JP3269595B2 - Novel calcium agent having viscoelasticity and method for producing the same - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel edible calcium agent having viscoelasticity and a method for producing the same. More specifically, the present invention relates to a novel viscoelastic edible calcium agent having specific physicochemical properties and being edible as it is, and a method for producing the same.

[0002] In the present specification, percentages and parts are values by weight unless otherwise specified (excluding the percentage of particle size distribution). In the present specification, "zaratsuki" is a texture when the calcium agent of the present invention is contained in the mouth, and is a particle size distribution analyzer [manufactured by Malvern Co., Ltd.]. EASY
In the particle distribution measured using Particle Sizer M6.10], when particles having a particle size of 15 μm or less account for 98% or more of all particles, graininess is not felt, but graininess is felt at about 75%. In addition, in the present specification, the fluidity is a value measured by a conventional method using a tensipresser (manufactured by Taketomo Electric Co., Ltd., TTP-50BX type).

[0003]

2. Description of the Related Art It has been pointed out that a Japanese who enjoys a seemingly rich diet is also deficient in calcium intake. Therefore, many techniques for enhancing calcium in various foods or calcium agents for enhancing calcium in various foods have been developed, and the following techniques can be exemplified as typical examples.

1) A milk beverage using calcium carbonate without precipitation and further enriched with 50-150 mg% of calcium (Japanese Patent Laid-Open No. 5-76279). 2) A calcium-fortified beverage in which a water-soluble organic acid calcium salt has been added to milk or milk beverage and the pH has been adjusted to 6.6 or more (JP-A-61-15645). 3) Process cheese to which fine calcium citrate generated by mixing and stirring calcium carbonate, citric acid and water is added (Japanese Patent Application Laid-Open No. 58-40041). 4) A calcium carbonate agent in which calcium carbonate in a slurry form is mixed with an aqueous solution of a hydrophilic emulsifier, the mixture is dehydrated, and dried under vacuum (Japanese Patent Application Laid-Open No. 63-173556).

[0005] 5) Calcium carbonate in a slurry form is mixed with an aqueous solution of a hydrophilic emulsifier, the mixture is dehydrated, dried under vacuum, and the resulting calcium carbonate composite is dispersed in butter oil. High-concentration calcium milk in which butterlam and reduced skim milk are added to the mixture, mixed and homogenized to remove coarse particles of calcium carbonate (Japanese Patent Publication No. 2-29301). 6) A calcium salt for strengthening which is separated from a mineral concentrate obtained when desalting whey and comprises a water-insoluble and non-crystalline calcium salt (Japanese Patent Publication No. 3-24191).

[0006] 7) a step of acidifying a milk raw material liquid to remove formed coagulated matter, a step of removing solidified matter and neutralizing with an alkali to precipitate and separate salts, and a step of condensing or drying the separated salts. And salts containing calcium as a main component (Japanese Patent Publication No. 2-60303). 8) Neutral beverage with calcium fortified with whey minerals (JP-A-5-103645). 9) A method of adhering or enclosing fine particles of a water-insoluble calcium salt to fat globules to prevent precipitation of the fine particles (JP-A-57-11)
0167). 10) A method in which microcrystalline cellulose is added to an aqueous phase, and fine particles of a water-insoluble calcium salt are supported in a fine network to prevent precipitation (Japanese Patent No. 1145334).

11) Coagulants for tofu production using calcium salts (JP-B-49-21772, JP-B-45-22)
499). 12) containing a compound selected from the group consisting of potassium citrate, lithium citrate, magnesium citrate and calcium citrate and a compound selected from the group consisting of citric acid, iron citrate and diammonium citrate,
And a tempura garment comprising a composition having an aqueous solution having a pH of 7 or more (Japanese Patent Application Laid-Open No. Sho 62-115249).

13) One or more saccharides selected from the group consisting of sodium citrate, sodium succinate, sodium tartrate and sodium malate corresponding to 1 to 50% by weight of one or more saccharides selected from sugars and sugar alcohols Freezing of raw fish meat raw material containing the above organic acid salt and one or more calcium compounds selected from calcium hydroxide, calcium oxide, calcium chloride, calcium acetate and calcium lactate equivalent to 0.1 to 7% by weight. Preservation composition (Japanese Patent Application Laid-Open No. 62-210944).

14) Citric acid, succinic acid, acetic acid, tartaric acid,
For one or more organic acid salts selected from fumaric acid, malic acid and adipic acid sodium salt and potassium salt,
Composition for enhancing the elasticity of kneaded products containing one or more calcium compounds selected from calcium hydroxide and calcium oxide corresponding to 0.3 to 60% by weight (JP-A-63-1)
69966).

15) A calcium fortifying agent obtained by dispersing calcium carbonate powder in an organic acid calcium solution (Japanese Patent Publication No.
-26519). In addition, calcium medicines in the form of tablets, powders, granules, and the like are commercially available as medicines for increasing the intake of calcium.

[0011]

Heretofore, apart from pharmaceuticals, calcium added to foods has been the largest problem in terms of graininess when eating the foods and precipitation of calcium in the products. As a measure, various improvements as described above have been attempted. However, in the prior art, unless a small amount of calcium is added to the food,
When a large amount of calcium is added, the above problem has not been solved yet, and further, there has been no idea that the calcium agent itself is used as a food.

In view of the above prior art, the present inventors have conducted intensive research on a completely new type of calcium agent which does not have graininess when eaten and precipitates in the product and which can be used as food. As a result, by dissolving the calcium salt in water with an acid and adjusting the pH at a higher concentration than that conventionally performed,
The present inventors have found that a novel calcium agent having viscoelasticity (that is, having clay-like properties) and excellent in texture without roughness can be obtained, and the present invention has been completed.

[0013] An object of the present invention is to provide a novel calcium agent which is free of sediment when eaten and precipitates in products, which has been regarded as a problem of calcium added to foods, and which can be used as foods. To provide.

Another object of the present invention is to produce a novel calcium agent having viscoelasticity (that is, clay-like properties) which is free from graininess when eaten and precipitates in a product, which can be used as a food itself. Is to provide a way.

[0015]

The present invention for solving the above-mentioned problems
Ming has the following physicochemical properties of a) to f): a) a water content of 60 to 75% (by weight) b) a calcium content of 3.8 to 5.7% (by weight) c A) an organic acid content of 18 to 30% (by weight) d) an alkali agent content of 2 to 4% (by weight) e) a fluidity of at least 120 g · w measured by a tensipressor f) In the particle distribution measured by the particle size distribution meter, the particle size 15
a calcium agent, wherein particles of μ or less are 98% or more of all particles, wherein the organic acid is citric acid,
Lactic acid or tartaric acid, and the alkaline agent is sodium hydroxide or potassium hydroxide.
In some embodiments, it is desirable that the weight be 450 g · w.

Another embodiment of the present invention for solving the above-mentioned problems is as follows.
Water, a calcium salt and an organic acid are mixed, the calcium salt is dissolved, and an alkaline agent is added to adjust the pH to 3.5 to 6.8.
A calcium agent which is adjusted to a temperature of room temperature or left at room temperature or heated to impart viscoelasticity, comprising 5.4 to 6.8 parts (by weight) of water and 1 part of a calcium salt. (Weight) and 2 to 4 parts (weight) of an organic acid are mixed, the calcium salt is dissolved, and an alkaline agent is added to adjust the pH to 3.5 to 3.5.
In another preferred embodiment, the viscosity is adjusted to 6.8 and left or heated at room temperature to impart viscoelasticity, and the calcium salt is calcium carbonate or milk calcium.

Next, the present invention will be described in more detail.
Method for producing a calcium agent of the present invention is as follows. Calcium salts (preferably calcium carbonate) such as calcium hydroxide, calcium carbonate, calcium chloride, milk calcium (isolated from milk by a known method)
5.4-6.8 parts of water (preferably 6-6.
75 parts), and further, an organic acid (preferably citric acid) such as citric acid, lactic acid, tartaric acid or the like is added at a rate of 2 to 4 parts (preferably 2-3 parts), and the calcium salt is completely added. Dissolve in If the calcium is not completely dissolved, it is not desirable because roughness is observed in the final product and viscoelasticity is not imparted. In this case, the order of addition of the above components is not particularly limited. For example, a calcium salt and an organic acid may be added to water to dissolve the calcium salt.

The concentration of the calcium salt can be arbitrarily changed depending on the amount of water to be dissolved. However, if the ratio to the dissolved water is not in the above-mentioned specific range, the calcium agent does not become a viscoelastic calcium agent. That is, when the concentration of the calcium salt is low,
When it is liquid and its concentration is high, it becomes solid, which is undesirable for use in food.

When the calcium salt and the organic acid are added to water, the pH of the solution is 2 to 4 (preferably 3.5 to 4.0).
And carbon dioxide gas is generated. A sufficient amount of carbon dioxide gas is generated, and an alkali agent such as sodium hydroxide and potassium hydroxide (preferably sodium hydroxide) is added at a ratio of 0.2 to 0.4 parts to adjust the pH to 3.5 to 6.8. (Preferably 5
Adjust to 6) and leave at room temperature or heat. At the stage of adjusting the pH, it is in the state of an aqueous solution and roughness is observed. However, the roughness disappears during standing or heating at room temperature, and the calcium agent has clay-like viscoelasticity.
When heated also for sterilization, it becomes desirable to have viscoelasticity in a short time, and in this case also, it exhibits the same properties as when left at room temperature.

The above manner mosquito Resid <br/> um agent of the present invention obtained is, a) that b) calcium content water content is 60 to 75 percent by 3.8 to 5.7% C) Organic acid content is 18 to 30% d) Alkaline agent content is 2 to 4% e) Fluidity measured by a tensipressor is 120 to
450 g · w f) In the particle distribution measured by a particle size distribution meter,
has a physicochemical property that particles of μ or less are 98% or more of all particles, has viscoelasticity, is not sticky,
It has new properties not found in conventional products.

The calcium agent can be used as it is, edible as it is, and can be used alone or together with other food ingredients, for example, foods such as topping, mayonnaise, tartar sauce, gratin, yogurt, etc.
It can also be added to other appropriate foods. In the latter case, the calcium agent of the present invention can be used as a very good calcium fortifier without the formation of a precipitate or the graininess in the product which has been a problem in the conventional product.

Next, the present invention will be described in detail with reference to test examples. Test Example 1 This test was performed to determine the amount of dissolved water exhibiting viscoelasticity for a certain amount of calcium salt and citric acid. 1) Preparation of sample 100 g of commercially available calcium carbonate (manufactured by Shiraishi Calcium Co., Corocarso, containing 40% as calcium), and crystalline citric acid (manufactured by Saneigen FFI Co., purity: 91%) 20
0 g and 175 g to 3675 g of water were mixed and dissolved to sufficiently generate carbon dioxide gas, and then 25 g of sodium hydroxide (manufactured by Nacalai Tesque, Inc., purity: 96%) was added and dissolved. Put this solution in a retort pouch (manufactured by Toyo Seikan Co., Ltd.)
Each 50 g was filled, sealed, and heated at 120 ° C. for 20 minutes with a retort apparatus (manufactured by Hisaka Seisakusho Co., Ltd., model FLAVOR ACE MASTER) to prepare eight types (samples 1 to 8) shown in Table 1.

2) Test method For each sample, appearance (observation with the naked eye and feel by hand), pH (measured with a pH meter), roughness (texture when in the mouth), particle size distribution and fluidity according to the above method Was tested.

3) Test results The results of this test were as shown in Table 1. As is evident from Table 1, there is a specific range between calcium content and citric acid content required to produce a viscoelastic calcium agent, and further detailed tests on calcium content and citric acid content As a result, the calcium content of 4.0 to 4.5% and the citric acid content of 18 to 20% are particularly desirable ranges. When the calcium content is large or small, a viscoelastic calcium agent cannot be obtained. It has been found. Similar tests were performed using other calcium salts, organic acids and alkali agents, but almost the same results were obtained.

[0025]

[Table 1]

Test Example 2 This test was conducted to determine the proper ratio of calcium salt, organic acid, and water necessary for producing a paste having viscoelasticity. 1) Preparation of sample 100 g of commercially available calcium carbonate (manufactured by Shiraishi Calcium Co., Corocarso, containing 40% as calcium), and crystalline citric acid (manufactured by San-Ei Gen FFI Co., purity: 91%) 10
0 to 500 g and 400 g to 800 g of water are mixed and dissolved, carbon dioxide gas is sufficiently generated, and then retort pouches (manufactured by Toyo Seisakusho) are filled with 100 to 150 g each.
Samples shown in Table 2 (Samples 1 to 5) were prepared in the same manner as described above.

2) Test Method For each sample, the pH and appearance immediately after mixing each component, and the appearance and roughness after heating were tested in the same manner as in Test Example 1.

3) Test results The results of this test were as shown in Table 2. As is clear from Table 2, in order to produce a viscoelastic calcium agent, it was found that there was a proper ratio of calcium salt, organic acid and water, and the calcium salt had to be completely dissolved with citric acid. If the calcium salt concentration is not within a specific range, it is impossible to produce a viscoelastic calcium agent without roughness. The pH can be freely adjusted with an alkali agent. However, considering the use of the product of the present invention as a food material, the pH is particularly preferably from 4.5 to 5.5.
The range of 5 is preferably 2.5 to 3.5% as sodium hydroxide. Similar tests were performed using other calcium salts, organic acids and alkali agents, but almost the same results were obtained.

[0029]

[Table 2]

[0030]

EXAMPLES Next, the present invention will be described in more detail by way of examples, but the present invention is not limited to the following examples. Example 1 Calcium carbonate (manufactured by Shiraishi Calcium Co., Corocalco, containing 40% as calcium) in 6.75 kg of water 1.0
kg and crystalline citric acid (manufactured by San-Ei Gen FFI Co., Ltd.
2.0 kg (purity: 91%) was added and dissolved by stirring, and then sodium hydroxide (manufactured by Nacalai Tesque, Inc., purity: 96)
%), The pH of the solution was adjusted to 5.0, and the solution was allowed to stand at room temperature for 12 hours to obtain about 10 kg of a viscoelastic calcium agent.

The resulting calcium agent has a water content of 75
%, Calcium content 4.0%, citric acid content 18.2
% And a sodium hydroxide content of 2.4%, and a fluidity of 13% as measured by a tensipressor in the same manner as described above.
The particle size was 6 g · w, and in the particle distribution measured by a particle size distribution analyzer in the same manner as described above, particles having a particle size of 15 μ or less accounted for 98% or more of all particles, and were viscoelastic calcium agents.

Example 2 Milk calcium (manufactured by Denmark Protein Co., containing 19% calcium) 2.0k in 5.76 kg of water
g and crystalline citric acid (manufactured by San-Ei Gen FFI Co .; purity: 91%) were added and dissolved by stirring, and then potassium hydroxide (manufactured by Nacalai Tesque, purity: 85%).
0.24 kg was added, the pH of the solution was adjusted to 4.0, 200 g each was filled into a retort pouch (manufactured by Toyo Seikan Co., Ltd.), sealed, and a retort apparatus (manufactured by HISAKA MFG. FLAVOR ACE MASTE)
The mixture was heated at 120 ° C. for 20 minutes by R) to obtain 50 viscoelastic calcium agents.

The obtained calcium agent has a water content of 63
%, Calcium content 3.8%, citric acid content 18.2
%, Potassium hydroxide content 2.0%, and a fluidity of 125% as measured with a tensipressor in the same manner as described above.
g · w, and in the particle distribution measured by a particle size distribution analyzer in the same manner as described above, particles having a particle size of 15 μ or less accounted for 98% or more of all the particles, and were viscoelastic calcium agents.

Example 3 Calcium carbonate (Corocalco S, manufactured by Shiraishi Calcium Co., containing 40% as calcium) in 6.75 kg of water.
0 kg and 2.0 kg of crystalline citric acid (manufactured by Saneigen FFI Co., Ltd., purity: 91%) were added and dissolved by stirring, and then 0.255 kg of potassium hydroxide (manufactured by Nacalai Tesque, Inc., purity: 85%) Was added to adjust the pH of the solution to 5.6, and 200 g each of retort pouches (manufactured by Toyo Seikan Co., Ltd.) was filled and sealed, and a retort device (manufactured by HISAKA SEISAKUSHO.
The mixture was heated at 120 ° C. for 20 minutes by ACE MASTER to obtain 50 viscoelastic calcium agents.

The obtained calcium agent has a water content of 75
%, Calcium content 4.0%, citric acid content 18.2
%, Potassium hydroxide content of 2.2%, and a fluidity of 145 measured with a tensipressor in the same manner as described above.
g · w, and in the particle distribution measured by a particle size distribution analyzer in the same manner as described above, particles having a particle size of 15 µm or less accounted for 98% or more of all the particles, and were viscoelastic calcium agents.

[0036]

As described above in detail, the present invention relates to novel calcium agent and a manufacturing method thereof having viscoelasticity, effects that can be Sose by the present invention is as follows. 1) It is possible to produce a novel calcium agent excellent in texture without roughness without any special treatment or use of additives. 2) It is easy to handle because it is viscoelastic, has no tackiness, and is clay-like. 3) Since there is no roughness, it can be used as it is as food. 4) Since its properties do not change even after sterilization or sterilization, it is suitable for food processing and is useful as a calcium enhancer for various foods.

Continuation of the front page (72) Inventor Kazuhiro Ozawa 5-1-83 Higashihara, Zama City, Kanagawa Prefecture Morinaga Milk Industry Co., Ltd. Nutrition Science Research Institute, Inc. (72) Keiko Takeda Inventor 5-1-83 Higashihara, Zama City, Kanagawa Prefecture Morinaga Milk Industry Co., Ltd. (72) Takako Suzuki 5-1-83 Higashihara, Zama City, Kanagawa Prefecture Inside the Nutrition Science Laboratory, Dairy Industries Co., Ltd. (72) Inventor Hitomi Yamashita 5-1-83, Higashihara, Zama City, Kanagawa Prefecture Morinaga Dairy Products Co., Ltd. Nutrition Science Laboratory Co., Ltd. (58) Fields investigated (Int. Cl. ⁷ , DB name) A23L 1/304 JICST file (JOIS) JAFIC file (JOIS)

Claims (3)

(57) [Claims] 1. The following physicochemical properties of a) to f): a) The water content is 60 to 75% (weight) b) The calcium content is 3.8 to 5.7% (weight) C) Organic acid content is 18 to 30% (by weight) d) Alkaline agent content is 2 to 4% (by weight) e) Fluidity measured by a tensipressor is at least 120 g · w f) In the particle distribution measured by the particle size distribution meter,
A calcium agent comprising particles having a particle size of not more than μ is 98% or more of all particles. 2. The organic acid is citric acid, lactic acid or tartaric acid,
The calcium agent according to claim 1, wherein the alkaline agent is sodium hydroxide or potassium hydroxide. 3. The calcium agent according to claim 1, which has a fluidity of 120 to 450 g · w.