JP2918710B2 - 洗剤組成物とその調製方法 - Google Patents
洗剤組成物とその調製方法Info
- Publication number
- JP2918710B2 JP2918710B2 JP3075544A JP7554491A JP2918710B2 JP 2918710 B2 JP2918710 B2 JP 2918710B2 JP 3075544 A JP3075544 A JP 3075544A JP 7554491 A JP7554491 A JP 7554491A JP 2918710 B2 JP2918710 B2 JP 2918710B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- particulate
- granulator
- mixer
- neutralization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 49
- 239000003599 detergent Substances 0.000 title claims description 48
- 238000002360 preparation method Methods 0.000 title description 7
- 238000000034 method Methods 0.000 claims description 71
- 238000006386 neutralization reaction Methods 0.000 claims description 36
- 239000007787 solid Substances 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 239000002243 precursor Substances 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 18
- 239000003945 anionic surfactant Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 17
- -1 alkali metal aluminosilicate Chemical class 0.000 claims description 15
- 229910010272 inorganic material Inorganic materials 0.000 claims description 12
- 239000011147 inorganic material Substances 0.000 claims description 12
- 230000003472 neutralizing effect Effects 0.000 claims description 12
- 238000005520 cutting process Methods 0.000 claims description 11
- 230000009471 action Effects 0.000 claims description 9
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 38
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 30
- 239000000047 product Substances 0.000 description 21
- 238000005469 granulation Methods 0.000 description 19
- 230000003179 granulation Effects 0.000 description 19
- 229910000029 sodium carbonate Inorganic materials 0.000 description 15
- 235000017550 sodium carbonate Nutrition 0.000 description 15
- 239000000344 soap Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000002736 nonionic surfactant Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 238000011065 in-situ storage Methods 0.000 description 7
- 239000010457 zeolite Substances 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 238000005054 agglomeration Methods 0.000 description 5
- 230000002776 aggregation Effects 0.000 description 5
- 150000004996 alkyl benzenes Chemical class 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000632 Alusil Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 235000014366 other mixer Nutrition 0.000 description 1
- 238000010951 particle size reduction Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB909001285A GB9001285D0 (en) | 1990-01-19 | 1990-01-19 | Detergent compositions and process for preparing them |
| GB9001285.7 | 1990-01-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04363398A JPH04363398A (ja) | 1992-12-16 |
| JP2918710B2 true JP2918710B2 (ja) | 1999-07-12 |
Family
ID=10669596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3075544A Expired - Fee Related JP2918710B2 (ja) | 1990-01-19 | 1991-01-18 | 洗剤組成物とその調製方法 |
Country Status (11)
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3192469B2 (ja) * | 1991-05-17 | 2001-07-30 | 花王株式会社 | ノニオン洗剤粒子の製造方法 |
| US5486317A (en) * | 1992-02-14 | 1996-01-23 | The Procter & Gamble Company | Process for making detergent granules by neutralization of sulphonic acids |
| ES2104884T3 (es) * | 1992-02-14 | 1997-10-16 | Procter & Gamble | Procedimiento para elaborar granulos de detergente por neutralizacion de acidos sulfonicos. |
| AU673926B2 (en) * | 1993-07-13 | 1996-11-28 | Colgate-Palmolive Company, The | Process for preparing detergent composition having high bulk density |
| GB9324129D0 (en) † | 1993-11-24 | 1994-01-12 | Unilever Plc | Detergent compositions and process for preparing them |
| ATE195549T1 (de) * | 1994-01-17 | 2000-09-15 | Procter & Gamble | Verfahren zur herstellung von reinigungsmittelgranulaten |
| EP0678573B1 (en) * | 1994-04-20 | 2000-11-29 | The Procter & Gamble Company | Process for the manufacture of free-flowing detergent granules |
| US5703037A (en) * | 1994-04-20 | 1997-12-30 | The Procter & Gamble Company | Process for the manufacture of free-flowing detergent granules |
| US5565137A (en) * | 1994-05-20 | 1996-10-15 | The Proctor & Gamble Co. | Process for making a high density detergent composition from starting detergent ingredients |
| TW326472B (en) * | 1994-08-12 | 1998-02-11 | Kao Corp | Method for producing nonionic detergent granules |
| US5573697A (en) * | 1995-05-31 | 1996-11-12 | Riddick; Eric F. | Process for making high active, high density detergent granules |
| GB9526097D0 (en) * | 1995-12-20 | 1996-02-21 | Unilever Plc | Process |
| EP0898614B2 (en) * | 1996-04-17 | 2005-06-15 | The Procter & Gamble Company | High density detergent-making process using a high active surfactant paste having improved stability |
| TW462987B (en) * | 1996-08-26 | 2001-11-11 | Kao Corp | Method for producing high-bulk density detergent composition |
| DE19700776A1 (de) * | 1997-01-13 | 1998-07-16 | Henkel Kgaa | Granulares Waschmittel mit verbessertem Fettauswaschvermögen |
| GB9711359D0 (en) * | 1997-05-30 | 1997-07-30 | Unilever Plc | Detergent powder composition |
| ID29296A (id) | 1997-05-30 | 2001-08-16 | Unilever Nv | Komposisi deterjen butiran lembut yang bebas mengalir |
| DE19822941A1 (de) * | 1998-05-22 | 1999-11-25 | Henkel Kgaa | Verfahren zur Herstellung von Wasch- und Reinigungsmitteln |
| DE19844523A1 (de) * | 1998-09-29 | 2000-03-30 | Henkel Kgaa | Granulationsverfahren |
| AU1581999A (en) * | 1998-10-28 | 2000-05-15 | Procter & Gamble Company, The | Process for making a free flowing detergent composition |
| US6576605B1 (en) | 1998-10-28 | 2003-06-10 | The Procter & Gamble Company | Process for making a free flowing detergent composition |
| DE10163603B4 (de) | 2001-12-21 | 2006-05-04 | Henkel Kgaa | Verfahren zur Herstellung builderhaltiger Tensidgranulate |
| DE10232304B4 (de) * | 2002-07-17 | 2005-10-27 | Henkel Kgaa | Neutralisation im Mischer |
| WO2004022688A1 (en) | 2002-09-06 | 2004-03-18 | Kao Corporation | Detergent particles |
| EP1832648A1 (en) * | 2006-03-08 | 2007-09-12 | Unilever Plc | Laundry detergent composition and process |
| WO2011061045A1 (en) * | 2009-11-20 | 2011-05-26 | Unilever Nv | Detergent granule and its manufacture |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA72295B (en) * | 1971-02-01 | 1973-09-26 | Colgate Palmolive Co | Method for neutralization of detergent acid |
| GB2209172A (en) * | 1987-08-28 | 1989-05-04 | Unilever Plc | Preparation of solid particulate components for detergents |
| GB8810193D0 (en) * | 1988-04-29 | 1988-06-02 | Unilever Plc | Detergent compositions & process for preparing them |
| MY105010A (en) * | 1988-07-21 | 1994-07-30 | Unilever Plc | Detergent compositions and process for preparing them. |
| IN170991B (US07118763-20061010-C00002.png) * | 1988-07-21 | 1992-06-27 | Lever Hindustan Ltd | |
| GB8818613D0 (en) * | 1988-08-05 | 1988-09-07 | Paterson Zochonis Uk Ltd | Detergents |
-
1990
- 1990-01-19 GB GB909001285A patent/GB9001285D0/en active Pending
-
1991
- 1991-01-14 BR BR919100127A patent/BR9100127A/pt not_active IP Right Cessation
- 1991-01-15 IN IN17/BOM/91A patent/IN171897B/en unknown
- 1991-01-15 TR TR00028/91A patent/TR27438A/xx unknown
- 1991-01-16 AU AU69389/91A patent/AU640979B2/en not_active Ceased
- 1991-01-16 MY MYPI91000070A patent/MY107892A/en unknown
- 1991-01-16 CA CA002034244A patent/CA2034244C/en not_active Expired - Fee Related
- 1991-01-18 ZA ZA91385A patent/ZA91385B/xx unknown
- 1991-01-18 EP EP19910300422 patent/EP0438320A3/en not_active Ceased
- 1991-01-18 KR KR1019910000856A patent/KR960000207B1/ko not_active IP Right Cessation
- 1991-01-18 JP JP3075544A patent/JP2918710B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU640979B2 (en) | 1993-09-09 |
| EP0438320A2 (en) | 1991-07-24 |
| ZA91385B (en) | 1992-09-30 |
| CA2034244C (en) | 1999-11-30 |
| EP0438320A3 (en) | 1992-02-19 |
| CA2034244A1 (en) | 1991-07-20 |
| AU6938991A (en) | 1991-07-25 |
| KR910014499A (ko) | 1991-08-31 |
| MY107892A (en) | 1996-06-29 |
| JPH04363398A (ja) | 1992-12-16 |
| IN171897B (US07118763-20061010-C00002.png) | 1993-01-30 |
| BR9100127A (pt) | 1991-10-22 |
| TR27438A (tr) | 1995-05-24 |
| GB9001285D0 (en) | 1990-03-21 |
| KR960000207B1 (ko) | 1996-01-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |