JP2962925B2 - High-speed spinning of polyester fiber - Google Patents

High-speed spinning of polyester fiber

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Publication number
JP2962925B2
JP2962925B2 JP7977192A JP7977192A JP2962925B2 JP 2962925 B2 JP2962925 B2 JP 2962925B2 JP 7977192 A JP7977192 A JP 7977192A JP 7977192 A JP7977192 A JP 7977192A JP 2962925 B2 JP2962925 B2 JP 2962925B2
Authority
JP
Japan
Prior art keywords
yarn
weight
oil agent
speed
polyester fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP7977192A
Other languages
Japanese (ja)
Other versions
JPH05287609A (en
Inventor
昭二 牧野
勝敏 谷口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=13699473&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP2962925(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP7977192A priority Critical patent/JP2962925B2/en
Priority to DE69322063T priority patent/DE69322063T2/en
Priority to KR1019930703656A priority patent/KR0163204B1/en
Priority to TW82102359A priority patent/TW221465B/zh
Priority to EP93906853A priority patent/EP0605727B1/en
Priority to PCT/JP1993/000398 priority patent/WO1993020268A1/en
Publication of JPH05287609A publication Critical patent/JPH05287609A/en
Priority to US08/371,170 priority patent/US5507989A/en
Priority to US08/537,250 priority patent/US5607634A/en
Publication of JP2962925B2 publication Critical patent/JP2962925B2/en
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/265—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/408—Acylated amines containing fluorine atoms; Amides of perfluoro carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/438—Sulfonamides ; Sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6433—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing carboxylic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【０００１】[0001]

【産業上の利用分野】本発明はポリエステル繊維の高速
製糸方法に関する。さらに詳しくは、３０００ｍ／分以
上の高速でも工程安定性が良好で、且つ高品位のポリエ
ステル繊維が得られる高速製糸方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing polyester fibers at high speed. More specifically, the present invention relates to a high-speed spinning method that has good process stability even at a high speed of 3000 m / min or more and can obtain high-quality polyester fibers.

【０００２】[0002]

【従来の技術】合成繊維の製糸技術の進歩はめざまし
く、殊に近年、高速ワインダーの開発に伴い、その製糸
速度は益々増大の方向となっている。これらの技術は、
吐出生産性の向上と、その紡糸過程で起きる特有の繊維
微細構造の変化から生ずる特異な素材としての用途展開
に着目し、各種研究開発が推し進められている。2. Description of the Related Art Synthetic fiber spinning technology has made remarkable progress, and in particular, in recent years, with the development of high-speed winders, the spinning speed has been increasing. These technologies are
Various research and development have been promoted, focusing on the improvement of discharge productivity and the development of applications as a unique material resulting from a change in the specific fiber microstructure that occurs during the spinning process.

【０００３】しかしながら、製糸速度の増大に伴い、走
行糸条と各種糸導（ローラー、ガイド等）との擦過、及
び走行糸束間内での繊維同士の擦過が増大し、単糸切れ
ひいては糸切れを誘発し、得られた糸の品位をそこなう
ばかりでなく、かえって生産効率を低下せしめることに
もなるという問題を含んでいる。[0003] However, as the yarn-making speed increases, the friction between the running yarn and various yarn guides (rollers, guides, etc.) and the friction between the fibers in the running yarn bundle increase, and the single yarn breaks and the yarn breaks. This involves the problem that not only does it cause breakage, which impairs the quality of the obtained yarn, but also decreases the production efficiency.

【０００４】これらの問題解消のためには、紡出糸条へ
の給油用油剤や給油方法に関する提案、並びに、走行糸
条の集束性向上のための糸束への空気処理に関する提案
等についていろいろとなされてきている。しかし、給油
用油剤そのものに関する提案については、いずれをもっ
てしても未だ不適切か不充分なものであり、上記問題点
を高度に解決するものは見出されていないのが現状であ
る。[0004] In order to solve these problems, various proposals have been made regarding oiling agents and oiling methods for spun yarns, and proposals for air treatment of yarn bundles for improving the convergence of running yarns. It has been done. However, the proposals regarding the refueling oil itself are still inadequate or inadequate in any case, and at present there has not been found any solution that highly solves the above problems.

【０００５】[0005]

【発明が解決しようとする課題】本発明は、上記背景に
鑑みなされたものであり、その目的とするところは、製
糸工程において生じる単糸切れや糸切れが極めて少な
く、且つ、良好な捲姿を有するパッケージを安定に得る
ことのできるポリエステル繊維の高速製糸方法を提供す
るところにある。SUMMARY OF THE INVENTION The present invention has been made in view of the above background, and an object of the present invention is to provide an excellent winding shape in which single yarn breakage or yarn breakage occurring in a yarn making process is extremely small. It is an object of the present invention to provide a high-speed spinning method of polyester fiber which can stably obtain a package having the following.

【０００６】[0006]

【課題を解決するための手段】本発明者らは、上記目的
を達成するべく鋭意検討した結果、高速度で製糸する際
には、特定の油剤組成物からなる処理油剤エマルジョン
を付与することが極めて重要であることを見出し、本発
明に至ったものである。Means for Solving the Problems The inventors of the present invention have conducted intensive studies to achieve the above object, and as a result, when producing yarn at a high speed, it is necessary to apply a treated oil agent emulsion comprising a specific oil agent composition. It has been found to be extremely important, and has led to the present invention.

【０００７】即ち、本発明によれば、３０００ｍ／分以
上の紡糸速度でポリエステル繊維を高速製糸する方法に
おいて、前記ポリエステル繊維に、平均分子量が３００
〜５００の一塩基酸エステルを５０重量％以上、下記
（ａ）を１〜１５重量％、及び下記（ｂ）を０．１〜３
重量％含有する油剤の水系エマルジョンを付与すること
を特徴とするポリエステル繊維の高速製糸方法、 （ａ）平均分子量が１０００以上のポリオキシアルキレ
ングリコール共重合体 （ｂ）有機シロキサン化合物及び／又はフルオロアルキ
ル基含有化合物が提供される。That is, according to the present invention, in a method for producing a polyester fiber at a high speed at a spinning speed of 3000 m / min or more, the polyester fiber has an average molecular weight of 300
50% by weight or more of the monobasic acid ester of 500 to
(A) is 1 to 15% by weight, and (b) is 0.1 to 3% by weight.
Fast reeling a polyester fiber characterized by imparting an aqueous emulsion of oil containing by weight%, (a) an average molecular weight of 1000 or more polyoxyalkylene glycol copolymer (b) an organosiloxane compound and / or fluoroalkyl group-containing compound.

【０００８】本発明のポリエステル繊維は、主たる繰り
返し単位がエチレンテレフタレートであるポリエステ
ル、例えばポリエチレンテレフタレートからなる繊維を
主たる対象とし、紡糸速度が３０００ｍ／分以上で紡糸
された繊維、好ましくは３５００〜４０００ｍ／分の速
度で引き取られ次いで延伸される繊維に適用される。[0008] The polyester fiber of the present invention is mainly intended for a polyester whose main repeating unit is ethylene terephthalate, for example, a fiber made of polyethylene terephthalate, and a fiber spun at a spinning speed of 3000 m / min or more, preferably 3500 to 4000 m / m. It is applied to fibers that are drawn at a speed of minutes and then drawn.

【０００９】紡糸速度が３０００ｍ／分未満の場合に
は、従来汎用されている給油用油剤を用いても前述の工
程調子あるいは品質上の問題は発生しないので、本発明
の対象外であり、本発明にかかる油剤は、３０００ｍ／
分以上の紡糸速度で製糸する際に初めて効果を発現する
ものである。[0009] If the spinning speed is less than 3000 m / min, the above-mentioned problems in process condition or quality do not occur even if a conventional oiling agent is widely used. The oil agent according to the invention is 3000 m /
The effect is exhibited only when spinning at a spinning speed of at least minutes.

【００１０】本発明においては、高速紡糸されたポリエ
ステル繊維には、高速で走行する糸条に抵抗なく付着せ
しめるといった観点より、油剤は水で希釈した水系エマ
ルジョンを付与する必要がある。いわゆる水を含まない
ストレート型では油剤の粘度が高く、走行糸条への濡れ
が悪くなって毛羽が発生し易くなったり、オイリング時
走行糸条に負荷がかかりすぎて単糸切れが発生し易くな
ったりするので好ましくない。In the present invention, it is necessary to provide the oil agent with an aqueous emulsion diluted with water from the viewpoint that the polyester fiber spun at high speed is adhered to the yarn running at high speed without resistance. In the so-called water-free straight type, the viscosity of the oil agent is high, the wetting of the running yarn is poor, and fluff is likely to occur, or the running yarn is overloaded and the single yarn breaks easily during oiling. This is not preferred because

【００１１】次に、本発明で用いられる油剤の主体成分
である一塩基酸エステル化合物は、油剤の有効成分に対
して５０重量％以上、好ましくは５０〜７５重量％以上
が必要であり、５０％未満の場合には３０００ｍ／分以
上といった高速紡糸に要求される潤滑性を付与すること
ができなくなって、毛羽及び糸切れの発生が増大するた
め好ましくない。Next, the monobasic acid ester compound, which is the main component of the oil agent used in the present invention, needs to be 50% by weight or more, preferably 50 to 75% by weight or more, based on the active ingredient of the oil agent. % Is not preferable because lubricity required for high-speed spinning of 3000 m / min or more cannot be imparted, and fluff and yarn breakage increase.

【００１２】かかる一塩基酸エステルは、一価の脂肪族
カルボン酸と一価の脂肪族アルコールとから得られるモ
ノエステル化合物であって、その分子量が３００〜５０
０、好ましくは３５０〜４５０である必要がある。具体
的には、オクチルパルミテート、オクチルステアレー
ト、ラウリルラウレート、２―エチルヘキシルステアレ
ート、イソトリデシルパルミテート、イソステアリルカ
プリレート等が好ましく用いられる。The monobasic acid ester is a monoester compound obtained from a monovalent aliphatic carboxylic acid and a monovalent aliphatic alcohol, and has a molecular weight of 300 to 50.
0, preferably 350-450. Specifically, octyl palmitate, octyl stearate, lauryl laurate, 2-ethylhexyl stearate, isotridecyl palmitate, isostearyl caprylate and the like are preferably used.

【００１３】ここにおいて、分子量が５００を越える一
塩基酸エステル、または二価以上の多塩基酸エステルを
用いた場合には、製糸時の走行糸と糸導の摩擦が増大し
て、毛羽、糸切れが発生することになり好ましくない。
一方分子量が３００未満の一塩基酸エステルでは、製糸
に続いて行なわれる延伸又は熱処理の段階の熱により発
煙を生じ易く、作業環境汚染の問題を引き起こすため好
ましくない。When a monobasic acid ester having a molecular weight of more than 500 or a polybasic acid ester having a valency of 2 or more is used, the friction between the running yarn and the yarn guide during yarn production increases, and fluff, yarn Cuts are generated, which is not preferable.
On the other hand, a monobasic acid ester having a molecular weight of less than 300 is not preferable because smoke is easily generated due to heat in a drawing or heat treatment step performed after the spinning and causes a problem of working environment pollution.

【００１４】本発明で用いられる油剤のもう一つの必須
成分であるポリオキシアルキレングリコール共重合体
は、油膜強度を高め、糸に耐摩耗性、耐擦過性を付与す
るものである。これらの特性向上の効果により、高速製
糸過程中の糸と糸導、あるいは糸同士の耐摩耗性に有効
に働き、毛羽が極めて少ない糸が断糸することなく効率
よく製糸できるといったことが見い出されたのである。
かかる油膜強度向上により糸の耐摩耗性を向上すること
は、従来より硬化ヒマシ油の高重合物、多価アルコール
のポリエステル等を添加する方法が提案されているが、
これらの方法ではある程度の効果は得られるものの、高
速製糸で要求される程度の効果を得るためには量的に多
くする必要がある。このため、逆に繊維間摩擦が低下し
すぎ、高速で捲き取る原糸のパッケージの捲姿が不安定
なものとなり、操業性の低下や後加工工程での原糸の解
舒性不良等の問題を引き起こすことになる。The polyoxyalkylene glycol copolymer, which is another essential component of the oil agent used in the present invention, enhances the oil film strength and imparts abrasion resistance and abrasion resistance to the yarn. It has been found that the effect of improving these properties effectively works on the yarn and yarn guide during the high-speed spinning process, or the abrasion resistance between the yarns, and that the yarn with extremely little fluff can be efficiently produced without breaking. It was.
To improve the abrasion resistance of the yarn by improving the oil film strength, a method of adding a high polymer of a hardened castor oil, a polyester of a polyhydric alcohol, or the like has been proposed.
Although these methods can provide a certain degree of effect, they need to be quantitatively increased in order to obtain the degree of effect required for high-speed spinning. For this reason, on the contrary, the friction between the fibers is too low, and the winding form of the yarn of the yarn to be wound at high speed becomes unstable, so that the operability is reduced and the unwound property of the yarn in the post-processing step is poor. Will cause problems.

【００１５】本発明者らは、かかる問題について鋭意研
究した結果、パッケージの捲姿は比較的低荷重下でうけ
る繊維間静摩擦との相関があり、一方高速製糸時にうけ
る耐摩擦性は高温、高荷重下での繊維間静摩擦との相関
があることを見い出した。そして後者の静摩擦の低減効
果が大きく且つ前者の静摩擦はあまり低減させない油剤
成分について検討した結果、ある程度の分子量をもつポ
リオキシアルキレングリコール共重合体を特定量配合す
ることが有効であることを見い出したのである。The present inventors have conducted intensive studies on such a problem, and as a result, the winding of the package has a correlation with the inter-fiber static friction under a relatively low load. It was found that there was a correlation with the inter-fiber static friction under load. As a result of examining an oil agent component which has a large effect of reducing the static friction of the latter and does not significantly reduce the static friction of the former, it has been found that it is effective to mix a specific amount of a polyoxyalkylene glycol copolymer having a certain molecular weight. It is.

【００１６】すなわち、本発明で用いられる油剤のもう
一つの必須成分は、平均分子量が１０００以上ポリオキ
シアルキレングリコール共重合体であり、油剤の有効成
分に対して１〜１５重量％含まれる必要がある。添加量
が１重量％未満の場合には、油膜強度向上の効果は不充
分であり、一方１５重量％を越える場合には、油剤の粘
度増加により走行糸条の動摩擦係数が増大して毛羽が発
生し易くなり、静摩擦係数は逆に低下してパッケージの
捲姿が悪化し易くなるので好ましくない。さらに、後加
工工程での糊付において、糊皮膜を軟化せしめて糊付効
果を低減したり、糊落ちを引き起こして製織効率を低下
せしめるといった問題がある。また平均分子量が１００
０未満の場合には、該剤の凝集力が不充分で、油膜強度
向上効果が不充分となり本発明の目的は達成できなくな
る。That is, another essential component of the oil agent used in the present invention is a polyoxyalkylene glycol copolymer having an average molecular weight of 1,000 or more, which must be contained in an amount of 1 to 15% by weight based on the active ingredient of the oil agent. is there. When the amount is less than 1% by weight, the effect of improving the oil film strength is insufficient. On the other hand, when the amount exceeds 15% by weight, the kinetic friction coefficient of the running yarn increases due to an increase in the viscosity of the oil agent, resulting in fluff. This is not preferable because it easily occurs, and the coefficient of static friction is reduced to the contrary, and the winding appearance of the package is easily deteriorated. Furthermore, in the pasting in the post-processing step, there is a problem that the paste film is softened to reduce the pasting effect, or that the weaving efficiency is reduced by causing the paste to be removed. In addition, the average molecular weight is 100
When it is less than 0, the cohesive force of the agent is insufficient, the effect of improving the oil film strength is insufficient, and the object of the present invention cannot be achieved.

【００１７】かかるポリオキシアルキレングリコール共
重合体としては、例えば側鎖としてアルキル基を有する
エチレンオキサイド／プロピレンオキサイド共重合体、
側鎖を有さないエチレンオキサイド／テトラヒドロフラ
ン共重合体（エチレンオキシ単位・テトラメチレンオキ
シ単位からなる共重合体）等をあげることができ、これ
らの末端水酸基は、アルキル基、アリール基、アシル基
等で封鎖されていてもよく、また未封鎖のままでもよ
い。これらのなかでエチレンオキサイド／プロピレンオ
キサイド共重合体を用いる場合には、平均分子量が９０
００以上のもの、特に共重合比が２０／８０〜８０／２
０（ＥＯ／ＰＯ重量比）の共重合体で分子量が９０００
〜３００００のものを４〜１５重量％用いることが望ま
しく、一方エチレンオキサイド／テトラヒドロフラン共
重合体を用いる場合には、共重合比が２０／８０〜８０
／２０（重量比）で平均分子量が１０００〜７０００の
ものを１〜１０重量％、特に１〜５重量％用いることが
望ましい。なかでも側鎖を有さないエチレンオキサイド
／テトラヒドロフラン共重合体を用いる場合には、油膜
強度向上の効果が大きいためと推定され、高速製糸時の
毛羽、断糸の抑制効果が極めて大きく好ましい。The polyoxyalkylene glycol copolymer includes, for example, an ethylene oxide / propylene oxide copolymer having an alkyl group as a side chain,
Examples include ethylene oxide / tetrahydrofuran copolymers having no side chains (copolymers composed of ethyleneoxy units / tetramethyleneoxy units), and these terminal hydroxyl groups are alkyl groups, aryl groups, acyl groups, and the like. And may be left unblocked. When an ethylene oxide / propylene oxide copolymer is used among these, the average molecular weight is 90%.
00 or more, especially copolymerization ratio of 20/80 to 80/2
0 (EO / PO weight ratio) copolymer with a molecular weight of 9000
It is preferable to use 4 to 15% by weight of a copolymer having a copolymerization ratio of 20/80 to 80 when an ethylene oxide / tetrahydrofuran copolymer is used.
/ 20 (weight ratio) and an average molecular weight of 1,000 to 7000 is preferably used in an amount of 1 to 10% by weight, particularly 1 to 5% by weight. In particular, when an ethylene oxide / tetrahydrofuran copolymer having no side chain is used, it is presumed that the effect of improving the oil film strength is large, and the effect of suppressing fluff and breakage during high-speed spinning is extremely large and is preferable.

【００１８】なお、ポリオキシアルキレングリコール共
重合体の平均分子量の上限は特に限定するものでない
が、あまりに大きい場合には油剤の粘度が増大して高速
走行糸条の動摩擦を高めてしまう傾向があり、また油剤
エマルジョンの安定性も低下してスカムとして堆積し易
くなるので、用いるポリオキシアルキレングリコール共
重合体に応じて適宜変更することが望ましい。The upper limit of the average molecular weight of the polyoxyalkylene glycol copolymer is not particularly limited, but if it is too large, the viscosity of the oil agent tends to increase and the dynamic friction of the high-speed running yarn tends to increase. In addition, the stability of the oil agent emulsion is reduced, and the oil agent emulsion is easily deposited as scum. Therefore, it is desirable to appropriately change the emulsion according to the polyoxyalkylene glycol copolymer to be used.

【００１９】また本発明で用いられるもう一つの必須成
分である有機シロキサン化合物及び／又はフルオロアル
キル基含有化合物の配合量は、０．１〜３重量％、好ま
しくは０．５〜２重量％の範囲とする必要がある。かく
することにより、油剤エマルジョンの表面張力が減少し
て高速度で走行する糸条への油剤均一付着性が向上する
とともに、走行糸条が該油剤エマルジョンに接する際に
受ける抵抗も低下して、糸の均質性及び製糸の工程調子
が著しく改善される。特に油剤エマルジョンの表面張力
が３０dyne／cm以下となる場合には、油剤の均一付着性
が極めて向上するとともに油剤付与時の接触応力も低下
するため、３０００ｍ／分以上といった高速製糸に有効
である。配合量が０．１重量％未満では上記効果が得ら
れず、一方３重量％を越えると油剤エマルジョンの安定
性が低下したり、染色時に染色斑が発生し易くなるので
好ましくない。The compounding amount of the organic siloxane compound and / or the fluoroalkyl group-containing compound which is another essential component used in the present invention is 0.1 to 3% by weight, preferably 0.5 to 2% by weight. Must be a range. By doing so, the surface tension of the oil agent emulsion is reduced and the oil agent uniform adhesion to the yarn running at high speed is improved, and the resistance received when the running yarn comes into contact with the oil agent emulsion is also reduced, The yarn homogeneity and the process quality of the yarn production are significantly improved. In particular, when the surface tension of the oil agent emulsion is 30 dyne / cm or less, the uniform adhesion of the oil agent is remarkably improved and the contact stress at the time of applying the oil agent is reduced, which is effective for high-speed spinning at 3000 m / min or more. If the amount is less than 0.1% by weight, the above effects cannot be obtained. If the amount is more than 3% by weight, the stability of the oil emulsion is lowered and stains are apt to occur during dyeing.

【００２０】かかる表面張力を低下させる有機シロキサ
ン化合物としては、アミノ変性シリコーン、ポリエーテ
ル変性シリコーン、ポリエステル変性シリコーンなど各
種変性シリコーン及び、例えば３０cst （２５℃）以下
のような低粘度ジメチルシリコーンなど有機シロキサン
化合物をあげることができ、またフルオロアルキル基含
有化合物としてはパーフルオロアルキルエーテル、パー
フルオロスルホネート、パーフルオロスルホン酸アミド
などのフッ素化合物をあげることができる。なお、表面
張力の値は、ウィルヘルミー法によって３０℃で測定し
た値である。Examples of the organic siloxane compound for lowering the surface tension include various modified silicones such as amino-modified silicone, polyether-modified silicone and polyester-modified silicone, and organic siloxane such as low-viscosity dimethyl silicone having a viscosity of 30 cst (25 ° C.) or less. Compounds can be mentioned, and as the fluoroalkyl group-containing compound, fluorine compounds such as perfluoroalkyl ether, perfluorosulfonate and perfluorosulfonic acid amide can be mentioned. The value of the surface tension is a value measured at 30 ° C. by the Wilhelmy method.

【００２１】本発明で用いる油剤は上記３成分を必須成
分として構成されていることが重要であるが、この他に
一般の乳化剤、高級アルコール、高級脂肪酸、グライコ
ール類、及び少量の有機もしくは無機化合物の添加剤、
及び帯電防止剤、脂肪酸のジエタノールアマイド等のア
マイド化合物を加えてもよい。It is important that the oil agent used in the present invention comprises the above three components as essential components. In addition to the above, general emulsifiers, higher alcohols, higher fatty acids, glycols, and a small amount of organic or inorganic Compound additives,
Further, an antistatic agent and an amide compound such as diethanolamide of a fatty acid may be added.

【００２２】以上のように、本発明においては、上記３
成分を必須成分とする油剤エマルジョンを、３０００ｍ
／分以上の高速紡糸の際に付与することにより、前述の
如く従来にない顕著な作用効果を奏し得たものであり、
これらのいずれかが欠けても、本発明の優れた効果を奏
することはできない。As described above, in the present invention, the above 3
Oil emulsion containing essential components as 3000m
/ Min or more at the time of high-speed spinning, as described above, it was possible to achieve a remarkable function and effect that has not been achieved conventionally.
If any of these are missing, the excellent effects of the present invention cannot be achieved.

【００２３】なお、本発明の油剤エマルジョンを付与す
るには、紡糸糸条が固化した時点以降であればいずれの
時点でもよいが、通常は引取ローラより前の時点で糸条
に付与する。付与する好ましい手段としては、本発明の
油剤エマルジョンを、計量オイリングノズルを介して油
剤純分量が糸重量に対して、例えば０．３５〜１．０重
量％になるように付与することにより達成されるが、こ
れに限定されるものではない。The oil agent emulsion of the present invention can be applied at any time after the spun yarn has solidified, but is usually applied to the yarn before the take-up roller. As a preferable means of applying, the oil agent emulsion of the present invention is achieved by applying the oil agent emulsion via a measuring oiling nozzle such that the oil agent pure content is, for example, 0.35 to 1.0% by weight with respect to the yarn weight. However, the present invention is not limited to this.

【００２４】[0024]

【発明の作用・効果】３０００ｍ／分以上といった高速
度の紡糸速度のもとでは、第一引取ローラに至るまでの
走行糸条にはできるだけ無理な張力負担をかけることな
く、高速度で走行する糸条に油剤を均一付着させること
及び高速度で走行する糸条の摩擦を低下させることが、
均質な糸を安定に製糸する上で重要なポイントである。Under the high spinning speed of 3000 m / min or more, the running yarn traveling to the first take-up roller runs at a high speed without imposing as much excessive tension load as possible. To uniformly apply the oil agent to the yarn and reduce the friction of the yarn running at high speed,
This is an important point in stably producing uniform yarn.

【００２５】本発明においては、上述の如く油剤を水系
エマルジョンとして粘度を低下させるとともに特定のシ
ロキサン化合物又はフッ素含有化合物を併用してエマル
ジョン表面張力を低下させているため、高速度で走行す
る糸条への油剤均一付着性が向上し、且つ油剤付与装置
と糸条との接触時発生する負荷応力も低下している。In the present invention, as described above, the viscosity of the oil agent is reduced as an aqueous emulsion, and the surface tension of the emulsion is reduced by using a specific siloxane compound or a fluorine-containing compound in combination. The uniform adhesion of the oil agent to the yarn is improved, and the load stress generated when the oil agent applying device comes into contact with the yarn is also reduced.

【００２６】また、特定量のポリオキシアルキレングリ
コール共重合体が配合されているため油剤系全体として
の油膜強度が向上し、３０００ｍ／分以上といった高速
度の製糸条件下でも走行糸条に負荷される応力に油膜が
充分耐えられるようになり、潤滑特性の低下がなくなっ
ている（極圧潤滑特性の低下が少ない）。Further, since a specific amount of the polyoxyalkylene glycol copolymer is blended, the oil film strength of the entire oil agent system is improved, and the oil is applied to the running yarn even under high-speed yarn forming conditions of 3000 m / min or more. The oil film has become able to withstand the applied stress sufficiently, and the deterioration of the lubrication characteristics is eliminated (the deterioration of the extreme pressure lubrication characteristics is small).

【００２７】さらに特定の一塩基酸エステルからなる平
滑剤を油剤の主体成分としているので、油剤全体として
の粘度が低下して高速製糸時の走行糸条と糸導等との摩
擦も低下している。Further, since a smoothing agent composed of a specific monobasic acid ester is used as a main component of the oil agent, the viscosity of the oil agent as a whole decreases, and the friction between the running yarn and the yarn guide during high-speed spinning also decreases. I have.

【００２８】上記効果が組み合わされることによって、
その理由は定かではないが、毛羽が少ない高品位のポリ
エステル繊維が安定に製糸することが可能となり、且つ
得られるパッケージの捲姿も良好になるものと推定され
る。By combining the above effects,
Although the reason is not clear, it is presumed that high-quality polyester fibers with little fluff can be stably produced and the obtained package has good winding appearance.

【００２９】本発明の方法により得られる繊維は、金属
・繊維間及び繊維・繊維間の擦過耐久性に優れているた
め製編織時にトラブルも発生し難く、また高速製糸され
たものであるため良好な織物風合を呈するものが得られ
る。The fiber obtained by the method of the present invention is excellent in abrasion durability between metal and fiber and between fiber and fiber, so that troubles do not easily occur at the time of knitting and weaving. A material exhibiting a good fabric feeling is obtained.

【００３０】[0030]

【実施例】以下、本発明を実施例によって更に説明す
る。なお、実施例において用いる原糸毛羽、耐擦過性
は、それぞれ下記の方法によって求めたものである。The present invention will be further described below with reference to examples. The raw yarn fluff and scratch resistance used in the examples were determined by the following methods.

【００３１】（１）原糸毛羽 原糸を１６０本採取して、各々４０万ｍ間の毛羽（単糸
切れ）の個数をカウント積算し、これから１０6 ｍ当た
りの毛羽個数を求め、表１に示す三段階で評価した。(1) Fluffs of the original yarn 160 yarns were collected, and the number of fluffs (single yarn breaks) between each of 400,000 m was counted and integrated, and the number of fluffs per 10 6 m was calculated from this. The evaluation was made in three steps as shown in FIG.

【００３２】[0032]

【表１】 [Table 1]

【００３３】（２）耐擦過性 繊維と金属（Ｆ／Ｍ）、及び繊維と繊維（Ｆ／Ｆ）との
それぞれの耐擦過性の評価を表２の測定法により行っ
た。(2) Scratch Resistance The abrasion resistance of each of the fiber and the metal (F / M) and the fiber and the fiber (F / F) was evaluated by the measurement methods shown in Table 2.

【００３４】[0034]

【表２】 [Table 2]

【００３５】[0035]

【実施例１】固有粘度［η］が０．６４のポリエチレン
テレフタレートを溶融吐出して、３６フィラメントの糸
条となした。この糸条の固化後計量オイリングノズルを
介して、表３に示す油剤純分を１０％水系エマルジョン
となし、糸重量に対して有効成分として０．４重量％と
なるように付与した。その後、表面速度４０００ｍ／分
の引取ローラを介して引き取り、引き続き引取ローラと
延伸ローラ間で１．５倍に延伸して、５０ｄ／３６ｆの
延伸糸を得た。この時得られた原糸をもって、前述の測
定法により評価した結果を表３にまとめた。Example 1 Polyethylene terephthalate having an intrinsic viscosity [η] of 0.64 was melt-discharged to form a 36-filament yarn. After the yarn was solidified, a 10% aqueous emulsion was prepared from the oil component shown in Table 3 through a metering oiling nozzle, and was applied so as to be 0.4% by weight as an active ingredient based on the weight of the yarn. Thereafter, the yarn was taken up via a take-up roller having a surface speed of 4000 m / min, and subsequently stretched 1.5 times between the take-up roller and the draw roller to obtain a 50d / 36f drawn yarn. Table 3 summarizes the results of the evaluation of the raw yarn obtained at this time by the above-described measurement method.

【００３６】なお、表中、表面張力は、３０℃の温度に
保って協和科学（株）製の表面張力計で測定した。In the table, the surface tension was measured at a temperature of 30 ° C. with a surface tensiometer manufactured by Kyowa Kagaku Co., Ltd.

【００３７】[0037]

【表３】 [Table 3]

【００３８】本結果から明らかなように、本発明の製造
法は、毛羽の少ない耐摩耗性に優れたポリエステル繊維
を高速で生産するに極めて顕著な効果が得られることが
わかる。As is evident from the results, it can be seen that the production method of the present invention has a remarkable effect in producing polyester fibers with little fluff and excellent abrasion resistance at high speed.

フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｄ０６Ｍ 15/647 Ｄ０６Ｍ 15/647 // Ｄ０６Ｍ 101:32 (56)参考文献 特開 昭58−220822（ＪＰ，Ａ) 特開 昭59−1779（ＪＰ，Ａ) 特開 平２−242977（ＪＰ，Ａ) 特開 平１−306684（ＪＰ，Ａ) 特開 平２−229272（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) D06M 13/00 - 13/353 D06M 15/00 - 15/72 D01F 6/62 301 D01F 11/04 - 11/08 Continuation of the front page (51) Int.Cl. 6 Identification symbol FI D06M 15/647 D06M 15/647 // D06M 101: 32 (56) References JP-A-58-220822 (JP, A) JP-A-59- 1779 (JP, A) JP-A-2-242977 (JP, A) JP-A-1-306684 (JP, A) JP-A-2-229272 (JP, A) (58) Fields investigated (Int. 6 , DB name) D06M 13/00-13/353 D06M 15/00-15/72 D01F 6/62 301 D01F 11/04-11/08

Claims (4)

(57)【特許請求の範囲】(57) [Claims] 【請求項１】 ３０００ｍ／分以上の紡糸速度でポリエ
ステル繊維を高速製糸する方法において、前記ポリエス
テル繊維に、平均分子量が３００〜５００の一塩基酸エ
ステルを５０重量％以上、下記（ａ）を１〜１５重量
％、及び下記（ｂ）を０．１〜３重量％含有する油剤の
水系エマルジョンを付与することを特徴とするポリエス
テル繊維の高速製糸方法。 （ａ）平均分子量が１０００以上のポリオキシアルキレ
ングリコール共重合体 （ｂ）有機シロキサン化合物及び／又はフルオロアルキ
ル基含有化合物 1. A method for producing a polyester fiber at a high speed at a spinning speed of 3000 m / min or more, wherein the polyester fiber has a monobasic acid ester having an average molecular weight of 300 to 500 at 50% by weight or more, and ~ 15 weight
%, And an aqueous emulsion of an oil agent containing 0.1 to 3% by weight of the following (b) : (A) an average molecular weight of 1000 or more polyoxyalkylene glycol copolymer (b) an organosiloxane compound and / or a fluoroalkyl group-containing compound 【請求項２】 ポリオキシアルキレングリコール共重合
体が平均分子量９０００以上のエチレンオキサイド・プ
ロピレンオキサイド共重合体であり、油剤中の含有量が
４〜１５重量％である請求項１記載のポリエステル繊維
の高速製糸方法。2. The polyester fiber according to claim 1, wherein the polyoxyalkylene glycol copolymer is an ethylene oxide / propylene oxide copolymer having an average molecular weight of 9000 or more, and the content in the oil agent is 4 to 15% by weight. High-speed spinning method. 【請求項３】 ポリオキシアルキレングリコール共重合
体が平均分子量１０００〜７０００のオキシテトラメチ
レン単位とオキシエチレン単位との共重合体であり、油
剤中の含有量が１〜１０重量％である請求項１記載のポ
リエステル繊維の高速製糸方法。3. The polyoxyalkylene glycol copolymer is a copolymer of oxytetramethylene units and oxyethylene units having an average molecular weight of 1,000 to 7000, and the content in the oil agent is 1 to 10% by weight. 2. The high-speed spinning method of the polyester fiber according to 1. 【請求項４】 油剤の水系エマルジョンの表面張力が３
０dyne／cm以下である請求項１ないし３のいずれか１項
に記載のポリエステル繊維の高速製糸方法。4. The surface tension of an aqueous emulsion of an oil agent is 3
The high-speed spinning method for polyester fibers according to any one of claims 1 to 3, wherein the drying speed is 0 dyne / cm or less.
JP7977192A 1992-04-01 1992-04-01 High-speed spinning of polyester fiber Expired - Fee Related JP2962925B2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP7977192A JP2962925B2 (en) 1992-04-01 1992-04-01 High-speed spinning of polyester fiber
EP93906853A EP0605727B1 (en) 1992-04-01 1993-03-30 Process for high-speed spinning of polyester fiber
KR1019930703656A KR0163204B1 (en) 1992-04-01 1993-03-30 Process for high-speed spinning of polyester
TW82102359A TW221465B (en) 1992-04-01 1993-03-30
DE69322063T DE69322063T2 (en) 1992-04-01 1993-03-30 METHOD FOR THE QUICK SPINNING OF POLYESTER FIBERS
PCT/JP1993/000398 WO1993020268A1 (en) 1992-04-01 1993-03-30 Process for high-speed spinning of polyester fiber
US08/371,170 US5507989A (en) 1992-04-01 1995-01-11 High speed process for producing polyester filaments
US08/537,250 US5607634A (en) 1992-04-01 1995-09-29 High speed process for producing polyester filaments

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7977192A JP2962925B2 (en) 1992-04-01 1992-04-01 High-speed spinning of polyester fiber

Publications (2)

Publication Number Publication Date
JPH05287609A JPH05287609A (en) 1993-11-02
JP2962925B2 true JP2962925B2 (en) 1999-10-12

Family

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Application Number Title Priority Date Filing Date
JP7977192A Expired - Fee Related JP2962925B2 (en) 1992-04-01 1992-04-01 High-speed spinning of polyester fiber

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EP (1) EP0605727B1 (en)
JP (1) JP2962925B2 (en)
KR (1) KR0163204B1 (en)
DE (1) DE69322063T2 (en)
TW (1) TW221465B (en)
WO (1) WO1993020268A1 (en)

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GB9412178D0 (en) * 1994-06-17 1994-08-10 Dow Corning Sa Foam control agent
CA2210288C (en) * 1995-01-13 2008-03-25 Imperial Chemical Industries Plc Surfactant compositions
WO2001048301A1 (en) 1999-12-28 2001-07-05 Sanyo Chemical Industries, Ltd. Spinning oil for synthetic fiber
JP4370836B2 (en) * 2003-07-10 2009-11-25 東レ株式会社 Oil for carbon fiber production and method for producing carbon fiber
JP5444681B2 (en) 2007-10-19 2014-03-19 Ｅｓファイバービジョンズ株式会社 Polyester-based heat-fusible composite fiber
JP6592862B2 (en) 2013-09-02 2019-10-23 国立大学法人東京工業大学 Polyester fiber
JP2016017231A (en) * 2014-07-04 2016-02-01 三菱レイヨン株式会社 Method for producing carbon fiber precursor acrylic fiber bundle and oil agent treatment liquid for carbon fiber precursor acrylic fiber
CN111819322B (en) * 2018-03-07 2023-05-12 株式会社可乐丽 Molten anisotropic aromatic polyester multifilament yarn

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JPS58174624A (en) * 1982-04-02 1983-10-13 Teijin Ltd Preparation of interlaced yarn in high-speed spinning
JPS6215319A (en) * 1985-07-06 1987-01-23 Asahi Chem Ind Co Ltd Production of polyester yarn
JPS63112769A (en) * 1986-10-31 1988-05-17 帝人株式会社 Polyester staple fiber
JPH0247372A (en) * 1988-08-03 1990-02-16 Matsumoto Yushi Seiyaku Co Ltd Treating agent for fiber
JP2505570B2 (en) * 1989-03-13 1996-06-12 帝人株式会社 Polyester fiber
JPH03180577A (en) * 1989-12-08 1991-08-06 Asahi Chem Ind Co Ltd Finishing agent for synthetic fiber
JP2557995B2 (en) * 1990-02-23 1996-11-27 帝人株式会社 Abrasion resistance improvement treatment agent

Also Published As

Publication number Publication date
KR0163204B1 (en) 1998-12-01
EP0605727B1 (en) 1998-11-11
EP0605727A1 (en) 1994-07-13
TW221465B (en) 1994-03-01
DE69322063D1 (en) 1998-12-17
EP0605727A4 (en) 1995-10-11
DE69322063T2 (en) 1999-05-20
WO1993020268A1 (en) 1993-10-14
JPH05287609A (en) 1993-11-02

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