JP3368056B2 - Curable composition - Google Patents

Description

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a building, an automobile, and a ship.
Useful as sealant and sealant for marine and road use
And a curable composition. [0002] Hydroxyl groups or hydrolysates bonded to silicon atoms
Crosslinking by forming a siloxane bond with a dissociation group
A silicon-containing group (hereinafter referred to as a reactive silicon group).
Saturated hydrocarbon polymers can be liquid polymers
Cured at room temperature due to moisture etc., resulting in a rubber-like cured product
Therefore, it is used as an elastic sealant for construction. Only
While the cured product of this polymer, alkyd
Good paintability when applying paints such as paints
However, it has the disadvantage that the paint is difficult to dry and harden.
Therefore, there is a problem that its use is limited. [0003] The object of the present invention is to
Solves the problems of
Excellent in properties and curability, adhesives, adhesives, paints, waterproof coatings
Agent, sealant composition, molding material, cast rubber material, foam
Curable composition that can be used for a wide range of applications such as materials
Is to provide. [0004] The present invention provides the above-mentioned features.
To solve the problems of conventional curable compositions,
As a result of repeated studies, it was found that the organic polymer reacts with oxygen in air
By adding a compatible unsaturated compound,
And achieved the present invention. Sand
That is, the present invention provides (A) a hydroxyl group or a hydroxyl group bonded to a silicon atom.
By having a hydrolytic group and forming a siloxane bond
Saturated carbonization having at least one crosslinkable silicon-containing group
A hydrogen-based polymer, and (B) the saturated hydrocarbon-based polymer 1
0.1 to 20 parts by weight of oxygen in air with respect to 00 parts by weight
A curable composition containing an unsaturated compound capable of reacting with
You. Hereinafter, the present invention will be described in detail. In the present invention
The hydroxyl or hydrolyzable group bonded to the silicon atom
Can be crosslinked by forming a siloxane bond.
At least one silicon-containing group, ie, a reactive silicon group
Having a saturated hydrocarbon polymer (hereinafter referred to as a saturated hydrocarbon polymer)
It is called the union (A). ) Is used. For use in the present invention
The reactive silicon group used is a well-known functional group.
Typical examples thereof include a compound represented by the general formula (I): (Where R ¹ And R ^Two Has 1 to 20 carbon atoms
Alkyl group, aryl group having 6 to 20 carbon atoms, 7 to 7 carbon atoms
20 aralkyl groups, or (R ′) _Three SiO- (R '
Is a monovalent hydrocarbon group having 1 to 20 carbon atoms, and three
R's may be the same or different. )
R represents a triorganosiloxy group; ¹ And R ^Two Is two
When they exist, they may be the same or different
No. X represents a hydroxyl group or a hydrolyzable group;
When doing so, they may be the same or different. a is
0, 1, 2, or 3, and b is 0, 1, or 2,
a + mb ≧ 1. In addition, m ## STR2 ## B need not be the same. m is 0 or 1 to 1
It is an integer of 9. )).
You. As a hydrolyzable group in the general formula (1)
Is not particularly limited, and conventionally known hydrolysis
Groups, but specific examples include, for example, a hydrogen atom,
Lucoxy group, acyloxy group, ketoxime group,
Groups, amide groups, aminooxy groups, mercapto groups,
A phenyl group and the like can be mentioned. Of these
Then, from the point that the hydrolyzability is mild and easy to handle,
Alkoxy groups are particularly preferred. The hydrolyzable group and the hydroxyl group form one silicon atom.
Can be bound in the range of 1 to 3
b) preferably ranges from 1 to 5. Hydrolysable
When two or more groups or hydroxyl groups are bonded to the reactive silicon group
May be the same or different. The silicon atom forming the reactive silicon group is 1
May be used, or two or more.
In the case of silicon atoms connected by bonding or the like, 20
Is preferred. In particular, the formula: (Where R ^Two , X and a are the same as described above. )
The reactive silicon group to be used is preferred because it is easily available. [0012] The reactive silicon group is formed of a saturated hydrocarbon polymer.
At least one, preferably 1.1 to 5 per molecule
Exist. Less than one reactive silicon group in the molecule
, The curability becomes insufficient and good rubber elastic behavior
Is difficult to express. The reactive silicon group is a component of a saturated hydrocarbon polymer.
May be present at the end of the strand,
And may be present in both. Especially reactive silicon groups
Is finally formed when is present at the end of the molecular chain
Effective network of saturated hydrocarbon polymer component contained in cured product
Since the chain amount increases, a high-strength, high-elongation rubber-like cured product can be obtained.
It is preferable in that it can be easily obtained. In addition, these reactions
Saturated hydrocarbon-based polymers having a crystalline silicon group
Or two or more of them may be used in combination. The saturated hydrocarbon used in the present invention
The polymer substantially has carbon-carbon unsaturated bonds other than the aromatic ring.
Is a concept that means a polymer that does not contain an organic solvent.
Of Saturated Hydrocarbon Polymer Containing Reactive Silicon Group Used
The rated polymer can be obtained by the following method
Things. (1) ethylene, propylene, 1-butene, i
An olefinic compound having 1 to 6 carbon atoms such as sobutylene
A method of polymerizing as a main monomer. (2) Diene compounds such as butadiene and isoprene are used alone
Polymerized or the above olefin compound and diene compound
And then hydrogenating. Of these polymers, a functional group is introduced at the terminal.
Easy to enter, easy to control molecular weight, large number of terminal functional groups
Isobutylene-based polymer and
It is preferably a hydrogenated polybutadiene polymer. The isobutylene-based polymer has a monomer unit
May be formed of isobutylene units.
Isobutylene monomer units copolymerizable with sobutylene
50% (wt%, the same applies hereinafter) in the polymer
Or less, more preferably 30% or less, particularly preferably 10% or less.
% Or less. As such a monomer component, for example,
C4-12 olefins, vinyl ethers, aromatics
Vinyl compounds, vinylsilanes, allylsilanes, etc.
I can do it. Specific examples of such a copolymer component include:
For example, 1-butene, 2-butene, 2-methyl-1-butene, 3-
Methyl-1-butene, pentene, 4-methyl-1-pentene,
Hexene, vinylcyclohexane, methyl vinyl ether
, Ethyl vinyl ether, isobutyl vinyl ether
Styrene, α-methylstyrene, dimethylstyrene
, Monochlorostyrene, dichlorostyrene, β-pine
, Indene, vinyltrichlorosilane, vinylmethyl
Dichlorosilane, vinyldimethylchlorosilane, vinyl
Dimethylmethoxysilane, vinyltrimethylsilane, di
Vinyl dichlorosilane, divinyl dimethoxy silane, di
Vinyldimethylsilane, 1,3-divinyl-1,1,3,3-tetra
Methyldisiloxane, trivinylmethylsilane, tetra
Vinylsilane, allyltrichlorosilane, allylmethyl
Dichlorosilane, allyldimethylchlorosilane, allyl
Dimethylmethoxysilane, allyltrimethylsilane, di
Allyl dichlorosilane, diallyldimethoxysilane, di
Allyldimethylsilane, γ-methacryloyloxypro
Piltrimethoxysilane, γ-methacryloyloxyp
And propylmethyldimethoxysilane. These monomers copolymerizable with isobutylene
When vinyl silanes or allyl silanes are used as
The silicon content of the coalesce increases, making it a silane coupling agent.
The number of groups that can act and increase the adhesiveness of the resulting composition
Is improved. Furthermore, hydrogenated polybutadiene-based polymers and other
Even in saturated hydrocarbon polymers, isobutylene-based
As in the case of the body, in addition to the main monomer unit, other
A monomer unit may be contained. The saturated hydrocarbon polymerization used in the present invention
In the body, butadiene as long as the object of the present invention is achieved,
Double bonding after polymerization such as polyene compounds such as isoprene
A small amount of the remaining monomer units, preferably 10% or less,
May be contained in a range of 5% or less, particularly 1% or less.
No. The saturated hydrocarbon polymer (A), in particular
Number of sobutylene polymers and hydrogenated polybutadiene polymers
The average molecular weight should be around 500-100,000
Preferred, especially about 1,000 to 30,000 liquids
It is preferable to use the most fluid because it is easy to handle.
No. Furthermore, the molecular weight distribution (M _w / M _n ) Is the same
M in terms of lower viscosity at molecular weight _w / M _n But
The narrower the better. Saturated Hydrocarbon Polymerization Having Reactive Silicon Group
Production method, especially isobutylene-based polymer and
The case of a hydrogenated polybutadiene polymer will be described as an example.
You. The above-mentioned isobutylene polymer having a reactive silicon group
Among them, isobutylene having a reactive silicon group at the molecular terminal
Polymers are based on a polymerization method called inifer method (inifer method).
Specific compounds that are both initiators and chain transfer agents
End-functional type obtained by the cationic polymerization method using
More preferably, it is manufactured using an all-terminal functional isobutylene polymer.
Can be built. Such a manufacturing method is disclosed in
No.-6003, No.63-6041, No.63-2541
No. 49, No. 64-22904, No. 64-38407
Are described in each specification. In addition, a compound having a reactive silicon group in the molecule
Sobutylene-based polymer is a monomer containing mainly isobutylene
Vinyl silanes or allyls containing reactive silicon groups in the body
Manufactured by adding silanes and copolymerizing
You. Further, a compound having a reactive silicon group at a molecular terminal
In the polymerization for producing sobutylene-based polymer,
It has a reactive silicon group other than the component isobutylene monomer.
Vinyl silanes and allyl silanes
Later, by introducing a reactive silicon group to the terminal,
And isobutylene system having a reactive silicon group inside the molecular chain
Polymers can be produced. Vinyl silanes having a reactive silicon group
And specific examples of allylsilanes, for example, vinyl
Trichlorosilane, vinylmethyldichlorosilane, vinyl
Dimethyl chlorosilane, vinyl dimethyl methoxy sila
, Divinyldichlorosilane, divinyldimethoxysila
, Allyltrichlorosilane, allylmethyldichlorosilane
Orchid, allyldimethylchlorosilane, allyldimethylme
Toxysilane, diallyldichlorosilane, diallyldimethyl
Toxysilane, γ-methacryloyloxypropyl tri
Methoxysilane, γ-methacryloyloxypropyl
Tildimethoxysilane and the like. A method for producing a hydrogenated polybutadiene polymer is described.
For example, for example, first, a polybutadi
The hydroxyl group of the ene polymer is converted to an oxime such as -ONa or -OK.
After converting to a tall group, the general formula (2): CH _Two = CH-R ^Three —Y (2) wherein Y is a halogen atom such as a chlorine atom and an iodine atom.
R ^Three Is -R ^Four -, -R ^Four -OC (= O)-, -R
^Four -C (= O)-(R ^Four Is a divalent carbon having 1 to 20 carbon atoms
Preferred examples of the hydrogen group include an alkylene group and a cycloalkyl group.
Loalkylene group, arylene group, aralkylene group
Is a divalent organic group represented by the formula _Two -And
R "-Ph-CH _Two -(R ″ is a hydrocarbon having 1 to 10 carbon atoms)
An element group, Ph, is a p-phenylene group. 2) selected from
Group is particularly preferable].
Is reacted with water having a terminal olefin group.
Hydrogenated polybutadiene polymer (hereinafter referred to as hydrogenated olefin
Polybutadiene polymer).
Wear. Hydroxy-terminated polybutadiene-based polymerization
As a method of converting the terminal hydroxyl group of the body into an oxymetal group,
Alkali metals such as Na and K; Metal water such as NaH
Hydride; NaOCH _Three Metal alkoxides such as
Method to react with caustic alkalis such as OH and KOH
Can be mentioned. In the above method, the starting material
Was approximately the same as the hydroxy-terminated polybutadiene polymer
Hydrogenated polybutadiene system with terminal olefin having the same molecular weight
A polymer is obtained, but to obtain a higher molecular weight polymer
Is reacted with an organic halogen compound of the general formula (2).
Before, methylene chloride, bis (chloromethyl) benzene,
Halogen in one molecule such as bis (chloromethyl) ether
Reacting with a polyvalent organic halogen compound containing two or more atoms
After increasing the molecular weight by an organic compound represented by the general formula (2)
When reacted with halogen compounds, higher molecular weight, terminal
A hydrogenated polybutadiene polymer having an olefin group
Obtainable. The organic halogen represented by the general formula (2)
Specific examples of the compound include allyl chloride and allyl chloride.
Lomide, vinyl (chloromethyl) benzene, allyl
(Chloromethyl) benzene, allyl (bromomethyl) benzene
Benzene, allyl (chloromethyl) ether, allyl
(Rolomethoxy) benzene, 1-butenyl (chloromethyl)
Ether, 1-hexenyl (chloromethoxy) benzene,
Allyloxy (chloromethyl) benzene
But can be, but not limited to. these
Of these, allyl is inexpensive and easily reacts.
Chloride is preferred. Hydrogenated polybutadiene based olefin polymerization
The reactive silicon group is introduced into the body by adding reactive silicon
As in the case of the isobutylene polymer having a group,
For example, a hydrogen atom is bonded to a group represented by the general formula (1).
Hydrosilane compound, preferably of the general formula: (Where R ^Two , X and a are the same as described above. )
Of the compound to be added using a platinum-based catalyst
Can be manufactured more. A hydrogen atom is added to the group represented by the general formula (1).
Specific examples of the hydrosilane compound bonded with
For example, trichlorosilane, methyldichlorosilane, dimethyl
Halogen such as ruchlorosilane and phenyldichlorosilane
Silanes: trimethoxysilane, triethoxysila
, Methyldiethoxysilane, methyldimethoxysila
, Alkoxysilanes such as phenyldimethoxysilane
: Methyldiacetoxysilane, phenyldiacetoxy
Acyloxysilanes such as silane; bis (dimethylketoki)
(Simate) methylsilane, bis (cyclohexyl ketoki)
Ketoximate silanes such as shimate) methyl silane
But are not limited to these. This
Of these, halogenated silanes, alkoxysila
Are preferred. It can react with oxygen in the air used in the present invention.
Examples of the unsaturated compound (B) component are generally those in air
With unsaturated groups in the molecule that cause polymerization by oxygen
An air oxidation hardened substance called a compound is included. Than
Specifically, for example, represented by tung oil, linseed oil, etc.
Dried oils and various types of alcohols obtained by modifying the compound.
Resin; acrylic polymer modified with drying oil, d.
Poxy resin, silicone resin; 1,2-polybutadier
1,4-polybutadiene, C _Five ~ C ₈ Diene polymerization
And copolymers, and various modifications of the polymers and copolymers
Products (maleated modified products, boiled oil modified products, etc.)
As a body example. Of these, tung oil, diene
Liquids (liquid diene polymers) and their
Modified products are particularly preferred. As a specific example of the above liquid diene polymer,
Is, for example, butadiene, chloroprene, isoprene,
Polymerization of diene compounds such as 1,3-pentadiene
Is a liquid polymer obtained by copolymerization,
Acrylonitrile and styrene copolymerizable with compounds
And other monomers so that the diene compound is mainly used.
Polymers such as NBR and SBR obtained by polymerization,
And their various modified products (maleated modified products, boiled
Oil-modified products). These are used alone
Or two or more of them may be used in combination. These liquid jets
Among polybutadiene polymers, liquid polybutadiene is preferred. Unsaturated compound capable of reacting with oxygen in the air
The component (B) may be used alone or in combination of two or more.
Good. Further, it promotes the oxidative curing reaction simultaneously with the component (B).
The effect can be enhanced by using a combined catalyst and metal dryer
There are cases. As these catalysts and metal dryers,
For example, cobalt naphthenate, lead naphthenate, naphthene
Zirconium phosphate, cobalt octylate, zirconium octylate
Examples thereof include metal salts such as conium, and amine compounds. Unsaturated compound capable of reacting with oxygen in the air
The amount of the component (B) used is the same as that of the component (A).
It is 0.1 to 20 parts by weight with respect to 100 parts by weight of the combined.
If the amount of the component (B) is less than 0.1 parts by weight,
The purpose of using unsaturated compounds that can react with oxygen
The dyeability is not sufficiently improved.
Tend to impair the tensile properties of the compound. Like
Or 1 to 10 parts by weight. The composition of the present invention may contain, if necessary,
Used with catalysts, plasticizers, fillers, and other additives
You may. Specific examples of the above curing catalyst are not particularly limited.
However, a commonly used curing catalyst is used. this
Specific examples of such a curing catalyst include, for example, octylic acid
Tin, dibutyltin dilaurate, dibutyltin maleate,
Carboxylic acid metal salts such as dibutyltin phthalate; organic stannic acid
Reaction product of a compound and an ester; tetrabutyl titanate,
Organic titanates such as organosiloxytitanium;
Mines, amine salts, quaternary ammonium salts, granidination
And the like. These curing catalysts are
0 to 10 parts by weight based on 100 parts by weight of the base polymer
Use. Specific examples of the plasticizer include dibutyl phthalate.
Talate, diheptyl phthalate, di (2-ethylhexyl)
F) phthalate, butyl benzyl phthalate, butyl phthalate
Phthalates such as taryl butyl glycolate; di
Non-fragrance such as octyl adipate and dioctyl sebacate
Dibasic acid esters; tricresyl phosphate,
Phosphate esters such as butyl phosphate
As a relatively high molecular weight type plasticizer, for example, 2
Polyesters such as polyesters of basic acids and dihydric alcohols
Stell plasticizer; polypropylene glycol and its derivatives
Such as polyethers; poly-α-methylstyrene,
Polystyrenes such as polystyrene, etc .; process oils,
And alkylbenzenes. These are
Alternatively, they can be used in combination. However, preferably,
It is necessary to select one with good properties. These plasticizers
20 per 100 parts by weight of the saturated hydrocarbon polymer (A)
Use about 200 parts by weight. As a specific example of the filler, for example,
Calcium carbonate, light calcium carbonate, colloidal calcium carbonate
Cium, kaolin, talc, silica, titanium oxide, silicic acid
Aluminum, magnesium oxide, zinc oxide, carbon
Black and the like. If a filler is used,
The amount used is based on 100 parts by weight of the saturated hydrocarbon polymer (A).
The preferred range is 10 to 300 parts by weight. Examples of the other additives include water
Anti-sagging agents such as castor oil and organic bentonite, coloring
Agents, antioxidants, adhesion promoters and the like. like this
The curable composition of the present invention obtained in
Agents, paints, paint waterproofing agents, sealant compositions, molding materials,
Useful as cast rubber material, foam material, etc.
Can be. Among them, application to sealants is particularly useful.
You. EXAMPLES Next, the present invention will be described specifically with reference to examples.
However, the present invention is not limited to these. Production Example 1 Production of saturated hydrocarbon polymer (A) Inside a four-necked flask equipped with a stirrer and nitrogen line
560 mL of dried methylene chloride and n-hexane 116
0 mL, α-methylpyridine 940 mg, p-dimethylcum loli
After weighing 22 g of the solution to make a uniform mixed solution,
And cooled under reduced pressure to 570 mL of isobutylene monomer.
Charged through a Molecula sieves tube. In the above reaction solution cooled to -70 ° C,
Under stirring, the polymerization catalyst solution (titanium tetrachloride 14
(mL / 80 mL of methylene chloride) at once to initiate polymerization
did. Once the temperature was raised to -54 ° C, the temperature was reduced to -7 in about 17 minutes.
The temperature was lowered to 0 ° C. About 20 minutes after the start of polymerization, 1,9-deca
132 g of diene was added and further stirred at -70 ° C for 4 hours.
Continued. The turbid reaction solution was mixed with 3 L of warm water (about 45 L).
C), stirred for about 2 hours, separated the organic layer,
Was repeated three times. The colorless and transparent thus obtained
The organic layer was concentrated under reduced pressure to give
About 400 g of butylene oligomer was obtained. Next, the vinyl group-containing a thus obtained
400 g of sobutylene oligomer is added to 200 mL of n-heptane
And heated to about 70 ° C.
Silane 1.5 [eq / vinyl group], platinum (vinyl siloxa
N) Complex 1 × 10 ^-Four [Eq / vinyl group]
A silylation reaction was performed. Reaction tracking by FT-IR
It is 1640cm in about 4 hours ^-1 Olefin absorption disappears
Was. By concentrating the reaction solution under reduced pressure,
Isobutylene oryl having reactive silicon groups at both ends
Gomer is obtained. [Structural formula] Production Example 2 Production of Saturated Hydrocarbon Polymer (A) In Production Example 1, allyl meth
Same as Production Example 1, except that 24 g of silane were used.
Isobutylene oligos whose production intermediates have partially different structures
Got Ma. [Structural formula] Production Example 3 Production of saturated hydrocarbon polymer (A) Inside a four-necked flask equipped with a stirrer and nitrogen line
560 mL of dried methylene chloride and n-hexane 116
0 mL, α-methylpyridine 940 mg, p-dimethylcum loli
After weighing 22 g of the solution to make a uniform mixed solution,
And cooled under reduced pressure to 570 mL of isobutylene monomer.
Charged through a Molecula sieves tube. In the reaction solution cooled to -70 ° C,
Under stirring, the polymerization catalyst solution (titanium tetrachloride 14
(mL / 80 mL of methylene chloride) at once to initiate polymerization
did. Once the temperature was raised to -54 ° C, the temperature was reduced to -7 in about 17 minutes.
The temperature was lowered to 0 ° C. Stirring is continued for about 60 minutes after the start of polymerization.
Continued. Transfer the yellow-colored reaction solution to 3 L of warm water (about 45 ° C).
And stirred for about 2 hours to separate the organic layer.
Washing was repeated three times. The colorless and transparent material thus obtained is
The organic layer was concentrated under reduced pressure to obtain a tertiary chloro group at both ends.
About 400 g of a sobutylene oligomer was obtained. Further, the isobutylene oligomer can be reduced.
By continuing heating at 170 ° C. under pressure for 2 hours,
Performs thermal dehydrochlorination and has an isopropenyl group at both ends.
The obtained isobutylene oligomer was obtained. Next, the isopropenyl thus obtained is obtained.
400 g of a group-containing isobutylene oligomer is added to n-heptane
Dissolve in 200 mL and heat to about 100 ° C in a pressure vessel
After that, methyl dichlorosilane 1.5 [eq / vinyl group],
Platinum (vinylsiloxane complex 1 × 10 ^-Four [Eq / vinyl
And a hydrosilylation reaction was carried out. FT-I
Follow the reaction with R, and 1640 cm in about 10 hours ^-1 of
Olefin absorption disappeared. Cool the reaction solution to 60 ° C
And then an excess of [/ methyldichlorosilane] methanol
And the mixture was stirred for about 4 hours to complete the methoxylation.
I let you. Concentrate the reaction solution under reduced pressure to obtain the target
Isobutylene oligomer having reactive silicon groups at both ends
was gotten. [Structural formula] Examples 1 to 6 and Comparative Examples 7 to 9 Obtained in Production Examples 1 to 3 as a saturated hydrocarbon polymer (A).
For the various polymers 100 obtained, the long-chain carbon shown in Table 1 below was used.
The hydride group-containing silicon compound was added in the amount shown in Table 1.
After that, calcium carbonate (manufactured by Shiraishi Industry Co., Ltd.,
Name biscolite R) 120 parts, heavy calcium carbonate (white
20 parts, manufactured by Ishi Kogyo Co., Ltd., trade name: Whiten SB
90 (manufactured by Idemitsu Petrochemical Co., Ltd., trade name PS-32)
Part, hindered phenolic anti-aging agent (Ciba Geigy
Co., Ltd., trade name Irganox 1010) 1 copy, Ben
Zotriazole UV absorber (Ciba Geigy Co., Ltd.)
1 part of Tinuvin 327), a crosslinking agent (hydrogen sulfate)
Thorium) 5 parts, tin octylate 3 parts, laurylamine 1
Add parts and mix well. Next, the mixture was added to a small 3
Pass between the paint rolls 3 times, 5mm thick sheet
Was prepared. Then cure at 23 ℃ / 65% RH for 1 day
After that, alkyd paint (trade name House Paint,
(Kansai Paint Co., Ltd.) and apply the date shown in Table 1 below.
The curability when the number was increased was evaluated by finger touch. [Table 1] Incidentally, it is possible to react with oxygen in the air shown in Table 1.
Of the unsaturated compounds, polyoil LCB-110
Liquid 1,4-polybutadiene having an average molecular weight of 1600 (e.g.
R-15HT has a number average molecular weight of 1,000.
Mixture of 1,2-polybutadiene (Idemitsu Petrochemical Co., Ltd.)
Made). Evaluation of curability of alkyd paint
In Table 1, as can be seen from the results in Table 1,
The curable composition is obtained by adding the component (B),
The paintability of kid paints has been improved,
Compared to the case without using unsaturated compounds that can react with
This shows that the improvement effect is remarkable. In recent years, contamination has become important from the viewpoint of placing importance on aesthetics.
Market demands on gender are very strict,
The curable composition of the present invention includes an adhesive, a pressure-sensitive adhesive, a paint, and a coating film.
Waterproofing agent, sealant composition, molding material, casting rubber material,
Can be used for a wide range of applications such as foam materials
But especially for buildings, automobiles, ships and roads.
Very useful as a sealing material and sealant.

──────────────────────────────────────────────────続 き Continuation of front page (56) References JP-A-5-295248 (JP, A) JP-A-1-146959 (JP, A) JP-A-62-1750 (JP, A) JP-A-2- 185565 (JP, A) JP-A-2-97562 (JP, A) JP-A-1-252670 (JP, A) JP-A-1-168764 (JP, A) JP-A-1-167371 (JP, A) JP-A-1-170658 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) C08L 1/00-101/16 C08K 3/00-13/08

Claims (1)

(A) Saturated having (A) a hydroxyl group or a hydrolyzable group bonded to a silicon atom and having at least one silicon-containing group which can be crosslinked by forming a siloxane bond. A hydrocarbon polymer, and (B) a compound having an unsaturated carbon-carbon bond capable of reacting with 0.1 to 20 parts by weight of oxygen in air with respect to 100 parts by weight of the saturated hydrocarbon polymer. A curable composition characterized by containing.