JP3134019B2 - Nozzle for casting - Google Patents

Nozzle for casting

Info

Publication number
JP3134019B2
JP3134019B2 JP04245013A JP24501392A JP3134019B2 JP 3134019 B2 JP3134019 B2 JP 3134019B2 JP 04245013 A JP04245013 A JP 04245013A JP 24501392 A JP24501392 A JP 24501392A JP 3134019 B2 JP3134019 B2 JP 3134019B2
Authority
JP
Japan
Prior art keywords
nozzle
casting
molten steel
slit
side wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP04245013A
Other languages
Japanese (ja)
Other versions
JPH0691355A (en
Inventor
貞信 杉浦
邦夫 速水
輝久 川島
Original Assignee
東芝セラミックス株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 東芝セラミックス株式会社 filed Critical 東芝セラミックス株式会社
Priority to JP04245013A priority Critical patent/JP3134019B2/en
Publication of JPH0691355A publication Critical patent/JPH0691355A/en
Application granted granted Critical
Publication of JP3134019B2 publication Critical patent/JP3134019B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Continuous Casting (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Ceramic Products (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、鋼の連続鋳造に使用
されるロングノズル、浸漬ノズル或いはタンディッシュ
パイプなどに関し、特に空気の遮断性および保温性を高
めた鋳造用ノズルに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a long nozzle, a submerged nozzle or a tundish pipe used for continuous casting of steel, and more particularly to a casting nozzle having improved air-blocking and heat-retaining properties.

【0002】[0002]

【従来の技術】鋼の連続鋳造では溶鋼が空気に接触する
と、溶鋼が酸化したり、溶鋼中の窒素ガス含有量が増加
したりで鋼の品質が劣化する。これを防ぐため、取鍋と
タンディッシュ間に、ロングノズルまたはタンディッシ
ュパイプを、またタンディッシュとモ−ルド間に、例え
ば図2に示すような浸漬ノズルを配置し、溶鋼を取鍋か
らタンディッシュへ、さらにタンディッシュからモ−ル
ドへと導くことが広く行われている。
2. Description of the Related Art In continuous casting of steel, when the molten steel comes into contact with air, the quality of the steel deteriorates due to oxidation of the molten steel and an increase in the nitrogen gas content in the molten steel. In order to prevent this, a long nozzle or tundish pipe is placed between the ladle and the tundish, and an immersion nozzle as shown in Fig. 2 is placed between the tundish and the mold. It is widely practiced to lead to dishes and from tundish to mold.

【0003】即ち、ここで使用するロングノズル、タン
ディッシュパイプ、浸漬ノズルが溶鋼流の流れ方向を制
御するとともに、溶鋼と空気との接触を絶つことで溶鋼
の酸化や、溶鋼に窒素ガスの混入するのを防いでいた。
しかしながら、こうしたロングノズル、タンディッシュ
パイプ或いは浸漬ノズルを使用しても、鋳造ノズルの材
質自体の気密性が使用中に低下し、溶鋼の酸化や温度拡
散の問題が十分に解決されていなかった。
That is, the long nozzle, tundish pipe, and immersion nozzle used here control the flow direction of the molten steel flow and cut off the contact between the molten steel and air, thereby oxidizing the molten steel and mixing nitrogen gas into the molten steel. Was prevented from doing so.
However, even when such a long nozzle, tundish pipe or immersion nozzle is used, the airtightness of the material of the casting nozzle itself is reduced during use, and the problems of oxidation and temperature diffusion of molten steel have not been sufficiently solved.

【0004】それは、ロングノズル、タンディッシュパ
イプ、浸漬ノズルの材質はAl2 3 −C質、ZrO2
−C質が主に採用されているため、この中のグラファイ
ト、ピッチコ−クス、レジンコ−クスなどの炭素成分や
シリカガラスがノズルの側壁内部に分布しており、ノズ
ルを高温で使用しているうちに、これらが側壁の気孔内
の空気と接触して酸化あるいは還元反応してガス化し、
CO、CO2 、SiOとなって揮散、消失し、これによ
ってノズルの側壁がポ−ラスとなり、ノズルの気密性が
低下するためであった。
The materials of the long nozzle, tundish pipe and immersion nozzle are Al 2 O 3 -C, ZrO 2
Since carbon is mainly used, carbon components such as graphite, pitch coke and resin coke and silica glass are distributed inside the side wall of the nozzle, and the nozzle is used at a high temperature. In the meantime, they come into contact with the air in the pores on the side walls and undergo oxidation or reduction to gasify,
This is because CO, CO 2 , and SiO volatilize and disappear, which causes the side wall of the nozzle to become porous, thereby reducing the airtightness of the nozzle.

【0005】このため、浸漬ノズルなどを用いて溶鋼と
空気との接触を絶って鋼の鋳造を行っても、必ずしも十
分に溶鋼の酸化や溶鋼への窒素ガスの流入を回避するこ
とは出来なかった。
For this reason, even if the steel is cast by cutting off the contact between the molten steel and the air using an immersion nozzle or the like, it is not always possible to sufficiently avoid oxidation of the molten steel and inflow of nitrogen gas into the molten steel. Was.

【0006】[0006]

【発明が解決しようとしている課題】この発明は、ロン
グノズル、タンディッシュパイプ、浸漬ノズルといっ
た、溶鋼ノズルの側壁内部に残存する空気がノズル内へ
通過するのを遮断して、溶鋼の酸化や窒素ガスの混入を
防止し、併せて溶鋼の熱拡散を回避し良好な鋼の鋳造が
行えるようにした鋳造用ノズルを得ようとするものであ
る。
SUMMARY OF THE INVENTION The present invention is intended to prevent the air remaining in the side wall of a molten steel nozzle, such as a long nozzle, a tundish pipe, and a submerged nozzle, from passing into the nozzle, thereby oxidizing the molten steel and reducing nitrogen. It is an object of the present invention to provide a casting nozzle that prevents gas from being mixed and avoids thermal diffusion of molten steel so that good steel can be cast.

【0007】[0007]

【課題を解決するための手段】この発明は、溶鋼の鋳造
用ノズルのノズル孔外周の側壁内部にスリットを設け、
ここに700〜1550℃で軟化、溶融する低融点物質
を充填し、ここに断熱兼通気遮断層を形成したことを特
徴とする鋳造用ノズル(請求項1)、700〜1550
℃で軟化、溶融する低融点物質がアルミナ−シリカフア
イバ−、岩綿、フリット、ガラスの中のいずれか一種で
ある請求項1記載の鋳造用ノズル(請求項2)および鋳
造用ノズルが、ロングノズル、タンディシュパイプ、浸
漬ノズルのいずれかである請求項1記載の鋳造用ノズル
(請求項3)である。
SUMMARY OF THE INVENTION According to the present invention, a slit is provided inside a side wall of a nozzle hole of a molten steel casting nozzle.
A casting nozzle (Claim 1), wherein a low-melting substance that softens and melts at 700 to 1550 ° C. is filled therein, and a heat insulating and ventilation blocking layer is formed therein.
The casting nozzle (Claim 2) and the casting nozzle according to claim 1, wherein the low-melting substance softened and melted at a temperature of one degree is any one of alumina-silica fiber, rock wool, frit and glass. The casting nozzle according to claim 1, which is one of a nozzle, a tundish pipe, and an immersion nozzle (claim 3).

【0008】[0008]

【作用】本願発明は、鋳造用ノズルのノズル孔外周の側
壁内部にスリットを設け、ここに700〜1550℃で
軟化、溶融する低融点物質を充填し、ここに通気兼断熱
層を形成したので、これを高温で使用している中に、組
織の炭素やシリカが酸化あるいは還元反応してガス化
し、CO、CO2 、SiOとなって揮散、消失し、組織
がポ−ラスとなっても、ノズル内を通過する溶鋼が空気
と接触したり、溶鋼の熱拡散を防ぐことが出来る。
According to the present invention, a slit is provided in the side wall of the outer periphery of the nozzle hole of the casting nozzle, and a low-melting substance softening and melting at 700 to 1550 ° C. is filled therein, and a ventilation and heat insulating layer is formed here. While this is used at a high temperature, the carbon or silica of the tissue is oxidized or reduced and gasified by the oxidation or reduction reaction to evaporate or disappear as CO, CO 2 or SiO, and the tissue becomes porous. In addition, the molten steel passing through the nozzle can be prevented from coming into contact with the air and the heat diffusion of the molten steel can be prevented.

【0009】[0009]

【実施例】図1はこの発明になる鋳造用ノズルの側断面
図で、1は鋳造用ノズル本体である。2はノズル1の側
壁で、この側壁2内部にはスリット3が設けられてお
り、これに低融点物質4が充填されている。5はノズル
孔で、溶鋼は矢印6の方向に流される。ノズルの側壁2
に設けられるスリット3はノズル孔5の全周に設けるこ
とが必要で、しかも長さは、ノズル全長に対して2〜8
割程度の範囲で設けるのが好ましい。また、この発明で
用いられる低融点物質は、700〜1550℃で軟化、
溶融する物質を用いる。これが700℃未満では、溶融
された物質の流動性が大きく、ノズル組織の微細気孔か
らこれが浸出するおそれがあり好ましくない。またこれ
が1550℃を超えると鋼の鋳造でこれが軟化、溶融し
ないので、これで必要な断熱兼通気遮断層を形成するこ
とは出来ない。かかる低融点物質は、例えばアルミナ−
シリカフアイバ−、岩綿、フリット、ガラスである。
1 is a sectional side view of a casting nozzle according to the present invention, and 1 is a casting nozzle body. Reference numeral 2 denotes a side wall of the nozzle 1. A slit 3 is provided inside the side wall 2, and a low melting point substance 4 is filled in the slit. Reference numeral 5 denotes a nozzle hole through which molten steel flows in the direction of arrow 6. Nozzle side wall 2
Is required to be provided on the entire circumference of the nozzle hole 5, and the length is 2 to 8 with respect to the entire length of the nozzle.
It is preferable to provide it in a range of about 30%. The low-melting substance used in the present invention softens at 700 to 1550 ° C.
Use a substance that melts. If the temperature is lower than 700 ° C., the flowability of the molten substance is large, and this may undesirably leak out from the fine pores of the nozzle structure. On the other hand, if it exceeds 1550 ° C., it does not soften or melt in the casting of steel, so that it is not possible to form the necessary heat-insulating / ventilating layer. Such low melting point materials include, for example, alumina-
Silica fiber, rock wool, frit, and glass.

【0010】本発明のノズルの材質は、従来と同様に、
例えばAl2 3 −C、ZrO2 −Cが使用されるが、
ノズルのモ−ルドパウダ−と接触する部分7は、ジルコ
ニア−グラファイトを用いるのが好ましい。
[0010] The material of the nozzle of the present invention is the same as the conventional one.
For example Al 2 O 3 -C, but ZrO 2 -C is used,
The portion 7 of the nozzle which comes into contact with the mold powder is preferably made of zirconia-graphite.

【0011】この発明の鋳造用ノズルは、例えば次のよ
うにして製造される。即ち、粉末原料をモ−ルド型に充
填するときに、ノズル側壁の内部に、ノズルの使用時の
高温で炭化するような例えばパラフイン紙と、低融点物
質を充填しておく。このようにしたモ−ルド型をラバ−
プレスなどで加圧成形し鋳造用ノズルとする。
The casting nozzle of the present invention is manufactured, for example, as follows. That is, when the powder raw material is filled into a mold, the inside of the nozzle side wall is filled with, for example, paraffin paper which is carbonized at a high temperature when the nozzle is used, and a low melting point material. This mold type is
It is molded under pressure by a press or the like to form a casting nozzle.

【0012】次いでこれを常法によって使用すると、ノ
ズル内のパラフイン紙は溶鋼の高熱で加熱されて炭化
し、ここに気密状態のスリットが形成される。それと同
時に、ここに充填しておいたアルミナ−シリカフアイバ
−、岩綿などの低融点物質がスリットの中で軟化、溶融
状態となる。溶融状態となったこれらの低融点物質は、
ノズル側壁のスリット内で、その片側壁或いは両側壁に
被膜を形成したり、その他様々の状態で存在して外部の
通気の遮断、断熱の作用を果たす。次に、この鋳造ノズ
ルにおいて、スリットに充填した低融点物質の軟化温度
の相違によるノズルの断熱性を調べた。
Then, when this is used in a conventional manner, the paraffin paper in the nozzle is heated by the high heat of the molten steel and carbonized, and an airtight slit is formed therein. At the same time, the low melting point material such as alumina-silica fiber and rock wool filled therein is softened and melted in the slit. These low-melting substances in the molten state
In the slit of the nozzle side wall, a film is formed on one side wall or both side walls, or exists in various other states, and functions to block external ventilation and to perform heat insulation. Next, in this casting nozzle, the heat insulating property of the nozzle due to the difference in the softening temperature of the low melting point material filled in the slit was examined.

【0013】実験は、図1に示す本願発明のノズルを用
いたが、そのノズルの長さ方向略中央部の断面サイズは
図3の通りとした。即ち、このノズルの長さ方向の略中
央部で、外径寸々が149mm、内径77mmとした。スリ
ットは、ノズル孔の外側から13mmのところに、幅3mm
でノズル孔の全外周に設けた。スリットには、図3で上
側半分の実線で示した部分に、700℃で軟化するアル
ミナ−シリカフアイバ−を充填し、下側半分には126
0℃で軟化するアルミナ−シリカフアイバ−を充填し
た。ノズル全長は580mm、スリット長は340mmとし
た。ノズルの測温は、ノズルの下端から300mmで、し
かも図3のA,B,Cの3箇所で行った。上記のノズル
孔の下端を閉じ、その上部から1500〜1700℃の
溶鋼(鋳鉄)を注入して、注湯側温テストを行った。こ
の結果を図4に示した。
In the experiment, the nozzle of the present invention shown in FIG. 1 was used, and the cross-sectional size of a substantially central portion in the longitudinal direction of the nozzle was as shown in FIG. That is, the outer diameter was 149 mm and the inner diameter was 77 mm at a substantially central portion in the length direction of the nozzle. The slit is 3mm wide at 13mm from the outside of the nozzle hole.
At the entire periphery of the nozzle hole. The slit is filled with an alumina-silica fiber softening at 700 ° C. in the upper half shown by a solid line in FIG.
An alumina-silica fiber softening at 0 ° C. was filled. The total nozzle length was 580 mm, and the slit length was 340 mm. The temperature of the nozzle was measured at 300 mm from the lower end of the nozzle and at three points A, B and C in FIG. The lower end of the nozzle hole was closed, and molten steel (cast iron) at 1500 to 1700 ° C. was injected from above to perform a pouring side temperature test. The result is shown in FIG.

【0014】図4から明らかなように、注湯後、時間の
経過とともにノズル孔内面Aの温度は急激に下がって行
くが、ノズル側部B,C部の温度の上昇は少なく、しか
も低融点物質として軟化温度が700℃の充填材を用い
た場合と、軟化温度1260℃の充填材を用いた場合と
で、断熱性に実質的な違いのないことが分かる。
As is clear from FIG. 4, after the pouring, the temperature of the inner surface A of the nozzle hole rapidly decreases with the passage of time, but the rise in the temperature of the nozzle side portions B and C is small and the melting point is low. It can be seen that there is no substantial difference in the heat insulating properties between the case where a filler having a softening temperature of 700 ° C. is used as the substance and the case where a filler having a softening temperature of 1260 ° C. is used.

【0015】[0015]

【発明の効果】以上のように、この発明によれば、鋳造
用ノズルの側壁内部にスリットを設け、ここに700〜
1550℃で軟化、溶融する低融点物質を充填したの
で、これを高温で使用中に、組織の炭素やシリカが酸化
あるいは還元反応してガス化し、CO、CO2 、SiO
となって揮散、消失し、組織がポ−ラスとなっても、ノ
ズル内を通過する溶鋼が空気と接触したり、溶鋼の熱拡
散を防ぐことが出来る。
As described above, according to the present invention, the slit is provided inside the side wall of the casting nozzle, and 700 to
Since a low melting point material that softens and melts at 1550 ° C. is filled, carbon or silica in the tissue is oxidized or reduced to gasify during use at a high temperature, resulting in CO, CO 2 , SiO 2 .
Thus, even if the structure volatilizes and disappears, and the structure becomes porous, the molten steel passing through the nozzle can be prevented from contacting with the air and the heat diffusion of the molten steel can be prevented.

【図面の簡単な説明】[Brief description of the drawings]

【図1】この発明の鋳造用ノズルの側断面図。FIG. 1 is a side sectional view of a casting nozzle of the present invention.

【図2】従来の鋳造用ノズルの側断面図。FIG. 2 is a side sectional view of a conventional casting nozzle.

【図3】この発明の鋳造用ノズルの中間部断面サイズを
示す寸法図。
FIG. 3 is a dimensional diagram showing a cross-sectional size of an intermediate portion of the casting nozzle of the present invention.

【図4】ノズルの側温を時間との関係を示す線図。FIG. 4 is a diagram showing the relationship between the side temperature of a nozzle and time.

【符号の説明】[Explanation of symbols]

1…鋳造用ノズル本体、2…側壁、3…スリット、4…
低融点物質、5…ノズル孔、7…パウダ−と接触する部
分。
DESCRIPTION OF SYMBOLS 1 ... Casting nozzle main body, 2 ... Side wall, 3 ... Slit, 4 ...
Low melting point material, 5: Nozzle hole, 7: Part in contact with powder.

フロントページの続き (56)参考文献 特開 平5−245603(JP,A) 特開 平5−367(JP,A) 特開 平4−294847(JP,A) 特開 平3−146246(JP,A) 特開 平1−284468(JP,A) 特開 昭63−13649(JP,A) 実開 平3−68962(JP,U) 実開 平3−31052(JP,U) 実開 平5−53757(JP,U) 実開 平4−54550(JP,U) 実開 平3−116246(JP,U) 特表 昭61−502319(JP,A) (58)調査した分野(Int.Cl.7,DB名) B22D 11/10 330 B22D 11/10 320 B22D 41/50 520 B22D 41/54 C04B 37/00 Continuation of the front page (56) References JP-A-5-245603 (JP, A) JP-A-5-367 (JP, A) JP-A-4-294847 (JP, A) JP-A-3-146246 (JP) JP-A-1-284468 (JP, A) JP-A-63-13649 (JP, A) JP-A-3-68962 (JP, U) JP-A-3-31052 (JP, U) 5-53757 (JP, U) JP-A-4-54550 (JP, U) JP-A-3-116246 (JP, U) Tokuyo Sho 61-502319 (JP, A) (58) Fields surveyed (Int. Cl. 7 , DB name) B22D 11/10 330 B22D 11/10 320 B22D 41/50 520 B22D 41/54 C04B 37/00

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 溶鋼の鋳造用ノズルのノズル孔外周の側
壁内部にスリットを設け、ここに700〜1550℃で
軟化、溶融する低融点物質を充填し、ここに断熱兼通気
遮断層を形成したことを特徴とする鋳造用ノズル。
1. A slit is provided in a side wall of an outer periphery of a nozzle hole of a molten steel casting nozzle, and a low melting point material which is softened and melted at 700 to 1550 ° C. is filled therein, and a heat insulation and ventilation blocking layer is formed thereon. A nozzle for casting, characterized in that:
【請求項2】 700〜1550℃で軟化、溶融する低
融点物質がアルミナ−シリカフアイバ−、岩綿、フリッ
ト、ガラスの中のいずれか一種である請求項1記載の鋳
造用ノズル。
2. The casting nozzle according to claim 1, wherein the low-melting substance softening and melting at 700 to 1550 ° C. is any one of alumina-silica fiber, rock wool, frit and glass.
【請求項3】 鋳造用ノズルが、ロングノズル、タンデ
ィシュパイプ、浸漬ノズルのいずれかである請求項1記
載の鋳造用ノズル。
3. The casting nozzle according to claim 1, wherein the casting nozzle is one of a long nozzle, a tundish pipe, and an immersion nozzle.
JP04245013A 1992-09-14 1992-09-14 Nozzle for casting Expired - Fee Related JP3134019B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP04245013A JP3134019B2 (en) 1992-09-14 1992-09-14 Nozzle for casting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP04245013A JP3134019B2 (en) 1992-09-14 1992-09-14 Nozzle for casting

Publications (2)

Publication Number Publication Date
JPH0691355A JPH0691355A (en) 1994-04-05
JP3134019B2 true JP3134019B2 (en) 2001-02-13

Family

ID=17127280

Family Applications (1)

Application Number Title Priority Date Filing Date
JP04245013A Expired - Fee Related JP3134019B2 (en) 1992-09-14 1992-09-14 Nozzle for casting

Country Status (1)

Country Link
JP (1) JP3134019B2 (en)

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