ートリートメント、ヘアカラースチック、カラークレヨ
ン、カラースプレーなどの中に混合して用いることもで
き、公知のヘアケア製品とは別々に製造し、使用時に該
製品と混合して用いることもできる。The dyeing assistant of the present invention can be used by mixing it in hair care products such as color rinses, hair dyes, color shampoos, color treatments, hair color sticks, color crayons and color sprays. It is also possible to manufacture it separately from the product and mix it with the product before use.
【００２９】本発明の染色補助剤を持続的毛髪染色剤に
含めて用いる場合の各成分の混合割合は、特に限定され
るものではないが、例えば酸化染料０．１〜５０重量％
に対し、過酸化物を０．１〜５０重量％程度、一般式
（１）の染色補助剤を０．０１〜２０重量％程度、好ま
しくは０．１〜５重量％程度用いることができる。When the dyeing auxiliary agent of the present invention is used by being included in a continuous hair dyeing agent, the mixing ratio of each component is not particularly limited, but is, for example, 0.1 to 50% by weight of an oxidation dye.
On the other hand, about 0.1 to 50% by weight of peroxide and about 0.01 to 20% by weight, preferably about 0.1 to 5% by weight of the dyeing assistant of the general formula (1) can be used.
【００３０】上記毛髪染料組成物には、これらの他に
も、界面活性剤、保存剤、安定化剤、アルカリ剤、油
分、香料などの従来から用いられている添加剤を適当量
添加することができる。これら毛髪染料組成物が液状の
場合の溶剤としては、水；エタノール、プロパノール、
セチルアルコール等のアルコール類；エチレングリコー
ルなどのグリコール類、その他、ポリビニルアルコー
ル、カルボキシメチルセルロースなどの水と混和性の有
機物質などが挙げられる。また、毛髪染料組成物が半固
形状の場合の添加剤としては、公知の添加剤が広く用い
られる。To the above hair dye composition, in addition to these, appropriate amounts of conventionally used additives such as surfactants, preservatives, stabilizers, alkali agents, oils, and fragrances should be added. You can When these hair dye compositions are liquid, the solvent is water; ethanol, propanol,
Examples thereof include alcohols such as cetyl alcohol; glycols such as ethylene glycol; and organic substances miscible with water such as polyvinyl alcohol and carboxymethyl cellulose. Known additives are widely used as additives when the hair dye composition is in a semi-solid state.
【００３１】本発明の染色補助剤は、頭髪の染色のみな
らず、脱色人毛などの染色にも好適である。The dyeing auxiliary agent of the present invention is suitable not only for dyeing hair, but also for dyeing bleached human hair.
【００３２】[0032]
【発明の効果】本発明のアルキルグリコシド類の少なく
とも１種を含有してなる染色補助剤をヘアケア製品に添
加すれば、該製品の染料の均染性、濃染性及び染色堅牢
性を向上させることができる。従って、持続性の染毛料
に用いる場合には、より緩和な染色条件を用いることが
でき、酸化染料及び過酸化物の染色剤の使用も少なくて
済むことになり、人毛組織を傷めることはなく、頭髪の
染色に用いた場合にも皮膚のかぶれなどを抑えることが
できる。また、生体に対して安全性が高い。しかも、該
アルキルグリコシド類はアルカリ性条件下で安定である
ので、使いやすい。[Effects of the Invention] When a dyeing auxiliary agent containing at least one of the alkyl glycosides of the present invention is added to a hair care product, the dye leveling property, the deep dyeing property and the dyeing fastness of the dye product are improved. be able to. Therefore, when used for a long-lasting hair dye, milder dyeing conditions can be used, and the use of oxidizing dyes and peroxide dyes can be reduced, resulting in no damage to human hair tissue. It is also possible to suppress skin irritation and the like when used for dyeing hair. In addition, it is highly safe for the living body. Moreover, since the alkyl glycosides are stable under alkaline conditions, they are easy to use.
【００３３】さらに、本発明の染色補助剤を一時的毛髪
染料組成物に適用すると均染性、濃染性、染料堅牢性が
向上し、これにより同等な染色効果を得るための吸着染
料の使用量を少なくすることができ、吸着染料による皮
膚に対する刺激を低く抑えることができる。Further, when the dyeing auxiliary agent of the present invention is applied to a temporary hair dye composition, the level dyeing property, the deep dyeing property and the dye fastness are improved, whereby the use of an adsorbing dye for obtaining an equivalent dyeing effect. The amount can be reduced and the irritation to the skin by the adsorbent dye can be suppressed to a low level.
【００３４】[0034]
【実施例】以下、本発明を実施例及び比較例を用いて、
より詳細に説明する。EXAMPLES Hereinafter, the present invention will be described with reference to Examples and Comparative Examples.
This will be described in more detail.
【００３５】[0035]
【実施例１及び比較例１】あらかじめブリーチ処理を行
った毛髪束を、水洗・乾燥して被験試料とした。 染毛方法
カラーリンス用の処方液Ａ〜Ｋを各々表１に記載の成分
及び割合で混合し、水を加えて全量を１００にして調製
した。この処方液を各試料に塗布し、５分間放置後水洗
・乾燥させた。一連の操作を１プロセスとして、このプ
ロセスを５回繰り返した。得られた染色試料の均染性及
び濃染性を、１０人のパネラーにより相対評価した。結
果を以下の表１に示す。なお、本願のアルキルグリコシ
ド類は、データとしては示さないが、染色堅牢性を高め
る効果があることも確認されている。なお、表１および
表２中：ＡＧ４は、ブチルグルコシドを示す。[Example 1 and Comparative Example 1] A bleaching process was performed in advance.
The obtained hair bundle was washed with water and dried to obtain a test sample. Hair dyeing method
Prescription liquids A to K for color rinse are the components listed in Table 1, respectively.
And mix in proportions and add water to make the total amount 100
did. Apply this prescription liquid to each sample, leave it for 5 minutes, and then wash with water.
-Dried. This process is a series of operations.
The process was repeated 5 times. Uniformity of the obtained dyed sample
The deep stainability was relatively evaluated by 10 panelists. Conclusion
The results are shown in Table 1 below. In addition, the alkylglycosyl group of the present application
Although not shown as data,
It has also been confirmed that there is an effect. In addition, Table 1 and
In Table 2: AG4 represents butyl glucoside.
【００３６】ＡＧ６は、ヘキシルグルコシドを示す。AG6 represents hexyl glucoside.
【００３７】ＡＧ８は、オクチルグルコシドを示す。AG8 represents octyl glucoside.
【００３８】ＡＧ１０は、デシルグルコシドを示す。AG10 represents decyl glucoside.
【００３９】ＡＧ１２は、ドデシルグルコシドを示す。AG12 represents dodecyl glucoside.
【００４０】ＯＭ８は、オクチルマルトシドを示す。OM8 represents octyl maltoside.
【００４１】染料は、赤色２２７号、橙２０５号、黒色
４０１号及び紫色４０１号の混合物を用いた。As the dye, a mixture of Red No. 227, Orange No. 205, Black No. 401 and Purple No. 401 was used.
【００４２】◎は、非常に良好であることを示す。⊚ indicates that it is very good.
【００４３】○は、良好であることを示す。◯ indicates that it is good.
【００４４】△は、普通であることを示す。Δ indicates that it is normal.
【００４５】×は、劣っていることを示す。X indicates inferior.
【００４６】また、表中の数値は重量％を示す。The numerical values in the table are% by weight.
【００４７】[0047]
【表１】 [Table 1]
【００４８】[0048]
【実施例２及び比較例２】実施例１で用いた毛髪束に対
し、下記表２に記載の持続性染毛用の処方液Ｌ〜Ｖと６
％過酸化水素水の等量混合物を染色用の処理液として用
いた他は、実施例１と同様にして染色を行った。結果を
表２に示す。[Example 2 and Comparative Example 2] With respect to the hair bundle used in Example 1, formulation liquids L to V and 6 for continuous dyeing shown in Table 2 below.
Dyeing was performed in the same manner as in Example 1 except that an equal amount mixture of% hydrogen peroxide solution was used as the treatment liquid for dyeing. The results are shown in Table 2.
【００４９】[0049]
【表２】 [Table 2]
【００５０】[0050]
【実施例３】本発明の一般式（１）のアルキルグリコシ
ド類において、Ｘ及びＹで表される基の有無は、染料の
均染、濃染及び染色堅牢性の向上に大きな影響はなく、
アルキルグリコシド構造が必須のものである。このこと
は、データとしては示さないが、Ｘ及びＹが各々単結合
の代わりに−ＣＨ2 ＣＨ2 Ｏ−、−ＣＨ（ＣＨ3 ）ＣＨ
2 Ｏ−または−ＣＨ2 ＣＨ（ＣＨ3 ）Ｏ−を示す場合に
も、同様な染色効果が得られたこと、およびｘが３以上
のオリゴ糖の場合にも、同様な染色効果が得られたこと
からも明らかである。Example 3 In the alkyl glycosides of the general formula (1) of the present invention, the presence or absence of the groups represented by X and Y does not significantly affect the level dyeing, the deep dyeing and the improvement of dyeing fastness.
The alkyl glycoside structure is essential. Although this is not shown as data, X and Y each represent —CH 2 CH 2 O—, —CH (CH 3 ) CH instead of a single bond.
Similar staining effects were obtained when 2 O- or -CH 2 CH (CH 3 ) O- was shown, and similar staining effects were obtained when x was 3 or more oligosaccharides. It is clear from this.
【００５１】[0051]
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平１−110613（ＪＰ，Ａ) 特表 平８−500351（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/00 ─────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-1-110613 (JP, A) Special table: 8-500351 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) A61K 7/00
Claims (2)
％、過酸化物０．０５〜２０重量％及び一般式（１）： 【化１】 〔式中、Ｒは炭素数１〜１８（但し、１２〜１６を除
く）の直鎖または分枝状のアルキル基を示し、Ｘおよび
Ｙは同一または異なって−ＣＨ2ＣＨ2Ｏ−、−ＣＨ（Ｃ
Ｈ3）ＣＨ2Ｏ−または−ＣＨ2ＣＨ（ＣＨ3）Ｏ−を示
し、Ｇは同一または異なって炭素数５または６の糖残基
を示し、ｎおよびｎ’は、平均値が０≦ｎ≦１０および
０≦ｎ’≦１０を示し、ｎ’’は平均値が０≦ｎ’’≦
３ｘ＋１を示し、ｘは平均値が１≦ｘ≦１０を示す〕で
表されるアルキルグリコシド０．０１〜１重量％を含む
持続的毛髪染料組成物（但し、ヨウ素イオンを含む組成
物を除く）。1. A para-phenylenediamine 0.1 to 20 wt%, the peroxide 0.05 to 20% by weight and general formula (1): ## STR1 ## [In the formula, R represents a linear or branched alkyl group having 1 to 18 carbon atoms (excluding 12 to 16), and X and Y are the same or different, and are —CH 2 CH 2 O—, — CH (C
H 3 ) CH 2 O- or —CH 2 CH (CH 3 ) O—, G is the same or different and represents a sugar residue having 5 or 6 carbon atoms, and n and n ′ have an average value of 0 ≦. n ≦ 10 and 0 ≦ n ′ ≦ 10, and n ″ has an average value of 0 ≦ n ″ ≦
3x + 1, where x is an average value of 1 ≦ x ≦ 10], and a continuous hair dye composition containing 0.01 to 1% by weight of an alkyl glycoside (provided that the composition contains iodine ions).
Excluding things) .
（１）： 【化２】 〔式中、Ｒは炭素数１〜１８の直鎖または分枝状のアル
キル基を示し、Ｘ、Ｙ、Ｇ、ｎ、ｎ’、ｎ’’およびｘ
は前記に同じ〕で表されるアルキルグリコシド０．０１
〜２０重量％を含む一時的毛髪染料組成物。2. An adsorption dye of 0.1 to 20% by weight and a general formula (1): [In the formula, R represents a linear or branched alkyl group having 1 to 18 carbon atoms, and X, Y, G, n, n ′, n ″ and x
Is the same as above] 0.01
A temporary hair dye composition comprising -20% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34620092A JP3521235B2 (en) | 1992-12-25 | 1992-12-25 | Dyeing aid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34620092A JP3521235B2 (en) | 1992-12-25 | 1992-12-25 | Dyeing aid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06206810A JPH06206810A (en) | 1994-07-26 |
| JP3521235B2 true JP3521235B2 (en) | 2004-04-19 |
Family
ID=18381792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP34620092A Expired - Lifetime JP3521235B2 (en) | 1992-12-25 | 1992-12-25 | Dyeing aid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3521235B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2879922B1 (en) * | 2004-12-23 | 2007-03-02 | Oreal | NOVEL METHOD FOR WASHING COLORED KERATINOUS FIBERS WITH A COMPOSITION COMPRISING A PARTICULAR NON-IONIC SURFACTANT AND USE FOR PROTECTING COLOR |
| JP5309469B2 (en) * | 2007-04-27 | 2013-10-09 | 花王株式会社 | Oxidative hair dye or decolorant composition |
| JP5792926B2 (en) | 2009-06-12 | 2015-10-14 | ホーユー株式会社 | Hair treatment method |
-
1992
- 1992-12-25 JP JP34620092A patent/JP3521235B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06206810A (en) | 1994-07-26 |
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