JP3126163U - Negative potential hydrogen generation electrode - Google Patents

Negative potential hydrogen generation electrode Download PDF

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JP3126163U
JP3126163U JP2006004900U JP2006004900U JP3126163U JP 3126163 U JP3126163 U JP 3126163U JP 2006004900 U JP2006004900 U JP 2006004900U JP 2006004900 U JP2006004900 U JP 2006004900U JP 3126163 U JP3126163 U JP 3126163U
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water
negative potential
hydrogen
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gas
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守孝 有田
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有限会社ライフガードプロダクト
株式会社中進電機
有田 百合子
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Abstract

【課題】環境、人体に優しい様々な気ガス溶解機能水の製造において、井戸水や水道水に気ガスを短時間で安全に高効率に溶解することが可能な気液混合装置の提供する。
【解決手段】マイナス電位水素水は、0.5mm〜6.0mmの間隙を設けて複数枚重ねた1.0mm〜5.0mmの厚さのステンレス合金板に交互に陽極陰極の直流電圧を印加する並列連続電極を特徴とするマイナス電位水素発生電極。
【選択図】図1
An object of the present invention is to provide a gas-liquid mixing apparatus capable of dissolving gas gas in well water and tap water safely and efficiently in a short time in the production of various gas gas-dissolving functional water that is friendly to the environment and the human body.
As for negative potential hydrogen water, a DC voltage of an anode / cathode is alternately applied to a stainless steel plate having a thickness of 1.0 mm to 5.0 mm which is stacked with a gap of 0.5 mm to 6.0 mm. A negative potential hydrogen generating electrode characterized by parallel continuous electrodes.
[Selection] Figure 1

Description

本考案は、水から水素ガスを発生し溶解する電解装置に関するものである。The present invention relates to an electrolysis apparatus that generates and dissolves hydrogen gas from water.

21世紀に入り地球環境にやさしい水素エネルギー技術が盛んに研究されている。同時に環境に優しく、人体に優しい機能水も様々研究されている。工業界では洗浄効果が高い、油脂成分と結合して浮上分離する高酸素水や金属成分除去効果の強い水として水素水が注目されている。活性酸素と中和して健康を保つとされる水素水は大変広がりつつある。水にも酸化還元電位(以下「ORP」という)という電気があり、ORP値の高い水は他の物質を酸化し易いプラスイオン状態の水で、ORP値の低い水は他の物質を還元し易いマイナスイオン状態とされる。電解装置ではプラチナ等の元素金属を用いたものがある。In the 21st century, hydrogen energy technology friendly to the global environment has been actively researched. At the same time, various functional waters that are environmentally friendly and gentle to the human body have been studied. Hydrogen water is attracting attention in the industry as high oxygen water that floats and separates when combined with oil and fat components, and water that has a strong metal component removal effect. Hydrogen water, which is said to be healthy by neutralizing with active oxygen, is spreading very much. Water also has electricity called redox potential (hereinafter referred to as “ORP”). Water with a high ORP value is water in a positive ion state that easily oxidizes other substances, and water with a low ORP value reduces other substances. Easy negative ion state. Some electrolyzers use elemental metals such as platinum.

酸素溶解水は高い電位を持ち、水素溶解水は低い電位を持つ水である。上水道水のORPは+400〜+800mVの酸化水であり、健康体の体液は−200〜+200mVである。従来の水素水製法には純水を電気分解し水素ガスを生成して水中に溶解する水素ガス発生器を用いる仕組みと酸性水と塩基水を生成する隔膜を用いた電気分解槽がある。水素ガス発生器ではガス生成原水を1μS以下にする必要があるので、水道水から活性炭ろ過や膜ろ過した純水をイオン交換して超純水に精製する付帯設備を要するので大変コストがかかる問題がある。隔膜を用いた電気分解槽では、ペーハー的な酸性水とアルカリ水が生成されるので水量的には半減する。また中性にするために中和剤を要する。プラチナを用いた電解装置では、プラチナは変性なく高性能を示すが高価である問題がある。Oxygen-dissolved water has a high potential, and hydrogen-dissolved water is water having a low potential. The ORP of tap water is +400 to +800 mV of oxidized water, and the body fluid of healthy body is -200 to +200 mV. Conventional hydrogen water production methods include a mechanism that uses a hydrogen gas generator that electrolyzes pure water to generate hydrogen gas and dissolves it in water, and an electrolysis tank that uses a diaphragm that generates acidic water and basic water. The hydrogen gas generator requires gas production raw water to be 1 μS or less, so it costs a lot of money because it requires ancillary equipment to purify the purified water from tap water by activated carbon filtration or membrane filtration into ultrapure water. There is. In an electrolysis tank using a diaphragm, pH-like acidic water and alkaline water are generated, so the amount of water is reduced by half. Moreover, in order to make it neutral, a neutralizing agent is required. In an electrolysis apparatus using platinum, platinum exhibits high performance without modification but has a problem of being expensive.

上記問題を回避し高いマイナス電位と水素発生を達成するためになされた請求項1の考案に係るマイナス電位水素発生電極は、ステンレス合金板を0.6mm〜6.0mmの間隙を設けて複数枚重ね、一枚置きにプラスとマイナスの12V〜24Vの直流電圧を印加する並列連続電極を特徴とするマイナス電位水素発生電極The negative potential hydrogen generating electrode according to the first aspect of the present invention, which has been made in order to avoid the above problem and achieve high negative potential and hydrogen generation, is a plurality of stainless alloy plates with a gap of 0.6 mm to 6.0 mm. A negative potential hydrogen generation electrode characterized by a parallel continuous electrode that applies a DC voltage of 12V to 24V plus and minus every other one piece

本考案はクロム、ニッケル、鉄の合金であるSUS304またはSUS316やSUS317を用いる。クロム、ニッケル、鉄がそれぞれ電子授受に働き、接触通過する水道水を瞬時に低電力で大量の水素と酸素に分解する。検証実験ではSUS電極間を通過し接触した水は1分間当たり10cm程の浮力の大変微細な水素気泡と酸素気泡を生成する。厚み2.0mm幅40mm長さ400mmのSUS304電極7枚を用いた電極間隙を2.8mmにセットした6隙間の電解装置に直流12Vを加え10リットル毎分の水道水を通した場合では、二次直流電流は9.8A、一次交流電流は0.7Aで水素濃度DHは0.5mg/L、酸化還元電位ORPはマイナス405mVを示す。電極間隙を4.8mmにすると二次直流電流は5.2A、一次交流電流は0.45Aで水素濃度DHは0.38mg/L、酸化還元電位ORPはマイナス335mVを示す。停水時には運転電流は1割程上昇する。
厚み2.0mm幅100mm長さ100mmSUS304電極9枚の電極で間隙を2.8mmにセットした8隙間のマイナス電位水素発生電極を、pH7.2の水道水15リットルを汲んだバケツに設置し直流12Vを加えると、即時微細な気泡を生じ始め、一分経過時ORPはマイナス250mV、pHは7.2。二分経過時ORPはマイナス300mV、pHは7.2で気泡により水全体が乳白色に見える。三分経過時ORPはマイナス350mV、pHは7.2。四分経過時ORPはマイナス400mV、pHは7.2のままである。このマイナス電位水素水をスポンジにとり油性マジック落書きを消すことが出来る。
酸性雨により車にこびりつく水垢も、水垢取りを用いずに簡単に取ることが出来る。
風呂も同様に実験、給湯ORP電位プラス500mVが給湯完了時にはプラス200mV、その後1時間ほど経過するとマイナス100mV近辺になる。
運転時状態で入浴すると湯泉は微細気泡が溶融し乳白色に映る。ORPは人体から酸化電位がマイナス電位の湯に引っ張られプラス50mV程度を指す。マイナス電位湯泉に浸かると体内まで温まり湯冷めが無く、肌はしっとりとし翌日もツルツルの肌状態を保つ。髪はサラサラとなる。バスタブも清浄され洗浄手間が大幅に軽減できる。追い炊き時にはボイラー配管内の清浄化に働くと共に酸化腐食を予防する。残水洗濯では洗剤は不要であった。
また通常は300mV程度の空気が、浴室内空気はマイナスイオン化しORPはプラス100mV。厚み2.0mm幅40mm長さ400mmのSUS304電極7枚を用いた電極間隙を2.8mmにセットした6隙間の電解装置に直流12Vを加え10リットル毎分で50トンのピット水を60日間循環運転で通した電極を分解確認したが、SUS電極表面は電食変化ない触媒作用で水のみを改質、ピット水循環ろ過器を逆洗すると普段よりも大量の汚れた逆洗水排水となった。また深さ4mのピット底(水圧約0.04Mpa)に設けると電流は2割ほど上昇。微細な気泡が不純物を抱き込み上昇してくることが判った。シャーレに上水道、水素添加マイナス電位水素水、軟水、電解マイナス電位水素水を取りクリップピンを投入したサビ実験では、水道水が3日目でサビが生じ14日目で全体が錆びた。軟水では7日目にサビが生じ30日後もその状態で推移した。水素添加及び電解マイナス電位水素水では30日経過後においてもサビは発生無くピカピカ状態を保った。
電解マイナス電位水素水に数匹の魚を入れて一ヶ月間生体実験では全匹共なんら問題なく生息した。
本考案のマイナス電位水素発生電極では純水装置や超純水装置等の多くの付帯設備を用いずにピット水や水道水をそのまま省電力、ローコスト、インライン省スペースのワンパスで大量にpH中性のままで速やかに電解でき、大量のマイナス電位水素水を生成することができるので、電気さえあれば車のバッテリーからどこでも簡単にマイナス電位水素水を作ることができる。風呂のような滞留水を長時間電解した場合に水中溶存マグネシウムが酸化マグネシウムに、溶存カルシウムが酸化カルシウムとなり、水が若干黄ばむので、請求項2のようにSUS電極に対しチタン電極を組み合わせることで黄ばみ到達時間を大幅に遅延できる。また清掃においてはSUS電極に対し銅電極を組み合わせ、銅電極にプラス電気を印加することで銅イオンの発生により細菌を滅菌することが出来る。マイナス電位水素水は物質の酸化低減と共にマイナスイオン効果で消臭作用もある。健康に影響を及ぼすとされる溶存活性酸素も抑制される。実験ではシリカや炭化カルシウムの除去、配管内部の清浄化、機械加工材の清浄に効果が見られる。無味無毒の溶存水素濃度が高いため気中酸素の溶解遅延に働き酸化しにくい中性の安全な水に生成され、プール・大衆浴場・医療機器や精密機器の洗浄、食品加工・製造、清涼飲料水、農業や工業用水の水質改善に用いることができる。取れにくい油汚れが洗剤を用いない状況下でかなり落ちる。水中生息する陰性グラム細菌の繁殖抑制と生存低減があり、エンドトキシン(毒素)低減の有用性がある(鈴鹿医療科学大学で検証)。洗浄消臭力が高いので環境破壊の一つである界面活性剤の使用量を低減でき、リネン業界や工業界で用いる事ができる。
The present invention uses SUS304, SUS316, or SUS317, which is an alloy of chromium, nickel, and iron. Chromium, nickel, and iron are each used for electronic transfer, and the tap water passing through the contact is instantly decomposed into a large amount of hydrogen and oxygen with low power. In the verification experiment, the water that passes through and contacts between the SUS electrodes generates very fine hydrogen bubbles and oxygen bubbles with a buoyancy of about 10 cm per minute. In the case where 12 VDC is applied to a 6-gap electrolyzer using 7 SUS304 electrodes having a thickness of 2.0 mm, a width of 40 mm, and a length of 400 mm and a gap of 2.8 mm, and tap water of 10 liters per minute is passed through, The secondary DC current is 9.8 A, the primary AC current is 0.7 A, the hydrogen concentration DH is 0.5 mg / L, and the oxidation-reduction potential ORP is minus 405 mV. When the electrode gap is 4.8 mm, the secondary DC current is 5.2 A, the primary AC current is 0.45 A, the hydrogen concentration DH is 0.38 mg / L, and the oxidation-reduction potential ORP is minus 335 mV. When the water stops, the operating current increases by about 10%.
Thickness 2.0mm Width 100mm Length 100mm SUS304 Electrodes Nine potential electrodes with 8 gaps set to a gap of 2.8mm are installed in a bucket pumped with 15 liters of tap water of pH 7.2 and 12V DC To start producing fine bubbles immediately, and after 1 minute, ORP is minus 250 mV and pH is 7.2. When two minutes elapse, the ORP is minus 300 mV, the pH is 7.2, and the whole water looks milky white due to bubbles. At 3 minutes, ORP is minus 350 mV and pH is 7.2. At the end of four minutes, the ORP remains minus 400 mV and the pH remains 7.2. This negative potential hydrogen water can be put on a sponge to erase the oil-based magic graffiti.
Dust sticking to the car due to acid rain can be easily removed without using descaling.
Similarly, in the case of the experiment, the hot water supply ORP potential plus 500 mV is plus 200 mV when the hot water supply is completed, and after about 1 hour, it becomes around minus 100 mV.
When bathing in the state of operation, the hot springs appear as milky white as the fine bubbles melt. ORP refers to about +50 mV when the oxidation potential is pulled from the human body to hot water with a negative potential. When immersed in a negative potential hot spring, the body warms up and does not cool off, leaving the skin moist and smooth the next day. The hair becomes smooth. The bathtub is also cleaned and the washing time can be greatly reduced. At the time of cooking, it works to clean the boiler piping and prevent oxidative corrosion. No detergent was required for washing with residual water.
In addition, air of about 300 mV is usually negatively ionized in the bathroom, and ORP is plus 100 mV. DC 12V was applied to a 6-gap electrolytic device using 7 SUS304 electrodes with a thickness of 2.0 mm, a width of 40 mm and a length of 400 mm, and the electrode gap was set to 2.8 mm. The electrode passed through the operation was confirmed to be disassembled, but the surface of the SUS electrode was reformed only by the catalytic action that did not change galvanic corrosion, and when the pit water circulation filter was backwashed, it became a larger amount of dirty backwash water drainage than usual. . If it is installed at the bottom of a pit with a depth of 4m (water pressure of about 0.04Mpa), the current will increase by about 20%. It has been found that fine bubbles are embraced by impurities and rise. In a rust experiment in which a petri dish was filled with tap water, hydrogenated minus potential hydrogen water, soft water, electrolytic minus potential hydrogen water and a clip pin was inserted, rust occurred on the third day and the whole rusted on the 14th day. In soft water, rust appeared on the 7th day, and remained in that state after 30 days. With hydrogenation and electrolysis minus potential hydrogen water, rust was not generated even after 30 days, and the shiny state was maintained.
Several animals were placed in electrolytic negative potential hydrogen water and lived for one month without any problems.
The negative potential hydrogen generation electrode of the present invention is neutral in pH in large quantities with one pass of power saving, low cost, in-line space saving pit water and tap water without using many auxiliary equipment such as pure water equipment and ultra pure water equipment Since it can be electrolyzed quickly and a large amount of negative potential hydrogen water can be generated, it is possible to easily make negative potential hydrogen water from a car battery anywhere with electricity. When electrolyzing stagnant water such as a bath for a long time, dissolved magnesium in water becomes magnesium oxide, dissolved calcium becomes calcium oxide, and the water turns slightly yellow. By combining the titanium electrode with the SUS electrode as in claim 2, The yellowish arrival time can be greatly delayed. In cleaning, a SUS electrode is combined with a copper electrode, and positive electricity is applied to the copper electrode to sterilize bacteria by generating copper ions. Negative potential hydrogen water has a deodorizing effect due to the negative ion effect as well as the reduction of oxidation of the substance. Dissolved active oxygen, which is thought to affect health, is also suppressed. In the experiment, it is effective in removing silica and calcium carbide, cleaning the inside of piping, and cleaning machined materials. Because it has a high concentration of tasteless and non-toxic dissolved hydrogen, it is generated in neutral safe water that delays the dissolution of atmospheric oxygen and is difficult to oxidize, cleaning pools, public baths, medical equipment and precision equipment, food processing and manufacturing, soft drinks It can be used to improve the quality of water, agricultural and industrial water. Oil stains that are difficult to remove drop considerably in the absence of detergent. It has the ability to suppress the growth and survival of negative gram bacteria that live in water, and is useful for reducing endotoxin (toxin) (verified by Suzuka University of Medical Science). Because it has high cleaning and deodorizing power, it can reduce the amount of surfactant used, which is one of the environmental destruction, and can be used in the linen and industrial industries.

本考案の実施の形態を図1の組立側面展開図を以って説明する。
ステンレス板電極1の結線部2を一枚毎に交互とし、各電極の間隙に絶縁スペーサー5を挟み電極組付け孔6に組付けボルト7を通して複数枚を組み付ける。一枚毎左右になった結線部2の穴に結線ボルト3を、それぞれ通して導通し口出し線8と結んで、結線水切り部4で水切り加工を行う(図3に記載)。チタン又は銅電極9をステンレス板電極1の一部に対に組付ける(図2)。
図2の水素溶解還元水製造装置のフロー図を以って説明する。
口出し線8を直流電源10に結び、入水路11より水を通し出水路12からマイナス電位水素水を得る
An embodiment of the present invention will be described with reference to an exploded side view of FIG.
The connecting portions 2 of the stainless steel plate electrodes 1 are alternately arranged one by one, and an insulating spacer 5 is sandwiched between the electrodes, and a plurality of pieces are assembled into the electrode assembly holes 6 through assembly bolts 7. The connection bolts 3 are respectively passed through the holes of the connection portions 2 which are left and right for each sheet and connected to the lead wire 8, and the connection draining portion 4 performs draining processing (described in FIG. 3). A titanium or copper electrode 9 is assembled to a part of the stainless steel plate electrode 1 in pairs (FIG. 2).
It demonstrates with the flowchart of the hydrogen-dissolved reduced water manufacturing apparatus of FIG.
The lead wire 8 is connected to the DC power source 10, water is passed from the water inlet 11, and negative potential hydrogen water is obtained from the water outlet 12.

本考案のマイナス電位水素発生電極の組立側面展開図Assembly side development of the negative potential hydrogen generation electrode of the present invention 請求項2の側面図Side view of claim 2 マイナス電位水素水製造装置のフロー図Flow diagram of negative potential hydrogen water production system

符号の説明Explanation of symbols

1 ステンレス板電極
2 結線部
3 結線ボルト
4 結線水切り部
5 絶縁スペーサー
6 電極組付け孔
7 組付けボルト
8 口出し線
9 チタン又は銅電極
10 直流電源
11 入水路
12 出水路
DESCRIPTION OF SYMBOLS 1 Stainless steel plate electrode 2 Connection part 3 Connection bolt 4 Connection draining part 5 Insulation spacer 6 Electrode assembly hole 7 Assembly bolt 8 Lead wire 9 Titanium or copper electrode 10 DC power supply 11 Inlet channel 12 Outlet channel

Claims (2)

0.5mm〜6.0mmの間隙を設けて複数枚重ねた1.0mm〜5.0mmの厚さのステンレス合金板に交互に陽極陰極の直流電圧を印加する並列連続電極を特徴とするマイナス電位水素発生電極Negative potential characterized by parallel continuous electrodes for applying a DC voltage of an anode / cathode alternately to a stainless steel plate having a thickness of 1.0 mm to 5.0 mm stacked with a gap of 0.5 mm to 6.0 mm. Hydrogen generation electrode 一部のステンレス合金板に対にチタン板又は銅板の電極を設けて陽極の直流電圧を印加する並列連続電極を特徴とする請求項1記載のマイナス電位水素発生電極2. A negative potential hydrogen generating electrode according to claim 1, wherein a parallel continuous electrode for applying a DC voltage of the anode by providing a titanium plate or a copper plate as a pair on a part of the stainless alloy plate is provided.
JP2006004900U 2006-05-25 2006-05-25 Negative potential hydrogen generation electrode Expired - Fee Related JP3126163U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008110342A (en) * 2006-10-26 2008-05-15 E & E Corp Method and apparatus for producing reduced hydrogen water, and method and apparatus for producing reduced hydrogen beverage, utilizing brown's gas
JP2021518254A (en) * 2018-03-21 2021-08-02 アクシン ウォーター テクノロジーズ インコーポレイテッドAxine Water Technologies Inc. Electrolytic cell with bipolar electrode for wastewater treatment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008110342A (en) * 2006-10-26 2008-05-15 E & E Corp Method and apparatus for producing reduced hydrogen water, and method and apparatus for producing reduced hydrogen beverage, utilizing brown's gas
JP2021518254A (en) * 2018-03-21 2021-08-02 アクシン ウォーター テクノロジーズ インコーポレイテッドAxine Water Technologies Inc. Electrolytic cell with bipolar electrode for wastewater treatment
JP7269253B2 (en) 2018-03-21 2023-05-08 アクシン ウォーター テクノロジーズ インコーポレイテッド Electrolytic cell with bipolar electrodes for wastewater treatment

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