JP3257255B2 - Cutting tools made of cubic boron nitride based ultra-high pressure sintered material with excellent wear resistance - Google Patents
Cutting tools made of cubic boron nitride based ultra-high pressure sintered material with excellent wear resistanceInfo
- Publication number
- JP3257255B2 JP3257255B2 JP14718994A JP14718994A JP3257255B2 JP 3257255 B2 JP3257255 B2 JP 3257255B2 JP 14718994 A JP14718994 A JP 14718994A JP 14718994 A JP14718994 A JP 14718994A JP 3257255 B2 JP3257255 B2 JP 3257255B2
- Authority
- JP
- Japan
- Prior art keywords
- high pressure
- sintered material
- wear resistance
- cubic boron
- nitride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Ceramic Products (AREA)
Description
【0001】[0001]
【産業上の利用分野】この発明は、特に鋳鉄や鋼などの
高速切削に用いた場合にすぐれた耐摩耗性を発揮する立
方晶窒化硼素(以下、CBNで示す)基超高圧焼結材料
製切削工具に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cubic boron nitride (hereinafter referred to as CBN) -based ultra-high pressure sintered material which exhibits excellent wear resistance particularly when used for high-speed cutting of cast iron and steel. It relates to a cutting tool.
【0002】[0002]
【従来の技術】従来、一般に、例えば特開昭59−27
303号公報に記載されるように、結合相形成成分とし
てTiの炭化物、窒化物、および炭窒化物(以下、それ
ぞれTiC、TiN、およびTiCNで示す)のうちの
1種または2種以上からなるTi炭・窒化物:20〜4
0%を含有し、残りが分散相形成成分としてのCBNと
不可避不純物からなる組成(以上容量%、以下%は容量
%を示す)を有するCBN基超高圧焼結材料で構成され
た切削工具が知られており、またこれが鋳鉄や鋼などの
切削に用いられていることも知られている。2. Description of the Related Art Conventionally, for example, Japanese Patent Application Laid-Open No.
As described in JP-A-303, one or more of Ti carbides, nitrides, and carbonitrides (hereinafter referred to as TiC, TiN, and TiCN, respectively) are used as a binder phase forming component. Ti charcoal / nitride: 20-4
A cutting tool comprising a CBN-based ultrahigh-pressure sintered material containing 0% and a balance of CBN as a disperse phase forming component and unavoidable impurities (above volume%, below% represents volume%). It is also known that it is used for cutting cast iron and steel.
【0003】[0003]
【発明が解決しようとする課題】一方、近年の切削機械
の高性能化はめざましく、省力化と相まって、切削速度
は高速化の傾向にあるが、上記の従来CBN基超高圧焼
結材料製切削工具においては、これを用いて高速切削を
行なうと、摩耗進行がきわめて速く、比較的短時間で使
用寿命に至るものである。On the other hand, in recent years, the performance of cutting machines has been remarkably improved, and the cutting speed tends to be increased in conjunction with labor saving. When a tool is used to perform high-speed cutting, wear progresses extremely rapidly, and the tool life is shortened in a relatively short time.
【0004】[0004]
【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の従来CBN基超高圧焼結
材料製切削工具に着目し、これの耐摩耗性向上をはかる
べく研究を行なった結果、上記の従来CBN基超高圧焼
結材料製切削工具において、これを構成するCBN基超
高圧焼結材料の結合相を、Ti炭・窒化物の素地に、い
ずれも0.5μm以下の粒径を有する炭化タングステン
(以下、WCで示す)、窒化アルミニウム(以下、Al
Nで示す)、硼化チタニウム(以下、TiB2 で示
す)、および酸化アルミニウム(以下、Al2 O3 で示
す)が、いずれも全体に占める割合で、WC:0.1〜
2%、 AlN:1〜5%、TiB2 :3〜7%、
Al2 O3 :5〜15%、の割合で分散分布した
組織を有するもので構成すること、この結果のCBN基
超高圧焼結材料からなる切削工具は、これを高速切削に
用いてもすぐれた耐摩耗性を示し、長期に亘ってすぐれ
た切削性能を発揮するようになるという研究結果を得た
のである。Means for Solving the Problems Accordingly, the present inventors have
From the above-mentioned viewpoint, the above-mentioned conventional CBN-based ultra-high pressure sintered material cutting tool was focused on, and as a result of researching to improve the wear resistance thereof, the above-mentioned conventional CBN-based ultra-high pressure sintered material was manufactured. In a cutting tool, a binder phase of a CBN-based ultra-high pressure sintered material constituting the cutting tool is formed on a Ti carbon / nitride base material by using tungsten carbide (hereinafter, referred to as WC) having a particle size of 0.5 μm or less. Aluminum nitride (hereinafter, Al
N), titanium boride (hereinafter referred to as TiB 2 ), and aluminum oxide (hereinafter referred to as Al 2 O 3 ), all of which account for WC: 0.1 to
2%, AlN: 1~5%, TiB 2: 3~7%,
Al 2 O 3 : A structure having a structure dispersed and distributed at a ratio of 5 to 15%. The resulting cutting tool made of a CBN-based ultrahigh-pressure sintered material is excellent even when it is used for high-speed cutting. The research results show that the steel shows excellent wear resistance and exhibits excellent cutting performance over a long period of time.
【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、以下いずれも結合相形成成分と
して、TiC、TiN、およびTiCNのうちの1種ま
たは2種以上からなるTi炭・窒化物:20〜40%、
WC:0.1〜2%、 AlN:1〜5%、TiB
2 :3〜7%、 Al2 O3 :5〜15%、を含有
し、残りが分散相形成成分としてのCBNと不可避不純
物からなる組成を有し、かつ結合相が、Ti炭・窒化物
の素地に粒径がいずれも0.5μm以下のWC,Al
N,TiB2 、およびAl2 O3 が分散分布した組織を
有するCBN基超高圧焼結材料で構成してなる耐摩耗性
のすぐれたCBN基超高圧焼結材料製切削工具に特徴を
有するものである。The present invention has been made based on the results of the above-mentioned research, and in any of the following, any one of TiC, TiN, and TiCN composed of at least one of TiC, TiN, and TiCN as a binder phase forming component. Nitride: 20-40%,
WC: 0.1 to 2%, AlN: 1 to 5%, TiB
2 : 3 to 7%, Al 2 O 3 : 5 to 15%, the remainder has a composition comprising CBN as a dispersed phase forming component and unavoidable impurities, and the binder phase is Ti charcoal / nitride. WC, Al with a particle size of 0.5 μm or less
Characterized by a cutting tool made of a CBN-based ultra-high pressure sintered material having excellent wear resistance and made of a CBN-based ultra-high pressure sintered material having a structure in which N, TiB 2 , and Al 2 O 3 are dispersed and distributed. It is.
【0006】つぎに、この発明の切削工具において、こ
れを構成するCBN基超高圧焼結材料の成分組成を上記
の通りに限定した理由を説明する。 (a) Ti炭・窒化物 これらの成分には、強度と靭性を向上させる作用がある
が、その含有量が20%未満では前記作用に所望の効果
が得られず、この結果切削加工に際して切刃に欠けやチ
ッピング(微小欠け)が発生し易くなり、一方その含有
量が40%を越えると耐摩耗性が急激に低下するように
なることから、その含有量を20〜40%と定めた。望
ましくは30〜35%の含有がよい。Next, the reason why the component composition of the CBN-based ultrahigh-pressure sintered material constituting the cutting tool of the present invention is limited as described above will be described. (A) Ti charcoal / nitride These components have the effect of improving the strength and toughness. However, if the content is less than 20%, the desired effect cannot be obtained in the above-mentioned effect. Chipping and chipping (small chipping) easily occur in the blade, and when the content exceeds 40%, the wear resistance rapidly decreases. Therefore, the content is set to 20 to 40%. . Desirably, the content is 30 to 35%.
【0007】(b) WC,AlN,TiB2 、および
Al2 O3 これらの成分には、上記の通りTi炭・窒化物の素地に
共存した状態で分散分布して結合相を強化し、もって耐
摩耗性の向上に寄与する作用があり、したがってこれら
4成分のうちのいずれかでもWC:0.1%未満、Al
N:1%未満、TiB2 :3%未満、およびAl
2 O3 :5%未満になると所望の耐摩耗性向上効果が得
られず、またこれら4成分のうちのいずれかでもWC:
2%、AlN:5%,TiB2 :7%、およびAl2 O
3 :15%を越えても耐摩耗性に低下傾向が現われるよ
うになることから、その含有量をWC:0.1〜2%、
AlN:1〜5%、TiB2 :3〜7%、およびAl2
O3 :5〜15%と定めた。なお、望ましくはWC:
0.5〜1%、AlN:2〜4%、TiB2 :4〜6
%、およびAl2 O3 :7〜12%の含有がよい。ま
た、これらの成分の粒径が0.5μmを越えて大きくな
ると、これが起点のチッピングが発生し易くなることか
ら、その粒径を0.5μm以下と定めた。(B) WC, AlN, TiB 2 , and Al 2 O 3 As described above, these components are dispersed and distributed in the state of coexisting with the Ti carbon / nitride matrix to strengthen the binder phase. It has the effect of contributing to the improvement of wear resistance, so that any one of these four components has a WC: less than 0.1%, Al
N: less than 1%, TiB 2 : less than 3%, and Al
If the content of 2 O 3 is less than 5%, the desired effect of improving abrasion resistance cannot be obtained.
2%, AlN: 5%, TiB 2: 7%, and Al 2 O
3 : Since the wear resistance tends to decrease even if it exceeds 15%, the content is set to WC: 0.1 to 2%,
AlN: 1~5%, TiB 2: 3~7%, and Al 2
O 3: was defined as 5-15%. Preferably, WC:
0.5~1%, AlN: 2~4%, TiB 2: 4~6
% And Al 2 O 3 : 7 to 12%. Further, when the particle size of these components is larger than 0.5 μm, chipping at the starting point tends to occur, so the particle size is set to 0.5 μm or less.
【0008】[0008]
【実施例】原料粉末として、1〜3.5μmの範囲内の
平均粒径を有するCBN粉末、同じく0.5〜1.8μ
mの範囲内の平均粒径を有するTiC粉末、TiN粉
末、およびTiCN粉末、さらにいずれも0.5μm以
下の粒度を有するWC粉末、AlN粉末、TiB2 粉
末、およびAl2 O3 粉末を用意し、これら原料粉末を
表1,2に示される配合組成に配合し、混合に際して
は、まずCBN粉末を除く原料粉末をWC基超硬合金ボ
ールと適量のアセトンと共にWC基超硬合金で内張りさ
れた容器に装入し、この容器をボールミルに装着して粉
砕および混合を行ない、ついでこれにCBN粉末を加
え、回転ボールミルで72時間の湿式混合を行ない、乾
燥後、3ton /cm2 の圧力で直径:20mm×厚さ:1.
5mmの寸法をもった圧粉体にプレス成形し、この圧粉体
を3×10-4torrの真空中、1000〜1300℃の範
囲内の所定温度に30分間保持の条件で仮焼結し、引続
いて直径:20mm×厚さ:2mmの寸法をもったWC基超
硬合金母材と重ね合わせた状態で超高圧焼結装置に装入
し、5GPaで1200〜1400℃の範囲内の所定温
度に30分間保持の条件で超高圧焼結し、上下面を研削
し、ワイヤカットにて4分割し、WC基超硬合金製台金
にろう付けし、所定のスローアウエイチップ形状に研磨
仕上げすることにより実質的に配合組成と同じ成分組成
をもった本発明CBN基超高圧焼結材料製切削工具(以
下、本発明切削工具という)1〜15、および比較CB
N基超高圧焼結材料製切削工具(以下、比較切削工具と
いう)1〜8をそれぞれ製造した。EXAMPLES As raw material powder, CBN powder having an average particle size in the range of 1 to 3.5 μm, and 0.5 to 1.8 μm
m, a TiC powder, a TiN powder, and a TiCN powder having an average particle diameter in the range of m, a WC powder, an AlN powder, a TiB 2 powder, and an Al 2 O 3 powder each having a particle diameter of 0.5 μm or less. These raw material powders were blended into the compounding compositions shown in Tables 1 and 2, and at the time of mixing, the raw material powders except for the CBN powder were first lined with a WC-based cemented carbide with WC-based cemented carbide balls and an appropriate amount of acetone. The mixture was charged in a container, and the container was mounted on a ball mill to grind and mix. Then, CBN powder was added thereto, and the mixture was wet-mixed in a rotary ball mill for 72 hours. After drying, the diameter was increased at a pressure of 3 ton / cm 2. : 20mm x thickness: 1.
It is press-molded into a green compact having a size of 5 mm, and this green compact is temporarily sintered in a vacuum of 3 × 10 -4 torr at a predetermined temperature in the range of 1000 to 1300 ° C. for 30 minutes. Then, it was charged into an ultra-high pressure sintering apparatus in a state of being superimposed on a WC-based cemented carbide base material having a size of diameter: 20 mm × thickness: 2 mm, at 5 GPa in the range of 1200 to 1400 ° C. Ultra-high pressure sintering under the condition of holding at a predetermined temperature for 30 minutes, grinding the upper and lower surfaces, dividing into four by wire cutting, brazing to a WC base cemented carbide base metal, and polishing to a predetermined throw-away tip shape Cutting tools made of the CBN-based ultrahigh-pressure sintered material of the present invention (hereinafter referred to as cutting tools of the present invention) 1 to 15 having substantially the same component composition as the finishing, and comparative CB
Cutting tools (hereinafter, referred to as comparative cutting tools) 1 to 8 made of an N-based ultrahigh-pressure sintered material were manufactured, respectively.
【0009】なお、上記比較切削工具1〜8は、これを
構成するCBN基超高圧焼結材料の構成成分のうち、特
にTi炭・窒化物からなる素地に分散分布して耐摩耗性
に影響を及ぼすWC,AlN,TiB2 、またはAl2
O3 の含有量(表2に※印を付す)がこの発明の範囲か
ら外れた組成をもつものである。[0009] The comparative cutting tools 1 to 8 are dispersed among the constituents of the CBN-based ultra-high pressure sintering material, especially the Ti carbon / nitride, and affect the wear resistance. , AlN, TiB 2 , or Al 2
The content of O 3 (marked with * in Table 2) has a composition outside the scope of the present invention.
【0010】ついで、この結果得られた本発明切削工具
1〜15および比較切削工具1〜8について、 被削材:FCD70(球状黒鉛鋳鉄)の丸棒、 切削速度:400m/min.、 切込み:0.25mm、 送り:0.2mm/rev .、 時間:20分、 の条件での鋳鉄の湿式連続高速切削試験、並びに、 被削材:SCM415の浸炭焼入れ丸棒、 切削速度:300m/min.、 切込み:0.1mm、 送り:0.1mm/rev .、 時間:20分、 の条件での鋼の乾式連続高速切削試験を行ない、いずれ
の試験でも切刃の逃げ面摩耗幅を測定した。これらの測
定結果を表1,2に示した。[0010] Next, for the cutting tools 1 to 15 of the present invention and the comparative cutting tools 1 to 8 obtained as a result, a work material: a round bar of FCD70 (spheroidal graphite cast iron), a cutting speed: 400 m / min. 0.25mm, feed: 0.2mm / rev. , Time: 20 minutes, wet continuous continuous high-speed cutting test of cast iron, and work material: carburized hardened round bar of SCM415, cutting speed: 300 m / min., Depth of cut: 0.1 mm, feed: 0.1 mm / Rev. A dry continuous high-speed cutting test of steel was performed under the following conditions: time: 20 minutes, and the flank wear width of the cutting edge was measured in each test. The results of these measurements are shown in Tables 1 and 2.
【0011】[0011]
【表1】 [Table 1]
【0012】[0012]
【表2】 [Table 2]
【0013】[0013]
【発明の効果】表1,2に示される結果から、本発明切
削工具1〜15は、これを構成するCBN基超高圧焼結
材料がいずれもTi炭・窒化物の素地に0.5μmの以
下の粒度の微細なWC,AlN,TiB2 ,およびAl
2 O3 が分散した組織を有し、高速切削ですぐれた耐摩
耗性を示すのに対して、比較切削工具1〜8に見られる
ように、前記WC,AlN,TiB2 、およびAl2 O
3 のうちのいずれかの含有でもこの発明の範囲から外れ
ると耐摩耗性の劣ったものになることが明らかである。
上述のように、この発明のCBN基超高圧焼結材料製切
削工具は、通常の切削は勿論のこと、特に高速切削です
ぐれた耐摩耗性を示し、長期に亘ってすぐれた切削性能
を発揮するのである。According to the results shown in Tables 1 and 2, the cutting tools 1 to 15 according to the present invention show that the CBN-based ultra-high pressure sintered material constituting the Fine WC, AlN, TiB 2 and Al with the following particle sizes
2 O 3 has a dispersed structure and exhibits excellent wear resistance in high-speed cutting, while the WC, AlN, TiB 2 , and Al 2 O
It is clear that any content of any of the three out of the range of the present invention results in poor wear resistance.
As described above, the cutting tool made of a CBN-based ultra-high pressure sintered material of the present invention exhibits excellent wear resistance not only in ordinary cutting but also particularly in high-speed cutting, and exhibits excellent cutting performance over a long period of time. You do it.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平3−20437(JP,A) 特開 平1−119564(JP,A) 特開 平5−17233(JP,A) 特開 平4−240006(JP,A) (58)調査した分野(Int.Cl.7,DB名) B23B 27/14 C04B 35/58 103 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-3-20437 (JP, A) JP-A-1-119564 (JP, A) JP-A-5-17233 (JP, A) JP-A-4-199 240006 (JP, A) (58) Field surveyed (Int. Cl. 7 , DB name) B23B 27/14 C04B 35/58 103
Claims (1)
たは2種以上からなるTi炭・窒化物:20〜40%、 炭化タングステン:0.1〜2%、 窒化アルミニウム:1〜5%、 硼化チタニウム:3〜7%、 酸化アルミニウム:5〜15%、 を含有し、残りが分散相形成成分としての立方晶窒化硼
素と不可避不純物からなる組成(以上容量%)を有し、
かつ結合相が、Ti炭・窒化物の素地に粒径がいずれも
0.5μm以下の炭化タングステン、窒化アルミニウ
ム、硼化チタニウム、および酸化アルミニウムが分散分
布した組織を有する立方晶窒化硼素基超高圧焼結材料で
構成したことを特徴とする耐摩耗性のすぐれた立方晶窒
化硼素基超高圧焼結材料製切削工具。The present invention provides a binder phase forming component comprising: 20 to 40% of Ti carbon / nitride comprising one or more of Ti carbides, nitrides, and carbonitrides; 0.1 to 2%, aluminum nitride: 1 to 5%, titanium boride: 3 to 7%, aluminum oxide: 5 to 15%, and the remainder is inevitable with cubic boron nitride as a dispersed phase forming component. Having a composition of impurities (more than volume%),
And a cubic boron nitride-based ultra-high pressure having a structure in which a binder phase has a structure in which tungsten carbide, aluminum nitride, titanium boride, and aluminum oxide, each having a particle size of 0.5 μm or less, are dispersed and distributed on a Ti carbon / nitride base material. A cutting tool made of a cubic boron nitride-based ultra-high pressure sintered material having excellent wear resistance, comprising a sintered material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14718994A JP3257255B2 (en) | 1994-06-06 | 1994-06-06 | Cutting tools made of cubic boron nitride based ultra-high pressure sintered material with excellent wear resistance |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14718994A JP3257255B2 (en) | 1994-06-06 | 1994-06-06 | Cutting tools made of cubic boron nitride based ultra-high pressure sintered material with excellent wear resistance |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07328814A JPH07328814A (en) | 1995-12-19 |
JP3257255B2 true JP3257255B2 (en) | 2002-02-18 |
Family
ID=15424585
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14718994A Expired - Lifetime JP3257255B2 (en) | 1994-06-06 | 1994-06-06 | Cutting tools made of cubic boron nitride based ultra-high pressure sintered material with excellent wear resistance |
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JP (1) | JP3257255B2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE529290C2 (en) * | 2005-10-28 | 2007-06-19 | Sandvik Intellectual Property | Cut off cubic boron nitride resistant to chipping and breaking |
US8507082B2 (en) | 2011-03-25 | 2013-08-13 | Kennametal Inc. | CVD coated polycrystalline c-BN cutting tools |
JP5804448B2 (en) * | 2012-02-28 | 2015-11-04 | 三菱マテリアル株式会社 | Cubic boron nitride based ultra-high pressure sintered body, cutting tool using this as a tool base, and surface-coated cutting tool |
US9028953B2 (en) | 2013-01-11 | 2015-05-12 | Kennametal Inc. | CVD coated polycrystalline c-BN cutting tools |
DE112021003480T5 (en) * | 2020-06-30 | 2023-04-27 | Kyocera Corporation | USE AND CUTTING TOOL |
-
1994
- 1994-06-06 JP JP14718994A patent/JP3257255B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH07328814A (en) | 1995-12-19 |
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