JP3064895B2 - Fat / oil emulsion composition and method for producing the same - Google Patents

Fat / oil emulsion composition and method for producing the same

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Publication number
JP3064895B2
JP3064895B2 JP8047160A JP4716096A JP3064895B2 JP 3064895 B2 JP3064895 B2 JP 3064895B2 JP 8047160 A JP8047160 A JP 8047160A JP 4716096 A JP4716096 A JP 4716096A JP 3064895 B2 JP3064895 B2 JP 3064895B2
Authority
JP
Japan
Prior art keywords
lactic acid
oil
complex
weight
milk protein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP8047160A
Other languages
Japanese (ja)
Other versions
JPH09238612A (en
Inventor
卓弥 辻中
厚子 田代
透 大西
愼一 橋本
敏彦 西山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaneka Corp
Original Assignee
Kaneka Corp
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Filing date
Publication date
Application filed by Kaneka Corp filed Critical Kaneka Corp
Priority to JP8047160A priority Critical patent/JP3064895B2/en
Publication of JPH09238612A publication Critical patent/JPH09238612A/en
Application granted granted Critical
Publication of JP3064895B2 publication Critical patent/JP3064895B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Dairy Products (AREA)
  • Confectionery (AREA)
  • Grain Derivatives (AREA)
  • Edible Oils And Fats (AREA)
  • General Preparation And Processing Of Foods (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、豊かな乳風味、呈
味、コク味および香りを有する油脂乳化組成物及びその
製造方法に関する。更に詳しくは、コーヒー用クリー
ム、ホイップ用クリーム、アイスクリーム等の水中油型
油脂乳化組成物、マーガリン、ショートニング等の油中
水型油脂乳化組成物、及びその製造方法に関する。
TECHNICAL FIELD The present invention relates to an oil-and-fat emulsified composition having a rich milky taste, taste, richness and aroma, and a method for producing the same. More specifically, the present invention relates to an oil-in-water type oil / fat emulsified composition such as coffee cream, whipped cream, ice cream and the like, a water-in-oil type oil / fat emulsified composition such as margarine and shortening, and a method for producing the same.

【0002】[0002]

【従来の技術】牛乳を遠心分離して得られる生クリーム
や、この生クリームをさらにチャーニングして得られる
バターは、天然の好ましい乳風味、呈味、コク味および
香りを有しており、ホイップ用、バタークリーム用、コ
ーヒー用等の他、製菓用、製パン用、調理用として幅広
く用いられている。しかしながら、生クリームやバター
は高価であること、また、その履歴加工条件(乳牛の種
類、飼料、分離温度、エージング条件、殺菌温度等)に
よりその物性は不安定であり、使用上制約されると言っ
た問題がある。
2. Description of the Related Art A fresh cream obtained by centrifuging milk and a butter obtained by further churning this fresh cream have a natural preferable milky taste, taste, richness and aroma, It is widely used for whipping, butter cream, coffee, etc., as well as for confectionery, baking, and cooking. However, the properties of raw cream and butter are expensive, and their physical properties are unstable due to their history processing conditions (type of dairy cow, feed, separation temperature, aging conditions, sterilization temperature, etc.), and there are restrictions on use. There's the problem I said.

【0003】これらの品質上、特性上及び価格上の問題
を解決するために、動植物性食用油脂を用いた合成クリ
ームやマーガリンが開発されている。しかし、これらの
合成クリームやマーガリンは風味的には満足できるもの
ではなく、乳風味、呈味、コク味および香りを発現させ
るために、多くの生クリーム或いはバターを使用してい
るのが現状である。
[0003] In order to solve these problems in terms of quality, characteristics and price, synthetic creams and margarines using animal and vegetable edible fats and oils have been developed. However, these synthetic creams and margarines are not satisfactory in flavor, and currently many fresh creams or butters are used in order to express milky taste, taste, richness and aroma. is there.

【0004】近年、これらの課題を解決するために、い
くつかの方法が提案されている。乳脂肪を用いる場合、
それがバターオイルの形であるとき、リン脂質は失われ
ており、乳脂肪と脱脂粉乳を用いて還元乳を作成する場
合、リン脂質を含有するバターミルクパウダーを添加す
ることにより乳のコクを与えることは従来周知の事実で
あり(乳技協資料、Vol.28、No.3、1987)、このリン脂
質と蛋白質が結合した構造を持つリポタンパク質を配合
する方法が見い出されている。
In recent years, several methods have been proposed to solve these problems. When using milk fat,
When it is in the form of butter oil, the phospholipids are lost, and when making reduced milk using milk fat and skim milk powder, the richness of the milk can be reduced by adding butter milk powder containing phospholipids. Giving is a well-known fact in the past (Nippon Gijutsu Kyokai, Vol. 28, No. 3, 1987), and a method of blending a lipoprotein having a structure in which this phospholipid and a protein are bound has been found.

【0005】例えば、卵黄を配合することにより天然生
クリームに近似した風味物性を有する気泡性乳化物の製
造方法(特開昭58−179454)、或いは水中油型
油脂乳化組成物中に脂質と蛋白質との結合体である脂質
蛋白質複合体を配合することにより、乳味感、コク味感
を向上させるという試み(特開平5−236896)が
なされている。
[0005] For example, a method for producing a foamed emulsion having a flavor property similar to that of a natural fresh cream by blending egg yolk (Japanese Patent Laid-Open No. 179454/1983), or a method of preparing an oil-in-water type oil-fat emulsion composition comprising lipid and protein (JP-A-5-236896) has been attempted to improve the milky feeling and the kokumi taste by blending a lipid protein complex which is a conjugate with lipoprotein.

【0006】しかしながら、これらいずれの方法に於い
ても風味を十分に満足させることはできず、さらに製造
面での手間やコスト等の点でも問題があるものである。
そこで本発明者らは、以上のような課題を解決するため
に、有機酸モノグリセリドと乳蛋白質との複合体を含有
する油脂乳化組成物及びその製造方法に関して特許出願
(特開平8−000170)をした。
[0006] However, none of these methods can sufficiently satisfy the flavor, and furthermore, there is a problem in terms of labor and cost in terms of production.
In order to solve the above problems, the present inventors have filed a patent application (Japanese Patent Application Laid-Open No. 8-000170) on an oil / fat emulsified composition containing a complex of an organic acid monoglyceride and a milk protein and a method for producing the same. did.

【0007】この有機酸モノグリセリドと乳蛋白質との
複合体を配合することで、上記の課題はある程度解決す
ることができた。しかしながら、風味を十分に満足させ
るためには乳成分を併用することが好ましく、更に香り
においては不十分なものである。
[0007] By blending a complex of this organic acid monoglyceride and milk protein, the above-mentioned problems could be solved to some extent. However, in order to sufficiently satisfy the flavor, it is preferable to use a milk component in combination, and the aroma is insufficient.

【0008】[0008]

【発明が解決しようとする課題】本発明は以上のような
状況を鑑み、少量の乳成分でも十分な乳風味、呈味、コ
ク味および香りを発現するクリーム類、マーガリン類等
の油脂乳化組成物及びその製造方法を提供するものであ
る。
DISCLOSURE OF THE INVENTION In view of the above situation, the present invention provides an emulsion composition of fats and oils such as creams and margarines which exhibit a sufficient milky taste, taste, richness and aroma even with a small amount of milk component. And a method of manufacturing the same.

【0009】[0009]

【課題を解決しょうとするための手段】本発明者らは上
記課題を解決すべく鋭意研究の結果、有機酸モノグリセ
リドと乳蛋白質との複合体を、さらに乳酸発酵処理する
ことにより、乳らしい風味、呈味、コク味および香りを
著しく向上させることを見い出し、本発明を完成するに
至った。
Means for Solving the Problems The inventors of the present invention have conducted intensive studies to solve the above-mentioned problems. As a result, the complex of organic acid monoglyceride and milk protein is further subjected to lactic acid fermentation treatment to obtain a milky flavor. The present inventors have found that the taste, kokumi and aroma are remarkably improved, and have completed the present invention.

【0010】即ち、本発明の第1は、有機酸モノグリセ
リドと乳蛋白質との複合体の乳酸発酵物を含有すること
を特徴とする油脂乳化組成物を、本発明の第2は、油相
又は水相に、有機酸モノグリセリドと乳蛋白質との複合
体の乳酸発酵物を添加することを特徴とする油脂乳化組
成物の製造方法をそれぞれ内容とするものである。
That is, a first aspect of the present invention is a fat and oil emulsified composition containing a lactic acid fermentation product of a complex of an organic acid monoglyceride and milk protein, and a second aspect of the present invention is an oil phase or A method for producing an oil-and-fat emulsified composition characterized by adding a lactic acid fermented product of a complex of an organic acid monoglyceride and a milk protein to an aqueous phase, respectively.

【0011】[0011]

【発明の実施の形態】以下、本発明について詳述する。
本発明の有機酸モノグリセリドと乳蛋白質との複合体に
用いられる有機酸モノグリセリドとしては、コハク酸モ
ノグリセリド、ジアセチル酒石酸モノグリセリド、クエ
ン酸モノグリセリド、酢酸モノグリセリド、及び乳酸モ
ノグリセリド等が挙げられ、これらは1種又は2種以上
組み合わせて用いられる。また、これら有機酸モノグリ
セリドの構成脂肪酸は、飽和脂肪酸であることが立体構
造的に有効に結合させることができるので望ましい。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
Examples of the organic acid monoglyceride used in the complex of the organic acid monoglyceride and milk protein of the present invention include succinic acid monoglyceride, diacetyltartaric acid monoglyceride, citrate monoglyceride, acetate monoglyceride, and lactic acid monoglyceride, and the like. It is used in combination of two or more. In addition, the constituent fatty acids of these organic acid monoglycerides are desirably saturated fatty acids because they can be effectively bonded in a three-dimensional structure.

【0012】本発明の有機酸モノグリセリドと乳蛋白質
との複合体に用いられる乳蛋白質は、カゼイン、特に非
ミセル状態の分子構造を持つカゼインを含有することが
望ましい。これらの非ミセル状態のカゼインとしては、
例えばカゼインアルカリであるナトリウムカゼイン、カ
リウムカゼイン、酸カゼイン等の他、生乳、還元全脂粉
乳液、脱脂乳、還元脱粉液、バターミルク、還元バター
ミルクパウダー液等にリン酸塩等のカルシウム封鎖剤を
添加したり、pHを4.4〜4.6に調整した沈殿物を
回収して得られるもの等が挙げられる。これらは1種又
は2種以上組み合わせて用いられる。
The milk protein used in the complex of the organic acid monoglyceride and milk protein of the present invention preferably contains casein, particularly casein having a non-micellar molecular structure. These non-micellar caseins include:
For example, in addition to sodium casein, potassium casein, and acid casein, which are alkali caseinates, calcium sequestering agents such as phosphates in raw milk, reduced whole milk powder, skim milk, reduced powder, buttermilk, reduced buttermilk powder, and the like. Or a precipitate obtained by collecting a precipitate whose pH has been adjusted to 4.4 to 4.6. These are used alone or in combination of two or more.

【0013】カゼインがミセルの状態をとっているか否
かを知る手段としては、カゼインがミセル状態の構造で
ある場合、それは約0.1〜0.5μmの直径を有する
リン酸カルシウム−カゼインの複合体の蛋白質微粒子と
して存在することが知られている。そこで本発明者ら
は、カゼインのミセル状態の構造を簡易に定量化する手
法として平均粒度分布により調べることに着目した。即
ち、レーザー回折式平均粒度分布測定装置(LA−50
0P、堀場製作所製)により蛋白質の粒度分布を調べ、
0.1〜0.5μmの直径を有する分布区分をカゼイン
のミセル状態とみなし、これより大きな粒度分布のもの
を非ミセル状態のカゼインと判断することにした。この
方法によると、本発明においては非ミセル状態のカゼイ
ン含量が乳蛋白質のうち好ましくは15%以上、更に好
ましくは30%以上である。
As a means for knowing whether or not casein is in a micellar state, when casein is in a micellar structure, it may be a complex of calcium phosphate-casein having a diameter of about 0.1 to 0.5 μm. It is known to exist as protein microparticles. Therefore, the present inventors focused on examining the micelle state of casein by means of an average particle size distribution as a technique for simply quantifying the structure. That is, a laser diffraction type average particle size distribution measuring device (LA-50)
0P, manufactured by Horiba, Ltd.)
The distribution section having a diameter of 0.1 to 0.5 μm was regarded as the micelle state of casein, and those having a larger particle size distribution were determined to be casein in the non-micellar state. According to this method, in the present invention, the casein content in a non-micellar state is preferably 15% or more, more preferably 30% or more, of milk proteins.

【0014】次に、本発明に用いられる有機酸モノグリ
セリドと乳蛋白質との複合体の製造方法を説明する。ま
ず、乳蛋白質を1〜50重量%濃度、好ましくは5〜2
5重量%濃度の水溶液を調製する。この際、蛋白質水溶
液のpHを通常6〜7の範囲に調整することが有機酸モ
ノグリセリドと有効に結合させる上で好ましい。次に、
このようにして調製した蛋白質水溶液を、通常50〜7
0℃の有機酸モノグリセリドの融点よりもわずかに高い
温度になるように加温する。そして、この蛋白質水溶液
に蛋白質の1/100〜1/1(重量比)の有機酸モノ
グリセリドを添加し、混合溶解をおこない、次いで超音
波均質機、ホモジナイザー、ホモミキサー、マイコロイ
ダー等の均質化手段により、有機酸モノグリセリドと乳
蛋白質との複合体を調製する。
Next, a method for producing a complex of the organic acid monoglyceride and milk protein used in the present invention will be described. First, the concentration of milk protein is 1 to 50% by weight, preferably 5 to 2%.
A 5% strength by weight aqueous solution is prepared. At this time, it is preferable to adjust the pH of the aqueous protein solution to a range of usually 6 to 7 in order to effectively combine with the organic acid monoglyceride. next,
The protein aqueous solution prepared in this manner is usually used for 50 to 7 days.
Heat to a temperature slightly above the melting point of the organic acid monoglyceride at 0 ° C. Then, 1/100 to 1/1 (weight ratio) of the organic acid monoglyceride of the protein is added to the aqueous protein solution, mixed and dissolved, and then homogenized by an ultrasonic homogenizer, a homogenizer, a homomixer, a mycolloider or the like. Thus, a complex of the organic acid monoglyceride and the milk protein is prepared.

【0015】本発明の有機酸モノグリセリドと乳蛋白質
との複合体は、こうして得られた水溶液をそのままの形
態で使用する場合は、保存上の点からUHTなどの殺菌
処理を施すことが望ましい。また水溶液の形態でも十分
に乳らしい風味の向上効果を有するが、取扱い、保存上
の点から噴霧乾燥、減圧乾燥、凍結乾燥等の手段により
乾燥処理を施しても良い。
The complex of the organic acid monoglyceride and milk protein of the present invention is desirably subjected to a sterilization treatment such as UHT from the viewpoint of preservation when the aqueous solution thus obtained is used as it is. The aqueous solution also has a sufficient milky flavor improving effect, but may be subjected to a drying treatment by means of spray drying, reduced pressure drying, freeze drying or the like from the viewpoint of handling and storage.

【0016】次に、本発明に用いられる有機酸モノグリ
セリドと乳蛋白質との複合体の乳酸発酵について説明す
る。本発明の乳酸発酵に用いられる乳酸菌は、乳製品の
主要な風味および香気成分であるジアセチルおよび乳酸
の生産能が高いものが好ましい。具体的には、ストレプ
トコッカス・ジアセチラクチス、ストレプトコッカス・
クレモリス、ロイコノストック・クレモリス、ロイコノ
ストック・デキストラニクム、ラクトバチルス・プラン
タルム、ラクトバチルス・ブルガリカス、ラクトバチル
ス・ヘルベテイカスおよびラクトバチルス・ブレビス等
が挙げられ、これらの1種又は2種以上を使用すればよ
い。
Next, the lactic acid fermentation of the complex of the organic acid monoglyceride and milk protein used in the present invention will be described. The lactic acid bacteria used in the lactic acid fermentation of the present invention are preferably those having a high ability to produce diacetyl and lactic acid, which are the main flavor and flavor components of dairy products. More specifically, Streptococcus diacetylactis, Streptococcus
Cremoris, Leuconostoc cremoris, Leuconostoc dextranicum, Lactobacillus plantarum, Lactobacillus bulgaricus, Lactobacillus helveuticus, Lactobacillus brevis, and the like. One or more of these may be used. I just need.

【0017】本発明の有機酸モノグリセリドと乳蛋白質
との複合体の乳酸菌の培養は、一般に用いられている条
件によって行うことができる。即ち、培地としては炭素
源、窒素源、無機質、ビタミン、アミノ酸を含む通常用
いられている培地が使用され得るが、更に乳糖、クエン
酸を含有することが望ましい。培養条件としては、好気
条件下および嫌気条件下のいずれでもよいが、好気条件
下での静置培養が好ましい。培地の初発pHは6〜8、
特に7付近が望ましく、培養温度は各乳酸菌株に適した
20〜40℃で行うのが好ましい。さらには、乳酸発酵
物の酸度が0.05〜2.0%の範囲に達するまで、上
記条件にて培養することが好ましい。酸度が0.05%
未満では十分な風味向上効果は得られず、また2.0%
を越えると酸味、酸味臭が強くなり風味的に好ましくな
い。
Cultivation of the complex of the organic acid monoglyceride and milk protein of the present invention with lactic acid bacteria can be carried out under generally used conditions. That is, as the medium, a commonly used medium containing a carbon source, a nitrogen source, an inorganic substance, a vitamin, and an amino acid can be used, and it is preferable that the medium further contains lactose and citric acid. Culture conditions may be either aerobic conditions or anaerobic conditions, but static culture under aerobic conditions is preferred. The initial pH of the medium is 6-8,
In particular, it is preferably around 7, and the culture temperature is preferably 20 to 40 ° C. suitable for each lactic acid bacteria strain. Furthermore, it is preferable to culture under the above conditions until the acidity of the lactic acid fermentation product reaches the range of 0.05 to 2.0%. Acidity is 0.05%
If less than 2.0%, a sufficient flavor improving effect cannot be obtained, and 2.0%
If it exceeds 3, the acidity and the sour odor become strong and the taste is not favorable.

【0018】尚、酸度の測定は「乳業技術綜典(上
巻)、酪農技術普及学会 P.350」を参照し、以下
の方法で行った。即ち、乳酸発酵物10gに水40mlを
加えたものに、フェノールフタレイン指示薬0.5mlを
加え、N/10水酸化ナトリウム溶液で滴定し、微紅色
が30秒間持続する点を終末点とし、次式により求め
た。
The measurement of the acidity was carried out by the following method with reference to "Daily Technology Collection (First Volume), Dairy Technology Promotion Association P.350". That is, 0.5 ml of a phenolphthalein indicator was added to 10 g of a lactic acid fermentation product and 40 ml of water were added, and titration was performed with an N / 10 sodium hydroxide solution. It was determined by the formula.

【0019】 酸度(%)=(Α×F×0.009/W)×100 Α:N/10水酸化ナトリウム溶液の滴定量(ml) F:N/10水酸化ナトリウム溶液の力価 W:試料採取料(10g) 上記のようにして得られる有機酸モノグリセリドと乳蛋
白質との複合体の乳酸発酵物は、こうして得られた水溶
液をそのままの形態でも、また取扱い、保存上の点から
噴霧乾燥、減圧乾燥、凍結乾燥等の手段により乾燥処理
を施しても良く、本発明に係わる油脂乳化組成物中の油
脂に対して、乾燥重量比で0.01〜20重量%配合す
ることが好ましい。配合量が0.01%未満では、豊か
な乳風味、呈味、コク味および香りの発現効果は不十分
であり、また20重量%を越えて添加しても効果は頭打
ちとなる。
Acidity (%) = (Α × F × 0.009 / W) × 100 Α: Titration of N / 10 sodium hydroxide solution (ml) F: Potency of N / 10 sodium hydroxide solution W: Sampling fee (10 g) The lactic acid fermentation product of the complex of organic acid monoglyceride and milk protein obtained as described above is spray-dried in the form of the aqueous solution obtained as it is, or in terms of handling and storage. Drying may be carried out by means such as drying under reduced pressure and freeze-drying, and it is preferable to mix the oils and fats in the oil and fat emulsion composition according to the present invention in a dry weight ratio of 0.01 to 20% by weight. If the compounding amount is less than 0.01%, the effect of expressing a rich milky flavor, taste, body taste and aroma is insufficient, and even if it is added in excess of 20% by weight, the effect levels off.

【0020】本発明の油脂乳化組成物は、公知の方法で
製造でき、食用油脂を主成分とする油相と、乳成分等を
含む水相を予備乳化した後、以下の通常の工程(均質
化、殺菌、冷却、エージング等)を経て調製される。本
発明において、有機酸モノグリセリドと乳蛋白質との複
合体の乳酸発酵物は油相、水相のいずれに添加しても良
いが、水溶液の形態のものを油相に添加することが望ま
しい。
The oil / fat emulsified composition of the present invention can be produced by a known method, and after preliminarily emulsifying an oil phase containing edible oil / fat as a main component and an aqueous phase containing dairy components, etc., , Sterilization, cooling, aging, etc.). In the present invention, the lactic acid fermentation product of the complex of the organic acid monoglyceride and the milk protein may be added to either the oil phase or the aqueous phase, but it is desirable to add the lactic acid fermentation product in the form of an aqueous solution to the oil phase.

【0021】本発明に用いられる油脂としては、通常食
用として用いられるものであれば、植物油脂、動物油
脂、或いはこれらの硬化、分別、エステル交換したもの
のいずれでもよく、これらのうち1種又は2種以上の油
脂を調合して使用することもできる。本発明で得られる
油脂乳化組成物の油脂の割合は、それが水中油型である
場合は5〜60重量%、油中水型である場合は30〜9
0重量%となる割合が好ましい。
The oils and fats used in the present invention may be vegetable oils and fats, animal fats and oils, or hardened, fractionated and transesterified ones thereof, as long as they are normally used as foods. More than one kind of fats and oils can be mixed and used. The proportion of fats and oils in the fat and oil emulsion composition obtained in the present invention is 5 to 60% by weight when the composition is oil-in-water, and 30 to 9 when the composition is water-in-oil.
A ratio of 0% by weight is preferable.

【0022】本発明の油脂乳化組成物の水相中には、特
に乳成分を配合することが好ましく、例えば生乳、脱脂
乳、全脱脂乳、バターミルク、乳清、生クリーム、チー
ズ類、ヨーグルト類、バターまたはこれらを濃縮、粉末
加工したものや、ミルクフレーバー、バターフレーバー
等の呈味剤、フレーバー等が挙げられる。またこの他、
糖類、乳化剤、増粘剤等の安定剤、調味料、香料及び着
色料等の添加物を水溶性のものは水相に、親油性のもの
は油相に、それぞれ配合することもできる。
In the aqueous phase of the oil / fat emulsified composition of the present invention, it is particularly preferable to mix a milk component. For example, raw milk, skim milk, whole skim milk, buttermilk, whey, fresh cream, cheeses, yogurt , Butter or those obtained by concentrating and powder-treating them, flavoring agents such as milk flavor and butter flavor, and flavors. In addition,
Additives such as saccharides, emulsifiers, thickeners, and other additives such as seasonings, flavors, and coloring agents can be added to the aqueous phase if water-soluble and to the oil phase if lipophilic.

【0023】本発明の油脂乳化組成物の製造方法として
は、まず油脂に親油性の乳化剤及び油溶性の配合体を添
加して調製した油相部と、一方で親水性の乳原料、乳化
剤及び水溶性の配合体を添加して調製した油相部を混合
攪拌して予備乳化を行う。次いで、それが水中油型油脂
乳化組成物である場合は、この乳化物をバルブ式ホモジ
ナイザー等の均質化装置を用いて均質化後、殺菌処理
し、必要に応じて再度均質化し、冷却して水中油型油脂
乳化組成物を得る。また、油中水型油脂乳化組成物の場
合は、予備乳化物を均一に攪拌しながら殺菌処理し、パ
ーフェクター、コンビネーター、ボテーター等の急冷捏
和機を通して安定化し、油中水型油脂乳化組成物を得
る。
The method for producing the oil / fat emulsified composition of the present invention is as follows: an oil phase prepared by adding a lipophilic emulsifier and an oil-soluble blend to an oil or fat; Preliminary emulsification is performed by mixing and stirring the oil phase portion prepared by adding the water-soluble compound. Then, when it is an oil-in-water type oil-fat emulsified composition, after homogenizing this emulsion using a homogenizer such as a valve-type homogenizer, sterilizing, homogenizing again if necessary, and cooling. An oil-in-water type oil / fat emulsified composition is obtained. In the case of a water-in-oil type oil / fat emulsified composition, the pre-emulsion is sterilized while being uniformly stirred, and stabilized through a quench machine such as a perfector, a combinator, and a votator. Obtain the composition.

【0024】[0024]

【実施例】次に、実施例を挙げて本発明を更に詳しく説
明するが、本発明はこれらに限定されるものではない。 製造例1〔有機酸モノグリセリドと乳蛋白質との複合体
(MP−1)の調製〕 ナトリウムカゼイン(商品名 ハプロ:新日本製薬株式
会社製)7重量%を92重量%の水に分散、溶解させ6
5℃まで加熱後、コハク酸モノグリセリド(商品名 ポ
エムB−10:理研ビタミン株式会社製)1重量%添加
し溶解後、超音波均質機(500W)にて均質化(5
分)し、コハク酸モノグリセリドと乳蛋白質との複合体
溶液を得た。 製造例2及び3〔有機酸モノグリセリドと乳蛋白質との
複合体(MP−2、3)の調製〕 表1に示す配合にて、脱脂粉乳、ヘキサメタリン酸ナト
リウムを水に分散溶解させ60℃まで加熱後、ジアセチ
ル酒石酸モノグリセリド(商品名 ポエムW−10:理
研ビタミン株式会社製)を添加し、バルブ式ホモジナイ
ザーにて60kg/cm2 で均質化後、140℃で4秒間U
HT殺菌して有機酸モノグリセリドと乳蛋白質との複合
体溶液を得た。
Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. Production Example 1 [Preparation of Complex (MP-1) of Organic Acid Monoglyceride and Milk Protein] 7% by weight of sodium casein (trade name: Haplo: manufactured by Nippon Pharmaceutical Co., Ltd.) is dispersed and dissolved in 92% by weight of water. 6
After heating to 5 ° C., 1% by weight of succinic acid monoglyceride (trade name: Poem B-10: manufactured by Riken Vitamin Co., Ltd.) was added and dissolved, and then homogenized with an ultrasonic homogenizer (500 W) (5 W).
To obtain a complex solution of succinic monoglyceride and milk protein. Production Examples 2 and 3 [Preparation of Complex (MP-2, 3) of Organic Acid Monoglyceride and Milk Protein] With the formulation shown in Table 1, skim milk powder and sodium hexametaphosphate were dispersed and dissolved in water and heated to 60 ° C. Thereafter, diacetyltartaric acid monoglyceride (trade name: Poem W-10: manufactured by Riken Vitamin Co., Ltd.) was added, and the mixture was homogenized with a valve-type homogenizer at 60 kg / cm 2.
HT sterilization was performed to obtain a complex solution of organic acid monoglyceride and milk protein.

【0025】上記複合体製造例に用いた乳蛋白質中の非
ミセル状態のカゼイン含有率(%)を調べた結果を表1
に示した。また、上記の各試料中の複合体の割合を定量
化するために、100ml容の密栓付三角フラスコに試料
30mlを入れ、20℃で15分間振とう後、遠心分離に
より、上層(ヘキサン層)20ml分取り出し、ヘキサン
を留去後、固形物量を精秤し試料中の脂質重量に対する
割合を求め、これを複合体形成に関与しなかった遊離脂
肪率(%)として表1に示した。
Table 1 shows the results of examining the non-micellar casein content (%) in the milk protein used in the above complex production example.
It was shown to. In addition, in order to quantify the ratio of the complex in each sample, 30 ml of the sample was placed in a 100 ml sealed conical flask, shaken at 20 ° C. for 15 minutes, and then centrifuged to separate the upper layer (hexane layer). After removing 20 ml of hexane and distilling off hexane, the solid content was precisely weighed to determine the ratio to the weight of lipid in the sample, and this was shown in Table 1 as the free fat ratio (%) not involved in complex formation.

【0026】[0026]

【表1】 [Table 1]

【0027】表1から明らかなように、乳蛋白質のうち
非ミセル状態のカゼイン含量が高い程、複合体の遊離脂
肪率は小さく、複合体を形成しやすいことがわかる。 製造例4〔複合体(MP−1)の乳酸発酵物(MPF−
1)の調製〕 上記、有機酸モノグリセリドと乳蛋白質との複合体(M
P−1)50重量%、脱脂粉乳5重量%、水45重量%
を溶解混合し滅菌したものに、マザースターター(10
%脱脂粉乳培地に乳酸菌として、ストレプトコッカス・
ジアセチラクチス(クリスチャン ハンセンス社製)を
0.7重量%、ストレプトコッカス・クレモリス(Stre
ptococus cremoris JDTA H-61)を0.3重量%接種
後、34℃で24時間前培養したもの)を1重量%接種
して、34℃で水溶液の酸度が0.65%になるまで静
置培養後、85℃で20分間加熱して、有機酸モノグリ
セリドと乳蛋白質との複合体の乳酸発酵物(MPF−
1)を得た。 製造例5〔非複合体の乳酸発酵物(MPF−2)の調
製〕 上記、MPF−1の製造において、表2に示す配合に変
更した以外は、同様の方法にて、非複合体の乳酸発酵物
(MPF−2)を得た。 製造例6〜7〔複合体の乳酸発酵物(MPF−3〜4)
の調製〕 上記、MPF−1の製造において、表2に示す配合に変
更した以外は、同様の方法にて、有機酸モノグリセリド
と乳蛋白質との複合体の乳酸発酵物(MPF−3〜4)
を得た。 製造例8〔複合体の乳酸発酵物(MPF−5)の調製〕 上記、有機酸モノグリセリドと乳蛋白質との複合体(M
P−2)80重量%、水20重量%を溶解混合し滅菌し
たものに、マザースターター(10%脱脂粉乳培地に乳
酸菌として、ラクトバチルス・ブルガリカス(Lactobac
illus bulgaricus JDTA B-5b)を1.0重量%接種後、
34℃で24時間前培養したもの)を1重量%接種し
て、34℃で水溶液の酸度が0.2%になるまで静置培
養後、85℃で20分間加熱して、有機酸モノグリセリ
ドと乳蛋白質との複合体の乳酸発酵物(MPF−5)を
得た。 製造例9〔複合体の乳酸発酵物(MPF−6)の調製〕 上記、MPF−5の製造において、表2に示す配合に変
更した以外は、同様の方法にて、有機酸モノグリセリド
と乳蛋白質との複合体の乳酸発酵物(MPF−6)を得
た。
As is clear from Table 1, the higher the casein content of the milk protein in the non-micellar state, the smaller the free fat percentage of the complex and the easier the complex is formed. Production Example 4 [lactic acid fermentation product of complex (MP-1) (MPF-
Preparation of 1)] The complex (M) of the above-described organic acid monoglyceride and milk protein
P-1) 50% by weight, 5% by weight of skim milk powder, 45% by weight of water
The mother starter (10
% Lactic acid bacteria in Streptococcus
0.7% by weight of diacetylactis (manufactured by Christian Hansens) and Streptococcus cremoris (Stre
After inoculating 0.3% by weight of ptococus cremoris JDTA H-61), 1% by weight was inoculated at 34 ° C. for 24 hours, and allowed to stand at 34 ° C. until the acidity of the aqueous solution became 0.65%. After the cultivation, the mixture was heated at 85 ° C. for 20 minutes to produce a lactic acid fermentation product of a complex of organic acid monoglyceride and milk protein (MPF-
1) was obtained. Production Example 5 [Preparation of Non-Complex Lactic Acid Fermented Product (MPF-2)] In the above-described production of MPF-1, a non-complex lactic acid fermentation product was prepared in the same manner except that the composition shown in Table 2 was changed. A fermentation product (MPF-2) was obtained. Production Examples 6-7 [lactic acid fermented product of complex (MPF-3-4)
Preparation of MPF-1] A lactic acid fermented product of a complex of organic acid monoglyceride and milk protein (MPF-3 to 4) in the same manner as described above, except that the composition shown in Table 2 was changed.
I got Production Example 8 [Preparation of complex lactic acid fermentation product (MPF-5)] The complex (M) of the above-mentioned organic acid monoglyceride and milk protein
P-2) A mother starter (Lactobacillus vulgaricus (Lactobac) as a lactic acid bacterium in a 10% skim milk medium was dissolved and mixed with 80% by weight of water and 20% by weight of water and sterilized.
illus bulgaricus JDTA B-5b) after 1.0% by weight inoculation,
1% by weight inoculated at 34 ° C. for 24 hours), incubated at 34 ° C. until the acidity of the aqueous solution became 0.2%, and then heated at 85 ° C. for 20 minutes to obtain organic acid monoglyceride and A lactic acid fermentation product (MPF-5) of a complex with milk protein was obtained. Production Example 9 [Preparation of Complex Lactic Acid Fermentation Product (MPF-6)] In the above-described production of MPF-5, an organic acid monoglyceride and milk protein were produced in the same manner except that the formulation shown in Table 2 was changed. A lactic acid fermentation product (MPF-6) of a complex with the above was obtained.

【0028】[0028]

【表2】 [Table 2]

【0029】実施例1(ホイップクリーム) ナタネ硬化油(融点32℃)20重量%、ヤシ硬化油
(融点35℃)6重量%バター脂肪(融点32℃)14
重量%を配合溶解した油相に、乳化剤としてレシチン
0.28重量%、有機酸モノグリセリドと乳蛋白質との
複合体の乳酸発酵物(MPF−1)8重量%を加えて油
相を調製した。
Example 1 (Whipped cream) 20% by weight of rapeseed oil (melting point 32 ° C.), 6% by weight of hardened coconut oil (melting point 35 ° C.) Butter fat (melting point 32 ° C.) 14
The oil phase was prepared by adding 0.28% by weight of lecithin as an emulsifier and 8% by weight of lactic acid fermentation product (MPF-1) of a complex of organic acid monoglyceride and milk protein to the oil phase in which the weight% was dissolved.

【0030】一方、脱脂粉乳4重量%、ヘキサメタリン
酸ナトリウム0.1重量%、蔗糖脂肪酸エステル(HL
B11)0.2重量%を水47.42重量%に溶解し水
相を調製した。60℃にて油相を水相に添加し、予備乳
化後50kg/cm2で均質化後、140℃で4秒間UHT
殺菌した後、再度100kg/cm2で均質化し、5℃まで
冷却して水中油型油脂乳化組成物を得た。このものを5
℃で一晩エージング後、水中油型油脂乳化組成物100
重量%に、グラニュー糖8重量%を混合し、ミキサーに
てホイップを行いホイップクリームを得た。 比較例1(ホイップクリーム) 実施例1において、MPF−1の代わりに有機酸モノグ
リセリドと乳蛋白質の未乳酸発酵物(MP−1)4重量
%、水3.6重量%を添加した以外は同様の方法で水中
油型油脂乳化組成物を作成し、同様にホイップしてホイ
ップクリームを得た。
On the other hand, skim milk powder 4% by weight, sodium hexametaphosphate 0.1% by weight, sucrose fatty acid ester (HL)
B11) 0.2% by weight was dissolved in 47.42% by weight of water to prepare an aqueous phase. The oil phase was added to the aqueous phase at 60 ° C, pre-emulsified and homogenized at 50 kg / cm 2 , and then UHT at 140 ° C for 4 seconds.
After sterilization, the mixture was homogenized again at 100 kg / cm 2 and cooled to 5 ° C. to obtain an oil-in-water oil / fat emulsion composition. This one is 5
After aging overnight at 100 ° C., the oil-in-water type oil-fat emulsified composition 100
8% by weight of granulated sugar was mixed with the mixture by weight and whipped with a mixer to obtain a whipped cream. Comparative Example 1 (Whipped cream) Same as Example 1, except that 4% by weight of non-lactic acid fermented product (MP-1) of organic acid monoglyceride and milk protein and 3.6% by weight of water were added instead of MPF-1. And a whipped cream was obtained in the same manner.

【0031】これらホイップクリーム風味の官能評価を
行ったところ、実施例1のクリームは比較例1のクリー
ムに比べ、より乳らしい風味が強く感じられ、特に後口
の乳の呈味、コク味が増強されていた。 実施例2(コーヒーホワイト用クリーム) 大豆硬化油(融点32℃)25重量%を溶解後、グリセ
リン脂肪酸エステル0.02重量%、有機酸モノグリセ
リドと乳蛋白質との複合体の乳酸発酵物(MPF−1)
5重量%を加えて油相を調製した。
When the whipped cream flavor was subjected to a sensory evaluation, the cream of Example 1 had a stronger milky flavor than the cream of Comparative Example 1, and the cream and the rich taste of the rear mouth were particularly strong. Had been strengthened. Example 2 (Cream for coffee white) After dissolving 25% by weight of hardened soybean oil (melting point 32 ° C.), 0.02% by weight of glycerin fatty acid ester, lactic acid fermentation product of a complex of organic acid monoglyceride and milk protein (MPF- 1)
An oil phase was prepared by adding 5% by weight.

【0032】一方、脱脂粉乳4重量%、蔗糖脂肪酸エス
テル(HLB15)0.2重量%、第2リン酸ナトリウ
ム0.02重量%を水65.76重量%に溶解し水相を
調製した。60℃にて油相を水相に徐々に添加し、予備
乳化後50kg/cm2で均質化後、140℃で4秒間UH
T殺菌した後、再度150kg/cm2で均質化し、5℃ま
で冷却してコーヒーホワイト用クリームを得た。 比較例2(コーヒーホワイト用クリーム) 実施例2において、有機酸モノグリセリドと乳蛋白質と
の複合体の乳酸発酵物(MPF−1)の代わりに、非複
合体の乳酸発酵物(MPF−2)を添加した以外は同様
の方法でコーヒーホワイト用クリームを得た。
On the other hand, 4% by weight of skim milk powder, 0.2% by weight of sucrose fatty acid ester (HLB15) and 0.02% by weight of dibasic sodium phosphate were dissolved in 65.76% by weight of water to prepare an aqueous phase. The oil phase was gradually added to the aqueous phase at 60 ° C, homogenized at 50 kg / cm 2 after pre-emulsification, and then subjected to UH at 140 ° C for 4 seconds.
After sterilization by T, the mixture was homogenized again at 150 kg / cm 2 and cooled to 5 ° C. to obtain a cream for coffee white. Comparative Example 2 (Cream for Coffee White) In Example 2, instead of the lactic acid fermentation product of a complex of organic acid monoglyceride and milk protein (MPF-1), a non-complex lactic acid fermentation product (MPF-2) was used. A cream for coffee white was obtained in the same manner except that it was added.

【0033】上記実施例2と比較例2のクリームを用い
てコーヒーテストを行った。即ち、インスタントコーヒ
ー2gを80℃の温水100mlに溶解し、その中にクリ
ームを10ml添加して官能評価を行った。実施例2のク
リームを添加したものは、乳らしい風味とコク味が強く
感じられ好ましかったが、比較例2のクリームを添加し
たものは、乳らしい風味は弱く、特にコク味はほとんど
感じられなかった。 実施例3(濃縮乳) 大豆油9重量%を加熱後、グリセリン脂肪酸エステル
0.1重量%と有機酸モノグリセリドと乳蛋白質との複
合体の乳酸発酵物(MPF−1)3重量%を加えて油相
を調製した。
Using the creams of Example 2 and Comparative Example 2, a coffee test was performed. That is, 2 g of instant coffee was dissolved in 100 ml of hot water at 80 ° C., and 10 ml of cream was added thereto, and the sensory evaluation was performed. The cream with the addition of the cream of Example 2 had a strong milky flavor and richness, which was favorable, whereas the cream with the cream of Comparative Example 2 had a weak milky flavor, and the bulky taste was particularly low. I couldn't. Example 3 (Concentrated Milk) After heating 9% by weight of soybean oil, 0.1% by weight of glycerin fatty acid ester and 3% by weight of lactic acid fermented product (MPF-1) of a complex of organic acid monoglyceride and milk protein were added. An oil phase was prepared.

【0034】一方、脱脂粉乳8重量%、ラクトース10
重量%、カラギーナン0.02重量%、蔗糖脂肪酸エス
テル(HLB15)0.05重量%を水69.83重量
%に溶解し水相を調製した。60℃にて油相を水相に徐
々に添加し、予備乳化後120kg/cm2で均質化後、1
40℃で4秒間UHT殺菌した後、再度150kg/cm2
で均質化し、10℃まで冷却して水中油型油脂乳化組成
物を得た。 実施例4および5(濃縮乳) 実施例3において、有機酸モノグリセリドと乳蛋白質の
乳酸発酵物(MPF−1)の代わりに、MPF−3およ
びMPF−4を添加した以外は同様の方法で水中油型油
脂乳化組成物を得た。
On the other hand, skim milk powder 8% by weight, lactose 10
Aqueous phase was prepared by dissolving 0.02% by weight of carrageenan, 0.05% by weight of sucrose fatty acid ester (HLB15) in 69.83% by weight of water. The oil phase was gradually added to the aqueous phase at 60 ° C., homogenized at 120 kg / cm 2 after pre-emulsification,
After UHT sterilization at 40 ° C for 4 seconds, 150 kg / cm 2 again
And cooled to 10 ° C. to obtain an oil-in-water oil / fat emulsion composition. Examples 4 and 5 (concentrated milk) In Example 3, water was added in the same manner as in Example 3, except that MPF-3 and MPF-4 were added instead of the organic acid monoglyceride and the lactic acid fermented product of milk protein (MPF-1). An oil-type oil-fat emulsion composition was obtained.

【0035】上記実施例3〜5の濃縮乳を用いて、ホワ
イトソースを作成し、食味評価を実施した。即ち、ショ
ートニング8重量%に小麦粉8重量%を加え、加熱しな
がらよく攪拌し、ルーを調製した。このルーを40℃に
冷やしたところに、水で3倍に希釈した実施例3〜5の
水中油型油脂乳化組成物を60℃に温めたもの100重
量%を加え、混合加熱後、食塩0.35重量%、コショ
ウ0.035重量%で味を整えてホワイトソースを作成
した。
Using the concentrated milks of Examples 3 to 5, white sauces were prepared, and the taste was evaluated. That is, 8% by weight of flour was added to 8% by weight of shortening, and the mixture was stirred well while heating to prepare a roux. After the roux was cooled to 40 ° C., 100% by weight of the oil-in-water type oil-and-fat emulsified compositions of Examples 3 to 5 diluted to 3 times with water and heated to 60 ° C. were added. The taste was adjusted with 0.35% by weight and pepper at 0.035% by weight to prepare a white sauce.

【0036】いずれのホワイトソースも、豊かな乳の風
味、呈味、コク味および香りが感じられ好ましかった
が、特に乳糖を添加した乳酸発酵物を用いた実施例4の
ホワイトソースはより乳の風味が強く、更に乳糖とクエ
ン酸を添加した乳酸発酵物を用いた実施例5のホワイト
ソースは、後口の乳のコク味がより一層強調されてい
た。 実施例6(パン練り込み用マーガリン) 乳脂肪(融点32℃)20重量%、大豆硬化油(融点3
0℃)60重量%、水7.8重量%にリパーゼ(リパー
ゼNo.600 マイルス社製)0.02重量%を添加
し、37℃で1時間攪拌後、85℃で15分間加熱し、
酵素を失活させた油脂に、レシチン 0.2重量%を添
加し油相を調製した。
Each of the white sauces was preferable because it had a rich milky taste, taste, richness and aroma, but the white sauce of Example 4 using the lactic acid fermented product to which lactose was added was particularly preferable. In the white sauce of Example 5 using a lactic acid fermented product to which milk was strong and lactose and citric acid were further added, the body taste of the rear mouth milk was further emphasized. Example 6 (Margarine for Bread Kneading) 20% by weight of milk fat (melting point 32 ° C.), hydrogenated soybean oil (melting point 3
Lipase (Lipase No. 600, manufactured by Miles Co.) 0.02% by weight was added to 60% by weight (0 ° C.) and 7.8% by weight of water, followed by stirring at 37 ° C. for 1 hour and heating at 85 ° C. for 15 minutes.
0.2% by weight of lecithin was added to the fat in which the enzyme had been inactivated to prepare an oil phase.

【0037】この油脂に、一方で有機酸モノグリセリド
と乳蛋白質との複合体の乳酸発酵物(MPF−5)10
重量%、食塩2重量%を混合した水相を徐々に添加し、
予備乳化したものを80℃で15分間殺菌し、次いでコ
ンビネータにて急冷可塑化して油中水型油脂乳化組成物
を得た。 実施例7(パン練り込み用マーガリン) 実施例6において、有機酸モノグリセリドと乳蛋白質と
の複合体の乳酸発酵物(MPF−5)の代わりに、MP
F−6を添加した以外は同様の方法にて、油中水型油脂
乳化組成物を得た。 比較例3(パン練り込み用マーガリン) 実施例6において、有機酸モノグリセリドと乳蛋白質と
の複合体の乳酸発酵物(MPF−5)の代わりに、14
%脱脂粉乳液を添加した以外は同様の方法にて、油中水
型油脂乳化組成物を得た。
On the other hand, a lactic acid fermentation product (MPF-5) of a complex of an organic acid monoglyceride and milk protein was added to this fat or oil.
% By weight, and an aqueous phase containing 2% by weight of salt is gradually added.
The pre-emulsified product was sterilized at 80 ° C. for 15 minutes, and then quenched and plasticized by a combinator to obtain a water-in-oil type oil / fat emulsified composition. Example 7 (Margarine for Bread Kneading) In Example 6, instead of lactic acid fermentation product (MPF-5) of a complex of organic acid monoglyceride and milk protein, MP
A water-in-oil type oil / fat emulsified composition was obtained in the same manner except that F-6 was added. Comparative Example 3 (Margarine for Bread Kneading) In Example 6, instead of lactic acid fermentation product (MPF-5) of a complex of organic acid monoglyceride and milk protein, 14
% Water-in-oil type oil / fat emulsified composition was obtained in the same manner except that a% skim milk powder was added.

【0038】上記実施例6、7および比較例3の油中水
型油脂乳化組成物を用いて食パンを作成し、風味評価を
行った。即ち、強力小麦粉70重量%にイースト2重量
%、イーストフード0.1重量%、水41重量%を加え
て軽く混ぜ合わせ、生地(中種)をつくり、27℃で4
時間半発酵させた。その後、これに強力小麦粉30重量
%、食塩2重量%、砂糖5重量%、脱脂粉乳1重量%、
水23重量%と、上記実施例6、7および比較例3の油
中水型油脂乳化組成物をそれぞれ7重量%加え、本練り
を十分に行った。
Bread was prepared using the water-in-oil type oil / fat emulsified compositions of Examples 6 and 7 and Comparative Example 3 and evaluated for flavor. That is, 2% by weight of yeast, 0.1% by weight of yeast food, and 41% by weight of water are added to 70% by weight of strong flour and lightly mixed to form a dough (medium seed).
Fermented for half an hour. After that, strong wheat flour 30% by weight, salt 2% by weight, sugar 5% by weight, skim milk powder 1% by weight,
23% by weight of water and 7% by weight of each of the water-in-oil type oil / fat emulsified compositions of Examples 6 and 7 and Comparative Example 3 were added, and the kneading was sufficiently performed.

【0039】次に生地を分割し、丸めて中間ホイロに入
れ、30℃で20分間保持した。次に成型し、型詰めし
て38℃で50分間発酵させ、最後に215℃で30分
オーブンで焼成し、食パンを作成した。実施例6および
7の油中水型油脂乳化組成物を添加したものは、比較例
3の油中水型油脂乳化組成物を添加したものに比べて乳
のコクが強く感じられ、特に香ばしい香りが顕著に向上
していた。
Next, the dough was divided, rolled and put into an intermediate wheel, and kept at 30 ° C. for 20 minutes. Next, it was molded, molded and fermented at 38 ° C. for 50 minutes, and finally baked in an oven at 215 ° C. for 30 minutes to prepare bread. In the case of adding the water-in-oil type fat / oil emulsified composition of Examples 6 and 7, the richness of milk was felt more strongly as compared with the case where the water-in-oil type fat / oil emulsified composition of Comparative Example 3 was added, and the fragrance was particularly fragrant. Was significantly improved.

【0040】また、実施例7のミセル状態のカゼイン含
量の多い乳蛋白質との複合体を乳酸発酵したものを用い
たパンは、非ミセル状態のカゼイン含量の多い乳蛋白質
との複合体を乳酸発酵したものを用いたパンに比べ、乳
の後口のコク味がより一層強く感じられ美味であった。
The bread using the lactic acid-fermented complex of the micellar state and the milk protein having a high casein content in Example 7 was obtained by lactic acid fermentation of the complex with the non-micellar state of the milk protein having a high casein content. Compared to the bread using the dried bread, the body taste of the rear mouth of the milk was more strongly felt and delicious.

【0041】[0041]

【発明の効果】叙上のとおり、本発明の有機酸モノグリ
セリドと乳蛋白質との複合体の乳酸発酵物を油脂乳化組
成物の製造の際に添加することにより、少量の乳成分で
も乳風味、呈味、コク味および香りを著しく向上させる
ことができる。
As described above, the lactic acid fermented product of the complex of the organic acid monoglyceride and the milk protein of the present invention is added during the production of the oil-and-fat emulsified composition, so that even a small amount of the milk component has a milk flavor, Taste, body taste and aroma can be remarkably improved.

フロントページの続き (72)発明者 西山 敏彦 兵庫県神戸市西区樫野台5丁目3−2− 108 (56)参考文献 特開 平8−170(JP,A) 特開 昭61−21075(JP,A) 特公 昭40−21229(JP,B1) (58)調査した分野(Int.Cl.7,DB名) A23C 11/00 - 11/04 A23D 7/00 A23L 1/19 A23L 1/22 - 1/226 Continuation of the front page (72) Inventor Toshihiko Nishiyama 5-2-2-10 Kashinodai, Nishi-ku, Kobe-shi, Hyogo (56) References JP-A-8-170 (JP, A) JP-A-61-21075 (JP, A) (Japanese) 40-21229 (JP, B1) (58) Fields investigated (Int. Cl. 7 , DB name) A23C 11/00-11/04 A23D 7/00 A23L 1/19 A23L 1/22-1 / 226

Claims (7)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 有機酸モノグリセリドと乳蛋白質との複
合体を、ジアセチルおよび乳酸の生産能が高い乳酸菌に
より乳酸発酵して得られる乳酸発酵物を含有することを
特徴とする食品用油脂乳化組成物。
1. A complex of an organic acid monoglyceride and milk protein is converted into a lactic acid bacterium having a high ability to produce diacetyl and lactic acid.
An oil-and-fat emulsified composition for food, comprising a lactic acid fermented product obtained by more lactic acid fermentation .
【請求項2】 有機酸モノグリセリドと乳蛋白質との複
合体、乳糖、及び/又はクエン酸を、ジアセチルおよび
乳酸の生産能が高い乳酸菌により乳酸発酵して得られる
乳酸発酵物を含有することを特徴とする食品用油脂乳化
組成物。
2. A complex of an organic acid monoglyceride and milk protein, lactose and / or citric acid is converted into diacetyl and
An oil-and-fat emulsified composition for food, comprising a lactic acid fermented product obtained by lactic acid fermentation by a lactic acid bacterium having a high lactic acid-producing ability .
【請求項3】 有機酸モノグリセリドが、コハク酸モノ
グリセリド、ジアセチル酒石酸モノグリセリド、クエン
酸モノグリセリド、酢酸モノグリセリド、及び乳酸モノ
グリセリドからなる群から選ばれる1種又は2種以上で
ある請求項1又は2記載の食品用油脂乳化組成物。
Wherein an organic acid monoglyceride is succinic acid monoglyceride, diacetyl tartaric acid monoglyceride, citric acid monoglyceride, acetic acid monoglyceride, and one or more in food products according to claim 1 or 2, wherein the member selected from the group consisting of lactic acid monoglyceride Fat emulsified composition for use .
【請求項4】 乳蛋白質が非ミセル状態の分子構造をも
つカゼインを含有する乳蛋白質である請求項1〜3のい
ずれか1項に記載の食品用油脂乳化組成物。
4. The method of claim milk protein is a milk protein containing the casein with a molecular structure of the non-micelle state 1-3 Neu
2. The oil / fat emulsified composition for food according to claim 1.
【請求項5】 乳酸発酵に用いる乳酸菌が、ラクトバチ
ルス属、ストレプトコッカス属、及びロイコノストック
属に属する菌株から選択される1種又は2種以上である
請求項1〜4のいずれか1項に記載の食品用油脂乳化組
成物。
5. The lactic acid bacterium used for lactic acid fermentation, Lactobacillus, Streptococcus, and Leuconostoc one selected from a strain belonging to the stock genus or two or more at which any one of claims 1 to 4 An oil-and-fat emulsified composition for food according to the above.
【請求項6】 油相又は水相に、有機酸モノグリセリド
と乳蛋白質との複合体をジアセチルおよび乳酸の生産能
が高い乳酸菌により乳酸発酵して得られる乳酸発酵物を
添加することを特徴とする食品用油脂乳化組成物の製造
方法。
6. A diacetyl and lactic acid-producing ability of a complex of an organic acid monoglyceride and milk protein in an oil phase or an aqueous phase.
A method for producing an oil-and-fat emulsified composition for food , comprising adding a lactic acid fermented product obtained by lactic acid fermentation with a lactic acid bacterium having a high content.
【請求項7】 有機酸モノグリセリドと乳蛋白質との複
合体を、ジアセチルおよび乳酸の生産能が高い乳酸菌に
より乳酸発酵して得られる乳酸発酵物を、水溶液状態で
油相に添加する請求項6記載の製造方法。
7. A lactic acid bacterium having a high ability to produce diacetyl and lactic acid by converting a complex of an organic acid monoglyceride and milk protein.
The production method according to claim 6, wherein the lactic acid fermentation product obtained by lactic acid fermentation is added to the oil phase in an aqueous solution state.
JP8047160A 1996-03-05 1996-03-05 Fat / oil emulsion composition and method for producing the same Expired - Lifetime JP3064895B2 (en)

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* Cited by examiner, † Cited by third party
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US20060251637A1 (en) * 2003-03-11 2006-11-09 Toshinori Ikehara Oil-in-water type emulsion containing coenzyme q10 and process for producting the same
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