JP2951418B2 - Sample liquid component analyzer - Google Patents

Sample liquid component analyzer

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JP2951418B2
JP2951418B2 JP1810291A JP1810291A JP2951418B2 JP 2951418 B2 JP2951418 B2 JP 2951418B2 JP 1810291 A JP1810291 A JP 1810291A JP 1810291 A JP1810291 A JP 1810291A JP 2951418 B2 JP2951418 B2 JP 2951418B2
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sample
sample liquid
switching valve
liquid
water quality
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JPH0540112A (en )
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達也 船橋
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トキコ株式会社
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【発明の詳細な説明】 DETAILED DESCRIPTION OF THE INVENTION

【0001】 [0001]

【産業上の利用分野】この発明は、例えばイオン交換分離法を用いて、特に、超純水中の微量な金属成分を効率良く分析したり、試料液中に含まれる様々な成分を分析したりする試料液成分分析装置に関するものである。 BACKGROUND OF THE INVENTION This invention, for example using ion exchange separation techniques, in particular, a small amount of metal components in ultrapure water or efficiently analyze, to analyze the various components contained in the sample solution it relates sample liquid component analyzer or.

【0002】 [0002]

【従来の技術】図2は本発明者らが先に特願昭63ー1 BACKGROUND OF THE INVENTION FIG 2 is present inventors No. Sho 63 - 1 to the previously
80529号で提案した金属成分分析装置である。 A metal component analyzer proposed in JP 80 529. 図中符号1は自動流路切換弁であって、この自動流路切換弁1の出口には試料液供給路30が接続されている。 Reference numeral 1 is an automatic channel switching valve, the outlet of the automatic channel switching valve 1 is connected with a sample supplying channel 30. 前記試料液供給路30には、送液ポンプ2、反応器3、オーバーフロー容器4、三方自動切換弁5、加圧ポンプ6、 Wherein the sample solution supply path 30, the liquid feed pump 2, the reactor 3, an overflow vessel 4, the three-way automatic switching valve 5, the pressurizing pump 6,
圧力センサ6Aが取り付けられている。 Pressure sensor 6A is attached. そしてこの試料液供給路30は最終的に第1の四方自動切替弁7に接続されている。 Then the sample solution supply path 30 is finally connected to the first four-way automatic switching valve 7. この第1の四方自動切替弁7には、第1の濃縮カラム8への流入路8aと第2の濃縮カラム9への流入路9aと、溶離液供給路31とが接続されている。 This first four-way automatic switching valve 7, and the inflow passage 8a into the first concentrating column 8 and inflow passage 9a to the second enrichment column 9, and the eluent supply channel 31 is connected.
溶離液供給路31には、加圧ポンプ17と溶離液貯留部18が設けられている。 Eluent supply channel 31, pressure pump 17 and the eluent reservoir 18 is provided. 前記第1の濃縮カラム8からの流出路8bと第2の濃縮カラム9からの流出路9bは第2の四方自動切替弁10に接続されている。 Wherein the outflow passage 8b from first concentrating column 8 outflow channel 9b from the second enrichment column 9 is connected to the second four-way automatic switching valve 10. この第2の四方自動切替弁10には、さらに分離カラム11と吸光光度計12とからなる分析手段32につながるライン3 This second four-way automatic switching valve 10, further separating columns 11 and the absorption photometer 12. Line 3 connected to the analysis means 32 consisting of
3と、排水路34につながるライン35とが接続されており、ライン35には流量計19が取り付けられている。 3, a line 35 leading to the drainage channel 34 is connected, the flow meter 19 is attached to the line 35. つまり、前記第1の四方自動切替弁7は試料液供給路30が流入路8a・9aに分岐される分岐部に設けられ、第2の四方自動切替弁10は流出路8b・9bがライン33に合流した合流部(分岐部)に設けられ、前記濃縮カラム8あるいは濃縮カラム9に対して、分析手段32あるいはライン35に対して選択的に試料液、溶離液を供給するものである。 In other words, the first four-way automatic switching valve 7 is provided in the branch portion in which the sample solution supply path 30 is branched into inlet channel 8a · 9a, the second four-way automatic switching valve 10 is the outflow passage 8b · 9b the line 33 provided the confluent portion (branch portion) joined the, relative to the concentration column 8 or concentration column 9, selectively sample liquid to the analysis means 32 or line 35, and supplies the eluent.

【0003】次に、この金属成分分析装置の詳細な構成とその動作について説明する。 [0003] Next, the detailed structure and operation of the metal component analyzer. 前記自動流路切換弁1には、6つの試料液流入路1A〜1Fが接続されている。 Wherein the automatic channel switching valve 1, the six sample liquid inlet passage 1A~1F is connected.
そしてこれら試料液流入路1A〜1Fの一つが試料液供給路30に選択的に接続される。 And one of these sample liquid inlet passage 1A~1F is selectively connected to the sample solution supply path 30. 試料液供給路30に流入した試料液は送液ポンプ2によって反応器3に送られる。 Sample solution which has flowed into the sample solution supply path 30 is fed to the reactor 3 by the liquid sending pump 2. 反応器3の上流側には、塩酸等の反応液が貯留された反応液貯留部15と送液ポンプ16とを備えた反応液供給路37が接続されており、試料液中の金属をイオン化するための反応液が試料液に添加される。 On the upstream side of the reactor 3, is connected to the reaction liquid supply passage 37 of the reaction solution and a and liquid feed pump 16 reaction liquid storing portion 15 stored in the hydrochloric acid or the like, ionizing a metal in a sample solution the reaction solution for is added to the sample solution. そして、この反応液が添加された試料液は反応器3中にて混合された後、所定温度に加熱され、その結果、試料液中の金属がイオン化される。 After sample liquid reaction solution was added, which is mixed in the reactor 3, it is heated to a predetermined temperature, as a result, the metal in the sample solution are ionized. この反応器3を通過した試料液はオーバーフロー容器4に一旦貯留されるとともに、一定の貯留量を越えた試料液は符号L2 で示すラインを通じて排水路34に排出される。 Sample liquid that has passed through the reactor 3 while being temporarily stored in the overflow container 4, the sample liquid exceeds a predetermined storage amount is discharged into the drainage channel 34 through a line indicated at L2. オーバーフロー容器4を通過した試料液は三方自動切替弁5に達する。 Sample liquid passing through the overflow vessel 4 reaches the three-way automatic switching valve 5. 三方自動切換弁5は、試料液供給路30を流れる試料液の一部を、符号L3 で示すラインを通じて排水路34に導くものである。 Three-way automatic switching valve 5, a portion of the sample liquid flowing through the sample solution supply path 30, and guides the drainage channel 34 through a line indicated at L3. すなわち前記自動流路切換弁1が切り換えられて別の試料液が供給された場合に、まず、ラインL3 側に流路を切り換えて、自動流路切換弁1と三方自動切替弁5 That is, if another sample liquid the automatic channel switching valve 1 is switched is supplied, firstly, by switching a flow path line L3 side, the automatic channel switching valve 1 and the three-way automatic switching valve 5
との間に残留していた先の試料液を完全に洗い流す。 Completely flush the sample solution to which the remaining in between. そしてこの後流路を切り換えて試料液を試料液供給路30 The sample solution supply path 30 to the sample liquid by switching the after passage
(の加圧ポンプ6側)に向けて流す。 Flow toward the (pressure pump 6 side). なお、前記自動流路切換弁1による試料液流入路1A〜1Fの選択、及び三方自動切替弁5の切替は制御部Cから出力される信号に基づき行われるようになっている。 The switching of the selection of the automatic channel sample stream inlet channel by switching valve 1 1A-1F, and the three-way automatic switching valve 5 is adapted to be performed on the basis of a signal outputted from the control unit C.

【0004】三方自動切替弁5を通過した試料液は加圧ポンプ6により加圧される。 [0004] three-way automatic switching valve 5 sample liquid that has passed through the is pressurized by the pressurizing pump 6. なお、この加圧ポンプ6によって試料液が所定圧以上に加圧された場合には、圧力センサ6Aから、制御部Cに対して加圧ポンプ6の動作を停止させるための検出信号を出力するようになっている。 Incidentally, the sample liquid by the pressurizing pump 6 is when pressurized above a predetermined pressure, from the pressure sensor 6A, and outputs a detection signal for stopping the operation of the pressure pump 6 to the control unit C It has become way. 加圧ポンプ6により加圧された試料液は第1の四方自動切替弁7によって第1の濃縮カラム8あるいは第2 Sample fluid pressurized by the pressurizing pump 6 or the first enrichment column 8 by the first four-way automatic switching valve 7 second
の濃縮カラム9に供給される。 It is feed to the concentration column 9. この第1の四方自動切替弁7と第2の四方自動切替弁10とは、試料液供給路3 The first four-way automatic switching valve 7 and the second four-way automatic switching valve 10, the sample solution supply pathway 3
0から供給される試料液を濃縮カラム8あるいは9を通過せしめたあとライン35を経て排水路34に導く金属イオン濃縮工程の流路と、溶離液供給路31から供給される溶離液を濃縮カラム9あるいは8を通過せしめたあと分析手段32に導く金属イオン溶離工程の流路とを、 0 and the flow path of the metal ion concentration step that leads to the drainage channel 34 through the after line 35 the sample liquid passed through a concentration column 8 or 9 which is supplied from the concentrated column eluting solution to be supplied from the eluent-liquid supply passage 31 a flow path of the metal ion elution steps leading after analyzing means 32 which passed through a 9 or 8,
濃縮カラム8,9に対して交互に形成するものである。 And forms alternately to the concentration column 8,9.
この四方自動切替弁7,10の切り換えは、流量計19 Switching of the four-way automatic switching valve 7 and 10, the flow meter 19
で測定したライン35を通過する試料液の流量値が設定の値になったときに制御部Cから発信される信号によって行なわれる。 In is performed by a signal transmitted from the control unit C when the flow rate of the sample liquid passing through the measured line 35 becomes equal to the setting.

【0005】また、試料液が濃縮カラム8あるいは9を通過すると試料液中の金属イオンが濃縮カラム8あるいは9に吸着される(前記金属イオン濃縮工程)。 Further, when the sample liquid is passed through the concentrator column 8 or 9 metal ions in the sample solution is adsorbed to the concentration column 8 or 9 (the metal ion concentration step). この濃縮カラム8あるいは9に吸着された金属イオンは、溶離液供給路31から供給される溶離液により濃縮カラム8,9から溶離されて分析手段32に運ばれる(前記金属イオン溶離工程)。 Metal ions adsorbed to the concentration column 8 or 9, is conveyed to the analysis means 32 is eluted from the eluate by concentration column 8,9 supplied from the eluent supply channel 31 (the metal ion elution process). なお、この加圧ポンプ17によって溶離液が所定圧以上に加圧された場合には、圧力センサ17Aから制御部Cに対して加圧ポンプ17の動作を停止させるための検出信号を出力するようになっている。 In the case where the eluent is pressurized above a predetermined pressure by the pressurizing pump 17, so as to output a detection signal for stopping the operation of the pressurizing pump 17 to the control unit C from the pressure sensor 17A It has become. また、分析手段32に運ばれた金属イオンは、分離カラム11で精製されたあと発色液供給路38からの発色液により発色され、吸光光度計12で濃度測定される。 The metal ions carried in the analysis unit 32 is developed by the colored liquid from the later color liquid supply passage 38 which is purified by the separation column 11 is the concentration measured by the absorption photometer 12. なお、前記発色液は符号20で示す送液ポンプにより発色液貯留部21から発色液供給路38に供給される。 Incidentally, the coloring solution is supplied to the color liquid supply passage 38 from the coloring solution reservoir 21 by the liquid feed pump indicated at 20.

【0006】 [0006]

【発明が解決しようとする課題】ところで、上記のように構成された金属成分分析装置では、自動流路切換弁1 [SUMMARY OF THE INVENTION Incidentally, in the configuration metal component analyzer as described above, the automatic channel switching valve 1
を通じて導入される試料液中に、本来の測定対象となる成分以外の成分が混入していた場合、例えば径の大きい粒子、強いアルカリ性を呈する成分が含有されていた場合に、装置の配管が詰まったり、配管が腐食することがあり、これによって試料液の金属成分分析の精度が低下するという不具合があった。 The sample liquid introduced through, when a component other than the component composed of the original measurement object was contaminated, when the components which represent for example a large particle diameter, the strong alkalinity was contained, clogged piping system or, piping may be corroded, the accuracy of the metal component analysis of the sample solution was a problem of a decrease thereby. この発明は、上記の事情に鑑みてなされたものであって、配管に導入される試料液の状態を監視し、金属成分分析の精度を低下させる成分が混入することを防止した試料液成分分析装置の提供を目的とする。 The present invention was made in view of the above circumstances, to monitor the state of the sample solution to be introduced into the pipe, the sample liquid component analysis that prevents components reduce the accuracy of the metallic component analysis is mixed an object of the present invention to provide the apparatus.

【0007】 [0007]

【課題を解決するための手段】本発明は、試料液中に含有される金属成分をイオン化してpH調整をした後、前記金属成分をカラム精製により抽出してその濃度を測定する試料液成分分析装置において、前記試料液を装置内に導入するための試料導入手段の上流側流路に設けられて、前記試料液の状態を監視する水質監視センサと、前記水質監視センサと前記試料導入手段との間に設けられて、前記水質監視センサを通過した試料液を、前記試料導入手段に通じる流路、あるいは該試料液を排出する流路のいずれか一方に切り換える切換弁と、前記水質監視センサにより検出された試料液の状態を示す数値データを、予め入力しておいた設定値と比較し、その比較の結果、数値データが設定値を越えた場合に、前記切換弁を、前記試料液を排 The present invention SUMMARY OF], after the pH adjustment the metal components contained in the sample solution and ionized sample liquid component and measuring the concentration of the metal component extracted by column purification in the analysis device, provided on the upstream side passage of the sample introduction means for introducing the sample liquid into the device, and water quality monitoring sensor for monitoring the state of the sample solution, the water quality monitoring sensor and the sample introduction means provided between the sample liquid that has passed through the water quality monitoring sensor, a switching valve for switching to either one of the flow path for discharging the flow path, or the sample liquid leading to said sample introducing means, said water quality monitor numerical data indicating the state of the sample liquid is detected by the sensor, compares the set value with which has been input in advance, result of the comparison, if the numerical data exceeds the set value, the switching valve, the sample discharge the liquid する側の流路に切り換えるための制御信号を出力する制御部とを設けるようにしている。 And it is provided with a control unit for outputting a control signal for switching the flow path of the side to be.

【0008】 [0008]

【作用】本発明に示す試料液成分分析装置においては、 In sample liquid component analyzer shown to the present invention,
試料液導入手段に試料液を供給する前の段階において、 In the stage before supplying the sample solution into the sample liquid introduction means,
水質監視センサにより、試料液中に金属成分の分析に際して適さない成分、例えば配管を詰まらせる成分、該配管を腐食させる成分が混入しているか否かを監視し、この水質監視センサの監視結果に基づき切換弁が操作される。 The water quality monitoring sensor, component unsuitable during analysis of the metal components in the sample liquid, for example, components that clog the piping, monitors whether or not the component to corrode the pipe is mixed, the result of monitoring the water quality monitoring sensor based Setsu valve is operated. すなわち、前記切換弁の操作により、金属成分の分析に不適当な試料液を該試料液を排出する側の流路に案内して外部の系に排出させることができる。 That is, by the operation of the switching valve can be discharged to the outside of the system to guide the flow path of the side for discharging the sample liquid inadequate sample liquid for analysis of metal components.

【0009】 [0009]

【実施例】以下、本発明の試料液成分分析装置の一例として挙げた金属成分分析装置の構成を図1を参照して説明する。 EXAMPLES Hereinafter, the configuration of the metal component analyzer as an example of a sample liquid component analyzer of the present invention with reference to FIG. なお、本実施例において、従来の技術で示した図2と構成を共通にする箇所に同一符号を付して説明を簡略化する。 In the present embodiment, to simplify the description the same reference numerals are applied to portions of a common Figure 2 the configuration shown in the prior art. まず、図1において符号40で示すものは流路41Aの途中に設けられた水質監視センサである。 First, a water quality monitoring sensor provided in the middle that indicated at 40 of the flow channel 41A in FIG.
この水質監視センサ40としては、例えば(1)試料液中に含有される粒子の粒径を測定するもの、(2)一定径以上の粒子が含まれる割合すなわち不純物粒子の濃度を測定するもの、(3)試料液のpHを測定するものが使用され、その検出値(粒径,濃度,pH値)が予め設定されたしきい値を越えた場合に異常とみなすようにしている。 Those As the water quality monitoring sensor 40, for example, (1) to measure the particle diameter of particles contained in the sample solution, to measure the concentration ratio i.e. impurity particles include (2) a constant diameter or on the particles, (3) is used to measure the pH of the sample solution, the detection value (particle size, density, pH value) so that regarded as abnormal if exceeds a preset threshold. なお、このような検出値が予め設定したしきい値を越えたか否かの判断は後述する制御部Cにより行う。 Incidentally, the determination whether exceeds a threshold such detection value preset is carried out by the control unit C to be described later. また、前記(2)の水質監視センサ40による濃度測定は、一定径以上の粒子の個数をカウントすることにより行われるほか、試料液の導電率に基づいても行われる。 The concentration measured by the water quality monitoring sensor 40 of the (2), in addition to be performed by counting the number of particles on the predetermined diameter or more is also performed on the basis of the electric conductivity of the sample solution. また、前記水質監視センサ40が設けられた流路4 Further, the flow path 4 to the water quality monitoring sensor 40 is provided
1Aの末端には三方流路切換弁42が設けられ、この三方流路切換弁42から二つに分かれた流路の内、流路4 1A-terminus provided that the three-way flow passage switching valve 42, among the flow passages divided into two by the three-way flow passage switching valve 42, the flow path 4
1Bは自動流路切換弁1の試料流入路1A〜1Fの一つに接続され、また流路41Cは排水路34に接続されるようになっている。 1B is connected to the one sample inlet channel 1A~1F automatic channel switching valve 1, also the channel 41C is adapted to be connected to the drainage channel 34. なお、本実施例では、流路41Bが接続される試料流入路を1Aとしたが、これに限定されず、1B〜1Fの試料流入路であっても良い。 In the present embodiment, although the sample inlet which a passage 41B is connected to the 1A, without being limited thereto, may be a sample inlet channel of 1B~1F.

【0010】そして、以上のように構成された金属成分分析装置では、水質監視センサ40において検出された検出値が制御部Cに供給され、この制御部Cにおいて、 [0010] In the configured metallic component analyzer as described above, the detection value detected in the water quality monitoring sensor 40 is supplied to the control unit C, and the control station C, a
前記検出値が予め設定された設定値(制御部Cに設定される)を越えた場合に、流路41Aを通じて供給された試料液が金属成分の分析に適さないものであると判断して、以下のような操作を行うようにする。 When the detected value exceeds a preset value (set in the control unit C), it is determined that the sample liquid supplied through the channel 41A is not suitable for the analysis of metal components, to perform the following operations. すなわち、前記制御部Cは、前記検出値が予め設定された設定値を越えたと判断した場合に、流路41Aを通じて供給された試料液が金属成分の分析に適さないものであると判定して、前記三方流路切換弁42に対し、流路41Aと流路41Cとを接続する制御信号を供給して、流路41Aを通じて供給された試料液を排水路34に供給する。 That is, the control unit C, if the detected value is judged to exceed the predetermined set value, the sample liquid supplied through the channel 41A is determined to be unsuitable for analysis of the metal components the relative three-way flow passage switching valve 42 supplies a control signal for connecting the passage 41A and the passage 41C, and supplies the drain passage 34 of the supplied sample solution through the channel 41A. 一方、前記制御部Cは、前記検出値が予め設定された設定値未満であると判断した場合に、流路41Aを通じて供給された試料液が金属成分の分析に適するものであると判定して、前記三方流路切換弁42に対し、流路41A Meanwhile, the control unit C, if the detected value is determined to be smaller than the preset value, the sample liquid supplied through the channel 41A is then determined to be suitable for the analysis of the metal components , relative to the three-way flow passage switching valve 42, the flow path 41A
と流路41Bとを接続する制御信号を供給して、流路4 By supplying a control signal for connecting the flow path 41B and flow channel 4
1Aを通じて供給された試料液を自動流路切換弁1の試料流入路1Aに供給する。 Liquid sample supplied through 1A supplied to the sample inlet channel 1A of automatic channel switching valve 1.

【0011】以上説明したような金属成分分析装置においては、自動流路切換弁1に試料液を供給する以前の段階において、該試料液中に金属成分の分析に際して適さない成分、すなわち配管を詰まらせる成分、該配管を腐食させる成分が混入している場合に、該試料液を自動流路切換弁1に送らず外部の系に排出するようにしたので、結果として装置を保護することができるとともに、 [0011] or more in the metal component analyzer as described, at a stage before the automatic channel switching valve 1 supplying the sample liquid, clogging ingredients unsuitable during analysis of the metal components to the sample solution, i.e. a pipe component to, when the components to corrode the pipe is mixed, since the sample liquid to be discharged out of the system without sending the automatic channel switching valve 1, it is possible to protect the device as a result of along with the
金属成分分析の精度が低下することを防止できるという効果が得られる。 Effect is obtained that the accuracy of the metallic component analysis can be prevented from decreasing. なお、本実施例では、水質監視センサ40の後段に金属成分分析装置を設けるようにしたが、 In the present embodiment, although acceptable to provide a metal component analyzer downstream of the water quality monitoring sensor 40,
水質監視センサ40の後段に設けるものは、金属成分分析装置に限定されるものではなく、炭素量を分析する炭素量測定装置や、他の成分の含有量(濃度)を測定する装置であっても良いことは言うまでもない。 Those provided downstream of the water quality monitoring sensor 40 is not limited to a metal component analyzer, and carbon content measuring apparatus for analyzing the amount of carbon, an apparatus for measuring the content of the other components (concentration) may it is needless to say also.

【0012】 [0012]

【発明の効果】以上の説明から明らかなように、本発明に示す試料液成分分析装置においては、試料液導入手段に試料液を供給する前の段階において、水質監視センサにより、試料液中に金属成分の分析に際して適さない成分が混入しているか否かを監視し、この水質監視センサの監視結果に基づき切換弁を操作するようにした。 As apparent from the above description, in the sample liquid component analyzer shown in the present invention, prior to the step of supplying the sample solution into the sample liquid introduction means, the water quality monitoring sensor, the sample solution ingredients unsuitable during the analysis of the metal component monitors whether mixed, and to operate the valve Setsu based on the monitoring result of the water quality monitoring sensor. すなわち、前記切換弁の操作により、金属成分の分析に不適当な試料液を該試料液を排出する側の流路に案内して外部の系に排出させることができ、これによって装置を保護することができ。 That is, by the operation of the switching valve, to guide the flow path of the side for discharging the sample liquid inadequate sample liquid for analysis of the metal component can be discharged to the outside of the system, thereby protecting the device It is possible. そして、このような本発明を金属成分分析装置に適用した場合には、上述したように、金属成分の分析に不適当な試料液を外部の系に排出させることができることから、金属成分分析の精度が低下することを防止できるという効果が得られるものである。 When the such the present invention is applied to a metal component analyzer, as described above, since it is possible to discharge the inadequate sample liquid to the outside of the system for the analysis of the metal component, the metal component analysis accuracy is what effect that can be prevented.

【図面の簡単な説明】 BRIEF DESCRIPTION OF THE DRAWINGS

【図1】本発明の試料液成分分析装置の一例として挙げた金属成分分析装置を示す概略構成図。 Schematic diagram showing a metal component analyzer as an example of a sample liquid component analyzer of the present invention; FIG.

【図2】従来の金属(試料液)成分分析装置を示す概略構成図。 [2] Conventional metal (sample solution) schematic diagram showing a particle analyzer.

【符号の説明】 DESCRIPTION OF SYMBOLS

1 自動流路切換弁(試料導入手段) 40 水質監視センサ 41A 流路 41B 流路(試料液導入手段に通じる流路) 41C 流路(試料液を排出する流路) 42 三方流路切換弁(切換弁) 1 Automatic channel switching valve (sample introduction means) 40 water quality monitoring sensor 41A passage 41B flow path (flow path leading to the sample liquid introduction means) 41C passage (passage for discharging the sample liquid) 42 three-way flow passage switching valve ( switching valve)

Claims (1)

    (57)【特許請求の範囲】 (57) [the claims]
  1. 【請求項1】 試料液の成分を分析する試料液成分分析装置であって、 分析すべき試料液を装置内に導入するための試料導入手段の上流側流路に設けられて、前記試料液の状態を監視する水質監視センサと、 前記水質監視センサと前記試料導入手段との間に設けられて、前記水質監視センサを通過した試料液を、前記試料導入手段に通じる流路、あるいは該試料液を排出する流路のいずれか一方に切り換える切換弁と、 前記水質監視センサにより検出された試料液の状態を示す数値データを、予め入力しておいた設定値と比較し、 1. A sample liquid component analyzer for analyzing components of a sample fluid, provided on the upstream side passage of the sample introduction means for introducing a sample liquid to be analyzed in the apparatus, the sample solution a water quality monitoring sensor state monitoring of the disposed between the water quality monitoring sensor and the sample introduction means, a sample solution which has passed through the water quality monitoring sensor, a flow path leading to said sample introducing means, or said sample comparing a switching valve for switching to either one of the flow path for discharging the liquid, the numerical data indicating the state of the sample liquid is detected by the water quality monitoring sensor, the pre-entered in advance set value,
    その比較の結果、数値データが設定値を越えた場合に、 Result of the comparison, if the numerical data exceeds a set value,
    前記切換弁を、前記試料液を排出する側の流路に切り換えるための制御信号を出力する制御部が設けられていることを特徴とする試料液成分分析装置。 Said switching valve, the sample liquid component analyzer, wherein a control unit for outputting a control signal for switching the flow path of the side is provided for discharging the sample liquid.
JP1810291A 1991-02-08 1991-02-08 Sample liquid component analyzer Expired - Fee Related JP2951418B2 (en)

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