JP3148856B2 - Synthetic resin molded product containing flour powder and method for producing the same - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention
te Jade) and belongs to the technical field of a novel synthetic resin molded product containing a fine powder (soft jade powder) and a method for producing the same.
You. Furthermore, the present invention relates to a method for producing soft jade powder having a very fine interwoven fiber suspension structure in which the fibers of the diagonite-positive series are mixed with a resin material such as polyethylene (PE), polychlorinated chloride. It is added to raw materials such as thermoplastic resin such as vinyl (PVC) and acrylonitrile-butadiene-styrene copolymer (ABS) and thermosetting resin such as phenol, urea and melanin.
The present invention relates to a synthetic resin molded article formed by molding and a method for producing the same, for example, by adding soft powder when manufacturing each of articles such as daily necessities, leisure goods, sports goods, packaging (container) goods, and agricultural goods for greenhouse horticulture. Outstanding properties such as treatment of human body diseases (headache, insomnia, indigestion, numbness of limbs, etc.), removal of impurities from objects (removal of heavy metals, etc.), improvement of water quality, promotion of animal and plant growth, etc. Synthetic that can exert its effects widely in the beneficial life of mankind
An object of the present invention is to provide a resin molded product and a method for producing the same.
You .

[0002]

2. Description of the Related Art As is well known, jade is roughly divided into hard jade and soft jade, and jadeite is classified as pyroxene fa.
mily) is a pyroxene group mineral and is a monoclinic substance composed of silicic acid, aluminum oxide and soda. Its hardness is equivalent to that of a dense mass such as quartz, and its color is black, blue-green, or green, and it is transparent or translucent.

[0003] Nephrite Jade is an inosilicate (I
Nosilicates) are divided into two types of monoclinic pyroxene minerals: gabbro in soft marble and serpentinized ultramafic soft marble. It is determined by the degree of coarseness of the set and the fiber, and it is known that the finer the fiber, the better the quality.

A report published in the German prestigious medical literature ("KRAFF der KRIS" by Mauda Palmer Die Verborgene
According to TALLE und der EDELSTEINE ”), jade and soft jade are two different ores that, like most gems, contain silicon and oxygen, but jade are made of granular crystals. In contrast, soft jade is composed of numerous crystals and fine aggregates, such as fibrous, hair, etc. In particular, soft jade is different from the sodium and aluminum components in jade, and three types of minerals that are beneficial to the human body, In other words, since calcium, iron, and magnesium are the main components, when wearing soft balls, high blood pressure, diabetic cardiovascular disorders,
It has recently been noted that it has a profound effect on the healing of illness due to heart disease and kidney damage.

[0005] According to the Eastern medicine treasure book, a classic of Oriental medicine, if you put jade in Umeshu and Jiyu liquor, it will turn into water. And waste products are discharged outside the body. One shod of litter, one sho of Jinyu grass, one sho of rice and rice, and three sho of white dew are mixed together and put in a copper pot to cook rice. It is known as a soybean liquor, so-called Shinsen Tamazuro. In addition, according to Shinnobu herb, Karamoto herb, and Herbaceae, crushing the ball into powder and making it like sesame seeds not only has the effect of enriching the stomach and excreting the waste products in the body, It removes the heat from the digestive system, produces bronchial asthma and body heat, is good for chest anemia, rests thirst, crushes like sesame seeds and takes it for a long time. It has a long life, lubricates the function of the lungs, helps vocal vocalization, is good for the throat, affects the hair, promotes the function of the viscera, and has the effect of calming especially stress-related nervous diseases. In addition, when muscle tension and convulsions occur, it is good to crush white balls into powder and eat it,
It has been known from a long time ago that the main components of soft balls have excellent side effects with almost no side effects, such as when scars are rubbed with soft balls for several days when there are scars on the face and body.

[0006]

However, despite the fact that soft beads are known for their outstanding medical efficacy due to their rarity, they are not suitable for use in neck wraps, rings, and the like.
It is limited to the use of jewelry such as bangles, etc., and processing of softball requires a long time, effort and delicate attention. It is economically disadvantageous because it cannot be worked on, and it is economically disadvantageous.Therefore, there is almost no development as a general living article using soft balls, and therefore, there is an urgent need for these research and development. Have been.

The present inventor has paid attention to the outstanding medical effects of such softballs, and after conducting research and experiments for over 10 years, during the production of raw materials for synthetic resins or during the production process of synthetic resin products. When the soft resin powder is added to the synthetic resin raw material, mixed and molded by the usual method, the manufactured synthetic resin product has medical functions such as heavy metal removal function, odor removal function, plant growth promotion function, water quality improvement function, etc. In addition to having excellent physical and physical efficacy, the synthetic resin product itself has tensile strength, compressive strength,
The inventors have also found that there is also a rising effect of improving abrasion resistance and the like, and have completed the present invention.

[0008] Accordingly, an object of the present invention is to use the above-mentioned excellent effects of softballs and flourballs for agricultural products such as daily necessities such as kitchenware, leisure, sports goods, and facility horticulture, and the like.
Widely used in daily life, such as fishery products such as fish boxes, transportation and transportation products such as automobile parts, packaging products such as food packaging films, medical products such as eyeglass components, and electronic equipment products such as electrical and electronic components. To provide a new synthetic resin molded article having excellent medical and physical effects applicable to
And there.

[0009]

It is a further object of the present invention to maximize the use of flour powders that are treated as spills or wastes that are derived during mining or jewelry processing of rare flour consisting of unique components. It is to be. Other objects and advantages of the present invention are set forth explicitly below.

[0011]

Means for Solving the Problems As a means for solving the above-mentioned problems of the prior art, a synthetic resin molded article containing fluffy powder according to the first aspect of the present invention is 100 to 350 mesh.
With a particle size of
Of soft-ball flour that is added to resin raw material in an amount of 5 to 15% by weight
Molded into a fixed shape with the mold of the molding machine.
You. Silicon 34% Magnesium 10% Calcium 4.9% Iron 0.23% Aluminum 0.16% Copper 0.17% Cobalt 0.046% Manganese 0.14% Tin 0.024% Beryllium 0.00072% Silver 0.0013 % Titanium 0.0038% Nickel 0.0028% Chromium 0.0030% Others 0

[0012] The flour powder according to the second aspect of the present invention is contained.
The production method of the synthetic resin molded product is 100-350 mesh
It has a particle size of
Of soft-ball flour added to resin material in an amount of 5 to 15% by weight
Manufacturing into products with a certain shape using molding machines
Features. Silicon 34% Magnesium 10% Calcium 4.9% Iron 0.23% Aluminum 0.16% Copper 0.17% Cobalt 0.046% Manganese 0.14% Tin 0.024% Beryllium 0.00072% Silver 0.0013 % Titanium 0038% Nickel 0028% Chromium 0.0030% Others 0

[0013]

Amount of DETAILED DESCRIPTION OF THE INVENTION Soft ball powder, 5 to 15 wt% is suitable (claim 1, claim 2). The added amount is fivefold
If the amount is less than%, it is not desirable because the effect of the addition of the softball powder cannot be expected, and the solid potency of the softball increases as the amount of the softball powder increases. In addition to making the product brittle by lowering the softness, not only may the molding fluidity be reduced,
Nephrite powder is because the price of expensive for products 15% by weight of the resin material total weight less suitable because increases.

The synthetic resin molded product to which flour powder is added can be used after making products such as accessories, bowls, sculptures and the like from fluff, and can be used by pulverizing the remaining stones, which is economical in terms of cost reduction. It is also highly economically evaluated in that a practical synthetic resin molded product having properties unique to soft balls can be obtained at a lower unit price than products such as expensive jade. In addition, the synthetic resin molded product of the present invention has mechanical and thermal properties as compared to general synthetic resin molded products that do not contain soft balls,
That is, heat resistance, tensile strength, compressive strength and the like are high.

In the present invention, synthetic resin means, in a non-restrictive sense, various types which require or are intended to be mixed with flour (see Claim 2). That is, among the synthetic resin raw materials described in the present specification, the thermoplastic synthetic resin is defined as polyvinyl chloride (PVC), polyvinyl acetate (PVAC), polyvinyl alcohol (PVA,
PVAL), polyvinyl acetal, polyvinyl formal (PVFM), polyvinyl butyral (PVB),
Polyvinylidene chloride (PVDC), polyvinylidene chloride-polyvinyl chloride copolymer, polyethylene (PE), polypropylene (PP), polystyrene (PS), styrene-butadiene copolymer (SB, H
IPS), polystyrene form (EPS, FS), acrylonitrile-styrene copolymer (AS, SAN),
Acrylonitrile-butadiene-styrene copolymer (ABS), ethylene-vinyl copolymer (EV
A), ionomer, polycarbonate (P
C), polyvinyl ether-polyvinyl methyl ether, polyvinyl ketone, polytetrafluoroethylene (PTFE), polychlorotrifluoroethylene (PC
TFE), polyvinyl fluoride, polyvinylidene fluoride, tetrafluoroethylene-hexafluoropropylene copolymer, polyamide (PA, Nylo
n), polyacrylamide, polyacrylonitrile (A
N), polyester, polyethylene terephthalate (P
ET), polybutylene terephthalate (PBT), polyacetal, polyoxymethylene (POM), polyethylene oxide, polyphenylene oxide (PPO), polyacrylate (= polyacrylic ester), polymethacrylate (= polymethacrylic ester), Polyurethane (PUR.AU.EU), polyphenylene sulfide (PPS), polysulfone (PSU), polymethacrylonitrile and the like are shown.

The thermosetting resin includes phenol resin (PF), urea resin (UF), and melamine resin (M
F), unsaturated polyester resin (UP), diallyl phthalate resin (PDAP, DAP), aniline-formaldehyde, epoxy resin (EP), furan, xylene-
Formaldehyde, sulfonamide-formaldehyde, silicon (SI), polyurethane form, formaldehyde resin, ketone resin and the like are shown.

The particle size of the soft ball powder is selected in consideration of the use of the synthetic resin molded product and the like, but generally 100 to 350 mesh is preferable ( claims 1 and 2 ). When the softness is to be increased, such as when the shape of the synthetic resin molded article is complicated or the article is thin, 250 to 30 finer particles are required.
0 The use of nephrite powder about the mesh is more favorable, generally the molded articles 100-500 nephrite powder mesh is used is added. Particle size of flour powder is 350 Messi
Undesirable and severe surface roughness of the product when from larger Interview, particles finer than the above range is not desirable to hardly crushed.

[0018] The nephrite powder is most desirable effect surface having a composition ratio of the lower Symbol Table 1.

[0019]

[Table 1] Semi-quantitative analysis value of ball flour sample (Semi-Quantitativ
e Analysis) (%) Silicon 34 Magnesium 10 Calcium 4.9 Iron 0.23 Aluminum 0.16 Copper 0.17 Cobalt 0.046 Manganese 0.14 Tin 0.024 Beryllium 0.00072 Silver 0.0013 Titanium 0.0038 Nickel 0.0028 Chromium 0.0030 Others 0 As the molding method of the synthetic resin, as shown in the following [Table 2], thermoplastics such as injection molding, extrusion molding, blow molding, etc. Resin molding method,
Alternatively, a method of molding a thermosetting resin such as cast molding may be used.

[0020]

[Table 2]

In order to produce a product using a thermoplastic resin, the above-mentioned flour powder is added to the raw material pulverized into granules, mixed and injected into a molding machine. Is pressed into a mold to produce a product having a certain shape (see claim 2 ). In a general molding process, 150 to 300 ° C. is used to soften the raw material resin.
A heating process is indispensable, and soft balls are excellent in heat resistance, so that such a heating process does not cause a thermal change and preserves the inherent effect.

The synthetic resin product produced by the above-mentioned method is more effective when applied to not only tableware and ornaments, but also to accessories such as neckbands, bracelets and rings. In the case of plastic manufacturing, products containing flourballs include plastic films (for industrial and agricultural use), plastic lumps, plastic floor sheets, plastic rods, tubes and profiles, plastic leather, plastic conveyor belts, vinyl wallpaper, and recycled plastic. Raw material (powder),
Can be manufactured into other plastic primary molded products.

On the other hand, in the case of a plastic foam molded product, it can be applied to expanded polystyrene (such as styrene) and industrial foam molded products (including soft and hard). In reinforced plastic molded products, it can be manufactured into other reinforced plastic molded products such as plastic machinery parts (durability, addition of special reinforcing material). In industrial plastic molded products, plastic electric and electronic machine parts, plastic automobile parts It can be applied to plastic cabinets for household appliances (TV, electric storage, sewing machine cabinet, etc.), plastic furniture and other mechanical parts for the plastic industry (pure plastic).

In the case of household plastic products, plastic tableware and kitchen utensils (tableware, dishes, cups, knives, spoons, etc.), plastic sanitary and cosmetic products (basins, bathtubs, soap boxes, trash boxes, etc.), Can be manufactured into plastic buttons, plastic decorations and other household plastic molded products. In the case of plastic molded packaging containers, it can be manufactured into plastic boxes (fish boxes, etc.), plastic bottles, tubs, similar containers, and other plastic packaging containers. it can.

That is, as the synthetic resin molded product containing soft ball powder, various products can be produced according to the classification of the synthetic resin raw materials as described below. PE: bottle, tube, wire coating, food packaging, film,
Pipes PS: Dolls, kitchen equipment, tableware, pipes, heat insulating materials, packaging supplies, office supplies, automobile, electricity, electronics, and other related industrial parts PP: EPDM, rubber for containers, pipes, films, artificial leather, packaging, etc. Automobile parts AS, kitchen parts, telephone parts, pipes PVC: pipes, films, bottles, dolls, record boards, food containers, electric wire coatings Acryl: optical lenses, automobile supplies, TV protection Plate PA: Bearing, hose, film PC: Electric parts Fluororesin: For gasket, fly fan painting Polyester: Various springs (elastic plates), metal inserts, gear bearings PF: Telephone parts, electric products, cups, car handles UF: Button, lighting equipment, clock, container, tableware, radio case MF: Bathtub, button, safety hat, tableware Unsaturated Polyester Aircraft parts, fuel tanks, pipes,
Automobile body, helmet, fishing rod EP: Automobile parts, electric parts, medical equipment PDAP: Electric parts, terminal board, micro switch board PUR: Electric wire coating, rubber SI: Tape, release agent, defoamer Fran: Laminate board, electric Insulation materials Xylene: molded laminates aniline: electrical insulation products, laminates In addition, ABS, which is a high-grade resin located between general-purpose resins and engineering plastics, is used in telephones, radios, toys, dolls, and other electrical and electronic products. It can be used to manufacture product exterior materials and automobile parts. In the agricultural field, it can be used for poultry and livestock shelter, grain rescue, greenhouses, flowerpots, etc.
In the field of fisheries, containers, artificial seaweeds, fish gear (ropes, fishing nets, floats), etc .; in the field of foods, containers or packaging of foods; in the field of medicine, blood vessels, esophagus, urethra, ureter, For teeth, eyes, nose, ears, skin, etc. and other injection tubes, diapers, etc. used in joints and outside the living body, for coated granules and tablets in the pharmaceutical field, and for sound-proofing and vibration-proofing agents in the acoustic field In the field of optics, eyeglass lenses, contact lenses, safety glasses, sunglasses and parts thereof, in the field of textiles, non-woven fabrics, carpets, rainwear, etc., in the field of papers, PE processed paper,
For plastics foam paper (ps paper), etc., for office supplies, such as desks and chairs and stationery such as ballpoint pens, and for household goods, tableware and tableware such as cutting boards, sinks, plates, etc., and dolls. , Baby goods such as toys, breast milk bottles, buckets, vegetable boxes, bathroom goods, etc., in the sports field, boats, sports cars, skates, tennis rackets, golf clubs, etc., in the mechanical field, bearings, gears, brake shoes, etc. In the aircraft field, wings (main, tail, auxiliary), fuselage, windows, indoor bulletin boards, safety glass, etc .; in the marine field, ships, porthole frames, portholes, cabin doors, etc .; For bumpers, body heat insulators, foam cushions for seats, etc., in the telecommunications field for telephones, exchangers, terminal boxes for telephones, etc., in the electronics industry, for organic semiconductors, etc. Washing machine, television,
Radios, refrigerators, barbers, etc.
For interior and exterior materials such as wall materials, flooring materials, tiles, veranda boards, etc., in the civil engineering field, for admixtures (eg, cement), waterproof boards, desert greening, etc. For resin duplicated boards, synthetic resin molds, magnetic tapes, etc., for reactors and various coating materials in the nuclear field, for storage tanks for liquid hydrogen and liquid oxygen in the space development field, and for plastic containers and plastic films in the packaging container field. Etc. can be produced.

A synthetic tree produced by the above-described production method
The effects of the resin molded product will be described in detail in the following examples.

[0027]

【Example】

<Example 1> 10 parts by weight of fluffy flour pulverized to a particle size of 150 mesh was added to and mixed with 90 parts by weight of polyethylene as a thermoplastic resin. The mixed raw materials were injected into the injection molding machine through a hopper of the injection molding machine, and then heated to 100 to 130 [deg.] C. to increase the softness and pressurized while pressing the raw materials into the mold.

The molded article cooled by the mold is drawn out at the same time as the mold is opened, and various forms of products (various containers such as tableware, accessories such as neckbands, bracelets, cormorants, and other decorative articles).
Was obtained. <Example 2> A raw material obtained by mixing 10 parts by weight of fluffy flour crushed to a particle size of 150 mesh with 90 parts by weight of a polyethylene resin was injected into an injection molding machine, and the mixture was heated to 35 to 45 ° C.
By pressing the raw material into the mold by pressurizing with a ram while increasing the softness to obtain a product of a certain shape (for example, tableware, bowls, ornaments, neckbands, bracelets, rings, earrings, etc.) ). <Example 3> A raw material obtained by mixing 10 parts by weight of soft ball powder crushed to a particle size of 300 mesh with 90 parts by weight of an acrylic resin is injected into an injection molding machine and heated to 35 to 45 ° C to be soft. By pressing the raw material into the mold by pressing with a ram while increasing the size, a product of a certain shape was obtained (for example, tableware, bowls, ornaments, neckbands, armbands, rings,
Earrings).

As shown in the above Examples 1-3, the produced synthetic resin product not only improves heat resistance, impact resistance, etc., but also is used as tableware due to the influence of far infrared rays generated from soft balls. In this case, the freshness of food and drink can be maintained for a long time, and when it is made into a jewelry and worn, it has a therapeutic effect. <Experimental Example 1> The following experiment was conducted to test the presence of lead, heavy metals and other toxic components in the soft-ball flour used in the examples of the present invention.

[0030]

[Table 3]

[0031]

[Table 4]

[0032]

[Table 5]

As shown in the above experimental results, the flour powder used in the present invention was safe even when used as tableware because lead, heavy metals and other toxic components harmful to the human body were not detected. It has been proven. <Experimental Example 2> The test cup and the control cup (polyethylene material) manufactured in Example 2 of the present invention were filled with homogeneous Class A milk, left at ambient temperature for 48 hours, and then analyzed. The results are shown in Table 6 below.

[0034]

[Table 6]

Conclusion: A decrease in microorganisms harmful to the human body has appeared. <Experimental Example 3> In this experiment, the effect of soft jade on the growth and development of silkworms and on the quality of silk was examined (see FIGS. 1, 2 and 3). Materials and Methods Announced silkworm variety: Shiratama silkworm 2. 2. Breeding time: hatching nest silkworm (11-December) Rearing method: constant temperature and humidity, all-age mulberry leaf growth 4. Announced head count: control-150 animals 2 repetitions Processing-130 animals 2 repetitions Treatment content: Control-Spraying mulberry leaves with sprayed distilled water Treatment-Spraying soft ball water with mulberry leaves Treatment time: From the 2nd instar silkworm

[0036]

[Table 7]

[0037]

[Table 8]

[0038]

[Table 9]

[0039]

[Table 10]

◎ Results In terms of the weight of the larvae, the softball water treatment device was heavier than the control device, which was a distilled water treatment device, in particular, and the mature silkworm weighed 0.48 g per individual in all ages. 2. The ratio of cultivation is about 15% lower than that of the control with the soft ball soup plant 7
1.2%, and the amount of 10,000 silk collected was 7% lower than that of the control1
It was 5.4 g.

3. The total silk weight of the soft-ball plant is 6% of that of the control.
Weighs 2.14 g, and the silk layer weight is also about 9% heavier4
It was 4.5 cg. The silk layer ratio appeared 2% higher in index than the control. 4. The soft-ball inlaying device had generally better threading results than the control. In particular, the length of the silk thread was long, the amount of the silk thread was large, and the disintegration rate was approximately 9% higher than that of the control by an index, and the disintegration thread amount was several times higher.

5. Regarding the yarn quality, the soft-ball-planted plant had a slightly thicker fineness, higher strength, elongation, and a higher raw silk ratio than the control. However, the amount of silk was small and the amount of the 10,000 raw silk was lower than the control. 6. No large difference was found between the control device and the treatment device in the surface structure of the silk thread. 7. The hypoglycemic effect of the silkworm larvae added to the softball was 70.3%, which was 24% higher than the control by an index.

8. The crystal structure of the planted soft ball had a pointed rod-like structure. <Experimental Example 4> In this experiment, changes in the activity of rats on day 20 after drinking the potato drinking water were observed. As a result, as shown in FIG. 4, in the stabilizing effect experiment, in the positive control group, the central nervous system began to stabilize 5 minutes after drinking the ubavito (Chinese name) drug, and gradually started 30 minutes later. The rats in the normal control group recovered to normal, and the activity of the rats showed undulations and showed a tendency to decrease overall.

The activity rate of the drinking test water of the present invention (mouse 20 days) is similar to that of the general control group, but the average value of the total activity rate is higher than that of the general control group. It can be seen that a more significant difference occurs when compared to the positive control group. Experimental Example 5 In this experimental example, an infrared experiment was performed.

[0045]

[Table 11]

Morphology: Tetrahydrofuran liquefied thin film Appeared as one conforming to the pattern of the polycarbonate resin, and appeared to emit electromagnetic waves having a wavelength of 6 to 52 μm. <Experimental Example 6> In this experimental example, an experiment was performed on the chemical and biological oxygen demand for the ball dust sample of the present invention.

[0047]

[Table 12]

<Experimental Example 7> In this experimental example, an experiment was performed on the influence of soft ball powder on an experimental device (rabbit).

[0049]

[Table 13]

Experimental process: 0.1 ml of the extract is placed on the inverted lower eyelid of the first side, and then gently grasped for 1 second before releasing the upper and lower eyelids. The other side is not treated and is observed as a control. The treated eyes of the six rabbits are kept unwashed, and the eyes of the three rabbits are washed immediately after treatment with a stream of warm water for 1 minute. The eyes were pre-examined by fluorescence before treatment with the samples, and only animals that did not show corneal damage were used for the test. Eye lesions were observed at 24, 48, 72, 7 and 14 days after treatment.

[0051]

[Table 14]

I. Cornea (A) Opacity-Density (area for detoxification) Normal-0 Diffusion areas are scattered-Iris details are clearly visible-1 Translucent areas that are easily identified, details of the iris are slightly faint -2 Milky white area, iris detail not visible, pupil size almost indistinguishable -3 Opaque, iris invisible-4 (B) Corneal area Normal-0 1/4 or less, but non-zero-1 1/4 or more, 1/2 or less-2 1/2 or more, 3/4 or less-3/4 or more, total area or less-4 points: A x B x 5, total maximum value = 80 II. Iris (A) value Normal-0 Folded more than normal, hyperemia, swelling, pericardial congestion (these symptoms appear alone or in combination at any size), and the iris responds to light before (slow) (Remarkable response) -1 No response to light, bleeding, total destruction (one or all of these symptoms)-2 points A x 5, total possible maximum = 10 III. Conjunctiva (A) Red tide (relevant only to the conjunctiva of the eyelid) Normal-0 The blood vessels are significantly more reddened than normal-1 More diffuse, deeper crimson appears, and each blood vessel is easily distinguished-2 Diffuse Is red like raw beef -3 (B) chemosis no swelling -0 any swelling phenomena above normal (including swelling membrane) -1 apparent swelling with partial reversal of eyelid -2 Approximately half closed and swollen -3 About half of eyelid to complete swelling -4 (C) Secretion Normal-0 Optional phenomena different from normal (does not include small amounts observed in the medial eye end of normal animals) -1 Eye Secretion wet only on the eyebrows adjacent to the lid and eyelid-2 occupies a considerable area around the eye-3 points (A + B + C) x 2, total maximum = 20 Conclusion: This sample has no irritation to the eyes Is determined. Therefore, it was understood to be suitable for eye makeup products.

[0053]

[Table 15]

Experimental procedure: The patch test technique was used on the peeled and original skin of white rabbits. Hair was shaved short on the back and flank. Two regions on the back about 10 cm apart were selected as patch positions. On one side, make a small incision in four places in the patch area and peel off the skin (two of which are perpendicular to the rest and use a "tic-tac-toe" method). A one inch square patch of surgical gauze is applied using a rubber band and adhesive tape. The sample is introduced in a volume of 0.5 ml (g) below the patch at each site. Animal torso
Wrap with a rubberized cloth for an exposure time of 4 hours. Animals become immobile during the exposure time. After removing the patch,
The results of evaluating the reactions that appeared at each site based on the following scores are as follows.

Evaluation of skin reaction Erythema and erythema formation No erythema-0 Very faint erythema (slightly recognizable) -1 Erythema roughly distinguished-2 Normal to severe erythema-3 Severe erythema (beat) Edema formation no edema-0 very weak edema (slightly perceptible) -1 slight edema (significant edge of area) Is)
-2 Normal edema (about 1 mm swelling) -3

[0056]

[Table 16]

Conclusion: This sample is judged to have no irritation to the skin. Therefore, it was understood that it was suitable for use in skin cosmetic products.

[0058]

[Table 17]

Preparation of sample: A portion of the sample was put into sterile distilled water, extracted by boiling for 10 minutes, and the extract was administered by intubation in an amount of 0.5 g per 100 g of body weight. Conclusion: The sample met the criteria that should not have oral toxicity. <Experimental Example 8> In this experimental example, an experiment was performed on the food decomposition rate of the rice bowl with the synthetic resin produced according to the present invention.

[0060]

[Table 18]

Experimental method: Five roses (test group) and the same number of general porcelain roses (control group) were filled with a mixture of rice and sterilized 1: 1 and left at room temperature for 24 hours. The flat rose lid was removed so that it was completely exposed to the air, and the two groups were placed approximately 1 meter apart. At the time point shown in the following results, the standard fine plate coefficient (Standard Plate Count) was performed.

[0062]

[Table 19]

Conclusion: In the decomposition of the food contents of the test group flat roses and the control group flat roses, the food decomposition rate of the test group flat roses was relatively lower than that of the control group flat roses. It is understood that this has a favorable effect on the food storability. <Experimental Example 9> In this experimental example, as another method for investigating the various effects of the ball dust on a living body, in order to know whether or not it actually has a good effect on the activity of a plant cell,
An experiment on the effects of Digitalis plant cell proliferation was performed on request from the Bioinformatics Engineering Laboratory at Inha University.

Next, the results of medical biomechanical research experiments on the biological effects of softballs will be described in detail. In this experiment, since 70% of the constituents of the human body were water, it was determined that there would be a large relationship between the change in water and the effect on the human body, and what kind of effect it had on hard water was examined.
Experiments on the effects on plant cell growth were performed. A. Change in Hard Water <Experiment 1> After 100 mL of artificially made hard water was transferred to each of four flasks by 50 ml, soft balls were placed on the bottoms of two flasks for about 10 minutes.

In order to know the change in hardness, an appropriate method using EDTA (titer: 2.9412) was used. pH 10
1 ml of the above buffer solution and the indicator EBT were used. The change in hardness was measured by the amount of EDTA up to the moment when the color of the hard water was changed by EDTA. At this time, the color may return to the original color over time, but in this experiment, the measurement was performed based on the moment when the color changed.

<Result 1> At 100 ppm of hard water, EDTA was
1.70 ml required, 1.25 ml EDTA required after softball experiment, so hardness of 100.00 ppm is 73.53 pp
m. That is, the hardness of 100.00 ppm is 2
6.47% softened. <Experiment 2> 200 ml of 100 ppm hard water produced in the same manner as in Experiment 1 was transferred to a beaker, and soft balls were pickled.

After about 30 minutes, the change in hardness was measured by dividing the water filled in the beaker into three flasks. In this experiment, the color of the hard water was changed to EDTA to perform a more precise experiment.
Even after the change, the EDTA was introduced until the change did not occur any more, and the hardness at that time was measured. <Result 2> The hard water of 100 ppm before the softball experiment was 89.26 ppm, 91.19 ppm, and 89.62 pp, respectively.
m, the average is 90.14 ppm. Therefore, 9.9%
This means that the hardness has decreased.

<Experiment 3> This experiment was conducted using ordinary tap water. After filling the containers with tap water, the flasks were transferred to six flasks, and soft balls were placed at the bottoms of three flasks, and the hardness was measured after about 5 minutes. <Result 3> 97.48p of tap water without soft ball experiment
pm, 97.48 ppm, 97.48 ppm, average 9
7.48 ppm, and the tap water after the softball experiment was 91.1
9 ppm, 91.19 ppm, and 91.19 ppm, and the average was 91.19 ppm, which means that the average hardness was reduced by 6.5%. B. Effect of soft jade on growth of Digitalis lanata cells in suspension of Digitalis lanata cells in growth medium

[0069]

[Table 20]

[0070]

[Table 21]

[0071]

[Table 22]

[0072]

[Table 23]

In Tables 20 to 23 above,
[Table 20] shows the change in the total volume of the culture solution of the cells growing in the growth medium for 11 days. As time elapses, the depletion of the medium components and the evaporation of the medium occur in proportion to the increase in the number of cells that grow, so that the change in the volume of the whole culture medium reflects such factors. In particular, the humidity or temperature of the atmosphere is closely related to the evaporation of the medium, and such factors also influence the cell growth rate. As shown in the table, the volume of the whole culture solution was gradually decreased when the soft jade was used, as compared with the control group in which the soft jade was not used. This is because the use of softballs compared to the control group has a faster cell growth rate with respect to medium evaporation or nutrient depletion, thus offsetting the rapid decrease in medium depleted to some extent. Such a phenomenon was measured by measuring the volume change of only the sinking cells [Table 2].
As in [1], it can be estimated from the fact that the case where soft balls are used continuously from day 4 to day 11 after inoculation shows that the cell volume shows a larger increase than the control group where no soft ball was used. Therefore, when the soft jade was used, the growth rate was faster than in the control group where no soft jade was used. Such a result can be said to be the result of offsetting nutrient depletion and the decrease in the volume of the whole culture medium due to evaporation of the medium, and the rate of decrease in the total volume is slower than in the control group. Also, the result of comparing the volume of the increased cells alone is observed to have a tendency to gradually increase the cell volume from 4 days later, and thus it is thought that such a result can be boosted.

As a method for measuring the growth state of a cell, the cell biological weight and dry weight, which are the most common measures, are measured.
In general, the growth curves of all cells are displayed as S-shaped curves, which are classified into four stages. In other words, there is a lag phase in which the cells do not proliferate as a period of adaptation to the medium and remain in a state where the mass does not increase, and a curve having a steep slope with the mass increasing to a rapid growth rate after this period has elapsed. The exponential phase shows a growth phase that is maximal and growth stops and no further mass increase is observed, and the cells are ruptured due to nutrient depletion, excretion of toxic components, and saturation of cell density. There is a dead phase in which the total cell volume and mass are reduced rather than the tendency to die.

[Table 22] and [Table 23] are the results of measuring the cell biological weight and dry weight. [Table 22] follows a four-stage growth curve. When the soft jade was used, compared to the control group that did not use the soft jade after 7 days, the growth rate was gradually increased, and then the growth was stopped, unlike the control group, which showed a decrease in cell biomass. It shows a tendency to be maintained until the day after. Compared to the change in the concentration of glucose, a nutrient that acts as the main metabolic substrate in the medium, cell growth continues even when this nutrient is almost depleted and the concentration in the medium becomes zero. Note the points. At this point when nutrients are depleted, as in the control group where no soft jade was used, it is common to show a tendency for growth to stop and the growth rate to decrease. Considering that the phenomena show different phenomena, it is speculated that there is an effect of softballs on cell growth. As can be seen from [Table 23], the results show that the cells grow at a higher rate than the control group after the third day, and the phenomena as shown in [Table 22] from the ninth day.

[0076] As a result, cells grown in the growth medium with the softballs approached had a better effect on cell growth than the control group, which did not. Di showing the growth limit period of about 10 days
When cultured using soft jade, gitalis lanata plant cells maintain a stable state in which cells do not undergo necrosis without replacement with a new medium even after 10 days. It is expected that this method can be applied as an advantageous method for optimizing cell growth and concentration in a production process for producing useful substances.

Effect of Softball on Changes in Medium pH

[0078]

[Table 24]

[0079]

[Table 25]

[Table 24] shows the change in the pH of the medium in the case where the soft jade was used in the growth medium and in the control group where the soft jade was not used. The control group shows a pH tendency in the medium applied to the case of general plant cells, and gradually becomes lower with the passage of time, and shows a phenomenon that the line is maintained.
However, when the soft jade was used, until the 7th day, the appearance was similar to that of the control group and then gradually increased. Such a phenomenon is extremely manifested in the results of [Table 25] which shows the results in a production medium in which flour powder is directly added to a culture solution. In the case of the control group to which no flour powder was added, the pH continuously decreased, but when the flour powder was added, the value tended to be maintained to some extent. This is presumed to be caused by the ionic reaction caused by the mineral organisms contained in the soft jade.

Table 26 and Table 27 below show the state of the analytical measuring instrument and the analytical results. These data are organized for each sample and shown in Table 28. ] To [Table 31]. [Table 2
8] is a measurement of each analysis item for 48 hours (Sample 1) after 20 g of soft globules were put into the solution. In this table, there is no change in each measurement item, and no influence by the softball appears. [Table 29] shows that 2
Forty-eight hours have elapsed since the 0 g of the soft-bead was placed (Sample 2), the measurement values were obtained for each analysis item. In this experiment, no change appeared for each analysis item. Even when flour powder was placed outside the solution shown in [Table 31] (Sample 4), there was no change for each analysis item. In the case of Sample 3, data obtained by measuring each analysis item of the sample 48 hours after the addition of 20 g of soft-ball flour in the solution is shown in [Table 30]. Many changes that can be seen from this table are as follows.

Cr, Pb, Ni and Co harmful to the human body are 4
After 8 hours, it changed greatly. When Cr was not added, that is, 45.30 mg before the reaction, Cr was reduced to 0 48 hours after the addition of the flour, and Cr was also reduced from 13.76 mg to 0. It has been completely removed. Ni decreased from 51.8 mg to 1.733 mg, and Co also decreased from 52.69 mg to 11.94 m.
g.

Mg, one of the elements necessary for the human body, is 4
It increased from 8.36 mg to 55.74 mg. This increased in combination with the components of the softball itself, but there was no change in hardness. The hydrogen ion concentration of the distilled water was acidic at pH 3.5, but after the reaction, the pH changed to neutral at pH 6.8, and the conductivity sharply decreased. The adsorption power is about 3-4 mmol.q / g (equivalent), which is a physically large amount.

[0084]

[Table 26]

[0085]

[Table 27]

[0086]

[Table 28]

[0087]

[Table 29]

[0088]

[Table 30]

[0089]

[Table 31]

As described above, in the case of Digitalis lanata plant suspension cells cultured for one week with a soft jade close to them, about 30% or more of the growth was observed when no soft jade was present. This is a rare good growth result than many experiments performed for growth effects on conventional Digitalis lanata plant cells for high concentration culture. Experiments on the effects of softballs on hard water showed that softballs softened hard water even without contact with water.

In particular, in a component analysis experiment on water using distilled water, in component analysis 48 hours after precipitation of the soft-ball flour, the Ni and Co components decreased with increasing pH, and C decreased.
Unusual phenomena such as the removal of r and Pb and the phenomena such as the increase of Mg with the removal of heavy metals were observed. Thus, the soft jade and soft jade flour according to the present invention, although not clearly theoretically investigated so far, change the hardness of water even without contact with water and reduce the number of Digitalislanata plant suspension cells by 30%. %, The removal of heavy metal components harmful to the human body, such as the reduction of Ni and Co components and the removal of Cr and Pb. It is evident that the radiation effect of the electromagnetic wave wavelength of the powder and the ionic reaction caused by the mineral components contained in the soft jade are apparent. This is also believed to be assured by the efficacy exhibited by the products according to the invention described above.

Such experimental results indicate that, in the case of the synthetic resin container containing the soft-ball flour of the present invention, the removal of heavy metals and the softening of hard water when storing food, drinking water, etc., and the synthetic resin product of the present invention This suggests the possibility of promoting the growth of organisms when used as a chalet or flower pot. <Experimental Example 10> In this experimental example, 50 male and female adults complaining or being diagnosed with symptoms such as headache, insomnia, numbness of limbs, indigestion, etc., were subjected to the accessory (neck) manufactured in Example 2 of the present invention. 20) at least one of the following:
After wearing for days, the effect was evaluated by questionnaire survey. The results are shown in [Table 32] below.

[0093]

[Table 32]

[0094]

[Effects of the present invention] As can be seen from the above experimental results, when wearing a jewelry made of the synthetic resin of the present invention on the body, headache (80%), insomnia (81%), numbness of limbs (90%) ), Indigestion (89%) was alleviated.

[Brief description of the drawings]

FIG. 1 is a SEM photograph of the crystal structure diagram of the ball powder of the present invention.
It is a magnification of 00 times.

FIG. 2A is a 1500-times enlarged SEM photograph of the non-treated water of the present invention, and FIG. 2B is a 5000-times enlarged SEM photograph of non-treated silk of the present invention. is there.

FIG. 3A is a 1500-times enlarged SEM photograph of the water-treated silk of the present invention, and FIG. 3B is a 5000 times magnification of a SEM photograph of the silk-treated water of the present invention.

FIG. 4 is a diagram showing the change in activity of a test device (mouse on day 20) after drinking the ball meal water of the present invention.

──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int. Cl. ⁷ , DB name) C08L 101/00

Claims (2)

(57) [Claims] 1. It has a particle size of 100-350 mesh,
Soft flour consisting of the components of the semi-quantitative analysis values
Add 5 to 15% by weight of the raw material to the mold of the molding machine.
Contains soft ball powder, characterized by being molded into a fixed shape
Synthetic resin molded products. Silicon 34% Magnesium 10% Calcium 4.9% Iron 0.23% Aluminum 0.16% Copper 0.17% Cobalt 0.046% Manganese 0.14% Tin 0.024% Beryllium 0.00072% Silver 0.0013 % Titanium 0.0038% Nickel 0.0028% Chromium 0.0030% Others 0 2. It has a particle size of 100-350 mesh,
Soft flour consisting of the components of the semi-quantitative analysis values
Using a molding machine, add 5 to 15% by weight of
Soft balls, manufactured in a product with a fixed shape
A method for producing a synthetic resin molded product containing powder. Silicon 34% Magnesium 10% Calcium 4.9% Iron 0.23% Aluminum 0.16% Copper 0.17% Cobalt 0.046% Manganese 0.14% Tin 0.024% Beryllium 0.00072% Silver 0.0013 % Titanium 0.0038% Nickel 0.0028% Chromium 0.0030% Others 0