JP2958605B2 - Melt treatment method for fibrous waste - Google Patents
Melt treatment method for fibrous wasteInfo
- Publication number
- JP2958605B2 JP2958605B2 JP6203346A JP20334694A JP2958605B2 JP 2958605 B2 JP2958605 B2 JP 2958605B2 JP 6203346 A JP6203346 A JP 6203346A JP 20334694 A JP20334694 A JP 20334694A JP 2958605 B2 JP2958605 B2 JP 2958605B2
- Authority
- JP
- Japan
- Prior art keywords
- waste
- electrode
- gas
- melting
- molten slag
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Description
【0001】[0001]
【産業上の利用分野】本発明は繊維質系の廃棄物の溶融
処理方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for melting and treating fibrous waste.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
建築物の内壁材や耐火物として使用していたアスベス
ト,その他,ロックウール,ガラスウール等、繊維質系
の廃棄物はビニール袋等に入れ、外部へ流出しないよう
な措置を施して廃棄したり、また、コンクリート等の凝
固材で固化してから埋立地へ廃棄したりしており、更に
廃棄後長期にわたって外部への流出がないよう管理しな
ければならず、その廃棄処理が非常に厄介である。特
に、アスベスト、ロックウール、ガラスウール等は見掛
け比重が小さいため、廃棄の際に容積が大きくなり、埋
立地の確保も難しく減容化が求められている。2. Description of the Related Art
Fiber materials such as asbestos, rock wool, glass wool, etc. used as inner wall materials and refractories of buildings are placed in plastic bags, etc. In addition, they are solidified with a solidifying material such as concrete and then disposed of in landfills.Furthermore, after disposal, they must be managed so that they do not flow out to the outside for a long period of time. is there. In particular, asbestos, rock wool, glass wool, and the like have small apparent specific gravities, so their volumes increase upon disposal, and it is difficult to secure landfill sites, and it is required to reduce the volume.
【0003】また、繊維質系の廃棄物の他の廃棄方法と
して、繊維質系の廃棄物に溶融促進剤等を添加し、溶融
処理する方法も提案されているが、処理コストがかかる
等の欠点がある。As another method of disposing of fibrous waste, a method of adding a melting accelerator or the like to fibrous waste and performing a melting treatment has been proposed. There are drawbacks.
【0004】本発明は繊維質系の廃棄物を適当な粒度に
解砕したものを溶融炉に供給し、溶融スラグ化し、固化
し、減容化、無害化を可能にする繊維質系の廃棄物の溶
融処理方法を提供するものである。According to the present invention, fibrous waste obtained by disintegrating fibrous waste into an appropriate particle size is supplied to a melting furnace, and is melted into slag, solidified, reduced in volume, and made harmless. It is intended to provide a method for melting a material.
【0005】[0005]
【課題を解決するための手段】添付図面を参照して本発
明の要旨を説明する。The gist of the present invention will be described with reference to the accompanying drawings.
【0006】アスベスト,ロックウール,ガラスウール
等の繊維質系の廃棄物11を溶融炉1に投入して該廃棄物
11を溶融せしめる方法であって、廃棄物11を電極7に近
い部分の層厚を厚くし且つ電極7より離れるに従い層厚
が薄くなるようにして投入し、電極7に通電せしめて廃
棄物11が溶融することにより生じる溶融スラグ2からの
抵抗熱により順次投入される廃棄物11を溶融せしめると
ともに、廃棄物11の溶融の際に溶融スラグ2と電極7と
の間に該廃棄物11により形成される架橋4を破壊して該
架橋4を溶融スラグ2中に埋没させる押圧手段9により
該架橋4を破壊することを特徴とする繊維質系の廃棄物
の溶融処理方法に係るものである。A fibrous waste material 11 such as asbestos, rock wool, glass wool or the like is put into a melting furnace 1 and
In this method, the waste 11 is put in such a manner that the thickness of the portion near the electrode 7 is increased and the thickness of the layer is reduced as the distance from the electrode 7 is increased. When the wastes 11 sequentially injected by the resistance heat from the molten slag 2 generated by the melting of
In both cases, when the waste 11 is melted, the pressing means 9 for breaking the bridge 4 formed by the waste 11 between the molten slag 2 and the electrode 7 and burying the bridge 4 in the molten slag 2 < The present invention relates to a method for melting and treating fibrous waste, characterized in that the crosslink 4 is destroyed .
【0007】[0007]
【作用】一般的に(電気)溶融処理方法の場合、電極7
の下面7aが最も高温になる為、ガスは該下面7aにお
いて最も多く発生する。よって、該ガスは廃棄物11の堆
積層を均一に通過することなく、そのまま電極7の近く
から上方に向かって排出されてしまうことが多い(廃棄
物11の堆積層を通過することなく、電極7の周面に沿っ
て上方に排出されたりもする。)。In general, in the case of the (electric) melting process, the electrode 7
Since the lower surface 7a has the highest temperature, the gas is generated most at the lower surface 7a. Therefore, the gas is often discharged upward from near the electrode 7 without passing uniformly through the deposited layer of the waste 11 (without passing through the deposited layer of the waste 11, 7 may be discharged upward along the peripheral surface.)
【0008】繊維質系の廃棄物11を溶融スラグ2上に投
入する際、電極7周辺の層厚を厚くし且つ電極7より離
れるに従い層厚が薄くなるようにしたから、電極7周辺
の通気抵抗が大きくなり、電極7の近くにおいて集中的
に排出されるガスが減少し、ガスは電極7から離れた所
から廃棄物11の堆積層を通過して均一に排出されること
になる。よって、ガスとの接触により生ずる電極7の酸
化消耗が防止されることになる。When the fibrous waste material 11 is poured onto the molten slag 2, the layer thickness around the electrode 7 is increased and the layer thickness is reduced as the distance from the electrode 7 is increased. The resistance is increased, and the amount of gas exhausted in the vicinity of the electrode 7 is reduced, and the gas is uniformly exhausted from a place away from the electrode 7 through the deposited layer of the waste 11. Therefore, oxidative consumption of the electrode 7 caused by contact with the gas is prevented.
【0009】更に、ガスは、上記のように必ず廃棄物11
の堆積層を通過して噴出するから、ガス中のダストは該
堆積層により補集され、浄化され、ガス中のダスト濃度
は低下する。尚、該補集されたダストは再溶融される。
この点においてもガスの浄化は効率的に行われる。[0009] Further, as described above, the gas must be a waste 11
Therefore, dust in the gas is collected and purified by the sedimentary layer, and the concentration of dust in the gas decreases. The collected dust is re-melted.
Also in this respect, the purification of the gas is performed efficiently.
【0010】また、特にアスベストは融点が高い(15
50℃以上)ため、電極7の周面と溶融スラグ2の液面
との間に架橋4を形成し易い。これまでは、この架橋4
の為、廃棄物11の溶融が妨げられる場合が往々にしてあ
ったが、押圧手段9により、架橋4に圧力を加え該架橋
4を破壊するようにしたから、該廃棄物11の溶融は効率
的に行われる。In particular, asbestos has a high melting point (15
(50 ° C. or higher), so that the bridge 4 is easily formed between the peripheral surface of the electrode 7 and the liquid surface of the molten slag 2. Until now, this bridge 4
For this reason, the melting of the waste 11 was often hindered. However, the pressing means 9 applied pressure to the bridge 4 to break the bridge 4, so that the melting of the waste 11 was efficient. It is done on a regular basis.
【0011】[0011]
【実施例】以下本発明の実施例について図面により詳細
に説明する。Embodiments of the present invention will be described below in detail with reference to the drawings.
【0012】図1は本発明の断面図、図2は電極7周辺
の繊維質系の廃棄物11の架橋現象を示す断面図である。FIG. 1 is a cross-sectional view of the present invention, and FIG. 2 is a cross-sectional view showing a cross-linking phenomenon of a fibrous waste 11 around an electrode 7.
【0013】溶融炉1は耐火材により形成されている。
溶融炉1は上部に耐火材により形成した炉蓋5が取り付
けられており、炉内の発生ガスは炉内空間6に溜まり、
排ガスダクト12を通過して適当な公知のガス処理設備
(図示せず。)により浄化され、浄化ガスとして大気に
放出される。The melting furnace 1 is formed of a refractory material.
The melting furnace 1 is provided with a furnace lid 5 formed of a refractory material on an upper portion, and generated gas in the furnace is accumulated in a furnace space 6.
After passing through the exhaust gas duct 12, the gas is purified by a suitable known gas processing equipment (not shown) and released to the atmosphere as a purified gas.
【0014】炉蓋5には電極7が貫挿配置されている。An electrode 7 is inserted through the furnace lid 5.
【0015】また、電極7に接近して溶融処理される繊
維質系の廃棄物11の投入管8が炉蓋5を貫通して設けら
れている。Further, a charging pipe 8 for a fibrous waste 11 to be melted near the electrode 7 is provided through the furnace lid 5.
【0016】この投入管8には該投入管8から突出する
押圧手段9としての押圧棒体9’が設けられ、また、該
投入管8には搬送手段14が連設され、この搬送手段14に
は解砕手段15を内装したホッパー13から連設され、この
ホッパー13内に繊維質系の廃棄物11を供給する供給手段
10が連設されている。The input pipe 8 is provided with a pressing rod 9 'as a pressing means 9 protruding from the input pipe 8, and a conveying means 14 is connected to the input pipe 8 so as to be connected thereto. Is provided continuously from a hopper 13 in which a crushing means 15 is provided, and a supply means for supplying the fibrous waste 11 into the hopper 13.
10 are connected in series.
【0017】尚、解砕手段15により繊維質系の廃棄物11
を解砕する場合の解砕寸法は、溶融炉1の大きさにもよ
るが、100mm以下が良く、好ましくは30mm以下
に解砕することが投入管8の閉塞防止のためにも良い。The crushing means 15 generates fibrous waste 11
The size of the crushing of pulverized water depends on the size of the melting furnace 1, but is preferably 100 mm or less, and more preferably 30 mm or less to prevent blockage of the charging pipe 8.
【0018】符号3,16は出湯口であって、溶融スラグ
2は出湯口3より適宜出湯し、冷却固化後、有効利用す
る。また、廃棄物11中に含まれる金属類は溶融メタルと
して炉床に溜まるので出湯口16より適宜出湯し、冷却固
化後回収する。Reference numerals 3 and 16 denote tap holes, and the molten slag 2 is discharged from the tap port 3 as appropriate, cooled, solidified, and effectively used. Further, the metals contained in the waste 11 accumulate on the hearth as molten metal, so that the molten metal is discharged from the tap hole 16 as appropriate, collected after cooling and solidification.
【0019】供給手段10,ホッパー13,搬送手段14を介
して投入管8から溶融炉1内に繊維質系の廃棄物11を投
入し、溶融スラグ2とする。この廃棄物11の投入の際、
投入管8が電極7に近接して設けられている為、該廃棄
物11は電極7に近い部分の層厚が厚くなり且つ電極7よ
り離れるに従い層厚が薄くなる。よって、この層厚部に
おける通気抵抗が増大し、よって、溶融スラグ2の液面
から発生するガスは電極7の周辺において減少し、電極
7から離れた部分からも排出されることになる。The fibrous waste 11 is charged into the melting furnace 1 from the charging pipe 8 through the supply means 10, the hopper 13, and the transfer means 14, and is made into the molten slag 2. When inputting this waste 11,
Since the charging tube 8 is provided close to the electrode 7, the thickness of the waste 11 becomes thicker in a portion near the electrode 7 and becomes thinner as the distance from the electrode 7 increases. Therefore, the gas flow resistance in the thick portion increases, and the gas generated from the liquid surface of the molten slag 2 decreases around the electrode 7 and is discharged from a portion remote from the electrode 7.
【0020】一般的に電気溶融炉の場合、電気7の下面
7aが最も高温にある為、ガスは、該電極7の下面7a
において最も多く発生する。従って、廃棄物11が平均的
な層厚の場合は、ガスのほとんどは電極7の近くから排
出される(電気7の周面と廃棄物11)との間から該隙間
を通過するようにして排出されたりもする。)。このよ
うに電極7の近くからガスが排出されるということは、
該ガスが電極7と接触し、該ガスによる電極7の酸化消
耗が進行し易いという問題が生じる。Generally, in the case of an electric melting furnace, since the lower surface 7a of the electricity 7 is at the highest temperature, the gas is supplied to the lower surface 7a of the electrode 7.
Occurs most often in Therefore, when the waste 11 has an average layer thickness, most of the gas is discharged from the vicinity of the electrode 7 (the periphery of the electricity 7 and the waste 11) so as to pass through the gap. It is also discharged. ). The fact that the gas is discharged from the vicinity of the electrode 7 in this way means that
The gas comes into contact with the electrode 7, and a problem arises in that the electrode 7 is easily oxidized and consumed by the gas.
【0021】この点、本実施例は、電極7の周辺の廃棄
物11の層厚を厚くすることにより通気抵抗を増大させて
いるため、ガスはそのほとんどが通気抵抗の小さい電極
7より離れた所(炉壁に近い部分)より排出されるた
め、電極7のガスによる酸化消耗はほとんど生じない。In this respect, in this embodiment, since the gas flow resistance is increased by increasing the thickness of the waste 11 around the electrode 7, most of the gas is separated from the electrode 7 having a small gas flow resistance. Since the gas is discharged from a place (a part close to the furnace wall), the gas of the electrode 7 is hardly oxidized and consumed.
【0022】更に、ガスは必ず廃棄物11の堆積層内を通
過して噴出されるため、ガス中のダストは該廃棄物11の
繊維質に補集され、浄化されるからガスのダスト負荷は
小さいものとなる。このため排ガスダスト12に接続され
る公知のガス浄化設備(図示せず。)のダスト負荷が小
さくてすみ、この点において経済的となる。Further, since the gas is always ejected after passing through the sedimentary layer of the waste 11, the dust in the gas is collected and purified by the fiber of the waste 11, so that the dust load of the gas is reduced. It will be small. For this reason, the known gas purifying equipment (not shown) connected to the exhaust gas dust 12 requires a small dust load, which is economical in this respect.
【0023】尚、この補集されたダストは再溶融され
る。この点においもガスの浄化は非常に効率的に行われ
る。The collected dust is re-melted. In this regard, the purification of the gas is performed very efficiently.
【0024】また、アスベストは融点が1550℃以上
と高く且つ見かけ比重も小さいため、電極7と溶融スラ
グ2の液面で図2に示すように架橋4が形成され易い。
架橋4が形成されると、廃棄物11の溶融スラグ2への埋
設が該架橋4の存する部分において阻害される。更に、
この架橋4の形成にともない発生するこのポケット17
は、電極7周辺の廃棄物11がなくなったことを意味し、
ガスがこのポケット17に導入され、上記したような電極
7の酸化消耗という事態が生じ易くなる。Since the melting point of asbestos is as high as 1550 ° C. or higher and the apparent specific gravity is small, the crosslinks 4 are easily formed on the liquid surface of the electrode 7 and the molten slag 2 as shown in FIG.
When the bridge 4 is formed, the embedding of the waste 11 in the molten slag 2 is hindered in the portion where the bridge 4 exists. Furthermore,
The pockets 17 generated by the formation of the bridges 4
Means that the waste 11 around the electrode 7 is gone,
The gas is introduced into the pocket 17, and the situation of oxidative consumption of the electrode 7 as described above tends to occur.
【0025】この点、本実施例は、投入部8に押圧棒体
9'を設け、押圧棒体9'により該廃棄物11の表面を適宜
加圧するから、架橋4は破壊され、よって、上記のよう
な問題は生じないこととなる。In this respect, in this embodiment, the pressing section 9 ′ is provided in the charging section 8 and the surface of the waste 11 is appropriately pressed by the pressing section 9 ′, so that the bridge 4 is destroyed. Such a problem does not occur.
【0026】[0026]
【発明の効果】本発明は上述のように構成したから次の
ような効果を発揮する。Since the present invention is constructed as described above, the following effects are exhibited.
【0027】1.電極周辺の廃棄物の層厚を厚くするこ
とにより、この部分の通気抵抗が増し、ガスは通気抵抗
の小さい電極から離れた所から噴出することになる為、
電極周辺での集中的な排出が低減し、電極の酸化消耗が
可及的に減少する。1. By increasing the layer thickness of the waste around the electrode, the ventilation resistance in this part increases, and gas will be ejected from a place away from the electrode with low ventilation resistance,
The intensive exhaust around the electrode is reduced, and the oxidative consumption of the electrode is reduced as much as possible.
【0028】2.上記のように電極周辺でのガスの集中
的排出が少なく、ガスは必ず廃棄物の堆積層を通過して
排出されるため、排出速度も遅くなり、従って、ガス中
のダストは廃棄物によって補集され、ガス中のダスト負
荷が小さくなり、よって、ガス浄化設備の負担が軽くな
る。2. As described above, the concentrated emission of gas around the electrode is small, and the gas is always discharged through the sedimentary layer of waste, so that the discharge speed is slow, and therefore, the dust in the gas is supplemented by the waste. The dust load in the collected gas is reduced, thereby reducing the burden on the gas purification equipment.
【0029】更に補集されたダストは廃棄物と共に再溶
融されるので廃棄物の減容の他、ダストの無害化が促進
される。Further, the collected dust is re-melted together with the waste, so that the volume of the waste is reduced and the detoxification of the dust is promoted.
【0030】3.電極周辺に形成されやすい架橋を押圧
手段により破壊するようにしたから、廃棄物の溶融スラ
グへの埋没がスムーズとなり、従って、電力が有効に使
われ、よって、この点においても廃棄物の効率的な処理
が可能となる。3. Since the bridging which is likely to be formed around the electrode is destroyed by the pressing means, the burial of the waste in the molten slag is smooth, and therefore, electric power is used effectively, and thus, in this respect, the waste is also efficiently used. Processing can be performed.
【図1】本実施例の断面図である。FIG. 1 is a sectional view of the present embodiment.
【図2】架橋現象を説明する為の本実施例の要部の断面
図である。FIG. 2 is a cross-sectional view of a main part of the present embodiment for explaining a crosslinking phenomenon.
1 溶融炉 2 溶融スラグ 4 架橋 7 電極 9 押圧手段 11 廃棄物 DESCRIPTION OF SYMBOLS 1 Melting furnace 2 Molten slag 4 Crosslinking 7 Electrode 9 Pressing means 11 Waste
フロントページの続き (58)調査した分野(Int.Cl.6,DB名) F23G 7/00 B09B 3/00 Continuation of front page (58) Field surveyed (Int.Cl. 6 , DB name) F23G 7/00 B09B 3/00
Claims (1)
ル等の繊維質系の廃棄物11を溶融炉1に投入して該廃棄
物11を溶融せしめる方法であって、廃棄物11を電極7に
近い部分の層厚を厚くし且つ電極7より離れるに従い層
厚が薄くなるようにして投入し、電極7に通電せしめて
廃棄物11が溶融することにより生じる溶融スラグ2から
の抵抗熱により順次投入される廃棄物11を溶融せしめる
とともに、廃棄物11の溶融の際に溶融スラグ2と電極7
との間に該廃棄物11により形成される架橋4を破壊して
該架橋4を溶融スラグ2中に埋没させる押圧手段9によ
り該架橋4を破壊することを特徴とする繊維質系の廃棄
物の溶融処理方法。1. A method in which a fibrous waste material 11 such as asbestos, rock wool, glass wool or the like is charged into a melting furnace 1 to melt the waste material 11, and the waste material 11 is placed in a portion close to the electrode 7 Is supplied in such a manner that the layer thickness is increased and the layer thickness becomes thinner as the distance from the electrode 7 increases, and the electrode 7 is energized to be sequentially supplied by resistance heat from the molten slag 2 generated by melting the waste 11. Melt waste 11
In addition, the molten slag 2 and the electrode 7
The pressurizing means 9 breaks the bridge 4 formed by the waste material 11 and embeds the bridge 4 in the molten slag 2 .
A method of melting and treating fibrous waste, characterized in that the crosslinking 4 is destroyed .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6203346A JP2958605B2 (en) | 1994-08-29 | 1994-08-29 | Melt treatment method for fibrous waste |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6203346A JP2958605B2 (en) | 1994-08-29 | 1994-08-29 | Melt treatment method for fibrous waste |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0861643A JPH0861643A (en) | 1996-03-08 |
JP2958605B2 true JP2958605B2 (en) | 1999-10-06 |
Family
ID=16472511
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP6203346A Expired - Lifetime JP2958605B2 (en) | 1994-08-29 | 1994-08-29 | Melt treatment method for fibrous waste |
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JP (1) | JP2958605B2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4977408B2 (en) * | 2006-06-22 | 2012-07-18 | 日工株式会社 | Method and apparatus for crushing and reducing volume of building materials containing asbestos |
JP5090748B2 (en) * | 2007-02-08 | 2012-12-05 | 大成建設株式会社 | Processing system |
KR101012861B1 (en) * | 2010-04-28 | 2011-02-08 | 한국전력공사 | Fuel preprocess system for coal combustion boiler |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5680613A (en) * | 1979-12-05 | 1981-07-02 | Daido Steel Co Ltd | Starting up method of waste treating arc furnace |
JPS6249110A (en) * | 1985-08-27 | 1987-03-03 | Daido Steel Co Ltd | Controling method for waste material melting and processing furnace |
JPH07111911B2 (en) * | 1985-12-16 | 1995-11-29 | 大同特殊鋼株式会社 | Control method of waste melting furnace |
JPH07243766A (en) * | 1994-02-28 | 1995-09-19 | Daido Steel Co Ltd | Restarting method of operation in melting treatment furnace for waste consisting principally of dust |
JPH07243767A (en) * | 1994-03-09 | 1995-09-19 | Daido Steel Co Ltd | Melting treatment furnace for waste consisting principally of dust |
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1994
- 1994-08-29 JP JP6203346A patent/JP2958605B2/en not_active Expired - Lifetime
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JPH0861643A (en) | 1996-03-08 |
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