JP3480179B2 - Automotive interior materials - Google Patents

Automotive interior materials

Info

Publication number
JP3480179B2
JP3480179B2 JP11777496A JP11777496A JP3480179B2 JP 3480179 B2 JP3480179 B2 JP 3480179B2 JP 11777496 A JP11777496 A JP 11777496A JP 11777496 A JP11777496 A JP 11777496A JP 3480179 B2 JP3480179 B2 JP 3480179B2
Authority
JP
Japan
Prior art keywords
melting point
polyethylene terephthalate
layer
mainly composed
interior material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11777496A
Other languages
Japanese (ja)
Other versions
JPH09301088A (en
Inventor
順 岡田
好一 根本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Motor Co Ltd
Original Assignee
Nissan Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Motor Co Ltd filed Critical Nissan Motor Co Ltd
Priority to JP11777496A priority Critical patent/JP3480179B2/en
Publication of JPH09301088A publication Critical patent/JPH09301088A/en
Application granted granted Critical
Publication of JP3480179B2 publication Critical patent/JP3480179B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Landscapes

  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
  • Laminated Bodies (AREA)
  • Soundproofing, Sound Blocking, And Sound Damping (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、自動車用内装材に
関し、特に乗員の快適性を向上させるために、車室内騒
音を低減できる自動車用内装材(以下、天井材という)
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an automobile interior material, and more particularly to an automobile interior material (hereinafter referred to as a ceiling material) capable of reducing vehicle interior noise in order to improve passenger comfort.
Regarding

【0002】[0002]

【従来の技術および発明が解決しようとする課題】現
在、自動車の高級化や高性能化に伴い車室内の静粛性を
向上させることが必要となってきている。しかしなが
ら、これまでの天井材は、吸遮音性を重視したものが少
なく、一般に安価なことが重要視されている。これらの
代表的なものとしては、木質ボードや再生繊維にフェノ
ール樹脂等の熱硬化性バインダーを使用しているフェル
トなどを芯材としたものであった。
2. Description of the Related Art At present, it is necessary to improve the quietness of the passenger compartment as automobiles become more sophisticated and have higher performance. However, there are few ceiling materials up to now that place importance on sound absorption and sound insulation, and it is generally important that they are inexpensive. As a typical example of these, a felt having a thermosetting binder such as a phenol resin as a wood board or a recycled fiber is used as a core material.

【0003】従って本発明は、従来の技術に鑑み、より
高い吸遮音性能をもつ天井材を提供することを目的とす
る。
Therefore, in view of the prior art, it is an object of the present invention to provide a ceiling material having a higher sound absorbing / insulating performance.

【0004】[0004]

【課題を解決するための手段】本発明の上記の目的は、
自動車用ヘッドライニングにおいて、ポリエステル繊維
を主な構成基材とする中間層の少なくとも一方に緻密層
を形成し、二重壁タイプの遮音構造体としたことを特徴
とする自動車用内装材により達成された。
The above objects of the present invention are as follows.
In a vehicle headlining, the present invention is achieved by an interior material for an automobile, characterized in that a double-wall type sound insulation structure is formed by forming a dense layer on at least one of the intermediate layers mainly composed of polyester fiber. It was

【0005】本発明では、図1に示したようにポリエス
テル繊維を主な構成基材とする中間層の少なくとも一
方、好ましくは両側に緻密層を形成し、二重壁タイプの
遮音構造体とすることで、遮音性能を向上させることが
できる。また、緻密層の重量をコントロールすることで
車両として必要な周波数域に最も有効に機能できるよう
にチューニングも可能となる。さらに、中間層に低バネ
層を配置することにより振動伝達を低減でき、遮音性能
を向上させることができる。
In the present invention, as shown in FIG. 1, a dense layer is formed on at least one, and preferably on both sides, of an intermediate layer mainly composed of polyester fiber to obtain a double wall type sound insulation structure. Therefore, the sound insulation performance can be improved. Also, by controlling the weight of the dense layer, it is possible to perform tuning so that it can function most effectively in the frequency range required for the vehicle. Further, by disposing the low spring layer in the intermediate layer, it is possible to reduce vibration transmission and improve sound insulation performance.

【0006】また、緻密層の通気量をコントロールする
ことにより中間層での吸音性能を向上させることができ
る。すなわち、遮音性能は若干減少するが、吸音性能を
向上させることができる。ポリエステル等は、高周波域
での吸音性能は優れるが、低周波域では性能が低下する
のが一般的であるので、対象車両の性能必要領域によっ
て吸音性能と遮音性能とを使い分けることが有効であ
り、本発明の天井材により対象車種ごとのチューニング
が可能となる。
Further, the sound absorption performance of the intermediate layer can be improved by controlling the air flow rate of the dense layer. That is, although the sound insulation performance is slightly reduced, the sound absorption performance can be improved. Polyester and the like have excellent sound absorption performance in the high frequency range, but generally have poor performance in the low frequency range, so it is effective to use sound absorption performance and sound insulation performance properly depending on the required performance area of the target vehicle. The ceiling material of the present invention enables tuning for each target vehicle type.

【0007】緻密層は、中間層の両側に配置することが
望ましいが、自動車用内装材として用いる場合には、車
体パネルがいずれにしても存在するので、緻密層は中間
層の少なくとも一方に有れば結果的に二重壁構造になり
上記効果を発揮することができる。望ましくは内装材単
体で二重壁構造を取れる中間層の両側に緻密層を配置し
たほうが良い。
It is desirable to dispose the dense layer on both sides of the intermediate layer. However, when the dense layer is used as an interior material for automobiles, since the vehicle body panel is present in any case, the dense layer is provided on at least one of the intermediate layers. As a result, a double wall structure is obtained, and the above effect can be exhibited. It is desirable to dispose the dense layers on both sides of the intermediate layer, which can have a double wall structure with the interior material alone.

【0008】この緻密層は、ポリエチレンテレフタレー
トを主体とする繊度1〜50デニールの高融点繊維0〜
60重量%と、ポリエチレンテレフタレートを主体とす
る芯成分とポリエチレンテレフタレートを主たる共重合
成分とする融点200℃以下の低融点エラステックポリ
エステル鞘成分とからなる繊度1〜20デニールの芯鞘
型複合繊維40〜100重量%とで構成され、加工成形
後に厚さ3mm以下で面密度200g/cm2 以上であ
ることが好ましい。
This dense layer is composed of polyethylene terephthalate as a main component and has a fineness of 1 to 50 denier and high melting point fibers 0 to
A core-sheath type composite fiber 40 having a fineness of 1 to 20 denier, which comprises 60% by weight and a core component mainly composed of polyethylene terephthalate and a low melting point elastic polyester sheath component having a melting point of 200 ° C. or less, which comprises polyethylene terephthalate as a main copolymerization component. It is preferable that the thickness is 3 mm or less and the areal density is 200 g / cm 2 or more after processing and molding.

【0009】遮音性能を重要視した場合に、緻密層はエ
チレンビニルアセテート、ポリエステルまたはポリエチ
レン等を主体とする50g/m2 以上の面密度を有する
高分子フィルムを使用することが好ましい。
When importance is attached to the sound insulation performance, it is preferable to use a polymer film mainly composed of ethylene vinyl acetate, polyester or polyethylene and having a surface density of 50 g / m 2 or more as the dense layer.

【0010】本発明においては、緻密層の面密度および
厚さが上記範囲を越える場合には遮音性能に十分な二重
壁構造を実現することができない。すなわち、緻密層の
厚さが厚すぎると壁構造として機能せず、また、緻密層
の面密度が低すぎると厚みが薄くても十分な重量が確保
できずそれ自身が膜共振して音圧を伝達することにな
る。
In the present invention, when the surface density and the thickness of the dense layer exceed the above ranges, a double wall structure having sufficient sound insulation performance cannot be realized. That is, if the dense layer is too thick, it does not function as a wall structure, and if the surface density of the dense layer is too low, sufficient weight cannot be ensured even if the dense layer is thin, and the film itself resonates and causes sound pressure. Will be transmitted.

【0011】また、本発明においては、緻密層の通気量
は0〜10cc/cm2 ・secの範囲であることが好
ましい。この範囲を越える通気量では殆ど遮音性能を期
待することができず、本発明の意図する遮音性と吸音性
とを両立することができない。
Further, in the present invention, it is preferable that the dense layer has an air permeability of 0 to 10 cc / cm 2 · sec. With a ventilation amount exceeding this range, almost no sound insulation performance can be expected, and the sound insulation properties and sound absorption properties intended by the present invention cannot be achieved at the same time.

【0012】さらに、本発明においては、中間層の一部
に低ばね層を設け、その動ばね定数が中間層の動ばね定
数に対して90%以下であることが好ましい。中間層内
に低ばね層を一部設けたのは、低ばねを一部に設置する
ことにより中間層内に直列ばねが生じ層内全体での低ば
ね化が達成できるためである。また、一部に設定したの
は、天井材としての剛性を低ばね化により落とすことを
できるだけ抑えるためである。
Further, in the present invention, it is preferable that a low spring layer is provided in a part of the intermediate layer, and the dynamic spring constant thereof is 90% or less of the dynamic spring constant of the intermediate layer. The reason why the low spring layer is partially provided in the intermediate layer is that by installing the low spring in a portion, a series spring is generated in the intermediate layer, and the low spring in the entire layer can be achieved. Moreover, the reason why it is set to a part is to prevent the rigidity of the ceiling material from being lowered by reducing the spring.

【0013】この低ばね層は、ポリエチレンテレフタレ
ートを主体とする繊度1〜デニールの高融点繊維90〜
100重量%と、ポリエチレンテレフタレートを主体と
する芯成分とポリエチレンテレフタレートを主たる共重
合成分とする融点200℃以下の低融点エラステックポ
リエステル鞘成分とからなる繊度1〜10デニールの芯
鞘型複合繊維0〜10重量%とで構成されることが好ま
しい。
This low spring layer is mainly composed of polyethylene terephthalate and has a high melting point fiber 90 having a fineness of 1 to denier.
A core-sheath composite fiber having a fineness of 1 to 10 denier consisting of 100% by weight and a core component mainly composed of polyethylene terephthalate and a low-melting point elastic polyester sheath component having a melting point of 200 ° C. or less which mainly comprises polyethylene terephthalate as a copolymerization component 0 It is preferably composed of 10 to 10% by weight.

【0014】本発明において、使用される繊維は、高融
点ポリエステル繊維としてはポリエチレンテレフタレー
トまたはそれに準じた成分を有するポリエステルが安価
で望ましい。芯鞘構造を有する熱融着型繊維に用いられ
るコポリエステルとしては、テレフタル酸やイソフタル
酸等の酸成分と、エチレングリコール、プロピレングリ
コール、ジエチレングリコール等のジオール成分、また
はラクトンを開環して共重合したコポリステルを用いる
ことが可能である。芯部に用いられるポリエチレンテレ
フタレートまたはそれに準ずる成分を有するポリエステ
ルが安価で望ましい。
In the present invention, the fiber used is preferably polyethylene terephthalate or a polyester having a component similar thereto as the high melting point polyester fiber because it is inexpensive and desirable. As the copolyester used for the heat-sealing type fiber having a core-sheath structure, an acid component such as terephthalic acid or isophthalic acid, a diol component such as ethylene glycol, propylene glycol or diethylene glycol, or a lactone is ring-opened and copolymerized. It is possible to use the copolyester. Polyethylene terephthalate used for the core or polyester having a component similar thereto is inexpensive and desirable.

【0015】[0015]

【実施例】以下、本発明を実施例によって更に詳細に説
明するが、本発明はこれによって限定されるものではな
い。
EXAMPLES The present invention will now be described in more detail by way of examples, which should not be construed as limiting the invention.

【0016】実施例1 中間層 13デニール52mm長の丸断面の通常ポリエステルス
テーブル繊維65重量%と、2デニール52mm長の芯
鞘構造を有する熱融着型のポリエステルステーブル繊維
(130 ℃溶融型)35重量%とをブレンド、カーディン
グ、クロスレイヤーおよびニードルパンチ工程を経て目
付600g/m2 の原反を得た。
Example 1 65% by weight of a normal polyester stable fiber having a circular cross section of 52 denier with an intermediate layer of 13 denier and a heat fusion type polyester stable fiber having a core-sheath structure of 52 denier with a denier of 2 mm (130 ° C. melt type ) 35 wt% was blended, carded, cross-layered and needle punched to obtain a fabric having a basis weight of 600 g / m 2 .

【0017】緻密層 13デニール52mm長の丸断面の通常ポリエステルス
テーブル繊維10重量%と、2デニール52mm長の芯
鞘構造を有する熱融着型のポリエステルステーブル繊維
(130 ℃溶融型)90重量%とをブレンド、カーディン
グ、クロスレイヤーおよびニードルパンチ工程を経て目
付200g/m2 の原反を得た。
Dense layer 13 denier 52 mm long 10% by weight of normal polyester stable fiber having a round cross section and 2 denier 52 mm long thermal fusion type polyester stable fiber having a core-sheath structure (melting at 130 ° C.) 90% by weight % To obtain a raw fabric having a basis weight of 200 g / m 2 through the steps of blending, carding, cross layer and needle punching.

【0018】得られた中間層を二層の緻密層ではさみ積
層し、ニードルパンチ工程を通すことで接着させて、さ
らに170℃に加熱し、プレス成形して天井芯材を作製
した。
The intermediate layer thus obtained was sandwiched between two dense layers, laminated by passing through a needle punching step, further heated to 170 ° C. and press-molded to produce a ceiling core material.

【0019】実施例2 中間層の10重量%部分を2dの通常繊維を混入するこ
とで実施例1におけるばね定数の90%のばね定数を持
つ層を追加した以外は、実施例1と全く同様にして天井
芯材を作製した。
Example 2 Exactly the same as Example 1 except that a layer having a spring constant of 90% of the spring constant in Example 1 was added by mixing 2d of ordinary fibers in the 10% by weight portion of the intermediate layer. Then, a ceiling core material was produced.

【0020】実施例3 緻密層の目付を300g/m2 および中間層の目付を4
00g/m2 とした以外は、実施例1と全く同様にして
天井芯材を作製した。
Example 3 The basis weight of the dense layer was 300 g / m 2 and the basis weight of the intermediate layer was 4.
A ceiling core material was produced in exactly the same manner as in Example 1 except that the amount was set to 00 g / m 2 .

【0021】実施例4 緻密層を車室内側一方にのみ設置した以外は、実施例1
と全く同様にして天井芯材を作製した。
Example 4 Example 1 was repeated except that the dense layer was provided only on one side of the vehicle interior.
A ceiling core material was produced in exactly the same manner as.

【0022】実施例5 緻密層をEVA、50g/m2 を用いた以外は、実施例
1と全く同様にして天井芯材を作製した。
Example 5 A ceiling core material was produced in exactly the same manner as in Example 1 except that EVA and 50 g / m 2 were used for the dense layer.

【0023】実施例6 緻密層に全融型ポリエステル繊維を90重量%配合した
以外は、実施例1と全く同様にして天井芯材を作製し
た。尚、緻密層の通気量は2cc/cm2・sec 以下であっ
た。
Example 6 A ceiling core material was produced in the same manner as in Example 1 except that 90% by weight of the fully melted polyester fiber was blended in the dense layer. The ventilation rate of the dense layer was 2 cc / cm 2 · sec or less.

【0024】比較例1 ポリスチレンとポリフェニレンオキシドをポリマーアロ
イ化したエンジニアリングプラスチクとを用い、加熱成
形して高発泡化したものを天井芯材とした。この時芯材
目付を550g/m2 とした。
Comparative Example 1 Polystyrene and an engineering plastic obtained by polymerizing polyphenylene oxide into a polymer were heat-molded to obtain a highly foamed ceiling core material. At this time, the basis weight of the core material was 550 g / m 2 .

【0025】比較例2 緻密層の目付を100g/m2 および中間層の目付を8
00g/m2 とした以外は、実施例1と全く同様にして
天井芯材を作製した。
COMPARATIVE EXAMPLE 2 The dense layer has a basis weight of 100 g / m 2 and the intermediate layer has a basis weight of 8
A ceiling core material was produced in exactly the same manner as in Example 1 except that the amount was set to 00 g / m 2 .

【0026】比較例3 緻密層のEVAフィルムの目付を40g/m2 とした以
外は、実施例1と全く同様にして天井芯材を作製した。
Comparative Example 3 A ceiling core material was produced in exactly the same manner as in Example 1 except that the EVA film of the dense layer had a basis weight of 40 g / m 2 .

【0027】評価結果 上記で得られた天井芯材にさらにトリコット150g/
2 の表皮を貼ったものを成形して天井材とした。この
天井材の吸音率および音響透過損失を測定した。その結
果を表1に示す。
Evaluation results Further, tricot 150 g /
A ceiling material of m 2 was formed to obtain a ceiling material. The sound absorption coefficient and sound transmission loss of this ceiling material were measured. The results are shown in Table 1.

【0028】[0028]

【表1】 [Table 1]

【0029】[0029]

【発明の効果】本発明の自動車用内装材(天井材)によ
れば、車室内騒音を低減することができるので、乗員の
快適性を向上させることができる。
According to the automobile interior material (ceiling material) of the present invention, the noise in the vehicle compartment can be reduced, and the comfort of the occupant can be improved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の二重壁構造内装材の断面図である。FIG. 1 is a cross-sectional view of a double wall structure interior material of the present invention.

【符号の説明】[Explanation of symbols]

1 ルーフパネル 2 緻密層 3 中間層 4 表皮 1 roof panel 2 dense layer 3 Middle class 4 epidermis

フロントページの続き (51)Int.Cl.7 識別記号 FI B32B 27/36 B32B 27/36 G10K 11/162 G10K 11/16 A (58)調査した分野(Int.Cl.7,DB名) B60R 13/02 B32B 5/02 B32B 27/00 B32B 27/12 B32B 27/28 101 B32B 27/36 G10K 11/162 Continuation of front page (51) Int.Cl. 7 Identification code FI B32B 27/36 B32B 27/36 G10K 11/162 G10K 11/16 A (58) Fields investigated (Int.Cl. 7 , DB name) B60R 13 / 02 B32B 5/02 B32B 27/00 B32B 27/12 B32B 27/28 101 B32B 27/36 G10K 11/162

Claims (5)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 自動車用ヘッドライニングにおいて、ポ
リエステル繊維を主な構成基材とする中間層の少なくと
も一方に緻密層を形成し、二重壁タイプの遮音構造体と
し、 当該緻密層がポリエチレンテレフタレートを主体とする
繊度1〜50デニールの高融点繊維0〜60重量%と、
ポリエチレンテレフタレートを主体とする芯成分とポリ
エチレンテレフタレートを主たる共重合成分とする融点
200℃以下の低融点エラステックポリエステル鞘成分
とからなる繊度1〜20デニールの芯鞘型複合繊維40
〜100重量%とで構成され、加工成形後に厚さ3mm
以下で面密度200g/cm2 以上であることを特徴と
する自動車用内装材。
1. A head lining for automobiles, wherein a dense layer is formed on at least one of intermediate layers mainly composed of polyester fibers to form a double-wall type sound insulation structure, and the dense layer is made of polyethylene terephthalate. 0-60% by weight of a high melting point fiber having a fineness of 1 to 50 denier as a main component,
A core-sheath type composite fiber 40 having a fineness of 1 to 20 denier, which comprises a core component mainly composed of polyethylene terephthalate and a low melting point elastic polyester sheath component having a melting point of 200 ° C. or less and mainly composed of polyethylene terephthalate.
~ 100% by weight, thickness 3mm after processing and molding
An automotive interior material having an areal density of 200 g / cm 2 or more below.
【請求項2】 自動車用ヘッドライニングにおいて、ポ
リエステル繊維を主な構成基材とする中間層の少なくと
も一方に緻密層を形成し、二重壁タイプの遮音構造体と
し、 緻密層がエチレンビニルアセテート、ポリエステルまた
はポリエチレン等を主体とする50g/cm2 以上の面
密度を有する高分子フィルムであることを特徴とする自
動車用内装材。
2. A head lining for automobiles, wherein a dense layer is formed on at least one of the intermediate layers containing polyester fiber as a main constituent base material to form a double wall type sound insulation structure, wherein the dense layer is ethylene vinyl acetate, An interior material for automobiles, which is a polymer film mainly composed of polyester or polyethylene and having an areal density of 50 g / cm 2 or more.
【請求項3】 緻密層が通気量0〜10cc/cm2
secであることを特徴とする請求項1または2記載の
自動車用内装材。
3. The dense layer has an air flow rate of 0 to 10 cc / cm 2 ·
The interior material for automobiles according to claim 1 or 2, wherein the interior material is sec.
【請求項4】 中間層の一部に低ばね層を設け、その動
ばね定数が中間層の動ばね定数に対して90%以下であ
ることを特徴とする請求項1または2記載の自動車用内
装材。
4. The automobile according to claim 1, wherein a low spring layer is provided in a part of the intermediate layer, and the dynamic spring constant is 90% or less of the dynamic spring constant of the intermediate layer. Interior material.
【請求項5】 低ばね層がポリエチレンテレフタレート
を主体とする繊度1〜15デニールの高融点繊維90〜
100重量%と、ポリエチレンテレフタレートを主体と
する芯成分とポリエチレンテレフタレートを主たる共重
合成分とする融点200℃以下の低融点エラステックポ
リエステル鞘成分とからなる繊度1〜10デニールの芯
鞘型複合繊維0〜10重量%とで構成されることを特徴
とする請求項4記載の自動車用内装材。
5. A high melting point fiber 90 having a fineness of 1 to 15 denier, in which the low spring layer is mainly composed of polyethylene terephthalate.
A core-sheath composite fiber having a fineness of 1 to 10 denier consisting of 100% by weight and a core component mainly composed of polyethylene terephthalate and a low-melting point elastic polyester sheath component having a melting point of 200 ° C. or less which mainly comprises polyethylene terephthalate as a copolymerization component 0 It is comprised by 10 to 10 weight%, The interior material for motor vehicles of Claim 4 characterized by the above-mentioned.
JP11777496A 1996-05-13 1996-05-13 Automotive interior materials Expired - Fee Related JP3480179B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11777496A JP3480179B2 (en) 1996-05-13 1996-05-13 Automotive interior materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11777496A JP3480179B2 (en) 1996-05-13 1996-05-13 Automotive interior materials

Publications (2)

Publication Number Publication Date
JPH09301088A JPH09301088A (en) 1997-11-25
JP3480179B2 true JP3480179B2 (en) 2003-12-15

Family

ID=14720002

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11777496A Expired - Fee Related JP3480179B2 (en) 1996-05-13 1996-05-13 Automotive interior materials

Country Status (1)

Country Link
JP (1) JP3480179B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009149117A (en) * 2007-12-18 2009-07-09 Yamaha Corp Sound absorbing structure for automobile ceiling, and its manufacturing method

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110039216A (en) * 2008-05-23 2011-04-15 에먼에이트 피티와이 리미티드 Sound absorption material and method of manufacturing sound absorption material
WO2016115138A1 (en) 2015-01-12 2016-07-21 Zephyros, Inc. Acoustic floor underlay system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009149117A (en) * 2007-12-18 2009-07-09 Yamaha Corp Sound absorbing structure for automobile ceiling, and its manufacturing method

Also Published As

Publication number Publication date
JPH09301088A (en) 1997-11-25

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