JP3376442B2 - Anti-binding agent for cooked rice - Google Patents

Anti-binding agent for cooked rice

Info

Publication number
JP3376442B2
JP3376442B2 JP05743999A JP5743999A JP3376442B2 JP 3376442 B2 JP3376442 B2 JP 3376442B2 JP 05743999 A JP05743999 A JP 05743999A JP 5743999 A JP5743999 A JP 5743999A JP 3376442 B2 JP3376442 B2 JP 3376442B2
Authority
JP
Japan
Prior art keywords
fatty acid
rice
oil
cooked rice
acid ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP05743999A
Other languages
Japanese (ja)
Other versions
JP2000245367A (en
Inventor
▲しん▼吾 中村
康隆 村椿
啓介 楠井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DKS CO. LTD.
Original Assignee
DKS CO. LTD.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DKS CO. LTD. filed Critical DKS CO. LTD.
Priority to JP05743999A priority Critical patent/JP3376442B2/en
Publication of JP2000245367A publication Critical patent/JP2000245367A/en
Application granted granted Critical
Publication of JP3376442B2 publication Critical patent/JP3376442B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は米飯用の結着防止剤
に関し、主として、冷凍、又はチルド流通の米飯の結着
防止剤に関し、詳しくは、ピラフ、チャーハン、混ぜご
飯など、米飯と具を混合したものや、おにぎり、焼きお
にぎり、弁当等に使用される白米飯あるいは味付け米飯
用の結着防止剤(ホグレ性改善剤)に関する。
TECHNICAL FIELD The present invention relates to an anti-binding agent for cooked rice, and mainly to an anti-binding agent for frozen or chilled-distributed cooked rice. More specifically, it relates to cooked rice and ingredients such as pilaf, fried rice and mixed rice. The present invention relates to a mixture, an anti-binder agent (hoggle improving agent) for white rice or seasoned rice used for rice balls, grilled rice balls, bento, etc.

【0002】[0002]

【従来の技術】従来、レトルトや冷凍のピラフ、チャー
ハン、混ぜご飯、チキンライスなどの加工米飯の製造に
おいては、米粒同士が結着するといった問題や油脂が均
一に分散しないなどの問題があった。
2. Description of the Related Art Conventionally, in the production of processed rice such as retort or frozen pilaf, fried rice, mixed rice, and chicken rice, there have been problems such as binding of rice grains and uneven distribution of oils and fats. .

【0003】このような問題点を解決する方法として過
去にいくつか提案された。例えば、1乳化剤(界面活性
剤)を使用する方法(特公昭60−8103号)2油脂
を添加する場合において、O/W型エマルションとする
方法(特開昭60−49754号)3油脂に乳化剤を添
加する方法(特開平3−175940号)が提案され
た。
Several methods have been proposed in the past as a method for solving such problems. For example, a method of using 1 emulsifier (surfactant) (Japanese Patent Publication No. 60-8103), a method of forming an O / W type emulsion when adding fats and oils (JP-A-60-49754), and an emulsifier for fats and oils. Was proposed (Japanese Patent Laid-Open No. 3-175940).

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上記1
の技術が開示された特公昭60−8103号公報には、
米飯のホグレ性を改善する油脂の添加について何ら触れ
られておらず、また乳化剤を使用する上で当該乳化剤を
一旦水に溶解して調製する必要があった。
However, the above-mentioned 1
JP-B-60-8103, which discloses the technology of
No mention was made of addition of fats and oils for improving the hoggle property of cooked rice, and it was necessary to prepare an emulsifier by dissolving it in water once.

【0005】ところで、日本で認可されている乳化剤は
水に難溶なものが多く、水溶液を調製するためには加熱
などの操作が必要なため、製造工程が煩雑であった。ま
た、油脂を加えず乳化剤のみを添加して炊飯した場合、
乳化剤は浸透力が強いため、炊き上がった米飯の表面を
著しく傷つけ、結果的には米飯の艶が全く無くなってし
まうなど実用上の問題点が生じた。従って、艶の保持
(付与)の為には、別途油脂を添加する必要があった。
Many emulsifiers approved in Japan are poorly soluble in water, and operations such as heating are required to prepare an aqueous solution, which complicates the manufacturing process. In addition, when rice is cooked by adding only an emulsifier without adding fats and oils,
Since the emulsifier has a strong penetrating power, the surface of the cooked cooked rice was markedly damaged, resulting in practical problems such as the gloss of the cooked rice being completely lost. Therefore, in order to retain (apply) gloss, it is necessary to add oil and fat separately.

【0006】2の方法のようにエマルションとする場
合、当該エマルションの製造工程が別途必要になるとい
うばかりか、エマルション自体の経時的な安定性や腐敗
の防止など、解決しなければならない問題点が多々あっ
た。
In the case of forming an emulsion as in the method 2), not only a separate manufacturing step for the emulsion is required, but also problems such as stability over time of the emulsion itself and prevention of spoilage must be solved. There were many.

【0007】3の方法のように油脂に乳化剤を添加する
場合、用いる乳化剤は油溶性のものが主体となる。つま
り、HLB値の低い乳化剤である。ところが炊飯に油脂
を用いる場合、水に油脂を分散させるため、低HLB値
の乳化剤では、O/W型乳化力が不足する。したがっ
て、油脂に乳化剤を添加する方法では、油脂がまんべん
なく米飯にいき渡らず、期待した効果が得られなかっ
た。
When an emulsifier is added to fats and oils as in the method of 3, the emulsifier used is mainly oil-soluble. That is, it is an emulsifier having a low HLB value. However, when fats and oils are used for cooking rice, since the fats and oils are dispersed in water, an emulsifier having a low HLB value lacks the O / W emulsifying power. Therefore, the method of adding an emulsifier to fats and oils did not spread the fats and oils evenly to the cooked rice, and the expected effect was not obtained.

【0008】このように、従来の方法のいずれにおいて
も、米飯のホグレ性について充分に満足のいく結果が得
られてはおらず、これにより食感についても悪いものと
なった。
[0008] As described above, none of the conventional methods has obtained sufficiently satisfactory results regarding the hoggle property of cooked rice, which results in poor texture.

【0009】すなわち、冷凍米飯の製造において、炊き
上げた後、冷却工程により米飯を冷却するが、米飯同士
の結着により、団子状になった部分の冷却が不十分とな
り、塊のまま冷凍されてしまう。できた塊部分は、解凍
されても解れることが無く、見た目(外観性)も食感も
悪いものとなってしまった。あるいは、米飯を容器に充
填する場合に、米飯のホグレが悪いと容器に定量充填が
できないという問題があった。また、米飯に混ぜご飯の
具(又は液)をかけて食する場合に、米飯のホグレが悪
いと、具や液との混合が悪く、見た目や食感が悪いもの
となった。
That is, in the production of frozen cooked rice, the cooked rice is cooled in a cooling step after it is cooked, but due to the binding of the cooked rice, the dumpling-shaped portion is insufficiently cooled and is frozen as a lump. Will end up. The formed lump portion was not untangled even when thawed, and had a bad appearance (appearance) and texture. Alternatively, when the cooked rice is filled in the container, there is a problem that if the hog of the cooked rice is bad, the container cannot be quantitatively filled. Further, when the rice (or liquid) is mixed with the cooked rice and eaten, if the hogle of the cooked rice is bad, the mixture of the rice and the liquid is poor, and the appearance and texture are bad.

【0010】油脂を米飯に混合することにより、上記の
問題はある程度改善されるが、米飯の表面は親水性であ
り、親油性の油脂を米飯に均一に混合させることは非常
に困難であり、また米飯同士の細かい隙間に入り込むこ
ともできない。多量の油脂を投入してこの問題に対処す
ることもできるが、結果的には油っぽい食感となってし
まう。油脂を乳化することによりその改善は可能である
が、事前に油脂を乳化し、米飯に添加することは煩雑で
あり、一般的には採用されにくい。
Although the above problems can be solved to some extent by mixing the oil and fat with the cooked rice, the surface of the cooked rice is hydrophilic, and it is very difficult to uniformly mix the lipophilic oil and fat with the cooked rice. Also, they cannot enter the small gaps between cooked rice. It is possible to add a large amount of oil and fat to deal with this problem, but as a result, an oily texture is obtained. This can be improved by emulsifying the oil or fat, but it is complicated to emulsify the oil or fat in advance and add it to the cooked rice, and it is generally difficult to adopt.

【0011】そこで、本発明者らは上記の実情を鑑み鋭
意検討を行った結果、乳化液を噴霧乾燥することによ
り、すなわちエマルションの形態を保ったまま乾燥する
方法を採れば、得られる噴霧乾燥品は加熱溶解の工程を
必要とすることなく低温の水にも溶解し得、容易に乳化
液が得られることを発見した。しかし、ここでも新たな
問題が発生した。すなわち、従来から提案されている粉
末油脂の製造条件において、噴霧乾燥効率を良くするた
めにカゼインナトリウム等の蛋白質が一般に使用される
が、肝心の米飯のホグレ性に対しては悪影響を及ぼし、
添加効果が不十分であった。また、粉末油脂を水に分散
させた液の平均粒径は非常に小さいものが得られるが、
小さすぎてもホグレ性に対する効果が小さかった。
Therefore, as a result of intensive studies made by the present inventors in view of the above-mentioned circumstances, as a result of spray drying an emulsion, that is, by adopting a method of drying while maintaining the form of the emulsion, the spray drying obtained can be obtained. It was discovered that the product can be dissolved in low temperature water without requiring a heating dissolution step, and an emulsion can be easily obtained. But again, new problems arose. That is, in the production conditions of powdered fats and oils conventionally proposed, proteins such as sodium caseinate are generally used in order to improve the spray drying efficiency, but they have an adverse effect on the hogle property of cooked rice, which is important.
The effect of addition was insufficient. Further, although the average particle size of the liquid obtained by dispersing the powdered fat and oil in water is very small,
Even if it was too small, the effect on the hogle resistance was small.

【0012】さらに、油脂を使用時に添加する方法など
では、乳化が不十分なために、乳化液の平均粒径が大き
いなどの問題があり、このため油脂の米飯粒の間への浸
透が困難となり、上記と同様、ホグレ性への効果が不十
分であった。
Further, the method of adding fats and oils at the time of use has a problem that the average particle size of the emulsion is large due to insufficient emulsification, and therefore it is difficult for the fats and oils to penetrate into the cooked rice grains. Therefore, as in the above case, the effect on hog resistance was insufficient.

【0013】そして、さらなる検討を重ねた結果、使用
時に水に分散させた時の液(再生液)の粒度分布のメデ
ィアン径が5〜120μmの範囲にある場合に限り、米
飯のホグレ性に対して効果的に作用することを見い出
し、そして本発明に至った。
As a result of further study, the hogle property of cooked rice was only obtained when the median diameter of the particle size distribution of the liquid (regenerated liquid) when dispersed in water at the time of use was in the range of 5 to 120 μm. The present invention has been found to work effectively, and has led to the present invention.

【0014】[発明の目的]本発明の目的は、何ら煩雑
な操作を行わずに米飯のホグレ性の改良を行わしめる米
飯用の結着防止剤を提供するところにある。
[Object of the Invention] An object of the present invention is to provide an anti-binder agent for cooked rice which can improve the hogle resistance of cooked rice without any complicated operations.

【0015】[0015]

【課題を解決するための手段】本発明の米飯用の結着防
止剤は、(A)食用油脂及び/又は油溶性乳化剤、
(B)HLB10以上のショ糖脂肪酸エステル、及び
(C)澱粉分解度(DE)が5〜80であるデキストリ
ンを含有する水中油型乳化液を噴霧乾燥して得られ、か
つこの乾燥物を水に乳化分散して得られる再生液の粒度
分布のメディアン径が5〜120μmであることを特徴
とする。
The binding inhibitor for cooked rice of the present invention comprises (A) edible oil and / or oil-soluble emulsifier,
It is obtained by spray-drying an oil-in-water emulsion containing (B) a sucrose fatty acid ester having an HLB of 10 or more , and (C) a dextrin having a starch decomposition degree (DE) of 5 to 80, and the dried product is water. The regenerated liquid obtained by emulsifying and dispersing is characterized in that the median diameter of the particle size distribution is 5 to 120 μm.

【0016】[0016]

【発明の実施の形態】(A)成分[食用油脂、油溶性乳
化剤] 本発明の(A)成分に使用される食用油脂は、たとえ
ば、大豆油、菜種油、サフラワー油、トウモロコシ油、
パーム油、パーム核油、ヤシ油などの植物油、牛脂、豚
脂、魚油などの動物油脂又はそれらの部分水素添加又は
完全水素添加したものが挙げられる。これらは単独で使
用してもよいし、2種以上を併用することもできる。
BEST MODE FOR CARRYING OUT THE INVENTION Component (A) [Edible oil and fat, oil-soluble milk
Agent] The edible oil / fat used in the component (A) of the present invention includes, for example, soybean oil, rapeseed oil, safflower oil, corn oil,
Examples thereof include vegetable oils such as palm oil, palm kernel oil, and palm oil, animal oils and fats such as beef tallow, lard, and fish oil, or those partially hydrogenated or completely hydrogenated. These may be used alone or in combination of two or more.

【0017】また油溶性乳化剤としては、親水基がグリ
セリン、ポリグリセリン、プロピレングリコール、ソル
ビタン、ショ糖などの多価アルコール類又はリン脂質で
あり、脂肪酸残基の炭素数が8〜22の飽和又は不飽和
のものが使用でき、具体的には、グリセリン脂肪酸エス
テル、プロピレングリコール脂肪酸エステル、レシチ
ン、HLB8未満のポリグリセリン脂肪酸エステルまた
はHLB5未満のソルビタン脂肪酸エステルが挙げられ
る。
The oil-soluble emulsifier is a polyhydric alcohol or phospholipid having a hydrophilic group such as glycerin, polyglycerin, propylene glycol, sorbitan and sucrose, and a saturated or saturated fatty acid residue having 8 to 22 carbon atoms. Unsaturated ones can be used, and specific examples thereof include glycerin fatty acid ester, propylene glycol fatty acid ester, lecithin, polyglycerin fatty acid ester less than HLB8, and sorbitan fatty acid ester less than HLB5.

【0018】以下、グリセリン脂肪酸エステル、ポリグ
リセリン脂肪酸エステル、ソルビタン脂肪酸エステル、
及びレシチンに関し、改めて説明を加える。
Hereinafter, glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester,
And lecithin will be explained again.

【0019】グリセリン脂肪酸エステル(モノグリセリ
ド)は、グリセリンと脂肪酸のモノエステルであり、脂
肪酸は炭素数が8〜22の飽和脂肪酸または不飽和脂肪
酸あるいはこれらの混合物が挙げられる。
The glycerin fatty acid ester (monoglyceride) is a monoester of glycerin and a fatty acid, and the fatty acid may be a saturated fatty acid having 8 to 22 carbon atoms, an unsaturated fatty acid, or a mixture thereof.

【0020】ポリグリセリン脂肪酸エステルは、平均重
合度が3〜10のポリグリセリンに脂肪酸がエステル結
合したものである。構成する脂肪酸は炭素数が8〜22
の飽和脂肪酸または不飽和脂肪酸あるいはこれらの混合
物が挙げられる。
The polyglycerin fatty acid ester is a polyglycerin having an average degree of polymerization of 3 to 10 in which a fatty acid is ester-bonded. The constituent fatty acids have 8 to 22 carbon atoms.
Saturated fatty acids or unsaturated fatty acids or mixtures thereof.

【0021】ソルビタン脂肪酸エステルは、ソルビタン
やソルビットまたはソルビドと脂肪酸がエステル結合し
たものである。構成する脂肪酸は炭素数が8〜22の飽
和脂肪酸または不飽和脂肪酸あるいはこれらの混合物が
挙げられる。
The sorbitan fatty acid ester is an ester bond of sorbitan, sorbit or sorbide with a fatty acid. Examples of the constituent fatty acids include saturated fatty acids having 8 to 22 carbon atoms, unsaturated fatty acids, and mixtures thereof.

【0022】レシチンとは、ホスファチジルコリン、ホ
スファチジルエタノールアミン、ホスファチジルイノシ
トール、ホスファチジン酸、ホスファチジルセリンなど
のリン脂質の混合物である。レシチンには、油脂を含ん
だクルードレシチンや溶剤により精製した高純度レシチ
ン等があるがいずれも用いることができる。
Lecithin is a mixture of phospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidic acid and phosphatidylserine. Examples of lecithin include crude lecithin containing oil and fat, high-purity lecithin purified by a solvent, and the like, and any of them can be used.

【0023】(B)成分[親水性乳化剤] (B)成分として使用される親水性乳化剤は、HLB1
0以上のショ糖脂肪酸エステルである。脂肪酸残基は、
C(炭素数、以下同様)12〜C22の飽和又は不飽和
のものが使用できる。味の点からC14〜C22の飽和
脂肪酸がより好ましい。なお、その他の親水性乳化剤を
含んでも構わない。具体的には、親水基がグリセリン、
ポリグリセリン、ソルビタンなどの多価アルコール類又
はリン脂質であり、具体的には有機酸モノグリセリド、
酵素処理レシチン、酵素分解レシチン、HLB5以上の
ソルビタン脂肪酸エステルまたはHLB8以上のポリグ
リセリン脂肪酸エステルが挙げられる。
Component (B) [hydrophilic emulsifier] The hydrophilic emulsifier used as component (B) is HLB1
It is 0 or more sucrose fatty acid ester. The fatty acid residue is
A saturated or unsaturated C (carbon number, the same applies below) 12 to C22 can be used. From the viewpoint of taste, C14 to C22 saturated fatty acids are more preferable. In addition, other hydrophilic emulsifier
You may include it. Specifically, the hydrophilic group is glycerin,
Polyglycerol a Sorubita emissions of any polyhydric alcohols or phospholipids, particularly organic acid monoglyceride,
Enzyme treatment lecithin, enzymatically decomposed lecithin emissions include sorbitan fatty acid esters or HLB8 more polyglycerol fatty acid esters or H LB5.

【0024】有機酸モノグリセリドは、前述のモノグリ
セリドにさらに有機酸がエステル結合したものであり、
乳酸モノグリセリド、クエン酸モノグリセリド、コハク
酸モノグリセリド、ジアセチル酒石酸モノグリセリドな
どが挙げられる。
The organic acid monoglyceride is the above monoglyceride in which an organic acid is further ester-bonded.
Lactic acid monoglyceride, citric acid monoglyceride, succinic acid monoglyceride, diacetyl tartaric acid monoglyceride and the like can be mentioned.

【0025】(C)成分[澱粉分解物、デキストリン] 次に(C)成分として使用される澱粉分解物とは、澱粉
を酸又は酵素で加水分解したものであって、具体的には
デキストリンが挙げられる。分解物の分解度(DE、以
下同様)は5未満では溶解性が悪い為に所定の機能が発
揮できないため5以上であることが好ましく、5〜80
の必要がある。この分解度はソモギ法、ベルトラン法に
より定量される還元糖%として測定される。還元糖を硫
酸銅のアルカリ性溶液とともに加熱すると、銅(II)
イオンの一部が糖により還元されて銅(I)となり、同
時に加えておいたヨウ素液中のKIは還元されてI2と
なる。このI2をチオ硫酸ナトリウム溶液で滴定し、糖
量を計算する配合割合 前記(A)成分、(B)成分、及び(C)成分の配合比
率(%)は、重量比で5〜60/3〜50/92〜10
であることが好ましく、10〜45/5〜45/85〜
15であることがより好ましい。(A)成分が5%未満
では、効果が充分期待できず、60%を超えると再生液
の粒度分布のメディアン径を満たすことができない。
(B)成分が3%未満では再生液の粒度分布のメディア
ン径を満たすことができなく、50%を超えるとそれ以
上の効果が期待できない。(C)成分が92%を超える
と有効成分の含有量が少ないために添加量が増加し、効
率的でなく、10%未満では被膜形成が不十分なため、
乾燥物の溶解性が悪くなり、充分な効果が期待できな
い。
Component (C) [Decomposed Starch, Dextrin] The decomposed starch used as the component (C) is a product obtained by hydrolyzing starch with an acid or an enzyme. Specifically, dextrin is Can be mentioned. If the degree of decomposition (DE, the same applies below) of the decomposed product is less than 5, the predetermined function cannot be exerted due to poor solubility, and therefore it is preferably 5 or more.
Need of This degree of decomposition is measured as% reducing sugar determined by the Somogi method and the Bertrand method. When reducing sugars are heated with an alkaline solution of copper sulfate, copper (II)
A part of the ions is reduced by sugar to copper (I), and the KI in the iodine solution added at the same time is reduced to I2. Titrated this I2 with sodium thiosulfate solution, the mixing ratio the calculating the amount of sugar (A), (B), and component (C) of the blending ratio (%) is 5 to 60/3 at a weight ratio of ~ 50 / 92-10
Is preferred, and 10-45 / 5-45 / 85-
It is more preferably 15. If the content of the component (A) is less than 5%, the effect cannot be expected sufficiently, and if it exceeds 60%, the median diameter of the particle size distribution of the regenerated liquid cannot be satisfied.
If the component (B) is less than 3%, the median diameter of the particle size distribution of the regenerant cannot be satisfied, and if it exceeds 50%, no further effect can be expected. If the content of the component (C) exceeds 92%, the amount of the active ingredient added is small, so the amount added increases, and if the content is less than 10%, the film formation is insufficient.
Solubility of the dried product deteriorates, and a sufficient effect cannot be expected.

【0026】調製方法、その他 上記(B)成分および(C)成分を水に加熱溶解し、撹
拌しながら(A)成分を溶解又はそのまま滴下添加し、
ホモミキサー又はホモディスパー等により乳化させる。
更に必要に応じて圧力式ホモジナイザーにより均質化
し、水中油型乳化液を調製し、これを公知の方法により
噴霧乾燥を行い、粉末状または顆粒状の結着防止剤を得
る。
Preparation Method and Others The above-mentioned components (B) and (C) are dissolved in water by heating, and the component (A) is dissolved or added dropwise while stirring.
Emulsify with a homomixer or homodisper.
Further, if necessary, the mixture is homogenized with a pressure homogenizer to prepare an oil-in-water emulsion, which is spray-dried by a known method to obtain a powdery or granular anti-binding agent.

【0027】本発明の結着防止剤は、水に乳化分散した
再生液の粒度分布のメディアン径が5〜120μmであ
ることを必要とする。このメディアン径は島津製作所製
SALD−2000や堀場製作所製CAPA−300等
の粒度分布測定装置により測定する。メディアン径が5
μm未満では粒子が小さくなり過ぎ、必要な性能が発揮
されない。また120μmを超えると粒子が大きくなり
過ぎ、米表面に油脂が浮き出るため、商品価値が低下す
る。
The anti-binding agent of the present invention requires that the regenerated liquid emulsified and dispersed in water has a median diameter of 5 to 120 μm in the particle size distribution. This median diameter is measured with a particle size distribution measuring device such as SALD-2000 manufactured by Shimadzu or CAPA-300 manufactured by Horiba. Median diameter is 5
If it is less than μm, the particles become too small and the required performance cannot be exhibited. Further, if it exceeds 120 μm, the particles become too large and oils and fats are raised on the surface of rice, so that the commercial value is lowered.

【0028】本発明の結着防止剤が対象とする米飯食品
は、冷凍、又はチルド流通の米飯に関するものであっ
て、具体的には、ピラフ、チャーハン、混ぜご飯、チキ
ンライスなど、米飯と具を混合したもの、あるいは、お
にぎり、焼きおにぎり、弁当等に使用される白米飯また
は味付け米飯である。
The cooked rice food targeted by the binding preventive agent of the present invention relates to frozen or chilled cooked rice, and specifically, pilaf, fried rice, mixed rice, chicken rice and the like It is a mixed rice or white rice or seasoned rice used for rice balls, grilled rice balls, bento, etc.

【0029】本発明の結着防止剤の米飯への添加量は、
対原料米0.01〜10重量%が好ましく、0.1〜3
重量%がより好ましい。0.01重量%未満では効果が
充分でなく、10重量%を超える場合ではそれ以上の効
果が期待できないため、経済的不利を招く。
The amount of the binding inhibitor of the present invention added to cooked rice is
0.01 to 10% by weight of raw rice is preferable, and 0.1 to 3
Weight percent is more preferred. If the amount is less than 0.01% by weight, the effect is not sufficient, and if the amount exceeds 10% by weight, no further effect can be expected, resulting in an economic disadvantage.

【0030】[作用] 乳化液を所定の条件において噴霧乾燥したものは、水に
溶解して得られた再生液においても乳化状態を保持して
おり、外側を親水基とした油脂乳化物となるため、親水
性である米飯表面に対して乳化物が微細に配向できる。
その結果、米飯粒同士の間に油脂が緻密に分散すること
になり、これにより米飯粒同士の結着が防止されて米飯
のホグレ性が改善される。
[Operation] The emulsion liquid spray-dried under predetermined conditions retains the emulsified state even in the regenerated liquid obtained by dissolving in water, and becomes an oil and fat emulsion having the hydrophilic group on the outside. Therefore, the emulsion can be finely oriented with respect to the surface of the cooked rice which is hydrophilic.
As a result, the oil and fat are densely dispersed between the cooked rice grains, which prevents the cooked rice grains from binding to each other and improves the hogle resistance of the cooked rice.

【0031】しかし、その時の油脂粒子の大きさが、期
待できる効果に影響する大きな要因であり、組織中に適
度に分散できることにより、その効果が著しく増大す
る。従って、通常の粉末油脂のように蛋白質を多量に含
み、再生液の平均粒子径が小さすぎてもその効果が期待
できない。食品に添加した時の油脂、又は油溶性乳化剤
の粒子径が適度な大きさであることが必須条件となる。
However, the size of oil particles at that time is a major factor that influences the expected effect, and the effect can be remarkably increased by being able to disperse the particles in the tissue appropriately. Therefore, even when the regenerated liquid contains a large amount of protein like ordinary powdered fats and oils and the average particle diameter of the regenerated liquid is too small, the effect cannot be expected. It is an essential condition that the particle size of the oil or fat or the oil-soluble emulsifier when added to food is an appropriate size.

【0032】[0032]

【実施例】以下、実施例を挙げて本発明をさらに具体的
に説明するが、本発明は、これらの実施例に限定される
ものではない。なお、実施例、比較例、(比較)参考例
中、部及び%は特に断らない限り重量基準である。
The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. In Examples, Comparative Examples , and (Comparative) Reference Examples , parts and% are by weight unless otherwise specified.

【0033】実施例1 HLB15のショ糖脂肪酸エステル17.5kgおよび
デキストリン(DE=20)30kgを水道水75kg
に室温分散後、70℃まで加熱撹拌し、完全溶解させ
た。その後、TKホモディスパー(特殊機化工業製)で
撹拌しながら、菜種油24kgにステアリン酸モノグリ
セリド2.5kgを70℃で溶解させたものを滴下乳化
し、圧力式ホモジナイザー(圧力=15MPa)で均質
化後、噴霧乾燥により乾燥し、これにより本発明の粉末
状の結着防止剤を得た(噴霧乾燥条件:入り口温度=1
50℃、アトマイザーの回転速度=21000rp
m)。
Example 1 17.5 kg of sucrose fatty acid ester of HLB15 and 30 kg of dextrin (DE = 20) were added to 75 kg of tap water.
After room temperature dispersion, the mixture was heated to 70 ° C. with stirring to completely dissolve it. Then, stirring with TK Homo Disper (manufactured by Tokushu Kika Kogyo), 2.5 kg of stearic acid monoglyceride was dissolved in 24 kg of rapeseed oil at 70 ° C, and the mixture was emulsified dropwise and homogenized with a pressure homogenizer (pressure = 15 MPa). After that, it was dried by spray drying, whereby a powdery binding inhibitor of the present invention was obtained (spray drying conditions: inlet temperature = 1
50 ° C, atomizer rotation speed = 21000 rp
m).

【0034】得られた結着防止剤10gを水990gに
分散させ、粒度分布とメディアン径を測定した。
10 g of the obtained binding inhibitor was dispersed in 990 g of water, and the particle size distribution and median diameter were measured.

【0035】次に米6kgを水洗し、2時間漬せきした
後、水8.4kgを加えた。のち、結着防止剤60gを
軽く分散させて自動炊飯器で炊飯した。
Next, 6 kg of rice was washed with water and soaked for 2 hours, and then 8.4 kg of water was added. After that, 60 g of the binding inhibitor was lightly dispersed and cooked with an automatic rice cooker.

【0036】一方、えび、にんじん、玉ねぎ、ピーマン
を炒め、これにより作成した具に前記炊飯米を加え、更
に炒めた。冷風で粗熱を取った後、急速冷凍にかけ、2
00gずつに分けて密封した後、−30℃で冷凍保存し
た。2週間保存後、電子レンジで解凍し、食味試験に供
した。また、炊飯米の一部をトレーに移し、室温まで冷
却後、120gを目開き26mmJIS篩でふるい、通
過した重量を120gで除し、ホグレ率として表示し
た。
On the other hand, prawns, carrots, onions and bell peppers were fried, and the cooked rice was added to the ingredients thus prepared and further fried. After taking rough heat with cold air, it is subjected to quick freezing, 2
The mixture was divided into 00 g and sealed, and then stored frozen at -30 ° C. After storing for 2 weeks, it was thawed in a microwave oven and subjected to a taste test. Further, a part of the cooked rice was transferred to a tray and cooled to room temperature, then 120 g was sieved with a mesh 26 mm JIS sieve, the passed weight was divided by 120 g, and the result was shown as a hogle ratio.

【0037】実施例2 HLB11のショ糖脂肪酸エステル11.5kgとHL
B11.6のポリグリセリン脂肪酸エステル(SYグリ
スターMS−500)6.5kg、HLB7のソルビタ
ン脂肪酸エステル(ソルゲン−FS−700)1.2k
g、デキストリン(DE=10)10kg、粉末ソルビ
ット5kgを水道水75kgに室温分散後、70℃まで
加熱撹拌し、完全溶解させた。その後、TKホモディス
パー(特殊機化工業製)で撹拌しながら、コーン油14
kgにレシチン4kgを70℃で溶解させたものを滴下
乳化し、圧力式ホモジナイザー(圧力=15MPa)で
均質化後、噴霧乾燥により乾燥し、これにより本発明の
粉末状の結着防止剤を得た(噴霧乾燥条件:入り口温度
=150℃、アトマイザーの回転速度=21000rp
m)。
Example 2 11.5 kg of sucrose fatty acid ester of HLB11 and HL
B11.6 polyglycerin fatty acid ester (SY Glister MS-500) 6.5 kg, HLB7 sorbitan fatty acid ester (Solgen-FS-700) 1.2 k
g, 10 kg of dextrin (DE = 10), and 5 kg of powdered sorbit were dispersed in 75 kg of tap water at room temperature, and then heated and stirred to 70 ° C. to completely dissolve them. Then, while stirring with TK Homo Disper (made by Tokushu Kika Kogyo), corn oil 14
4 kg of lecithin dissolved in 70 kg at 70 ° C. was added dropwise to emulsify, homogenized with a pressure homogenizer (pressure = 15 MPa), and then dried by spray drying, whereby a powdery anti-binding agent of the present invention was obtained. (Spray drying conditions: inlet temperature = 150 ° C, atomizer rotation speed = 21000 rp
m).

【0038】次に米6kgを水洗し、2時間漬せきした
後、水8.6kgを加えた。のち、結着防止剤12gを
軽く分散させて自動炊飯器で炊飯した。炊飯米を軽くほ
ぐして粗熱を取った後、弁当容器に充填した。2時間室
温放置後、食味試験に供した。また、実施例1と同様に
メディアン径とホグレ率を測定した。
Next, 6 kg of rice was washed with water and soaked for 2 hours, and then 8.6 kg of water was added. After that, 12 g of the binding inhibitor was lightly dispersed and cooked with an automatic rice cooker. The cooked rice was lightly loosened to remove coarse heat, and then filled into a bento container. After left at room temperature for 2 hours, it was subjected to a taste test. In addition, the median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0039】実施例3 HLB13のショ糖脂肪酸エステル3.6kg、クエン
酸モノグリセリド(ポエムK−30)8.6kg、デキ
ストリン(DE=40)15kgを水道水75kgに室
温分散後、70℃まで加熱撹拌し、完全溶解させた。そ
の後、TKホモディスパー(特殊機化工業製)で撹拌し
ながら、パーム油4kgにHLB5.5のポリグリセリ
ン脂肪酸エステル(ポエムJ2681)1kgを70℃
で溶解させたものを滴下乳化し、圧力式ホモジナイザー
(圧力=15MPa)で均質化後、噴霧乾燥により乾燥
し、これにより本発明の粉末状の結着防止剤を得た(噴
霧乾燥条件:入り口温度=150℃、アトマイザーの回
転速度=21000rpm)。
Example 3 3.6 kg of sucrose fatty acid ester of HLB13, 8.6 kg of citric acid monoglyceride (Poem K-30), and 15 kg of dextrin (DE = 40) were dispersed in 75 kg of tap water at room temperature and then heated to 70 ° C. with stirring. And completely dissolved. After that, while stirring with TK Homo Disper (manufactured by Tokushu Kika Kogyo), 1 kg of polyglycerin fatty acid ester of HLB 5.5 (Poem J2681) was added to 4 kg of palm oil at 70 ° C.
What was dissolved in the above was dropped and emulsified, homogenized by a pressure homogenizer (pressure = 15 MPa), and then dried by spray drying to obtain a powdery binding inhibitor of the present invention (spray drying condition: inlet Temperature = 150 ° C., atomizer rotation speed = 21000 rpm).

【0040】次に米6kgを水洗し、2時間漬せきした
後、薄口醤油で味付けした水8.6kgを加え、結着防
止剤12gを軽く分散させた後、自動炊飯器で炊飯し
た。炊飯米を軽くほぐし、粗熱を取った後、成形機でお
にぎりを成形し、焼き色を付けた後包装した。2時間室
温放置後、食味試験に供した。また、実施例1と同様に
メディアン径とホグレ率を測定した。
Next, 6 kg of rice was washed with water and soaked for 2 hours, then 8.6 kg of water seasoned with thin soy sauce was added, 12 g of the binding inhibitor was lightly dispersed, and then cooked with an automatic rice cooker. The cooked rice was lightly loosened to remove coarse heat, and then a rice ball was molded with a molding machine, colored with a brown color, and then packaged. After left at room temperature for 2 hours, it was subjected to a taste test. In addition, the median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0041】実施例4 HLB11のショ糖脂肪酸エステル9.2kg、酵素処
理レシチン(エルマイザーA)1.6kg、デキストリ
ン(DE=10)10kg、ショ糖3kgを水道水75
kgに室温分散後、70℃まで加熱撹拌し、完全溶解さ
せた。その後、TKホモディスパー(特殊機化工業製)
で撹拌しながら、大豆硬化油(融点=34℃)15.4
kgを70℃に加熱したものを滴下乳化し、圧力式ホモ
ジナイザー(圧力=15MPa)で均質化後、噴霧乾燥
により乾燥し、これにより本発明の粉末状の結着防止剤
を得た(噴霧乾燥条件:入り口温度=150℃、アトマ
イザーの回転速度=21000rpm)。
Example 4 HLB11 sucrose fatty acid ester 9.2 kg, enzyme-treated lecithin (Elmizer A) 1.6 kg, dextrin (DE = 10) 10 kg, sucrose 3 kg, tap water 75.
After being dispersed in kg at room temperature, the mixture was heated to 70 ° C. with stirring to completely dissolve it. After that, TK Homo Disper (made by Tokushu Kika Kogyo)
Stirred oil, soybean hydrogenated oil (melting point = 34 ° C.) 15.4
What was heated to 70 ° C. was dropped and emulsified, homogenized by a pressure homogenizer (pressure = 15 MPa), and then dried by spray drying, whereby a powdery binding inhibitor of the present invention was obtained (spray drying Conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000 rpm).

【0042】米6kgを水洗し、2時間漬せきした後、
水8.6kgを加え、結着防止剤48gを軽く分散させ
た後、自動炊飯器で炊飯した。炊飯米を軽くほぐし、粗
熱を取った後、カップに充填し、急速冷凍した。別途作
成したとんかつ、及びどんぶり用調味液をパックしたも
のを同梱し、シールした。その後、−30℃で2週間保
存し、電子レンジで解凍したものを、米飯の上にとんか
つを乗せ、調味液を上からかけたものを食味試験に供し
た。また、炊飯米のみについて、実施例1と同様にメデ
ィアン径とホグレ率を測定した。
After washing 6 kg of rice with water and soaking it for 2 hours,
After adding 8.6 kg of water and lightly dispersing 48 g of the binding inhibitor, rice was cooked with an automatic rice cooker. The cooked rice was lightly loosened to remove coarse heat, then filled in a cup and rapidly frozen. A pork cutlet and a bowl of seasoning liquid prepared separately were packaged and sealed. Then, it was stored at -30 ° C for 2 weeks, thawed in a microwave oven, placed a tonkatsu on top of cooked rice, and sprinkled with a seasoning solution was subjected to a taste test. In addition, only for cooked rice, the median diameter and the hogle ratio were measured as in Example 1.

【0043】参考例1 HLB=11のショ糖脂肪酸エステル6.5kg、HL
B=7のソルビタン脂肪酸エステル6.5kg、ソルビ
トール70%液25kg、ショ糖5kgを水道水75k
gに室温分散後、70℃まで加熱撹拌し、完全溶解させ
た。その後、TKホモディスパー(特殊機化工業製)で
撹拌しながら、菜種油7.5kgを70℃に加熱したも
のを滴下乳化し、圧力式ホモジナイザー(圧力=15M
Pa)で均質化後、噴霧乾燥により乾燥し、これにより
本発明の結着防止剤を得た(噴霧乾燥条件:入り口温度
=150℃、アトマイザーの回転速度=21000rp
m)。
Reference Example 1 6.5 kg of sucrose fatty acid ester of HLB = 11, HL
B = 7 sorbitan fatty acid ester 6.5 kg, sorbitol 70% liquid 25 kg, sucrose 5 kg tap water 75 k
After being dispersed at room temperature in g, the mixture was heated to 70 ° C. with stirring to completely dissolve it. After that, 7.5 kg of rapeseed oil heated to 70 ° C. was added dropwise to the emulsion while stirring with TK Homo Disper (made by Tokushu Kika Kogyo), and a pressure homogenizer (pressure = 15 M
After homogenizing at (Pa), it was dried by spray drying to obtain the binding inhibitor of the present invention (spray drying conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000 rp).
m).

【0044】次に米6kgを水洗し、2時間漬せきした
後、水8.4kgを加えた。その後、結着防止剤60g
を軽く分散させた後、自動炊飯器で炊飯した。
Next, 6 kg of rice was washed with water and soaked for 2 hours, and then 8.4 kg of water was added. After that, 60g of anti-binding agent
After lightly dispersing, rice was cooked with an automatic rice cooker.

【0045】一方、えび、にんじん、玉ねぎ、グリンピ
ースを炒め、これにより作成した具に前記炊飯米を加
え、更に炒め、玉子を加えてチャーハンを作成した。冷
風で粗熱を取った後、急速冷凍にかけ、200gずつに
分けて密封した後、−30℃で冷凍保存した。2週間保
存後、電子レンジで解凍し、食味試験に供した。また、
実施例1と同様にメディアン径とホグレ率を測定した。
On the other hand, prawns, carrots, onions and green peas were fried, and the cooked rice was added to the ingredients thus prepared, further fried and eggs were added to prepare fried rice. After taking crude heat with cold air, it was subjected to quick freezing, sealed in 200 g portions, and stored frozen at -30 ° C. After storing for 2 weeks, it was thawed in a microwave oven and subjected to a taste test. Also,
The median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0046】実施例1〜4および参考例1における
(A)〜(C)成分の種類と配合割合を、再度、下記の
[表1]にて表わす。
The types and blending ratios of the components (A) to (C) in Examples 1 to 4 and Reference Example 1 are again shown in [Table 1] below.

【0047】[0047]

【表1】 [Table 1]

【0048】比較例1 HLB15のショ糖脂肪酸エステル0.2kg、カゼイ
ンナトリウム2.0kg、デキストリン(DE=20)
30kgを水道水75kgに室温分散後、70℃まで加
熱撹拌し、完全溶解させた。その後、TKホモディスパ
ー(特殊機化工業製)で撹拌しながら、大豆油25kg
を70℃に加熱したものを滴下乳化し、圧力式ホモジナ
イザー(圧力=15MPa)で均質化後、噴霧乾燥によ
り乾燥し、これにより比較用の結着防止剤を得た(噴霧
乾燥条件:入り口温度=150℃、アトマイザーの回転
速度=21000rpm)。
Comparative Example 1 HLB15 sucrose fatty acid ester 0.2 kg, sodium caseinate 2.0 kg, dextrin (DE = 20)
After 30 kg was dispersed in 75 kg tap water at room temperature, the mixture was heated to 70 ° C. with stirring to completely dissolve it. Then, while stirring with TK Homo Disper (made by Tokushu Kika Kogyo), soybean oil 25 kg
Was heated to 70 ° C., and the mixture was added by drop emulsification, homogenized by a pressure homogenizer (pressure = 15 MPa), and then dried by spray drying to obtain a binding inhibitor for comparison (spray drying conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000 rpm).

【0049】結着防止剤が比較例1で得られた結着防止
剤である点を除いて、実施例1と同様に冷凍ピラフを作
製した。また、実施例1と同様にメディアン径とホグレ
率を測定した。
A frozen pilaf was prepared in the same manner as in Example 1 except that the anti-binding agent was the anti-binding agent obtained in Comparative Example 1. In addition, the median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0050】比較例2 HLB7のソルビタン脂肪酸エステル2.5kg、デキ
ストリン(DE=10)10kg、粉末ソルビット5k
gを水道水75kgに室温分散後、70℃まで加熱撹拌
し、完全溶解させた後、70℃まで加熱撹拌し、完全溶
解させた。その後、圧力式ホモジナイザー(圧力=15
MPa)で均質化後、噴霧乾燥により乾燥し、これによ
り比較用の結着防止剤を得た(噴霧乾燥条件:入り口温
度=150℃、アトマイザーの回転速度=21000r
pm)。
Comparative Example 2 2.5 kg sorbitan fatty acid ester of HLB7, 10 kg dextrin (DE = 10), 5 k powder sorbit
g was dispersed in 75 kg of tap water at room temperature, heated and stirred to 70 ° C. to completely dissolve it, and then heated and stirred to 70 ° C. to completely dissolve it. After that, pressure homogenizer (pressure = 15
After homogenizing at (MPa), it was dried by spray drying, whereby a binding inhibitor for comparison was obtained (spray drying conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000r).
pm).

【0051】得られた改質剤10gを水990gに分散
させ、次いで、コーン油3gを混合し、粒度分布を測定
し、ついでメディアン径を測定した。
10 g of the obtained modifier was dispersed in 990 g of water, then 3 g of corn oil was mixed, the particle size distribution was measured, and then the median diameter was measured.

【0052】結着防止剤が比較例2で得られた結着防止
剤である点を除いて、実施例2と同様に弁当を作製し
た。但し、結着防止剤を添加する時に、コーン油3.2
gを加えた。また、実施例1と同様にホグレ率を測定し
た。
A bento was prepared in the same manner as in Example 2 except that the binding inhibitor was the binding inhibitor obtained in Comparative Example 2. However, when adding an anti-binding agent, corn oil 3.2
g was added. In addition, the hogle ratio was measured in the same manner as in Example 1.

【0053】比較例3 クエン酸モノグリセリド(ポエムK−30)0.6k
g、カゼインナトリウム1.5kg、デキストリン(D
E=40)15kgを水道水75kgに室温分散後、7
0℃まで加熱撹拌し、完全溶解させた。その後、TKホ
モディスパー(特殊機化工業製)で撹拌しながら、パー
ム油5kgを70℃に加熱したものを滴下乳化し、圧力
式ホモジナイザー(圧力=15MPa)で均質化後、噴
霧乾燥により乾燥し、これにより比較用の結着防止剤を
得た(噴霧乾燥条件:入り口温度=150℃、アトマイ
ザーの回転速度=21000rpm)。
Comparative Example 3 Citric acid monoglyceride (Poem K-30) 0.6k
g, sodium caseinate 1.5 kg, dextrin (D
E = 40) After dispersing 15 kg in 75 kg tap water at room temperature,
The mixture was heated to 0 ° C. with stirring to completely dissolve it. Then, while stirring with TK Homo Disper (manufactured by Tokushu Kika Kogyo), 5 kg of palm oil heated to 70 ° C. was added dropwise to emulsify, homogenized with a pressure homogenizer (pressure = 15 MPa), and then dried by spray drying. Thus, a binding inhibitor for comparison was obtained (spray drying conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000 rpm).

【0054】結着防止剤が比較例3で得られた結着防止
剤である点を除いて、実施例3と同様に味付けおにぎり
を作製した。また、実施例1と同様にメディアン径とホ
グレ率を測定した。
A seasoned rice ball was prepared in the same manner as in Example 3 except that the binding inhibitor was the binding inhibitor obtained in Comparative Example 3. In addition, the median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0055】比較例4 酵素処理レシチン(エルマイザーA)0.6kg、アラ
ビアガム0.2kg,デキストリン(DE=10)10
kg、ショ糖3kgを水道水75kgに室温分散後、7
0℃まで加熱撹拌し、完全溶解させた。その後、TKホ
モディスパー(特殊機化工業製)で撹拌しながら、大豆
硬化油(融点=34℃)15.4kgを70℃に加熱し
たものを滴下乳化し、圧力式ホモジナイザー(圧力=1
5MPa)で均質化後、噴霧乾燥により乾燥し、これに
より比較用の結着防止剤を得た(噴霧乾燥条件:入り口
温度=150℃、アトマイザーの回転速度=21000
rpm)。
Comparative Example 4 0.6 kg of enzyme-treated lecithin (Elmizer A), 0.2 kg of gum arabic, dextrin (DE = 10) 10
kg and sucrose 3 kg were dispersed in tap water 75 kg at room temperature.
The mixture was heated to 0 ° C. with stirring to completely dissolve it. Then, while stirring with TK Homo Disper (made by Tokushu Kika Kogyo), 15.4 kg of hydrogenated soybean oil (melting point = 34 ° C.) heated to 70 ° C. was dropped and emulsified, and a pressure homogenizer (pressure = 1)
After homogenizing at 5 MPa, it was dried by spray drying to obtain a binding inhibitor for comparison (spray drying conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000).
rpm).

【0056】結着防止剤が比較例4で得られた結着防止
剤である点を除いて、実施例4と同様にカップどんぶり
を調製した。また、炊飯米について、実施例1と同様に
メディアン径とホグレ率を測定した。
A cup bowl was prepared in the same manner as in Example 4, except that the binding inhibitor was the binding inhibitor obtained in Comparative Example 4. Further, with respect to the cooked rice, the median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0057】比較参考例1 HLB=11のショ糖脂肪酸エステル0.2kg、カゼ
インナトリウム2.0kg、ソルビトール70%液25
kg、ショ糖5kgを水道水75kgに室温分散後、7
0℃まで加熱撹拌し、完全溶解させた。その後、TKホ
モディスパー(特殊機化工業製)で撹拌しながら、菜種
油7.5kgを70℃に加熱したものを滴下乳化し、圧
力式ホモジナイザー(圧力=15MPa)で均質化後、
噴霧乾燥により乾燥し、これにより比較用の結着防止剤
を得た(噴霧乾燥条件:入り口温度=150℃、アトマ
イザーの回転速度=21000rpm)。
Comparative Reference Example 1 0.2 kg of sucrose fatty acid ester of HLB = 11, 2.0 kg of sodium caseinate, sorbitol 70% liquid 25
kg and 5 kg of sucrose were dispersed in 75 kg of tap water at room temperature.
The mixture was heated to 0 ° C. with stirring to completely dissolve it. Then, while stirring with TK Homo Disper (made by Tokushu Kika Kogyo), 7.5 kg of rapeseed oil heated to 70 ° C. was added dropwise to emulsify and homogenized with a pressure homogenizer (pressure = 15 MPa).
It was dried by spray drying, whereby a binding inhibitor for comparison was obtained (spray drying conditions: inlet temperature = 150 ° C., atomizer rotation speed = 21000 rpm).

【0058】結着防止剤が比較参考例1で得られた結着
防止剤である点を除いて、参考例1と同様に冷凍チャー
ハンを調製した。また、炊飯米について、実施例1と同
様にメディアン径とホグレ率を測定した。
Frozen fried rice was prepared in the same manner as in Reference Example 1, except that the binding inhibitor was the binding inhibitor obtained in Comparative Reference Example 1. Further, with respect to the cooked rice, the median diameter and the hogle ratio were measured in the same manner as in Example 1.

【0059】各々の結果を、下記[表2][表3]に記
載する。なお、食味試験(食感評価試験)は、次のよう
にして行なった。
The respective results are shown in the following [Table 2] and [Table 3]. The taste test (texture evaluation test) was performed as follows.

【0060】すなわち、15人のパネラーにて比較例に
対する評価を行った(実施例1は比較例1と、実施例2
は比較例2と、実施例3は比較例3と、実施例4は比較
例4と、参考例1は比較参考例1と比較した)。
That is, 15 panelists evaluated the comparative example (Example 1 is Comparative Example 1 and Example 2).
Comparative Example 2, Comparative Example 3 was compared with Example 3, Comparative Example 4 was compared with Example 4, and Comparative Example 1 was compared with Comparative Example 1. )

【0061】 5点:(比較例のものに比べて)極めて良好 4点:(比較例のものに比べて)良好 3点:比較例と同等 2点:(比較例のものより)悪い 1点:(比較例のものより)極めて悪い[0061] 5 points: very good (compared to the comparative example) 4 points: good (compared to the comparative example) 3 points: equivalent to the comparative example 2 points: worse (compared to the comparative example) 1 point: extremely worse (compared to the comparative example)

【表2】 [Table 2]

【表3】 [Table 3]

【0062】[0062]

【発明の効果】本発明により、何ら煩雑な操作を行わず
に米飯のホグレ性を向上させることのできる米飯用の結
着防止剤を提供することができる。
Industrial Applicability According to the present invention, it is possible to provide an anti-binding agent for cooked rice, which can improve the hogle resistance of cooked rice without any complicated operations.

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平10−191925(JP,A) 特開 平9−271348(JP,A) 特開 平7−147914(JP,A) (58)調査した分野(Int.Cl.7,DB名) A23L 1/10 A23D 7/00 504 ─────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-10-191925 (JP, A) JP-A-9-271348 (JP, A) JP-A-7-147914 (JP, A) (58) Field (Int.Cl. 7 , DB name) A23L 1/10 A23D 7/00 504

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】(A)食用油脂及び/又は油溶性乳化剤 (B)HLB10以上のショ糖脂肪酸エステル、及び (C)澱粉分解度が5〜80であるデキストリンを含有
する水中油型乳化液を噴霧乾燥して得られる米飯用の結
着防止剤であって、かつ水に乳化分散して得られる液の
粒度分布のメディアン径が5〜120μmであることを
特徴とする米飯用の結着防止剤。
1. An oil-in-water emulsion containing (A) an edible oil and / or an oil-soluble emulsifier (B) a sucrose fatty acid ester having an HLB of 10 or more , and (C) a dextrin having a starch decomposition degree of 5 to 80. An anti-binding agent for cooked rice obtained by spray drying, wherein the median diameter of the particle size distribution of the liquid obtained by emulsifying and dispersing in water is 5 to 120 μm. Agent.
【請求項2】油溶性乳化剤が、グリセリン脂肪酸エステ
ル、プロピレングリコール脂肪酸エステル、レシチン、
HLB8未満のポリグリセリン脂肪酸エステル、及びH
LB5未満のソルビタン脂肪酸エステルからなる群より
選ばれた少なくとも1種である請求項1記載の結着防止
剤。
2. The oil-soluble emulsifier is glycerin fatty acid ester, propylene glycol fatty acid ester, lecithin,
Polyglycerin fatty acid ester less than HLB8, and H
The anti-binding agent according to claim 1, which is at least one selected from the group consisting of sorbitan fatty acid esters having an LB of less than 5.
JP05743999A 1999-03-04 1999-03-04 Anti-binding agent for cooked rice Expired - Fee Related JP3376442B2 (en)

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Publication number Priority date Publication date Assignee Title
JP2003092987A (en) * 2001-09-21 2003-04-02 Kanegafuchi Chem Ind Co Ltd Oil and fat composition for cooking
JP5274807B2 (en) * 2007-09-28 2013-08-28 理研ビタミン株式会社 Frozen cooked rice
JP5565616B2 (en) * 2010-02-22 2014-08-06 株式会社Mizkan Holdings Cooked rice suitable for preservation, cooked rice production method, and cooked rice processing improver used therefor
JP2013051916A (en) * 2011-09-02 2013-03-21 Kao Corp Additive for cooked rice
JP6071291B2 (en) * 2012-07-12 2017-02-01 キッコーマン株式会社 Edible oil-containing solubilized soy sauce and method for producing the same
JP6071776B2 (en) * 2013-06-27 2017-02-01 日本製粉株式会社 Method for producing frozen cooked rice that does not easily cause range burning during thawing heating
WO2022114126A1 (en) * 2020-11-30 2022-06-02 キユーピー株式会社 Cooked-rice improver and method for producing cooked rice

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