JP2976054B2 - Acid milk drink - Google Patents

Acid milk drink

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Publication number
JP2976054B2
JP2976054B2 JP2000467A JP46790A JP2976054B2 JP 2976054 B2 JP2976054 B2 JP 2976054B2 JP 2000467 A JP2000467 A JP 2000467A JP 46790 A JP46790 A JP 46790A JP 2976054 B2 JP2976054 B2 JP 2976054B2
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JP
Japan
Prior art keywords
alginic acid
milk
added
water
acidic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2000467A
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Japanese (ja)
Other versions
JPH03206838A (en
Inventor
武憲 加藤
かおる 山部
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Individual
Original Assignee
Individual
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Priority to JP2000467A priority Critical patent/JP2976054B2/en
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Application granted granted Critical
Publication of JP2976054B2 publication Critical patent/JP2976054B2/en
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Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION 【産業上の利用分野】[Industrial applications]

本発明は、酸性乳飲料に関するものである。 The present invention relates to an acidic milk beverage.

【発明の背景】BACKGROUND OF THE INVENTION

従来、酸性乳飲料用のスタビライザーとしては、ハイ
メトキシルペクチンが使用されてきたが、酸性サイドで
乳蛋白質を安定化させる為には、蛋白含有量が多くなる
とそれに比例してペクチン使用量も多くしなければなら
なかった。 ところで、ペクチンは茶褐色の粉末であるので、ペク
チンの色がそのまま製品に移行することより、白度が要
求される酸性乳飲料の場合には著しく商品価値が失われ
る。さらには、ペクチンの添加量が多くなると、ペクチ
ンの味が製品にでてくるだけでなく、糊感が強くなると
いう欠点を有している。 又、酸性乳飲料では殺菌して常温流通させることがあ
り、この場合ペクチンが経日で分解され、乳蛋白を巻き
込んで茶褐色の沈澱が生じる。沈澱物が白色の場合は商
品としてあまり気にならないが、茶褐色の沈澱の場合
は、消費者はそれを異物として不安に感じることから、
問題が多い。 これらの解決策として特願昭63−38270号及び特願昭6
3−110928号において、本願出願人はアルギン酸を使用
することを提案していたが、これらの技術は乳蛋白が1
%程度の場合には極めて良好な製品を抵抗できるもの
の、乳蛋白の含有量が3%といったように多くなるとゲ
ル化の傾向が生じ、殺菌酸性乳飲料の場合は経日で部分
的に亀裂現象が生じることもある等の問題のあることが
判明した。
Conventionally, high methoxyl pectin has been used as a stabilizer for acidic milk beverages.However, in order to stabilize milk proteins on the acidic side, the amount of pectin used increases in proportion to the increase in protein content. I had to. By the way, since pectin is a brownish powder, the color of the pectin is transferred to the product as it is, so that in the case of an acidic milk beverage requiring whiteness, the commercial value is remarkably lost. Further, when the added amount of pectin increases, not only does the taste of pectin appear in the product, but also there is a drawback that the feeling of glue becomes strong. In addition, acidic milk drinks may be sterilized and distributed at room temperature. In this case, pectin is decomposed over time, and milk proteins are involved, resulting in a brown precipitate. If the precipitate is white, it is not much of a concern as a commercial product, but if the precipitate is brown, consumers will feel uneasy as a foreign substance.
There are many problems. To solve these problems, Japanese Patent Application No. 63-38270 and Japanese Patent Application No.
In 3-110928, the applicant has proposed the use of alginic acid.
%, A very good product can be resisted, but when the milk protein content is as high as 3%, gelling tends to occur, and in the case of sterilized acidic milk beverages, partial cracking occurs over time. It has been found that there are problems such as the occurrence of a problem.

【発明の開示】DISCLOSURE OF THE INVENTION

本発明の第1の目的は、酸性サイドで乳蛋白質が安定
化した酸性乳飲料を提供することである。 本発明の第2の目的は、ペクチン使用の場合のような
茶褐色が乳製品に付くことがなく、かつ、酸性サイドで
乳蛋白質が安定化した酸性乳飲料を提供することであ
る。 本発明の第3の目的は、ペクチン使用の場合のような
糊感が強くなる欠点がなく、かつ、酸性サイドで乳蛋白
質が安定化した酸性乳飲料を提供することである。 本発明の第4の目的は、乳蛋白の含有量が3%といっ
たように多くなっても、ゲル化の問題がなく、経日で部
分的に亀裂現象が生じることもなく、かつ、酸性サイド
で乳蛋白質が安定化した酸性乳飲料を提供することであ
る。 上記本発明の目的は、pHが3.8以下で水に溶解するア
ルギン酸及び/又はアルギン酸塩を含有することを特徴
とする酸性乳飲料によって達成される。 すなわち、本発明は前記の問題を解決すべく鋭意研究
の結果、酸性サイドで溶解するアルギン酸のうちpH3.8
以下で水に溶解するアルギン酸は、乳蛋白の保護コロイ
ドをつくる作用が強いことを見出し、このpHが3.8以下
で水に溶解するアルギン酸及び/又はアルギン酸塩を使
用することにより、酸性乳飲料の他に、 経日で沈澱の生じない乳酸菌飲料(殺菌)をつくり
得る、 乳漿分離の生じない醗酵乳、ヨーグルト等をつくり
得る、 製品に糊感を与えない、すなわちサラッとしたテク
スチャーなものをつくり得る、 醗酵乳の風味が阻害されない為、風味の良好なもの
をつくり得る、 添加量の調整で新規なテクスチャーの乳デザートを
つくり得る、 ことを見出した。 ところで、pHが3.8以下で水に溶解するアルギン酸及
び/又はアルギン酸塩は、原藻から直接抽出する方法
と、粉末として製品化されたものから酸又はアルカリ剤
を用いて抽出する方法等があるが、どの方法で得られた
ものでも良い。 例えば、pHを所定の値(pHが3.8以下の値)に調整し
た粉末アルギン酸水溶液を加温して所定のpH域で溶解す
るアルギン酸を溶出せしめた後、遠心分離機で不溶性の
アルギン酸を除去し、エタノールを添加してアルギン酸
を折出せしめ、この折出物を加圧脱水して乾燥させるこ
とで、pHが3.8以下の水で溶解するアルギン酸が得られ
る。 又、裁断した乾燥昆布を布袋に入れ、このものを予め
クエン酸を添加した水溶液に入れ、そして水溶液の最終
pHが3.8以下の値になるようにコントロールしながら昆
布からアルギン酸を溶出させ、この溶液にエタノールを
添加してアルギン酸を折出させ、この折出物を加圧脱水
して乾燥させることで、pHが3.8以下の水で溶解するア
ルギン酸が得られる。 又、アルギン酸の溶液をpHが3.8以下の値になるよう
に炭酸ナトリウムを用いてpH調整してアルギン酸を溶解
させ、不溶物を除去した濾過液に炭酸ナトリウムを添加
してpHを7に中和したものにエタノールを添加して、ア
ルギン酸ナトリウムを折出させ、この折出物を加圧脱水
して乾燥させることで、pHが3.8以下の水で溶解するア
ルギン酸塩が得られる。 尚、使用するアルギン酸及びアルギン酸塩はpHが3.3
〜3.8で溶解するものがより好ましい。
A first object of the present invention is to provide an acidic milk beverage in which milk protein is stabilized on the acidic side. A second object of the present invention is to provide an acidic milk beverage in which dairy products do not have a dark brown color as in the case of using pectin, and milk proteins are stabilized on the acidic side. A third object of the present invention is to provide an acidic milk beverage which does not have the drawback of increasing the feeling of glue as in the case of using pectin, and in which milk protein is stabilized on the acidic side. A fourth object of the present invention is to prevent the problem of gelation even when the content of milk protein is as large as 3%, no partial cracking over time, and the acid side. And to provide an acidic milk beverage in which milk protein is stabilized. The above object of the present invention is achieved by an acidic milk beverage characterized by containing alginic acid and / or alginate soluble in water at a pH of 3.8 or less. That is, the present invention, as a result of intensive studies to solve the above problems, as a result of the pH 3.8 of alginic acid dissolved in the acidic side.
Alginic acid soluble in water is found to have a strong action to form a protective colloid of milk protein below, and by using alginic acid and / or alginate soluble in water at a pH of 3.8 or less, it is possible to use it for other acidic milk drinks. In addition, it can produce lactic acid bacteria beverages (sterilized) that does not precipitate over time, can produce fermented milk and yogurt that do not produce whey separation, and does not give the product a feeling of glue, that is, produce a smooth textured product It was found that the flavor of fermented milk was not hindered, so that a good flavored one could be made, and that a milk dessert with a new texture could be made by adjusting the amount added. By the way, alginic acid and / or alginate soluble in water at a pH of 3.8 or less include a method of directly extracting from algae and a method of extracting from a powdered product using an acid or alkali agent. Any method may be used. For example, after heating a powdered alginic acid aqueous solution whose pH is adjusted to a predetermined value (pH of 3.8 or less) to elute alginic acid that dissolves in a predetermined pH range, insoluble alginic acid is removed by a centrifuge. Then, ethanol is added to cause alginic acid to be deposited, and the deposited product is dehydrated under pressure and dried to obtain alginic acid that is soluble in water having a pH of 3.8 or less. Also, put the dried dried kelp in a cloth bag, put this in an aqueous solution to which citric acid has been added in advance, and
The alginic acid was eluted from the kelp while controlling the pH to a value of 3.8 or less, ethanol was added to the solution to precipitate alginic acid, and the resulting precipitate was dehydrated under pressure and dried to obtain a pH. Alginic acid that is soluble in water having a pH of 3.8 or less is obtained. The pH of the solution of alginic acid was adjusted to 3.8 or less using sodium carbonate to dissolve alginic acid, and sodium carbonate was added to the filtrate from which the insolubles were removed to neutralize the pH to 7. Ethanol is added to the resulting mixture to precipitate sodium alginate, and the resulting precipitate is dehydrated under pressure and dried to obtain an alginate soluble in water having a pH of 3.8 or less. The alginic acid and alginates used had a pH of 3.3.
Those that dissolve at ~ 3.8 are more preferred.

【実施例1】 (I)粉末アルギン酸(商品名アシッドアルギンG#2
富士化学工業(株)製)を水に2.0%濃度になるように
分散させたもの(pHが2.8)(A)と、このアルギン酸
2%含有水溶液に更にクエン酸ナトリウムを添加してpH
が3.5のもの(B)、pHが4.0のもの(C)、pHが4.5の
もの(D)、pHが5.0のもの(E)を作製し、これらを
それぞれ60℃迄加温して各pH域に溶解するアルギン酸を
溶出せしめた後、遠心分離機で不溶性のアルギン酸を除
去した溶液に99%エタノールを等量添加してアルギン酸
を折出せしめ、この折出物を加圧脱水して乾燥させ、粉
体A′、B′、C′、D′、E′を得た。 (II)乾燥昆布を裁断したものを布袋に入れ、このもの
を予めクエン酸を添加した水に入れ、水溶液の最終pHが
それぞれ2.8(F)、3.5(G)、4.0(H)、4.5
(I)、5.0(J)になるようにコントロールしながら
昆布からアルギン酸を溶出させ、これらの溶液に99%エ
タノールを等量添加してアルギン酸を折出させ、これを
加圧脱水して乾燥させ、粉体F′、G′、H′、I′、
J′を得た。 (III)アルギン酸の2%溶液をpH2.8(K)、3.5
(L)、4.0(M)、4.5(N)、5.0(O)なるように
炭酸ナトリウムを用いてpH調整してアルギン酸を溶解さ
せ、不溶物を除去した濾過液に炭酸ナトリウムを添加
し、pHを7に中和したものに99%エタノールを等量添加
してアルギン酸ナトリウムを折出させ、このものを加圧
脱水して乾燥させ、粉体K′、L′、M′、N′、O′
を得た。 〔配 合〕 醗酵乳(無脂乳固形分20.0%含有物) 15.0% 上記粉末アルギン酸又は塩(A′〜O′) 0.2% 水 84.8% 合 計 100.0% 上記の配合組成でアルギン酸を水に溶解させ、これに
醗酵乳を添加し、6000rpmのホモジナイザーで5分間ホ
モジナイズし、これを70ccのプラスチックカップに充填
し、蓋をシールして85℃で15分間殺菌し、凝集の有無、
経日で沈澱物の発生の有無、及び官能検査を行った。 又、ハイメトキシルペクチン(商品名HM#1ユニペク
チン社製)を上記アルギン酸の代わりに0.4%使用し
た。 凝集の有無、10日後の沈澱物の発生の有無、及び官能
検査の結果を次の表に示す。
Example 1 (I) Powdered alginic acid (trade name: acid algin G # 2)
(A) prepared by dispersing a 2.0% concentration of water (manufactured by Fuji Chemical Industry Co., Ltd.) into water (pH 2.8) (A).
Were prepared at 3.5 (B), at pH 4.0 (C), at pH 4.5 (D), and at pH 5.0 (E). After eluting the alginic acid that dissolves in the area, an equal volume of 99% ethanol is added to the solution from which the insoluble alginic acid has been removed using a centrifuge to extract the alginic acid. And powders A ', B', C ', D', and E '. (II) The cut dried kelp is put into a cloth bag and put into water to which citric acid has been added in advance, and the final pH of the aqueous solution is 2.8 (F), 3.5 (G), 4.0 (H), 4.5, respectively.
(I) Alginic acid was eluted from kelp while controlling to 5.0 (J), and an equal amount of 99% ethanol was added to these solutions to precipitate alginic acid, which was dehydrated under pressure and dried. , Powder F ', G', H ', I',
J 'was obtained. (III) A 2% solution of alginic acid was prepared at pH 2.8 (K), 3.5
(L), 4.0 (M), 4.5 (N), 5.0 (O) pH was adjusted using sodium carbonate to dissolve alginic acid, and sodium carbonate was added to the filtrate from which insolubles had been removed. Was neutralized to 7 and 99% ethanol was added in an equal amount to precipitate sodium alginate, which was dehydrated under pressure and dried to obtain powders K ', L', M ', N', O ′
I got [Combination] Fermented milk (20.0% solid content of non-fat milk) 15.0% Alginic acid powder or salt (A 'to O') 0.2% Water 84.8% Total 100.0% Alginic acid dissolved in water with the above composition The fermented milk was added thereto, homogenized with a homogenizer at 6000 rpm for 5 minutes, filled in a 70 cc plastic cup, sealed with a lid, and sterilized at 85 ° C for 15 minutes.
The presence or absence of precipitates and sensory tests were conducted over time. In addition, high methoxyl pectin (trade name: HM # 1 manufactured by Unipectin) was used in place of the alginic acid at 0.4%. The following table shows the presence / absence of aggregation, the presence / absence of a precipitate after 10 days, and the results of the sensory test.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】pHが3.8以下で水に溶解するアルギン酸及
び/又はアルギン酸塩を含有することを特徴とする酸性
乳飲料。
1. An acidic milk beverage comprising alginic acid and / or alginate soluble in water at a pH of 3.8 or less.
JP2000467A 1990-01-08 1990-01-08 Acid milk drink Expired - Fee Related JP2976054B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000467A JP2976054B2 (en) 1990-01-08 1990-01-08 Acid milk drink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000467A JP2976054B2 (en) 1990-01-08 1990-01-08 Acid milk drink

Publications (2)

Publication Number Publication Date
JPH03206838A JPH03206838A (en) 1991-09-10
JP2976054B2 true JP2976054B2 (en) 1999-11-10

Family

ID=11474605

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000467A Expired - Fee Related JP2976054B2 (en) 1990-01-08 1990-01-08 Acid milk drink

Country Status (1)

Country Link
JP (1) JP2976054B2 (en)

Also Published As

Publication number Publication date
JPH03206838A (en) 1991-09-10

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