JP3109999B2 - Method of fixing compressed state of wood material molded article and method of removing residual stress of wood material - Google Patents

Method of fixing compressed state of wood material molded article and method of removing residual stress of wood material

Info

Publication number
JP3109999B2
JP3109999B2 JP09060365A JP6036597A JP3109999B2 JP 3109999 B2 JP3109999 B2 JP 3109999B2 JP 09060365 A JP09060365 A JP 09060365A JP 6036597 A JP6036597 A JP 6036597A JP 3109999 B2 JP3109999 B2 JP 3109999B2
Authority
JP
Japan
Prior art keywords
container
particles
compressed state
molded article
log
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP09060365A
Other languages
Japanese (ja)
Other versions
JPH10249812A (en
Inventor
民雄 荒川
明彦 伊藤
正子 櫻井
Original Assignee
マイウッド株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by マイウッド株式会社 filed Critical マイウッド株式会社
Priority to JP09060365A priority Critical patent/JP3109999B2/en
Priority to DK199701018A priority patent/DK175650B1/en
Priority to NZ328700A priority patent/NZ328700A/en
Priority to AU37504/97A priority patent/AU732280B2/en
Priority to US08/929,651 priority patent/US6267920B1/en
Priority to CA002215876A priority patent/CA2215876A1/en
Priority to DE19743703A priority patent/DE19743703A1/en
Priority to SE9703598A priority patent/SE519408C2/en
Publication of JPH10249812A publication Critical patent/JPH10249812A/en
Application granted granted Critical
Publication of JP3109999B2 publication Critical patent/JP3109999B2/en
Priority to DK200300380A priority patent/DK200300380A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/15Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/001Heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/06Softening or hardening of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27MWORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M1/00Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
    • B27M1/02Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by compressing

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、木材の改質処理方
法に関するものであり、圧縮により一時的に成形された
木質材料の形状及び体積が湿度や温度の変化に耐えて長
期間保持されるように、圧縮状態を固定化するための方
法に関する。他の本発明は、上記の圧縮状態固定化技術
を用いて丸太またはこれを木挽した製材に残留する応力
を除去する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for modifying wood, in which the shape and volume of a wood material temporarily formed by compression can be maintained for a long period of time while resisting changes in humidity and temperature. Thus, the present invention relates to a method for fixing a compressed state. Another aspect of the present invention relates to a method for removing stress remaining in a log or sawn sawn timber using the above-described compression state fixing technique.

【0002】[0002]

【従来の技術】木材の物理的性質を改良するため、軟化
状態の木質材料を圧縮し高密度化する改質処理は古くか
ら知られ、工業的に実用化されている。しかし、軟化し
た木材を単に圧縮成形しただけでは成形の際に生じた圧
縮応力が残留するので、成形品が軟化点以上に加熱され
ると、一時的に固定されていた圧縮状態が残留応力の作
用により破壊され、圧縮木材の体積が圧縮加工前の体積
近くまで回復(体積緩和と呼ぶ。)し、形状も圧縮前の
形に近い状態まで拡大される。
2. Description of the Related Art In order to improve the physical properties of wood, a reforming treatment for compressing a wood material in a softened state to increase the density has been known for a long time and has been industrially put to practical use. However, simply compressing softened wood leaves the compressive stress generated during the molding process.If the molded product is heated above its softening point, the temporarily fixed compression state will change to the residual stress. It is destroyed by the action, the volume of the compressed wood recovers to near the volume before compression (referred to as volume relaxation), and the shape is expanded to a state close to the shape before compression.

【0003】このため圧縮木材の実用化にはこの応力の
除去に依る圧縮状態の固定化が重要であり、従来から圧
縮成形された木材の圧縮状態を半永久的に固定する有効
な方法として、一時的に圧縮状態を維持したままで20
0℃以上の乾式加熱または180℃付近での湿式加熱、
即ち水蒸気等による加熱を行うことが知られている。例
えば特開平3−231802号公報には、高温高圧の水
蒸気中において軟化させた木材を、高圧下または常圧下
に一対の金型間で圧縮して多角柱等の形状に圧縮成形
し、圧縮状態のまま再び高温の水蒸気中に或る時間置い
て形状を固定化する技術が開示されている。
For practical use of compressed wood, therefore, it is important to fix the compressed state by removing the stress. Conventionally, as an effective method for semi-permanently fixing the compressed state of compression-molded wood, a temporary method has been proposed. 20 while maintaining the compressed state
Dry heating at 0 ° C or higher or wet heating at around 180 ° C,
That is, it is known to perform heating using steam or the like. For example, JP-A-3-231802 discloses that wood softened in high-temperature and high-pressure steam is compressed between a pair of molds under high pressure or normal pressure to be compression-molded into a polygonal column shape and the like. A technique has been disclosed in which the shape is fixed again by leaving it in high-temperature steam for a certain period of time.

【0004】しかし上記先行技術では、上記固定化を完
了するまでの間、圧縮木材を金型内に加圧状態に保持し
たまま置くことが必要であるため金型内での滞留時間が
長くなり、高価な金型の稼働率が低下して製品のコスト
アップの要因となる。
However, in the above-mentioned prior art, the compressed wood must be kept in a pressurized state in the mold until the fixing is completed, so that the residence time in the mold becomes longer. This lowers the operating rate of expensive molds and increases the cost of products.

【0005】また、天然の立木の生長過程で生じた応力
は丸太や製材に残留し、使用中に高温になるとこの応力
の作用により丸太や製材に歪を生じる。これは無垢の木
材を構造材料として用いる際の致命的欠陥であり、従来
は長期の時間をかけて乾燥を充分に行ってから製材する
以外に有効な対処法が無かった。
[0005] In addition, the stress generated during the growth process of natural standing trees remains in logs and lumber. When the temperature becomes high during use, the log and lumber are distorted by the action of the stress. This is a fatal defect when solid wood is used as a structural material, and there has been no effective countermeasure except for long time and sufficient drying before lumbering.

【0006】[0006]

【発明が解決しようとする課題】本発明は、圧縮木材の
一時的に固定された圧縮状態を金型を使用せずに固定化
する新規、簡便且つ経済的な圧縮状態固定化方法の提供
を課題とする。また、他の本発明は、上記と同じ技術を
用いて丸太または製材に残留する生長応力或は曲げ加工
後等の残留応力を木質材料の形状に変化を生じさせるこ
と無く除去する新規、簡便且つ経済的な応力除去方法の
提供を課題とする。
SUMMARY OF THE INVENTION The present invention provides a new, simple, and economical method for fixing a compressed state of compressed wood, in which a temporarily fixed state of compressed wood is fixed without using a mold. Make it an issue. Further, the present invention uses a new, simple, and simple method for removing growth stress remaining in a log or lumber or residual stress after bending without causing a change in the shape of a wooden material using the same technique as described above. It is an object to provide an economical stress removing method.

【0007】[0007]

【課題を解決するための手段】第一の本発明の方法は、
圧縮により一時的に形状が固定された木質材料成形品と
耐熱性硬質粒子を容器内に納め、該粒子を該成形品間及
び該容器との間隙に密に充填した状態にして加熱するこ
と、を特徴とする木質材料成形品の圧縮状態固定化方法
である。ここで、一時的に固定された形状とは、軟化し
た木材を金型等により圧縮成形したままの状態におい
て、圧縮木材が保持している形状及び圧縮状態下の体積
を言う。また圧縮状態の固定化とは、上記一時的に固定
化された寸法、形状、体積、導管や有縁壁孔対或いは細
胞内腔等の内部構造等が圧縮された状態を、該圧縮木材
に負荷される湿度や温度の変化に耐えて半永久的に保持
するように、永続させることを言う。
The first method of the present invention comprises:
A wooden material molded product having a shape temporarily fixed by compression and heat-resistant hard particles are placed in a container, and the particles are heated in a state in which the particles are tightly filled between the molded products and a gap between the container and the container. This is a method for fixing a compressed state of a wooden material molded product. Here, the temporarily fixed shape refers to the shape held by the compressed wood and the volume under the compressed state in a state where the softened wood is compressed and molded by a mold or the like. The immobilization in the compressed state means that the temporarily immobilized size, shape, volume, the state in which the internal structure of the conduit, the pair of bounded wall holes or the cell lumen, etc. is compressed is applied to the compressed wood. Permanent so that it can withstand changes in humidity and temperature and keep it semi-permanently.

【0008】また、第二の本発明の方法は、丸太または
これを木挽した製材と耐熱性硬質粒子を容器内に納め、
該粒子を該丸太または製材の間及び該容器との間隙に密
充填した状態にして加熱すること、を特徴とする丸太ま
たは製材の残留応力除去方法である。
[0008] In the second method of the present invention, a log or sawn timber and heat-resistant hard particles are placed in a container.
A method for removing residual stress in a log or lumber, characterized in that the particles are heated in a state of being closely packed between the log or lumber and the gap between the log and lumber and the container.

【0009】[0009]

【発明の実施の形態】本発明において一時的に形状が固
定された木質材料成形品は、角柱、角材、円柱、厚板等
の所謂製材を圧縮加工したもの、及び丸太を圧縮加工し
た成形品を包含する。
BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, a wood material molded product whose shape is temporarily fixed is a product obtained by compressing so-called lumber such as a prism, a rectangular bar, a cylinder, a thick plate, and a product obtained by compressing a log. Is included.

【0010】本発明において一時的に形状を固定するた
めの圧縮は、当業界で公知の方法を用いることができ
る。例えば軟質針葉樹の製材や丸太を軟化点である10
0℃前後の温度の水蒸気中または空気中で加熱し軟化さ
せた後、一対の金型間で機械的に圧縮し、圧縮状態を保
持したまま金型及び成形品を冷却して一時的に形状を固
定化する。或いは繊維飽和点付近まで乾燥した丸太を防
水処理したのち熱水中に浸し、95−100℃に加熱し
軟化させた後、熱水の水圧をポンプ等により10−30
kg/cm2 に昇圧し、次いで熱水を冷水に切り換える
等の方法で圧力を保持したまま冷却して絞丸太調の成形
品を得る。
In the present invention, compression for temporarily fixing the shape can be performed by a method known in the art. For example, soft softwood lumber and logs are softened to 10
After being heated and softened in steam or air at a temperature of about 0 ° C, it is mechanically compressed between a pair of dies, and the dies and molded products are cooled while maintaining the compressed state to form temporarily. Is immobilized. Alternatively, a log dried to near the fiber saturation point is waterproofed, immersed in hot water, heated to 95-100 ° C. and softened, and then the water pressure of the hot water is increased by 10-30 with a pump or the like.
The pressure is increased to kg / cm 2 and then cooled while maintaining the pressure by a method such as switching hot water to cold water to obtain a molded article having a chopped log tone.

【0011】本発明に用いる耐熱性硬質粒子は、比較的
粒度の揃った天然の砂、或は合成シリカ、合成アルミナ
等のような無機質微粒子である。耐熱性は、後記する熱
処理の操作温度付近において軟化しない程度、例えば3
00℃程度の耐熱性があれば良い。実用的には市販のア
ルミナ研磨材等を例示することができる。
The heat-resistant hard particles used in the present invention are natural sand having a relatively uniform particle size, or inorganic fine particles such as synthetic silica and synthetic alumina. The heat resistance is such that it does not soften near the operating temperature of the heat treatment described later, for example, 3
Any heat resistance of about 00 ° C. is sufficient. Practically, commercially available alumina abrasives can be exemplified.

【0012】硬質粒子の粒度は、成形品の形状や表面精
度等により異なるが、請求項2の発明に記載するよう
に、平均粒径が0.3mm−4mmが良い。特に0.3
mm−3mmの範囲が使用し易い。表面の平滑性を要求
される板材や、静水圧により圧縮された側面にある細か
い皺を装飾外観として用いる絞丸太調成形品等では粒度
は細かいものが好ましいが、平均粒径が0.3mm未満
では固定化処理終了後に粒子を除去し難く、好ましくな
い。圧密化後に製材を行う製材用圧縮丸太を製造する場
合には平均粒径2mm−3mmのものが使用し易い。4
mmを超えた粒径では成形品の表面が肌荒れし、また硬
質粒子を容器へ出し入れする際の空気輸送が困難とな
る。
The particle size of the hard particles varies depending on the shape and surface accuracy of the molded product, but as described in the second aspect of the present invention, the average particle size is preferably 0.3 mm to 4 mm. Especially 0.3
The range of mm-3 mm is easy to use. Plate materials requiring surface smoothness, squeezed log-like molded products using fine wrinkles on the side compressed by hydrostatic pressure as decorative appearance, etc., preferably have a fine particle size, but the average particle size is less than 0.3 mm In this case, it is difficult to remove the particles after the completion of the fixing treatment, which is not preferable. When manufacturing a compressed log for lumber which performs lumbering after consolidation, it is easy to use a log with an average particle diameter of 2 mm to 3 mm. 4
If the particle size exceeds mm, the surface of the molded article becomes rough, and it becomes difficult to transport the hard particles in and out of the container by air.

【0013】本発明に用いる容器の形状及び寸法には特
に制限がないが、単数または複数個の木質材料成形品を
収納できるものであれば良い。通常、角柱等長尺材料の
固定化処理に用いるために充分な長さの円筒形容器が実
用的である。円筒形の一方の閉じた底部に粒子排出用孔
及び弁を設け、他方の底部は木質材料の挿入及び取り出
しの為の開閉蓋を設ければ便利である。
The shape and dimensions of the container used in the present invention are not particularly limited, but may be any as long as they can store one or a plurality of molded wood materials. Usually, a cylindrical container having a sufficient length to be used for immobilizing a rectangular column or other long material is practical. It is convenient if one closed bottom of the cylindrical shape is provided with a hole for discharging particles and a valve, and the other bottom is provided with an opening / closing lid for insertion and removal of wood material.

【0014】容器の耐圧性については、例えば容器が通
常の鋼板製であれば特別な耐圧性を必要としない。その
理由は、例えば長尺の木質材料成形品の膨張力を金型で
直接封じ込める場合、金型には強い曲げ応力がかかるの
で厚い肉厚が要求されるが、本発明の場合、容器と木質
材料成形品の相対的位置を考慮することにより、容器壁
と成形品の間に介在する硬質粒子が上記膨脹力を均等化
して容器壁へ伝達するので、結果として容器壁の引張り
強度により上記膨脹力を押え込むことが出来るからであ
る。
Regarding the pressure resistance of the container, for example, if the container is made of a normal steel plate, no special pressure resistance is required. The reason is that, for example, when the expansion force of a long wooden material molded product is directly confined by a mold, a strong bending stress is applied to the mold, so that a thick wall is required. By considering the relative position of the material molded article, the hard particles interposed between the container wall and the molded article equalize the expansion force and transmit the same to the container wall. As a result, the expansion due to the tensile strength of the container wall occurs. It is because it can hold down power.

【0015】本発明において、木質材料成形品を上記容
器に収納する場合、硬質粒子が成形品の周囲を充分に囲
んで充填されるような空間を設けること、すなわち例え
ばスペーサーを使用する等により容器壁と成形品との間
隙を確保し且つ木質材料成形品相互の間隙も確保するこ
とが必要である。この間隙は硬質粒子の形状や粒度にも
よるが、通常の目安は数cm程度であれば良い。
In the present invention, when a wooden material molded article is housed in the container, a space is provided so that the hard particles are sufficiently surrounded and filled around the molded article, that is, by using a spacer, for example. It is necessary to ensure a gap between the wall and the molded article and also a gap between the wooden material molded articles. This gap depends on the shape and the particle size of the hard particles, but a general standard may be about several cm.

【0016】本発明において、硬質粒子の充填は所謂密
充填状態になるように密にする必要がある。ここで密充
填とは、粒子が単に静かに上記間隙に注ぎ込まれた状態
では無く、容器に振動を与える等の操作によって最早粒
子が空間を残さずに充填し尽くし、しかも木質材料成形
品が容易に容器の半径方向に動くことがない状態まで粒
子を充填して空隙率をできる限り小さくすることであ
る。この状態は、もし粒子が等径の真球であれば規則的
最密充填と呼ばれるが、本発明では形状が非球で粒径が
分布を有する粒子であっても良いので、所謂ランダム密
充填と呼ばれる状態である。
In the present invention, the hard particles need to be densely packed so as to form a so-called densely packed state. Here, the dense packing means that the particles are no longer simply gently poured into the gap but are completely filled without leaving any space by an operation such as applying vibration to the container, and the wooden material molded product is easily manufactured. The porosity is reduced as much as possible by filling the particles so that they do not move in the radial direction of the container. This state is called regular close-packing if the particles are spherical particles having the same diameter.However, in the present invention, particles having a non-spherical shape and a particle size distribution may be used. It is a state called.

【0017】請求項3の発明に記載するように、密充填
状態を実現する手段としては、粒子注入後に容器全体を
揺動させて振動を与えながら粒子を追加する方法、粒子
注入後に木質材料成形品または容器壁を手動でまたは機
械的に叩くなどして振動させながら粒子を追加する方
法、注入した粒子に振動棒を挿入して粒子を振動させつ
つ粒子を追加注入する方法、等が挙げられる。
As described in the third aspect of the present invention, the means for realizing the tightly packed state includes a method of adding particles while oscillating the whole container after the particles are injected, and a method of forming a wood material after the particles are injected. A method of adding particles while vibrating the product or container wall manually or mechanically, and a method of additionally injecting particles while vibrating the particles by inserting a vibrating rod into the injected particles, and the like. .

【0018】容器内に粒子を密充填した後、容器の開閉
蓋を閉じて内部の粒子を押さえ付けるようにする。但
し、必要な場合は開閉蓋に代えて粒子を通過させない金
網で押さえ、後述する熱処理中に膨脹した空気や発生し
た水蒸気を圧力差によって自由に通過させても差支えな
い。また、容器内の軸方向において、粒子の層が成形品
の上端を覆う層厚みが充分厚い場合は、粒子を押さえる
蓋は必ずしも必要ではない。このように木質材料成形品
の形状、圧縮成形の圧縮度、容器と成形品の相対的大き
さ等により蓋の必要性が異なるので、容器の蓋は本発明
で必要な要件ではない。
After the particles are densely packed in the container, the opening and closing lid of the container is closed to hold down the particles inside. However, if necessary, instead of the opening / closing lid, it may be held by a wire mesh that does not allow particles to pass through, and air expanded during the heat treatment described later or water vapor generated may be freely passed by a pressure difference. When the layer of the particles covers the upper end of the molded product in the axial direction in the container, the lid for holding the particles is not necessarily required. As described above, since the necessity of the lid varies depending on the shape of the wooden material molded article, the degree of compression of the compression molding, the relative size of the container and the molded article, the lid of the container is not a necessary requirement in the present invention.

【0019】次いで本発明の方法では、硬質粒子を密充
填した状態において木質材料成形品を熱処理する。請求
項4の発明で記載するように、熱処理は乾式加熱により
180−250℃の温度に加熱、または湿式加熱により
140−190℃に加熱することにより行う。乾式加熱
には、当業界で通常用いられる方法を使用することがで
きる。実用的には、火焔による外部加熱、熱風乾燥機に
於ける熱風の送入、熱媒体、電熱、マイクロ波等を例示
できる。また湿式加熱には、当業界で通常用いられる蒸
気釜による高温高圧水蒸気の送入、熱水の送入等を例示
できる。
Next, in the method of the present invention, the wooden material molded article is heat-treated in a state where the hard particles are densely packed. As described in the fourth aspect of the present invention, the heat treatment is performed by heating to a temperature of 180 to 250 ° C. by dry heating or to 140 to 190 ° C. by wet heating. For the dry heating, a method usually used in the art can be used. Practically, external heating by a flame, feeding of hot air in a hot air dryer, a heating medium, electric heating, microwaves and the like can be exemplified. Examples of the wet heating include feeding of high-temperature and high-pressure steam by a steam pot commonly used in the art, feeding of hot water, and the like.

【0020】加熱時間は、加熱温度、所望する固定化の
程度、雰囲気中の水蒸気の分圧、成形品の厚み等により
異なるので一概に規定できないが、実用的には10−2
00分が使用される。ただし、製品によってはより長い
加熱時間が望ましい場合もある。
The heating time varies depending on the heating temperature, the desired degree of immobilization, the partial pressure of water vapor in the atmosphere, the thickness of the molded product, and the like, and cannot be specified unconditionally.
00 minutes are used. However, longer heating times may be desirable for some products.

【0021】上記熱処理を行うことにより、圧縮成形し
た木質材料成形品の圧縮状態が固定されるので、容器内
から高温粒子を振動により抜き出すか、または放置して
自然冷却した粒子を振動により抜き出し、成形品を取り
出す。
By performing the above heat treatment, the compressed state of the compression molded wood material molded article is fixed, so that the high temperature particles are extracted from the container by vibration, or the naturally cooled particles are extracted by vibration, Take out the molded product.

【0022】圧縮状態の固定化の程度(固定化度)は、
固定化後の成形品を所定時間、例えば95℃で60分間
熱水で処理した場合に、圧縮によって減少した断面積ま
たは圧縮方向の厚みの何%が回復するかという回復率で
表される。成形品が屋内の乾燥した雰囲気で使用される
場合は回復率が多少高くても良いが、湯気や結露、雨水
に曝される用途の場合は低い回復率が必要である。
The degree of fixation of the compressed state (degree of fixation)
When the molded article after the immobilization is treated with hot water for a predetermined time, for example, at 95 ° C. for 60 minutes, it is expressed by a recovery rate of the cross-sectional area reduced by compression or the percentage of the thickness in the compression direction. The recovery rate may be slightly higher when the molded article is used in a dry atmosphere indoors, but a lower recovery rate is required for applications that are exposed to steam, dew, or rainwater.

【0023】なお、本発明は実用上、杉、唐松、檜、ベ
イ松、ベイ栂など軟質針葉樹に多く適用されるが、基本
的に樹種によって制限されるものではない。
The present invention is practically widely applied to soft conifers such as cedar, karamatsu, cypress, bay pine, bay toga, but is not basically limited by tree species.

【0024】次に、請求項5に記載の発明では、立木を
切断した丸太またはこれを木挽した角柱等の製材であっ
て圧縮加工無しに使用するものを前記容器に適当な間隙
を保ちながら収納し、前記耐熱性硬質粒子を振動等によ
り密充填し、密充填状態のまま例えば高圧水蒸気を用い
て70−150℃に1−100時間程度加熱する。加熱
処理終了後、高圧空気に切り換えて容器内部の冷却を兼
ねて丸太または製材を適度に乾燥させることも可能であ
る。加熱処理終了後、振動により粒子を容器から排出さ
せ、製品を取り出す。
Next, according to the fifth aspect of the present invention, a log cut from a standing tree or a lumber such as a square pillar obtained by cutting the tree and used without compression is stored in the container while maintaining an appropriate gap. Then, the heat-resistant hard particles are densely packed by vibration or the like, and heated to 70 to 150 ° C. for about 1 to 100 hours using, for example, high-pressure steam in the tightly packed state. After the completion of the heat treatment, it is also possible to switch to high-pressure air and appropriately dry the log or lumber while also cooling the inside of the container. After the heat treatment, the particles are discharged from the container by vibration, and the product is taken out.

【0025】[0025]

【実施例】本発明を更に詳しく説明するため実施例を示
すが、本発明はこれに限定されるものではない。ここで
特に断らない限り、固定化度は前記定義による回復率で
表示する。
EXAMPLES The present invention will be described in more detail with reference to Examples, but it should not be construed that the invention is limited thereto. Here, unless otherwise specified, the degree of fixation is represented by the recovery rate defined above.

【0026】[実施例1] 木質材料成形品(1)の製造 寸法が900mm(L)×50mm(R)×150mm
(T)、含水率23%の杉の板目材を蒸気釜に入れ、2
kg/cm2 の水蒸気雰囲気中で60分間蒸煮した後、
大気中に取り出し、120℃に調温された2枚の対向す
る熱盤により放射方向厚さ(R)22mmに圧縮した。
次いで圧締したままこの熱盤に内蔵するパイプを通じて
冷却水を循環させ、圧縮木材の内部温度を30℃以下に
冷却して一時的に圧縮状態が固定化された木質材料成形
品(1)を得た。この成形品から周辺部を切断除去して
300mm(L)×22mm(R)×102mm(T)
の試験片を切り出し、図1に示すように木材の接線方向
(T)にA、B、Cの3箇所、繊維方向(L)に1、
2、3の3箇所の合計9箇所の碁盤目状の測定点を選
び、放射方向(R)の寸法を測定し、結果を表1に示し
た。
[Example 1] Manufacture of a wooden material molded product (1) dimensions 900 mm (L) x 50 mm (R) x 150 mm
(T) Put the cedar mesh material with a moisture content of 23% into a steam kettle,
After steaming for 60 minutes in a steam atmosphere of kg / cm 2 ,
It was taken out into the atmosphere and compressed to a radial thickness (R) of 22 mm by two opposing hot plates adjusted to 120 ° C.
Then, while being pressed, cooling water is circulated through a pipe built in the hot platen to cool the internal temperature of the compressed wood to 30 ° C. or less, and the wooden material molded product (1) in which the compressed state is temporarily fixed is obtained. Obtained. The peripheral part is cut and removed from this molded product, and 300 mm (L) × 22 mm (R) × 102 mm (T)
1 was cut out, and as shown in FIG. 1, three points A, B, and C in the tangential direction (T) of the wood, and 1 in the fiber direction (L).
A total of nine grid-like measuring points, three and two, were selected, and the dimensions in the radial direction (R) were measured. The results are shown in Table 1.

【0027】硬質粒子の密充填 内径105mm×400mm(L)の円筒形状の容器本
体の両端にフランジ式の蓋(通気性有り)を付けた容器
を立て、上記試験片を器壁と接触しないように収納し、
耐熱性硬質粒子として平均粒径0.5mmの溶融アルミ
ナ粉砕粉(昭和電工社製、モランダムA−40、No3
6)を満杯に充填し、蓋を閉じた。次に容器をハンマー
で叩いて振動を与え、蓋のボルトナットを増し締めし、
充填の空隙がなくなり蓋の増し締めが出来なくなるまで
これを繰り返した。
Closely packed with hard particles A cylindrical container body having an inner diameter of 105 mm × 400 mm (L) is provided with a flange-type lid (with air permeability) attached to both ends of a cylindrical container body so that the test piece does not come into contact with the container wall. Stored in
As heat-resistant hard particles, pulverized fused alumina having an average particle size of 0.5 mm (Morundum A-40, No. 3 manufactured by Showa Denko KK)
6) was filled completely, and the lid was closed. Next, hit the container with a hammer to apply vibration, tighten the bolt and nut on the lid,
This was repeated until the filling gap disappeared and the lid could not be retightened.

【0028】熱処理 高圧蒸気釜に上記容器を入れ、175℃で1時間蒸煮し
て加熱を行った後、蒸気釜を常圧まで徐々に減圧し、容
器を自然冷却後、試験片を容器から取り出し、固定化処
理した成形品(1)である試験片を得た。この試験片に
ついて、前記測定点における放射方向(R)寸法を測定
し、結果を表1に示した。固定化処理による放射方向寸
法の変化は極く微量に留まった。なお、成形品の重量は
5.8%減少した。
Heat treatment The above vessel is put in a high-pressure steam pot, steamed at 175 ° C. for 1 hour and heated, then the steam pot is gradually depressurized to normal pressure, the vessel is naturally cooled, and a test piece is taken out of the vessel. Then, a test piece as a molded article (1) subjected to the immobilization treatment was obtained. For this test piece, the dimension in the radial direction (R) at the measurement point was measured, and the results are shown in Table 1. The change in the radial dimension due to the immobilization treatment was extremely small. In addition, the weight of the molded article decreased by 5.8%.

【0029】固定化度の測定 上記固定化処理後の成形品(1)である試験片を95℃
に保たれた熱水中に60分浸漬した後、105℃の熱風
乾燥機中で3日間乾燥して絶乾状態にした。この試験片
について前記9測定点での放射方向(R)の厚みを測定
し、次式により回復率を計算した結果を表1に示す。圧
縮状態を固定化した試験片は絶乾状態に乾燥されていな
いのに対し、これを熱水処理した後の試験片は絶乾状態
に乾燥して厚みを測定したため、回復率は見掛けは負の
値を示すが、実際には固定化が完全に行われたことを示
している。
Measurement of degree of immobilization A test piece as a molded article (1) after the above-mentioned immobilization treatment was heated to 95 ° C.
After being immersed in hot water kept at 60 ° C. for 60 minutes, it was dried in a hot air dryer at 105 ° C. for 3 days to make it completely dry. Table 1 shows the results of measuring the thickness of the test piece in the radial direction (R) at the nine measurement points and calculating the recovery rate by the following equation. The test specimens with the compressed state fixed were not dried to the absolute dry state, whereas the test specimens after hot water treatment were dried to the absolute dry state and the thickness was measured. , But actually indicates that the immobilization was completely completed.

【0030】[0030]

【数式1】 0 : 圧縮成形前の板厚 t1 : 圧縮状態固定化後の板厚 t2 : 熱水処理・乾燥後の板厚[Formula 1] t 0 : Thickness before compression molding t 1 : Thickness after fixing in a compressed state t 2 : Thickness after hot water treatment / drying

【0031】[0031]

【表1】 ─────────────────────────────────── 測定点 圧縮成形品 固定化後 固定化処理 熱水処理品 回復率 厚み 厚みt1 変化率(%) 厚みt2 (%) ─────────────────────────────────── A1 21.6 21.9 1.4 21.2 -2.5 2 21.9 22.6 3.2 22.3 -1.1 3 21.7 22.3 2.8 22.0 -1.1 B1 22.5 22.2 -1.3 22.1 -0.3 2 22.4 22.7 1.3 22.5 -0.7 3 22.2 21.8 -1.8 21.5 -1.1 C1 21.9 21.9 0 21.3 -2.1 2 21.7 22.5 3.7 22.0 -1.8 3 21.5 22.5 4.7 22.0 -1.8 ─────────────────────────────────── (註)厚みの単位:mm、 t0 =50mm [Table 1] ─────────────────────────────────── Measurement point Compression molded product After fixation Fixation treatment the hot-water treated product recovery rate thickness thickness t 1 the rate of change (%) thickness t 2 (%) ───────────────────────────── A A1 21.6 21.9 1.4 21.2 -2.5 2 21.9 22.6 3.2 22.3 -1.1 3 21.7 22.3 2.8 22.0 -1.1 B1 22.5 22.2 -1.3 22.1 -0.3 2 22.4 22.7 1.3 22.5 -0.7 3 22.2 21.8 -1.8 21.5 -1.1 C1 21.9 21.9 0 21.3 -2.1 2 21.7 22.5 3.7 22.0 -1.8 3 21.5 22.5 4.7 22.0 -1.8 ───────────────────────────── ────── (Note) Unit of thickness: mm, t 0 = 50 mm

【0032】[実施例2] 木質材料成形品(2)の製造 葉枯らし乾燥した直径約170mm、長さ950mmの
樹皮付き杉丸太を高温乾燥機に入れ、水蒸気圧を1kg
/cm2 で、温度を101−105℃で2日間乾燥し、
平均含水率37重量%の乾燥丸太を得た。これの両木口
にクロロプレン系接着剤(コニシ社製、商品名ボンドG
17)を塗布し、市販のポリ塩化ビニリデン製ラップフ
ィルムをを貼り付けて木口からの水の浸透を防止した。
この丸太を90℃の熱風炉中で2時間加熱した後、95
℃の熱水を満たした竪型円筒形の密閉釜に入れ、ポンプ
で釜の下部から毎分2リットルの冷水を圧入した。釜の
圧力は約5分で30kg/cm2 に達し、予め釜上部に
設けたリリーフバルブがこの時点で作動して、以後内圧
30kg/cm2 に保持されたまま冷水の圧入が続けら
れた。バルブから排出される水の温度は15分で30℃
以下に低下した。更に冷水の圧入を90分続けた後、釜
を開き丸太を取り出した。丸太の木部はかなり圧縮され
ており樹皮は容易に除去できた。この丸太を大気中に1
週間放置して風乾し、圧縮木材である木質材料成形品
(2)を得た。該成形品は表面が複雑な凹凸を持つ所謂
絞丸太調の外観を呈し、両木口の断面形状を紙に写し取
り、面積を計測したところ圧縮前と比較して平均48%
に減少していた。
[Example 2] Production of a wood material molded article (2) A cedar log with bark having a diameter of about 170 mm and a length of 950 mm, which had been dried, was put into a high-temperature dryer, and the steam pressure was set at 1 kg.
/ Cm 2 at a temperature of 101-105 ° C. for 2 days,
A dried log having an average moisture content of 37% by weight was obtained. A chloroprene-based adhesive (manufactured by Konishi Co., trade name: Bond G)
17) was applied, and a commercially available wrap film made of polyvinylidene chloride was stuck thereon to prevent water from permeating through the kiguchi.
After heating this log in a hot air oven at 90 ° C. for 2 hours, 95%
The mixture was placed in a vertical cylindrical hermetic kettle filled with hot water at ℃, and 2 liters of cold water per minute was injected from the bottom of the kettle with a pump. The pressure in the kettle reached 30 kg / cm 2 in about 5 minutes, the relief valve previously provided on the top of the kettle was activated at this time, and thereafter the injection of cold water was continued while the internal pressure was maintained at 30 kg / cm 2 . The temperature of the water discharged from the valve is 30 ° C in 15 minutes
It fell below. After the cold water injection was further continued for 90 minutes, the kettle was opened and the log was taken out. The xylem of the log was considerably compressed and the bark could be easily removed. Put this log in the air
It was left to stand for a week and air-dried to obtain a wooden material molded product (2) which was compressed wood. The molded product had a so-called squeezed log-like appearance with complicated irregularities on the surface. The cross-sectional shape of both lips was copied on paper, and the area was measured.
Was decreasing.

【0033】固定化処理 木質材料成形品(2)を縦割りし、割面をプラナー仕上
し、長さ220mmに切り取ることにより、図2(a)
に示す断面形状を有する試験体を作製し、断面形状を紙
に写し取り、断面積を測定した。なお、同図の木口に表
示されている文字Aは、この木口が両木口のうちの元口
であることを示す標識である。次いで、実施例1と同じ
容器及び硬質粒子を使用して、実施例1と同様にして上
記試験体と粒子を充填した。この容器を実施例1と同じ
高圧蒸気釜に入れ、同様にして固定化処理した成形品
(2)である試験体を得た。この試験体の固定化処理後
の断面形状を上記同様に紙に写し取り、上記と同一の元
口について比較したところ図2(b)に示すように相似
形に保持されていた。但し、固定化処理によって断面積
は1.6%減少した。つまり、圧縮状態固定化のために
成形品(2)を加熱したが体積緩和は起こらず、成形品
(2)が膨張しなかったことが実証された。また、重量
を測定したところ固定化処理により5.4%減少してい
た。
Immobilization treatment The wood material molded product (2) is vertically divided, the cut surface is planarized, and cut into 220 mm in length to obtain FIG.
Specimens having the cross-sectional shape shown in Table 1 were prepared, the cross-sectional shape was copied on paper, and the cross-sectional area was measured. The character A displayed at the tip of the figure is a sign indicating that this tip is the original one of the two tips. Next, using the same container and hard particles as in Example 1, the above-described specimen and particles were filled in the same manner as in Example 1. This container was placed in the same high-pressure steam kettle as in Example 1, and a test body as a molded article (2) similarly fixed was obtained. The cross-sectional shape of this test body after the immobilization treatment was copied onto paper in the same manner as described above, and the same original port as above was compared. As a result, as shown in FIG. However, the cross-sectional area was reduced by 1.6% by the immobilization treatment. That is, although the molded article (2) was heated for fixing the compressed state, the volume relaxation did not occur, and it was proved that the molded article (2) did not expand. Further, when the weight was measured, the weight was reduced by 5.4% due to the immobilization treatment.

【0034】固定化度の測定 上記固定化処理後の試験体を用いて実施例1と同様に9
5℃熱水処理した後、105℃の熱風乾燥機中で3日間
乾燥して絶乾状態とし、上記同様に元口の断面積を測定
した。熱水処理により断面積は全く変わらなかった。従
って、次式により計算した回復率はゼロ%であった。
Measurement of the degree of immobilization Using the test body after the immobilization treatment, 9
After hot water treatment at 5 ° C., it was dried in a hot air drier at 105 ° C. for 3 days to make it completely dry, and the cross-sectional area of the base was measured in the same manner as described above. The cross-sectional area did not change at all by the hot water treatment. Therefore, the recovery rate calculated by the following equation was 0%.

【0035】[0035]

【数式2】 0 : 圧縮成形前の断面積 s1 : 圧縮状態固定化後の断面積 s2 : 熱水処理・乾燥後の断面積[Formula 2] s 0 : cross-sectional area before compression molding s 1 : cross-sectional area after fixing in a compressed state s 2 : cross-sectional area after hot water treatment and drying

【0036】[0036]

【発明の効果】本発明の方法を所望の断面形状を有する
圧縮木材に適用する場合に、高価な金型は軟化した木材
を成形するために短時間使用するのみであり、その後長
時間を要する圧縮状態の固定化は木質材料成形品を金型
から取り出して行う。従って金型占有時間当たりの生産
性が著しく向上する。
When the method of the present invention is applied to compressed wood having a desired cross-sectional shape, an expensive mold is used only for a short time to form softened wood, and thereafter requires a long time. The immobilization of the compressed state is performed by removing the wooden material molded product from the mold. Therefore, productivity per mold occupation time is significantly improved.

【0037】本発明の方法のよれば、絞丸太調のような
複雑な外観の圧縮成形品でも容易に硬質粒子が充填する
ので、高圧の印加を継続すること無しに簡便に外観形状
を固定化できる。
According to the method of the present invention, even a compression-molded product having a complicated appearance such as a round log tone can be easily filled with hard particles, so that the external shape can be easily fixed without applying a high pressure. it can.

【0038】本発明の方法では、密充填した粒子の摩擦
力が木材の膨脹しようとする力を吸収する作用を発揮す
るので容器は耐圧性の低いもので足り、器壁の薄い低コ
ストの装置が使用できる。
In the method of the present invention, since the frictional force of the densely packed particles exerts an action of absorbing the expanding force of the wood, the container need only have low pressure resistance, and a low-cost apparatus having a thin wall can be used. Can be used.

【0039】本発明の方法によれば、密充填された粒子
が流体を通すことができるため、水蒸気の流通による効
率的加熱ができる。また過熱水蒸気を使用すれば、圧縮
状態の固定化を行いながら成形品を乾燥することがで
き、木質材料成形品を経済的に製造することができる。
According to the method of the present invention, since the densely packed particles can pass through the fluid, efficient heating can be achieved by the flow of steam. If superheated steam is used, the molded product can be dried while fixing the compressed state, and a wooden material molded product can be economically manufactured.

【0040】第二の本発明によれば原木を長期間自然乾
燥せずに、温度や湿度によって形状に歪を生じ難い丸太
や製材を簡便にかつ生産性良く製造することができる。
According to the second aspect of the present invention, logs and lumbers whose shapes are unlikely to be deformed by temperature and humidity can be easily produced with high productivity without naturally drying the raw wood for a long period of time.

【0041】[0041]

【図面の簡単な説明】[Brief description of the drawings]

【図1】木質材料成形品(1)について本発明の効果を
測定するための試験片における板目上の測定点を示す平
面図である。
FIG. 1 is a plan view showing measurement points on a grain of a test piece for measuring an effect of the present invention for a wooden material molded article (1).

【0042】[0042]

【図2】木質材料成形品(2)について本発明の効果を
示すための試験体の元口の断面図であり、夫々(a)は
圧縮状態固定化前、(b)は圧縮状態固定化後のもので
ある。
FIGS. 2A and 2B are cross-sectional views of a base of a specimen for showing the effect of the present invention with respect to a wooden material molded article (2), in which (a) is before fixing in a compressed state, and (b) is fixed in a compressed state. Later.

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平3−231802(JP,A) 特開 平4−201503(JP,A) 特開 平5−50409(JP,A) 特開 平6−91611(JP,A) 特開 平8−155910(JP,A) 特開 平8−224709(JP,A) 特開 平8−276407(JP,A) (58)調査した分野(Int.Cl.7,DB名) B27K 5/00 B27K 5/06 ────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-3-231802 (JP, A) JP-A-4-201503 (JP, A) JP-A-5-50409 (JP, A) JP-A-6-206 91611 (JP, A) JP-A-8-155910 (JP, A) JP-A-8-224709 (JP, A) JP-A 8-276407 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) B27K 5/00 B27K 5/06

Claims (6)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 圧縮により一時的に形状が固定された木
質材料成形品と耐熱性硬質粒子を容器内に納め、該粒子
を該成形品間及び該容器との間隙に密充填した状態にし
て加熱すること、を特徴とする木質材料成形品の圧縮状
態固定化方法。
1. A wooden material molded article whose shape is temporarily fixed by compression and heat-resistant hard particles are placed in a container, and the particles are tightly filled between the molded articles and the gap between the container and the container. A method for fixing a compressed state of a wooden material molded article, comprising heating.
【請求項2】 耐熱性硬質粒子の平均粒径が0.3−4
mmである請求項1記載の圧縮状態固定化方法。
2. The heat-resistant hard particles have an average particle size of 0.3-4.
2. The method for fixing a compressed state according to claim 1, wherein the diameter is mm.
【請求項3】 振動手段を用いて耐熱性硬質粒子を密充
填させる請求項1記載の圧縮状態固定化方法。
3. The method for fixing a compressed state according to claim 1, wherein the heat-resistant hard particles are densely packed using a vibration means.
【請求項4】 熱処理を乾式加熱により180−250
℃で、または湿式加熱により140−190℃で行うこ
とを特徴とする請求項1、2、または3記載の圧縮状態
固定化方法。
4. The heat treatment is performed by 180-250 by dry heating.
The method for fixing a compressed state according to claim 1, wherein the method is performed at 140 ° C. or 190 ° C. by wet heating.
【請求項5】 丸太又はこれを木挽した製材と耐熱性硬
質粒子を容器内に納め、該粒子を該丸太または製材の間
及び該容器との間隙に密充填した状態にして加熱するこ
と、を特徴とする丸太または製材の残留応力除去方法。
5. A method in which a log or a sawn sawn timber and heat-resistant hard particles are placed in a container, and the particles are heated in a state of being tightly packed between the log or the sawn timber and a gap between the log and the container. Characteristic method for removing residual stress from logs or lumber.
【請求項6】 平均粒径が0.3−4mmである耐熱性
硬質粒子を用い、熱処理を70−150℃で行うことを
特徴とする請求項5記載の丸太または製材の残留応力除
去方法。
6. The method according to claim 5, wherein heat treatment is performed at 70 to 150 ° C. using heat-resistant hard particles having an average particle diameter of 0.3 to 4 mm.
JP09060365A 1996-10-04 1997-03-14 Method of fixing compressed state of wood material molded article and method of removing residual stress of wood material Expired - Fee Related JP3109999B2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP09060365A JP3109999B2 (en) 1997-03-14 1997-03-14 Method of fixing compressed state of wood material molded article and method of removing residual stress of wood material
DK199701018A DK175650B1 (en) 1996-10-04 1997-09-08 Method for hydrostatic pressure forming of wood
NZ328700A NZ328700A (en) 1996-10-04 1997-09-09 Hydrostatic processing of wood
AU37504/97A AU732280B2 (en) 1996-10-04 1997-09-12 Hydrostatic compression forming for wood and novel ligneous material therefrom
US08/929,651 US6267920B1 (en) 1996-10-04 1997-09-16 Hydrostatic compression method for producing a fancy log from a primary wood
CA002215876A CA2215876A1 (en) 1996-10-04 1997-09-19 Hydrostatic compression forming for wood and novel ligneous material therefrom
DE19743703A DE19743703A1 (en) 1996-10-04 1997-10-02 Hydrostatic method for compressing wood in liquid
SE9703598A SE519408C2 (en) 1996-10-04 1997-10-02 Hydrostatic compression molding of wood materials and such new lignin-containing materials
DK200300380A DK200300380A (en) 1996-10-04 2003-03-13 Hydrostatic method for compressing wood in liquid - involves softening wood, compressing wood under hydrostatic pressure until desired dimensions are achieved and treating timber to fix size

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP09060365A JP3109999B2 (en) 1997-03-14 1997-03-14 Method of fixing compressed state of wood material molded article and method of removing residual stress of wood material

Publications (2)

Publication Number Publication Date
JPH10249812A JPH10249812A (en) 1998-09-22
JP3109999B2 true JP3109999B2 (en) 2000-11-20

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ID=13140053

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Country Status (1)

Country Link
JP (1) JP3109999B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5060791B2 (en) * 2007-01-26 2012-10-31 独立行政法人森林総合研究所 Method for drying wood, method for penetrating chemicals into wood and drying apparatus
CN106217563A (en) * 2016-07-28 2016-12-14 阜南县东奥工艺品有限公司 A kind of mildew and insect proof method weaving the stem or leaf of cattail
CN106217544A (en) * 2016-08-31 2016-12-14 安徽阜南县万家和工艺品有限公司 A kind of rattan weaving pretreating reagent

Also Published As

Publication number Publication date
JPH10249812A (en) 1998-09-22

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