JP3409609B2 - Easy-adhesion stretched polylactic acid sheet - Google Patents
Easy-adhesion stretched polylactic acid sheetInfo
- Publication number
- JP3409609B2 JP3409609B2 JP27096696A JP27096696A JP3409609B2 JP 3409609 B2 JP3409609 B2 JP 3409609B2 JP 27096696 A JP27096696 A JP 27096696A JP 27096696 A JP27096696 A JP 27096696A JP 3409609 B2 JP3409609 B2 JP 3409609B2
- Authority
- JP
- Japan
- Prior art keywords
- polylactic acid
- easy
- stretched sheet
- adhesion
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Biological Depolymerization Polymers (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、易接着の界面が被
覆された生分解性プラスチックであるポリ乳酸延伸シー
トに関し、さらに詳しくは、各種の印刷塗料と良好な易
接着性を有し、しかもコーティング加工時におけるブロ
ッキング等のトラブルが防止できる易接着性ポリ乳酸延
伸シートに関するものである。TECHNICAL FIELD The present invention relates to a polylactic acid stretched sheet which is a biodegradable plastic having an easily-adhesive interface coated, and more specifically, it has good easy-adhesion properties with various printing paints, and The present invention relates to an easily-adhesive polylactic acid stretched sheet capable of preventing problems such as blocking during coating processing.
【０００２】[0002]
【従来の技術】近年、生分解性プラスチック材料の開発
が盛んであり、多数の生分解性プラスチックが市場に出
回っている。例えば、３−ヒドロキシ酪酸・３−ヒドロ
キシ吉草酸共重合体Ｐ（３ＨＢ−３ＨＶ）等の微生物産
生ポリエステル、ポリカブロラクトン（ＰＣＬ）などの
脂肪族ポリエステル、ポリビニルアルコール・でんぷん
複合体、ポリ乳酸等が挙げられる。さらには、これらの
分解性を有するプラスチック同士の混合体や積層体等が
挙げられる。これらの生分解性プラスチックは使用した
後、自然環境に放置されると、土中或いは水中に存在す
る微生物により分解され、最終的には、水、炭酸ガス、
メタン等にまで分解する。このなかでも、物理特性、加
工性等が優れた生分解性プラスチックであるポリ乳酸が
注目されており、ポリ乳酸を用いた射出成形品、ポリ乳
酸の薄膜フィルム、ポリ乳酸延伸シートなどの製品或い
は基材が開発されている。2. Description of the Related Art In recent years, biodegradable plastic materials have been actively developed, and many biodegradable plastics are on the market. For example, microbial polyesters such as 3-hydroxybutyric acid / 3-hydroxyvaleric acid copolymer P (3HB-3HV), aliphatic polyesters such as polycaprolactone (PCL), polyvinyl alcohol / starch complex, polylactic acid, etc. Can be mentioned. Furthermore, a mixture of these degradable plastics, a laminated body, etc. are mentioned. When these biodegradable plastics are used and left to stand in a natural environment, they are decomposed by microorganisms existing in the soil or water, and finally water, carbon dioxide,
Decomposes to methane. Among these, polylactic acid, which is a biodegradable plastic excellent in physical properties and processability, has been drawing attention, and products such as injection molded products using polylactic acid, thin films of polylactic acid, and stretched sheets of polylactic acid, or Substrates have been developed.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、上記基
材であるポリ乳酸延伸シートは、印刷インキ等の接着性
が低く、すなわち、印刷適性がなく、従って、直接製品
に応用することは難しかった。そこで本発明は、上記の
課題に鑑みなされたもので、その目的とするところは、
ポリ乳酸延伸シートに溶剤可溶な飽和共重合ポリエステ
ル樹脂等による易接着インキを塗工して、シートの易接
着性の向上とブロッキング防止が施された易接着性ポリ
乳酸延伸シートを提供することにある。However, the polylactic acid stretched sheet, which is the above-mentioned substrate, has low adhesiveness to printing ink or the like, that is, it has no printability, and therefore it was difficult to directly apply it to products. Therefore, the present invention has been made in view of the above problems, and its object is to:
To provide an easy-adhesive polylactic acid stretched sheet that is coated with an easy-adhesive ink such as a solvent-soluble saturated copolyester resin on a polylactic acid stretched sheet to improve the easy adhesion of the sheet and prevent blocking. It is in.
【０００４】[0004]
【課題を解決するための手段】本発明の請求項１によれ
ば、ポリ乳酸延伸シートの片面もしくは両面に、平均分
子量５０００〜２５０００の溶剤可溶な熱可塑性飽和共
重合ポリエステル樹脂を５〜５０重量％と、平均粒子径
０．１〜５μｍのフィラーを１０〜５０重量％と有機溶
剤とからなる易接着インキによる、易接着層を設けたこ
とを特徴とするものである。According to claim 1 of the present invention, a solvent-soluble thermoplastic saturated copolymerized polyester resin having an average molecular weight of 5,000 to 25,000 is provided on one side or both sides of a polylactic acid stretched sheet in an amount of 5 to 50. %, A filler having an average particle diameter of 0.1 to 5 .mu.m, 10 to 50% by weight, and an easy-adhesion layer made of an easy-adhesion ink composed of an organic solvent.
【０００５】本発明の請求項２によれば、前記溶剤可溶
な熱可塑性ポリエステル樹脂塗布液に添加するフィラー
が、二酸化珪素を主成分とする多孔性合成シリカである
ことを特徴とするものである。According to a second aspect of the present invention, the filler added to the solvent-soluble thermoplastic polyester resin coating liquid is porous synthetic silica containing silicon dioxide as a main component. is there.
【０００６】本発明の請求項３によれば、前記易接着層
の膜厚が、０．５〜５μｍ（ドライ膜厚）としたことを
特徴とするものである。According to a third aspect of the present invention, the easy-adhesion layer has a film thickness of 0.5 to 5 μm (dry film thickness).
【０００７】本発明の請求項４によれば、前記ポリ乳酸
延伸シートに、コロナ放電処理を施したことを特徴とす
るものである。According to a fourth aspect of the present invention, the stretched polylactic acid sheet is subjected to corona discharge treatment.
【０００８】[0008]
【発明の実施の形態】本発明の易接着性ポリ乳酸延伸シ
ートは、ポリ乳酸延伸シートの片面もしくは両面に、平
均分子量５０００〜２５０００の溶剤に可溶な熱可塑性
飽和共重合ポリエステル樹脂を５〜５０重量％と、平均
粒子径０．１〜５μｍのフィラーを１０〜５０重量％と
有機溶剤とからなる、易接着インキの塗工による、易接
着層を設けたことでポリ乳酸延伸シートの表面状態を改
良し、接着性を向上させた。BEST MODE FOR CARRYING OUT THE INVENTION The easily adhesive polylactic acid stretched sheet of the present invention comprises a solvent-soluble thermoplastic saturated copolyester resin having an average molecular weight of 5,000 to 25,000 on one or both sides of the polylactic acid stretched sheet. The surface of the polylactic acid stretched sheet by forming an easy-adhesion layer by coating 50% by weight, 10-50% by weight of a filler having an average particle diameter of 0.1 to 5 μm, and an organic solvent The condition was improved and the adhesiveness was improved.
【０００９】また、ポリ乳酸延伸シートの表面状態を改
良、及びこのシートに印刷するときのプロッキング防止
のため、分散性が優れ、表面改質の効果がある二酸化珪
素を主成分とする多孔性合成シリカを易接着インキに添
加した。Further, in order to improve the surface condition of the polylactic acid stretched sheet and to prevent plucking at the time of printing on this sheet, the dispersibility is excellent and the porosity containing silicon dioxide as a main component is effective for surface modification. Synthetic silica was added to the easy-adhesion ink.
【００１０】また、易接着性及びブロッキング防止性を
有するため、易接着インキによる膜厚は塗工乾燥後０．
１〜５μｍとし、生分解性プラスチック延伸シートのこ
とを考えるとできる限り易接着層を薄く塗工することが
望ましく、好ましくは０．５〜２μｍが良い。Further, since it has an easy-adhesion property and an anti-blocking property, the film thickness of the easy-adhesion ink is not more than 0 after coating and drying.
1 to 5 μm, it is desirable to apply the easy-adhesion layer as thinly as possible considering the biodegradable plastic stretched sheet, and preferably 0.5 to 2 μm.
【００１１】また、ポリ乳酸延伸シートと易接着インキ
との接着性を向上させるため、シートに易接着インキを
塗工する前に、コロナ放電処理を施すことが望ましい。In order to improve the adhesion between the stretched polylactic acid sheet and the easy-adhesion ink, it is desirable to perform corona discharge treatment before applying the easy-adhesion ink to the sheet.
【００１２】[0012]
【実施例】 、以
下、図面を参照しながら、本発明の実施例を説明する。
図１の１は本発明の易接着性ポリ乳酸延伸シートであ
る。２は平均分子量５０００〜２５０００の溶剤に可溶
な熱可塑性飽和共重合ポリエステル樹脂を５〜５０重量
％と、平均粒子径０．１〜５μｍのフィラーを１０〜５
０重量％と有機溶剤とからなる易接着インキによる易接
着層である。３はポリ乳酸１軸或いは２軸延伸したシー
トである。EXAMPLES Examples of the present invention will be described below with reference to the drawings.
1 in FIG. 1 is an easily adhesive polylactic acid stretched sheet of the present invention. 2 is 5 to 50% by weight of a thermoplastic saturated copolyester resin soluble in a solvent having an average molecular weight of 5,000 to 25,000, and 10 to 5 a filler having an average particle diameter of 0.1 to 5 μm.
An easy-adhesion layer made of an easy-adhesion ink composed of 0% by weight and an organic solvent. 3 is a uniaxially or biaxially stretched sheet of polylactic acid.
【００１３】ポリ乳酸延伸シート３は、ポリ乳酸樹脂ペ
レット（島津製作所製・商品名：ラクティ）を用いて、
まず押し出し成型機でシートを成形し、成形したシート
を、インライン或いはオフラインで１軸或いは２軸を延
伸することにより成形した。The polylactic acid stretched sheet 3 is formed by using polylactic acid resin pellets (manufactured by Shimadzu Corporation, trade name: Lacty).
First, a sheet was formed by an extrusion molding machine, and the formed sheet was formed by stretching uniaxially or biaxially in-line or off-line.
【００１４】＜実施例１＞図に示すように、ポリ乳酸延
伸シートの両面に、下記の易接着インキを塗工し、乾燥
させて易接着層を設けて、易接着性ポリ乳酸延伸シート
を得た。易接着インキの組成は、
・ポリエステル樹脂（ユニチカ製商品名：エイーテルＵＥ３３８０）３０部
・フィラー（富士シリシア化学製商品名：サイロホーピック２００）２５部
・溶剤（東洋インキ製商品名：ＶＣ２０２） ４５部
である。上記のインキを用いて、グラビア塗工法で易接
着層を設けた。グラビア法以外、マイクログラビア塗工
法、リバース塗工法、スロットダイ塗工法等を使用する
ことができる。<Example 1> As shown in the figure, an easily adhesive polylactic acid stretched sheet was prepared by coating the following easily adhesive ink on both sides of a polylactic acid stretched sheet and drying it to form an easily adhesive layer. Obtained. The composition of the easy-adhesion ink is as follows: -Polyester resin (Unitika, trade name: Eitel UE3380) 30 parts-Filler (Fuji Silysia Chemical, trade name: Syrophopic 200) 25 parts-Solvent (Toyo Ink, trade name: VC202) 45 It is a department. An easily adhesive layer was provided by the gravure coating method using the above ink. Other than the gravure method, a micro gravure coating method, a reverse coating method, a slot die coating method or the like can be used.
【００１５】＜実施例２＞前記ポリ乳酸延伸シートの両
面に、下記の易接着インキを塗工し、乾燥させて易接着
層を設けて、易接着性ポリ乳酸延伸シートを得た。易接
着インキの組成は、
・ポリエステル樹脂（ユニチカ製商品名：エイーテルＵＥ３３００）３０部
・フィラー（富士シリシア化学製商品名：サイロホーピック１００）２０部
・溶剤（東洋インキ製商品名ＶＣ２０２） ５０部
である。上記のインキを用いて、グラビア塗工法で易接
着層を設けた。グラビア法以外、マイクログラビア塗工
法、リバース塗工法、スロットダイ塗工法等を使用する
ことができる。Example 2 The following easy-adhesion ink was applied to both surfaces of the polylactic acid stretched sheet and dried to form an easy-adhesion layer to obtain an easy-adhesion polylactic acid stretched sheet. The composition of the easy-adhesion ink is as follows: -Polyester resin (Unitika product name: Eitel UE3300) 30 parts-Filler (Fuji Silysia Chemical product name: Sylophopic 100) 20 parts-Solvent (Toyo Ink product name VC202) 50 parts Is. An easily adhesive layer was provided by the gravure coating method using the above ink. Other than the gravure method, a micro gravure coating method, a reverse coating method, a slot die coating method or the like can be used.
【００１６】上記易接着インキを塗工した実施例１にお
けるシート及び実施例２におけるシートと、未処理のポ
リ乳酸延伸シートの印刷インキの接着性の比較を行っ
た。結果を表１に示す。The adhesiveness of the printing ink between the sheet of Example 1 and the sheet of Example 2 coated with the above-mentioned easily adhesive ink and the untreated polylactic acid stretched sheet was compared. The results are shown in Table 1.
【００１７】[0017]
【表１】 [Table 1]
【００１８】[0018]
【発明の効果】本発明は、ポリ乳酸延伸シートの片面も
しくは両面に、溶剤可溶な熱可塑性飽合共重合ポリエス
テル樹脂と、フィラーと有機溶剤とからなる、易接着イ
ンキによる易接着層を設けたことにより、ポリ乳酸延伸
シートの印刷適正、印刷インキとの接着性の向上、さら
には印刷時のブロッキングが防止できる易接着性ポリ乳
酸延伸シートが得られた。INDUSTRIAL APPLICABILITY According to the present invention, an easy-adhesion layer made of an easy-adhesion ink comprising a solvent-soluble thermoplastic saturable copolyester resin, a filler and an organic solvent is provided on one or both surfaces of a polylactic acid stretched sheet. As a result, an easily-adhesive polylactic acid stretched sheet capable of improving the printability of the polylactic acid stretched sheet, improving the adhesiveness with a printing ink, and preventing blocking during printing was obtained.
【図１】本発明の実施例における易接着性ポリ乳酸延伸
シートの断面説明図である。FIG. 1 is a cross-sectional explanatory view of an easily adhesive polylactic acid stretched sheet in an example of the present invention.
１ …易接着性ポリ乳酸延伸シート ２ …易接着層 ３ …ポリ乳酸延伸シート 1 ... Easy-adhesive polylactic acid stretched sheet 2 ... Easy adhesion layer 3 ... Polylactic acid stretched sheet
Claims (4)
に、平均分子量５０００〜２５０００の溶剤可溶な熱可
塑性飽和共重合ポリエステル樹脂を５〜５０重量％と、
平均粒子径０．１〜５μｍのフィラーを１０〜５０重量
％と有機溶剤とからなる易接着インキを塗工し、易接着
層を設けたことを特徴とする易接着性ポリ乳酸延伸シー
ト。1. A solvent-soluble thermoplastic saturated copolymerized polyester resin having an average molecular weight of 5,000 to 25,000 is contained on one or both sides of a polylactic acid stretched sheet in an amount of 5 to 50% by weight.
An easily-adhesive polylactic acid stretched sheet, characterized in that an easily-adhesive ink comprising 10 to 50% by weight of a filler having an average particle diameter of 0.1 to 5 μm and an organic solvent is applied to provide an easily adhesive layer.
に添加するフィラーが、二酸化珪素を主成分とする多孔
性合成シリカであることを特徴とする請求項１に記載の
易接着性ポリ乳酸延伸シート。2. The easily-adhesive polylactic acid stretched product according to claim 1, wherein the filler added to the solvent-soluble thermoplastic polyester resin is porous synthetic silica whose main component is silicon dioxide. Sheet.
したことを特徴とする請求項１に記載の易接着性ポリ乳
酸延伸シート。3. The easily adhesive polylactic acid stretched sheet according to claim 1, wherein the easily adhesive layer has a thickness of 0.5 to 5 μm.
理を施したことを特徴とする請求項１に記載の易接着性
ポリ乳酸延伸シート。4. The easily adhesive polylactic acid stretched sheet according to claim 1, wherein the polylactic acid stretched sheet is subjected to corona discharge treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27096696A JP3409609B2 (en) | 1996-10-14 | 1996-10-14 | Easy-adhesion stretched polylactic acid sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27096696A JP3409609B2 (en) | 1996-10-14 | 1996-10-14 | Easy-adhesion stretched polylactic acid sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10120811A JPH10120811A (en) | 1998-05-12 |
| JP3409609B2 true JP3409609B2 (en) | 2003-05-26 |
Family
ID=17493515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27096696A Expired - Fee Related JP3409609B2 (en) | 1996-10-14 | 1996-10-14 | Easy-adhesion stretched polylactic acid sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3409609B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69942600D1 (en) | 1998-07-22 | 2010-09-02 | Toyo Boseki | Aliphatic polyester film and gas barrier film |
| JP4967194B2 (en) * | 2000-01-11 | 2012-07-04 | 東レ株式会社 | Laminated film |
| JP4220770B2 (en) * | 2002-12-11 | 2009-02-04 | 三菱樹脂株式会社 | Molded body having printed layer and method for producing the same |
| KR101093053B1 (en) | 2009-04-27 | 2011-12-13 | 금오공과대학교 산학협력단 | Hydrophobicity process of PLA fabric with nanosilica grafted by UV irradiation |
| CN108659484B (en) * | 2015-10-30 | 2020-04-17 | 天津大学 | Application of silicon dioxide in reduction of melt viscosity in polylactic acid melt processing process |
-
1996
- 1996-10-14 JP JP27096696A patent/JP3409609B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10120811A (en) | 1998-05-12 |
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