JP2984916B2 - Hard coat film - Google Patents
Hard coat filmInfo
- Publication number
- JP2984916B2 JP2984916B2 JP9090062A JP9006297A JP2984916B2 JP 2984916 B2 JP2984916 B2 JP 2984916B2 JP 9090062 A JP9090062 A JP 9090062A JP 9006297 A JP9006297 A JP 9006297A JP 2984916 B2 JP2984916 B2 JP 2984916B2
- Authority
- JP
- Japan
- Prior art keywords
- film
- hard coat
- particle diameter
- secondary particle
- average secondary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【０００１】[0001]
【発明が属する技術分野】本発明は、ハードコートフィ
ルムに関し、特にＣＲＴディスプレイやフラットパネル
ディスプレイ（液晶表示体、プラズマディスプレイ、Ｅ
Ｌディスプレイ等）の表面に用いる防眩フィルムとして
適したハードコートフィルムに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hard coat film, and particularly to a CRT display and a flat panel display (liquid crystal display, plasma display, E
L display, etc.).
【０００２】[0002]
【従来技術】従来より、プラスチックフィルム等の支持
基材表面にシリカ微粒子等及び電離放射線硬化型樹脂等
からなる層を設け、プラスチックフィルム表面に、防眩
性、耐薬品性及び耐擦傷性の機能を付与したハードコー
トフィルムが種々提案されている。特に、液晶表示体の
高精細化に対応して視認性を向上させるために、従来、
平均粒径が１μｍ〜２μｍのシリカ粒子を使用し、１０
０μｍ角あたり、０．５〜２μｍの凸部を５〜２０個有
するフィラー配合方式のノングレアシートが提案されて
いる（特開平７−１８１３０６）が、その効果は未だ十
分と言えるものではなかった。2. Description of the Related Art Conventionally, a layer made of silica fine particles and an ionizing radiation curable resin has been provided on the surface of a support substrate such as a plastic film, and the surface of the plastic film has functions of antiglare property, chemical resistance and scratch resistance. There have been proposed various types of hard coat films provided with. In particular, in order to improve visibility in response to higher definition of liquid crystal display,
Using silica particles having an average particle size of 1 μm to 2 μm,
A non-glare sheet of a filler compounding type having 5 to 20 convex portions of 0.5 to 2 μm per square of 0 μm has been proposed (Japanese Patent Application Laid-Open No. 7-181306), but the effect has not yet been said to be sufficient.
【０００３】[0003]
【発明が解決しようとする課題】そこで、本発明者等
は、微粒子を用いたハードコートフィルムの視認性に関
して鋭意検討を行った結果、ハードコートフィルムを通
して表示を見た場合、バックライトの光等が、該フィル
ム内の大きな粒子で大きく散乱したり、後方散乱する光
の割合が増加するためにギラツキが発生し、これが視認
性を悪化させるので、従来の如き、粒度分布に対して全
く配慮していない通常のフィラー配合方式では、必然的
に含有される大きな粒径の粒子によって視認性が悪化す
ること、及び、特に透過鮮明度を２０％以上とし、反射
鮮明度を２０．１％以下とすることにより視認性を改善
することができることを見出し、本発明に到達した。従
って本発明の目的は、防眩性のみならず視認性にも優れ
たハードコートフィルムを提供することにある。Accordingly, the present inventors have conducted intensive studies on the visibility of a hard coat film using fine particles, and as a result, when a display was viewed through the hard coat film, the light of a backlight or the like was observed. However, large scattering in the large particles in the film or an increase in the percentage of light backscattered causes glare, which deteriorates visibility, so that, as in the conventional case, the particle size distribution is completely considered. In a normal filler compounding method which is not included, visibility is deteriorated by particles having a large particle size which is inevitably contained, and in particular, transmission clarity is set to 20% or more, and reflection clarity is set to 20.1% or less. found that it is possible to improve visibility by be Rukoto, we have reached the present invention. Accordingly, an object of the present invention is to provide a hard coat film which is excellent not only in antiglare properties but also in visibility.
【０００４】[0004]
【課題を解決するための手段】 本発明の上記の目的
は、透明プラスチックフィルムの少なくとも一方の面
に、平均二次粒子径が１．７μｍ〜２μｍであると共に
平均二次粒子径の標準偏差が０．２〜０．７の微粒子及
び電離放射線硬化型樹脂からなる組成物に電離放射線を
照射し硬化させた硬化被膜層を設けてなる、透過鮮明度
（透過Ｃ （２．０） ）が２０％以上であると共に反射鮮
明度（反射Ｃ （２．０） ）が２０．１％以下であること
を特徴とするハードコートフィルムによって達成され
た。Means for Solving the Problems The object of the present invention is to provide a transparent plastic film having an average secondary particle diameter of at least one surface of at least one surface. A composition comprising fine particles having an average secondary particle diameter of 7 to 2 μm and a standard deviation of an average secondary particle diameter of 0.2 to 0.7 and an ionizing radiation curable resin is provided with a cured film layer which is irradiated with ionizing radiation and cured. Become transparent clarity
(Transmission C (2.0) ) is 20% or more, and
This was achieved by a hard coat film characterized by a brightness (reflection C (2.0) ) of 20.1% or less .
【０００５】[0005]
【発明の実施の形態】本発明に使用する透明プラスチッ
クフィルムは、特に限定されるものではなく公知の透明
プラスチックフィルムの中から適宜選択して用いること
が出来る。このような透明プラスチックフィルムとして
は、例えば、ポリエステルフィルム、ポリエチレンフィ
ルム、ポリプロピレンフィルム、セロファンフィルム、
ジアセチルセルロースフィルム、トリアセチルセルロー
スフィルム、アセチルセルロースブチレートフィルム、
ポリ塩化ビニルフィルム、ポリ塩化ビニリデンフィル
ム、ポリビニルアルコールフィルム、エチレンビニルア
ルコールフィルム、ポリスチレンフィルム、ポリカーボ
ネートフィルム、ポリメチルペンテルフィルム、ポリス
ルフォンフィルム、ポリエーテルエーテルケトンフィル
ム、ポリエーテルスルフォンフィルム、ポリエーテルイ
ミドフィルム、ポリイミドフィルム、フッ素樹脂フィル
ム、ナイロンフィルム、アクリルフィルム等を挙げるこ
とが出来るが、本発明においては、特に光学異方性が無
いという特徴から液晶表示体に偏光板の部材として広く
実用されている、トリアセチルセルロースフィルムを使
用することが好ましい。BEST MODE FOR CARRYING OUT THE INVENTION The transparent plastic film used in the present invention is not particularly limited, and can be appropriately selected from known transparent plastic films. As such a transparent plastic film, for example, a polyester film, a polyethylene film, a polypropylene film, a cellophane film,
Diacetyl cellulose film, triacetyl cellulose film, acetyl cellulose butyrate film,
Polyvinyl chloride film, polyvinylidene chloride film, polyvinyl alcohol film, ethylene vinyl alcohol film, polystyrene film, polycarbonate film, polymethylpentel film, polysulfone film, polyetheretherketone film, polyethersulfone film, polyetherimide film, Polyimide film, fluororesin film, nylon film, acrylic film and the like can be mentioned, but in the present invention, it is widely used as a member of a polarizing plate in a liquid crystal display from the feature that there is no particular optical anisotropy, It is preferable to use a triacetyl cellulose film.
【０００６】本発明で使用する微粒子は、平均二次粒子
径が１．７μｍ〜２μｍ、かつ平均二次粒子径の標準偏
差が０．２〜０．７であって、電離放射線硬化型樹脂に
分散させることが出来るものであれば特に限定されるも
のではない。上記微粒子としては、例えば、シリカ、ア
ルミナ、ジルコニア等の無機微粒子の他、電離放射線硬
化樹脂の透明性を損なわないように、電離放射線硬化型
樹脂の屈折率に近い、例えば、アクリル樹脂、ポリスチ
レン樹脂、ポリ塩化ビニル樹脂、ポリカーボネート樹
脂、ＰＭＭＡ樹脂等のポリマービーズも使用されるが、
防眩性や解像性等の点からシリカ粒子が好ましい。上記
微粒子は、公知の方法によって被膜層塗布液に混合・分
散させることにより、容易に硬化被膜層に含有させるこ
とが出来る。The fine particles used in the present invention have an average secondary particle diameter of 1. It is not particularly limited as long as it is 7 μm to 2 μm, the standard deviation of the average secondary particle diameter is 0.2 to 0.7 , and it can be dispersed in the ionizing radiation-curable resin. As the fine particles, for example, silica, alumina, other inorganic fine particles such as zirconia, so as not to impair the transparency of the ionizing radiation-curable resin, close to the refractive index of the ionizing radiation-curable resin, for example, acrylic resin, polystyrene resin Although polymer beads such as polyvinyl chloride resin, polycarbonate resin and PMMA resin are also used,
Silica particles are preferred from the viewpoint of anti-glare properties and resolution. The fine particles can be easily contained in the cured coating layer by mixing and dispersing in the coating liquid for the coating layer by a known method.
【０００７】被膜層に含有される微粒子の含有量は、被
膜層の透過鮮明度（透過Ｃ（２．０））が２０％以上で
あると共に、反射鮮明度（反射Ｃ（２．０））が２０．
１％以下となるように設定する。例えば、３〜１０μｍ
厚の硬化被膜層を設ける場合には、上記平均二次粒子径
の微粒子を５〜２０重量％含有させる。尚、上記透明鮮
明度及び反射鮮明度は、ＪＩＳＫ７１０５の６．６に従
って測定されるものであり、透過Ｃ（２．０）及び反射
Ｃ（２．０）は、それぞれ、光学くしの幅が２ｍｍの場
合の測定値を表す。The content of the fine particles contained in the coating layer is such that the transmission clarity (transmission C (2.0) ) of the coating layer is 20% or more and the reflection clarity (reflection C (2.0) ). Is 20.
Set so that it is 1 % or less. For example, 3 to 10 μm
When a thick cured film layer is provided, the fine particles having the above average secondary particle diameter are contained in an amount of 5 to 20% by weight. The clear clarity and the reflective clarity are measured according to 6.6 of JIS K7105, and the transmission C (2.0) and the reflection C (2.0) each have an optical comb width of 2 mm. Represents the measured value in the case of
【０００８】本発明において使用する電離放射線硬化型
樹脂は、電子線又は紫外線等を照射することによって硬
化する透明な樹脂であれば特に限定されるものではな
く、例えば、ウレタンアクリレート系樹脂、ポリエステ
ルアクリレート系樹脂及びエポキシアクリレート系樹脂
等の中から適宜選択することができる。[0008] The ionizing radiation-curable resin used in the present invention is not particularly limited as long as it is a transparent resin which is cured by irradiating an electron beam or ultraviolet rays or the like. Examples thereof include urethane acrylate resins and polyester acrylates. It can be appropriately selected from resin-based resins and epoxy acrylate-based resins.
【０００９】被膜塗布液をフィルムに塗布するに際して
は、塗布を容易とし塗布膜の厚さを均一とする観点か
ら、前記被膜塗布液に、適宜溶剤を添加したり、電離放
射線硬化を阻害しない範囲で各種の添加剤を添加し、塗
布液の粘度及び性質を調整することも出来る。上記溶剤
としては、例えばイソプロピルアルコール、エタノール
等のアルコール系溶剤、トルエン、キシレン等の芳香族
炭化水素系溶剤、酢酸エチル等のエステル系溶剤、アセ
トン等のケトン系溶剤等を挙げることが出来る。In applying the coating solution to the film, from the viewpoint of facilitating the application and making the thickness of the coating film uniform, a solvent is appropriately added to the coating solution or the ionizing radiation curing is not hindered. , Various additives can be added to adjust the viscosity and properties of the coating solution. Examples of the solvent include alcohol solvents such as isopropyl alcohol and ethanol, aromatic hydrocarbon solvents such as toluene and xylene, ester solvents such as ethyl acetate, and ketone solvents such as acetone.
【００１０】被膜層を設けるに際しては、公知のスプレ
ーコート、グラビアコート、ロールコート、バーコート
等の塗布法を用いることが出来る。塗布量は、必要とさ
れる特性と透過度及び反射鮮明度を考慮し、所望の厚さ
となるように適宜調整される。本発明においては、フィ
ルム上に前記被膜塗布液を塗布して設けた被膜層に、電
離放射線、例えば電子線や紫外線等を照射することによ
り、該被膜層を硬化させる。In providing the coating layer, known coating methods such as spray coating, gravure coating, roll coating, and bar coating can be used. The coating amount is appropriately adjusted so as to have a desired thickness in consideration of required characteristics, transmittance and reflection sharpness. In the present invention, the coating layer formed by applying the coating liquid on a film is irradiated with ionizing radiation, for example, an electron beam or ultraviolet light, to cure the coating layer.
【００１１】特に紫外線を照射する場合には、ハロゲン
ランプ等の公知の大型の光源を用いて被膜層に紫外線を
照射し、硬化させる。硬化は、例えば、１２０〜２４０
Ｗ／ｃｍのハロゲンランプを、１０〜２０ｃｍの距離か
ら数秒間照射することにより容易に行うことが出来る。
このようにして得られた本発明のハードコートフィルム
は、車載用計器盤、コンピューターやテレビのディスプ
レイ用途、特に、液晶表示体の表面に貼着して使用する
防眩フィルムとして好適である。In particular, when irradiating ultraviolet rays, the coating layer is irradiated with ultraviolet rays using a known large light source such as a halogen lamp and cured. Curing is, for example, 120-240
Irradiation with a halogen lamp of W / cm from a distance of 10 to 20 cm for several seconds can be easily performed.
The hard coat film of the present invention thus obtained is suitable for use as an instrument panel for a vehicle, a display of a computer or a television, and particularly as an antiglare film to be used by being adhered to the surface of a liquid crystal display.
【００１２】本発明は、例えば、トリアセチルセルロー
スフィルム等の透明フィルムの表面に、平均二次粒子系
が１．７μｍ〜２μｍであると共に平均二次粒子径の標
準偏差が０．２〜０．７である微粒子を、例えば５〜２
０重量％含有する、透明な電離放射線硬化型樹脂を公知
の方法に従って塗布し、電離放射線を照射することによ
って容易に得ることができる。According to the present invention, for example, a transparent film such as a triacetyl cellulose film has an average secondary particle system of 1. Fine particles having a diameter of 7 μm to 2 μm and a standard deviation of the average secondary particle diameter of 0.2 to 0.7 are, for example, 5 to 2 μm.
It can be easily obtained by applying a transparent ionizing radiation-curable resin containing 0% by weight according to a known method and irradiating it with ionizing radiation.
【００１３】[0013]
【発明の効果】本発明のハードコートフィルムに含有さ
せる微粒子は、平均二次粒子径が１．７μｍ〜２μｍで
その標準偏差は０．２〜０．７であり、ギラツキの原因
となる大きな粒子を含まないので、防眩性のみならず視
認性にも優れている。The fine particles contained in the hard coat film of the present invention have an average secondary particle diameter of 1. It has a standard deviation of 0.2 to 0.7 at 7 μm to 2 μm and does not contain large particles that cause glare, so that it is excellent not only in antiglare properties but also in visibility.
【００１４】[0014]
【実施例】以下本発明を実施例に従ってさらに詳述する
が、本発明はこれによって限定されるものではない。 比較例１．８０μｍのトリアセチルセルロースフィルム
（フジタック；富士写真フイルム株式会社の商品名）の
一方の面に、ワイヤーバー♯５を用いて、下記表１の組
成の塗布液を塗布して被膜層を得、加熱乾燥した後、該
被膜層に１２０Ｗ／ｃｍの紫外線ランプで１０ｃｍの距
離から１秒間光照射し、前記フィルム上に、厚みが５μ
ｍのハードコート層を有するハードコートフィルムを作
製した。The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto. Comparative Example 1. A coating solution having the composition shown in Table 1 below was applied to one surface of a triacetylcellulose film (Fujitac; trade name of Fuji Photo Film Co., Ltd.) of 80 μm using a wire bar # 5. After drying by heating, the coating layer was irradiated with light from a UV lamp of 120 W / cm from a distance of 10 cm for 1 second to form a film having a thickness of 5 μm on the film.
A hard coat film having m hard coat layers was prepared.
【００１５】[0015]
【表１】 ─────────────────────────────────── ウレタン：９２．５重量部 （ビームセット５５０Ｂ；荒川化学株式会社製の商品名） 無形シリカ：７．５重量部 （サイリシア４３０；富士シリシア化学株式会社製の商品；平均二次粒子径４． ０μｍ−標準偏差１．５） 光反応開始剤５．０重量部 （イルガキュア１８４；チバ・ガイキー社製の商品名） イソプロピルアルコール；粘度調整のため希釈剤として適宜の量 ──────────────────────────────────[Table 1] ─────────────────────────────────── Urethane: 92.5 parts by weight (Beam set 550B ; Arakawa Chemical Co., Ltd.) Intangible silica: 7.5 parts by weight (Sylysia 430; product from Fuji Silysia Chemical Ltd .; average secondary particle diameter 4.0 μm-standard deviation 1.5) Photoreaction initiator 5.0 parts by weight (Irgacure 184; trade name of Ciba-Gaiky) Isopropyl alcohol; appropriate amount as a diluent for viscosity adjustment ───────────────
【００１６】実施例１．微粒子として、比較例１で使用
したサイリシア４３０を粉砕し、平均二次粒子径を２．
０μｍ、標準偏差を０．７としてから使用した他は、比
較例１と全く同様にしてハードコートフィルムを作製し
た。Embodiment 1 FIG. As fine particles, Sylysia 430 used in Comparative Example 1 was pulverized to have an average secondary particle diameter of 2.
A hard coat film was prepared in exactly the same manner as in Comparative Example 1 except that the standard deviation was 0 μm and the standard deviation was 0.7.
【００１７】実施例２．無定形シリカとして、サイリシ
ア４３０を粉砕し、平均二次粒子径を１．８μｍ、標準
偏差を０．６としてから使用した他は、比較例１と全く
同様にしてハードコートフィルムを作製した。Embodiment 2 FIG. A hard coat film was prepared in exactly the same manner as in Comparative Example 1, except that thyricia 430 was pulverized as amorphous silica, and the average secondary particle diameter was set to 1.8 μm and the standard deviation was set to 0.6.
【００１８】実施例３．無定形シリカとして、サイリシ
ア４３０を粉砕し、平均二次粒子径を１．７μｍ、標準
偏差を０．５としてから使用した他は、比較例１と全く
同様にしてハードコートフィルムを作製した。Embodiment 3 FIG. A hard coat film was produced in exactly the same manner as in Comparative Example 1, except that Sylysia 430 was pulverized as amorphous silica and the average secondary particle diameter was set to 1.7 μm and the standard deviation was set to 0.5.
【００１９】比較例２． 無定形シリカとして、サイリシア４３０を粉砕し、平均
二次粒子径を１．５μｍ、標準偏差を０．４としてから
使用した他は、比較例１と全く同様にしてハードコート
フィルムを作製した。 Comparative Example 2 A hard coat film was produced in exactly the same manner as in Comparative Example 1, except that thyricia 430 was pulverized as amorphous silica and the average secondary particle diameter was set to 1.5 μm and the standard deviation was set to 0.4.
【００２０】比較例３． 無定形シリカとしては、サイリシア４３０を粉砕し、平
均二次粒子径を０．５μｍ、標準偏差を０．１としてか
ら使用した他は、比較例１と全く同様にしハードコート
フィルムを作製した。実施例１〜３及び比較例１〜３で
得られたハードコートフィルムについて、以下の測定方
法により諸物性を測定し評価した結果は表２に示した通
りである。 Comparative Example 3 As amorphous silica, a hard coat film was produced in exactly the same manner as in Comparative Example 1 except that Sylysia 430 was pulverized and used after setting the average secondary particle diameter to 0.5 μm and the standard deviation to 0.1. The physical properties of the hard coat films obtained in Examples 1 to 3 and Comparative Examples 1 to 3 were measured and evaluated by the following measurement methods, and the results are shown in Table 2.
【００２１】鉛筆高度；ＨＥＩＤＯＮ１４を使用し、Ｊ
ＩＳ（Ｋ−５４００）に準拠して実施。 耐薬品性；フィルムの硬化被膜層表面に、トルエン、エ
タノール、酢酸エチル、１０重量％塩酸、及び、１０重
量％カセイソーダを各々滴下し、１分経過後の硬化被膜
層の表面の変化を目視により観察した。 鮮明度；写像性測定器ＩＣＭ−１ＤＰ（スガ試験器社
製）を使用し、ＪＩＳ（Ｋ−７１０５）に準拠して実
施。 視認性；市販液晶セル（６インチ−ＳＶＧＡタイプ）に
サンプルを貼り合わせ、フィルムを通してバックライト
の光を観察し、ギラツキ度合を評価した。 防眩性：フィルム表面の反射度合を目視によって評価し
た。Pencil height; using HEIDON14, J
Implemented in accordance with IS (K-5400). Chemical resistance: Toluene, ethanol, ethyl acetate, 10% by weight hydrochloric acid, and 10% by weight sodium hydroxide are dropped on the surface of the cured film layer of the film, and the change of the surface of the cured film layer after 1 minute is visually observed. Observed. Sharpness: Performed in accordance with JIS (K-7105) using an image clarity measuring device ICM-1DP (manufactured by Suga Test Instruments Co., Ltd.). Visibility: The sample was bonded to a commercially available liquid crystal cell (6 inch-SVGA type), and the backlight light was observed through the film to evaluate the degree of glare. Anti-glare property: The degree of reflection on the film surface was visually evaluated.
【００２２】[0022]
【表２】 以上の結果から、本発明のハードコートフィルムが特に
視認性に優れていることが確認された。 [Table 2] From the above results, it was confirmed that the hard coat film of the present invention was particularly excellent in visibility.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 久々津 裕 東京都新宿区上落合１−30−６ 日本製 紙株式会社 商品開発研究所 内 (56)参考文献 特開 平９−269403（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) B32B 1/00 - 35/00 G02B 1/10 - 1/12 ──────────────────────────────────────────────────続 き Continuation of the front page (72) Inventor Hiroshi Kugatsu 1-30-6 Kamiochiai, Shinjuku-ku, Tokyo Nippon Paper Industries Co., Ltd. Product Development Laboratory (56) References JP-A-9-269403 (JP, A (58) Field surveyed (Int.Cl. 6 , DB name) B32B 1/00-35/00 G02B 1/10-1/12
Claims (2)
方の面に、平均二次粒子径が１．７μｍ〜２μｍである
と共に平均二次粒子径の標準偏差が０．２〜０．７の微
粒子及び電離放射線硬化型樹脂からなる組成物に電離放
射線を照射し硬化させた硬化被膜層を設けてなる、透過
鮮明度（透過Ｃ （２．０） ）が２０％以上であると共に
反射鮮明度（反射Ｃ （２．０） ）が２０．１％以下であ
ることを特徴とするハードコートフィルム。An average secondary particle diameter of at least one surface of a transparent plastic film is 1. A composition comprising fine particles having an average secondary particle diameter of 7 to 2 μm and a standard deviation of an average secondary particle diameter of 0.2 to 0.7 and an ionizing radiation curable resin is provided with a cured film layer which is irradiated with ionizing radiation and cured. Become transparent
Sharpness (transmission C (2.0) ) is not less than 20%
The reflection sharpness (reflection C (2.0) ) is 20.1% or less.
The hard coat film, characterized in that that.
載されたハードコートフィルム。2. The hard coat film according to claim 1, wherein the fine particles are silica particles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9090062A JP2984916B2 (en) | 1997-03-24 | 1997-03-24 | Hard coat film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9090062A JP2984916B2 (en) | 1997-03-24 | 1997-03-24 | Hard coat film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10264322A JPH10264322A (en) | 1998-10-06 |
| JP2984916B2 true JP2984916B2 (en) | 1999-11-29 |
Family
ID=13988082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9090062A Expired - Fee Related JP2984916B2 (en) | 1997-03-24 | 1997-03-24 | Hard coat film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2984916B2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4267741B2 (en) * | 1999-03-09 | 2009-05-27 | 富士フイルム株式会社 | Anti-glare antireflection film and image display device |
| JP4497782B2 (en) * | 2001-03-08 | 2010-07-07 | 日本製紙株式会社 | Touch panel in which Newton ring is prevented and transparent electrode for the touch panel |
| JP2004217847A (en) * | 2003-01-17 | 2004-08-05 | Nippon Paper Industries Co Ltd | Coating composition for forming hard coat layer and hard coat film |
| JP5175468B2 (en) * | 2005-11-04 | 2013-04-03 | 富士フイルム株式会社 | Optical film, polarizing plate and image display device |
| JP4929780B2 (en) * | 2006-03-24 | 2012-05-09 | 住友化学株式会社 | Liquid crystal display device and antiglare polarizing film laminate used therefor |
| JP4997147B2 (en) * | 2007-03-08 | 2012-08-08 | 富士フイルム株式会社 | Antireflection laminate, polarizing plate and image display device |
| JP2009145837A (en) * | 2007-12-18 | 2009-07-02 | Bridgestone Corp | Optical filter for display, its manufacturing method, and display and plasma display panel having the optical filter |
| JP6189642B2 (en) * | 2013-05-30 | 2017-08-30 | リンテック株式会社 | Touch panel |
-
1997
- 1997-03-24 JP JP9090062A patent/JP2984916B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10264322A (en) | 1998-10-06 |
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