JP3267700B2 - Preservative for fiber treatment oil - Google Patents
Preservative for fiber treatment oilInfo
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- JP3267700B2 JP3267700B2 JP30066092A JP30066092A JP3267700B2 JP 3267700 B2 JP3267700 B2 JP 3267700B2 JP 30066092 A JP30066092 A JP 30066092A JP 30066092 A JP30066092 A JP 30066092A JP 3267700 B2 JP3267700 B2 JP 3267700B2
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- oil
- fiber treatment
- parts
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- oils
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Description
【０００１】[0001]
【産業上の利用分野】本発明は繊維処理油剤用防腐剤に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a preservative for a fiber treatment oil.
【０００２】[0002]
【従来の技術】合成繊維の製糸工程、仮撚加工工程、製
編織準備工程などで、良品質の繊維製品を効率よく製造
するために、種々の繊維処理用油剤が使用されている。
繊維処理用油剤は通常、水で５〜１００倍に希釈して使
用されるため、きわめて腐敗し易く、夏季では３〜４
日、冬季でも７〜８日で腐敗し、腐敗臭を発すると共
に、エマルジョンの分離が起こる。その結果、繊維処理
用油剤を取扱う各種工程で種々の障害が発生する。2. Description of the Related Art Various fiber treatment oils have been used for efficiently producing high-quality fiber products in the process of producing synthetic fibers, the process of false twisting, and the process of preparing knitting and weaving.
Since the oil agent for fiber treatment is usually used after being diluted 5 to 100 times with water, it is very susceptible to decay, and 3 to 4 in summer.
Even in winter, it rots in 7 to 8 days, emits a rot odor and separates the emulsion. As a result, various obstacles occur in various processes for handling the oil agent for fiber treatment.
【０００３】例えば紡糸工程で糸の平滑性又は潤滑性を
向上させるために、循環する繊維処理用油剤に浸したオ
イリングローラー上を一定の速度で糸を移動させる場合
に、腐敗した油剤を使用すると、腐敗油剤から発生する
スカムのため、オイリングローラー受皿の循環用ノズル
に目詰まりを起こし、油剤の循環を妨げ、あるいは糸質
に悪影響、例えば糸の着色、糸の毛ば立ち等を与えるな
どの障害が起こる。そのために従来は油剤にトリス（ヒ
ドロキシメチル）ニトロメタン、ヘキサクロロフェン等
の殺菌剤が使用されてきたが、満足すべき効力を有せ
ず、有効な繊維処理油剤用防腐剤の出現が望まれてい
る。For example, in order to improve the smoothness or lubricity of a yarn in a spinning process, when a yarn is moved at a constant speed on an oiling roller immersed in a circulating oil for treating fibers, a putrid oil is used. The scum generated from putrefactive oil causes clogging of the circulation nozzle of the oiling roller tray, hinders the circulation of the oil, or adversely affects the yarn quality, for example, coloring the yarn, giving the yarn fluff, etc. Failure occurs. For this purpose, tris (hydroxymethyl) nitromethane, hexachlorophene, and other bactericides have conventionally been used as oil agents, but they do not have satisfactory efficacy, and the emergence of an effective preservative for fiber treatment oil agents is desired. .
【０００４】[0004]
【発明が解決しようとする課題および手段】本発明者ら
は、繊維処理用油剤を水で希釈して使用した場合に生ず
る腐敗を防止するため、研究を進めた結果、本発明を完
成した。本発明は、鉱油、流動パラフィン、スピンドル
油、菜種油、オリーブ油、綿実油、ヤシ油、コーン油、
牛脂、魚油、鯨油、これらの加工油の少なくとも１種か
らなる繊維処理油に対する防腐剤であって、メチレンビ
スチオシアネートと２−ブロモ−２−ニトロプロパン−
１，３−ジオールを１：２０〜２０：１の重量比で含有
し、かつ前記繊維処理油の実際の使用状態下において５
〜２０００ｐｐｍとなるように添加することを特徴とす
る繊維処理油剤用防腐剤である。DISCLOSURE OF THE INVENTION The inventors of the present invention have conducted studies to prevent spoilage which occurs when an oil agent for fiber treatment is diluted with water and used. As a result, the present invention has been completed. The present invention relates to mineral oil, liquid paraffin, spindle
Oil, rapeseed oil, olive oil, cottonseed oil, coconut oil, corn oil,
Tallow, fish oil, whale oil, at least one of these processed oils
Preservatives for fiber treatment oils comprising methylene bisthiocyanate and 2-bromo-2-nitropropane-
Contains 1,3-diol in a weight ratio of 1:20 to 20: 1
And 5 under the actual use condition of the fiber treatment oil.
It is a preservative for a fiber treatment oil characterized by being added so as to be ２０００2000 ppm .
【０００５】本発明における繊維処理用油剤は、鉱油、
流動パラフィン、スピンドル油の鉱物油、菜種油、オリ
ーブ油、綿実油、ヤシ油、コーン油の植物油、牛脂、魚
油、鯨油の動物油、硬化油その他の加工油が用いられ
る。繊維処理用油剤は、通常、界面活性剤、帯電防止剤
等を含有している。界面活性剤としては、下記の化合物
が用いられる。オレイン酸、半硬化牛脂、ヒマシ油など
の脂肪酸塩、ウラリル硫酸塩、高級アルコール硫酸塩、
アルキルベンゼンスルホン酸塩、アルキルナフタレンス
ルホン酸塩、ジアルキルスルホコハク酸塩、アルキルリ
ン酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、
ポリオキシエチレンアルキルエーテル硫酸アミン塩、ポ
リオキシエチレンアルキルフェノールエーテル硫酸塩、
ナフタリンスルホン酸ホルマリン縮合物、高分子活性剤
等の陰イオン界面活性剤。[0005] fiber treatment oil agent in the present invention, mineral oil,
Mineral oils, liquid paraffin, spindle oil, rapeseed oil, olive oil, cottonseed oil, coconut oil, vegetable oil corn oil, beef tallow, fish oils, animal oils whale oil, hydrogenated oil and other processing oil is used. The fiber treatment oil agent usually contains a surfactant, an antistatic agent and the like. The following compounds are used as the surfactant. Fatty acid salts such as oleic acid, semi-hardened tallow, castor oil, uralyl sulfate, higher alcohol sulfate,
Alkyl benzene sulfonate, alkyl naphthalene sulfonate, dialkyl sulfosuccinate, alkyl phosphate, polyoxyethylene alkyl ether sulfate,
Polyoxyethylene alkyl ether sulfate amine salt, polyoxyethylene alkyl phenol ether sulfate,
Anionic surfactants such as naphthalenesulfonic acid formalin condensate and polymer activator.
【０００６】ポリオキシエチレンアルキルエーテル、ポ
リオキシエチレンアルキルフェノールエーテル、ポリオ
キシエチレン高級アルコールエーテル、ソルビタンアル
キルエステル、ポリオキシエチレンソルビタンアルキル
エステル、ポリエチレングリコールアルキルエステル、
高級脂肪酸のグリセライド、オキシエチレンオキシプロ
ピレンブロックポリマー等の非イオン界面活性剤。Polyoxyethylene alkyl ether, polyoxyethylene alkyl phenol ether, polyoxyethylene higher alcohol ether, sorbitan alkyl ester, polyoxyethylene sorbitan alkyl ester, polyethylene glycol alkyl ester,
Nonionic surfactants such as glycerides of higher fatty acids and oxyethyleneoxypropylene block polymers.
【０００７】メチレンビスチオシアネートは、製紙用ス
ライム・コントロール剤として使用されている。また２
−ブロモ−２−ニトロプロパン−１，３−ジオールは製
紙用スライム・コントロール剤、一般の工業製品例えば
ラテックスの防腐剤として使用されている。[0007] Methylene bisthiocyanate has been used as a slime control agent for papermaking. Also 2
-Bromo-2-nitropropane-1,3-diol is used as a slime control agent for papermaking and as a preservative for general industrial products such as latex.
【０００８】本発明の防腐剤は、メチレンビスチオシア
ネートと２−ブロモ−２−ニトロプロパン−１，３−ジ
オールを溶媒に溶解し、液剤として使用することが好ま
しい。溶媒としては、例えばメタノール、エタノール、
イソプロパノール等のアルコール類、エチレングリコー
ル、ジエチレングリコール、ジエチレングリコール、ト
リエチレングリコール、ポリエチレングリコール、エチ
レングリコールモノメチルエーテル、エチレングリコー
ルモノブチルエーテル、ジエチレングリコールモノメチ
ルエーテル、ジエチレングリコールモノブチルエーテ
ル、メトキシ化ポリエチレングリコール等のグリコール
類、エチレングリコールジアセテート、ジメチルスルホ
キシド等が用いられる。本発明の防腐剤は、繊維処理用
油剤に直接添加してもよく、水希釈液に添加してもよ
い。添加量は水希釈液に対し、５〜２０００ｐｐｍ好ま
しくは５０〜１０００ｐｐｍである。The preservative of the present invention is preferably used as a solution by dissolving methylene bisthiocyanate and 2-bromo-2-nitropropane-1,3-diol in a solvent. As the solvent, for example, methanol, ethanol,
Alcohols such as isopropanol, ethylene glycol, diethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, glycols such as methoxylated polyethylene glycol, ethylene glycol di Acetate, dimethyl sulfoxide and the like are used. The preservative of the present invention may be added directly to the oil agent for treating fibers or may be added to a water diluent. The addition amount is 5 to 2000 ppm, preferably 50 to 1000 ppm, based on the water diluent.
【０００９】[0009]
【実施例】下記例中の部は重量部を表す。 製剤例１ メチレンビスチオシアネート ２部 ２−ブロモ−２−ニトロプロパン−１，３−ジオール １３部 ジエチレングリコールモノメチルエーテル ８５部 攪拌溶解して液剤を得た。 製剤例２ メチレンビスチオシアネート ５部 ２−ブロモ−２−ニトロプロパン−１，３−ジオール １０部 ジエチレングリコールモノメチルエーテル ８５部 攪拌溶解して液剤を得た。 製剤例３ メチレンビスチオシアネート ７．５部 ２−ブロモ−２−ニトロプロパン−１，３−ジオール ７．５部 ジエチレングリコールモノメチルエーテル ８５部 加温攪拌溶解して液剤を得た。EXAMPLES In the following examples, parts are parts by weight. Formulation Example 1 methylene bisthiocyanate 2 parts 2-bromo-2-nitropropane-1,3-diol 13 parts Diethylene glycol monomethyl ether 85 parts A solution was obtained by stirring and dissolving. Formulation Example 2 Methylene bisthiocyanate 5 parts 2-Bromo-2-nitropropane-1,3-diol 10 parts Diethylene glycol monomethyl ether 85 parts A solution was obtained by stirring and dissolving. Formulation Example 3 Methylene bisthiocyanate 7.5 parts 2-bromo-2-nitropropane-1,3-diol 7.5 parts Diethylene glycol monomethyl ether 85 parts A solution was obtained by heating and stirring to dissolve.
【００１０】製剤例４ メチレンビスチオシアネート １０部 ２−ブロモ−２−ニトロプロパン−１，３−ジオール ５部 エチレングリコールモノメチルエーテル ８５部 加温攪拌溶解して液剤を得た。 製剤例５ メチレンビスチオシアネート １３部 ２−ブロモ−２−ニトロプロパン−１，３−ジオール ２部 エチレングリコールモノメチルエーテル ８５部 加温攪拌溶解して液剤を得た。 比較製剤例１ メチレンビスチオシアネート １５部 エチレングリコールモノメチルエーテル ８５部 攪拌溶解して液剤を得た。 比較製剤例２ ２−ブロモ−２−ニトロプロパン−１，３−ジオール １５部 エチレングリコール ８５部 攪拌溶解して液剤を得た。Formulation Example 4 Methylene bisthiocyanate 10 parts 2-Bromo-2-nitropropane-1,3-diol 5 parts Ethylene glycol monomethyl ether 85 parts A solution was obtained by heating and stirring to dissolve. Formulation Example 5 methylene bisthiocyanate 13 parts 2-bromo-2-nitropropane-1,3-diol 2 parts Ethylene glycol monomethyl ether 85 parts A solution was obtained by heating and stirring to dissolve. Comparative Preparation Example 1 Methylene bisthiocyanate 15 parts Ethylene glycol monomethyl ether 85 parts A solution was obtained by stirring and dissolving. Comparative Preparation Example 2 2-bromo-2-nitropropane-1,3-diol 15 parts Ethylene glycol 85 parts A solution was obtained by stirring and dissolving.
【００１１】実施例１ 菜種油３０部、流動パラフィン１０部、牛脂１５部、ラ
ウリルアルコール硫酸エステル３５部、ニッサンノニオ
ン０−４（非イオン界面活性剤、日本油脂社製）４部、
ニッサンノニオン０−１５（非イオン界面活性剤、日本
油脂社製）３部より成る油剤に各防腐剤を３部攪拌溶解
した。（防腐剤有効成分として０．４５％）各油剤をイ
オン交換水で２０倍に希釈してエマルジョンとし、これ
に繊維工場より採取した油剤の腐敗油を２％の割合で加
え、３７℃の恒温槽中に入れて、７０回／分の速度で振
盪した。４日後及び７日後に各希釈液を取出して腐敗の
有無及び細菌類、カビ類、酵母類の生菌数（個／ｍｌ）
を測定した。 生菌数測定法 エマルジョン中の生菌数測定は混釈平板培養法で行っ
た。測定条件は次の通り 細菌類：ブイヨン寒天培地、３３℃、４８時間培養 酵母類：サブロー寒天培地、２８℃、７日間培養 かび類：サブロー寒天培地、２８℃、７日間培養 試験結果を表１に示す。Example 1 30 parts of rapeseed oil, 10 parts of liquid paraffin, 15 parts of beef tallow, 35 parts of lauryl alcohol sulfate, 4 parts of Nissan Nonion 0-4 (nonionic surfactant, manufactured by NOF Corporation),
3 parts of each preservative was stirred and dissolved in 3 parts of Nissan Nonion 0-15 (nonionic surfactant, manufactured by NOF CORPORATION). (0.45% as the preservative active ingredient) Each oil was diluted 20 times with ion-exchanged water to form an emulsion, to which was added 2% of decay oil of the oil collected from a textile factory, and the temperature was kept constant at 37 ° C. It was placed in a tank and shaken at a rate of 70 times / min. After 4 days and 7 days, each diluent is taken out to determine the presence or absence of decay and the viable count of bacteria, molds, and yeasts (number / ml).
Was measured. Viable cell count method The viable cell count in the emulsion was measured by a pour plate culture method. The measurement conditions are as follows Bacteria: Bouillon agar medium, cultivated at 33 ° C. for 48 hours Yeast: Sabouraud agar medium, cultivated at 28 ° C. for 7 days Molds: Sabouraud agar medium, cultivated at 28 ° C. for 7 days Test results are shown in Table 1. Shown in
【００１２】[0012]
【表１】 [Table 1]
【００１３】実施例２ ナイロン原糸用繊維処理油剤を用いてオイリングローラ
ー試験を行った。繊維処理油剤を約３０℃のイオン交換
水に攪拌下少量づつ添加し、エマルジョン濃度１０％、
ｐＨ７．１のエマルジョンを調製した。ビーカーにエマ
ルジョンを１リットル採り、防腐剤を８００ｐｐｍ添加
後循環ポンプを用いてビーカーとオイルパンの間を５０
ｍｌ／分の循環量、温度３０℃で循環させた。尚オイリ
ングローラーは１０回転／分で回転させた。試験中は毎
日１０％量のエマルジョンを抜き取り、新しく調製した
油剤エマルジョン（防腐剤８００ｐｐｍ入り）と交換し
た。また毎日腐敗エマルジョンを種菌として１ｍｌ加え
た。効果の判定は、エマルジョン中の菌数測定とオイリ
ングローラーへのスカムの付着量でみた。結果を表２に
示す。本発明の製剤を添加した場合は、３０日目の細菌
数が０であり、オイリングローラーにスライム付着が認
められず、非常に優れていることがわかる。Example 2 An oiling roller test was conducted using a fiber treatment oil agent for a nylon yarn. The fiber treatment oil was added little by little to the ion-exchanged water at about 30 ° C with stirring, and the emulsion concentration was 10%.
An emulsion having a pH of 7.1 was prepared. Take 1 liter of the emulsion into a beaker, add 800 ppm of preservative, and use a circulating pump to move
Circulation was performed at a circulation rate of 30 ml. The oiling roller was rotated at 10 revolutions / minute. During the test, 10% of the emulsion was withdrawn every day and replaced with a freshly prepared oil emulsion (containing 800 ppm of preservative). Further, 1 ml of the putrefaction emulsion was added daily as a seed fungus. The effect was determined by measuring the number of bacteria in the emulsion and the amount of scum adhering to the oiling roller. Table 2 shows the results. When the preparation of the present invention was added, the number of bacteria on day 30 was 0, and no slime was observed on the oiling roller, indicating that the preparation was extremely excellent.
【００１４】[0014]
【表２】 [Table 2]
【００１５】実施例３ ３５００ｍ／分で紡糸したポリエステル繊維の巻取工程
のオイリングローラーで使用する繊維処理用油剤エマル
ジョン（１０倍希釈液）に、製剤例２の防腐剤が８００
ｐｐｍになるように添加し、操業を開始した。３週間後
オイリングローラーにスカムの付着は認められず、エマ
ルジョン中の細菌数は２．１×１０2 個／ｍｌであり、
操業上の問題は認められなかった。防腐剤無添加の繊維
処理油剤を用いると、１週間後オイリングローラ全面に
スカムが付着し、操業不可となった。エマルジョン中の
細菌数は３．８×１０8 個／ｍｌであった。本発明の繊
維処理油剤用防腐剤は優れていることがわかる。Example 3 The preservative of Formulation Example 2 was added to the oil treatment emulsion for fiber treatment (10-fold dilution) used in the oiling roller in the winding step of the polyester fiber spun at 3500 m / min.
ppm, and the operation was started. After 3 weeks, no scum was adhered to the oiling roller, and the number of bacteria in the emulsion was 2.1 × 10 2 / ml.
No operational problems were noted. When a fiber treatment oil solution without preservatives was used, scum adhered to the entire surface of the oiling roller after one week, and operation was impossible. The number of bacteria in the emulsion was 3.8 × 10 8 cells / ml. It turns out that the preservative for fiber treatment oil agents of the present invention is excellent.
【００１６】[0016]
【発明の効果】本発明の防腐剤を繊維処理油剤の水希釈
液に添加すると、腐敗臭の発生及びエマルジョンの分離
を長期間にわたり防止することができる。When the preservative of the present invention is added to a water dilution of a fiber treatment oil, the generation of putrefaction odor and the separation of emulsion can be prevented for a long period of time.
フロントページの続き (72)発明者 福田 武 神奈川県横浜市金沢区鳥浜町14−29 株 式会社パーマケム・アジア内 (72)発明者 渡辺 道雄 神奈川県横浜市金沢区鳥浜町14−29 株 式会社パーマケム・アジア内 (56)参考文献 特開 平２−53703（ＪＰ，Ａ) 特開 平２−42007（ＪＰ，Ａ) 特開 昭61−251603（ＪＰ，Ａ) 特開 昭52−61221（ＪＰ，Ａ) 特公 昭40−8917（ＪＰ，Ｂ１) (58)調査した分野(Int.Cl.7，ＤＢ名) A01N 47/46 - 47/48 A01N 35/08 A01N 33/20 ＣＡ（ＳＴＮ) ＲＥＧＩＳＴＲＹ（ＳＴＮ)Continued on the front page (72) Inventor Takeshi Fukuda 14-29 Torihamacho, Kanazawa-ku, Yokohama-shi, Kanagawa Prefecture Inside Permachem Asia Co., Ltd. (72) Michio Watanabe 14-29 Torihamacho, Kanazawa-ku, Yokohama-shi, Kanagawa Corporation Permachem Asia (56) References JP-A-2-53703 (JP, A) JP-A-2-42007 (JP, A) JP-A-61-251603 (JP, A) JP-A-52-61221 (JP) , A) JP 40-8917 (JP, B1) (58) Fields investigated (Int. Cl. 7 , DB name) A01N 47/46-47/48 A01N 35/08 A01N 33/20 CA (STN) REGISTRY (STN)
Claims (1)
菜種油、オリーブ油、綿実油、ヤシ油、コーン油、牛
脂、魚油、鯨油、これらの加工油の少なくとも１種から
なる繊維処理油に対する防腐剤であって、メチレンビス
チオシアネートと２−ブロモ−２−ニトロプロパン−
１，３−ジオールを１：２０〜２０：１の重量比で含有
し、かつ前記繊維処理油の実際の使用状態下において５
〜２０００ｐｐｍとなるように添加することを特徴とす
る繊維処理油剤用防腐剤。Claims: 1. Mineral oil, liquid paraffin, spindle oil,
Rapeseed oil, olive oil, cottonseed oil, coconut oil, corn oil, cow
Fat, fish oil, whale oil, at least one of these processing oils
Preservatives against fiber treatment oils comprising methylene bisthiocyanate and 2-bromo-2-nitropropane-
Contains 1,3-diol in a weight ratio of 1:20 to 20: 1
And 5 under the actual use condition of the fiber treatment oil.
An antiseptic for fiber treatment oils, which is added so as to be 2,000 ppm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30066092A JP3267700B2 (en) | 1992-10-14 | 1992-10-14 | Preservative for fiber treatment oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30066092A JP3267700B2 (en) | 1992-10-14 | 1992-10-14 | Preservative for fiber treatment oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06128113A JPH06128113A (en) | 1994-05-10 |
| JP3267700B2 true JP3267700B2 (en) | 2002-03-18 |
Family
ID=17887538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30066092A Expired - Lifetime JP3267700B2 (en) | 1992-10-14 | 1992-10-14 | Preservative for fiber treatment oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3267700B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2666746C1 (en) * | 2017-05-17 | 2018-09-12 | Ювеналий Александрович Крутяков | Device for achieving supersonic speeds |
-
1992
- 1992-10-14 JP JP30066092A patent/JP3267700B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2666746C1 (en) * | 2017-05-17 | 2018-09-12 | Ювеналий Александрович Крутяков | Device for achieving supersonic speeds |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06128113A (en) | 1994-05-10 |
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