JP3127859B2 - Resin-coated PC steel stranded wire with excellent relaxation - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin-coated PC steel stranded wire used for prestressed concrete structures such as bridges and circular structures, and a resin-coated PC steel stranded wire used for reinforcing slopes and the like. It is about. In particular, it relates to a resin-coated PC steel stranded wire having excellent relaxation.

[0002]

2. Description of the Related Art When a PC steel stranded wire is used for a diagonal cable or an external cable method of a cable-stayed bridge or an extra-dost bridge, the PC steel stranded wire is exposed to a corrosive environment because it is not buried in concrete. Further, when a PC steel strand is used for an anchor, the anchor is always in the soil under a corrosive environment even though the anchor is protected by cement mortar. Therefore, there has been proposed a PC steel stranded wire coated with a synthetic resin and subjected to anticorrosion treatment.

Various methods of coating a synthetic resin on a PC steel strand have been proposed, for example, Japanese Patent Publication No. 3-28551, Japanese Patent No.
The techniques described in Japanese Patent No. 2597795, Japanese Patent No. 2510442, Japanese Patent Application Laid-Open No. H6-142595, and Japanese Patent Application Laid-Open No. 8-226191 are known. The strands of PC steel used in such technology are usually JIS G 35
After applying the patenting process to the piano wire specified in 02 and drawing and further twisting it,
It has been subjected to bluing or hot stretching at about ° C. And any of these technologies are PC
In order to coat the steel strand with the synthetic resin, the PC strand is reheated (about 170 to 350 ° C.) before and after the coating step. This is because the temperature during bluing and hot stretching is as high as 350 to 400 ° C,
At such a temperature, the synthetic resin is degraded, and if the synthetic resin coating line is connected after the steel stranded wire production line, the line becomes very long.

[0004] In general, relaxation properties are an important quality characteristic of a PC steel stranded wire. The relaxation property is a property in which the prestress is reduced after a long time elapses when prestressing by arranging and tensioning a PC steel strand on a structure. The smaller this is, the more effective prestress is secured . Therefore, recently, low relaxation PC steel strands are often used.
In the case of a cable for diagonal material that requires corrosion protection, when used as a hanging material for a girder, since relaxation itself affects the hanging load of the girder, a low-relaxation PC steel stranded wire is used.

[0005]

However, even if a PC steel stranded wire that has been reduced in relaxation by hot stretching before being coated is used, the relaxation increases when the PC steel stranded wire is reheated at the time of forming the resin coating. I understood.

JIS G 3536
Heat treatment at various temperatures is performed on a PC steel strand that meets the low relaxation standard (2.5% or less for 1000 hours, about 0.3 to 0.7% for 10 hours) at different temperatures. FIG. 1 shows the results of an investigation of the change in. In addition, it is made of a PC steel that meets the JIS G 3536 standard relaxation standard (8.0% or less for 1000 hours, and about 1.0 to 1.5% for 10 hours) by performing bluing without hot stretching. The same heat treatment was applied to the line, and the change in relaxation at room temperature after the heat treatment is also shown in FIG.

[0007] In the case of the hot-stretched one, the relaxation of the PC steel strand before heating is 0.1 hr at 10 hours.
While it was 6%, it was found that the relaxation increased as the heating temperature increased. That is, 15
Relaxation began to increase from around 0 ° C, 200
It becomes 1.5 to 2.0% by heating at about 250 ° C. This value is equal to or larger than that of a normal relaxation PC steel strand without coating. When the temperature is further increased, the relaxation value is usually much larger than the relaxation standard, but it is found that the relaxation value is saturated at about 300 to 400 ° C.

[0008] Further, in the case of the bluing processing,
Similarly, relaxation increases from around 150 ° C,
It can be seen that heating at around 250 ° C. further increases.
Of course, in this case, the relaxation before heating is the standard for normal relaxation, so that heating will make it even larger than the standard for relaxation.

Accordingly, the main object of the present invention is to provide a coated PC having a low relaxation value even after forming a resin coating.
An object of the present invention is to provide a steel strand and a method for manufacturing the same.

[0010]

SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems, and is characterized by a resin-coated PC steel stranded wire having a resin coating on a steel stranded wire having the following chemical component (A). Therefore, it is to meet the low relaxation standard specified in JIS G 3536. (A) C: 0.75 to 1.20% by weight%, Mn: 0.
Steel stranded wire containing 30 to 0.90% and satisfying the following conditions: When 0 ≦ Si <0.8%, 1.0 + 0.28Si−
5.84Si ² + 4.91Si ³ ≦ Cr ≦ 2.0%
When 8 ≦ Si ≦ 2.0%, 0 ≦ Cr <≦ 2.0%

[0011] Here, the relaxation standard defined in JIS G 3536 means that low relaxation is 2.5% or less in 1000 hours, and normal relaxation is 8.0% or less in 1000 hours. However, since the measurement for 1000 hours is a long time, the measurement result of 10 hours is often used as a guide. In that case, 0.3 ~
About 0.7%, 1.0 to 1.5 for normal relaxation
% Is shown.

In the measurement of the relaxation described above, the test pieces are gripped at appropriate intervals at room temperature, and the loading speed is set at 20 minutes per minute.
A load equivalent to 70% of the standard tensile load is applied at 0 N / mm ² , the load is maintained for 120 ± 2 seconds, and the reduction of the load is measured for 1000 hours while maintaining the gripping interval.

[0013] The resin coating applied to the PC steel strand is preferably applied to the entire circumference of each strand, covering the entire outer circumference of the steel strand and filling the gaps between the strands with resin.

Further, the method for producing a resin-coated PC steel stranded wire according to the present invention comprises the steps of subjecting a steel stranded wire having the following chemical composition (A) to a bluing treatment or a hot stretching treatment; Applying a resin coating by heating to 350 ° C. (A) C: 0.75 to 1.20% by weight%, Mn: 0.
Steel stranded wire containing 30 to 0.90% and satisfying the following conditions: When 0 ≦ Si <0.8%, 1.0 + 0.28Si−
5.84Si ² + 4.91Si ³ ≦ Cr ≦ 2.0%
When 8 ≦ Si ≦ 2.0%, 0 ≦ Cr <≦ 2.0%

In this manufacturing method, it is desirable to perform a bluing treatment or a hot stretching treatment before heating the steel strand and coating it with a resin. Examples of the resin to be coated include an epoxy resin and a polyethylene resin.

The reasons for limiting the chemical composition of the steel strand in the present invention are as follows. C is an effective and economical element for increasing the strength. As the content of C increases, the strength and the amount of wire hardening after patenting increase. However, in order to satisfy the tensile strength of PC steel wires and PC stranded wires specified in JIS G 3536, 0.75 % As the lower limit. On the other hand, when the content of C is increased, proeutectoid cementite is likely to be generated in the central portion, resulting in inferior wire drawability. Therefore, the upper limit is set to 1.20%.

Each of Si and Cr has an effect of suppressing an increase in relaxation at a reheating temperature when coating the surface of a steel wire or a steel stranded wire with a synthetic resin. On the other hand, when the content of Si is increased, the surface of the steel wire is easily damaged during rolling and drawing. In addition, when the content of Cr increases, martensite is easily generated at the center of the steel wire during patenting, but it is necessary to suppress the generation of martensite to such an extent that the drawability is not deteriorated. Considering these points, S
The contents of i and Cr were specified.

When only Si is contained and Cr is not contained, the lower limit of Si is 0.8% and the upper limit is 2.0% from the viewpoint of harmony between the above effects and disadvantages. When only Cr is contained and Si is not contained, for the same reason,
Is 1.0% and the upper limit is 2.0%. And S
When both i and Cr are included, the total upper limit of both is set to 4.0% for the same reason. Note that Si and C
As an example of the content of Si and Cr when both of r are contained, Si: 0.15 to 0.35%, Cr: 1.
0% to 2.0%.

The suitable range of Mn is 0.3% to 0.9%, which is the content specified in JIS G 3536.

[0020]

Embodiments of the present invention will be described below. (Test Example 1) The materials of the chemical components shown in Table 1 were subjected to a patenting treatment, followed by pickling, drawing, and obtaining a strand. The strand was twisted while applying tension at a temperature of 370 ° C. Blueing processing (so-called hot stretch processing)
To obtain a strand of PC steel. The relaxation value after the hot stretch treatment (before coating) satisfies the low relaxation standard.

[0021]

[Table 1]

This PC steel strand was subjected to the following coating processes (1) to (3) to produce coating materials 1 to 3.

(1) Coating material 1 The entire surface of the PC steel strand is degreased and roughened by blasting or pickling, washed with water, and heated at 200 ° C. for 10 seconds by high frequency induction heating. After that, once untwisted, epoxy resin was coated with electrostatic powder coating,
Before the resin solidifies, return
The resin is hardened through a heat-retaining oven at a temperature of ° C.

(2) Coating material 2 The entire surface of the PC steel strand is degreased and roughened by blasting or pickling, washed with water, and heated at 300 ° C. for 10 seconds by high frequency induction heating. Thereafter, a coating is formed by inserting a PC steel stranded wire into a tank in which molten polyethylene is stored under pressure.

(3) Coating Material 3 The same treatment as that of the coating material 1 is performed except that the heating temperature by the high frequency induction heating is set to 250 ° C.

By the above-described processes (1) to (3), the outer periphery of the PC steel strand is covered with the synthetic resin, and at the same time, the coated PC strand having the resin filled in the gaps between the strands is obtained. Was. Note that no resin is interposed at the contact points between the strands. A relaxation test (10 hours) was performed on these PC steel strands. Table 2 shows the results. In addition,
For a part of the coating material 1, a relaxation value of 1000Hr is also shown.

[0027]

[Table 2]

<Evaluation of Coating Material 1> The relaxation value (10 Hr) of the test material HST (before coating) after the hot stretching treatment was 0.56% and 0.45% (measured two data). However, as shown in Table 2, the test material HST
Is 1.3%, which is about the same as the standard value for normal relaxation.

On the other hand, a test material with an increased content of Si and Cr
It can be seen that HS-1 to HSC-5 have improved relaxation. In the test materials HS-1 to 5 and HCR-1 to 5, Si,
Cr content of about 0.6% (HS-1, HCR-1)
Has not been improved to the standard value for low relaxation, but at 0.9%, it is at the same level as the standard value for low relaxation. In addition, HSC-1 to 5 in which the total content of Si + Cr was changed, this total content was about 0.65% (HS
In C-1), it is not possible to improve to the standard value of low relaxation, but above 0.9% (HSC-2), it is the same level as the standard value of low relaxation. In addition, 1000
It can be seen that the relaxation value of Hr also satisfies the standard of low relaxation like the relaxation value of 10 Hr.

<Evaluation of Coating Material 2> In the test material HST, the relaxation value was 2.6%, which was larger than the standard value of ordinary relaxation.

On the other hand, in the test materials HS-1 to 5 and HCR-1 to 5 in which the contents of Si and Cr were changed, the contents of Si and Cr were 0.6% and 0.9%, respectively. (HS-1,2, HCR-
1,2) have not been improved to the standard value for low relaxation, but at about 1.2%, they are at the same level as the standard value for low relaxation. Also, HSC-1 to 5 in which the total content of Si + Cr was changed, this total content was 0.65.
% And 0.91% (HSC-1,2) cannot be improved to the standard value of low relaxation, but above 1.25%, it is at the same level as the standard value of low relaxation.

<Evaluation of Coating Material 3> The relaxation of the test material HST in the coating material 3 was 1.9%, which was not as large as that of the coating material 2 but exceeded the standard for relaxation. .

On the other hand, in the test materials HS-1 to 5 and HCR-1 to 5 in which the contents of Si and Cr were changed, the content of HS-1 and Cr was about 0.6% and 0.9%, respectively. HCR-1 and HCR-2 have not been improved to the level of low relaxation,
Is 0.9% and Cr is 1.18%, which is at the same level as the standard value of low relaxation. Also, Si + C
HSC-1 to 5 with different total content of r cannot be improved to low relaxation standard value when the total content is 0.65% (HSC-1), but low relaxation standard when 0.91% or more. It is at the same level as the value.

(Test Example 2) Further, the test materials HS-1 to HS
With respect to C-5, it was examined how relaxation changes depending on the contents of Si and Cr and the type of coating material (difference in reheating temperature). The results are shown in FIGS. As shown in FIG. 2 to FIG. 4, it can be seen that the relaxation becomes smaller with an increase in Si or Cr and an increase in Si + Cr.

Further, the coating materials 1 to 3 are different in the heating temperature of the PC steel strand when the synthetic resin is coated, and how the relaxation changes depending on the heating temperature during coating and the Si content is also examined. The result is shown in FIG. FIG.
As shown in Fig. 2, when the heating temperature is about 200 ° C, Si is contained at about 0.8% or more, when the heating temperature is about 250 ° C, Si is contained at 1.0% or more. 2%
It can be seen that if it is contained more than about, it satisfies the standard of low relaxation. Normally, when resin coating is applied to a PC steel strand, since heating is performed to 150 ° C. or more, if the content of Si is adjusted as described above according to the heating temperature during coating,
Can meet low relaxation standards. These effects can be said to be substantially the same when Cr or Si + Cr is contained. However, the effect of the addition of Si is slightly greater than the effect of reducing the relaxation by the addition of Cr.

The above results were arranged and the relationship between the contents of Si and Cr satisfying the standard value of low relaxation was examined. FIG. 6 shows the result. The curve in the figure is: Cr = 1.0 + 0.28Si−5.84Si ² +4.9
Represented by 1si ^3.

Therefore, when 0 ≦ Si <0.8%, 1.
^{0 + 0.28Si-5.84Si 2 + 4.91Si} 3 ≦
When Cr ≦ 2.0% and 0.8 ≦ Si ≦ 2.0%, by satisfying 0 ≦ Cr <≦ 2.0%, a low relaxation resin-coated PC steel strand can be obtained.

(Test Example 3) Next, when the relaxation value before coating with a synthetic resin is increased in the amount of Si and Cr in a PC steel strand, which is a standard for relaxation, what is the relaxation after coating? I checked.

After subjecting the materials having the same chemical components as the test materials HST, HS-3 and HCR-3 shown in Table 1 to a patenting treatment, the materials were pickled, drawn, and obtained to obtain a strand. 37
At the temperature of 0 ° C., a bluing treatment was performed to obtain a strand of PC steel.

The surface of the PC steel strand is degreased and roughened by blasting, pickling, or the like, washed with water, and heated at 300 ° C. for 10 seconds by high-frequency induction heating. Then, after unwinding, the epoxy resin is coated with the electrostatic powder coating, and the resin is returned before the resin is solidified, and the resin is further cured through a 150 ° C. heat insulating furnace,
A wire was obtained from a resin-coated PC steel (coating material 4). Table 3 shows the relaxation (10 hours) of the obtained resin-coated PC steel strand.

[0041]

[Table 3]

The relaxation value of HST before coating was 1.2%, 1.3% (each measured 10 hours / two data) and 4.5% (1000 hours).
It can be seen that the PC steel stranded wire after coating, in which the amount of Si and Cr is increased, satisfies the standard of low relaxation.

When combined with the results of Test Example 1 described above, even if the relaxation value before coating satisfies the standard of low relaxation by applying hot stretch treatment, the relaxation value can be satisfied only by the bluing treatment. It can be seen that even after coating, it meets the low relaxation standard after coating.

[0044]

As described above, by increasing the amounts of Si and Cr added, even if a heat treatment is performed when coating the PC steel stranded wire, the coated PC steel stranded wire is a standard of low relaxation. Can be satisfied.

[Brief description of the drawings]

FIG. 1 is a graph showing a relationship between a heating temperature at the time of coating and relaxation.

FIG. 2 is a graph showing the relationship between Si content and relaxation.

FIG. 3 is a graph showing the relationship between Cr content and relaxation.

FIG. 4 is a graph showing the relationship between the content of Si + Cr and relaxation.

FIG. 5 is a graph showing a relationship between a heating temperature at the time of coating and relaxation.

FIG. 6: Si and Cr satisfying the standard of low relaxation
The graph which shows the relationship of content of.

──────────────────────────────────────────────────続 き Continuation of the front page (72) Inventor Shinichi Yoshida 1-1-1, Koyokita, Itami-shi, Hyogo Sumitomo Electric Industries, Ltd. Itami Works (56) References JP-A-48-16 (JP, A) JP-A-7-292441 (JP, A) JP-A-7-292442 (JP, A) JP-A-8-296022 (JP, A) JP-A-10-226973 (JP, A) Patent 2986645 (JP, A) B2) Patent 2510442 (JP, B2) Patent 2552604 (JP, B2) Patent 2597795 (JP, B2) Patent 29,537,457 (JP, B2) Patent 2676594 (JP, B2) Patent 2725168 (JP, B2) (58) (Int.Cl. ⁷ , DB name) E04C 5/08 B05D 7/20 B21F 21/00 C22C 38/00 301 C22C 38/22

Claims (4)

(57) [Claims] 1. A coated PC steel strand having a resin coating on the steel strand of the following (A), which satisfies a low relaxation standard specified in JIS G 3536, and has excellent relaxation. PC steel strand. (A) C: 0.75 to 1.20% by weight%, Mn: 0.
Steel stranded wire containing 30 to 0.90% and satisfying the following conditions: When 0 ≦ Si <0.8%, 1.0 + 0.28Si−5.84Si ² + 4.91Si
³ ≦ Cr ≦ 2.0%, 0.8 ≦ Si ≦ 2.0%, 0 ≦ Cr <≦ 2.0% 2. The resin-coated PC stranded wire excellent in relaxation according to claim 1, wherein the resin-coated wire is provided on the entire circumference of each strand of the steel stranded wire. 3. The resin-coated PC steel strand excellent in relaxation according to claim 1, wherein the resin coating is filled between the strands of the steel strand. 4. A method comprising the steps of: (A) applying a bluing treatment or a hot stretching treatment to a steel strand; and heating the obtained steel strand to 150 to 350 ° C. to apply a resin coating. A method for producing a resin-coated PC steel strand excellent in relaxation. (A) C: 0.75 to 1.20% by weight%, Mn: 0.
Steel stranded wire containing 30 to 0.90% and satisfying the following conditions: When 0 ≦ Si <0.8%, 1.0 + 0.28Si−5.84Si ² + 4.91Si
³ ≦ Cr ≦ 2.0%, 0.8 ≦ Si ≦ 2.0%, 0 ≦ Cr <≦ 2.0%