JP3487332B2 - Aluminum structure having excellent surface treatment properties and method for producing the same - Google Patents

Aluminum structure having excellent surface treatment properties and method for producing the same

Info

Publication number
JP3487332B2
JP3487332B2 JP9119998A JP9119998A JP3487332B2 JP 3487332 B2 JP3487332 B2 JP 3487332B2 JP 9119998 A JP9119998 A JP 9119998A JP 9119998 A JP9119998 A JP 9119998A JP 3487332 B2 JP3487332 B2 JP 3487332B2
Authority
JP
Japan
Prior art keywords
welding
aluminum
joining
friction stir
joint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP9119998A
Other languages
Japanese (ja)
Other versions
JPH11285862A (en
Inventor
久司 堀
慎也 牧田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Light Metal Co Ltd
Original Assignee
Nippon Light Metal Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Light Metal Co Ltd filed Critical Nippon Light Metal Co Ltd
Priority to JP9119998A priority Critical patent/JP3487332B2/en
Publication of JPH11285862A publication Critical patent/JPH11285862A/en
Application granted granted Critical
Publication of JP3487332B2 publication Critical patent/JP3487332B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/12Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding
    • B23K20/122Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding using a non-consumable tool, e.g. friction stir welding

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、接合強度が要求さ
れる建築・土木用構造体、車両用構造体、船舶用構造体
等は勿論接合強度がそれほど要求されない一般構造体と
しても用いられ、アルミニウム及び/又はアルミニウム
合金(以下アルミニウム系と称する)部材を接合してな
る表面処理性に優れるアルミニウム系構造体およびその
製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used not only for structures for construction and civil engineering, structures for vehicles, structures for ships, etc., which are required to have high joint strength, but also for general structures which are not required to have high joint strength. TECHNICAL FIELD The present invention relates to an aluminum-based structure excellent in surface treatability obtained by joining aluminum and / or aluminum alloy (hereinafter referred to as aluminum-based) members and a method for manufacturing the same.

【0002】[0002]

【従来の技術】従来、アルミニウム系の建築・土木用構
造体、車両用構造体、船舶用構造体等は、以下のように
形成されていた。 (1)予め塗装、アルマイト処理、またはヘアライン加
工等の表面処理の済んだアルミニウム系部材同士をボル
ト接合等の機械的結合方法を用いて接合する。 (2)TIG溶接およびMIG溶接でアルミニウム系部
材を溶接したときは、溶接ビードを切削・研削等により
削除したのちに、塗装処理する。 (3)アルマイト処理される部材のMIG溶接では、溶
接ワイヤを「JIS Z3232〕に規定されているA
l純度が高くSi含有量の低いA1000系アルミニウ
ムワイヤや、Mn、Mg、Cr、Ti等を添加し、かつ
Si含有量の少ないA5000系アルミニウム合金ワイ
ヤに限定して溶接している。これは、Siを4.5〜
6.0%あるいは11.0〜13.0%と各々多量に含
有するA4043−WYやA4047−WY等のA40
00系アルミニウム合金ワイヤを使用すると、アルマイ
ト処理した溶接ビード部の色調が母材と大きく異なるた
めである。
2. Description of the Related Art Conventionally, aluminum-based structures for construction and civil engineering, structures for vehicles, structures for ships, etc. have been formed as follows. (1) The aluminum-based members that have been subjected to surface treatment such as painting, alumite treatment, or hairline processing in advance are joined together by a mechanical joining method such as bolt joining. (2) When aluminum-based members are welded by TIG welding and MIG welding, the welding bead is removed by cutting, grinding, etc., and then the coating process is performed. (3) In MIG welding of alumite treated members, the welding wire is A specified in "JIS Z3232".
l Welding is limited to A1000 series aluminum wire with high purity and low Si content, and A5000 series aluminum alloy wire with added Mn, Mg, Cr, Ti and the like and low Si content. This is Si 4.5 ~
A40 such as A4043-WY or A4047-WY containing a large amount of 6.0% or 11.0 to 13.0%, respectively.
This is because the color tone of the weld bead portion subjected to the alumite treatment is greatly different from that of the base material when the 00 series aluminum alloy wire is used.

【0003】[0003]

【発明が解決しようとする課題】上記のような方法には
以下のような問題点がある。 (1)予め塗装、アルマイト処理、またはヘアライン加
工等の表面処理の済んだアルミニウム系部材同士をボル
ト接合等の機械的結合方法を用いて接合する方法では、
人手と時間が掛かる。 (2)MIG溶接では上記のようなフィラーワイヤが用
いられるので、溶接部と母材部の成分・組織が異なるた
め、アルマイト処理した場合には、溶接部と母材部の色
調が異なる。また、溶接変形量が大きく、溶接後に変形
の矯正を必要とすることがあり、そのため工程が増え、
構造体の製造コストが高くなる。 (3)フィラーワイヤを用いないTIG溶接では、「J
IS H 4100」に規定される1000系、300
0系、4000系、5000系のアルミニウム系押出形
材の溶接は問題ないが、2000系、6000系、70
00系のアルミニウム系押出形材では溶接割れが発生し
易い。また、溶接割れが発生しない場合でも溶接部は凝
固組織となるため、アルマイト処理後は、溶接部と母材
部の色調が異なる。また、前記MIG溶接と同様に、溶
接変形量が大きく、溶接後に変形の矯正を必要とするこ
とがあり、そのため工程が増え、構造体の製造コストが
高くなる。
The above method has the following problems. (1) In a method of joining aluminum-based members that have been subjected to surface treatment such as painting, alumite treatment, or hairline processing in advance by using a mechanical joining method such as bolt joining,
It takes manpower and time. (2) Since the filler wire as described above is used in MIG welding, since the composition and structure of the welded portion and the base material portion are different, the color tone of the welded portion and the base material portion is different when anodized. In addition, the amount of welding deformation is large and it may be necessary to correct the deformation after welding, which increases the number of processes,
The manufacturing cost of the structure increases. (3) In TIG welding without using a filler wire, “J
1000 series, 300 specified in ISH 4100 "
Welding of 0 series, 4000 series and 5000 series extruded aluminum materials is not a problem, but 2000 series, 6000 series, 70 series
Weld cracks are likely to occur in 00-based extruded aluminum products. Further, even if welding cracks do not occur, the welded part has a solidified structure, so that the color tone of the welded part and the base metal part are different after the alumite treatment. Further, as in the case of the MIG welding, the amount of welding deformation is large, and it may be necessary to correct the deformation after welding, which increases the number of steps and increases the manufacturing cost of the structure.

【0004】また、前記の方法以外に、適切な接着剤を
用いた接着による構造体の形成方法もあるが、この方法
による場合は、塗装性やアルマイト処理性には問題がな
い。しかし、接合強度に問題があり、強度が要求される
アルミニウム系構造体、例えば、前記の建築・土木用構
造体、車両用構造体、船舶用構造体等には適用できな
い。
In addition to the above method, there is also a method of forming a structure by adhesion using an appropriate adhesive, but this method has no problem in paintability and alumite processability. However, it cannot be applied to aluminum-based structures, which have a problem in joint strength and require strength, such as the above-mentioned construction / civil engineering structures, vehicle structures, and ship structures.

【0005】本発明は、前記従来技術の問題点を解消
し、接合強度が要求される建築・土木用構造体、車両用
構造体、船舶用構造体等は勿論接合強度がそれほど要求
されない一般構造体体としても用いられ、アルミニウム
系部材を接合してなる、アルマイト処理、塗装又はヘア
ライン加工等の表面処理性に優れ、かつ、接合変形量が
少なく景観性に優れるアルミニウム系構造体およびその
製造方法の提供を課題とする。
The present invention solves the above-mentioned problems of the prior art and, of course, not only construction / civil engineering structures, vehicle structures, marine structures, etc., which require joint strength, but also general structures which do not require much joint strength. An aluminum-based structure which is also used as a body and has excellent surface treatment properties such as alumite treatment, painting or hairline processing, which is formed by joining aluminum-based members, and has a small amount of joint deformation and excellent landscape, and a method for producing the same. Is an issue.

【0006】[0006]

【課題を解決するための手段】本発明は、上記課題を解
決するために、外表面にアルマイト処理、塗装又はヘア
ライン加工される複数のアルミニウム及び/又はアルミ
ニウム合金部材を接合してなり、表面処理性に優れるア
ルミニウム系構造体を、前記外表面の裏側から摩擦攪拌
接合により接合した表面処理性に優れる接合部を有する
ことを特徴とするように構成したものである。
In order to solve the above-mentioned problems, the present invention comprises a plurality of aluminum and / or aluminum alloy members to be anodized, painted or hairline-bonded on the outer surface, and surface-treated. The aluminum-based structure having excellent properties is joined by friction stir welding from the back side of the outer surface and has a joining portion having excellent surface treatment properties.

【0007】本発明においては、上記の表面処理性に優
れるアルミニウム系構造体を、前記外表面に接触する摩
擦攪拌接合用裏当の表面粗さがRmax 6.3S以下、R
max 0.8S以上であるように構成することが望まし
い。
In the present invention, the surface roughness of the friction stir welding backing which contacts the outer surface of the aluminum-based structure excellent in surface treatment is Rmax 6.3 S or less, R
It is desirable to configure so that the maximum is 0.8 S or more.

【0008】本発明においてはまた、上記の表面処理性
に優れるアルミニウム系構造体が、前記外表面に接触す
る摩擦攪拌接合用裏当の表面粗さがRmax 6.3Sを超
え、Rmax 25S以下である場合に、該裏当てに接触し
た前記外表面の接合部表面をヘアライン加工したもので
あることが望ましい。
In the present invention, the aluminum-based structure having excellent surface treatment property has a surface roughness of the friction stir welding backing contacting the outer surface of more than Rmax 6.3S and not more than Rmax 25S. In some cases, it is desirable that the joint surface of the outer surface in contact with the backing be hairline-processed.

【0009】本発明は、上記課題を解決するために、外
表面にアルマイト処理、塗装又はヘアライン加工される
複数のアルミニウム及び/又はアルミニウム合金部材を
接合してなり、表面処理性に優れるアルミニウム系構造
体の製造方法を、前記外表面の裏側から摩擦攪拌接合に
より接合することを特徴とするように構成したものであ
る。
In order to solve the above-mentioned problems, the present invention comprises an aluminum-based structure having excellent surface treatability, which is formed by joining a plurality of aluminum and / or aluminum alloy members to be anodized, painted or hairline-processed on the outer surface. The method for producing a body is configured so as to be joined by friction stir welding from the back side of the outer surface.

【0010】本発明においては、上記の表面処理性に優
れるアルミニウム系構造体の製造方法を、前記外表面に
接触する摩擦攪拌接合用裏当の表面粗さがRmax 6.3
S以下、Rmax 0.8S以上であるように構成すること
が望ましい。
In the present invention, the surface roughness of the friction stir welding backing contacting the outer surface is Rmax 6.3 according to the above method for producing an aluminum-based structure having excellent surface treatment property.
It is desirable to configure so that it is S or less and Rmax is 0.8S or more.

【0011】本発明においてはまた、上記の表面処理性
に優れるアルミニウム系構造体の製造方法を、前記外表
面に接触する摩擦攪拌接合用裏当の表面粗さがRmax
6.3Sを超え、Rmax 25S以下である場合に、該裏
当てに接触した前記外表面の接合部表面をヘアライン加
工するように構成することが望ましい。
In the present invention, the surface roughness of the friction stir welding backing contacting the outer surface is Rmax according to the above method for producing an aluminum-based structure having excellent surface treatment property.
It is desirable that the surface of the joined portion of the outer surface in contact with the backing be subjected to hairline processing when it exceeds 6.3 S and Rmax is 25 S or less.

【0012】[0012]

【発明の実施の形態】本発明の実施の形態を、添付の図
面と具体的な実施例に基づいて以下に説明する。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to the accompanying drawings and specific embodiments.

【0013】1.実施例1 本発明の請求項1および請求項2に係る実施例とその比
較例として、下記の実験を行った。すなわち、試験片と
して長さ300mm、幅100mm、厚さ3mmの、「JIS
H 4000」に規定されるアルミニウム合金板材5083−
H34と、「JIS H 4100」に規定されるアルミニウム押
出形材6N01−T5をそれぞれ用いて、下記の3種類
の接合方法を用いた突合わせ接合と、突合わせ接合部の
加工を行い、その後アルマイト処理を行った。
1. Example 1 The following experiment was conducted as an example according to claims 1 and 2 of the present invention and a comparative example thereof. That is, a test piece of 300 mm in length, 100 mm in width, and 3 mm in thickness, "JIS
Aluminum alloy plate material 5083 specified in "H 4000"
H34 and aluminum extruded profile 6N01-T5 specified in “JIS H 4100” are used to perform butt joining using the following three joining methods and butt joint processing, and then alumite Processed.

【0014】(1)表面処理する外表面に表面粗さがR
max 6.3Sの裏当材を当て、前記外表面の裏側から摩
擦攪拌接合(以下、FSWと略称することがある)を行
い、接合後の外表面の接合部の加工は行わない。 (2)「JIS Z 3232」に規定されるアルミニウム合金フ
ィラーワイヤA5356−WYを用いてMIG溶接を行
い、溶接ビードを切削加工によって削除し、表面粗さが
Rmax 6.3Sになるように仕上げた。 (3)フィラーワイヤや溶加棒を用いないでTIG溶接
を行い、溶接ビードを切削加工によって削除し、表面粗
さがRmax 6.3Sになるように仕上げた。
(1) The surface roughness of the outer surface to be treated is R
A backing material of max 6.3 S is applied, friction stir welding (hereinafter sometimes abbreviated as FSW) is performed from the back side of the outer surface, and the joining portion of the outer surface after joining is not processed. (2) MIG welding was performed using aluminum alloy filler wire A5356-WY specified in "JIS Z 3232", the welding bead was removed by cutting, and the surface roughness was finished to be Rmax 6.3S. . (3) TIG welding was performed without using a filler wire or a filler rod, the welding bead was removed by cutting, and the surface roughness was finished to be Rmax 6.3S.

【0015】なお、上記(1)項の摩擦攪拌接合は以下
のように行われる。すなわち、図1の断面図に示すよう
に、接合後表面処理される各々の外表面1osと2osが下
面となるように、一対の被接合材1と2の端面同士を接
触させて突合わせ部3を形成し、該突合わせ部3の周辺
の前記外表面1osと2osに表面4usが接するように裏当
4を配置する。そして、前記一対の被接合材1、2の裏
面1rs、2rs側から、摩擦攪拌接合用プローブ本体5の
凹面または平面の円形底面5bsの中心から前記プローブ
本体5の回転軸と同軸に下方へ突出した攪拌ピン6を回
転させつつ前記突合わせ部の一対の被接合材1、2に押
し込み、前記プローブ本体5を矢印Fpで示す方向へ所
定の押圧力Fp(kgf)で押圧して、プローブ本体5の凹面
または平面の円形底面5bsを前記被接合材1、2の裏面
1rs、2rsに押し付けながら、前記プローブ本体を矢印
(r)の方向に回転させつつ接合ライン(突合わせ部3
の上端線)に沿って、図1の紙面に垂直な方向に移動さ
せて、攪拌ピン6の周囲やプローブ本体5の凹面または
平面の円形底面5bsの下方に発生する摩擦熱で、前記突
合わせ部3を固相接合する。
The friction stir welding in the above item (1) is performed as follows. That is, as shown in the cross-sectional view of FIG. 1, the end faces of the pair of materials 1 and 2 to be joined are brought into contact with each other so that the outer surfaces 1 os and 2 os to be surface-treated after joining are lower surfaces, but the abutting portion 3 is formed, and the backing 4 is arranged so that the surface 4us contacts the outer surfaces 1os and 2os around the abutting portion 3. Then, from the rear surface 1rs, 2rs side of the pair of materials to be welded 1, 2 is projected downward from the center of the concave surface of the friction stir welding probe main body 5 or the flat circular bottom surface 5bs coaxially with the rotation axis of the probe main body 5. The stirring pin 6 is rotated and pushed into the pair of materials 1 and 2 to be joined at the abutting portion, and the probe body 5 is pressed in a direction indicated by an arrow Fp with a predetermined pressing force Fp (kgf), so that the probe body While pressing the concave or flat circular bottom surface 5bs of 5 onto the back surfaces 1rs, 2rs of the materials to be joined 1, 2 while rotating the probe body in the direction of the arrow (r), the joining line (butt 3)
1 in the direction perpendicular to the paper surface of FIG. 1 and the friction heat generated around the stirring pin 6 or below the concave surface of the probe body 5 or the flat circular bottom surface 5bs causes the butting. The part 3 is solid-phase bonded.

【0016】上記のように接合・接合部加工・アルマイ
ト処理した試験片の溶接割れの有無の目視観察、接合
(溶接)変形量の測定とアルマイト処理後の母材と接合
部の色調差の目視観察を行い、その結果を下記表1に示
した。なお、接合(溶接)変形量の測定は以下のように
行った。すなわち、図2の斜視図に示すように、一対の
被接合材1と2とを接合ライン3tlに沿って接合した接
合材7を、その反り方向が上面になるように表面が平坦
な定盤8の上に載置し、前記接合材7の長手方向(接合
法ライン3tlの方向)の両端、および、長手方向を略三
等分する位置の合計4箇所、前記接合材7の幅方向の両
端の合計2箇所、全合計で4×2=8箇所の前記接合材
7の端面の位置7pmで、該接合材7の表面から定盤8の
上面までの高をダイヤルゲージ9により測定し、これ
ら8箇所の測定値の一つの値を基準値として、その他の
測定値の前記基準値に対する変化量(差)で溶接変形量
を求めた。
Visual observation of the presence or absence of welding cracks in the test piece that has been joined, joined portion processed, and anodized as described above, measurement of the amount of joining (welding) deformation, and visual inspection of the color tone difference between the base material and the joined portion after the anodizing treatment. Observations were made and the results are shown in Table 1 below. The amount of deformation of welding (welding) was measured as follows. That is, as shown in the perspective view of FIG. 2, a joining material 7 obtained by joining a pair of materials 1 and 2 to be joined along a joining line 3tl is used as a platen having a flat surface such that its warp direction is the upper surface. 8 on both sides of the joining material 7 in the longitudinal direction (direction of the joining method line 3tl), and a total of four positions that divide the longitudinal direction into three equal parts, in the width direction of the joining material 7. the total two places at both ends, at the position 7pm the end face of the bonding material 7 of 4 × 2 = 8 points in total sum, the height from the surface of the bonding material 7 to the top surface of the base plate 8 is measured by a dial gauge 9 Using one of the measured values at these eight locations as a reference value, the amount of welding deformation was determined by the amount of change (difference) in the other measured values with respect to the reference value.

【0017】[0017]

【表1】 [Table 1]

【0018】上記表1から、以下のことがいえる。 (1)アルマイト処理後の母材と接合部の色調差は、摩
擦攪拌接合された部材では見られなかったが、上記のフ
ィラーワイヤA5356−WYを用いたMIG溶接部材
では、若干の色調差が見られた。溶加棒を用いないTI
G溶接部材では、前記アルミニウム合金5083−H3
4を母材としたものも6N01−T5を母材としたもの
でも、色調差は非常に軽微であった。 (2)溶接割れは、前記アルミニウム合金6N01−T
5を母材としたTIG溶接部材で発生したが、その他で
は発生しなかった。 (3)接合(溶接)変形量は、摩擦攪拌接合部材では1
mm以下と小さかったが、MIG溶接部材およびTIG溶
接部材では3mm以上と大きかった。
The following can be said from Table 1 above. (1) The difference in color tone between the base material and the joint after the alumite treatment was not seen in the member that was friction stir welded, but in the MIG welded member using the above filler wire A5356-WY, a slight difference in color tone was observed. I was seen. TI without filler rod
In the G welding member, the aluminum alloy 5083-H3 is used.
The difference in color tone was very slight both in the case of using 4 as the base material and in the case of using 6N01-T5 as the base material. (2) Weld cracks are caused by the aluminum alloy 6N01-T.
It occurred in the TIG welded member having 5 as a base material, but did not occur in other parts. (3) The amount of welding (welding) deformation is 1 for friction stir welding members.
Although it was as small as mm or less, it was as large as 3 mm or more for the MIG welded member and the TIG welded member.

【0019】以上のことから、アルマイト処理する外表
面に表面粗さがRmax 6.3Sの裏当を当て、前記外表
面の裏側から摩擦攪拌接合した部材は、アルマイト処理
後の母材と接合部の色調差はみられず、溶接割れもな
く、接合(溶接)変形量も小さいことから、表面処理性
に優れ、その他の観点も含めて景観性に優れたアルミニ
ウム系構造体であり、また、アルマイト処理する外表面
の裏側から摩擦攪拌接合する方法は、表面処理性に優
れ、その他の外観も含めて景観性に優れたアルミニウム
系構造体を製造するに適した方法であることが分かる。
From the above, a member having a surface roughness of Rmax 6.3S applied to the outer surface to be anodized and friction stir welding from the back side of the outer surface is a member to be joined to the base material after the alumite treatment. Since there is no difference in color tone, there is no weld cracking, and the amount of joint (welding) deformation is small, it is an aluminum-based structure that has excellent surface treatment properties and excellent scenery including other points of view. It can be seen that the method of friction stir welding from the back side of the outer surface subjected to alumite treatment is a method suitable for producing an aluminum-based structure which is excellent in surface treatment property and is also excellent in landscape including other appearances.

【0020】2.実施例2 本発明の請求項1および請求項2に係る他の実施例とそ
の比較例として、下記の実験を行った。すなわち、前記
実施例1に示したのと同寸法で、同じ2種類のアルミニ
ウム合金材料を用いた試験片を、前記実施例1の(1)
〜(3)項に示したのと同じ3種類の接合方法を用いた
突合わせ接合と、突合わせ接合部の加工を行い、その後
塗装処理を行った。なお、塗装は接合材を脱脂処理後、
市販のカラースプレー塗料を用いてスプレー塗装を行っ
た。
2. Example 2 The following experiment was conducted as another example according to claims 1 and 2 of the present invention and its comparative example. That is, a test piece using the same two kinds of aluminum alloy materials as the one shown in Example 1 was used, and
Butt-joining using the same three types of joining methods as described in (3) to (3), the butt-joining portion was processed, and then the coating process was performed. In addition, after painting, degreasing the joint material,
Spray coating was performed using a commercially available color spray paint.

【0021】上記のように接合・接合部加工・塗装処理
した試験片の溶接割れの有無の目視観察、接合(溶接)
変形量の測定と塗装処理後の母材と接合部の色調差の目
視観察、さらに塗膜の付着性試験を行い、その結果を下
記表2に示した。なお、塗膜の付着性試験は「JIS H 02
01」( 「JIS H 8602」、「JIS K 5400」)に規定するス
クラッチ試験によった。
Visual observation of the presence or absence of weld cracks in the test pieces that have been joined, joined portion processed, and painted as described above, and joined (welded)
The amount of deformation was measured, the difference in color tone between the base material and the joint portion after the coating treatment was visually observed, and the adhesion test of the coating film was performed. The results are shown in Table 2 below. In addition, the adhesion test of the coating film is "JIS H 02
01 ”(“ JIS H 8602 ”,“ JIS K 5400 ”).

【0022】[0022]

【表2】 [Table 2]

【0023】上記表2から、以下のことがいえる。 (1)塗装処理後の母材と接合部の塗膜の色調差は、前
記3種類の接合・接合部加工方法の間には見られなかっ
た。 (2)塗膜の付着性試験結果は、接合方法および接合部
加工方法による差は殆ど見られなかった。 (3)溶接割れは、前記6N01−T5合金をTIG溶
接したもの以外では観察されなかった。 (4)接合(溶接)変形量は,摩擦攪拌接合部材では1
mm以下と小さかったが、MIG溶接部材およびTIG溶
接部材では3mm以上と大きかった。
From Table 2 above, the following can be said. (1) No difference in color tone between the base material after coating and the coating film on the joint was observed between the three types of joining / joint processing methods. (2) In the adhesion test result of the coating film, almost no difference was observed depending on the joining method and the joining portion processing method. (3) Weld cracks were not observed except for the TIG welded 6N01-T5 alloy. (4) The amount of deformation of welding (welding) is 1 for friction stir welding members.
Although it was as small as mm or less, it was as large as 3 mm or more for the MIG welded member and the TIG welded member.

【0024】以上のことから、塗装処理する外表面の裏
側から摩擦攪拌接合した部材は、塗装処理後の母材と接
合部の色調差はみられず、塗膜の付着性もよく、溶接割
れもなく、接合(溶接)変形量も小さいことから、表面
処理性に優れ、その他の外観も含めて景観性に優れたア
ルミニウム系構造体であり、また、塗装処理する外表面
の裏側から摩擦攪拌接合する方法は、表面処理性に優
れ、接合(溶接)変形量も小さく、その他の観点も含め
て景観性に優れたアルミニウム系構造体を製造するに適
した方法であることが分かる。
From the above, it can be seen that, in the case of the member which was friction stir welded from the back side of the outer surface to be coated, there was no difference in color tone between the base metal and the joint after the coating treatment, the adhesion of the coating film was good, and welding cracks were observed. It is an aluminum-based structure that has excellent surface treatment properties because it has a small amount of welding (welding) deformation, and has excellent scenery including other appearances. Also, friction stir from the back side of the outer surface to be coated. It can be seen that the joining method is a method suitable for producing an aluminum-based structure having excellent surface treatment properties, a small amount of joining (welding) deformation, and other aspects, and having excellent scenery.

【0025】3.実施例3 本発明の請求項1および請求項2に係る実施例とその比
較例として、下記の実験を行った。すなわち、試験片と
して長さ300mm、幅100mm、厚さ3mmの前記アル
ミニウム合金板材6N01−T5を用いた。前記実施例
1と実施例2に示されたように、MIG溶接およびTI
G溶接では溶接割れが発生したり、接合(溶接)変形量
が摩擦攪拌接合に比べて大きいこと、さらにアルマイト
処理において色調差がみられたので、突合わせ接合法は
摩擦攪拌接合に限定した。外表面にアルマイト処理され
る前記のアルミニウム合金部材を、前記外表面の裏側か
ら摩擦攪拌接合する際に、該外表面に接触する摩擦攪拌
接合用裏当の表面粗さを3段階に分け、該裏当の表面が
転写された外表面をアルマイト処理して、前記摩擦攪拌
接合用裏当の表面粗さとアルマイト処理後の外観(母材
部と接合部の色調差)との関係を調査した。なお、この
際、アルマイト処理前に前記外表面(裏当接触側)をヘ
アライン加工した場合と、ヘアライン加工しない場合に
ついて分けて調査した。その調査結果を下記表3に示
す。
3. Example 3 The following experiment was conducted as an example according to claims 1 and 2 of the present invention and a comparative example thereof. That is, as the test piece, the aluminum alloy plate material 6N01-T5 having a length of 300 mm, a width of 100 mm and a thickness of 3 mm was used. As shown in Examples 1 and 2 above, MIG welding and TI
Since welding cracks occurred in G welding, the amount of welding (welding) deformation was larger than that in friction stir welding, and color differences were observed in the alumite treatment, the butt welding method was limited to friction stir welding. When the aluminum alloy member to be anodized on the outer surface is friction stir welded from the back side of the outer surface, the surface roughness of the friction stir welding backing contacting the outer surface is divided into three stages, The outer surface to which the surface of the backing was transferred was subjected to an alumite treatment, and the relationship between the surface roughness of the friction stir welding backing and the appearance after the alumite treatment (color tone difference between the base material and the joint) was investigated. At this time, the case where the outer surface (on the backing contact side) was hairline-processed before the alumite treatment and the case where the hairline was not processed were separately investigated. The survey results are shown in Table 3 below.

【0026】[0026]

【表3】 [Table 3]

【0027】上記表3から、以下のことがいえる。 (1)裏当の表面粗さがRmax 6.3S以下であれば、
裏当の当接面のヘアライン加工の有無に関わりなく、母
材部と接合部の色調差がなく、良好な外観が得られた。 (2)裏当の表面粗さがRmax 25Sの場合には、ヘア
ライン加工を施した場合は、母材部と接合部の色調差が
なく、良好な外観が得られた。しかし、ヘアライン加工
なしの場合には、母材部と接合部との表面粗さが異なる
ために両者の色調差が明確に認められ、母材部と接合部
とがハッキリ判別された。
The following can be said from Table 3 above. (1) If the surface roughness of the backing is Rmax 6.3S or less,
With or without hairline processing on the contact surface of the backing, there was no difference in color tone between the base material and the joint, and a good appearance was obtained. (2) When the surface roughness of the backing was Rmax 25S, there was no difference in color tone between the base material portion and the joint portion when hairline processing was performed, and a good appearance was obtained. However, in the case of no hairline processing, the difference in color tone between the base material portion and the joint portion was clearly recognized because the surface roughness of the base material portion and the joint portion were different, and the base material portion and the joint portion were clearly discriminated.

【0028】以上のことから、アルマイト処理する外表
面の裏側から摩擦攪拌接合した部材は、外表面と接触す
る摩擦攪拌接合用裏当の表面粗さが、Rmax 6.3S以
下であれば、裏当の当接面のヘアライン加工の有無に関
わりなく、母材部と接合部の色調差がなく、その他の観
点(例えば、被接合材変形量)も含めて良好な景観性が
得られ、表面処理性に優れたアルミニウム系構造体とし
て適し、アルミニウム系部材を表面処理する外表面の裏
側から摩擦攪拌接合する際の、摩擦攪拌接合用裏当ての
表面粗さがRmax 6.3S以下のものを使用する方法
は、表面処理性のすぐれたアルミニウム系構造体の製造
法として、適切であることが分かる。
From the above, a member friction-stir-welded from the back side of the outer surface to be alumite-treated is provided if the surface roughness of the friction stir-welding backing contacting the outer surface is Rmax 6.3S or less. With or without hairline processing on the contact surface, there is no difference in color tone between the base material and the joint, and good scenery can be obtained including other viewpoints (for example, the amount of deformation of the material to be joined). Suitable for use as an aluminum-based structure having excellent processability, and having a surface roughness of Rmax of 6.3 S or less for the friction stir welding backing when friction stir welding is performed from the back side of the outer surface of the aluminum member for surface treatment. It can be seen that the method used is suitable as a method for producing an aluminum-based structure having excellent surface treatment properties.

【0029】なお、摩擦攪拌接合用裏当の表面粗さは、
Rmax 0.8S以上であれば十分である。これは、前記
裏当の表面粗さがRmax 6.3S〜Rmax 0.8Sの範
囲であれば、アルマイト処理後の母材部と接合部の色調
差がなく、表面粗さをRmax0.8S未満にしようとす
れば、裏当の表面加工コストも上昇し、使用の回数を重
ねるに連れて裏当の表面粗さが急激に上昇し、直ぐに表
面粗さがRmax 0.8S以上となってしまうからであ
る。
The surface roughness of the backing for friction stir welding is
Rmax 0.8S or more is sufficient. If the surface roughness of the backing is in the range of Rmax 6.3S to Rmax 0.8S, there is no difference in color tone between the base material and the joint after the alumite treatment, and the surface roughness is less than Rmax 0.8S. If this is done, the surface processing cost of the backing will increase, and the surface roughness of the backing will rapidly increase as the number of times of use increases, and soon the surface roughness will become Rmax 0.8S or more. Because.

【0030】さらに、アルマイト処理する外表面の裏側
から摩擦攪拌接合した部材は、外表面と接触する摩擦攪
拌接合用裏当の表面粗さが、Rmax 6.3Sを超え、R
max25S以下の場合は、外表面の接合部をヘアライン
加工したものであれば、母材部と接合部の色調差がな
く、その他の観点(例えば、被接合材変形量)も含めて
良好な景観性が得らる表面処理性に優れたアルミニウム
系構造体として適し、アルミニウム系部材を表面処理す
る外表面の裏側から摩擦攪拌接合する際の、摩擦攪拌接
合用裏当ての表面粗さがRmax 6.3Sを超え、Rmax
25S以下の場合に、該裏当の接触部位をヘアライン加
工する方法は、表面処理性のすぐれたアルミニウム系構
造体の製造法として、適切であることが分かる。
Further, in the member which is friction stir welded from the back side of the alumite treated outer surface, the surface roughness of the friction stir welding backing which contacts the outer surface exceeds Rmax 6.3S, and R
If max25S or less, there is no difference in color tone between the base material and the joint as long as the outer surface joint is hairline-processed, and a good view including other viewpoints (for example, the amount of deformation of the jointed material) Suitable as an aluminum-based structure having excellent surface treatment property, and the surface roughness of the backing for friction-stir welding is Rmax 6 when friction-stir welding from the back side of the outer surface of the aluminum-based member to be surface-treated. Over 3S, Rmax
In the case of 25 S or less, it can be seen that the method of hairline-processing the contact portion of the backing is suitable as a method for producing an aluminum-based structure having excellent surface treatment properties.

【0031】以上、本発明の実施の形態について具体的
な実施例に基づき説明したが、本発明は上記の実施の形
態に限られるものではなく、発明の構成の主旨を逸脱し
ない範囲内で、他の実施の形態を含むものである。
Although the embodiments of the present invention have been described above based on specific examples, the present invention is not limited to the above-mentioned embodiments, and within the scope of the gist of the invention, It includes other embodiments.

【0032】次に、上記に説明した本発明の実施の形態
の基本的な作用について、以下に述べる。すなわち、摩
擦攪拌接合されたアルミニウム系部材の外観は、接合中
に摩擦攪拌接合用回転プローブの底面と接した面はリッ
プル状の跡が観察されるが、裏面は非常に平滑である。
また、接合部の内部は非常に微細な組織を備え、母材部
よりも結晶粒径は小さい。また、MIG溶接やTIG溶
接のような溶融溶接で見られるような溶接欠陥も存在し
ない。前記表1や表3に示したように、外表面にアルマ
イト処理を施される複数のアルミニウム及び/又はアル
ミニウム合金部材を、前記外表面の裏側から摩擦攪拌接
合された部材の前記外表面にアルマイト処理した場合、
母材部と接合部に色調差のないものが得られた。この理
由としては、フィラーワイヤを用いないため母材部と接
合部の成分が同じで、粒径の差があるものの金属組織と
しては同じ加工組織(再結晶組織)が得られること、ま
た、強い塑性歪みの下で熱間加工される固相接合プロセ
スであるため接合部の組織が微細であることによると考
えられる。さらに、接合部内に欠陥がないことも理由の
一つである。前記表2に示したように、塗装処理におい
ても、上記アルマイト処理と同じ理由により、接合部に
おいても塗装下地処理性に優れるために、接合部におい
ても塗膜の付着性の優れたアルミニウム系構造体が得ら
れるものと考えられる。
Next, the basic operation of the embodiment of the present invention described above will be described below. That is, in the appearance of the friction stir welded aluminum-based member, ripple-like marks are observed on the surface in contact with the bottom surface of the friction stir welding rotary probe during welding, but the back surface is very smooth.
Further, the inside of the joint has a very fine structure, and the crystal grain size is smaller than that of the base material. Also, there are no welding defects such as those found in fusion welding such as MIG welding and TIG welding. As shown in Tables 1 and 3, a plurality of aluminum and / or aluminum alloy members whose outer surface is anodized are anodized on the outer surface of the member that is friction stir welded from the back side of the outer surface. If processed,
A material having no difference in color tone between the base material portion and the joint portion was obtained. The reason for this is that since the filler wire is not used, the components of the base metal part and the joint part are the same, and the same processed structure (recrystallized structure) can be obtained as the metal structure although there is a difference in grain size. It is considered that the structure of the joint is fine because it is a solid-state joining process in which hot working is performed under plastic strain. Another reason is that there are no defects in the joint. As shown in Table 2, for the same reason as the alumite treatment in the coating process as well, since the coating base treatment property is excellent also in the bonding part, the aluminum-based structure having excellent adhesion of the coating film also in the bonding part. It is thought that the body is obtained.

【0033】さらに、鋳物と展伸材および鋳物同士を接
合する場合、MIG溶接やTIG溶接等の溶融溶接で
は、接合部の品質は材料の鋳物の品質に大きな影響を受
ける。すなわち、水素その他のガスを含む鋳物をMIG
溶接やTIG溶接等の溶融溶接を施した場合、溶融金属
の冷却・凝固時にガスが放出され溶接部の内部に多量の
ポロシティが発生する。それに対して、摩擦攪拌接合は
固相プロセスであるので、接合部にポロシティ等の欠陥
が発生しない。その結果、アルマイト処理性および塗装
性に優れるアルミニウム系構造体が得られる。
Further, in the case of joining a casting, a wrought material and castings together, in fusion welding such as MIG welding or TIG welding, the quality of the joint is greatly affected by the quality of the casting of the material. That is, MIG is used for castings containing hydrogen and other gases.
When fusion welding such as welding and TIG welding is performed, a large amount of porosity is generated inside the weld due to the release of gas when the molten metal is cooled and solidified. On the other hand, since friction stir welding is a solid phase process, defects such as porosity do not occur at the joint. As a result, an aluminum-based structure having excellent alumite processability and paintability can be obtained.

【0034】[0034]

【発明の効果】本発明の表面処理性に優れるアルミニウ
ム系構造体及びその製造方法によれば以下のように優れ
た効果を奏する。 (1)予め表面処理の済んだアルミニウム系部材同士を
ボルト接合等の機械的結合方法を用いて接合する場合に
比べ、人手と時間が掛からない。 (2)MIG溶接やTIG溶接のような溶融溶接の場合
に比べて、溶接割れ、ポロシティ等の欠陥がなく、また
接合(溶接変形)も少なくアルマイト処理した場合に、
母材部と接合部との間に色調差のない、表面処理性に優
れ、他の観点{例えば、接合(溶接)変形量}を含めて
景観性の良いアルミニウム系構造体が容易に形成可能で
ある。 (3)接着剤を用いた接着による構造体の形成方法に比
べて、接合強度が要求されるアルミニウム系構造体、例
えば、建築・土木用構造体、車両用構造体、船舶用構造
体等に適用でき、かつ接合強度がそれほど要求されない
一般構造体としても用いられるアルミニウム系構造体が
容易に得られる。
EFFECTS OF THE INVENTION According to the aluminum-based structure having excellent surface treatment property and the method for producing the same, the following excellent effects are exhibited. (1) Compared with a case where aluminum-based members that have been surface-treated in advance are joined together by a mechanical joining method such as bolt joining, it takes less time and labor. (2) Compared with the case of fusion welding such as MIG welding or TIG welding, there are no defects such as welding cracks and porosity, and there is little joining (welding deformation), and when anodized,
There is no color difference between the base metal part and the joint part, it has excellent surface treatment properties, and it is easy to form an aluminum-based structure with good scenery including other viewpoints {for example, the amount of joint (welding) deformation}. Is. (3) Aluminum-based structures that require higher bonding strength than the method of forming structures by adhesion using an adhesive, for example, structures for construction and civil engineering, structures for vehicles, structures for ships, etc. An aluminum-based structure that can be applied and is also used as a general structure that does not require much bonding strength can be easily obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】 請求項1に係る本発明の表面処理性に優れる
アルミニウム系構造体を製造するための、請求項2に係
る本発明の表面処理性に優れるアルミニウム系構造体の
製造に適用される摩擦攪拌接合方法をしめす概略断面図
である。
[1] for producing the aluminum-based structure which is excellent in surface treatment of the present invention according to claim 1, applied to the production of aluminum-based structure which is excellent in surface treatment of the present invention according to claim 2 It is a schematic sectional drawing which shows the friction stir welding method.

【図2】 突合わせ接合(溶接)後の接合(溶接)材の
変形量の測定方法を示す斜視図である。
FIG. 2 is a perspective view showing a method for measuring the amount of deformation of a joining (welding) material after butt joining (welding).

【符号の説明】[Explanation of symbols]

1、2 被接合材 3 突合わせ部 4 裏当 5 プローブ本体 5bs 凹面または平面の底面 6 攪拌ピン 7 接合材 8 定盤 9 ダイヤルゲージ 1, 2 Materials to be joined 3 Butt 4 backing 5 probe body 5bs concave or flat bottom 6 stirring pins 7 Bonding material 8 surface plate 9 dial gauge

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平9−309164(JP,A) 特開 平10−202374(JP,A) 特開 平10−52770(JP,A) (58)調査した分野(Int.Cl.7,DB名) B23K 20/12 ─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-9-309164 (JP, A) JP-A-10-202374 (JP, A) JP-A-10-52770 (JP, A) (58) Field (Int.Cl. 7 , DB name) B23K 20/12

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 外表面にアルマイト処理、塗装又はヘア
ライン加工される複数のアルミニウム及び/又はアルミ
ニウム合金部材を接合してなり、表面処理性に優れるア
ルミニウム系構造体であって、前記外表面の裏側から摩
擦攪拌接合により接合した表面処理性に優れる接合部を
有し、前記外表面に接触する摩擦攪拌接合用裏当の表面
粗さが max 3.0S未満、Rmax0.8S以上であるこ
とを特徴とした表面処理性に優れるアルミニウム系構造
体。
1. An aluminum-based structure having excellent surface treatability, which is formed by joining a plurality of aluminum and / or aluminum alloy members to be anodized, painted or hairlined to the outer surface, and the back side of the outer surface. From the surface roughness of the backing for friction stir welding that is in contact with the outer surface is less than R max 3.0 S and R max 0.8 S or more. Aluminum-based structure with excellent surface treatment characteristics.
【請求項2】 外表面にアルマイト処理、塗装又はヘア
ライン加工される複数のアルミニウム及び/又はアルミ
ニウム合金部材を、前記外表面の裏側から摩擦攪拌接合
により接合してなり、表面処理性に優れるアルミニウム
系構造体の製造方法であって、前記外表面に接触する摩
擦攪拌接合用裏当の表面粗さが max 3.0S未満、Rm
ax0.8S以上であることを特徴とした表面処理性に優
れるアルミニウム系構造体の製造方法。
2. An aluminum-based material having excellent surface treatability, which is obtained by joining a plurality of aluminum and / or aluminum alloy members to be anodized, painted or hairlined on the outer surface by friction stir welding from the back side of the outer surface. A method of manufacturing a structure, wherein the surface roughness of a friction stir welding backing contacting the outer surface is less than R max 3.0 S , R m
A method for producing an aluminum-based structure having excellent surface treatability, which is characterized by having ax of 0.8 S or more.
JP9119998A 1998-04-03 1998-04-03 Aluminum structure having excellent surface treatment properties and method for producing the same Expired - Lifetime JP3487332B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9119998A JP3487332B2 (en) 1998-04-03 1998-04-03 Aluminum structure having excellent surface treatment properties and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9119998A JP3487332B2 (en) 1998-04-03 1998-04-03 Aluminum structure having excellent surface treatment properties and method for producing the same

Publications (2)

Publication Number Publication Date
JPH11285862A JPH11285862A (en) 1999-10-19
JP3487332B2 true JP3487332B2 (en) 2004-01-19

Family

ID=14019778

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9119998A Expired - Lifetime JP3487332B2 (en) 1998-04-03 1998-04-03 Aluminum structure having excellent surface treatment properties and method for producing the same

Country Status (1)

Country Link
JP (1) JP3487332B2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6745929B1 (en) 1998-06-16 2004-06-08 Hitachi, Ltd. Method of manufacturing structural body and structural body
JP2004106037A (en) * 2002-09-20 2004-04-08 Hitachi Ltd Method for bonding metal
JP4599608B2 (en) * 2006-05-02 2010-12-15 財団法人大阪産業振興機構 Friction stir processing method and backing jig for friction stir processing
JP2008238252A (en) * 2007-03-29 2008-10-09 Sumitomo Light Metal Ind Ltd Manufacturing method of housing made of aluminum alloy, and housing manufactured by this method
WO2012046352A1 (en) * 2010-10-08 2012-04-12 住友軽金属工業株式会社 Aluminum alloy welded member
CN103894726A (en) * 2014-03-13 2014-07-02 哈尔滨工业大学 Friction stir welding method capable of achieving back thickening to eliminate weak connection and adapting to plate thickness changes

Also Published As

Publication number Publication date
JPH11285862A (en) 1999-10-19

Similar Documents

Publication Publication Date Title
JP4053243B2 (en) Weldable aluminum alloy structural material
EP1057573A2 (en) A method of mending a friction stir joint
US20090148719A1 (en) Friction-stir weldments and systems and methods for producing the same
WO2015022894A1 (en) Friction stir welding method
De Giorgi et al. Effect of shoulder geometry on residual stress and fatigue properties of AA6082 FSW joints
JP3487332B2 (en) Aluminum structure having excellent surface treatment properties and method for producing the same
JPH11156559A (en) Welding method of hardenable nickel base alloy
JPH0481288A (en) Method for joining steel material with aluminum material
JP5875302B2 (en) Aluminum plate joining method
JP2003200273A (en) Method of manufacturing weldingless bonded magnetic/ aluminum member
Colligan Friction stir welding for ship construction
JP3552956B2 (en) Stainless clad steel plate welding method
JP4232339B2 (en) Butt welding method of metal by friction stir welding
EP1025943A2 (en) Method for making a welded joint
JP6043692B2 (en) Friction stir welding method
JPH05263875A (en) Metallic composite counterweight for aluminum drive shaft and attachment technique
US20140023874A1 (en) Method for welding aluminum alloy materials and aluminum alloy panel produced thereby
EP2687313A1 (en) Method of friction stir welding aluminum alloy materials containing second phase particles, and aluminum alloy panel produced thereby
JPH07266068A (en) Method for laser beam welding aluminum or aluminum alloy member
JPH071143A (en) Method of welding aluminum or aluminum alloy article
JPS5970481A (en) Spot welding method
JP7332872B2 (en) Composite welding method
JPH0615110B2 (en) One-sided welding method
JPH03248776A (en) Welding method for aluminum alloy clad material
Pickering et al. Production and performance of high speed GTA welded aluminum tailored blanks

Legal Events

Date Code Title Description
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081031

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091031

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091031

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101031

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111031

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111031

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121031

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121031

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131031

Year of fee payment: 10

EXPY Cancellation because of completion of term