JP3077802B1 - Method and apparatus for carbonizing sludge - Google Patents

Method and apparatus for carbonizing sludge

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Publication number
JP3077802B1
JP3077802B1 JP11232080A JP23208099A JP3077802B1 JP 3077802 B1 JP3077802 B1 JP 3077802B1 JP 11232080 A JP11232080 A JP 11232080A JP 23208099 A JP23208099 A JP 23208099A JP 3077802 B1 JP3077802 B1 JP 3077802B1
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JP
Japan
Prior art keywords
sludge
exhaust gas
activated
gas
flash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11232080A
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Japanese (ja)
Other versions
JP2001058806A (en
Inventor
正和 澤井
玉貴 桜井
修一郎 畠山
浩史 黒田
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Kawasaki Motors Ltd
Original Assignee
Kawasaki Jukogyo KK
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Priority to JP11232080A priority Critical patent/JP3077802B1/en
Application granted granted Critical
Publication of JP3077802B1 publication Critical patent/JP3077802B1/en
Publication of JP2001058806A publication Critical patent/JP2001058806A/en
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Expired - Fee Related legal-status Critical Current

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  • Carbon And Carbon Compounds (AREA)
  • Treatment Of Sludge (AREA)

Abstract

【要約】 【課題】 気流乾燥機と活性炭化炉を用いて汚泥から吸
着性能の高い活性炭化物を製造する。気流乾燥排ガスを
活性炭化炉に導入して臭気を熱分解する。 【解決手段】 循環乾燥汚泥に汚泥脱水ケーキを混合
し、これを解砕機20で粉砕・乾燥させ、乾燥汚泥を気
流乾燥管22でさらに乾燥させた後、乾燥汚泥を含む気
流をサイクロン24で固気分離し、乾燥汚泥の大部分を
循環乾燥汚泥とし、残りの乾燥汚泥を活性炭化炉32で
炭化・賦活して活性炭化物を製造し、サイクロン24か
らの乾燥排ガスの一部を活性炭化炉32排ガスと熱交換
して乾燥排ガスを加熱し、この加熱気体を解砕機20に
供給し、サイクロン24からの乾燥排ガスの一部と熱交
換した活性炭化炉32排ガスを排気し、サイクロン24
からの乾燥排ガスの残部を水洗式のスクラバー60に供
給して水洗し除湿した後、活性炭化炉32に導入してガ
ス中の臭気成分を熱分解する。
Abstract: PROBLEM TO BE SOLVED: To produce activated carbide having high adsorption performance from sludge using a flash dryer and an activated carbon furnace. The flue gas is introduced into an activated carbonization furnace to thermally decompose odors. SOLUTION: A sludge dewatered cake is mixed with a circulating dried sludge, and this is pulverized and dried by a crusher 20. The dried sludge is further dried by a flash drying tube 22, and an airflow containing the dried sludge is solidified by a cyclone 24. The activated sludge is separated into air and the majority of the dried sludge is converted into circulating dried sludge. The remaining dried sludge is carbonized and activated in the activated carbonization furnace 32 to produce activated carbon. The heated exhaust gas is heated by exchanging heat with the cyclone 24, and the heated gas is supplied to the crusher 20 to exhaust the exhaust gas from the activated carbonization furnace 32 which has exchanged heat with a part of the dried exhaust gas from the cyclone 24.
The remaining portion of the dried exhaust gas is supplied to a scrubber 60 of a washing type, washed with water and dehumidified, and then introduced into an activated carbonizing furnace 32 to thermally decompose odor components in the gas.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、下水汚泥等の汚泥
を気流乾燥機によって乾燥させ、得られた粉体状の乾燥
汚泥を活性炭化炉で炭化・賦活処理して吸着性能の高い
活性炭化物を製造するとともに、活性炭化炉からの排ガ
スの廃熱を気流乾燥の熱源として利用し、さらに、気流
乾燥排ガスを活性炭化炉に導入して乾燥排ガス中の臭気
を熱分解するようにした汚泥の炭化処理方法及び装置に
関するものである。
[0001] The present invention relates to activated carbon having high adsorption performance by drying sludge such as sewage sludge by a flash dryer and carbonizing and activating the obtained powdery dried sludge in an activated carbonizing furnace. And the waste heat of flue gas from the activated carbonization furnace is used as a heat source for flash drying, and the flash dried exhaust gas is introduced into the activated carbonization furnace to thermally decompose the odor in the dried exhaust gas. The present invention relates to a carbonization method and apparatus.

【0002】[0002]

【従来の技術】従来から、下水汚泥等の汚泥の処理方法
として、汚泥を乾燥させ、ついで、炭化・賦活処理して
炭化物を製造し、この炭化物を吸着剤等として利用する
ことが行われている。しかし、従来技術では、得られる
炭化物の吸着剤としての能力が低いために、活性炭の代
用品としての用途を期待することはできない。
2. Description of the Related Art Conventionally, as a method of treating sludge such as sewage sludge, sludge is dried, then carbonized and activated to produce a carbide, and this carbide is used as an adsorbent or the like. I have. However, in the prior art, use of the obtained carbon as a substitute for activated carbon cannot be expected due to the low ability of the obtained carbide as an adsorbent.

【0003】また、従来の汚泥の炭化処理においては、
特開平7−242408号公報に記載されているよう
に、水処理に伴って得られる脱水汚泥(脱水ケーキ)
を、そのままあるいは乾燥した後、成型あるいは造粒し
た上で炭化処理する方法が知られている。上記のような
方法で得られた炭化物の吸着剤としての利用は、充填塔
式の活性炭吸着脱臭装置における粒状活性炭の代替とな
るものであった。
[0003] In the conventional sludge carbonization treatment,
Dewatered sludge (dewatered cake) obtained with water treatment as described in JP-A-7-242408
There is known a method of subjecting it to carbonization treatment as it is or after drying it, followed by molding or granulation. The use of the carbide obtained by the above method as an adsorbent has been an alternative to granular activated carbon in a packed tower activated carbon adsorption and deodorization apparatus.

【0004】[0004]

【発明が解決しようとする課題】下水汚泥等の汚泥から
活性炭の代用品となり得る吸着能力の高い炭化物を製造
するためには、粒径の小さい粉体状の乾燥汚泥を製造し
て、炭化処理で得られる炭化物の粒径を小さくし、炭化
物を賦活して吸着能力を高めるのに必要な反応表面積を
多く確保する必要がある。また、乾燥汚泥の炭化・賦活
処理においては、炭化処理の前段で発生した水蒸気及び
炭化処理で発生した炭酸ガスを賦活に利用できる流れを
作り出して、炭化物の賦活反応を効率的に行い吸着性能
を向上させる必要がある。
SUMMARY OF THE INVENTION In order to produce carbide having a high adsorption capacity, which can be used as a substitute for activated carbon, from sludge such as sewage sludge, powdery dry sludge having a small particle size is produced and carbonized. It is necessary to reduce the particle size of the carbide obtained in the above and to secure a large reaction surface area necessary for activating the carbide and increasing the adsorption capacity. In addition, in the carbonization and activation treatment of dry sludge, a stream that can be used to activate the steam generated in the previous stage of the carbonization treatment and the carbon dioxide gas generated in the carbonization treatment is created, and the activation reaction of the carbide is efficiently performed to improve the adsorption performance. Need to improve.

【0005】本発明は上記の諸点に鑑みなされたもの
で、本発明の目的は、下水汚泥等の汚泥を気流乾燥機に
よって乾燥させ、得られた粉体状の乾燥汚泥を活性炭化
炉で炭化・賦活処理することにより、吸着性能の高い活
性炭化物を製造することができる汚泥の炭化処理方法及
び装置を提供することにある。また、本発明の目的は、
気流乾燥用熱源として、活性炭化炉排ガスから熱回収し
た気流乾燥排ガス又は/及び直接活性炭化炉排ガスを利
用することができ、かつ、気流乾燥排ガスを活性炭化炉
に導入して乾燥排ガス中の臭気成分を熱分解することが
できる汚泥の炭化処理方法及び装置を提供することにあ
る。
[0005] The present invention has been made in view of the above-mentioned points, and an object of the present invention is to dry sludge such as sewage sludge by a flash dryer and to carbonize the obtained powdery dried sludge in an activated carbonization furnace. An object of the present invention is to provide a sludge carbonization method and apparatus capable of producing activated carbide having high adsorption performance by performing an activation treatment. The object of the present invention is
As a flash drying heat source, flash drying exhaust gas heat-recovered from the activated carbonization furnace exhaust gas and / or direct activated carbonization furnace exhaust gas can be used, and odors in the drying exhaust gas by introducing the flash drying exhaust gas into the activated carbonization furnace can be used. An object of the present invention is to provide a method and an apparatus for carbonizing sludge capable of thermally decomposing components.

【0006】[0006]

【課題を解決するための手段】上記の目的を達成するた
めに、本発明の汚泥の炭化処理方法は、気流乾燥装置か
らの循環乾燥汚泥に汚泥脱水ケーキを混合し、この乾燥
汚泥混合物を気流乾燥装置の解砕機で粉砕(解砕)して
熱風乾燥させ、得られた粉体状の乾燥汚泥を気流乾燥装
置の気流乾燥管でさらに熱風乾燥させた後、粉体状の乾
燥汚泥を含む気流を固気分離器に導入して粉体状の乾燥
汚泥と気流乾燥排ガスとに分離し、粉体状の乾燥汚泥の
大部分を循環乾燥汚泥として汚泥脱水ケーキと混合し、
循環を繰り返して得られた残りの粉体状の乾燥汚泥を活
性炭化装置に導入し炭化・賦活処理して活性炭化物を製
造し、固気分離器からの気流乾燥排ガスの一部を活性炭
化装置からの高温排ガスの一部と混合して気流乾燥用熱
源として気流乾燥装置の解砕機に供給し、活性炭化装置
からの高温排ガスの残部を固気分離器からの気流乾燥排
ガスの残部と熱交換して高温排ガスを冷却して排気し、
熱交換により加熱された気流乾燥排ガスの残部を活性炭
化装置に導入して乾燥排ガス中の臭気成分を熱分解する
ように構成されている(図1参照)。この場合、活性炭
化装置からの排ガスを前記の炭化・賦活処理で得られた
活性炭化物の一部とともにろ過式集塵器に導入して排ガ
ス中の有害物質を除去することができる。ろ過式集塵器
としては、例えば、バグフィルタ、セラミックフィルタ
等が挙げられ、ろ過式集塵器の代わりに、電気集塵機等
を用いることも可能である。また、固気分離器として
は、例えば、サイクロン、バグフィルタ、マルチサイク
ロン等が挙げられる。
In order to achieve the above object, a method for carbonizing sludge according to the present invention comprises mixing a dewatered sludge cake with circulating dried sludge from a flash drying apparatus, and subjecting the dried sludge mixture to air flow. Pulverized (crushed) with a crusher of a drying device and dried with hot air, and the obtained powdery dried sludge is further dried with hot air in a flash drying tube of a flash drying device, and contains powdery dried sludge. The air stream is introduced into the solid-gas separator to separate the powdery dry sludge and the flash drying exhaust gas, and most of the powdery dry sludge is mixed with the sludge dewatering cake as circulating dry sludge,
The remaining powdery dry sludge obtained by repeating the circulation is introduced into an activated carbonization device, where it is activated and carbonized to produce activated carbide, and a portion of the gas-flow dried exhaust gas from the solid-gas separator is activated carbonized. Mixed with a part of the high-temperature exhaust gas from the furnace and supplied as a heat source for flash-drying to the crusher of the flash dryer, where the remaining high-temperature exhaust gas from the activated carbonizer is exchanged with the remaining flash-dry exhaust gas from the solid-gas separator. To cool and exhaust the hot exhaust gas,
The rest of the flash dried exhaust gas heated by heat exchange is introduced into the activated carbonization device to thermally decompose odor components in the dried exhaust gas (see FIG. 1). In this case, it is possible to remove the harmful substances in the exhaust gas by introducing the exhaust gas from the activated carbon device together with a part of the activated carbon obtained by the above-mentioned carbonization and activation treatment into a filtration dust collector. Examples of the filter-type dust collector include a bag filter and a ceramic filter, and an electric dust collector can be used instead of the filter-type dust collector. Examples of the solid-gas separator include a cyclone, a bag filter, and a multicyclone.

【0007】また、本発明の方法は、気流乾燥装置から
の循環乾燥汚泥に汚泥脱水ケーキを混合し、この乾燥汚
泥混合物を気流乾燥装置の解砕機で粉砕(解砕)して熱
風乾燥させ、得られた粉体状の乾燥汚泥を気流乾燥装置
の気流乾燥管でさらに熱風乾燥させた後、粉体状の乾燥
汚泥を含む気流を固気分離器に導入して粉体状の乾燥汚
泥と乾燥過程で発生した水蒸気を含む気流乾燥排ガスと
に分離し、粉体状の乾燥汚泥の大部分を循環乾燥汚泥と
して汚泥脱水ケーキと混合し、循環を繰り返して得られ
た残りの粉体状の乾燥汚泥を活性炭化装置に導入し炭化
・賦活処理して活性炭化物を製造し、固気分離器からの
気流乾燥排ガスの一部を活性炭化装置からの高温排ガス
の一部と混合して気流乾燥用熱源として気流乾燥装置の
解砕機に供給し、活性炭化装置からの高温排ガスの残部
を固気分離器からの気流乾燥排ガスの残部と熱交換して
高温排ガスを冷却して排気し、熱交換により加熱された
水蒸気を含む気流乾燥排ガスの残部を水洗式のスクラバ
ーに供給して水洗し除湿した後、活性炭化装置に導入し
て乾燥排ガス中の臭気成分を熱分解することを特徴とし
ている(図2参照)。この場合、活性炭化装置からの排
ガスを前記の炭化・賦活処理で得られた活性炭化物の一
部とともにろ過式集塵器に導入して排ガス中の有害物質
を除去することができる。
In the method of the present invention, the sludge dewatered cake is mixed with the circulating dried sludge from the flash drying device, and the dried sludge mixture is pulverized (crushed) by a pulverizer of the flash drying device and dried with hot air. After the obtained powdery dried sludge is further dried with hot air in a flash drying tube of a flash drying device, an airflow containing the powdery dry sludge is introduced into a solid-gas separator to form a powdery dry sludge. It is separated into flash drying exhaust gas containing water vapor generated in the drying process, and most of the powdery dry sludge is mixed with the sludge dewatering cake as circulating dry sludge, and the remaining powdery The dried sludge is introduced into the activated carbonization device and carbonized and activated to produce activated carbide.Part of the flash dried exhaust gas from the solid-gas separator is mixed with part of the high temperature exhaust gas from the activated carbon device to flash dry. To the crusher of the flash dryer as heat source for The high-temperature exhaust gas from the carbonized device is heat-exchanged with the remainder of the flash drying exhaust gas from the solid-gas separator to cool and exhaust the high-temperature exhaust gas, and the flash drying exhaust gas containing steam heated by the heat exchange is removed. It is characterized in that it is supplied to a washing scrubber, washed with water and dehumidified, and then introduced into an activated carbonization device to thermally decompose odor components in the dried exhaust gas (see FIG. 2). In this case, it is possible to remove the harmful substances in the exhaust gas by introducing the exhaust gas from the activated carbon device together with a part of the activated carbon obtained by the above-mentioned carbonization and activation treatment into a filtration dust collector.

【0008】また、本発明の方法は、気流乾燥装置から
の循環乾燥汚泥に汚泥脱水ケーキを混合し、この乾燥汚
泥混合物を気流乾燥装置の解砕機で粉砕(解砕)して熱
風乾燥させ、得られた粉体状の乾燥汚泥を気流乾燥装置
の気流乾燥管でさらに熱風乾燥させた後、粉体状の乾燥
汚泥を含む気流を固気分離器に導入して粉体状の乾燥汚
泥と気流乾燥排ガスとに分離し、粉体状の乾燥汚泥の大
部分を循環乾燥汚泥として汚泥脱水ケーキと混合し、循
環を繰り返して得られた残りの粉体状の乾燥汚泥を活性
炭化装置に導入し炭化・賦活処理して活性炭化物を製造
し、固気分離器からの気流乾燥排ガスの一部を活性炭化
装置からの高温排ガスと熱交換して気流乾燥排ガスを加
熱し、この加熱気体を気流乾燥用熱源として気流乾燥装
置の解砕機に供給し、固気分離器からの気流乾燥排ガス
の一部と熱交換して冷却された活性炭化装置からの排ガ
スを排気し、固気分離器からの気流乾燥排ガスの残部を
活性炭化装置に導入して乾燥排ガス中の臭気成分を熱分
解することを特徴としている(図3参照)。この場合、
活性炭化装置からの排ガスを前記の炭化・賦活処理で得
られた活性炭化物の一部とともにろ過式集塵器に導入し
て排ガス中の有害物質を除去することができる。
In the method of the present invention, the circulating dried sludge from the flash drying apparatus is mixed with a sludge dewatered cake, and the dried sludge mixture is pulverized (crushed) by a pulverizer of the flash drying apparatus and dried with hot air. After the obtained powdery dried sludge is further dried with hot air in a flash drying tube of a flash drying device, an airflow containing the powdery dry sludge is introduced into a solid-gas separator to form a powdery dry sludge. It is separated into flash drying exhaust gas and most of the powdery dry sludge is mixed with the sludge dewatering cake as circulating dry sludge, and the remaining powdery dry sludge obtained by repeating the circulation is introduced into the activated carbonization device. Activated carbide is produced by carbonization and activation treatment, and part of the flash dried exhaust gas from the solid-gas separator is exchanged with high temperature exhaust gas from the activated carbonizer to heat the flash dried exhaust gas. Supplied to the crusher of the flash dryer as a heat source for drying Exhaust gas from the activated carbonization device cooled by heat exchange with a part of the flash drying exhaust gas from the solid-gas separator, and the remaining portion of the flash drying exhaust gas from the solid-gas separator is introduced into the activated carbonization device. It is characterized by thermally decomposing odor components in the dried exhaust gas (see FIG. 3). in this case,
Exhaust gas from the activated carbonization device can be introduced into a filter-type dust collector together with a part of the activated carbide obtained by the above-mentioned carbonization and activation treatment to remove harmful substances in the exhaust gas.

【0009】また、本発明の方法は、気流乾燥装置から
の循環乾燥汚泥に汚泥脱水ケーキを混合し、この乾燥汚
泥混合物を気流乾燥装置の解砕機で粉砕(解砕)して熱
風乾燥させ、得られた粉体状の乾燥汚泥を気流乾燥装置
の気流乾燥管でさらに熱風乾燥させた後、粉体状の乾燥
汚泥を含む気流を固気分離器に導入して粉体状の乾燥汚
泥と乾燥過程で発生した水蒸気を含む気流乾燥排ガスと
に分離し、粉体状の乾燥汚泥の大部分を循環乾燥汚泥と
して汚泥脱水ケーキと混合し、循環を繰り返して得られ
た残りの粉体状の乾燥汚泥を活性炭化装置に導入し炭化
・賦活処理して活性炭化物を製造し、固気分離器からの
気流乾燥排ガスの一部を活性炭化装置からの高温排ガス
と熱交換して気流乾燥排ガスを加熱し、この加熱気体を
気流乾燥用熱源として気流乾燥装置の解砕機に供給し、
固気分離器からの気流乾燥排ガスの一部と熱交換して冷
却された活性炭化装置からの排ガスを排気し、固気分離
器からの水蒸気を含む気流乾燥排ガスの残部を水洗式の
スクラバーに供給して水洗し除湿した後、活性炭化装置
に導入して乾燥排ガス中の臭気成分を熱分解することを
特徴としている(図4参照)。この場合、活性炭化装置
からの排ガスを前記の炭化・賦活処理で得られた活性炭
化物の一部とともにろ過式集塵器に導入して排ガス中の
有害物質を除去することができる。
In the method of the present invention, the sludge dewatered cake is mixed with the circulating dried sludge from the flash drying apparatus, and the dried sludge mixture is pulverized (crushed) by a pulverizer of the flash drying apparatus and dried with hot air. After the obtained powdery dried sludge is further dried with hot air in a flash drying tube of a flash drying device, an airflow containing the powdery dry sludge is introduced into a solid-gas separator to form a powdery dry sludge. It is separated into flash drying exhaust gas containing water vapor generated in the drying process, and most of the powdery dry sludge is mixed with the sludge dewatering cake as circulating dry sludge, and the remaining powdery The dried sludge is introduced into the activated carbonization device, and carbonized and activated to produce activated carbide, and a part of the flash dried exhaust gas from the solid-gas separator is heat-exchanged with the high temperature exhaust gas from the activated carbon device to produce the flash dried exhaust gas. Heat the heated gas and use it as a flash drying heat source. Supplied to disintegrator flash drying apparatus Te,
Exhaust gas from the activated carbonizer cooled by heat exchange with a part of the flash drying exhaust gas from the solid-gas separator is exhausted, and the remaining flash drying exhaust gas containing water vapor from the solid-gas separator is converted into a water-washing scrubber. After supplying, washing and dehumidifying, it is introduced into an activated carbonization device to thermally decompose odor components in the dried exhaust gas (see FIG. 4). In this case, it is possible to remove the harmful substances in the exhaust gas by introducing the exhaust gas from the activated carbon device together with a part of the activated carbon obtained by the above-mentioned carbonization and activation treatment into a filtration dust collector.

【0010】また、本発明の方法は、気流乾燥装置から
の循環乾燥汚泥に汚泥脱水ケーキを混合し、この乾燥汚
泥混合物を気流乾燥装置の解砕機で粉砕(解砕)して熱
風乾燥させ、得られた粉体状の乾燥汚泥を気流乾燥装置
の気流乾燥管でさらに熱風乾燥させた後、粉体状の乾燥
汚泥を含む気流を固気分離器に導入して粉体状の乾燥汚
泥と気流乾燥排ガスとに分離し、粉体状の乾燥汚泥の大
部分を循環乾燥汚泥として汚泥脱水ケーキと混合し、循
環を繰り返して得られた残りの粉体状の乾燥汚泥を活性
炭化装置に導入し炭化・賦活処理して活性炭化物を製造
し、固気分離器からの気流乾燥排ガスの一部を活性炭化
装置からの高温排ガスと熱交換して気流乾燥排ガスを加
熱し、この加熱気体を気流乾燥用熱源として気流乾燥装
置の解砕機に供給し、固気分離器からの気流乾燥排ガス
の一部と熱交換して冷却された活性炭化装置からの排ガ
スの一部を排気し、固気分離器からの気流乾燥排ガスの
残部を活性炭化装置からの排ガスの残部とともに活性炭
化装置に導入して排ガス中の臭気成分を熱分解すること
を特徴としている(図5参照)。この場合、活性炭化装
置からの排ガスの一部を前記の炭化・賦活処理で得られ
た活性炭化物の一部とともにろ過式集塵器に導入して排
ガス中の有害物質を除去することができる。
In the method of the present invention, the sludge dewatered cake is mixed with the circulating dried sludge from the flash drying apparatus, and the dried sludge mixture is pulverized (crushed) by a pulverizer of the flash drying apparatus and dried with hot air. After the obtained powdery dried sludge is further dried with hot air in a flash drying tube of a flash drying device, an airflow containing the powdery dry sludge is introduced into a solid-gas separator to form a powdery dry sludge. It is separated into flash drying exhaust gas and most of the powdery dry sludge is mixed with the sludge dewatering cake as circulating dry sludge, and the remaining powdery dry sludge obtained by repeating the circulation is introduced into the activated carbonization device. Activated carbide is produced by carbonization and activation treatment, and part of the flash dried exhaust gas from the solid-gas separator is exchanged with high temperature exhaust gas from the activated carbonizer to heat the flash dried exhaust gas. Supplied to the crusher of the flash dryer as a heat source for drying A part of the flue gas from the activated carbonizer cooled by exchanging heat with a part of the flue gas from the solid-gas separator is exhausted, and the remaining part of the flue gas from the solid-gas separator is discharged from the activated carbon device. It is characterized in that it is introduced into an activated carbonizer together with the rest of the exhaust gas to thermally decompose odor components in the exhaust gas (see FIG. 5). In this case, a part of the exhaust gas from the activated carbonization device can be introduced into the filter-type dust collector together with a part of the activated carbide obtained by the above-mentioned carbonization and activation treatment, thereby removing harmful substances in the exhaust gas.

【0011】また、本発明の方法は、気流乾燥装置から
の循環乾燥汚泥に汚泥脱水ケーキを混合し、この乾燥汚
泥混合物を気流乾燥装置の解砕機で粉砕(解砕)して熱
風乾燥させ、得られた粉体状の乾燥汚泥を気流乾燥装置
の気流乾燥管でさらに熱風乾燥させた後、粉体状の乾燥
汚泥を含む気流を固気分離器に導入して粉体状の乾燥汚
泥と乾燥過程で発生した水蒸気を含む気流乾燥排ガスと
に分離し、粉体状の乾燥汚泥の大部分を循環乾燥汚泥と
して汚泥脱水ケーキと混合し、循環を繰り返して得られ
た残りの粉体状の乾燥汚泥を活性炭化装置に導入し炭化
・賦活処理して活性炭化物を製造し、固気分離器からの
気流乾燥排ガスの一部を活性炭化装置からの高温排ガス
と熱交換して気流乾燥排ガスを加熱し、この加熱気体を
気流乾燥用熱源として気流乾燥装置の解砕機に供給し、
固気分離器からの気流乾燥排ガスの一部と熱交換して冷
却された活性炭化装置からの排ガスの一部を排気し、固
気分離器からの水蒸気を含む気流乾燥排ガスの残部を水
洗式のスクラバーに供給して水洗し除湿した後、この乾
燥排ガスを活性炭化装置からの排ガスの残部とともに活
性炭化装置に導入して排ガス中の臭気成分を熱分解する
ことを特徴としている(図6参照)。この場合、活性炭
化装置からの排ガスの一部を前記の炭化・賦活処理で得
られた活性炭化物の一部とともにろ過式集塵器に導入し
て排ガス中の有害物質を除去することができる。
In the method of the present invention, the sludge dewatered cake is mixed with the circulating dried sludge from the flash drying device, and the dried sludge mixture is pulverized (crushed) by a pulverizer of the flash drying device and dried with hot air. After the obtained powdery dried sludge is further dried with hot air in a flash drying tube of a flash drying device, an airflow containing the powdery dry sludge is introduced into a solid-gas separator to form a powdery dry sludge. It is separated into flash drying exhaust gas containing water vapor generated in the drying process, and most of the powdery dry sludge is mixed with the sludge dewatering cake as circulating dry sludge, and the remaining powdery The dried sludge is introduced into the activated carbonization device, and carbonized and activated to produce activated carbide, and a part of the flash dried exhaust gas from the solid-gas separator is heat-exchanged with the high temperature exhaust gas from the activated carbon device to produce the flash dried exhaust gas. Heat the heated gas and use it as a flash drying heat source. Supplied to disintegrator flash drying apparatus Te,
Part of the flue gas from the activated carbonizer cooled by heat exchange with part of the flash drying flue gas from the solid-gas separator is exhausted, and the remainder of the flash drying flue gas containing steam from the solid-gas separator is washed with water. After being supplied to a scrubber for washing and dehumidification, the dried exhaust gas is introduced into the activated carbonization device together with the rest of the exhaust gas from the activated carbonization device to thermally decompose odor components in the exhaust gas (see FIG. 6). ). In this case, a part of the exhaust gas from the activated carbonization device can be introduced into the filter-type dust collector together with a part of the activated carbide obtained by the above-mentioned carbonization and activation treatment, thereby removing harmful substances in the exhaust gas.

【0012】また、これらの本発明の方法において、熱
交換により冷却された活性炭化装置からの排ガスの少な
くとも一部を、排気する前に、炭化・賦活処理で得られ
た活性炭化物の一部及び/又はアルカリ剤とともにろ過
式集塵器に導入して排ガス中の有害物質を除去すること
が好ましい(図1〜図6参照)。また、これらの本発明
の方法において、活性炭化物の原料となる粉体状の乾燥
汚泥を、間接加熱方式である活性炭化装置に導入して、
乾燥汚泥中の水分を炭化処理の前段で蒸発させ、つい
で、乾燥汚泥を熱分解して炭化処理し、炭化された汚泥
を、炭化処理の前段で発生した水蒸気及び熱分解時に発
生する炭酸ガスにより賦活処理して活性炭化物を製造す
ることが好ましい。
Further, in the method of the present invention, at least a part of the exhaust gas from the activated carbonization device cooled by the heat exchange is exhausted before exhausting at least a part of the activated carbide obtained by the carbonization and activation treatment. It is preferable to remove the harmful substances in the exhaust gas by introducing into a filtration type dust collector together with an alkali agent (see FIGS. 1 to 6). Further, in these methods of the present invention, the powdery dry sludge as a raw material of the activated carbide is introduced into an activated carbonization apparatus of an indirect heating system,
The moisture in the dried sludge is evaporated before the carbonization treatment, and then the dried sludge is thermally decomposed and carbonized, and the carbonized sludge is removed by the steam generated in the previous stage of the carbonization treatment and the carbon dioxide gas generated during the pyrolysis. Preferably, the activated carbon is produced by an activation treatment.

【0013】本発明の汚泥の炭化処理装置は、固気分離
器で固気分離されて循環する粉体状の乾燥汚泥を搬送
し、この粉体状の乾燥汚泥に汚泥脱水ケーキを混合して
さらに搬送し、この乾燥汚泥混合物を気流乾燥装置の解
砕機に供給するための混合供給手段と、混合供給手段で
搬送され循環される粉体状の乾燥汚泥の一部を取り出し
て貯留するための混合供給手段上部に連通して設けられ
た乾燥粉体ホッパと、混合供給手段からの乾燥汚泥混合
物とともに、気流乾燥用熱源として活性炭化装置からの
高温排ガスの一部を固気分離器からの気流乾燥排ガスの
一部と混合して解砕機に供給し、解砕機で乾燥汚泥混合
物を粉砕(解砕)して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥管でさらに熱風乾燥させる気流乾燥
装置と、気流乾燥装置からの粉体状の乾燥汚泥を含む気
流を導入して粉体状の乾燥汚泥と気流乾燥排ガスとに分
離するための固気分離器と、乾燥粉体ホッパから取り出
された粉体状の乾燥汚泥を炭化・賦活処理して活性炭化
物を製造するための活性炭化装置と、気流乾燥用熱源と
して高温排ガスの一部を解砕機に供給した活性炭化装置
からの高温排ガスの残部を固気分離器からの気流乾燥排
ガスの残部と熱交換するための熱交換器と、熱交換器で
加熱された気流乾燥排ガスの残部を熱分解脱臭するため
に活性炭化装置に導入するための気流乾燥排ガス導入手
段とを包含することを特徴としている(図1参照)。
The sludge carbonization apparatus of the present invention conveys powdery dry sludge circulated after being separated into solid and gas by a solid-gas separator, and mixes the powdery dry sludge with a sludge dewatering cake. Further conveying and mixing and supplying means for supplying the dried sludge mixture to the crusher of the flash drying device, and for extracting and storing a part of the powdery dried sludge which is conveyed and circulated by the mixing and supplying means. A part of the high temperature exhaust gas from the activated carbonization device as a heat source for flash drying together with the dry powder hopper provided in communication with the upper part of the mixing and feeding means and the dry sludge mixture from the mixing and feeding means is supplied to the airflow from the solid-gas separator. A part of the dried exhaust gas is mixed and supplied to a crusher, and the dried sludge mixture is crushed (crushed) by the crusher and dried with hot air, and the obtained powdery dried sludge is further dried with hot air by a flash drying tube. Flash drying device and flash drying device A solid-gas separator for introducing an air stream containing powdery dry sludge from the tank into powdery dry sludge and flash drying exhaust gas, and drying of the powdery form taken out from the dry powder hopper An activated carbonizer for producing activated carbide by carbonizing and activating sludge, and a solid-gas separator for the remaining high-temperature exhaust gas from the activated carbonizer that supplied part of the high-temperature exhaust gas to the crusher as a heat source for flash drying Heat exchanger for heat exchange with the rest of the flash drying exhaust gas from the furnace, and means for introducing the flash drying exhaust gas to the activated carbonization device to thermally deodorize the remaining flash drying exhaust gas heated by the heat exchanger (See FIG. 1).

【0014】また、本発明の装置は、固気分離器で固気
分離されて循環する粉体状の乾燥汚泥を搬送し、この粉
体状の乾燥汚泥に汚泥脱水ケーキを混合してさらに搬送
し、この乾燥汚泥混合物を気流乾燥装置の解砕機に供給
するための混合供給手段と、混合供給手段で搬送され循
環される粉体状の乾燥汚泥の一部を取り出して貯留する
ための混合供給手段上部に連通して設けられた乾燥粉体
ホッパと、混合供給手段からの乾燥汚泥混合物ととも
に、気流乾燥用熱源として活性炭化装置からの高温排ガ
スの一部を固気分離器からの気流乾燥排ガスの一部と混
合して解砕機に供給し、解砕機で乾燥汚泥混合物を粉砕
(解砕)して熱風乾燥させ、得られた粉体状の乾燥汚泥
を気流乾燥管でさらに熱風乾燥させる気流乾燥装置と、
気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気を含
む気流乾燥排ガスとに分離するための固気分離器と、乾
燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭化
・賦活処理して活性炭化物を製造するための活性炭化装
置と、気流乾燥用熱源として高温排ガスの一部を解砕機
に供給した活性炭化装置からの高温排ガスの残部を固気
分離器からの気流乾燥排ガスの残部と熱交換するための
熱交換器と、熱交換器で加熱された水蒸気を含む気流乾
燥排ガスの残部を供給して水洗し除湿するための水洗式
のスクラバーと、水洗式のスクラバーからの乾燥排ガス
を熱分解脱臭するために活性炭化装置に導入するための
気流乾燥排ガス導入手段とを包含することを特徴として
いる(図2参照)。
Further, the apparatus of the present invention conveys powdery dry sludge which is separated into solid and gas by a solid-gas separator and circulates, mixes the powdery dry sludge with a sludge dewatering cake and further conveys it. A mixing and supplying means for supplying the dried sludge mixture to a crusher of a flash drying apparatus; and a mixing and supplying means for extracting and storing a part of the powdery dried sludge conveyed and circulated by the mixing and supplying means. A part of the hot exhaust gas from the activated carbonization device as a heat source for flash drying together with the dry powder hopper provided in communication with the upper part of the means and the dry sludge mixture from the mixing and feeding means Of the dried sludge mixture is crushed (crushed) by a crusher and dried with hot air, and the resulting powdery dried sludge is further dried with hot air by a flash dryer. Drying equipment;
A solid-gas separator for introducing an air flow containing powdery dry sludge from a flash drying device to separate the powdery dry sludge and a flash drying exhaust gas containing steam generated in the drying process; Activated carbonizer for producing activated carbide by carbonizing and activating powdery dried sludge taken out from body hopper, and activated carbonizer that supplies part of high-temperature exhaust gas to crusher as heat source for flash drying A heat exchanger for exchanging heat with the rest of the flash exhaust gas from the solid-gas separator for heat exchange with the rest of the high-temperature exhaust gas from the solid-gas separator, and supplying and washing the water with the remainder of the flash exhaust gas containing steam heated by the heat exchanger It is characterized by including a flush scrubber for dehumidifying, and a flash drying flue gas introducing means for introducing dry flue gas from the flush scrubber into an activated carbonization device for thermal decomposition and deodorization (FIG. 2). reference)

【0015】また、本発明の装置は、固気分離器で固気
分離されて循環する粉体状の乾燥汚泥を搬送し、この粉
体状の乾燥汚泥に汚泥脱水ケーキを混合してさらに搬送
し、この乾燥汚泥混合物を気流乾燥装置の解砕機に供給
するための混合供給手段と、混合供給手段で搬送され循
環される粉体状の乾燥汚泥の一部を取り出して貯留する
ための混合供給手段上部に連通して設けられた乾燥粉体
ホッパと、混合供給手段からの乾燥汚泥混合物ととも
に、気流乾燥用熱源として固気分離器からの気流乾燥排
ガスの一部を熱交換器で活性炭化装置からの高温排ガス
と熱交換し加熱して解砕機に供給し、解砕機で乾燥汚泥
混合物を粉砕(解砕)して熱風乾燥させ、得られた粉体
状の乾燥汚泥を気流乾燥管でさらに熱風乾燥させる気流
乾燥装置と、気流乾燥装置からの粉体状の乾燥汚泥を含
む気流を導入して粉体状の乾燥汚泥と気流乾燥排ガスと
に分離するための固気分離器と、乾燥粉体ホッパから取
り出された粉体状の乾燥汚泥を炭化・賦活処理して活性
炭化物を製造するための活性炭化装置と、活性炭化装置
からの高温排ガスを固気分離器からの気流乾燥排ガスの
一部と熱交換するための熱交換器と、固気分離器からの
気流乾燥排ガスの残部を熱分解脱臭するために活性炭化
装置に導入するための気流乾燥排ガス導入手段とを包含
することを特徴としている(図3参照)。
Further, the apparatus of the present invention conveys powdery dry sludge which is separated into solid and gas by a solid-gas separator and circulates, mixes the powdery dry sludge with a sludge dewatering cake, and further conveys it. A mixing and supplying means for supplying the dried sludge mixture to a crusher of a flash drying apparatus; and a mixing and supplying means for extracting and storing a part of the powdery dried sludge conveyed and circulated by the mixing and supplying means. A dry powder hopper provided in communication with the upper part of the means, together with the dry sludge mixture from the mixing and supply means, and a part of the flash drying exhaust gas from the solid-gas separator as a heat source for flash drying is activated carbonized by a heat exchanger. Heat exchange with the high temperature exhaust gas from the furnace, heat it and supply it to the crusher, pulverize (crush) the dried sludge mixture with the crusher and dry it with hot air, and further dry the obtained powdery dry sludge with a flash drying tube. Flash drying device for hot air drying and flash drying A solid-gas separator for introducing an air stream containing powdery dry sludge from the device to separate the powdery dry sludge and flash-dry exhaust gas, and the powdery gas extracted from the dry powder hopper An activated carbonizer for producing activated carbide by carbonizing and activating dry sludge, and a heat exchanger for exchanging heat from high-temperature exhaust gas from the activated carbonizer with a part of flash drying exhaust gas from a solid-gas separator. And a means for introducing a flash drying exhaust gas for introducing the remaining flash gas drying exhaust gas from the solid-gas separator into the activated carbonization device for thermal decomposition and deodorization (see FIG. 3).

【0016】また、本発明の装置は、固気分離器で固気
分離されて循環する粉体状の乾燥汚泥を搬送し、この粉
体状の乾燥汚泥に汚泥脱水ケーキを混合してさらに搬送
し、この乾燥汚泥混合物を気流乾燥装置の解砕機に供給
するための混合供給手段と、混合供給手段で搬送され循
環される粉体状の乾燥汚泥の一部を取り出して貯留する
ための混合供給手段上部に連通して設けられた乾燥粉体
ホッパと、混合供給手段からの乾燥汚泥混合物ととも
に、気流乾燥用熱源として固気分離器からの気流乾燥排
ガスの一部を熱交換器で活性炭化装置からの高温排ガス
と熱交換し加熱して解砕機に供給し、解砕機で乾燥汚泥
混合物を粉砕(解砕)して熱風乾燥させ、得られた粉体
状の乾燥汚泥を気流乾燥管でさらに熱風乾燥させる気流
乾燥装置と、気流乾燥装置からの粉体状の乾燥汚泥を含
む気流を導入して粉体状の乾燥汚泥と乾燥過程で発生し
た水蒸気を含む気流乾燥排ガスとに分離するための固気
分離器と、乾燥粉体ホッパから取り出された粉体状の乾
燥汚泥を炭化・賦活処理して活性炭化物を製造するため
の活性炭化装置と、活性炭化装置からの高温排ガスを固
気分離器からの気流乾燥排ガスの一部と熱交換するため
の熱交換器と、固気分離器からの水蒸気を含む気流乾燥
排ガスの残部を供給して水洗し除湿するための水洗式の
スクラバーと、水洗式のスクラバーからの乾燥排ガスを
熱分解脱臭するために活性炭化装置に導入するための気
流乾燥排ガス導入手段とを包含することを特徴としてい
る(図4参照)。
Further, the apparatus of the present invention conveys powdery dry sludge which is separated into solid and gas by a solid-gas separator and circulates, mixes the powdery dry sludge with a sludge dewatering cake, and further conveys it. A mixing and supplying means for supplying the dried sludge mixture to a crusher of a flash drying apparatus; and a mixing and supplying means for extracting and storing a part of the powdery dried sludge conveyed and circulated by the mixing and supplying means. A dry powder hopper provided in communication with the upper part of the means, together with the dry sludge mixture from the mixing and supply means, and a part of the flash drying exhaust gas from the solid-gas separator as a heat source for flash drying is activated carbonized by a heat exchanger. Heat exchange with the high temperature exhaust gas from the furnace, heat it and supply it to the crusher, pulverize (crush) the dried sludge mixture with the crusher and dry it with hot air, and further dry the obtained powdery dry sludge with a flash drying tube. Flash drying device for hot air drying and flash drying A solid-gas separator for introducing an air stream containing powdery dry sludge from the device into a powdery dry sludge and a gas stream drying exhaust gas containing steam generated in the drying process, and a dry powder hopper Activated carbonizer for producing activated carbide by carbonizing and activating the powdery dried sludge taken out from the plant, and a portion of the high-temperature exhaust gas from the activated carbonizer to the flash drying exhaust gas from the solid-gas separator. A heat exchanger for heat exchange, a flush scrubber for supplying the remainder of the flash drying exhaust gas containing water vapor from the solid-gas separator to wash and dehumidify the water, and heat the drying exhaust gas from the flush scrubber to heat. A flash drying exhaust gas introduction means for introducing into a activated carbonization device for decomposing and deodorizing is provided (see FIG. 4).

【0017】また、本発明の装置は、固気分離器で固気
分離されて循環する粉体状の乾燥汚泥を搬送し、この粉
体状の乾燥汚泥に汚泥脱水ケーキを混合してさらに搬送
し、この乾燥汚泥混合物を気流乾燥装置の解砕機に供給
するための混合供給手段と、混合供給手段で搬送され循
環される粉体状の乾燥汚泥の一部を取り出して貯留する
ための混合供給手段上部に連通して設けられた乾燥粉体
ホッパと、混合供給手段からの乾燥汚泥混合物ととも
に、気流乾燥用熱源として固気分離器からの気流乾燥排
ガスの一部を熱交換器で活性炭化装置からの高温排ガス
と熱交換し加熱して解砕機に供給し、解砕機で乾燥汚泥
混合物を粉砕(解砕)して熱風乾燥させ、得られた粉体
状の乾燥汚泥を気流乾燥管でさらに熱風乾燥させる気流
乾燥装置と、気流乾燥装置からの粉体状の乾燥汚泥を含
む気流を導入して粉体状の乾燥汚泥と気流乾燥排ガスと
に分離するための固気分離器と、乾燥粉体ホッパから取
り出された粉体状の乾燥汚泥を炭化・賦活処理して活性
炭化物を製造するための活性炭化装置と、活性炭化装置
からの高温排ガスを固気分離器からの気流乾燥排ガスの
一部と熱交換するための熱交換器と、固気分離器からの
気流乾燥排ガスの残部を熱分解脱臭するために活性炭化
装置に導入するための排ガス導入手段と、熱交換器で冷
却された活性炭化装置からの排ガスの一部を、固気分離
器からの気流乾燥排ガスの残部とともに活性炭化装置に
導入するための活性炭化装置排ガス導入手段とを包含す
ることを特徴としている(図5参照)。
Further, the apparatus of the present invention conveys powdery dry sludge which is separated into solid and gas by a solid-gas separator and circulates, mixes the powdery dry sludge with a sludge dewatering cake, and further conveys it. A mixing and supplying means for supplying the dried sludge mixture to a crusher of a flash drying apparatus; and a mixing and supplying means for extracting and storing a part of the powdery dried sludge conveyed and circulated by the mixing and supplying means. A dry powder hopper provided in communication with the upper part of the means, together with the dry sludge mixture from the mixing and supply means, and a part of the flash drying exhaust gas from the solid-gas separator as a heat source for flash drying is activated carbonized by a heat exchanger. Heat exchange with the high temperature exhaust gas from the furnace, heat it and supply it to the crusher, pulverize (crush) the dried sludge mixture with the crusher and dry it with hot air, and further dry the obtained powdery dry sludge with a flash drying tube. Flash drying device for hot air drying and flash drying A solid-gas separator for introducing an air stream containing powdery dry sludge from the device to separate the powdery dry sludge and flash-dry exhaust gas, and the powdery gas extracted from the dry powder hopper An activated carbonizer for producing activated carbide by carbonizing and activating dry sludge, and a heat exchanger for exchanging heat from high-temperature exhaust gas from the activated carbonizer with a part of flash drying exhaust gas from a solid-gas separator. And an exhaust gas introducing means for introducing the remaining portion of the flash dried exhaust gas from the solid-gas separator into the activated carbonization device for pyrolysis and deodorization, and a part of the exhaust gas from the activated carbonization device cooled by the heat exchanger. And an active carbonization device exhaust gas introduction means for introducing the remaining portion of the flash drying exhaust gas from the solid-gas separator together with the activated carbonization device (see FIG. 5).

【0018】また、本発明の装置は、固気分離器で固気
分離されて循環する粉体状の乾燥汚泥を搬送し、この粉
体状の乾燥汚泥に汚泥脱水ケーキを混合してさらに搬送
し、この乾燥汚泥混合物を気流乾燥装置の解砕機に供給
するための混合供給手段と、混合供給手段で搬送され循
環される粉体状の乾燥汚泥の一部を取り出して貯留する
ための混合供給手段上部に連通して設けられた乾燥粉体
ホッパと、混合供給手段からの乾燥汚泥混合物ととも
に、気流乾燥用熱源として固気分離器からの気流乾燥排
ガスの一部を熱交換器で活性炭化装置からの高温排ガス
と熱交換し加熱して解砕機に供給し、解砕機で乾燥汚泥
混合物を粉砕(解砕)して熱風乾燥させ、得られた粉体
状の乾燥汚泥を気流乾燥管でさらに熱風乾燥させる気流
乾燥装置と、気流乾燥装置からの粉体状の乾燥汚泥を含
む気流を導入して粉体状の乾燥汚泥と乾燥過程で発生し
た水蒸気を含む気流乾燥排ガスとに分離するための固気
分離器と、乾燥粉体ホッパから取り出された粉体状の乾
燥汚泥を炭化・賦活処理して活性炭化物を製造するため
の活性炭化装置と、活性炭化装置からの高温排ガスを固
気分離器からの気流乾燥排ガスの一部と熱交換するため
の熱交換器と、固気分離器からの水蒸気を含む気流乾燥
排ガスの残部を供給して水洗し除湿するための水洗式の
スクラバーと、水洗式のスクラバーからの乾燥排ガスを
熱分解脱臭するために活性炭化装置に導入するための排
ガス導入手段と、熱交換器で冷却された活性炭化装置か
らの排ガスの一部を、水洗式のスクラバーで水洗・除湿
された乾燥排ガスとともに活性炭化装置に導入するため
の活性炭化装置排ガス導入手段とを包含することを特徴
としている(図6参照)。
The apparatus of the present invention conveys powdery dry sludge which is separated into solid and gas by a solid-gas separator and circulates, mixes the powdery dry sludge with a sludge dewatering cake, and further conveys it. A mixing and supplying means for supplying the dried sludge mixture to a crusher of a flash drying apparatus; and a mixing and supplying means for extracting and storing a part of the powdery dried sludge conveyed and circulated by the mixing and supplying means. A dry powder hopper provided in communication with the upper part of the means, together with the dry sludge mixture from the mixing and supply means, and a part of the flash drying exhaust gas from the solid-gas separator as a heat source for flash drying is activated carbonized by a heat exchanger. Heat exchange with the high temperature exhaust gas from the furnace, heat it and supply it to the crusher, pulverize (crush) the dried sludge mixture with the crusher and dry it with hot air, and further dry the obtained powdery dry sludge with a flash drying tube. Flash drying device for hot air drying and flash drying A solid-gas separator for introducing an air stream containing powdery dry sludge from the device into a powdery dry sludge and a gas stream drying exhaust gas containing steam generated in the drying process, and a dry powder hopper Activated carbonizer for producing activated carbide by carbonizing and activating the powdery dried sludge taken out from the plant, and a portion of the high-temperature exhaust gas from the activated carbonizer to the flash drying exhaust gas from the solid-gas separator. A heat exchanger for heat exchange, a flush scrubber for supplying the remainder of the flash drying exhaust gas containing water vapor from the solid-gas separator to wash and dehumidify the water, and heat the drying exhaust gas from the flush scrubber to heat. Exhaust gas introduction means for introduction into the activated carbonizer to decompose and deodorize, and a part of the exhaust gas from the activated carbonizer cooled by the heat exchanger together with dry exhaust gas washed and dehumidified by a washing scrubber. Costume Is characterized in that it comprises an activated carbon apparatus exhaust gas introducing means for introducing a (see FIG. 6).

【0019】上記の本発明の装置において、熱交換器で
冷却された活性炭化装置からの排ガスを排気するための
排気手段に、活性炭化装置で製造された活性炭化物の一
部を吹き込むための活性炭化物吹込手段と、アルカリ剤
を吹き込むためのアルカリ剤吹込手段とを設け、前記排
気手段に活性炭化物及びアルカリ剤が吹き込まれた排ガ
スが導入されるろ過式集塵器を接続し、ろ過式集塵器の
ろ過体上に活性炭化物及びアルカリ剤のコーティング層
を形成させて、排ガス中の有害物質を除去することが好
ましい(図1〜図6参照)。上記の本発明の装置におい
て、活性炭化装置としては、乾燥粉体ホッパから投入さ
れる粉体状の乾燥汚泥を間接加熱するようになってお
り、乾燥汚泥の移動方向の上流側が乾燥汚泥中の水分を
蒸発させるための低温の乾燥ゾーンで、乾燥汚泥の移動
方向に進むにつれて乾燥汚泥を熱分解して炭化するため
の炭化ゾーンとなり、乾燥汚泥の移動方向の下流側が乾
燥ゾーンで発生した水蒸気及び炭化ゾーンで発生した炭
酸ガスにより炭化された汚泥を賦活するための高温の賦
活ゾーンとなっている構成とすることが好ましい。
In the above-described apparatus of the present invention, the active means for injecting a part of the activated carbide produced by the activated carbonization apparatus into the exhaust means for exhausting the exhaust gas from the activated carbonization apparatus cooled by the heat exchanger. Providing a carbide blowing means and an alkali blowing means for blowing an alkali agent, and connecting a filtration type dust collector into which exhaust gas into which the activated carbide and the alkali agent have been blown is introduced to the exhaust means; It is preferable to form a coating layer of activated carbide and an alkaline agent on the filter of the vessel to remove harmful substances in the exhaust gas (see FIGS. 1 to 6). In the above-described apparatus of the present invention, the activated carbonization apparatus is configured to indirectly heat powdery dry sludge supplied from the dry powder hopper, and the upstream side in the moving direction of the dry sludge is the dry sludge. This is a low-temperature drying zone for evaporating water, and becomes a carbonization zone for thermally decomposing and carbonizing the dry sludge as it proceeds in the moving direction of the dry sludge. It is preferable to adopt a configuration in which a high-temperature activation zone for activating sludge carbonized by carbon dioxide gas generated in the carbonization zone is provided.

【0020】[0020]

【発明の実施の形態】以下、本発明の実施の形態につい
て説明するが、本発明は下記の実施の形態に何ら限定さ
れるものではなく、適宜変更して実施することができる
ものである。図1は、本発明の実施の第1形態による汚
泥の炭化処理装置を示している。本実施の形態では、ろ
過式集塵器としてバグフィルタ、固気分離器としてサイ
クロンを使用し、また、処理する汚泥として下水汚泥を
利用している。なお、下水汚泥の他に、し尿汚泥、畜産
廃棄物、各種工業排水からの廃棄物等を利用することも
可能である。図1に示すように、汚泥ホッパ(図示略)
内に貯留された下水汚泥脱水ケーキは、混合供給機10
内の混合・搬送手段12に供給され、混合供給機10の
搬送手段14により搬送された下水汚泥の循環乾燥粉体
(以下、乾燥汚泥)と混合される。ここで、汚泥脱水ケ
ーキに対する乾燥汚泥の混合比は、乾燥重量比で10〜
500倍、望ましくは、50〜200倍であり、これに
より、後述する気流乾燥機での乾燥速度を大幅に向上さ
せることができる。なお、混合・搬送手段12は、混合
機能と搬送機能とを兼ね備えた構造であり、例えば、ス
クリューフィーダ等が用いられる。また、搬送手段14
としては、混合・搬送手段12と同じ駆動軸を有するス
クリューフィーダ等が用いられる。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below, but the present invention is not limited to the following embodiments and can be implemented with appropriate modifications. FIG. 1 shows a sludge carbonization apparatus according to a first embodiment of the present invention. In the present embodiment, a bag filter is used as a filtration type dust collector, a cyclone is used as a solid-gas separator, and sewage sludge is used as sludge to be treated. In addition to the sewage sludge, it is also possible to use human waste sludge, livestock waste, waste from various industrial wastewaters, and the like. As shown in FIG. 1, a sludge hopper (not shown)
The sewage sludge dewatered cake stored in the inside of the
The sewage sludge is supplied to the mixing / transporting means 12 in the inside, and is mixed with the circulating dry powder of sewage sludge (hereinafter, dried sludge) transported by the transporting means 14 of the mixing / supplying device 10. Here, the mixing ratio of the dried sludge to the sludge dewatered cake is 10 to 10 in terms of dry weight ratio.
It is 500 times, desirably 50 to 200 times, whereby the drying speed in a flash dryer described later can be greatly improved. The mixing / transporting means 12 has a structure having both a mixing function and a transport function, and for example, a screw feeder or the like is used. Also, the transporting means 14
For example, a screw feeder having the same drive shaft as the mixing / transporting means 12 is used.

【0021】混合供給機10内で搬送手段14により搬
送される粉体状の乾燥汚泥の一部は、混合供給機10上
側に連通して設けられた乾燥粉体ホッパ16に貯留され
る。一方、上述したように、大部分の乾燥汚泥は混合・
搬送手段12により汚泥脱水ケーキと混合されてさらに
搬送される。混合・搬送手段12で搬送された乾燥汚泥
混合物は気流乾燥機18の解砕機20に導入される。解
砕機20には、後述する活性炭化炉から排出される高温
排ガスの一部をサイクロンからの乾燥排ガスと混合した
加熱気体が乾燥用熱源として導入される。解砕機20で
細かく粉砕され、熱風により乾燥された粉体状の乾燥汚
泥は、気流乾燥機18の気流乾燥管22を介して気流搬
送され、さらに熱風乾燥される。気流乾燥管22からの
粉体状の乾燥汚泥を含む気流(乾燥排ガス)は、サイク
ロン24で固気分離され、粉体状の乾燥汚泥は混合供給
機10の搬送手段14に供給される。サイクロン24で
分離された乾燥排ガスについては後述する。
A part of the powdery dry sludge conveyed by the conveying means 14 in the mixing and feeding device 10 is stored in a dry powder hopper 16 provided in communication with the upper side of the mixing and feeding device 10. On the other hand, as mentioned above, most dry sludge is mixed and
The mixture with the sludge dewatered cake is further conveyed by the conveying means 12. The dried sludge mixture transported by the mixing / transporting means 12 is introduced into a crusher 20 of a flash dryer 18. A heated gas obtained by mixing a part of the high-temperature exhaust gas discharged from the activated carbonization furnace described later with the dry exhaust gas from the cyclone is introduced into the crusher 20 as a heat source for drying. The powdery dried sludge finely pulverized by the crusher 20 and dried by hot air is transported by airflow through the airflow drying pipe 22 of the airflow dryer 18 and further hot-air dried. The airflow (dry exhaust gas) containing the powdery dry sludge from the airflow drying pipe 22 is separated into solid and gas by the cyclone 24, and the powdery dry sludge is supplied to the conveying means 14 of the mixing and feeding device 10. The drying exhaust gas separated by the cyclone 24 will be described later.

【0022】前述の乾燥粉体ホッパ16に貯留された粉
体状の乾燥汚泥は、スクリューフィーダ等の乾燥粉体搬
出手段26により乾燥粉体ホッパ16から搬出され、乾
燥粉体貯槽28を経由してロータリーフィーダ等の供給
機30により活性炭化炉32内に設けられたスクリュー
コンベアのケーシング34に投入される。活性炭化炉3
2のケーシング(円筒管)34内に投入された粉体状の
乾燥汚泥は、ケーシング34内に設けられたスクリュー
コンベア36によってケーシング34内を移動し、バー
ナ38からの燃焼ガス(熱風)により間接加熱される。
なお、バーナ38には燃料及び燃焼用空気が供給され
る。この場合、活性炭化炉32の構造として、ケーシン
グ34内の汚泥と熱分解ガス等の流れを並流とすること
が好ましい。これにより、ケーシング34内の上流側が
乾燥汚泥中の水分を蒸発させるための低温の乾燥ゾーン
となり、ケーシング34内を汚泥の移動方向に進むにつ
れて乾燥汚泥を熱分解して炭化するための炭化ゾーンと
なり、ケーシング34内の下流側が乾燥ゾーンで発生し
た水蒸気及び炭化ゾーンで発生した炭酸ガスにより炭化
された汚泥を賦活するための高温の賦活ゾーンとなる。
なお、上記の流れを作り出すために、ケーシング34中
には熱分解ガス等の排気口は設けないか、又は賦活ゾー
ンのみに排気口が設けられる。なお、ケーシング内を移
動する汚泥とバーナからの燃焼ガスの流れを向流とする
ように構成する場合もある。
The powdery dry sludge stored in the above-mentioned dry powder hopper 16 is carried out of the dry powder hopper 16 by a dry powder carry-out means 26 such as a screw feeder, and passes through a dry powder storage tank 28. Then, the raw material is fed into a casing 34 of a screw conveyor provided in an activated carbonization furnace 32 by a feeder 30 such as a rotary feeder. Activated carbonization furnace 3
The powdery dry sludge introduced into the second casing (cylindrical tube) 34 moves in the casing 34 by a screw conveyor 36 provided in the casing 34, and is indirectly transferred by a combustion gas (hot air) from a burner 38. Heated.
The burner 38 is supplied with fuel and combustion air. In this case, as the structure of the activated carbonization furnace 32, it is preferable that the flow of the sludge and the pyrolysis gas and the like in the casing 34 be co-current. Thereby, the upstream side in the casing 34 becomes a low-temperature drying zone for evaporating moisture in the dried sludge, and becomes a carbonizing zone for pyrolyzing and drying the dried sludge as it proceeds in the moving direction of the sludge in the casing 34. The downstream side in the casing 34 becomes a high-temperature activation zone for activating sludge carbonized by steam generated in the drying zone and carbon dioxide generated in the carbonization zone.
In order to create the above flow, an exhaust port for pyrolysis gas or the like is not provided in the casing 34, or an exhaust port is provided only in the activation zone. In some cases, the flow of the sludge moving in the casing and the flow of the combustion gas from the burner may be configured to be countercurrent.

【0023】活性炭化炉32で炭化・賦活処理された活
性炭化物は、ロータリーフィーダ等の供給機40により
ケーシング34から取り出され、その一部が後述するバ
グフィルタでの活性炭化炉32の排ガスの浄化処理に利
用される。また、残りの活性炭化物は系外で利用され、
例えば、活性炭の代用品等として、ごみ焼却炉等の排ガ
ス浄化、臭気ガスの脱臭剤、排水中のCOD除去、下水
汚泥や畜産糞尿等の脱水助剤などに有効利用される。な
お、上述したような活性炭化炉32で製造された活性炭
化物は、活性炭と比較して孔径の大きい細孔分布を有し
ており、排ガス中のダイオキシン類等や臭気成分等の高
分子成分の吸着、液相成分での吸着に適したものであ
る。
The activated carbon which has been carbonized and activated in the activated carbonization furnace 32 is taken out of the casing 34 by a feeder 40 such as a rotary feeder, and a part of the activated carbon is purified by a bag filter described later to purify the exhaust gas from the activated carbonization furnace 32. Used for processing. Also, the remaining activated carbide is used outside the system,
For example, as a substitute for activated carbon, it is effectively used for purifying exhaust gas from garbage incinerators and the like, removing odorous gas from deodorants, removing COD from wastewater, and dehydrating aids for sewage sludge and livestock manure. The activated carbide produced in the activated carbonization furnace 32 as described above has a pore distribution having a large pore size as compared with activated carbon, and high molecular components such as dioxins and odor components in exhaust gas. It is suitable for adsorption and adsorption in liquid phase components.

【0024】活性炭化炉32から排出される高温排ガス
は、その一部がサイクロン24から排ガスファン42を
経由して排出される乾燥排ガスの一部と混合され、気流
乾燥用熱源として気流乾燥機18の解砕機20に導入さ
れる。また、活性炭化炉32から排出される高温排ガス
の残部は熱交換器44に導入され、ここでサイクロン2
4からの乾燥排ガスの残部と熱交換して、活性炭化炉3
2からの排ガスが冷却される。46、48は制御ダンパ
である。熱交換器44で熱交換して加熱されたサイクロ
ン24からの乾燥排ガスは、活性炭化炉32内のケーシ
ング34外側に導入され、バーナ38からの燃焼ガス
(熱風)により直接加熱されてガス中の臭気成分が熱分
解される。
A part of the high-temperature exhaust gas discharged from the activated carbonization furnace 32 is mixed with a part of the dry exhaust gas discharged from the cyclone 24 through the exhaust gas fan 42, and the flash dryer 18 is used as a flash drying heat source. Is introduced into the crusher 20. The remainder of the high-temperature exhaust gas discharged from the activated carbonization furnace 32 is introduced into a heat exchanger 44, where the cyclone 2
Heat exchange with the rest of the dried exhaust gas from
The exhaust gas from 2 is cooled. 46 and 48 are control dampers. The dried exhaust gas from the cyclone 24 that has been heated by heat exchange in the heat exchanger 44 is introduced to the outside of the casing 34 in the activated carbonization furnace 32, and is directly heated by the combustion gas (hot air) from the burner 38 and is contained in the gas. Odor components are thermally decomposed.

【0025】熱交換器44で冷却された活性炭化炉32
からの排ガスは、誘引ファン50を経由してバグフィル
タ52に導入される。このとき、バグフィルタ52入口
側の煙道には、活性炭化炉32で製造された活性炭化物
の一部及び消石灰等のアルカリ剤が吹き込まれ、バグフ
ィルタ52のろ布54の表面に活性炭化物及びアルカリ
剤のコーティング層が形成されて、これにより、活性炭
化炉排ガス中のダイオキシン類、SOx等の酸性ガス成
分、重金属などの有害物質が吸着と反応とで除去され
る。バグフィルタ52で浄化処理された活性炭化炉排ガ
スは系外に排出される。56は、活性炭化物の一部を取
り出すためのロータリーフィーダ等の供給機、58は、
活性炭化物を吹き込むためのブロワである。なお、アル
カリ剤としては、消石灰の他に、生石灰、Mg(OH)
2、MgO等が用いられ、アルカリ剤は粉末状又はスラ
リー状で吹き込まれる。また、活性炭化物とアルカリ剤
は一緒に吹き込んでもよいし、別々に吹き込んでもよ
い。また、図1では、バグフィルタ52入口側の煙道に
活性炭化物等を吹き込む構成としているが、バグフィル
タ52本体に活性炭化物等を吹き込む構成とすることも
できる。また、バグフィルタを直列2段に設け、2段目
のバグフィルタ入口側煙道又はバグフィルタ本体に活性
炭化物又は/及びアルカリ剤を添加することも可能であ
る。さらに、2段目のバグフィルタの代わりに、NaO
H水溶液等の吸収液を供給して循環・スプレーする型式
の湿式ガス洗浄装置を設けることも可能である。
The activated carbonization furnace 32 cooled by the heat exchanger 44
Is introduced into the bag filter 52 via the attraction fan 50. At this time, a part of the activated carbon produced in the activated carbonization furnace 32 and an alkali agent such as slaked lime are blown into the flue on the inlet side of the bag filter 52, and the activated carbon and the alkaline A coating layer of an alkali agent is formed, whereby harmful substances such as dioxins, acidic gas components such as SOx, and heavy metals in the exhaust gas of the activated carbonization furnace are removed by adsorption and reaction. The activated carbonization furnace exhaust gas purified by the bag filter 52 is discharged out of the system. 56 is a feeder such as a rotary feeder for removing a part of the activated carbide, and 58 is
It is a blower for blowing activated carbide. In addition, in addition to slaked lime, quick lime, Mg (OH)
2. MgO or the like is used, and the alkaline agent is blown in powder or slurry form. Further, the activated carbide and the alkali agent may be blown together or separately. Further, in FIG. 1, the activated carbon or the like is blown into the flue on the inlet side of the bag filter 52, but the activated carbon or the like may be blown into the bag filter 52 body. It is also possible to provide a bag filter in two stages in series, and to add an activated carbon and / or an alkali agent to the flue at the inlet of the second stage bag filter or to the bag filter body. Furthermore, instead of the second-stage bag filter, NaO
It is also possible to provide a wet gas cleaning device of a type that supplies and circulates and sprays an absorbing solution such as an H aqueous solution.

【0026】図2は、本発明の実施の第2形態による汚
泥の炭化処理装置を示している。本実施の形態は、サイ
クロン24で分離された気流乾燥排ガスのうち、熱交換
器44において活性炭化炉32からの高温排ガスと熱交
換して加熱された気流乾燥排ガスを、水洗式のスクラバ
ー60に供給して水洗し除湿した後、この乾燥排ガスを
活性炭化炉32内のケーシング34外側に導入し、バー
ナ38からの燃焼ガス(熱風)により直接加熱してガス
中の臭気成分を熱分解するようにしたものである。気流
乾燥排ガスには、気流乾燥機18での乾燥工程で発生し
た水蒸気が含まれており、この気流乾燥排ガスを水洗式
のスクラバー60に導入して、スクラバー60のスプレ
ーノズルから水を噴霧することにより、排ガスに含まれ
る水蒸気が凝縮して排ガスの除湿が行えるとともに、排
ガスを洗浄することができる。なお、水洗式のスクラバ
ーの代わりに、他の湿式排ガス洗浄装置を用いることも
可能である。他の構成及び作用は、実施の第1形態の場
合と同様である。
FIG. 2 shows a sludge carbonization apparatus according to a second embodiment of the present invention. In the present embodiment, of the flash drying exhaust gas separated by the cyclone 24, the flash drying exhaust gas heated by heat exchange with the high temperature exhaust gas from the activated carbonization furnace 32 in the heat exchanger 44 is supplied to the water scrubber 60. After supplying, washing and dehumidifying, the dried exhaust gas is introduced to the outside of the casing 34 in the activated carbonization furnace 32, and is directly heated by the combustion gas (hot air) from the burner 38 to thermally decompose the odor component in the gas. It was made. The flash drying exhaust gas contains water vapor generated in the drying process in the flash drying device 18. The flash drying exhaust gas is introduced into a scrubber 60 of a washing type, and water is sprayed from a spray nozzle of the scrubber 60. Thereby, the water vapor contained in the exhaust gas is condensed and the exhaust gas can be dehumidified, and the exhaust gas can be washed. It should be noted that another wet exhaust gas cleaning device can be used instead of the water-washing type scrubber. Other configurations and operations are the same as those in the first embodiment.

【0027】図3は、本発明の実施の第3形態による汚
泥の炭化処理装置を示している。本実施の形態は、気流
乾燥機18の解砕機20に供給する気流乾燥用熱源とし
て、サイクロン24からの気流乾燥排ガスの一部を、活
性炭化炉32からの高温排ガスで加熱して利用するもの
である。すなわち、サイクロン24からの気流乾燥排ガ
スの一部を熱交換器44に導入し、ここで活性炭化炉3
2からの高温排ガスと熱交換して乾燥排ガスを加熱し、
この加熱空気を気流乾燥機18の解砕機20に導入する
ようにしたものである。また、サイクロン24からの気
流乾燥排ガスの残部は、活性炭化炉32内のケーシング
34外側に導入され、バーナ38からの燃焼ガス(熱
風)により直接加熱されてガス中の臭気成分が熱分解さ
れる。なお、活性炭化炉32に導入される気流乾燥排ガ
スの一部を、前記の加熱した気流乾燥排ガスに混入させ
て、気流乾燥機18の解砕機20に気流乾燥用熱源とし
て導入することができる。他の構成及び作用は、実施の
第1形態の場合と同様である。
FIG. 3 shows a sludge carbonization apparatus according to a third embodiment of the present invention. In this embodiment, as a flash drying heat source to be supplied to the crusher 20 of the flash dryer 18, a part of the flash drying exhaust gas from the cyclone 24 is heated and used by the high temperature exhaust gas from the activated carbonization furnace 32. It is. That is, a part of the flash drying exhaust gas from the cyclone 24 is introduced into the heat exchanger 44, where the activated carbonization furnace 3
Heat exchange with the high temperature exhaust gas from 2 to heat the dry exhaust gas,
This heated air is introduced into the crusher 20 of the flash dryer 18. The remaining portion of the flue gas discharged from the cyclone 24 is introduced to the outside of the casing 34 in the activated carbonization furnace 32 and is directly heated by the combustion gas (hot air) from the burner 38 to thermally decompose the odor component in the gas. . A part of the flash drying exhaust gas introduced into the activated carbonizing furnace 32 can be mixed with the heated flash drying exhaust gas and introduced into the crusher 20 of the flash dryer 18 as a flash drying heat source. Other configurations and operations are the same as those in the first embodiment.

【0028】図4は、本発明の実施の第4形態による汚
泥の炭化処理装置を示している。本実施の形態は、気流
乾燥機18の解砕機20に供給する気流乾燥用熱源とし
て、サイクロン24からの気流乾燥排ガスの一部を、活
性炭化炉32からの高温排ガスで加熱して利用するもの
である。すなわち、サイクロン24からの気流乾燥排ガ
スの一部を熱交換器44に導入し、ここで活性炭化炉3
2からの高温排ガスと熱交換して乾燥排ガスを加熱し、
この加熱空気を気流乾燥機18の解砕機20に導入する
ようにしたものである。また、本実施の形態は、サイク
ロン24からの気流乾燥排ガスの残部を、水洗式のスク
ラバー60に供給して水洗し除湿した後、この乾燥排ガ
スを活性炭化炉32内のケーシング34外側に導入し、
バーナ38からの燃焼ガス(熱風)により直接加熱して
ガス中の臭気成分を熱分解するようにしたものである。
他の構成及び作用は、実施の第1、第2、第3形態の場
合と同様である。
FIG. 4 shows a sludge carbonization apparatus according to a fourth embodiment of the present invention. In this embodiment, as a flash drying heat source to be supplied to the crusher 20 of the flash dryer 18, a part of the flash drying exhaust gas from the cyclone 24 is heated and used by the high temperature exhaust gas from the activated carbonization furnace 32. It is. That is, a part of the flash drying exhaust gas from the cyclone 24 is introduced into the heat exchanger 44, where the activated carbonization furnace 3
Heat exchange with the high temperature exhaust gas from 2 to heat the dry exhaust gas,
This heated air is introduced into the crusher 20 of the flash dryer 18. Further, in the present embodiment, after the remaining portion of the gas-flow drying exhaust gas from the cyclone 24 is supplied to the water-washing type scrubber 60 for washing and dehumidification, the drying exhaust gas is introduced to the outside of the casing 34 in the activated carbonization furnace 32. ,
The odor component in the gas is thermally decomposed by direct heating by the combustion gas (hot air) from the burner 38.
Other configurations and operations are the same as those in the first, second, and third embodiments.

【0029】図5は、本発明の実施の第5形態による汚
泥の炭化処理装置を示している。本実施の形態は、気流
乾燥機18の解砕機20に供給する気流乾燥用熱源とし
て、サイクロン24からの気流乾燥排ガスの一部を、活
性炭化炉32からの高温排ガスで加熱して利用するもの
である。すなわち、サイクロン24からの気流乾燥排ガ
スの一部を熱交換器44に導入し、ここで活性炭化炉3
2からの高温排ガスと熱交換して乾燥排ガスを加熱し、
この加熱空気を気流乾燥機18の解砕機20に導入する
ようにしたものである。また、本実施の形態は、熱交換
器44で熱交換して冷却された活性炭化炉32からの排
ガスの一部を、サイクロン24からの気流乾燥排ガスの
残部とともに、活性炭化炉32内のケーシング34外側
に導入し、バーナ38からの燃焼ガス(熱風)により直
接加熱してガス中の臭気成分を熱分解するようにしたも
のである。他の構成及び作用は、実施の第1、第3形態
の場合と同様である。
FIG. 5 shows an apparatus for carbonizing sludge according to a fifth embodiment of the present invention. In this embodiment, as a flash drying heat source to be supplied to the crusher 20 of the flash dryer 18, a part of the flash drying exhaust gas from the cyclone 24 is heated and used by the high temperature exhaust gas from the activated carbonization furnace 32. It is. That is, a part of the flash drying exhaust gas from the cyclone 24 is introduced into the heat exchanger 44, where the activated carbonization furnace 3
Heat exchange with the high temperature exhaust gas from 2 to heat the dry exhaust gas,
This heated air is introduced into the crusher 20 of the flash dryer 18. Further, in the present embodiment, a part of the exhaust gas from the activated carbonization furnace 32 that has been cooled by heat exchange in the heat exchanger 44 is used together with the remaining portion of the flash drying exhaust gas from the cyclone 24 in the casing in the activated carbonization furnace 32. The odor component is introduced directly outside by a combustion gas (hot air) from a burner 38 to thermally decompose odor components in the gas. Other configurations and operations are the same as those in the first and third embodiments.

【0030】図6は、本発明の実施の第6形態による汚
泥の炭化処理装置を示している。本実施の形態は、気流
乾燥機18の解砕機20に供給する気流乾燥用熱源とし
て、サイクロン24からの気流乾燥排ガスの一部を、活
性炭化炉32からの高温排ガスで加熱して利用するもの
である。すなわち、サイクロン24からの気流乾燥排ガ
スの一部を熱交換器44に導入し、ここで活性炭化炉3
2からの高温排ガスと熱交換して乾燥排ガスを加熱し、
この加熱空気を気流乾燥機18の解砕機20に導入する
ようにしたものである。また、本実施の形態は、サイク
ロン24からの気流乾燥排ガスの残部を、水洗式のスク
ラバー60に供給して水洗し除湿した後、この乾燥排ガ
スを、熱交換器44で熱交換して冷却された活性炭化炉
32からの排ガスの一部とともに、活性炭化炉32内の
ケーシング34外側に導入し、バーナ38からの燃焼ガ
ス(熱風)により直接加熱してガス中の臭気成分を熱分
解するようにしたものである。他の構成及び作用は、実
施の第1〜第5形態の場合と同様である。
FIG. 6 shows an apparatus for carbonizing sludge according to a sixth embodiment of the present invention. In this embodiment, as a flash drying heat source to be supplied to the crusher 20 of the flash dryer 18, a part of the flash drying exhaust gas from the cyclone 24 is heated and used by the high temperature exhaust gas from the activated carbonization furnace 32. It is. That is, a part of the flash drying exhaust gas from the cyclone 24 is introduced into the heat exchanger 44, where the activated carbonization furnace 3
Heat exchange with the high temperature exhaust gas from 2 to heat the dry exhaust gas,
This heated air is introduced into the crusher 20 of the flash dryer 18. Further, in the present embodiment, the remaining portion of the flash drying exhaust gas from the cyclone 24 is supplied to the scrubber 60 of a washing type to be washed with water and dehumidified, and the dried exhaust gas is cooled by heat exchange in the heat exchanger 44. A part of the exhaust gas from the activated carbonization furnace 32 is introduced into the outside of the casing 34 in the activated carbonization furnace 32 and directly heated by the combustion gas (hot air) from the burner 38 to thermally decompose the odor component in the gas. It was made. Other configurations and operations are the same as those in the first to fifth embodiments.

【0031】[0031]

【発明の効果】本発明は上記のように構成されているの
で、つぎのような効果を奏する。 (1) 下水汚泥等の汚泥を気流乾燥装置によって乾燥
させ、得られた粉体状の乾燥汚泥を活性炭化装置で炭化
・賦活処理することにより、吸着性能の高い活性炭化物
を製造することができる。 (2) 気流乾燥用熱源として、活性炭化装置の排ガス
から熱回収した気流乾燥排ガス又は/及び直接活性炭化
装置排ガスを利用することができる。 (3) 気流乾燥排ガスを活性炭化装置に導入すること
により、乾燥排ガス中の臭気成分が熱分解され、気流乾
燥排ガスの脱臭処理を行うことができる。 (4) 気流乾燥排ガスを水洗式のスクラバーに供給し
て水洗・除湿を行う構成とする場合は、さらに熱効率が
高くなる。 (5) 活性炭化装置で製造した活性炭化物を活性炭化
装置排ガスの浄化処理に利用することができる。具体的
には、得られた活性炭化物及び消石灰等のアルカリ剤
を、活性炭化装置からの排ガスとともにバグフィルタ等
のろ過式集塵器に導入することにより、排ガス中のダイ
オキシン類、SOx等の酸性ガス成分、重金属などの有
害物質を吸着や反応で除去することができる。 (6) 汚泥の移動方向の上流側が乾燥ゾーンで、つい
で炭化ゾーンとなり、汚泥の移動方向の下流側が賦活ゾ
ーンとなる活性炭化装置を用いる場合は、乾燥ゾーンで
発生した水蒸気及び炭化ゾーンで発生した炭酸ガスを、
賦活ゾーンで炭化物の賦活反応に利用することができ
る。 (7) 汚泥廃棄物の減容化と廃棄物の有効利用を図る
ことができる。
As described above, the present invention has the following effects. (1) Sludge such as sewage sludge is dried by a flash dryer, and the obtained powdery dried sludge is carbonized and activated by an activated carbonizer, whereby an activated carbide having high adsorption performance can be produced. . (2) As a flash drying heat source, flash drying exhaust gas heat recovered from the exhaust gas of the activated carbonization device or / and direct activated carbonization device exhaust gas can be used. (3) By introducing the flash dried exhaust gas into the activated carbonization device, the odor components in the dried exhaust gas are thermally decomposed, and the flash dried exhaust gas can be deodorized. (4) When the flash drying exhaust gas is supplied to a scrubber of a washing type to perform washing and dehumidification, the heat efficiency is further increased. (5) The activated carbide produced by the activated carbonization device can be used for the purification treatment of the activated carbonization device exhaust gas. Specifically, by introducing the obtained activated carbon and an alkali agent such as slaked lime into a filter-type dust collector such as a bag filter together with the exhaust gas from the activated carbon device, acidity such as dioxins and SOx in the exhaust gas is introduced. Harmful substances such as gas components and heavy metals can be removed by adsorption or reaction. (6) In the case of using an activated carbonization device in which the upstream side in the moving direction of the sludge is the drying zone and then the carbonization zone, and the downstream side in the moving direction of the sludge is the activation zone, the activated carbonized water is generated in the steam generated in the drying zone and the carbonized zone. Carbon dioxide,
It can be used for the activation reaction of carbide in the activation zone. (7) Sludge waste volume can be reduced and waste can be used effectively.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施の第1形態による汚泥の炭化処理
装置を示す系統的概略構成図である。
FIG. 1 is a systematic schematic configuration diagram showing a sludge carbonization apparatus according to a first embodiment of the present invention.

【図2】本発明の実施の第2形態による汚泥の炭化処理
装置を示す系統的概略構成図である。
FIG. 2 is a systematic schematic configuration diagram showing an apparatus for carbonizing sludge according to a second embodiment of the present invention.

【図3】本発明の実施の第3形態による汚泥の炭化処理
装置を示す系統的概略構成図である。
FIG. 3 is a systematic schematic configuration diagram showing a sludge carbonization apparatus according to a third embodiment of the present invention.

【図4】本発明の実施の第4形態による汚泥の炭化処理
装置を示す系統的概略構成図である。
FIG. 4 is a systematic schematic configuration diagram showing a sludge carbonization apparatus according to a fourth embodiment of the present invention.

【図5】本発明の実施の第5形態による汚泥の炭化処理
装置を示す系統的概略構成図である。
FIG. 5 is a systematic schematic configuration diagram showing a sludge carbonization apparatus according to a fifth embodiment of the present invention.

【図6】本発明の実施の第6形態による汚泥の炭化処理
装置を示す系統的概略構成図である。
FIG. 6 is a systematic schematic configuration diagram showing a sludge carbonization apparatus according to a sixth embodiment of the present invention.

【符号の説明】[Explanation of symbols]

10 混合供給機 12 混合・搬送手段 14 搬送手段 16 乾燥粉体ホッパ 18 気流乾燥機 20 解砕機 22 気流乾燥管 24 サイクロン 26 乾燥粉体搬出手段 28 乾燥粉体貯槽 30、40、56 供給機 32 活性炭化炉 34 ケーシング 36 スクリューコンベア 38 バーナ 42 排ガスファン 44 熱交換器 46、48 制御ダンパ 50 誘引ファン 52 バグフィルタ 54 ろ布 58 ブロワ 60 水洗式のスクラバー REFERENCE SIGNS LIST 10 mixing / supplying machine 12 mixing / transporting means 14 transporting means 16 dry powder hopper 18 flash drying machine 20 crusher 22 flash drying tube 24 cyclone 26 dry powder discharging means 28 dry powder storage tanks 30, 40, 56 feeding machine 32 activated carbon Gasifier 34 Casing 36 Screw conveyor 38 Burner 42 Exhaust gas fan 44 Heat exchanger 46, 48 Control damper 50 Induction fan 52 Bag filter 54 Filter cloth 58 Blower 60 Water-washing scrubber

───────────────────────────────────────────────────── フロントページの続き (72)発明者 黒田 浩史 神戸市中央区東川崎町1丁目1番3号 川崎重工業株式会社 神戸本社内 (56)参考文献 特開 平11−11922(JP,A) 特開 平7−242408(JP,A) 特開 平2−293100(JP,A) 実公 昭45−14388(JP,Y1) (58)調査した分野(Int.Cl.7,DB名) C01B 31/02 - 31/08 C02F 11/00 C02F 11/18 C02F 11/12 C10B 53/00 - 53/02 ────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Hiroshi Kuroda 1-3-1 Higashikawasakicho, Chuo-ku, Kobe Kawasaki Heavy Industries, Ltd. Kobe Head Office (56) References JP-A-11-11922 (JP, A) JP-A-7-242408 (JP, A) JP-A-2-293100 (JP, A) Jikken Sho 45-14388 (JP, Y1) (58) Fields investigated (Int. Cl. 7 , DB name) C01B 31 / 02-31/08 C02F 11/00 C02F 11/18 C02F 11/12 C10B 53/00-53/02

Claims (16)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 気流乾燥装置からの循環乾燥汚泥に汚泥
脱水ケーキを混合し、この乾燥汚泥混合物を気流乾燥装
置の解砕機で粉砕して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥装置の気流乾燥管でさらに熱風乾燥
させた後、粉体状の乾燥汚泥を含む気流を固気分離器に
導入して粉体状の乾燥汚泥と気流乾燥排ガスとに分離
し、粉体状の乾燥汚泥の大部分を循環乾燥汚泥として汚
泥脱水ケーキと混合し、循環を繰り返して得られた残り
の粉体状の乾燥汚泥を活性炭化装置に導入し炭化・賦活
処理して活性炭化物を製造し、固気分離器からの気流乾
燥排ガスの一部を活性炭化装置からの高温排ガスの一部
と混合して気流乾燥用熱源として気流乾燥装置の解砕機
に供給し、活性炭化装置からの高温排ガスの残部を固気
分離器からの気流乾燥排ガスの残部と熱交換して高温排
ガスを冷却して排気し、熱交換により加熱された気流乾
燥排ガスの残部を活性炭化装置に導入して乾燥排ガス中
の臭気成分を熱分解することを特徴とする汚泥の炭化処
理方法。
1. A sludge dewatered cake is mixed with a circulating dried sludge from a flash drying device, and the dried sludge mixture is pulverized by a pulverizer of a flash drying device and dried with hot air to obtain a powdery dried sludge. After further drying with hot air in a flash drying tube of a flash drying device, an airflow containing powdery dry sludge is introduced into a solid-gas separator to separate into powdery dry sludge and flash-drying exhaust gas. Most of the dry sludge is mixed with the sludge dewatered cake as circulating dry sludge, and the remaining powdery dry sludge obtained by repeating the circulation is introduced into the activated carbonization device, where it is carbonized and activated to form activated carbon. Manufacture and mix a part of the flash drying exhaust gas from the solid-gas separator with a part of the high temperature exhaust gas from the activated carbonization device and supply it as a heat source for flash drying to the crusher of the flash drying device. Flash drying of the rest of the hot exhaust gas from a solid-gas separator The high-temperature exhaust gas is cooled and exhausted by heat exchange with the rest of the exhaust gas, and the remainder of the flash dried exhaust gas heated by the heat exchange is introduced into the activated carbonization device to thermally decompose the odor components in the dried exhaust gas. Sludge carbonization method.
【請求項2】 気流乾燥装置からの循環乾燥汚泥に汚泥
脱水ケーキを混合し、この乾燥汚泥混合物を気流乾燥装
置の解砕機で粉砕して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥装置の気流乾燥管でさらに熱風乾燥
させた後、粉体状の乾燥汚泥を含む気流を固気分離器に
導入して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気
を含む気流乾燥排ガスとに分離し、粉体状の乾燥汚泥の
大部分を循環乾燥汚泥として汚泥脱水ケーキと混合し、
循環を繰り返して得られた残りの粉体状の乾燥汚泥を活
性炭化装置に導入し炭化・賦活処理して活性炭化物を製
造し、固気分離器からの気流乾燥排ガスの一部を活性炭
化装置からの高温排ガスの一部と混合して気流乾燥用熱
源として気流乾燥装置の解砕機に供給し、活性炭化装置
からの高温排ガスの残部を固気分離器からの気流乾燥排
ガスの残部と熱交換して高温排ガスを冷却して排気し、
熱交換により加熱された水蒸気を含む気流乾燥排ガスの
残部を水洗式のスクラバーに供給して水洗し除湿した
後、活性炭化装置に導入して乾燥排ガス中の臭気成分を
熱分解することを特徴とする汚泥の炭化処理方法。
2. A sludge dewatering cake is mixed with the circulating dried sludge from the flash drying device, and the dried sludge mixture is pulverized by a pulverizer of the flash drying device and dried with hot air to obtain a powdery dried sludge. After further hot-air drying with the flash drying tube of the flash drying device, the air flow containing the powdery dry sludge is introduced into the solid-gas separator, and the flash drying containing the powdery dry sludge and the steam generated in the drying process It is separated into exhaust gas and most of the powdery dried sludge is mixed with the sludge dewatered cake as circulating dried sludge,
The remaining powdery dry sludge obtained by repeating the circulation is introduced into an activated carbonization device, where it is activated and carbonized to produce activated carbide, and a portion of the gas-flow dried exhaust gas from the solid-gas separator is activated carbonized. Mixed with a part of the high-temperature exhaust gas from the furnace and supplied as a heat source for flash-drying to the crusher of the flash dryer, where the remaining high-temperature exhaust gas from the activated carbonizer is exchanged with the remaining flash-dry exhaust gas from the solid-gas separator. To cool and exhaust the hot exhaust gas,
The remaining part of the flash drying exhaust gas containing steam heated by heat exchange is supplied to a washing scrubber, washed and dehumidified, and then introduced into an activated carbonization device to thermally decompose odor components in the drying exhaust gas. Sludge carbonization method.
【請求項3】 気流乾燥装置からの循環乾燥汚泥に汚泥
脱水ケーキを混合し、この乾燥汚泥混合物を気流乾燥装
置の解砕機で粉砕して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥装置の気流乾燥管でさらに熱風乾燥
させた後、粉体状の乾燥汚泥を含む気流を固気分離器に
導入して粉体状の乾燥汚泥と気流乾燥排ガスとに分離
し、粉体状の乾燥汚泥の大部分を循環乾燥汚泥として汚
泥脱水ケーキと混合し、循環を繰り返して得られた残り
の粉体状の乾燥汚泥を活性炭化装置に導入し炭化・賦活
処理して活性炭化物を製造し、固気分離器からの気流乾
燥排ガスの一部を活性炭化装置からの高温排ガスと熱交
換して気流乾燥排ガスを加熱し、この加熱気体を気流乾
燥用熱源として気流乾燥装置の解砕機に供給し、固気分
離器からの気流乾燥排ガスの一部と熱交換して冷却され
た活性炭化装置からの排ガスを排気し、固気分離器から
の気流乾燥排ガスの残部を活性炭化装置に導入して乾燥
排ガス中の臭気成分を熱分解することを特徴とする汚泥
の炭化処理方法。
3. A sludge dewatering cake is mixed with the circulating dried sludge from the flash drying device, and the dried sludge mixture is pulverized by a pulverizer of the flash drying device and dried with hot air to obtain the powdery dried sludge. After further drying with hot air in a flash drying tube of a flash drying device, an airflow containing powdery dry sludge is introduced into a solid-gas separator to separate into powdery dry sludge and flash-drying exhaust gas. Most of the dry sludge is mixed with the sludge dewatered cake as circulating dry sludge, and the remaining powdery dry sludge obtained by repeating the circulation is introduced into the activated carbonization device, where it is carbonized and activated to form activated carbon. Manufactures and heat-exchanges a part of the flash drying exhaust gas from the solid-gas separator with the high-temperature exhaust gas from the activated carbonization device to heat the flash drying exhaust gas, and uses the heated gas as a heat source for flash drying to crack the flash drying device. And dry it by flash drying from a solid-gas separator. Exhaust gas from the activated carbonizer cooled by exchanging heat with a part of the gas is exhausted, and the remainder of the flash dried exhaust gas from the solid-gas separator is introduced into the activated carbonizer to thermally decompose odor components in the dried exhaust gas. A method of carbonizing sludge.
【請求項4】 気流乾燥装置からの循環乾燥汚泥に汚泥
脱水ケーキを混合し、この乾燥汚泥混合物を気流乾燥装
置の解砕機で粉砕して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥装置の気流乾燥管でさらに熱風乾燥
させた後、粉体状の乾燥汚泥を含む気流を固気分離器に
導入して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気
を含む気流乾燥排ガスとに分離し、粉体状の乾燥汚泥の
大部分を循環乾燥汚泥として汚泥脱水ケーキと混合し、
循環を繰り返して得られた残りの粉体状の乾燥汚泥を活
性炭化装置に導入し炭化・賦活処理して活性炭化物を製
造し、固気分離器からの気流乾燥排ガスの一部を活性炭
化装置からの高温排ガスと熱交換して気流乾燥排ガスを
加熱し、この加熱気体を気流乾燥用熱源として気流乾燥
装置の解砕機に供給し、固気分離器からの気流乾燥排ガ
スの一部と熱交換して冷却された活性炭化装置からの排
ガスを排気し、固気分離器からの水蒸気を含む気流乾燥
排ガスの残部を水洗式のスクラバーに供給して水洗し除
湿した後、活性炭化装置に導入して乾燥排ガス中の臭気
成分を熱分解することを特徴とする汚泥の炭化処理方
法。
4. A sludge dewatering cake is mixed with the circulating dried sludge from the flash drying device, and the dried sludge mixture is pulverized by a pulverizer of the flash drying device and dried with hot air to obtain a powdery dried sludge. After further hot-air drying with the flash drying tube of the flash drying device, the air flow containing the powdery dry sludge is introduced into the solid-gas separator, and the flash drying containing the powdery dry sludge and the steam generated in the drying process It is separated into exhaust gas and most of the powdery dried sludge is mixed with the sludge dewatered cake as circulating dried sludge,
The remaining powdery dry sludge obtained by repeating the circulation is introduced into an activated carbonization device, where it is activated and carbonized to produce activated carbide, and a portion of the gas-flow dried exhaust gas from the solid-gas separator is activated carbonized. Heat-exchanges the high-temperature exhaust gas from the air to dry the flash-dry exhaust gas, and supplies the heated gas to the crusher of the flash-drying device as a heat source for flash-drying, and exchanges heat with a part of the flash-dry exhaust gas from the solid-gas separator. The exhaust gas from the activated carbonization device that has been cooled is exhausted, and the remainder of the flash dried exhaust gas containing water vapor from the solid-gas separator is supplied to a water-washing type scrubber, washed with water and dehumidified, and then introduced into the activated carbonization device. Wherein the odor component in the dried exhaust gas is thermally decomposed by thermal decomposition.
【請求項5】 気流乾燥装置からの循環乾燥汚泥に汚泥
脱水ケーキを混合し、この乾燥汚泥混合物を気流乾燥装
置の解砕機で粉砕して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥装置の気流乾燥管でさらに熱風乾燥
させた後、粉体状の乾燥汚泥を含む気流を固気分離器に
導入して粉体状の乾燥汚泥と気流乾燥排ガスとに分離
し、粉体状の乾燥汚泥の大部分を循環乾燥汚泥として汚
泥脱水ケーキと混合し、循環を繰り返して得られた残り
の粉体状の乾燥汚泥を活性炭化装置に導入し炭化・賦活
処理して活性炭化物を製造し、固気分離器からの気流乾
燥排ガスの一部を活性炭化装置からの高温排ガスと熱交
換して気流乾燥排ガスを加熱し、この加熱気体を気流乾
燥用熱源として気流乾燥装置の解砕機に供給し、固気分
離器からの気流乾燥排ガスの一部と熱交換して冷却され
た活性炭化装置からの排ガスの一部を排気し、固気分離
器からの気流乾燥排ガスの残部を活性炭化装置からの排
ガスの残部とともに活性炭化装置に導入して排ガス中の
臭気成分を熱分解することを特徴とする汚泥の炭化処理
方法。
5. A sludge dewatering cake is mixed with the circulating dried sludge from the flash drying device, the dried sludge mixture is pulverized by a pulverizer of the flash drying device and dried with hot air, and the obtained powdery dried sludge is dried. After further drying with hot air in a flash drying tube of a flash drying device, an airflow containing powdery dry sludge is introduced into a solid-gas separator to separate into powdery dry sludge and flash-drying exhaust gas. Most of the dry sludge is mixed with the sludge dewatered cake as circulating dry sludge, and the remaining powdery dry sludge obtained by repeating the circulation is introduced into the activated carbonization device, where it is carbonized and activated to form activated carbon. Manufactures and heat-exchanges a part of the flash drying exhaust gas from the solid-gas separator with the high-temperature exhaust gas from the activated carbonization device to heat the flash drying exhaust gas, and uses the heated gas as a heat source for flash drying to crack the flash drying device. And dry it by flash drying from a solid-gas separator. A part of the exhaust gas from the activated carbonizer cooled by exchanging heat with a part of the gas is exhausted, and the remaining part of the flash dried exhaust gas from the solid-gas separator is sent to the activated carbonizer together with the remaining part of the exhaust gas from the activated carbonizer. A method for carbonizing sludge, comprising introducing and thermally decomposing odor components in exhaust gas.
【請求項6】 気流乾燥装置からの循環乾燥汚泥に汚泥
脱水ケーキを混合し、この乾燥汚泥混合物を気流乾燥装
置の解砕機で粉砕して熱風乾燥させ、得られた粉体状の
乾燥汚泥を気流乾燥装置の気流乾燥管でさらに熱風乾燥
させた後、粉体状の乾燥汚泥を含む気流を固気分離器に
導入して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気
を含む気流乾燥排ガスとに分離し、粉体状の乾燥汚泥の
大部分を循環乾燥汚泥として汚泥脱水ケーキと混合し、
循環を繰り返して得られた残りの粉体状の乾燥汚泥を活
性炭化装置に導入し炭化・賦活処理して活性炭化物を製
造し、固気分離器からの気流乾燥排ガスの一部を活性炭
化装置からの高温排ガスと熱交換して気流乾燥排ガスを
加熱し、この加熱気体を気流乾燥用熱源として気流乾燥
装置の解砕機に供給し、固気分離器からの気流乾燥排ガ
スの一部と熱交換して冷却された活性炭化装置からの排
ガスの一部を排気し、固気分離器からの水蒸気を含む気
流乾燥排ガスの残部を水洗式のスクラバーに供給して水
洗し除湿した後、この乾燥排ガスを活性炭化装置からの
排ガスの残部とともに活性炭化装置に導入して排ガス中
の臭気成分を熱分解することを特徴とする汚泥の炭化処
理方法。
6. A sludge dewatering cake is mixed with the circulating dried sludge from the flash drying device, and the dried sludge mixture is pulverized by a pulverizer of the flash drying device and dried with hot air to obtain a powdery dried sludge. After further hot-air drying with the flash drying tube of the flash drying device, the air flow containing the powdery dry sludge is introduced into the solid-gas separator, and the flash drying containing the powdery dry sludge and the steam generated in the drying process It is separated into exhaust gas and most of the powdery dried sludge is mixed with the sludge dewatered cake as circulating dried sludge,
The remaining powdery dry sludge obtained by repeating the circulation is introduced into an activated carbonization device, where it is activated and carbonized to produce activated carbide, and a portion of the gas-flow dried exhaust gas from the solid-gas separator is activated carbonized. Heat-exchanges the high-temperature exhaust gas from the air to dry the flash-dry exhaust gas, and supplies the heated gas to the crusher of the flash-drying device as a heat source for flash-drying, and exchanges heat with a part of the flash-dry exhaust gas from the solid-gas separator. A part of the exhaust gas from the activated carbonization device cooled and exhausted is exhausted, and the remainder of the flash drying exhaust gas containing water vapor from the solid-gas separator is supplied to a washing scrubber to be washed with water and dehumidified. Characterized in that odor components in the exhaust gas are thermally decomposed by introducing the waste gas into the activated carbon device together with the rest of the exhaust gas from the activated carbon device.
【請求項7】 熱交換により冷却された活性炭化装置か
らの排ガスの少なくとも一部を、排気する前に、炭化・
賦活処理で得られた活性炭化物の一部及び/又はアルカ
リ剤とともにろ過式集塵器に導入して排ガス中の有害物
質を除去する請求項1〜6のいずれかに記載の汚泥の炭
化処理方法。
7. The method of claim 1, wherein at least a part of the exhaust gas from the activated carbonization device cooled by the heat exchange is carbonized before being exhausted.
The method for carbonizing sludge according to any one of claims 1 to 6, wherein the activated carbon is introduced into a filter-type dust collector together with a part of the activated carbide obtained by the activation treatment and / or an alkali agent to remove harmful substances in the exhaust gas. .
【請求項8】 活性炭化物の原料となる粉体状の乾燥汚
泥を、間接加熱方式である活性炭化装置に導入して、乾
燥汚泥中の水分を炭化処理の前段で蒸発させ、ついで、
乾燥汚泥を熱分解して炭化処理し、炭化された汚泥を、
炭化処理の前段で発生した水蒸気及び熱分解時に発生す
る炭酸ガスにより賦活処理して活性炭化物を製造する請
求項1〜7のいずれかに記載の汚泥の炭化処理方法。
8. Dry powdery sludge, which is a raw material of activated carbon, is introduced into an activated carbonization device of an indirect heating method, and water in the dried sludge is evaporated at a stage prior to carbonization treatment.
The dried sludge is pyrolyzed and carbonized, and the carbonized sludge is
The method for carbonizing sludge according to any one of claims 1 to 7, wherein the activated carbon is produced by an activation treatment using steam generated in a preceding stage of the carbonizing processing and carbon dioxide generated during pyrolysis.
【請求項9】 固気分離器で固気分離されて循環する粉
体状の乾燥汚泥を搬送し、この粉体状の乾燥汚泥に汚泥
脱水ケーキを混合してさらに搬送し、この乾燥汚泥混合
物を気流乾燥装置の解砕機に供給するための混合供給手
段と、 混合供給手段で搬送され循環される粉体状の乾燥汚泥の
一部を取り出して貯留するための混合供給手段上部に連
通して設けられた乾燥粉体ホッパと、 混合供給手段からの乾燥汚泥混合物とともに、気流乾燥
用熱源として活性炭化装置からの高温排ガスの一部を固
気分離器からの気流乾燥排ガスの一部と混合して解砕機
に供給し、解砕機で乾燥汚泥混合物を粉砕して熱風乾燥
させ、得られた粉体状の乾燥汚泥を気流乾燥管でさらに
熱風乾燥させる気流乾燥装置と、 気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と気流乾燥排ガスとに分離するた
めの固気分離器と、 乾燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭
化・賦活処理して活性炭化物を製造するための活性炭化
装置と、 気流乾燥用熱源として高温排ガスの一部を解砕機に供給
した活性炭化装置からの高温排ガスの残部を固気分離器
からの気流乾燥排ガスの残部と熱交換するための熱交換
器と、 熱交換器で加熱された気流乾燥排ガスの残部を熱分解脱
臭するために活性炭化装置に導入するための気流乾燥排
ガス導入手段と、を包含することを特徴とする汚泥の炭
化処理装置。
9. Dry powdery sludge circulated by solid-gas separation by a solid-gas separator and circulated, mixed with this powdery dry sludge and further mixed with a sludge dewatering cake, and further dried. And a mixing and supplying means for supplying the powdery sludge to the crusher of the flash drying device, and a portion of the powdery dry sludge which is conveyed and circulated by the mixing and supplying means and communicates with an upper part of the mixing and supplying means for storing the sludge. Along with the provided dry powder hopper and the dry sludge mixture from the mixing and supplying means, a part of the high-temperature exhaust gas from the activated carbonizer is mixed with a part of the flash-dry exhaust gas from the solid-gas separator as a heat source for flash drying. A flash drying device that pulverizes the dried sludge mixture with a crusher, hot-air-drys the obtained powdered sludge, and further hot-air-drys the obtained powdery sludge with a flash drying tube; and a powder from the flash drying device. Air flow containing dry sludge A solid-gas separator for separation into powdery dry sludge and flash drying exhaust gas by introduction, and carbonization and activation treatment of powdery dry sludge taken out from the dry powder hopper to produce activated carbon To heat exchange the remainder of the high-temperature exhaust gas from the activated carbonizer that supplied part of the high-temperature exhaust gas to the crusher as a heat source for flash drying, with the remainder of the flash-dry exhaust gas from the solid-gas separator. A heat exchanger, and a flash drying exhaust gas introduction means for introducing the activated flash carbonization device to thermally deodorize the remainder of the flash drying exhaust gas heated by the heat exchanger. Carbonization equipment.
【請求項10】 固気分離器で固気分離されて循環する
粉体状の乾燥汚泥を搬送し、この粉体状の乾燥汚泥に汚
泥脱水ケーキを混合してさらに搬送し、この乾燥汚泥混
合物を気流乾燥装置の解砕機に供給するための混合供給
手段と、 混合供給手段で搬送され循環される粉体状の乾燥汚泥の
一部を取り出して貯留するための混合供給手段上部に連
通して設けられた乾燥粉体ホッパと、 混合供給手段からの乾燥汚泥混合物とともに、気流乾燥
用熱源として活性炭化装置からの高温排ガスの一部を固
気分離器からの気流乾燥排ガスの一部と混合して解砕機
に供給し、解砕機で乾燥汚泥混合物を粉砕して熱風乾燥
させ、得られた粉体状の乾燥汚泥を気流乾燥管でさらに
熱風乾燥させる気流乾燥装置と、 気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気を含
む気流乾燥排ガスとに分離するための固気分離器と、 乾燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭
化・賦活処理して活性炭化物を製造するための活性炭化
装置と、 気流乾燥用熱源として高温排ガスの一部を解砕機に供給
した活性炭化装置からの高温排ガスの残部を固気分離器
からの気流乾燥排ガスの残部と熱交換するための熱交換
器と、 熱交換器で加熱された水蒸気を含む気流乾燥排ガスの残
部を供給して水洗し除湿するための水洗式のスクラバー
と、 水洗式のスクラバーからの乾燥排ガスを熱分解脱臭する
ために活性炭化装置に導入するための気流乾燥排ガス導
入手段と、を包含することを特徴とする汚泥の炭化処理
装置。
10. A powdery dry sludge which is separated by solid-gas separation in a solid-gas separator and circulated, is conveyed, mixed with the powdery dry sludge and a sludge dewatering cake, and further conveyed. And a mixing and supplying means for supplying the powdery sludge to the crusher of the flash drying device, and a portion of the powdery dry sludge which is conveyed and circulated by the mixing and supplying means and communicates with an upper part of the mixing and supplying means for storing the sludge. Along with the provided dry powder hopper and the dry sludge mixture from the mixing and supplying means, a part of the high-temperature exhaust gas from the activated carbonizer is mixed with a part of the flash-dry exhaust gas from the solid-gas separator as a heat source for flash drying. A flash drying device that pulverizes the dried sludge mixture with a crusher, hot-air-drys the obtained powdered sludge, and further hot-air-drys the obtained powdery sludge with a flash drying tube; and a powder from the flash drying device. Airflow containing dry sludge A solid-gas separator for separating into powdery dry sludge and flash drying exhaust gas containing steam generated in the drying process, and carbonize the powdery dry sludge taken out from the dry powder hopper.・ Activated carbonization equipment for producing activated carbides by activation treatment, and the rest of the high-temperature exhaust gas from the activated carbonization equipment that supplied a part of the high-temperature exhaust gas to the crusher as a heat source for flash drying A heat exchanger for exchanging heat with the rest of the drying exhaust gas, a flush scrubber for supplying the rest of the flash drying exhaust gas containing steam heated by the heat exchanger to wash and dehumidify the water, and a scrubber of the flush type A flue gas exhaust gas introducing means for introducing the dried exhaust gas from the wastewater into the activated carbonization device for thermal decomposition and deodorization.
【請求項11】 固気分離器で固気分離されて循環する
粉体状の乾燥汚泥を搬送し、この粉体状の乾燥汚泥に汚
泥脱水ケーキを混合してさらに搬送し、この乾燥汚泥混
合物を気流乾燥装置の解砕機に供給するための混合供給
手段と、 混合供給手段で搬送され循環される粉体状の乾燥汚泥の
一部を取り出して貯留するための混合供給手段上部に連
通して設けられた乾燥粉体ホッパと、 混合供給手段からの乾燥汚泥混合物とともに、気流乾燥
用熱源として固気分離器からの気流乾燥排ガスの一部を
熱交換器で活性炭化装置からの高温排ガスと熱交換し加
熱して解砕機に供給し、解砕機で乾燥汚泥混合物を粉砕
して熱風乾燥させ、得られた粉体状の乾燥汚泥を気流乾
燥管でさらに熱風乾燥させる気流乾燥装置と、 気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と気流乾燥排ガスとに分離するた
めの固気分離器と、 乾燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭
化・賦活処理して活性炭化物を製造するための活性炭化
装置と、 活性炭化装置からの高温排ガスを固気分離器からの気流
乾燥排ガスの一部と熱交換するための熱交換器と、 固気分離器からの気流乾燥排ガスの残部を熱分解脱臭す
るために活性炭化装置に導入するための気流乾燥排ガス
導入手段と、を包含することを特徴とする汚泥の炭化処
理装置。
11. A powdery dry sludge which is separated by a solid-gas separator and circulated, is conveyed, and the powdery dry sludge is mixed with a sludge dewatering cake and further conveyed. And a mixing and supplying means for supplying the powdery sludge to the crusher of the flash drying device, and a portion of the powdery dry sludge which is conveyed and circulated by the mixing and supplying means and communicates with an upper part of the mixing and supplying means for storing the sludge. Along with the dry powder hopper provided and the dry sludge mixture from the mixing and feeding means, a part of the flash drying exhaust gas from the solid-gas separator is used as a heat source for flash drying by using a heat exchanger to convert the high temperature exhaust gas from the activated carbonizer into heat. A flash drying device for exchanging, heating and supplying to the crusher, crushing the dried sludge mixture with the crusher and drying with hot air, and further drying the obtained powdery dried sludge with hot air using a flash drying tube; Dry dust from the equipment A solid-gas separator for introducing an air stream containing mud into powdery dry sludge and flash drying exhaust gas, and carbonizing and activating powdery dry sludge taken out from the dry powder hopper. An activated carbonizer for producing activated carbon by heating; a heat exchanger for exchanging high-temperature exhaust gas from the activated carbonizer with a part of flash drying exhaust gas from a solid-gas separator; A sludge carbonization apparatus, comprising: a flash drying flue gas introduction means for introducing the remaining flash flue gas into the activated carbonization apparatus for thermal decomposition and deodorization.
【請求項12】 固気分離器で固気分離されて循環する
粉体状の乾燥汚泥を搬送し、この粉体状の乾燥汚泥に汚
泥脱水ケーキを混合してさらに搬送し、この乾燥汚泥混
合物を気流乾燥装置の解砕機に供給するための混合供給
手段と、 混合供給手段で搬送され循環される粉体状の乾燥汚泥の
一部を取り出して貯留するための混合供給手段上部に連
通して設けられた乾燥粉体ホッパと、 混合供給手段からの乾燥汚泥混合物とともに、気流乾燥
用熱源として固気分離器からの気流乾燥排ガスの一部を
熱交換器で活性炭化装置からの高温排ガスと熱交換し加
熱して解砕機に供給し、解砕機で乾燥汚泥混合物を粉砕
して熱風乾燥させ、得られた粉体状の乾燥汚泥を気流乾
燥管でさらに熱風乾燥させる気流乾燥装置と、 気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気を含
む気流乾燥排ガスとに分離するための固気分離器と、 乾燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭
化・賦活処理して活性炭化物を製造するための活性炭化
装置と、 活性炭化装置からの高温排ガスを固気分離器からの気流
乾燥排ガスの一部と熱交換するための熱交換器と、 固気分離器からの水蒸気を含む気流乾燥排ガスの残部を
供給して水洗し除湿するための水洗式のスクラバーと、 水洗式のスクラバーからの乾燥排ガスを熱分解脱臭する
ために活性炭化装置に導入するための気流乾燥排ガス導
入手段と、を包含することを特徴とする汚泥の炭化処理
装置。
12. A powdery dry sludge which is separated by solid-gas separation in a solid-gas separator and circulated, is conveyed, mixed with the powdery dry sludge and a sludge dewatering cake, and further conveyed. And a mixing and supplying means for supplying the powdery sludge to the crusher of the flash drying device, and a portion of the powdery dry sludge which is conveyed and circulated by the mixing and supplying means and communicates with an upper part of the mixing and supplying means for storing the sludge. Along with the dry powder hopper provided and the dry sludge mixture from the mixing and feeding means, a part of the flash drying exhaust gas from the solid-gas separator is used as a heat source for flash drying by using a heat exchanger to convert the high temperature exhaust gas from the activated carbonizer into heat. A flash drying device for exchanging, heating and supplying to the crusher, crushing the dried sludge mixture with the crusher and drying with hot air, and further drying the obtained powdery dried sludge with hot air using a flash drying tube; Dry dust from the equipment A solid-gas separator for introducing a gas stream containing mud into powdery dry sludge and a gas stream drying exhaust gas containing steam generated in the drying process, and a powdery gas removed from the dry powder hopper. An activated carbonizer for producing activated carbide by carbonizing and activating dry sludge, and a heat exchanger for heat-exchanging high-temperature exhaust gas from the activated carbonizer with a part of the gas-flow dried exhaust gas from a solid-gas separator. And a scrubber of the washing type for supplying the remainder of the flash drying exhaust gas containing water vapor from the solid-gas separator to wash and dehumidify the water, and an activated carbon device for thermally deodorizing the drying exhaust gas from the washing scrubber. A sludge carbonization apparatus, comprising: a flash drying exhaust gas introduction means for introducing the flue gas into the sludge.
【請求項13】 固気分離器で固気分離されて循環する
粉体状の乾燥汚泥を搬送し、この粉体状の乾燥汚泥に汚
泥脱水ケーキを混合してさらに搬送し、この乾燥汚泥混
合物を気流乾燥装置の解砕機に供給するための混合供給
手段と、 混合供給手段で搬送され循環される粉体状の乾燥汚泥の
一部を取り出して貯留するための混合供給手段上部に連
通して設けられた乾燥粉体ホッパと、 混合供給手段からの乾燥汚泥混合物とともに、気流乾燥
用熱源として固気分離器からの気流乾燥排ガスの一部を
熱交換器で活性炭化装置からの高温排ガスと熱交換し加
熱して解砕機に供給し、解砕機で乾燥汚泥混合物を粉砕
して熱風乾燥させ、得られた粉体状の乾燥汚泥を気流乾
燥管でさらに熱風乾燥させる気流乾燥装置と、 気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と気流乾燥排ガスとに分離するた
めの固気分離器と、 乾燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭
化・賦活処理して活性炭化物を製造するための活性炭化
装置と、 活性炭化装置からの高温排ガスを固気分離器からの気流
乾燥排ガスの一部と熱交換するための熱交換器と、 固気分離器からの気流乾燥排ガスの残部を熱分解脱臭す
るために活性炭化装置に導入するための排ガス導入手段
と、 熱交換器で冷却された活性炭化装置からの排ガスの一部
を、固気分離器からの気流乾燥排ガスの残部とともに活
性炭化装置に導入するための活性炭化装置排ガス導入手
段と、を包含することを特徴とする汚泥の炭化処理装
置。
13. A powdery dry sludge which is separated by solid-gas separation by a solid-gas separator and circulated, is conveyed, mixed with the powdery dry sludge and a sludge dewatered cake, and further conveyed. And a mixing and supplying means for supplying the powdery sludge to the crusher of the flash drying device, and a portion of the powdery dry sludge which is conveyed and circulated by the mixing and supplying means and communicates with an upper part of the mixing and supplying means for storing the sludge. Along with the dry powder hopper provided and the dry sludge mixture from the mixing and feeding means, a part of the flash drying exhaust gas from the solid-gas separator is used as a heat source for flash drying by using a heat exchanger to convert the high temperature exhaust gas from the activated carbonizer into heat. A flash drying device for exchanging, heating and supplying to the crusher, crushing the dried sludge mixture with the crusher and drying with hot air, and further drying the obtained powdery dried sludge with hot air using a flash drying tube; Dry dust from the equipment A solid-gas separator for introducing an air stream containing mud into powdery dry sludge and flash drying exhaust gas, and carbonizing and activating powdery dry sludge taken out from the dry powder hopper. An activated carbonizer for producing activated carbon by heating; a heat exchanger for exchanging high-temperature exhaust gas from the activated carbonizer with a part of flash drying exhaust gas from a solid-gas separator; Exhaust gas introduction means for introducing the remaining part of the flash drying exhaust gas into the activated carbonization device for thermal decomposition and deodorization, and a part of the exhaust gas from the activated carbonization device cooled by the heat exchanger is supplied to the airflow from the solid-gas separator. An activated carbonization device exhaust gas introduction means for introducing the remaining portion of the dried exhaust gas into the activated carbonization device together with the remaining portion of the dried exhaust gas.
【請求項14】 固気分離器で固気分離されて循環する
粉体状の乾燥汚泥を搬送し、この粉体状の乾燥汚泥に汚
泥脱水ケーキを混合してさらに搬送し、この乾燥汚泥混
合物を気流乾燥装置の解砕機に供給するための混合供給
手段と、 混合供給手段で搬送され循環される粉体状の乾燥汚泥の
一部を取り出して貯留するための混合供給手段上部に連
通して設けられた乾燥粉体ホッパと、 混合供給手段からの乾燥汚泥混合物とともに、気流乾燥
用熱源として固気分離器からの気流乾燥排ガスの一部を
熱交換器で活性炭化装置からの高温排ガスと熱交換し加
熱して解砕機に供給し、解砕機で乾燥汚泥混合物を粉砕
して熱風乾燥させ、得られた粉体状の乾燥汚泥を気流乾
燥管でさらに熱風乾燥させる気流乾燥装置と、 気流乾燥装置からの粉体状の乾燥汚泥を含む気流を導入
して粉体状の乾燥汚泥と乾燥過程で発生した水蒸気を含
む気流乾燥排ガスとに分離するための固気分離器と、 乾燥粉体ホッパから取り出された粉体状の乾燥汚泥を炭
化・賦活処理して活性炭化物を製造するための活性炭化
装置と、 活性炭化装置からの高温排ガスを固気分離器からの気流
乾燥排ガスの一部と熱交換するための熱交換器と、 固気分離器からの水蒸気を含む気流乾燥排ガスの残部を
供給して水洗し除湿するための水洗式のスクラバーと、 水洗式のスクラバーからの乾燥排ガスを熱分解脱臭する
ために活性炭化装置に導入するための排ガス導入手段
と、 熱交換器で冷却された活性炭化装置からの排ガスの一部
を、水洗式のスクラバーで水洗・除湿された乾燥排ガス
とともに活性炭化装置に導入するための活性炭化装置排
ガス導入手段と、を包含することを特徴とする汚泥の炭
化処理装置。
14. A powdery dry sludge which is separated into a solid and a gas by a solid-gas separator and circulated, is conveyed, and the powdery dry sludge is mixed with a sludge dewatering cake and further conveyed. And a mixing and supplying means for supplying the powdery sludge to the crusher of the flash drying device, and a portion of the powdery dry sludge which is conveyed and circulated by the mixing and supplying means and communicates with an upper part of the mixing and supplying means for storing the sludge. Along with the dry powder hopper provided and the dry sludge mixture from the mixing and feeding means, a part of the flash drying exhaust gas from the solid-gas separator is used as a heat source for flash drying by using a heat exchanger to convert the high temperature exhaust gas from the activated carbonizer into heat. A flash drying device for exchanging, heating and supplying to the crusher, crushing the dried sludge mixture with the crusher and drying with hot air, and further drying the obtained powdery dried sludge with hot air using a flash drying tube; Dry dust from the equipment A solid-gas separator for introducing a gas stream containing mud into powdery dry sludge and a gas stream drying exhaust gas containing steam generated in the drying process, and a powdery gas removed from the dry powder hopper. An activated carbonizer for producing activated carbide by carbonizing and activating dry sludge, and a heat exchanger for heat-exchanging high-temperature exhaust gas from the activated carbonizer with a part of the gas-flow dried exhaust gas from a solid-gas separator. And a scrubber of the washing type for supplying the remainder of the flash drying exhaust gas containing water vapor from the solid-gas separator to wash and dehumidify the water, and an activated carbon device for thermally deodorizing the drying exhaust gas from the washing scrubber. Exhaust gas introduction means for introducing into the activated carbonizer, and a part of the exhaust gas from the activated carbonizer cooled by the heat exchanger together with the dry exhaust gas washed and dehumidified by the washing scrubber. Carbonization apparatus sludge characterized in that it comprises a reduction device exhaust gas introducing means.
【請求項15】 熱交換器で冷却された活性炭化装置か
らの排ガスを排気するための排気手段に、活性炭化装置
で製造された活性炭化物の一部を吹き込むための活性炭
化物吹込手段と、アルカリ剤を吹き込むためのアルカリ
剤吹込手段とを設け、前記排気手段に活性炭化物及びア
ルカリ剤が吹き込まれた排ガスが導入されるろ過式集塵
器を接続し、ろ過式集塵器のろ過体上に活性炭化物及び
アルカリ剤のコーティング層を形成させて、排ガス中の
有害物質を除去するようにした請求項9〜14のいずれ
かに記載の汚泥の炭化処理装置。
15. An activated carbide blowing means for injecting a part of the activated carbide produced by the activated carbon device into an exhaust device for exhausting exhaust gas from the activated carbon device cooled by the heat exchanger; An alkaline agent blowing means for injecting the agent, connecting a filtration type dust collector into which the exhaust gas into which the activated carbide and the alkaline agent have been injected is introduced to the exhaust means, and on a filter of the filtration type dust collector The sludge carbonization apparatus according to any one of claims 9 to 14, wherein a harmful substance in the exhaust gas is removed by forming a coating layer of an activated carbide and an alkali agent.
【請求項16】 活性炭化装置が、乾燥粉体ホッパから
投入される粉体状の乾燥汚泥を間接加熱するようになっ
ており、乾燥汚泥の移動方向の上流側が乾燥汚泥中の水
分を蒸発させるための低温の乾燥ゾーンで、乾燥汚泥の
移動方向に進むにつれて乾燥汚泥を熱分解して炭化する
ための炭化ゾーンとなり、乾燥汚泥の移動方向の下流側
が乾燥ゾーンで発生した水蒸気及び炭化ゾーンで発生し
た炭酸ガスにより炭化された汚泥を賦活するための高温
の賦活ゾーンとなっている請求項9〜15のいずれかに
記載の汚泥の炭化処理装置。
16. An activated carbonization device indirectly heats powdery dry sludge fed from a dry powder hopper, and evaporates moisture in the dry sludge on the upstream side in the moving direction of the dry sludge. Is a low-temperature drying zone, which becomes a carbonization zone for pyrolysis and carbonization of the dried sludge as it proceeds in the moving direction of the dried sludge, and the downstream side in the moving direction of the dried sludge is generated by steam and carbonized zone generated in the drying zone. The sludge carbonization apparatus according to any one of claims 9 to 15, which is a high-temperature activation zone for activating sludge carbonized by the carbon dioxide gas.
JP11232080A 1999-08-19 1999-08-19 Method and apparatus for carbonizing sludge Expired - Fee Related JP3077802B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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JP5504959B2 (en) * 2010-02-19 2014-05-28 大同特殊鋼株式会社 Sludge carbonization equipment
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