JP3235416B2 - Manufacturing method of high strength hot rolled steel sheet with excellent workability and fatigue properties - Google Patents
Manufacturing method of high strength hot rolled steel sheet with excellent workability and fatigue propertiesInfo
- Publication number
- JP3235416B2 JP3235416B2 JP18723795A JP18723795A JP3235416B2 JP 3235416 B2 JP3235416 B2 JP 3235416B2 JP 18723795 A JP18723795 A JP 18723795A JP 18723795 A JP18723795 A JP 18723795A JP 3235416 B2 JP3235416 B2 JP 3235416B2
- Authority
- JP
- Japan
- Prior art keywords
- strength
- content
- steel sheet
- less
- cooling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Metal Rolling (AREA)
Description
【0001】[0001]
【発明の属する技術分野】この発明は、自動車あるいは
産業機械などの高強度部材用鋼板であって、特に自動車
のホイールディスクに代表されるような、優れた成形性
と構造部材としての耐久強度を有し、さらに外装部材と
しての優れた表面性状を持つ引張強さ 540N/mm2 以上
の高強度熱延鋼板の製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a steel plate for a high-strength member such as an automobile or an industrial machine, and particularly to a steel plate having excellent formability and a durable strength as a structural member typified by a wheel disk of an automobile. The present invention relates to a method for producing a high-strength hot-rolled steel sheet having a tensile strength of 540 N / mm 2 or more, which has excellent surface properties as an exterior member.
【0002】[0002]
【従来の技術】連続熱間圧延により製造されるいわゆる
熱延鋼板は、比較的安価な構造材料として、自動車を始
めとする各種の産業機械に広く使用されている。そして
経済性の観点からプレス加工によって成形される部材が
多く、優れた加工性が要求される。2. Description of the Related Art Hot-rolled steel sheets produced by continuous hot rolling are widely used in automobiles and various other industrial machines as relatively inexpensive structural materials. Many members are formed by press working from the viewpoint of economy, and excellent workability is required.
【0003】近年、地球環境の保護の観点から、自動車
の燃費向上の規制強化が叫ばれており、リーンバーンエ
ンジンに代表される高燃費型のエンジンの開発が活発に
行われるとともに、部材の高強度・薄肉化による車体重
量の軽減が検討されている。[0003] In recent years, from the viewpoint of protection of the global environment, regulations for improving fuel efficiency of automobiles have been strengthened, and the development of high fuel efficiency engines typified by lean burn engines has been actively carried out, and the height of components has been increased. Reduction of vehicle weight by strength and thinning is being studied.
【0004】例えば、ホイールディスクに使用される鋼
板には、 590N/mm2 以下の引張強さの高張力鋼板が一
般に使用されているが、このホイールディスクに代表さ
れるような自動車の構造部材は、高い静的強度(引張強
さ)のみならず、優れた耐久強度(疲労強度)が要求さ
れ、加えて、延性や伸びフランジ性(穴拡げ性)などの
プレス成形性も良好である必要がある。For example, as a steel plate used for a wheel disk, a high-tensile steel plate having a tensile strength of 590 N / mm 2 or less is generally used. In addition to high static strength (tensile strength), excellent durability strength (fatigue strength) is required, and in addition, press formability such as ductility and stretch flangeability (hole expanding property) must be good. is there.
【0005】しかしながら、引張強さの増大に伴い、通
常の平滑試験片による疲労強度は向上するものの、切り
欠き試験片による疲労強度は引張強さが 540N/mm2 以
上でほぼ飽和すると言われている。さらに、加工性は通
常引張強さの増加に伴い低下してくるので、高い静的強
度あるいは高い耐久強度と、優れた加工性とを両立させ
るのは容易なことではない。However, as the tensile strength increases, the fatigue strength of a normal smooth test piece improves, but the fatigue strength of a notched test piece is said to be almost saturated when the tensile strength is 540 N / mm 2 or more. I have. Further, since workability usually decreases with an increase in tensile strength, it is not easy to achieve both high static strength or high durability and excellent workability.
【0006】高い静的強度と加工性とを兼備する材料と
して、例えば特公昭61-15128号公報あるいは特公昭61-1
1291号公報に記載されているような Dual-Phase 組織鋼
が知られている。この Dual-Phase 鋼は、フェライト相
とマルテンサイト相の二相混合組織であり、降伏比(降
伏強さと引張強さの比)が低く、均一伸びと破断伸びが
高く、優れた強度延性バランスを示すことを特徴として
いる。しかし、加工性向上に好ましいポリゴナルフェラ
イト(等軸晶のフェライト相)を安定して生成させるた
めに、多量のSiやCrを含有させる必要がある。As a material having both high static strength and workability, for example, Japanese Patent Publication No. 61-15128 or Japanese Patent Publication No. 61-1
A Dual-Phase microstructure steel as described in Japanese Patent No. 1291 is known. This Dual-Phase steel has a two-phase mixed structure of ferrite phase and martensite phase, low yield ratio (ratio of yield strength to tensile strength), high uniform elongation and high elongation at break, and excellent balance between strength and ductility. It is characterized by showing. However, in order to stably produce polygonal ferrite (equiaxial ferrite phase) which is preferable for improving workability, it is necessary to contain a large amount of Si or Cr.
【0007】また、高い静的強度と優れた加工性とを両
立させた鋼材として、例えば特開平3ー264646号公報に記
載されているような Tri-Phase組織鋼が知られている。
このTri-Phase 鋼は、フェライト相、ベイナイト相およ
びマルテンサイト相の三相組織であり、フェライト+ベ
イナイト二相組織鋼の持つ優れた伸びフランジ性と、フ
ェライト+マルテンサイト二相組織鋼の持つ優れた延性
をバランスさせたことを特徴としているが、加工性の向
上に必要なポリゴナルフェライトを安定して生成させる
ために、やはり多量のSiを含有させる必要がある。Further, as a steel material having both high static strength and excellent workability, for example, a Tri-Phase structure steel as disclosed in Japanese Patent Application Laid-Open No. 3-264646 is known.
This Tri-Phase steel has a three-phase structure of ferrite phase, bainite phase and martensite phase. It has the excellent stretch flangeability of ferrite + bainite dual phase steel and the excellent ferrite + martensite dual phase steel. However, in order to stably produce polygonal ferrite necessary for improving workability, it is necessary to contain a large amount of Si.
【0008】ところがSiを多く含む鋼では、スラブ加
熱時にスケール中にFe2 SiO4が生成し、これが圧
延中のデスケーリング性を劣化させて、酸洗後の鋼板表
面を荒したりスケール疵が残ったりするため、ホイール
用など外に現われる部材に適用することは好ましくなか
った。また、鋼板表面が荒れていると有害なヘゲ疵等の
検出が容易でなく、表面検査時の通板速度を落とさねば
ならず、生産性を低下させるという問題もある。[0008] However, in the steel containing a large amount of Si, Fe 2 SiO 4 is generated in the scale at the time of slab heating, which is deteriorates the descaling property during rolling, leaving scale defects or roughened surface of the steel sheet after pickling Therefore, it is not preferable to apply the present invention to a member that appears outside such as for a wheel. Further, if the surface of the steel sheet is rough, it is not easy to detect harmful scabs and the like, and it is necessary to reduce the sheet passing speed at the time of surface inspection, which causes a problem that the productivity is reduced.
【0009】さらに、SiやCrを多量に含有する鋼板
に生成する酸化物は、酸洗性を劣化させて酸洗後も鋼板
表層部にスケールが残りやすく、その上化成処理性を低
下させて、塗装後の耐食性を低下させると言う懸念があ
る。Furthermore, oxides generated in steel sheets containing a large amount of Si and Cr deteriorate the pickling properties, and scales are apt to remain on the surface layer of the steel sheets even after pickling, and further, the chemical conversion property is reduced. However, there is a concern that the corrosion resistance after painting is reduced.
【0010】一方、 Tri-Phase鋼では、温度や熱履歴に
よりフェライト、ベイナイト、マルテンサイト各相の体
積率が変動し、それによって特性が大きく影響されるた
め、鋼板の長手方向や幅方向の特性のバラツキを生じや
すいという問題点もある。On the other hand, in a Tri-Phase steel, the volume ratio of each phase of ferrite, bainite, and martensite fluctuates due to temperature and heat history, and the characteristics are greatly affected by the temperature. There is also a problem that the variation is easily caused.
【0011】[0011]
【発明が解決しようとする課題】本発明の目的は、優れ
た延性、伸びフランジ性、疲労強度、および表面性状を
有する、 540N/mm2 以上の高い引張強さの加工用高強
度熱延鋼板を安定して製造できる方法を確立することに
ある。SUMMARY OF THE INVENTION An object of the present invention is to provide a high-strength hot-rolled steel sheet for processing having a high tensile strength of 540 N / mm 2 or more, having excellent ductility, stretch flangeability, fatigue strength and surface properties. It is an object of the present invention to establish a method capable of stably producing a product.
【0012】[0012]
【課題を解決するための手段】本発明者等は、上記の目
的を達成すべく低Si鋼にて合金元素と金属組織、ない
しは熱延、冷却、巻取の条件が機械的性質に及ぼす影響
について鋭意検討を重ね、次に示すような知見を得た。In order to achieve the above object, the present inventors have studied the effects of the alloying elements and metallographic structure or the conditions of hot rolling, cooling and winding on the mechanical properties of low Si steel. As a result, the following findings were obtained.
【0013】 Siを低くすると、鋼板の表面性状や
化成処理性の改善が可能である。ただし、Si低減によ
る強度低下は、他の固溶強化型元素を添加したり、熱間
圧延条件や冷却条件を制御し硬質なベイナイトやマルテ
ンサイト量を増して補うことができるが、加工性はやや
劣化する。When the Si content is reduced, the surface properties of the steel sheet and the chemical conversion property can be improved. However, the decrease in strength due to the reduction of Si can be compensated by adding other solid solution strengthening elements or increasing the amount of hard bainite and martensite by controlling hot rolling conditions and cooling conditions, but the workability is poor. Slightly deteriorates.
【0014】 微量のNbを含有させることにより、
熱間圧延時オーステナイトに積極的に加工歪みを導入
し、その後の冷却過程でのフェライト相の生成を促進さ
せ、かつ、NbとTiの適量を複合添加してフェライト
相を強化することで、加工性の向上と共に強度を向上さ
せることができる。さらに、低N化により粗大なTiN
析出物の生成を抑制して延性を大幅に向上させることが
可能である。By including a trace amount of Nb,
Actively introduces working strain into austenite during hot rolling, promotes the formation of a ferrite phase in the subsequent cooling process, and strengthens the ferrite phase by adding an appropriate amount of Nb and Ti in combination. The strength can be improved along with the improvement of the properties. In addition, coarse TiN
It is possible to significantly improve ductility by suppressing the formation of precipitates.
【0015】基本組成が0.05%C−0.01%Si− 1.5%
Mn− 0.002%Nであって、Nbを添加しない鋼と、N
bを0.02%含有させた鋼とで、それぞれTi含有量を種
々変更した鋼片(スラブ)を溶製した。これらのスラブ
を1220℃に加熱して熱間圧延をおこない、 860℃にて仕
上圧延した後、40℃/sで 670℃まで加速冷却し、 5s
間空冷後、70℃/sで 100℃まで加速冷却し、引き続い
て巻取後の冷却状態を想定して 100℃から室温までを20
℃/hで炉冷することによって 3.2mm厚の熱延鋼板を製
造した。そして、この鋼板から JIS5号引張試験片を採
取し、引張特性を調査した。The basic composition is 0.05% C-0.01% Si-1.5%
Mn-0.002% N steel, without adding Nb,
A steel slab (slab) in which the Ti content was variously changed was melted with a steel containing 0.02% of b. These slabs are heated to 1220 ° C, hot-rolled, finish-rolled at 860 ° C, accelerated to 670 ° C at 40 ° C / s, and cooled for 5 seconds.
After air cooling, accelerate cooling at 70 ° C / s to 100 ° C, and then continue cooling from 100 ° C to room temperature, assuming the cooling state after winding.
A 3.2 mm-thick hot-rolled steel sheet was manufactured by cooling the furnace at a rate of ° C / h. Then, a JIS No. 5 tensile test piece was sampled from the steel sheet, and the tensile properties were examined.
【0016】この引張強さと伸びに及ぼすTi含有量の
影響の調査結果を図1に示す。この図から明らかなよう
に、低NのNb添加鋼に適量のTiを含有させ、仕上げ
圧延後の冷却条件を制御することによって、延性の低下
を小さくして強度を向上させることができ、 540N/mm
2 以上の引張強さと、30%以上の高い破断伸びを両立さ
せることが可能となる。これは、加工フェライトの生成
が抑制されて、加工性を向上させるポリゴナルフェライ
トの生成が促進され、マルテンサイトの生成を適量に抑
制することができたためと考えられる。FIG. 1 shows the results of examination of the effect of the Ti content on the tensile strength and elongation. As is apparent from this figure, by adding an appropriate amount of Ti to the low N N-added steel and controlling the cooling conditions after the finish rolling, the decrease in ductility can be reduced and the strength can be improved. / Mm
It is possible to achieve both a tensile strength of 2 or more and a high elongation at break of 30% or more. This is presumably because the generation of processed ferrite was suppressed, the generation of polygonal ferrite for improving workability was promoted, and the generation of martensite was appropriately suppressed.
【0017】 上記のNbを0.02%含有させTi量を
変えた鋼により上記条件で圧延した鋼板から、疲労試験
片を採取し、両振り平面曲げ疲労試験を行い、107 回の
繰り返し曲げに耐え得る応力を疲労限度、または疲労強
度とした。[0017] From rolled steel sheet under the above conditions of steel with varying the Ti content is 0.02% of the above Nb, the fatigue test piece was taken, subjected to Reversed plane bending fatigue test, withstand 10 7 times repeated bending The obtained stress was defined as a fatigue limit or fatigue strength.
【0018】結果を図2に示す。一般には疲労限度比
(疲労強度と引張強さの比)はほとんど変化せず、強度
上昇に比例して疲労強度が向上する。ところが、図1と
図2の対比からからわかるように、Ti含有量が増すと
強度上昇とともに疲労限度比が向上しており、疲労強度
が大きく改善されていることがわかる。これは軟質なフ
ェライト相がTiCにより強化されるためと考えられ
る。FIG. 2 shows the results. Generally, the fatigue limit ratio (the ratio of fatigue strength to tensile strength) hardly changes, and the fatigue strength increases in proportion to the increase in strength. However, as can be seen from the comparison between FIG. 1 and FIG. 2, it can be seen that as the Ti content increases, the fatigue limit ratio increases as the strength increases, and the fatigue strength is greatly improved. This is considered because the soft ferrite phase is strengthened by TiC.
【0019】次に炭素量の影響を調査した。まずFe
−0.01%Si−1.65%Mn−0.10%Ti−0.02%Nb−
0.002%Nの組成を基本とし、C含有量を0.03〜0.13%
の範囲で変えたスラブを溶製した。これらのスラブを12
50℃に加熱してから熱間圧延をおこない、 840℃で仕上
圧延した後、 680℃まで加速冷却してから 3s間空冷
し、さらに 200℃まで加速冷却した後、巻取相当の緩冷
処理を施して、 3.2mm厚の熱延鋼板を製造した。それら
の鋼板から JIS5号引張試験片を採取して引張特性を調
査するとともに、 100mm× 100mmの正方形の試験片を切
り出して10mmφのポンチ穴をクリアランス15%として打
ち抜いた後、60゜の円錐ポンチで穴拡げ試験をおこな
い、限界穴拡げ率を求めた。Next, the influence of the carbon content was investigated. First, Fe
-0.01% Si-1.65% Mn-0.10% Ti-0.02% Nb-
Based on the composition of 0.002% N, C content is 0.03-0.13%
The slab changed in the range of was melted. 12 of these slabs
After heating to 50 ° C, hot rolling is performed, finish rolling at 840 ° C, accelerated cooling to 680 ° C, air-cooled for 3 seconds, accelerated cooling to 200 ° C, and slow cooling equivalent to winding. To produce a 3.2 mm thick hot rolled steel sheet. A JIS No. 5 tensile test piece was sampled from those steel sheets to investigate the tensile properties, and a 100 mm x 100 mm square test piece was cut out and punched with a 10 mmφ punch hole with a clearance of 15%, and then a 60 mm conical punch. A hole expansion test was performed to determine the critical hole expansion rate.
【0020】C含有量変化に伴う引張り試験値および限
界穴拡げ率の変化を図3に示すが、炭素含有量が0.08%
を超えると、穴拡げ性が大きく低下することがわかる。FIG. 3 shows the change in the tensile test value and the limit hole expansion ratio with the change in the C content.
It can be seen that when the value exceeds, the hole expandability is greatly reduced.
【0021】以上のような知見から本発明に至ったが、
その要旨は次の通りである。Although the present invention has been made based on the above findings,
The summary is as follows.
【0022】重量%で、C:0.03〜0.08%、S
i:0.30%以下(0.30%を除く)、Mn:1.
00〜2.00%、P:0.010〜0.030%、T
i:0.05〜0.15%、Nb:0.01〜0.06
%、N:0.0040%以下、さらにCr:0〜0.6
%、V:0〜0.06%、Ca:0〜0.01%、Z
r:0〜0.10%および希土類元素:0〜0.10%
で、残部が鉄および不可避不純物からなる鋼を、780
〜950℃で熱間圧延を完了した後、30℃/s以上の
冷却速度で600〜700℃の範囲の温度まで加速冷却
し、その温度から2〜10s間空冷した後、さらに50
℃/s以上の冷却速度で250℃以下まで加速冷却し、
巻取ることを特徴とする加工性、疲労特性および表面性
状に優れた540N/mm2 以上の引張強さを有する
高強度熱延鋼板の製造方法。C: 0.03-0.08% by weight, S
i: 0.30% or less (excluding 0.30%) , Mn: 1.
00-2.00%, P: 0.010-0.030%, T
i: 0.05 to 0.15%, Nb: 0.01 to 0.06
%, N: 0.0040% or less, and Cr: 0 to 0.6
%, V: 0 to 0.06 %, Ca: 0 to 0.01 %, Z
r: 0~ 0.10% you and rare earth element: 0 to 0.10%
In, the steel and the balance of iron and inevitable impurities, 780
After completion of hot rolling at 950 ° C. to 950 ° C., accelerated cooling is performed at a cooling rate of 30 ° C./s or more to a temperature in the range of 600 ° C. to 700 ° C., and air-cooled from that temperature for 2 to 10 s.
Accelerated cooling to 250 ° C or less at a cooling rate of 200 ° C / s or more,
A method for producing a high-strength hot-rolled steel sheet having a tensile strength of 540 N / mm 2 or more, which is excellent in workability, fatigue characteristics, and surface properties characterized by winding.
【0023】[0023]
【発明の実施の形態】以下、本発明の実施の形態につい
て詳述する。Embodiments of the present invention will be described below in detail.
【0024】A.鋼板の化学組成 (1) C:0.03〜0.08% Cは鋼板の強度を高める元素であり、加工性に優れた高
強度鋼を製造するためには特に重要な元素である。すな
わち、0.03%未満ではマルテンサイトなどの硬質な第二
相の量を十分に確保できず、 540N/mm2 以上の引張強
さを有する高強度鋼板を容易に製造することができな
い。一方、0.08%を超えて含有させると第二相の量が増
大し過ぎて、穴拡げ性の劣化を招く。したがって、C含
有量を0.03〜0.08%と定めた。なお、とくに加工性を重
視する場合には、C含有量の上限を0.06%とすることが
望ましい。A. Chemical composition of steel sheet (1) C: 0.03 to 0.08% C is an element that increases the strength of the steel sheet, and is an especially important element for producing a high-strength steel excellent in workability. That is, if it is less than 0.03%, a sufficient amount of a hard second phase such as martensite cannot be secured, and a high-strength steel sheet having a tensile strength of 540 N / mm 2 or more cannot be easily produced. On the other hand, when the content exceeds 0.08%, the amount of the second phase is excessively increased, which causes deterioration of hole expandability. Therefore, the C content is determined to be 0.03 to 0.08%. When the workability is particularly important, the upper limit of the C content is preferably set to 0.06%.
【0025】 (2)Si:0.30%以下(0.30%を除く) Siは固溶強化によってフェライト相を強化できるだけ
でなく、ポリゴナルフェライトの生成を促進し延性を向
上させることが可能なので、高い強度とすぐれた加工性
を兼備する熱延鋼板を製造するには好ましい元素であ
る。ことに降伏比の低い二相混合組織を得るためには活
用したい元素である。(2) Si: 0.30% or less (excluding 0.30%) Si can not only strengthen the ferrite phase by solid solution strengthening, but also promote the formation of polygonal ferrite and improve ductility. Therefore, it is a preferable element for producing a hot-rolled steel sheet having both high strength and excellent workability. In particular, it is an element to be used to obtain a two-phase mixed structure with a low yield ratio.
【0026】しかし、Siは、デスケーリング性劣化に
よる表面疵の発生や、化成処理性に悪影響をおよぼすこ
となど表面品質を劣化させる点からは含有しない方がよ
い。However, it is better not to contain Si from the viewpoint of deteriorating the surface quality, such as generation of surface flaws due to deterioration of the descaling property and adversely affecting the chemical conversion property.
【0027】そこで、本発明においては、表面性状を重
視し、大きな影響をおよぼさない限界として多くても
0.30%以下(0.30%を除く)とする。より一層
優れた性状の表面を安定して得るには、0.05%未満
にすることが望ましい。Therefore, in the present invention, emphasis is placed on the surface properties, and at most 0.30% or less (excluding 0.30%) as a limit that does not significantly affect the surface properties. In order to stably obtain a surface having more excellent properties, the content is desirably less than 0.05%.
【0028】(3) Mn: 1.0〜 2.0% Mnは固溶強化と変態強化を通じて、鋼板の強度を高め
る作用を有する。しかし、 1.0%未満の含有量では所望
の効果が得られず、一方、 2.0%を超えて含有させる
と、マルテンサイト相が増加しすぎ、穴拡げ性を劣化さ
せる。そこでその含有量範囲を 1.0〜 2.0%に定めた。(3) Mn: 1.0 to 2.0% Mn has the effect of increasing the strength of the steel sheet through solid solution strengthening and transformation strengthening. However, if the content is less than 1.0%, the desired effect cannot be obtained. On the other hand, if the content is more than 2.0%, the martensite phase is excessively increased, and the hole expandability is deteriorated. Therefore, the content range was set to 1.0 to 2.0%.
【0029】(4) P:0.010 〜0.030 % Pは固溶強化によってフェライト相を強化し、鋼板の強
度を高める作用を有する。また、Siの存在下におい
て、スラブ加熱時にFeOと地鉄との界面に生成するF
e2 SiO4 に固溶してFe2 (Si,P)O4 を形成
し、デスケーリング性を向上させる効果がある。その含
有量が0.01%未満ではこれらの効果が得られず、一方、
0.03%を超えて含有させると、連続鋳造スラブの中心偏
析に基づく溶接性や加工性の低下を来すので、その含有
量を 0.010〜 0.030%に限定する。(4) P: 0.010 to 0.030% P has the effect of strengthening the ferrite phase by solid solution strengthening and increasing the strength of the steel sheet. In addition, in the presence of Si, F generated at the interface between FeO and ground iron during slab heating
It has the effect of forming a solid solution in e 2 SiO 4 to form Fe 2 (Si, P) O 4 and improving the descaling property. If the content is less than 0.01%, these effects cannot be obtained.
If the content exceeds 0.03%, the weldability and workability are deteriorated due to the segregation of the center of the continuous cast slab, so the content is limited to 0.010 to 0.030%.
【0030】とくにSi含有量が0.05%以上の場合は、
P含有量を 0.015%以上にすると、より安定して表面性
状の良好な鋼板を得ることができる。In particular, when the Si content is 0.05% or more,
When the P content is 0.015% or more, it is possible to more stably obtain a steel sheet having good surface properties.
【0031】(5)Ti:0.05〜0.15% Tiは本発明においてはNbと共に最も重要な元素の一
つである。TiはTiCの析出によってフェライト相を
強化する作用があり、比較的安価な強化元素の一つとし
て一般に使用されている。しかしながら、析出強化は大
幅な延性の低下を伴うため、高強度鋼において良好なプ
レス成形性が必要な場合には、その含有量を制限する必
要があった。ところが、とくにNを低下させた鋼におい
ては、Tiを微量のNbと複合添加すると、延性の大幅
な低下を伴うことなく強度の向上が可能である。(5) Ti: 0.05 to 0.15% Ti is one of the most important elements together with Nb in the present invention. Ti has an effect of strengthening the ferrite phase by precipitation of TiC, and is generally used as one of relatively inexpensive strengthening elements. However, since precipitation strengthening involves a significant decrease in ductility, it is necessary to limit the content of high-strength steel when good press formability is required. However, especially in steel with reduced N, if Ti is added in combination with a trace amount of Nb, the strength can be improved without a significant decrease in ductility.
【0032】まず、N含有量を低減することにより、加
工性に有害な粗大なTiN析出物の生成が防止される。
次に熱延仕上圧延時に、微量のNb添加によってオース
テナイト域での再結晶の進行が遅延され、圧延スタンド
間で再結晶が終了する前に次のスタンドで加工を受け、
オーステナイトの加工歪みの累積量が増加するようにな
る。このため、熱間圧延時のオーステナイト域での析出
が促進されてTiCは均一微細になり、その状態でオー
ステナイトがフェライトに変態することによって、Ti
C析出物は生じたフェライト地との整合性を失ってく
る。このようにして、延性を著しく劣化させるTiCの
整合析出物の生成が防止され、強度は増加するが延性の
劣化が低減される結果になると推定される。First, by reducing the N content, formation of coarse TiN precipitates harmful to workability is prevented.
Next, at the time of hot rolling finish rolling, the addition of a small amount of Nb delays the progress of recrystallization in the austenite region, and is processed at the next stand before recrystallization is completed between rolling stands.
The cumulative amount of austenite processing strain increases. For this reason, precipitation in the austenite region during hot rolling is promoted, and TiC becomes uniform and fine. In this state, austenite is transformed into ferrite, and TiC is formed.
The C precipitate loses consistency with the generated ferrite ground. In this way, it is presumed that the formation of coherent precipitates of TiC which significantly deteriorates ductility is prevented, and the strength is increased but the deterioration of ductility is reduced.
【0033】さらにTi含有量を高めに管理すること
と、上記の歪みの累積量を増加させることにより、熱間
圧延時のTiC析出物生成量を増加させると、熱延後の
加速冷却条件や巻取温度による、TiCの析出物分布の
変動が小さくなる。以上のような理由により、軟質なフ
ェライト相が微細に分散したTiCにより強化され、通
常の疲労強度や切り欠き疲労強度が安定して向上するの
である。Further, by increasing the amount of TiC precipitates generated during hot rolling by controlling the Ti content to be relatively high and increasing the cumulative amount of the above-mentioned strain, the accelerated cooling conditions after hot rolling, Variations in the TiC precipitate distribution due to the winding temperature are reduced. For the reasons described above, the soft ferrite phase is strengthened by finely dispersed TiC, and ordinary fatigue strength and notch fatigue strength are stably improved.
【0034】Ti含有量が0.05%未満では、少なす
ぎて上記作用による所望の効果が得られず、一方、0.
15%を超えて含有させると上記作用が飽和するのみな
らず、粗大なTiNの析出を促進し加工性の低下を招く
ので、その含有量を0.05〜0.15%と定めた。な
お、より優れた加工性を安定して得るための望ましい含
有量は、0.08〜0.13%である。If the Ti content is less than 0.05 %, the desired effect due to the above-mentioned effects cannot be obtained because the content is too small.
If the content exceeds 15%, not only the above-mentioned action is saturated, but also the precipitation of coarse TiN is promoted and the workability is lowered, so the content is set to 0.05 to 0.15%. In addition, a desirable content for stably obtaining more excellent workability is 0.08 to 0.13%.
【0035】(6) Nb:0.01〜0.06% Nbは本発明においてTiとともに最も重要な元素の一
つである。NbはNb(C,N)の析出によってフェラ
イト相を強化する作用を有するために、比較的安価な強
化元素として一般に使用されている。しかし、析出強化
にともない延性の低下が避けられないことと、固溶Nb
はポリゴナルフェライトの生成を抑制して鋼板の加工性
を低下させ易いことから、プレス成形性を要求される場
合にはその含有量を制限する必要がある。(6) Nb: 0.01 to 0.06% Nb is one of the most important elements together with Ti in the present invention. Nb is generally used as a relatively inexpensive strengthening element because Nb has an effect of strengthening the ferrite phase by precipitation of Nb (C, N). However, the decrease in ductility due to precipitation strengthening is unavoidable, and
Since it is easy to reduce the workability of a steel sheet by suppressing the formation of polygonal ferrite, it is necessary to limit the content of the steel sheet when press formability is required.
【0036】しかし、微量のNbの存在は、オーステナ
イトの未再結晶圧延温度域を拡大して歪みの累積量を増
加させ、これが駆動力となって、フェライト相を安定的
に生成させることが可能になる。したがって、本発明で
は、微量のNbを含有させることとした。However, the presence of a small amount of Nb expands the non-recrystallization rolling temperature range of austenite and increases the amount of strain accumulation, and this becomes a driving force, whereby a ferrite phase can be stably formed. become. Therefore, in the present invention, a small amount of Nb is included.
【0037】Nb含有量が0.01%未満では上記の効果が
十分得られず、一方、0.06%を超えて含有させると、逆
にポリゴナルフェライトの生成を抑制し、加工性を低下
させる。そこで、Nb含有量の範囲を0.01%〜0.06%と
定めた。なお、加工性を安定して向上させるのに望まし
い含有量範囲は、0.015 %〜0.03%である。If the Nb content is less than 0.01%, the above effects cannot be sufficiently obtained. On the other hand, if the Nb content exceeds 0.06%, the formation of polygonal ferrite is suppressed and the workability is reduced. Therefore, the range of the Nb content is determined to be 0.01% to 0.06%. The content range desirable for stably improving workability is 0.015% to 0.03%.
【0038】(7) N:0.0040%以下 Nは、製鋼や鋳造工程において不可避的に混入する不純
物の1つであり、通常は鋼中のAlやTiなどと結合し
て窒化物を形成する。しかしTiを含む鋼ではN含有量
が高い場合、溶鋼が凝固する過程で粗大なTiNが生成
しやすく、これが割れ発生の起点になって鋼板の加工性
を低下させる恐れがある。また、Nbの炭窒化物の析出
温度が上昇して、粗圧延工程において析出し粗大化して
しまい、仕上圧延工程にてNbが有効に作用しなくなっ
てしまう。したがって、Nの含有量は少なければ少ない
ほどよいが、その影響が顕著でない限界として、含有量
を0.0040%以下と定めた。望ましいのは0.0020%以下で
ある。(7) N: 0.0040% or less N is one of the impurities inevitably mixed in the steel making or casting process, and usually forms a nitride by combining with Al, Ti or the like in the steel. However, in the case of steel containing Ti, when the N content is high, coarse TiN is likely to be generated in the process of solidifying the molten steel, and this may be a starting point of crack generation, which may lower the workability of the steel sheet. In addition, the precipitation temperature of carbonitride of Nb rises and precipitates and coarsens in the rough rolling step, so that Nb does not work effectively in the finish rolling step. Therefore, the smaller the content of N, the better, but as a limit that the effect is not remarkable, the content is set to 0.0040% or less. Desirable is 0.0020% or less.
【0039】(8) Cr: 0.6%以下 Crはマルテンサイトの生成を促進する効果があり、そ
の変態強化を通じて強度の向上に有効なので、必要に応
じて含有させる。含有させる場合には、0.02%以上で所
望の効果を得ることができる。一方、 0.6%を超えて含
有させると酸洗性や化成処理性の低下が顕著になるた
め、その含有量は 0.6%以下とする。(8) Cr: 0.6% or less Cr has an effect of promoting the formation of martensite, and is effective in improving the strength through its transformation enhancement. When it is contained, a desired effect can be obtained at 0.02% or more. On the other hand, if the content exceeds 0.6%, the pickling property and the chemical conversion property deteriorate remarkably, so the content is set to 0.6% or less.
【0040】なお、特に表面性状や化成処理性を重視す
る場合には含有させない方がよく、多くてもその含有量
を0.05%以下に抑制することが望ましい。It should be noted that it is better not to include the metal oxide, particularly when the surface properties and chemical conversion property are emphasized, and it is desirable to control the content to 0.05% or less at most.
【0041】(9) V:0.06%以下 Vは添加しなくてもよいが、NやCとの結合による析出
強化を通じて強度向上に有効な元素であり、必要に応じ
て含有させる。含有させる場合には、 0.001%以上の含
有量で所望の効果を得ることができる。一方、0.06%を
超えて含有させても上記の効果が飽和し、経済性を損な
う。そこで、その含有量を0.06%以下と定めた。(9) V: 0.06% or less V may not be added, but is an element effective for improving strength through precipitation strengthening by bonding with N and C, and may be contained as necessary. When it is contained, a desired effect can be obtained with a content of 0.001% or more. On the other hand, if the content exceeds 0.06%, the above effect is saturated, and the economic efficiency is impaired. Therefore, the content was determined to be 0.06% or less.
【0042】(10) Ca:0.01%以下、Zr:0.10%以
下および希土類元素:0.10%以下 Ca、Zrおよび希土類元素の添加は、いずれも介在物
のMnSの性質を変化させ、熱延時に展伸し難くさせる
効果があり、とくに圧延の幅方向に引張り変形を受ける
ような加工の割れ防止に有効である。(10) Ca: 0.01% or less, Zr: 0.10% or less and rare earth element: 0.10% or less Any addition of Ca, Zr and rare earth elements changes the properties of MnS of inclusions and expands during hot rolling. This has the effect of making it difficult to elongate, and is particularly effective in preventing cracking in processing that undergoes tensile deformation in the width direction of rolling.
【0043】このような割れ発生が問題にならない場合
は添加の必要はない。しかし、その効果を期待して添加
する場合、少なければ効果が発揮されないので、それぞ
れCaでは0.0002%以上、Zrでは0.01%以上、希土類
元素では 0.002%以上含有させるのが望ましい。ただ
し、Caは0.01%、Zrは0.10%、希土類元素は0.10%
をそれぞれ超えて含有させると、鋼中の介在物が多くな
りすぎて加工性が劣化する。If the occurrence of such cracks is not a problem, there is no need to add them. However, if the effect is expected, the effect is not exhibited if the amount is small. Therefore, it is preferable that the content of Ca is 0.0002% or more, the content of Zr is 0.01% or more, and the content of rare earth element is 0.002% or more. However, Ca is 0.01%, Zr is 0.10%, and rare earth element is 0.10%
, The inclusions in the steel become too large and the workability deteriorates.
【0044】そこで、それぞれの含有量を、Ca:0.01
%以下、Zr:0.10%以下、希土類元素:0.10%以下と
定めた。なお、S含有量を 0.001%未満に低減できた場
合はMnSの形態変化による加工性の劣化はないので、
S含有量が 0.001%を超える場合に添加すると効果的で
ある。Therefore, each content is set to Ca: 0.01
%, Zr: 0.10% or less, rare earth element: 0.10% or less. When the S content can be reduced to less than 0.001%, there is no deterioration in workability due to a change in the form of MnS.
It is effective to add when the S content exceeds 0.001%.
【0045】Alは製鋼時健全な鋳片を得るために脱酸
剤として添加されるが、本発明の製造方法による場合、
鋼板の性質にはほとんど影響をおよぼさず、とくにその
含有量は規制しない。ただし、多量に添加すると加工性
を低下させるので、0.10%以下の含有量とするのが望ま
しい。なお、脱酸作用を得るためには0.03%以下で十分
である。Al is added as a deoxidizing agent in order to obtain a sound slab during steel making.
It has little effect on the properties of the steel sheet, in particular its content is not regulated. However, if added in a large amount, the workability is reduced, so that the content is desirably 0.10% or less. Note that 0.03% or less is sufficient to obtain a deoxidizing effect.
【0046】不可避的不純物の一つであるSは、Mnと
反応してMnS系の介在物を形成しプレス加工性を低下
させるので、少なければ少ないほどよい。望ましい含有
量の上限は0.02%であるが、好ましくは 0.005%以下
で、特にCa処理などによるMnSの形態制御を行わな
い場合には、 0.001%以下に低減することがより好まし
い。S, which is one of the inevitable impurities, reacts with Mn to form MnS-based inclusions and lowers the press workability, so the smaller the better, the better. The desirable upper limit of the content is 0.02%, but is preferably 0.005% or less, and particularly preferably is reduced to 0.001% or less when the form control of MnS by Ca treatment or the like is not performed.
【0047】その他、鋼中に不可避的に混入する「不可
避不純物」としては、O、Cu、Moなどが挙げられる
が、これら不純物元素の含有は少なければ少ないほど望
ましい。In addition, examples of "unavoidable impurities" unavoidably mixed into steel include O, Cu, Mo, and the like. The smaller the content of these impurity elements, the more desirable.
【0048】上述のような成分組成の鋼は、例えば電気
炉、などでも溶製できるが、とくにN含有量を低く保つ
には転炉による溶製が好ましい。また、熱延のスラブの
製造についても、造塊−分塊圧延、あるいは連続鋳造の
いずれの手段によってもかまわない。The steel having the above-described composition can be melted in, for example, an electric furnace. However, in order to keep the N content low, melting in a converter is preferred. Also, the production of hot-rolled slabs may be performed by any of ingot-bulking rolling and continuous casting.
【0049】B.熱間圧延条件 本発明の製造方法の熱間圧延の工程は、加熱したスラブ
を圧延して仕上温度を780 〜 950℃にて圧延を完了した
後、 600〜 700℃の範囲の温度まで30℃/s以上の冷却
速度で加速冷却し、その温度から 2〜10s間空冷後、50
℃/s以上の冷却速度で 400℃以下まで加速冷却して巻
取ることからなる。以下各工程の条件について説明す
る。B. Hot Rolling Conditions The hot rolling step of the production method of the present invention involves rolling the heated slab and completing the rolling at a finishing temperature of 780 to 950 ° C., and then 30 ° C. to a temperature in the range of 600 to 700 ° C. / S accelerated cooling at a cooling rate of at least
Winding is performed by accelerated cooling to 400 ° C or less at a cooling rate of at least ° C / s. Hereinafter, the conditions of each step will be described.
【0050】(1) スラブ加熱温度 この熱間圧延に際して、連続鋳造スラブまたは分塊圧延
スラブを用いてもよいし、直送圧延スラブをまたは一旦
冷却されたスラブを再加熱して用いてもよい。(1) Slab Heating Temperature In this hot rolling, a continuous cast slab or a bulk rolled slab may be used, or a directly-rolled slab or a slab once cooled may be reheated and used.
【0051】ただし、スラブを再加熱する場合には、N
bの炭窒化物やTiCなどを完全に再固溶させるために
再加熱温度は1150℃以上とするのが好ましい。加熱温度
が1150℃未満の加熱では、一旦析出したNbの炭窒
化物の再溶解が不十分となり、仕上圧延時に作用するN
b量が不足してオーステナイトの加工硬化が促進され
ず、オーステナイト域でのTiCの析出が不十分にな
る。また、仕上圧延後の加速冷却時に生成するフェライ
ト量が減少し、延性の低下を招く。However, when reheating the slab, N
The reheating temperature is preferably 1150 ° C. or higher in order to completely re-dissolve the carbonitride b and TiC in b. When the heating temperature is lower than 1150 ° C., the re-dissolution of the Nb carbonitride once precipitated becomes insufficient, and the N
The work hardening of austenite is not promoted due to the shortage of b, and the precipitation of TiC in the austenite region becomes insufficient. Also, the amount of ferrite generated during accelerated cooling after finish rolling is reduced, leading to a reduction in ductility.
【0052】(2) 仕上げ温度 次に、仕上温度を 780〜 950℃の範囲で圧延を完了する
ことによってオーステナイト粒を微細化するとともにオ
ーステナイトを加工硬化させ、その後の冷却過程でのポ
リゴナルフェライトの生成を促進させることができる。
この場合、仕上圧延温度が 780℃未満になると、熱間圧
延中にフェライトが生成し加工フェライトとなるため、
熱延鋼板の加工性が低下してしまう。一方、仕上温度が
950℃を超えると、オーステナイトの加工硬化が不十分
となり、その後の冷却過程でポリゴナルフェライトが十
分に生成せず、加工性の低下を招く。したがって熱間圧
延の仕上温度を 780〜 950℃とする。より望ましいのは
780〜 860℃で仕上圧延を行うことで、ポリゴナルフェ
ライトをさらに安定して生成させ得る。(2) Finishing temperature Next, the austenite grains are refined by completing rolling at a finishing temperature in the range of 780 to 950 ° C., and the austenite is work-hardened. Production can be promoted.
In this case, when the finish rolling temperature is less than 780 ° C, ferrite is generated during hot rolling and becomes processed ferrite,
Workability of the hot-rolled steel sheet is reduced. On the other hand, the finishing temperature
If the temperature exceeds 950 ° C., work hardening of austenite becomes insufficient, and in the subsequent cooling process, polygonal ferrite is not sufficiently generated, resulting in deterioration of workability. Therefore, the finishing temperature of hot rolling is set to 780 to 950 ° C. More desirable
By performing finish rolling at 780 to 860 ° C., polygonal ferrite can be generated more stably.
【0053】(3) 冷却過程 熱間圧延完了後の冷却過程において 600〜 700℃の範囲
内に入る温度まで加速冷却しその温度から 2〜10s間空
冷することにより、さらに多くの量のポリゴナルフェラ
イトを安定して生成させることができる。これにより、
加工性、とくにに延性にすぐれた高強度熱延鋼板が得ら
れる。(3) Cooling process In the cooling process after the completion of hot rolling, accelerated cooling to a temperature falling within the range of 600 to 700 ° C. and air cooling from that temperature for 2 to 10 s give a larger amount of polygonal material. Ferrite can be generated stably. This allows
A high-strength hot-rolled steel sheet having excellent workability, particularly excellent ductility, can be obtained.
【0054】空冷を開始する温度が 600℃未満、または
空冷時間が 2s未満であるとポリゴナルフェライトの生
成が不十分であり、空冷開始温度が 700℃を上回るか、
あるいは所定温度範囲内でも空冷時間が10sを超える
と、パーライトが生成して鋼板の強度と延性が低下す
る。したがって冷却過程途中での空冷条件を 600〜 700
℃の温度域で 2〜10s間の空冷とした。空冷時の冷却速
度は、鋼板の板厚や通板速度によって変化するが、 2〜
4mm 厚の場合 6〜12℃/s程度である。If the temperature at which air cooling is started is less than 600 ° C., or if the air cooling time is less than 2 seconds, the formation of polygonal ferrite is insufficient, and the air cooling starting temperature exceeds 700 ° C.
Alternatively, if the air cooling time exceeds 10 s even within the predetermined temperature range, pearlite is generated, and the strength and ductility of the steel sheet decrease. Therefore, the air cooling conditions during the cooling process should be 600-700.
Air cooling was performed for 2 to 10 seconds in the temperature range of ° C. The cooling rate during air cooling varies depending on the thickness of the steel sheet and the passing speed.
In case of 4mm thickness, it is about 6 ~ 12 ℃ / s.
【0055】なお、熱間圧延後空冷開始温度までの加速
冷却を、30℃/s以上の冷却速度とするのは、一つには
フェライトを微細に生成させるためであり、さらには 2
〜10秒の空冷時間の確保を容易にするためである。The reason why the accelerated cooling to the air-cooling start temperature after hot rolling is set to a cooling rate of 30 ° C./s or more is, in part, to form ferrite finely.
This is to make it easy to secure an air cooling time of up to 10 seconds.
【0056】さらに、空冷終了後の冷却を50℃/s以上
とするのは、50℃/s未満の冷却速度ではベイナイトが
生成し、降伏比が増大して、延性が低下するためであ
り、ベイナイトの生成がなければそれ以上に冷却速度を
大きくする必要はない。The reason why the cooling after the completion of the air cooling is set to 50 ° C./s or more is that if the cooling rate is less than 50 ° C./s, bainite is formed, the yield ratio increases, and the ductility decreases. Without the formation of bainite, there is no need to increase the cooling rate any further.
【0057】巻取温度については、前記の第1の熱間圧
延条件と同様、250℃を超える温度では巻取後にベイ
ナイトが生成して降伏比が上昇し、伸びが低下する。そ
こで、巻取温度を250℃以下とした。巻取り温度は2
50℃を下回るなら過剰に冷却する必要はない。Regarding the winding temperature, as in the first hot rolling condition, at a temperature exceeding 250 ° C. , bainite is formed after winding, the yield ratio increases, and the elongation decreases. Therefore, the winding temperature was set to 250 ° C. or less . Winding temperature is 2
If it is below 50 ° C., there is no need for excessive cooling.
【0058】[0058]
【実施例】表1に示す化学組成の鋼種A〜Xのスラブ
を、表2に示す条件で熱間圧延と圧延後冷却処理を行な
い、板厚 3.2mmの熱延鋼板とした。EXAMPLES Slabs of steel types A to X having the chemical compositions shown in Table 1 were subjected to hot rolling and rolling after cooling under the conditions shown in Table 2 to obtain hot-rolled steel sheets having a thickness of 3.2 mm.
【0059】圧延後の鋼板の表面性状については、酸洗
後の鋼板表面を目視観察し、スケール残りが全くないも
のを◎(極めて良好)、ぼぼ完全にスケールが除去され
ているものを○(ほぼ良好)、部分的にスケール残りが
あるものを△、スケール疵があるものを×とした。この
結果も合せて表2に示す。Regarding the surface properties of the steel sheet after rolling, the surface of the steel sheet after pickling was visually observed, and those having no scale residue were evaluated as ◎ (very good), and those with almost completely removed scale were evaluated as ○ ( Almost good), those with partial scale residue were rated as Δ, and those with scale flaws were rated as x. Table 2 also shows the results.
【0060】[0060]
【表1】 [Table 1]
【0061】[0061]
【表2】 [Table 2]
【0062】得られた鋼板から圧延方向に平行な方向の
JIS5号引張試験片を採取し、引張試験をおこなった。
また、100mm 幅×100mm 長さの鋼片を採取し、10mmφの
穴を打ち抜いた後、頂角60゜の円錐ポンチで穴拡げ試験
をおこなった。疲労試験は、両振り平面曲げと、切欠き
試験片による片振り引張りとをおこなった。図4に示す
ように平面曲げは幅20mmの1号試験片をもちい、切欠き
試験片は、12mmφの穴をクリアランス10%で打ち抜いた
試験片をもちいて、107 回の繰り返しに耐える応力、す
なわち疲労限度を求め、これを疲労強度とした。これら
の結果を合せて表3に示す。なお表には疲労限度比(疲
労強度/引張り強度)も示してある。From the obtained steel sheet, a direction parallel to the rolling direction
A JIS No. 5 tensile test piece was collected and subjected to a tensile test.
Further, a steel slab having a width of 100 mm and a length of 100 mm was sampled, a hole of 10 mmφ was punched out, and a hole expansion test was performed with a conical punch having a vertex angle of 60 °. In the fatigue test, a bilateral plane bending and a pulsating pull with a notched test piece were performed. As shown in Fig. 4, plane bending uses a No. 1 test piece with a width of 20 mm, and a notched test piece uses a test piece punched out with a clearance of 10% with a hole of 12 mm in diameter to withstand 10 7 repetitions. That is, the fatigue limit was determined, and this was defined as the fatigue strength. Table 3 shows the results together. The table also shows the fatigue limit ratio (fatigue strength / tensile strength).
【0063】[0063]
【表3】 [Table 3]
【0064】表2に示すように、圧延後の表面は、本発
明で定める化学組成範囲に入る鋼では良好である(試験
番号 1〜21)。さらに、これらの鋼により、本発明で定
める条件で圧延冷却して製造された熱延鋼板(試験番号
1〜15)は、表3に示すように、いずれも 540N/mm2
以上の引張強さを満足すると同時に、同じ強度の比較例
の鋼に対し、より大きい伸び、より高い穴拡げ率、およ
びより高い疲労強度が得られる。As shown in Table 2, the surface after rolling is good for steels falling within the chemical composition range specified in the present invention (test numbers 1 to 21). Further, as shown in Table 3, hot rolled steel sheets (test numbers 1 to 15) manufactured by rolling and cooling these steels under the conditions specified in the present invention were all 540 N / mm 2.
At the same time as satisfying the above tensile strength, a larger elongation, a higher hole expansion ratio, and a higher fatigue strength can be obtained with respect to the comparative steel having the same strength.
【0065】一方、鋼の化学組成が本発明範囲内ではあ
るが、仕上温度が規定値の下限を外れた試験番号16で
は、強度、延性、穴拡げ性および疲労限度比が改善され
ていない。これは加工フェライトとパーライトが生成し
たためである。空冷時間が規定値の上限を外れた試験番
号19と、空冷後の冷却速度が規定値の下限を外れた試験
番号20では、パーライトが生成して強度、穴拡げ性が向
上しないとともに疲労限度比もよくない。一方、空冷温
度が規定値の上限を外れた試験番号17および下限を外れ
た試験番号21では、ポリゴナルフェライトの生成量が不
十分で、延性と穴拡げ性が改善されず、切欠き疲労の疲
労限度比も向上しない。さらに、巻取温度が規定値の上
限を外れた試験番号18では、マルテンサイトが生成せ
ず、強度と延性が不足するとともに切欠き疲労の疲労限
度比もよくない。On the other hand, in Test No. 16 in which the steel had a chemical composition within the range of the present invention but the finishing temperature was below the lower limit of the specified value, the strength, ductility, hole expandability, and fatigue limit ratio were not improved. This is because processed ferrite and pearlite were formed. In Test No. 19, in which the air cooling time exceeded the upper limit of the specified value, and in Test No. 20, in which the cooling rate after air cooling exceeded the lower limit of the specified value, pearlite was formed and strength and hole expandability were not improved, and the fatigue limit ratio was not improved. Not good either. On the other hand, in Test No. 17 in which the air cooling temperature was out of the upper limit of the specified value and in Test No. 21 in which the air cooling temperature was out of the lower limit, the amount of polygonal ferrite generated was insufficient, the ductility and hole expandability were not improved, and the notch fatigue was not improved. The fatigue limit ratio does not improve. Further, in Test No. 18, in which the winding temperature was outside the upper limit of the specified value, martensite was not formed, the strength and ductility were insufficient, and the notch fatigue ratio was not good.
【0066】また、C量が本発明で定める上限を外れた
試験番号22、31では、伸びと穴拡げ性が改善されない。
Si量が規定値の上限を外れた試験番号23、Cr量が規
定値の上限を超えた試験番号27、Si量とCr量が規定
値の上限を外れた試験番号28およびP量が規定値の下限
を外れた試験番号29では、表面性状が劣っている。さら
に、Ti量が規定値の下限を外れた試験番号24、30で
は、引張強さないしは疲労強度が不十分であり、疲労限
度比が低い。これは析出強化が不十分なためと考えられ
る。Mn量が規定値の下限を外れた試験番号26では、引
張強さと疲労強度が低く、切欠き疲労の疲労限度比が低
いが、これはマルテンサイトが生成しないためである。
Nb量が規定値の下限を外れた試験番号25、30、31、お
よびN量が規定値の上限を外れた試験番号27、29では、
伸びが劣っている。In Test Nos. 22 and 31 in which the C content was outside the upper limit specified in the present invention, the elongation and the hole expandability were not improved.
Test number 23 in which the amount of Si exceeded the upper limit of the specified value, test number 27 in which the amount of Cr exceeded the upper limit of the specified value, test number 28 in which the amount of Si and Cr exceeded the upper limit of the specified value, and the specified amount of P In Test No. 29, which fell outside the lower limit of, the surface properties were inferior. Further, in Test Nos. 24 and 30 in which the Ti content was below the lower limit of the specified value, the tensile strength or the fatigue strength was insufficient, and the fatigue limit ratio was low. This is considered to be due to insufficient precipitation strengthening. In Test No. 26 in which the amount of Mn was below the lower limit of the specified value, the tensile strength and the fatigue strength were low and the fatigue limit ratio of the notch fatigue was low, but this was because martensite was not generated.
In test numbers 25, 30, 31 in which the Nb amount was outside the lower limit of the specified value, and in test numbers 27, 29 in which the N amount was out of the upper limit of the specified value,
Growth is poor.
【0067】このように、本発明にて定める範囲の条件
にて製造された鋼板は、範囲外の製造条件の鋼板に比較
して、すぐれた性能を有していることがわかる。As described above, it can be seen that the steel sheet manufactured under the conditions in the range defined by the present invention has excellent performance as compared with the steel sheets manufactured under the manufacturing conditions outside the range.
【0068】[0068]
【発明の効果】以上に説明したように、本発明によれ
ば、 540N/mm2 以上の引張強さで、伸びや穴拡げ性、
疲労強度にすぐれ、かつ表面性状の良好な熱延鋼板を安
定して量産することが可能になる。この熱延鋼板は自動
車用あるいは産業機械用の、高強度部材、特にホイール
用材料として好適であり、産業上極めて有用な効果がも
たらされる。As described above, according to the present invention, the tensile strength of 540 N / mm 2 or more, the elongation and the hole expanding property,
Hot rolled steel sheets with excellent fatigue strength and good surface properties can be stably mass-produced. The hot-rolled steel sheet is suitable as a high-strength member for automobiles or industrial machines, particularly as a material for wheels, and has an extremely useful effect in industry.
【図1】熱延鋼板の引張強さと伸びにおよぼすTi含有
量の影響を示した図である。FIG. 1 is a view showing the effect of Ti content on tensile strength and elongation of a hot-rolled steel sheet.
【図2】熱延鋼板の疲労強度とTi含有量との関係を示
した図である。FIG. 2 is a diagram showing the relationship between the fatigue strength of a hot-rolled steel sheet and the Ti content.
【図3】熱延鋼板の引張強さ、伸び、および穴拡げ性に
およぼすC含有量の影響を示した図である。FIG. 3 is a view showing the influence of the C content on the tensile strength, elongation, and hole expandability of a hot-rolled steel sheet.
【図4】疲労試験に用いた2種類の試験片の形状を示し
た図である。FIG. 4 is a diagram showing the shapes of two types of test pieces used in a fatigue test.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平6−293910(JP,A) 特開 平5−179346(JP,A) 特開 平7−118740(JP,A) 特開 平8−188847(JP,A) 特開 平8−143952(JP,A) (58)調査した分野(Int.Cl.7,DB名) C21D 8/00 - 8/10 C21D 9/46 C22C 38/00 - 38/60 ────────────────────────────────────────────────── ─── Continuation of front page (56) References JP-A-6-293910 (JP, A) JP-A-5-179346 (JP, A) JP-A-7-118740 (JP, A) JP-A-8-118 188847 (JP, A) JP-A-8-149542 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C21D 8/00-8/10 C21D 9/46 C22C 38/00- 38/60
Claims (1)
i:0.30%以下(0.30%を除く)、Mn:1.
00〜2.00%、P:0.010〜0.030%、T
i:0.05〜0.15%、Nb:0.01〜0.06
%、N:0.0040%以下、さらにCr:0〜0.6
%、V:0〜0.06%、Ca:0〜0.01%、Z
r:0〜0.10%および希土類元素:0〜0.10%
で、残部が鉄および不可避不純物からなる鋼を、780
〜950℃で熱間圧延を完了した後、30℃/s以上の
冷却速度で600〜700℃の範囲内の温度まで加速冷
却し、その温度から2〜10s間空冷した後さらに50
℃/s以上の冷却速度で250℃以下まで加速冷却し、
巻取ることを特徴とする加工性、疲労特性および表面性
状に優れた540N/mm2 以上の引張強さを有する
高強度熱延鋼板の製造方法。C .: 0.03 to 0.08% by weight, S
i: 0.30% or less (excluding 0.30%) , Mn: 1.
00-2.00%, P: 0.010-0.030%, T
i: 0.05 to 0.15%, Nb: 0.01 to 0.06
%, N: 0.0040% or less, and Cr: 0 to 0.6
%, V: 0 to 0.06 %, Ca: 0 to 0.01 %, Z
r: 0~ 0.10% you and rare earth element: 0 to 0.10%
In, the steel and the balance of iron and inevitable impurities, 780
After completing the hot rolling at 950 ° C. to 950 ° C., accelerated cooling is performed at a cooling rate of 30 ° C./s or more to a temperature in the range of 600 ° C. to 700 ° C.
Accelerated cooling to 250 ° C or less at a cooling rate of 200 ° C / s or more,
A method for producing a high-strength hot-rolled steel sheet having a tensile strength of 540 N / mm 2 or more, which is excellent in workability, fatigue characteristics, and surface properties characterized by winding.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18723795A JP3235416B2 (en) | 1995-07-24 | 1995-07-24 | Manufacturing method of high strength hot rolled steel sheet with excellent workability and fatigue properties |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18723795A JP3235416B2 (en) | 1995-07-24 | 1995-07-24 | Manufacturing method of high strength hot rolled steel sheet with excellent workability and fatigue properties |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0931534A JPH0931534A (en) | 1997-02-04 |
JP3235416B2 true JP3235416B2 (en) | 2001-12-04 |
Family
ID=16202461
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18723795A Expired - Lifetime JP3235416B2 (en) | 1995-07-24 | 1995-07-24 | Manufacturing method of high strength hot rolled steel sheet with excellent workability and fatigue properties |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3235416B2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4507364B2 (en) * | 1999-07-19 | 2010-07-21 | Jfeスチール株式会社 | Manufacturing method of high strength hot-rolled steel sheet |
JP4502646B2 (en) | 2004-01-21 | 2010-07-14 | 株式会社神戸製鋼所 | High-strength hot-rolled steel sheet with excellent workability, fatigue characteristics and surface properties |
JP4840567B2 (en) * | 2005-11-17 | 2011-12-21 | Jfeスチール株式会社 | Manufacturing method of high strength steel sheet |
CN104711480B (en) * | 2015-03-20 | 2017-01-18 | 苏州劲元油压机械有限公司 | Dedicated wear-resisting anticorrosion steel plate for storage rack platform and preparation method of steel plate |
ES2951778T3 (en) * | 2017-02-10 | 2023-10-24 | Tata Steel Ltd | High-strength, precipitation-hardened and grain-refined, hot-rolled dual-phase steel sheet, having a minimum tensile strength of 600 MPa, and a process thereof |
-
1995
- 1995-07-24 JP JP18723795A patent/JP3235416B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH0931534A (en) | 1997-02-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4193315B2 (en) | High strength steel sheet and high strength galvanized steel sheet with excellent ductility and low yield ratio, and methods for producing them | |
JP3347151B2 (en) | Manufacturing method of low yield ratio cold rolled high strength steel sheet with excellent corrosion resistance | |
JP2001226741A (en) | High strength cold rolled steel sheet excellent in stretch flanging workability and producing method therefor | |
JP3247908B2 (en) | High strength hot rolled steel sheet excellent in ductility and delayed fracture resistance and method for producing the same | |
JPH1161327A (en) | High strength automobile steel plate superior in collision safety and formability, and its manufacture | |
JP3247907B2 (en) | High strength cold rolled steel sheet excellent in ductility and delayed fracture resistance and method for producing the same | |
JPH09118952A (en) | Member made of high-strength hot rolled steel sheet having lower yield ratio | |
JPH08337840A (en) | Titanium-containing rolled steel sheet having high strength and excellent drawability and its production | |
JP3864663B2 (en) | Manufacturing method of high strength steel sheet | |
JP3235416B2 (en) | Manufacturing method of high strength hot rolled steel sheet with excellent workability and fatigue properties | |
JP4438614B2 (en) | High-strength hot-rolled steel sheet and manufacturing method thereof | |
JP3410241B2 (en) | Method for producing ultra-thick H-section steel excellent in strength, toughness and weldability | |
JPH10237547A (en) | Cold rolled steel sheet with high ductility and high strength, and its production | |
JP3440710B2 (en) | H-section steel excellent in toughness of fillet portion and method for producing the same | |
JP2621744B2 (en) | Ultra-high tensile cold rolled steel sheet and method for producing the same | |
JP3169293B2 (en) | Automotive thin steel sheet excellent in impact resistance and method for producing the same | |
JP3332172B2 (en) | High strength hot rolled steel sheet with excellent strength-stretch flange balance and strength-ductility balance | |
JP3295900B2 (en) | High strength alloyed hot-dip galvanized steel sheet for deep drawing with excellent secondary work brittleness resistance | |
JP2990214B2 (en) | Alloyed molten Zn-plated steel sheet of ultra-low C-base thin hot rolled sheet excellent in workability and method for producing the same | |
JP3350945B2 (en) | High tensile hot rolled steel sheet with excellent ductility and corrosion resistance and manufacturing method | |
JP3043901B2 (en) | Method for producing high-strength cold-rolled steel sheet and galvanized steel sheet with excellent deep drawability | |
JP3288456B2 (en) | Manufacturing method of cold drawn steel sheet for deep drawing with excellent corrosion resistance | |
JP3107695B2 (en) | Method for producing shaped steel having flange with excellent strength, toughness and weldability | |
JP3827106B2 (en) | Manufacturing method of high-strength hot-rolled steel sheet with excellent press formability and impact properties | |
JP3969351B2 (en) | High-tensile cold-rolled steel sheet and its manufacturing method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080928 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080928 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090928 Year of fee payment: 8 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090928 Year of fee payment: 8 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100928 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100928 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110928 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120928 Year of fee payment: 11 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120928 Year of fee payment: 11 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130928 Year of fee payment: 12 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130928 Year of fee payment: 12 |
|
R371 | Transfer withdrawn |
Free format text: JAPANESE INTERMEDIATE CODE: R371 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130928 Year of fee payment: 12 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130928 Year of fee payment: 12 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
EXPY | Cancellation because of completion of term |