JP3333901B2 - Transparent hologram laminated metal plate and method of manufacturing the same - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transparent hologram laminated metal plate and a method of manufacturing the same, and more particularly, to a transparent hologram laminated metal plate in which a transparent hologram film is laminated and fixed to a metal plate on which a background image is printed, and a method of manufacturing the same. It is about.

[0002]

2. Description of the Related Art Conventionally, as a method of laminating and fixing a synthetic resin film to a metal plate (lamination), there are a method of applying an adhesive to a joint surface, and a method of heat-fusing the metal plate and the synthetic resin film by heating. is there. In the former bonding method, it takes a long time to dry the adhesive, and the drying step is indispensable, so that the size of the apparatus tends to be large. Therefore, the latter heat fusion method is generally adopted.

[0003] The heat fusion method involves passing a metal plate and a synthetic resin film through a heating furnace, heating the plate with Joule heat caused by eddy current induced in the metal plate by an electromagnetic induction coil, or applying the method of the present applicant. Tokuhei 7-
There is a flame treatment described in Japanese Patent No. 100350.
In the method described in this publication, the surfaces of a metal plate and a synthetic resin film are continuously joined while being subjected to a flame treatment immediately before joining, and the metal plate and the synthetic resin film are subjected to a pretreatment for improving adhesion. And a sufficient bonding strength can be obtained.

On the other hand, polyethylene terephthalate (PE)
T) A hologram film in which an acrylic resin layer is formed on the back surface of a film or a polyvinyl chloride (PVC) film, a fine uneven pattern is formed on the acrylic resin layer, and a light-transmitting metal deposited layer is formed on the acrylic resin layer, It is provided by Hologram Company (USA) and the like. In this hologram film, the state of reflection, refraction, and interference of light slightly changes depending on the viewing angle, and the color of the concavo-convex pattern changes to iridescent. In other words, the back side of the hologram film is very delicate, with irregularities and thickness changes with an accuracy of about the wavelength of light.

[0005]

When the above-mentioned hologram film is laminated on a metal plate on which a background image such as a pattern, a pattern or a picture is printed on the surface, excessive heating and pressure impair the characteristics of the hologram film. In addition, the quality of the background drawing on the metal plate is altered and modulated, and its commercial value is lost. When a hologram film is simply laminated on a metal plate, a certain amount of adhesion can be achieved by electrostatic force or surface tension, but the adhesion force is weak and easily peels off from the end, so that the end of the metal plate can be mechanically pressed. Is required.

For example, when a can is manufactured using a laminated metal plate on which a hologram film is laminated as a can body,
The laminated metal plate is subjected to press cutting to cut it into a predetermined size, bending to join it into a cylindrical shape, and curling at the end, but the hologram film peels off during the processing. Therefore, problems such as low yield and low productivity are expected. Therefore, a product using a transparent hologram laminated metal plate has not been put to practical use except for a special use such as a structure in which an end portion is mechanically pressed by a frame or the like.

In view of the above situation, the present invention aims to solve the problem by firmly laminating and integrating a transparent hologram film and a metal plate having a background image printed on its surface.
Another object of the present invention is to provide a transparent hologram laminated metal plate having a high commercial value, in which a background drawing of the metal plate and a rainbow-colored pattern of the hologram film are visually synthesized, and a method of manufacturing the same.

[0008]

SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention is directed to a polyethylene terephthalate film.
An acrylic resin layer is formed on the surface, and the acrylic resin layer
It forms a fine uneven pattern and is translucent
Between a transparent hologram film having a hologram layer formed by forming a metallized layer and a metal plate having a background image printed on the surface, a transparent synthetic resin film made of ionomer resin or low-density polyethylene. A transparent hologram laminate metal plate was formed by laminating and integrating the adhesive layer interposed therebetween to visually synthesize the background drawing of the metal plate and the pattern of the hologram film.

The present invention also relates to a polyethylene terephthalate
An acrylic resin layer is formed on the back of
A fine uneven pattern is formed on the krill resin layer.
The hologram layer is formed by forming a light-transmitting metal
On the back side of the transparent hologram film, softening temperature is lower than that of the constituent material , and Iono
Mer resin dry laminate or low density polyethylene
A transparent hologram sheet subjected to extrusion lamination and a metal plate on which a background image is printed on the surface to form a printing layer are fed to a laminating roll so that the adhesive layer and the printing layer are superimposed, and immediately before the laminating roll. The metal plate is heated at 800-1800 ° C. for 0.005-60 seconds.
Irradiating the metal plate with a flame and treating the surface of the metal plate.
A method for producing a transparent hologram-laminated metal plate heated to a temperature of 160 to 180 ° C was established.

And an ionomer resin dry laminate
In the case of ト, the hologram sheet and the metal plate laminated by passing through the above-mentioned laminating roll are heated at 155 to 165 ° C.
It is necessary to reheat in a drying furnace under the conditions of 7 to 15 minutes.

[0011]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, embodiments of the present invention will be described in more detail with reference to the accompanying drawings. FIG. 1 is a conceptual diagram showing a manufacturing process of a transparent hologram laminated metal plate according to the present invention, and FIG. 2 schematically shows a cross-sectional structure of the transparent hologram laminated metal plate. In the figure, reference numeral 1 denotes a transparent hologram sheet, 2 denotes a metal plate, 3 denotes a laminating roll, 4 denotes a heating device, 5 denotes a trimming device, and 6 denotes a drying furnace.

A transparent hologram laminated metal plate A according to the present invention comprises a transparent hologram film 7 and a pattern on its surface.
Between the metal plate 2 on which the background drawing 8 such as a pattern and a picture is printed,
The transparent hologram film 7 is firmly laminated and integrated with an adhesive layer 9 made of a transparent synthetic resin film interposed therebetween, so that the transparent hologram film 7 does not peel off from the metal plate 2 during the subsequent metal working. The background drawing 8 of the metal plate 2 and the rainbow-colored pattern of the hologram film 7 are visually combined, and the commercial value is greatly improved.

Here, in the present invention, the transparent hologram sheet 1 is integrally formed with an adhesive layer 9 made of a transparent synthetic resin film having a softening temperature lower than that of the constituent material on the back side of the transparent hologram film 7. Are laminated. The transparent hologram film 7 is formed by forming an acrylic resin layer 11 on the back surface of a polyethylene terephthalate (PET) film 10.
In addition to forming a fine concave and convex pattern 12, a light-transmitting metal deposition layer 13 is formed. The PE
A transparent hologram film 7 using a polyvinyl chloride (PVC) film in place of the T film 10 is also commercially available, but the use of the PET film 10 is more preferable because wrinkles and folds are less likely to occur. The transparent hologram film 7 is such that the state of reflection, refraction, and interference of light slightly changes depending on the viewing angle, and the color of the uneven pattern 12 changes to iridescent. The thickness of the layer 11 may be varied, and the structure and characteristics of the transparent hologram film 7 need not be limited in the present invention. The thickness of the transparent hologram film 7 used in the present invention is 12 μm, 23 μm, 50 μm, and 75 μm.
μm.

An adhesive layer 9 made of a synthetic resin film laminated and integrated on the back side of the transparent hologram film 7.
Used is one subjected to Himilan (HM) dry lamination. Here, "Himi Milan" means Mitsui
It is a trade name of an ionomer resin of DuPont Polychemical Co., Ltd., which is tough, has a high elastic effect, and has excellent impact resistance. Further, the adhesive layer 9 may be formed by performing low density polyethylene extrusion lamination. As described above, in the present invention, the transparent hologram sheet 1 in which the adhesive layer 9 is preliminarily laminated on the rear surface side of the transparent hologram film 7 is used. Adhesive layer 9 made of
May be laminated. Here, the thickness of the adhesive layer 9 is set to 25 to 50 μm.

As the metal plate 2, an iron plate, an aluminum plate, a stainless steel plate, a magnesium alloy plate, or the like can be used. The thickness of the metal plate 2 varies depending on the application. A thickness of 60 mm is used. In addition, as a method of printing the background image 8 on the surface of the metal plate 2, known gravure printing, UV printing, offset printing, or the like can be adopted.

Next, a method for manufacturing a transparent hologram laminated metal plate of the present invention will be described with reference to FIG. The transparent hologram sheet 1 is sequentially unwound from a supply roll 14, and a band-shaped metal plate 2 having a printed layer formed by printing a background image 8 on the surface in advance is bonded to the adhesive layer 9 and the printed layer 8 (background image 8). The metal plate 2 is heated by a flame treatment with a heating device 4 and heated immediately before the laminating roll 3 so that the adhesive layer 9 is melted and the transparent hologram sheet 1 is laminated. It is. Here, the flame treatment is performed by heating a direct flame at 800 to 1800 ° C., preferably 1400 to 1600 ° C. for 0.005 to 6 ° C.
This is a treatment in which the surface temperature of the metal plate 2 is heated to 160 to 180 ° C. by irradiating the metal plate 2 for 0 second, preferably 1 to 5 seconds, and the printing layer 8 has heat resistance sufficient to withstand this temperature. It is formed of a paint having:

More specifically, the metal plate 2 has a thickness of 0.1 mm.
When an iron plate of 2 to 0.24 mm is used, about 1500
Flame treatment for about 3 seconds with a direct flame of
Heated to 0-180 ° C. The laminating roll 3
When the transparent hologram sheet 1 and the heated metal plate 2 are polymerized, the adhesive layer 9 of the transparent hologram sheet 1 in contact with the metal plate 2 is melted and firmly fused to the print layer 8. The transparent hologram sheet 1 is in contact with one of the laminating rolls 3 so that the entire surface thereof is
Therefore, the hologram layer (acrylic resin layer 11, concavo-convex pattern 12, metal deposition layer 13) does not deteriorate in characteristics. Actually, the surface temperature of the transparent hologram sheet 1 immediately after laminating the transparent hologram sheet 1 and the metal plate 2 was about 150 ° C.

Then, the end portion of the hologram sheet 1 protruding from the metal plate 2 is cut by the trimming device 5 to obtain a transparent hologram laminated metal plate A.

The adhesive layer 9 of the transparent hologram sheet 1
In the case where a highland land ply laminate is used, the hologram sheet 1 and the metal plate 2 that have been laminated by passing through the laminating roll 3 are heated at 155 to 165 ° C.
It is necessary to reheat in the drying furnace 6 under the conditions of up to 15 minutes.
By reheating in the drying furnace 6, the adhesiveness between the hologram sheet 1 and the metal plate 2 is further improved. still,
The drying furnace 6 is not limited to a furnace using a flame, and may be an oven or an atmosphere furnace using hot air.

In the present invention, the metal plate 2 does not require any pre-treatment, but it is also possible to varnish the adhesive surface of the hologram sheet 1 to further improve the adhesiveness.
Also, the hologram sheet 1 can be similarly laminated even if the printing layer 8 on the surface of the metal plate 2 is omitted,
In that case, a similar effect can be expected by printing a surface drawing on the front side of the transparent hologram film 7. For printing on the front side of the transparent hologram film 7, known gravure printing, UV printing, offset printing, and the like can be adopted.

The application of the transparent hologram laminate metal plate A manufactured as described above is not limited to the above-mentioned metal can body, but may be various toys, coasters, trays, display panels, stationery, other metal containers, cosmetic containers. And the like.

[0022]

According to the transparent hologram laminated metal plate of the first aspect of the present invention, the transparent hologram film is firmly adhered to the metal plate. Since the background drawing of the metal plate and the rainbow-colored pattern of the hologram film are visually synthesized without being peeled off from the metal plate, the commercial value is greatly improved. Ma
In addition, polyethylene terephthalate film was used as the base film.
The use of film makes it difficult for wrinkles and folds to be formed,
Hologram layer protection
A real, further ionomer resin on the back surface of the hologram layer
Dry lamination or low density polyethylene extrusion lamination
The metal plate with a printed layer on the surface.
Good adhesion to

The transparent hologram laminate according to the second aspect of the present invention.
According to the method of manufacturing a metal plate , a transparent hologram laminated metal plate can be easily manufactured with a simple process and a short working time, and therefore, the stability of the work, and furthermore, the stability of the performance and the cost reduction are achieved, Moreover, since the transparent hologram film adheres firmly to the metal plate, the transparent hologram film does not peel off from the metal plate during handling or metal processing, and shines in the rainbow color of the background drawing of the metal plate and the hologram film. The pattern and the pattern are visually combined, and the commercial value is greatly improved. Ma
In addition, only the necessary parts can be heated in a short time
Changes the background image formed on the surface of the metal plate
Can be prevented, and the metal plate or hologram sheet
Even if no treatment is applied, sufficient adhesive strength can be obtained.
You. In addition, polyethylene terephthale
Wrinkles and folds are hard to be formed because
It has excellent weather resistance and impact resistance,
Protection and the ionomer on the back of the hologram layer.
-Resin dry lamination or low density polyethylene pressing
The printed layer was formed on the surface.
Good adhesion to metal plates.

According to claim 3, a transparent hologram fill is provided.
This further improves the adhesiveness between the system and the metal plate.

[Brief description of the drawings]

FIG. 1 is a simplified explanatory view showing a method for producing a transparent hologram laminated metal plate of the present invention.

FIG. 2 is a cross-sectional view schematically showing a transparent hologram laminated metal plate of the present invention.

[Explanation of symbols]

 A transparent hologram laminated metal plate 1 transparent hologram sheet 2 metal plate 3 laminating roll 4 heating device 5 trimming device 6 drying furnace or oven 7 hologram film 8 background drawing (printing layer) 9 adhesive layer 10 PET film 11 acrylic resin layer 12 uneven pattern 13 Metal deposition layer 14 Supply roll

Continuation of front page (58) Field surveyed (Int.Cl. ⁷ , DB name) B32B 15/00-15/20

Claims (3)

(57) [Claims] 1. A polyethylene terephthalate film
An acrylic resin layer is formed on the back surface, and the acrylic resin layer
Form a fine uneven pattern and have translucency
Between a transparent hologram film with a hologram layer formed by forming a metal deposition layer and a metal plate with a background image printed on the surface, an ionomer resin or low-density polyethylene
A transparent hologram laminated metal plate characterized by being laminated and integrated with an adhesive layer made of a transparent synthetic resin film interposed therebetween, and visually synthesizing the background drawing of the metal plate and the pattern of the hologram film. . 2. A polyethylene terephthalate film
An acrylic resin layer is formed on the back surface, and the acrylic resin layer
Form a fine uneven pattern and have translucency
On the back side of the transparent hologram film on which a hologram layer is formed by forming a metal deposition layer, the softening temperature is lower than that of the constituent materials.
Low-cost, ionomer resin dryer as a transparent adhesive layer
Minate or low density polyethylene extrusion laminate
A transparent hologram sheet and a metal plate having a printed layer formed by printing a background image on the surface are fed to a laminating roll so that the adhesive layer and the printing layer are superimposed, and the metal sheet is formed immediately before the laminating roll. Board, 800 ~
A direct flame of 1800 ° C is applied to the metal plate for 0.005 to 60 seconds.
Irradiation and flame treatment to reduce the surface temperature of the metal plate to 160-1
A method for producing a transparent hologram laminated metal plate, characterized by heating to 80 ° C. 3. The laminated sheet passing through the laminating roll.
Between the hologram sheet and the metal plate
The method for producing a transparent hologram-laminated metal sheet according to claim 2, wherein the sheet is reheated in a drying oven at 7 ° C for 7 to 15 minutes .