JP3357007B2 - Low temperature dyeing method for carrier and polyester fiber - Google Patents
Low temperature dyeing method for carrier and polyester fiberInfo
- Publication number
- JP3357007B2 JP3357007B2 JP05087899A JP5087899A JP3357007B2 JP 3357007 B2 JP3357007 B2 JP 3357007B2 JP 05087899 A JP05087899 A JP 05087899A JP 5087899 A JP5087899 A JP 5087899A JP 3357007 B2 JP3357007 B2 JP 3357007B2
- Authority
- JP
- Japan
- Prior art keywords
- carrier
- dyeing
- polyester
- polyester fiber
- low temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Coloring (AREA)
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、キャリヤー及びポ
リエステル系繊維の低温染色方法に関する。さらに詳し
く述べるならば、本発明は、自然界から得られる単環式
モノテルペンの炭化水素化合物を含有するキャリヤー及
び該キャリヤーの存在下でポリエステル系繊維を染色す
る方法に関する。The present invention relates to a carrier and a method for low-temperature dyeing of polyester fibers. More specifically, the present invention relates to a carrier containing a hydrocarbon compound of a monocyclic monoterpene obtained from nature and a method of dyeing a polyester fiber in the presence of the carrier.
【０００２】[0002]
【従来の技術】従来から、キャリヤーは、ポリエステル
繊維やナイロン繊維の精練、リラックス、収縮加工、シ
ボ立て、すじむら防止及び低温染色などに用いられてい
る。特に、ポリエステル繊維と他繊維との複合素材、例
えば、ポリエステル／ウールの場合、通常のポリエステ
ル繊維の染色条件である１３０℃にまで温度を上げると
他方の繊維の脆化がおこるため、その脆化を防ぐため１
００℃〜１１０℃の低温で染色を行っているが、この際
ポリエステル繊維の良好な濃染効果を得るためにキャリ
ヤーの使用が不可欠である。2. Description of the Related Art Hitherto, carriers have been used for scouring, relaxing, shrinking, embossing, preventing streaks and low-temperature dyeing of polyester fibers and nylon fibers. In particular, in the case of a composite material of polyester fibers and other fibers, for example, polyester / wool, when the temperature is raised to 130 ° C., which is the usual dyeing condition for polyester fibers, the other fibers are embrittled. 1 to prevent
The dyeing is carried out at a low temperature of 00 ° C to 110 ° C. At this time, use of a carrier is indispensable in order to obtain a good deep dyeing effect of the polyester fiber.
【０００３】しかし、従来のキャリヤーは、トリクロロ
ベンゼン、ジクロロベンゼン、フェニルフェノール、ジ
フェニル、メチルナフタレン等を主成分としており、こ
れらの化合物は環境汚染や人体への悪影響が懸念される
物質として挙げられており、環境問題を配慮した場合、
今後これらの化合物を主成分とするキャリヤーを使用す
ることは好ましくない。[0003] However, conventional carriers mainly contain trichlorobenzene, dichlorobenzene, phenylphenol, diphenyl, methylnaphthalene, and the like, and these compounds are listed as substances that are likely to cause environmental pollution and adverse effects on the human body. When considering environmental issues,
It is not preferable to use carriers containing these compounds as main components in the future.
【０００４】[0004]
【発明が解決しよとする課題】本発明は、このような環
境問題に鑑み、環境汚染が少なく、また人体への悪影響
のない化合物により、従来のキャリヤーに代わるものを
提供することを目的とする。SUMMARY OF THE INVENTION In view of such environmental problems, an object of the present invention is to provide an alternative to a conventional carrier by using a compound which causes less environmental pollution and has no adverse effect on the human body. I do.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、上記課題
を解決するために鋭意検討の結果、環境汚染が少なく、
人体への悪影響の少ない化合物である、天然界から得ら
れる植物油がキャリヤーとして有効であることを見い出
し、この知見に基づき本発明を完成させたものである。Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, have reduced environmental pollution.
The present inventors have found that a vegetable oil obtained from the natural world, which is a compound having little adverse effect on the human body, is effective as a carrier, and completed the present invention based on this finding.
【０００６】すなわち、本発明は、テルピネン、フェラ
ンドレン及び／又はリモネンを含有することを特徴とす
るポリエステル系繊維染色用キャリヤーを提供する。ま
た、本発明は、被染色繊維に対して２〜２０重量％の、
該キャリヤーの存在下で染色を行うことを特徴とするポ
リエステル系繊維の染色方法を提供する。That is, the present invention relates to a terpinene,
Provided is a carrier for dyeing a polyester fiber, which comprises drain and / or limonene . In addition, the present invention provides 2 to 20% by weight of the fiber to be dyed,
The present invention provides a method for dyeing a polyester fiber, which comprises dyeing in the presence of the carrier.
【０００７】[0007]
【発明の実施の形態】本発明に有用なテルピネン、フェ
ランドレン、リモネンはいずれも植物の精油等から得る
ことができる天然物であり、環境の汚染、健康への影響
も少ない。テルピネン、フェランドレン、リモネンをキ
ャリヤーとして使用する場合、分散または乳化された状
態で水性浴に添加するのがよく、分散または乳化のため
には従来公知の非イオン活性剤、アニオン活性剤などを
用いることができる。 Useful Te Rupinen to the embodiment of the present invention, any phellandrene, limonene is a natural product which can be obtained from essential oils of plants, pollution of the environment, also significantly affect the health. When terpinene, ferrandrene and limonene are used as carriers, it is preferable to add them to the aqueous bath in a dispersed or emulsified state, and use a conventionally known nonionic activator, anionic activator or the like for dispersion or emulsification. be able to.
【０００８】本発明のキャリヤーを用いて染色できるポ
リエステル系繊維としては、ポリエステル１００％の繊
維のみならず、ポリエステル／ウール、ポリエステル／
ナイロン、ポリエステル／絹などポリエステル繊維と他
繊維との複合繊維も含まれ、また糸、織物、編物、不織
布等さまざまな組織素材に使用できる。次に、本発明の
キャリヤーを用いて、ポリエステル系繊維を染色する方
法を説明する。The polyester fibers which can be dyed using the carrier of the present invention include not only 100% polyester fibers but also polyester / wool, polyester /
It also includes composite fibers of polyester fibers and other fibers such as nylon and polyester / silk, and can be used for various tissue materials such as yarn, woven fabric, knitted fabric, and nonwoven fabric. Next, a method of dyeing a polyester fiber using the carrier of the present invention will be described.
【０００９】本発明のキャリヤーは、被染色繊維に対し
て２〜２０重量％、好ましくは４〜１５重量％になるよ
うに染色浴に添加して使用される。また、あらかじめ染
色すべき被染色繊維に該キャリヤーを付着させ、その後
染色浴にキャリヤーを追加せずに、また場合によっては
キャリヤーを追加して染色行うことも可能である。ポリ
エステル繊維を染色するための染料は、従来公知の分散
染料であってよく、複合繊維の場合には、ポリエステル
繊維に対しては分散染料、ポリエステル繊維以外の繊維
には、その繊維に適合した染料（例えば、ウールやナイ
ロンに対する酸性染料など）を用いることができる。ま
た、ポリエステル系繊維を染色する際には、均染性を補
助するために、いわゆる分散均染剤を併用することもで
きる。分散均染剤としては従来より用いられているもの
でよく、使用する量は０．１〜２．０ｇ／Ｌを染色浴に
添加する。染色の際の浴比は、通常行われている浴比で
あってよく、一般には１：５〜１：３０の間で行われ
る。染色温度は９０〜１１０℃、好ましくは１０３〜１
１０℃であり、染色時間は３０分〜６０分の範囲で従来
のキャリヤーを用いた場合と同等の濃色効果が得られ
る。The carrier of the present invention is used by being added to a dyeing bath so as to be 2 to 20% by weight, preferably 4 to 15% by weight based on the fiber to be dyed. It is also possible to attach the carrier to the fibers to be dyed in advance and then dye without adding a carrier to the dyeing bath, or in some cases by adding a carrier. The dye for dyeing the polyester fiber may be a conventionally known disperse dye, and in the case of a conjugate fiber, a disperse dye for the polyester fiber, and a dye suitable for the fiber other than the polyester fiber. (For example, an acid dye for wool or nylon) can be used. When dyeing polyester fibers, a so-called dispersion leveling agent can be used in combination to assist leveling. Conventionally used dispersing and leveling agents may be used, and 0.1 to 2.0 g / L is added to the dyeing bath. The bath ratio at the time of dyeing may be a conventional bath ratio, and is generally between 1: 5 and 1:30. The dyeing temperature is 90 to 110 ° C, preferably 103 to 1
The dyeing time is 10 ° C., and the dyeing time is in the range of 30 minutes to 60 minutes, and the same deep color effect as that obtained by using a conventional carrier can be obtained.
【００１０】本発明のキャリヤーも、従来のキャリヤー
と同様に、ポリエステル繊維を膨潤させる効果があり、
従ってポリエステル繊維の低温染色や、収縮加工を可能
にするものと考えられる。[0010] The carrier of the present invention also has the effect of swelling the polyester fiber, as in the case of the conventional carrier.
Therefore, it is considered that low-temperature dyeing and shrinkage processing of the polyester fiber are enabled.
【００１１】[0011]
【実施例】以下、実施例でもって本発明を更に具体的に
説明するが、本発明はこれらの実施例により何ら限定さ
れるものではない。 実施例１ 以下の配合組成にてキャリヤーを作成した。EXAMPLES The present invention will be described in more detail with reference to the following Examples, which should not be construed as limiting the present invention. Example 1 A carrier was prepared with the following composition.
【００１２】 テルピネン ９０重量部 ドデシルベンゼンスルホン酸カルシウム ２重量部 ソフタノール ５０（日本触媒（株）社製） ４重量部 ソフタノール ９０（日本触媒（株）社製） ４重量部 １００重量部 実施例２ 実施例１のテルピネンをリモネンに代えた以外は、実施
例１と同様にしてキャリヤーを作成した。Terpinene 90 parts by weight Calcium dodecylbenzenesulfonate 2 parts by weight Softanol 50 (manufactured by Nippon Shokubai Co., Ltd.) 4 parts by weight Sophthalanol 90 (manufactured by Nippon Shokubai Co., Ltd.) 4 parts by weight 100 parts by weight Example 2 A carrier was prepared in the same manner as in Example 1 except that limonene was used instead of terpinene in Example 1.
【００１３】比較例１ 実施例１のテルピネンをトリクロロベンゼンに代えた以
外は、実施例１と同様にしてキャリヤーを作成した。 比較例２ 実施例１のテルピネンをメチルナフタレンに代えた以外
は、実施例１と同様にしてキャリヤーを作成した。Comparative Example 1 A carrier was prepared in the same manner as in Example 1 except that terpinene was replaced with trichlorobenzene. Comparative Example 2 A carrier was prepared in the same manner as in Example 1 except that terpinene in Example 1 was changed to methylnaphthalene.
【００１４】実施例３ 実施例１、２及び比較例１、２のキャリヤーを用いて、
ポリエステル１００％の繊維を以下の条件にて染色し
た。 供試布： ポリエステル織物 染色条件： 分散染料 DIANIX BLACK RN-SE 01 １０％ o.w.f. （ダイスター（株）社製） キャリヤー ８％ o.w.f. 分散剤均染剤 ニッカサンソルト RM-340 ０．２ｇ／Ｌ （日華化学（株）社製） pH調整剤 酢酸にて pH=5.0 〜5.5 に調整 浴比 １：１０ 染色温度×時間 １０５℃×４５分（６０℃から２℃／分で昇温） 次いで、下記の条件にてソーピングを行った。Example 3 Using the carriers of Examples 1 and 2 and Comparative Examples 1 and 2,
Fiber of 100% polyester was dyed under the following conditions. Test cloth: Polyester fabric Dyeing condition: Disperse dye DIANIX BLACK RN-SE 01 10% owf (manufactured by Dystar Co., Ltd.) Carrier 8% owf Dispersant leveling agent Nikka Sun Salt RM-340 0.2 g / L (day PH control agent adjusted to pH = 5.0 to 5.5 with acetic acid Bath ratio 1:10 Dyeing temperature × time 105 ° C. × 45 minutes (temperature rises from 60 ° C. at 2 ° C./minute) Soaping was performed under the following conditions.
【００１５】 ソーピング剤 サンモール RC-700 １．０ｇ／Ｌ （日華化学（株）社製） ハイドロサルファイト ２．０ｇ／Ｌ 浴比 １：１０ ソーピング温度×時間 ７０℃×２０分濃染効果の評価 実施例３で得られた染色布を、ミノルタ社製SPECTROPHO
TOMETER CM-3700dにてＫ／Ｓ濃度を測色し、比較例１の
Ｋ／Ｓ濃度を１００とした時の相対比較値を表１に示
す。Ｋ／Ｓ濃度は、値が大きいほど濃色に染まっている
ことを表す。[0015] soaping agent Saint-Maur-RC-700 1.0g / L (Nicca Chemical Co., Ltd.) hydrosulfite 2.0g / L bath ratio of 1:10 soaping temperature × time 70 ℃ × 20 minutes-enhancement effect The dyed cloth obtained in Example 3 was applied to Minolta SPECTROPHO
The K / S concentration was measured by TOMETER CM-3700d, and the relative comparison value when the K / S concentration in Comparative Example 1 was set to 100 is shown in Table 1. The K / S concentration indicates that the larger the value, the deeper the color.
【００１６】[0016]
【表１】 [Table 1]
【００１７】上記より、環境汚染及び健康への影響の少
ない植物油である単環式モノテルペン化合物の炭化水素
化合物を含有する実施例１、２のキャリヤーを用いてポ
リエステル繊維を低温染色した場合には、従来のキャリ
ヤーを用いた場合と同等の濃染効果が得られることがわ
かる。From the above, when polyester fibers are dyed at low temperature using the carriers of Examples 1 and 2 containing a hydrocarbon compound of a monocyclic monoterpene compound which is a vegetable oil having little effect on environmental pollution and health. It can be seen that the same deep dyeing effect as that obtained by using the conventional carrier can be obtained.
【００１８】[0018]
【発明の効果】本発明によれば、環境汚染や健康への影
響を少なくして、ポリエステル系繊維を低温で染色する
ことができる。According to the present invention, polyester fibers can be dyed at a low temperature with less influence on environmental pollution and health.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) D06P 1/44 D06P 3/00 D06P 5/00 D06M 5/00 D06M 13/00 ──────────────────────────────────────────────────続 き Continued on the front page (58) Fields investigated (Int. Cl. 7 , DB name) D06P 1/44 D06P 3/00 D06P 5/00 D06M 5/00 D06M 13/00
Claims (3)
リモネンを含有することを特徴とするポリエステル系繊
維染色用キャリヤー。(1) terpinene, ferrandrene and / or
Polyester fiber characterized by containing limonene
Carrier for textile dyeing .
ン活性剤を含む、請求項１記載のキャリヤー。2. A nonionic surfactant and / or anio.
The carrier of claim 1 , comprising a surfactant .
請求項１又は２に記載のキャリヤーの存在下で染色を行
うことを特徴とするポリエステル系繊維の染色方法。3. An amount of 2 to 20% by weight based on the fiber to be dyed,
A method for dyeing polyester fibers, comprising dyeing in the presence of the carrier according to claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05087899A JP3357007B2 (en) | 1999-02-26 | 1999-02-26 | Low temperature dyeing method for carrier and polyester fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05087899A JP3357007B2 (en) | 1999-02-26 | 1999-02-26 | Low temperature dyeing method for carrier and polyester fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000248475A JP2000248475A (en) | 2000-09-12 |
| JP3357007B2 true JP3357007B2 (en) | 2002-12-16 |
Family
ID=12870994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05087899A Expired - Lifetime JP3357007B2 (en) | 1999-02-26 | 1999-02-26 | Low temperature dyeing method for carrier and polyester fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3357007B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1348801B1 (en) * | 2002-03-29 | 2007-05-09 | Hoya Corporation | Method of dyeing thermoplastic resin and colored plastic lens obtainable by that method |
-
1999
- 1999-02-26 JP JP05087899A patent/JP3357007B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000248475A (en) | 2000-09-12 |
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