JP2873138B2 - Dyeing method of polyester fiber material with excellent flameproofing and lightfastness for washing durability - Google Patents
Dyeing method of polyester fiber material with excellent flameproofing and lightfastness for washing durabilityInfo
- Publication number
- JP2873138B2 JP2873138B2 JP4326767A JP32676792A JP2873138B2 JP 2873138 B2 JP2873138 B2 JP 2873138B2 JP 4326767 A JP4326767 A JP 4326767A JP 32676792 A JP32676792 A JP 32676792A JP 2873138 B2 JP2873138 B2 JP 2873138B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polyester fiber
- fiber material
- dye
- dyed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、防炎性と耐光堅牢度の
良好なバランスを有するポリエステル繊維材料の染色方
法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for dyeing a polyester fiber material having a good balance between flame resistance and light fastness.
【０００２】[0002]
【従来の技術】近年、防炎性と同時に耐光性を有するポ
リエステル繊維の染色物に対する高い要求がある。例え
ば、ポリエステル繊維の染色物をカーテンとして使用す
る場合、防災上の観点から防炎性に優れていることが必
要であり、なお且つ長期間にわたり直射日光を受ける箇
所で使用する場合には、できるだけ高い耐光性を有する
ことが好ましい。2. Description of the Related Art In recent years, there has been a high demand for dyed polyester fibers having flame resistance and light resistance. For example, when using a dyed product of polyester fiber as a curtain, it is necessary to be excellent in flame resistance from the viewpoint of disaster prevention, and when used in a place that receives direct sunlight for a long time, It is preferable to have high light resistance.
【０００３】ポリエステル繊維材料に防炎性を付与する
方法として、一般に防炎剤をポリエステル繊維表面に付
着させる方法やハロゲン化合物や燐化合物をポリエステ
ル繊維内に導入する方法が行われている。より最近にな
って、脂肪族ハロゲン化物、ビスフェノールのハロゲン
化物およびハロゲン化燐酸エステルを、染色と同時にあ
るいは染色後にポリエステル繊維内に導入してポリエス
テル繊維材料の防炎性を改良する方法が提案されてい
る。例えば、特公平２−３１１５１号公報には、脂環族
のハロゲン化物、ビスフェノールのハロゲン化物、ハロ
ゲン化燐酸エステルおよびポリウレタンの４種類の化合
物を併用した防炎性の優れたポリエステル繊維材料の製
造方法が、また特開平１−６０５９２号公報には脂環族
のハロゲン化物、ビスフェノールのハロゲン化物および
ハロゲン化燐酸エステルの３種類の化合物を併用した耐
洗濯性、耐ドライクリーニング性および防炎性の優れた
ポリエステル繊維材料の製造方法が記載されている。As a method for imparting flame retardancy to a polyester fiber material, a method of attaching a flame retardant to the surface of the polyester fiber and a method of introducing a halogen compound or a phosphorus compound into the polyester fiber are generally employed. More recently, a method has been proposed to improve the flame resistance of polyester fiber materials by introducing aliphatic halides, bisphenol halides and halogenated phosphates into polyester fibers simultaneously or after dyeing. I have. For example, Japanese Patent Publication No. 2-31151 discloses a method for producing a polyester fiber material having excellent flameproofing properties by using four kinds of compounds of an alicyclic halide, a bisphenol halide, a halogenated phosphoric ester and a polyurethane in combination. However, Japanese Patent Application Laid-Open No. 1-60592 discloses washing resistance, dry cleaning resistance and flame resistance using a combination of three kinds of compounds of an alicyclic halide, a bisphenol halide and a halogenated phosphoric acid ester. A method for producing a polyester fiber material is described.
【０００４】一方、ポリエステル繊維材料に耐光性を付
与する方法として、紫外線吸収剤、特にベンゾトリアゾ
ール系の紫外線吸収剤をポリエステル繊維内に導入する
方法が行われている（特開平２−２９３１７７号公報お
よび特開平３−２７１７９号方法を参照のこと）。On the other hand, as a method of imparting light resistance to a polyester fiber material, a method of introducing an ultraviolet absorber, particularly a benzotriazole-based ultraviolet absorber, into polyester fibers has been used (Japanese Patent Application Laid-Open No. 2-293177). And JP-A-3-27179).
【０００５】[0005]
【発明が解決しようとする課題】しかしながら、これら
の方法を単に組み合わせて防炎性と耐光性の両方を満足
いくレベルで兼ね備えたポリエステル繊維材料の染色物
を得ようとしても、満足できる範囲で両方の性質を有す
るポリエステル繊維材料の染色物を得ることは難しい。
何故なら、高い耐光性を得るために紫外線吸収剤を多用
すると防炎性能が低下し、逆に、防炎性能を高めるため
に防炎剤を多用すると耐光性能が低下するためである。However, even if these methods are simply combined to obtain a dyed product of a polyester fiber material having both a flameproof property and a lightfastness at a satisfactory level, it is possible to obtain a dyed material of a polyester fiber material in a satisfactory range. It is difficult to obtain a dyed product of a polyester fiber material having the following properties.
This is because the use of an ultraviolet absorber in order to obtain high light resistance lowers the flameproofing performance, and conversely, the use of a large amount of the flameproofing agent in order to increase the flameproofing performance lowers the light resistance.
【０００６】従って、本発明の目的は、洗濯耐久性のあ
る防炎性能と耐光性の優れたバランスを有するポリエス
テル繊維材料の染色物を提供する方法を見出すことであ
る。[0006] It is therefore an object of the present invention to find a method for providing a dyed polyester fiber material having a good balance of flame resistance and light fastness with washing durability.
【０００７】[0007]
【課題を解決するための手段】本発明は上記の現状に鑑
み、鋭意検討した結果、特定の防炎剤と特定の耐光性向
上剤との特定の比率での組み合わせを用いてポリエステ
ル繊維材料を処理すると、上記の目的に合致した、優れ
た防炎性能と同時に優れた耐光性を有するポリエステル
繊維材料の染色物が得られることを見出して、本発明に
到達した。DISCLOSURE OF THE INVENTION The present invention has been made in view of the above situation, and as a result of intensive studies, it has been found that a polyester fiber material is produced by using a combination of a specific flame retardant and a specific lightfastness improver in a specific ratio. The present inventors have found that, upon treatment, a dyed product of a polyester fiber material having excellent flameproofing performance and excellent light resistance, which meets the above-mentioned object, can be obtained.
【０００８】すなわち、本発明は、（ａ）０．１〜１０
重量％ｏｗｆ（被染物重量％）の防炎剤としての多臭素
化有機化合物、（ｂ）０．１〜６重量％ｏｗｆ（被染物
重量％）の防炎剤としてのハロゲン化有機リン化合物、
（ｃ）０．１〜６重量％ｏｗｆ（被染物重量％）の耐光
性向上剤としてのベンゾトリアゾール系化合物、および
（ｄ）染料を含有してなる染浴中で１００〜１４０℃の
温度で３０〜１２０分間ポリエステル繊維材料の内部に
成分（ａ）〜（ｄ）を吸尽させることを特徴とする洗濯
耐久性のある防炎性能と耐光堅牢度に優れたポリエステ
ル繊維材料の染色加工方法である。That is, the present invention relates to (a) 0.1 to 10
(B) a halogenated organophosphorus compound as a flame retardant of 0.1 to 6% by weight owf (weight of dye),
(C) at a temperature of 100 to 140 ° C. in a dye bath containing 0.1 to 6% by weight owf (weight to be dyed) of a benzotriazole-based compound as a light fastness improver and (d) a dye. A dyeing method for a polyester fiber material having excellent flameproofing performance and light fastness, which is characterized by absorbing components (a) to (d) into the polyester fiber material for 30 to 120 minutes. is there.
【０００９】本発明において適用可能なポリエステル繊
維材料とは、従来使用されているポリエステル系の繊維
であって特に制限されるものではない。ポリエステル繊
維材料の形状についても、本発明による染色法により処
理できるものであれば特に制限されるものではなく、例
えば、長繊維、短繊維等の繊維状物、織物、編物等の織
布、不織布等の何れの形状であってもよい。The polyester fiber material applicable in the present invention is a conventionally used polyester fiber and is not particularly limited. The shape of the polyester fiber material is also not particularly limited as long as it can be treated by the dyeing method according to the present invention. For example, long fibers, fibrous materials such as short fibers, woven fabrics, woven fabrics such as knitted fabrics, and nonwoven fabrics Or any other shape.
【００１０】本発明において成分（ａ）として使用され
る多臭素化有機化合物は、例えば、７ないし１２個の環
構成炭素原子を持ち、該環構成原子に４ないし６個の臭
素原子が結合しているシクロアルカン類、例えば１，
２，４，６−または１，２，３，４−テトラブロムシク
ロヘプタン、１，２，３，４−テトラブルムシクロオク
タン、ヘキサブロムシクロドデカン（Ｃ12Ｈ18Ｂｒ6 ）
等である。上記化合物を、単独でまたは２種類以上を組
み合わせて使用できる。The polybrominated organic compound used as the component (a) in the present invention has, for example, 7 to 12 ring-constituting carbon atoms, and 4 to 6 bromine atoms are bonded to the ring-constituting atoms. Cycloalkanes, such as 1,
2,4,6 or 1,2,3,4 tetrabromo cycloheptane, 1,2,3,4 Blum cyclooctane, hexamethylene bromine cyclododecane (C 12 H 18 Br 6)
And so on. The above compounds can be used alone or in combination of two or more.
【００１１】本発明において成分（ｂ）として使用され
るハロゲン化有機リン化合物は、例えば燐酸、亜燐酸、
フォスホン酸、ホスフィン酸のハロゲン化物、特にその
エステル類およびそのオリゴマーであって、例えばトリ
クロロエチルホスフェート、トリクロロプロピルホスフ
ェート等が挙げられる。上記化合物を単独でまたは２種
類以上を組み合わせて使用できる。The halogenated organic phosphorus compound used as the component (b) in the present invention includes, for example, phosphoric acid, phosphorous acid,
Phosphonic acid and phosphinic acid halides, particularly esters and oligomers thereof, such as trichloroethyl phosphate and trichloropropyl phosphate. The above compounds can be used alone or in combination of two or more.
【００１２】本発明において成分（ｃ）として使用され
るベンゾトリアゾール系化合物は、一般式The benzotriazole compound used as the component (c) in the present invention has the general formula
【００１３】[0013]
【化１】 （式中、Ｒ1 およびＲ2 は互いに独立して水素原子、ヒ
ドロキシル基、低級アルキル基または低級アルコキシ基
であり、好ましくは低級アルキル基である）で表される
化合物、例えば２−（２−ヒドロキシ−５−メチルフェ
ニル）ベンゾトリアゾールである。上記化合物を単独で
または２種類以上を組み合わせて使用できる。Embedded image (Wherein R 1 and R 2 are each independently a hydrogen atom, a hydroxyl group, a lower alkyl group or a lower alkoxy group, and preferably a lower alkyl group), for example, 2- (2- (Hydroxy-5-methylphenyl) benzotriazole. The above compounds can be used alone or in combination of two or more.
【００１４】上記成分（ａ）〜（ｃ）は、それぞれ０．
１〜１０重量％ｏｗｆ（被染物重量％）、０．１〜６重
量％ｏｗｆ（被染物重量％）、０．１〜６％重量ｏｗｆ
（被染物重量％）の範囲で染浴内に導入される。ここ
で、（ａ）、（ｂ）および（ｃ）成分の割合が上記の範
囲を逸脱すると、防炎性と耐光堅牢度の良好なバランス
を有するポリエステル繊維材料の染色物が得られない。Each of the above components (a) to (c) has a content of 0.1%.
1 to 10% by weight owf (weight to be dyed), 0.1 to 6% by weight owf (weight to be dyed), 0.1 to 6% by weight owf
(Weight to be dyed) is introduced into the dye bath. Here, if the proportions of the components (a), (b) and (c) deviate from the above ranges, a dyed product of a polyester fiber material having a good balance between flame resistance and light fastness cannot be obtained.
【００１５】本発明において成分（ｄ）として使用され
る染料は、例えば従来公知の分散染料等のポリエステル
繊維の染色用の染料であれば特に制限されず、その使用
量は、使用するポリエステル繊維材料および使用する染
料に依存する。具体的な染料（ｄ）の例として、例えば
三菱化成ヘキスト社から市販されているＤｉａｎｉｘＹ
ｅｌｌｏｗ ＸＬＦ、Ｄｉａｎｉｘ Ｒｅｄ ＸＬＦ、
Ｄｉａｎｉｘ Ｂｌｕｅ ＸＬＦ等がが挙げられる。The dye used as the component (d) in the present invention is not particularly limited as long as it is a dye for dyeing polyester fibers, such as a conventionally known disperse dye. And the dye used. As a specific example of the dye (d), for example, DianixY commercially available from Mitsubishi Kasei Hoechst Co., Ltd.
yellow XLF, Dianix Red XLF,
Dianix Blue XLF and the like.
【００１６】本発明において、ポリエステル繊維の染色
に通常使用されているその他の染色助剤、例えば分散剤
（例えば多環系エステル型非イオン活性剤）、金属イオ
ン封鎖剤（例えば、ポリ燐酸塩）等を本発明の効果を損
なわない範囲で少量添加してもよい。In the present invention, other dyeing auxiliaries usually used for dyeing polyester fibers, such as dispersants (eg, polycyclic ester type nonionic activators), sequestering agents (eg, polyphosphates) May be added in a small amount as long as the effects of the present invention are not impaired.
【００１７】本発明によれば、上記成分（ａ）〜（ｃ）
を上記の割合で成分（ｄ）と一緒に含む染色浴内で従来
の吸尽法に適用されている条件下に（すなわち、１００
〜１４０℃、好ましくは約１３５℃の温度で３０〜１２
０分、好ましくは約９０分間）処理することによって、
染色時にポリエステル繊維材料に洗濯耐久性のある防炎
性と耐光堅牢性を良好なバランスで付与することができ
る。According to the present invention, the above components (a) to (c)
In the dyeing bath containing component (d) in the above proportions under the conditions applied to conventional exhaustion methods (ie, 100
30 to 12 at a temperature of about 140 ° C, preferably about 135 ° C.
0 minutes, preferably about 90 minutes)
The polyester fiber material can be provided with a good balance of flame resistance and light fastness, which are durable during washing, during dyeing.
【００１８】[0018]
【実施例】以下、本発明を実施例に基づいてより詳細に
説明する。なお、防炎性能および耐光堅牢度は、以下の
通りに測定した。防炎性能 消防法施行規則第４条３、ＪＩＳ−Ｌ１０９１ Ａ−１
法およびＤ法に従って水洗い洗濯およびドライクリーニ
ングしたサンプルについて防炎性能の評価を行った。評
価基準は以下の通りである。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in more detail with reference to embodiments. The flameproofing performance and light fastness were measured as follows. Article 4.3 of the Ordinance for Enforcement of the Fire Service Act, JIS-L1091 A-1
Samples washed with water and washed and dry-cleaned according to the methods D and D were evaluated for their flameproof performance. The evaluation criteria are as follows.
【００１９】１分間加熱において、残炎および残燼とも
の３秒以内であること。着炎後３秒加熱において、残炎
および残燼ともの３秒以内であること。炭化面積は、３
０ｃｍ以内であること。After heating for 1 minute, the afterflame and afterglow must be within 3 seconds. After heating for 3 seconds after the flame, the residual flame and afterglow must be within 3 seconds. The carbonization area is 3
Be within 0cm.
【００２０】コイル法において接炎回数３回以上である
こと。耐光堅牢度 ＪＩＳ−Ｌ−０８４２に従って８３℃で２００時間耐光
堅牢度を評価した。すなわち、フェード・オ・メーター
を使用し、試験用支持枠に試料を保持し、試験機室内温
度を８３℃に保ち、２００時間連続してカーボンアーク
灯を照射する。ここで、試料とカーボンアーク灯との距
離は１５ｃｍとする。試験体とグレースケールとの比較
対象判定により評価し、４級以上のものを合格とした。 実施例１ ７５デニール／３６フィラメントのポリエステル糸を用
いた綾織物を液流染色機（日坂製作所社製，ＲＺ−２Ｔ
ＹＰＥ）で予め精練加工する。精練加工した綾織物をピ
ンテンターを用いて１９０℃で４０秒間熱処理する。熱
処理した綾織物を下記の条件で液流染色機で染色加工す
る。 ダイアニックス イエロー ＸＬＦ ０．０６重量％ｏｗｆ （被染物重量％） ダイアニックス レッド ＸＬＦ ０．０５重量％ｏｗｆ （被染物重量％） ダイアニックス ブルー ＸＬＦ ０．０３重量％ｏｗｆ （被染物重量％） 多臭素化有機化合物（ヘキサブロムシクロドデカン；日華化学工業株式会社） ９％重量ｏｗｆ （被染物重量％） ハロゲン化有機リン化合物（ビスクロロエチルホスホネート；丸菱油化工業株式 会社） ５％重量ｏｗｆ （被染物重量％） ベンゾトリアゾール系化合物（２−（２−ヒドロキシ−５−メチルフェニル）ベ ンゾトリアゾール；第一工業製薬株式会社） ５％重量ｏｗｆ （被染物重量％） 酢酸（９０％） ０．５重量％ｏｗｆ （被染物重量％） 浴比 １：１０ 浴温 １３０℃ 染色時間 ９０分 得られた綾織物の防炎性能と耐光性能を上記の通りに測
定した。結果を表１に示す。 比較例１ 多臭素化有機化合物、ハロゲン化有機リン化合物および
ベンゾトリアゾール系化合物の割合を各々８．００重量
％ｏｗｆ（被染物重量％）、４．００重量％ｏｗｆ（被
染物重量％）および０．０５重量％ｏｗｆ（被染物重量
％）に変えた以外は、実施例１を繰り返し、得られた綾
織物の防炎性能と耐光性能を上記の通りに測定した。結
果を表２に示す。 比較例２ 多臭素化有機化合物、ハロゲン化有機リン化合物および
ベンゾトリアゾール系化合物の割合を各々６．００重量
％ｏｗｆ（被染物重量％）、５．００重量％ｏｗｆ（被
染物重量％）および７．００重量％ｏｗｆ（被染物重量
％）に変えた以外は、実施例１を繰り返し、得られた綾
織物の防炎性能と耐光性能を上記の通りに測定した。結
果を表３に示す。In the coil method, the number of times of flame contact must be 3 or more. They were evaluated for 200 hours light fastness at 83 ℃ according to the light fastness JIS-L-0842. That is, using a fade-o-meter, the sample is held on a test support frame, the temperature inside the tester is kept at 83 ° C., and a carbon arc lamp is continuously irradiated for 200 hours. Here, the distance between the sample and the carbon arc lamp is 15 cm. The evaluation was made by judging the comparison between the test body and the gray scale. Example 1 A twill fabric using 75 denier / 36 filament polyester yarn is subjected to a liquid jet dyeing machine (Hisaka Seisakusho Co., Ltd., RZ-2T).
YPE). The scoured twill fabric is heat-treated at 190 ° C. for 40 seconds using a pin tenter. The heat-treated twill fabric is dyed by a jet dyeing machine under the following conditions. DIANIX Yellow XLF 0.06% by weight owf (weight of dye) DIANIX Red XLF 0.05% by weight owf (weight of dye) DIANIX Blue XLF 0.03% by weight owf (weight of dye) Polybromine Organic compound (hexabromocyclododecane; Nika Chemical Industry Co., Ltd.) 9% by weight owf (weight to be dyed) Halogenated organic phosphorus compound (bischloroethyl phosphonate; Marubishi Yuka Kogyo Co., Ltd.) 5% by weight owf ( Dye weight%) Benzotriazole compound (2- (2-hydroxy-5-methylphenyl) benzotriazole; Daiichi Kogyo Seiyaku Co., Ltd.) 5% weight owf (Dye weight%) Acetic acid (90%) 0 0.5% by weight owf (weight to be dyed) Bath ratio 1:10 Bath temperature 130 ° C Dyeing time 90 minutes Prevention of the obtained twill fabric The performance and light performance was measured as described above. Table 1 shows the results. Comparative Example 1 The proportions of the polybrominated organic compound, the halogenated organophosphorus compound and the benzotriazole-based compound were respectively 8.00% by weight owf (weight of dyed material), 4.00% by weight owf (weight% of dyed material) and 0% by weight. Example 1 was repeated except that the weight was changed to 0.05% by weight owf (weight to be dyed), and the flameproof performance and light resistance of the obtained twill fabric were measured as described above. Table 2 shows the results. Comparative Example 2 The proportions of the polybrominated organic compound, the halogenated organophosphorus compound and the benzotriazole-based compound were respectively 6.00% by weight owf (weight to be dyed), 5.00% by weight owf (weight% to be dyed) and 7%. Example 1 was repeated except that the weight was changed to 0.000% by weight owf (weight to be dyed), and the flameproof performance and light resistance of the obtained twill fabric were measured as described above. Table 3 shows the results.
【００２１】[0021]
【表１】 [Table 1]
【００２２】[0022]
【表１】 [Table 1]
【表２】 上記の結果から明らかなとおり、多臭素化有機化合物、
ハロゲン化有機リン化合物およびベンゾトリアゾール系
化合物の割合が本発明の範囲内である場合（実施例
１）、得られた綾織物は、防炎性能と耐光性能との良好
なバランスで付与されたが、本発明の範囲を逸脱した場
合には、耐光性能および防炎性能が不適であった。[Table 2] As is clear from the above results, the polybrominated organic compound,
When the ratio of the halogenated organophosphorus compound and the benzotriazole-based compound was within the range of the present invention (Example 1), the obtained twill woven fabric was provided with a good balance between the flameproofing performance and the light resistance performance. On the other hand, when it deviated from the range of the present invention, the light resistance and the flameproofing performance were unsuitable.
【００２３】[0023]
【発明の効果】本発明によると、洗濯耐久性のある防炎
性と耐光堅牢度の良好なバランスで付与されたポリエス
テル繊維の染色物を得ることができる。According to the present invention, it is possible to obtain a dyed polyester fiber provided with a good balance of flame resistance and light fastness having washing durability.
フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｄ０６Ｐ 1/651 Ｄ０６Ｐ 1/651 // Ｄ０６Ｍ 101:32 Ｄ０６Ｍ 13/32 13/08 13/38 (58)調査した分野(Int.Cl.6，ＤＢ名) D06P 3/52 - 3/56 D06P 1/642 D06P 1/651 Continuation of the front page (51) Int.Cl. 6 Identification symbol FI D06P 1/651 D06P 1/651 // D06M 101: 32 D06M 13/32 13/08 13/38 (58) Field surveyed (Int.Cl. 6 , DB name) D06P 3/52-3/56 D06P 1/642 D06P 1/651
Claims (1)
物重量％）の防炎剤としての多臭素化有機化合物、 （ｂ）０．１〜６重量％ｏｗｆ（被染物重量％）の防炎
剤としてのハロゲン化有機リン化合物、 （ｃ）０．１〜６重量％ｏｗｆ（被染物重量％）の耐光
性向上剤としてのベンゾトリアゾール系化合物、および （ｄ）染料 を含有してなる染浴中で１００〜１４０℃の温度で３０
〜１２０分間ポリエステル繊維材料の内部に成分（ａ）
〜（ｄ）を吸尽させることを特徴とする洗濯耐久性のあ
る防炎性能と耐光堅牢度に優れたポリエステル繊維材料
の染色加工方法。1. A polybrominated organic compound as a flameproofing agent of (a) 0.1 to 10% by weight owf (weight of dye), (b) 0.1 to 6% by weight owf (weight of dye) A) a halogenated organophosphorus compound as a flame retardant, (c) 0.1 to 6% by weight owf (weight of the material to be dyed), a benzotriazole-based compound as a light fastness improver, and (d) a dye. At a temperature of 100 to 140 ° C in a dye bath
Component (a) inside polyester fiber material for ~ 120 minutes
(D) a method of dyeing a polyester fiber material which is excellent in flame resistance and light fastness with washing durability characterized by exhaustion of (d).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4326767A JP2873138B2 (en) | 1992-12-07 | 1992-12-07 | Dyeing method of polyester fiber material with excellent flameproofing and lightfastness for washing durability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4326767A JP2873138B2 (en) | 1992-12-07 | 1992-12-07 | Dyeing method of polyester fiber material with excellent flameproofing and lightfastness for washing durability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07252782A JPH07252782A (en) | 1995-10-03 |
| JP2873138B2 true JP2873138B2 (en) | 1999-03-24 |
Family
ID=18191470
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4326767A Expired - Fee Related JP2873138B2 (en) | 1992-12-07 | 1992-12-07 | Dyeing method of polyester fiber material with excellent flameproofing and lightfastness for washing durability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2873138B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200710208A (en) * | 2005-06-27 | 2007-03-16 | Nippon Kayaku Kk | Dispersions of phosphorous flame retarding agent for fibers, flame retarding modification method using the dispersions and flame retarding modified fibers by the method |
-
1992
- 1992-12-07 JP JP4326767A patent/JP2873138B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07252782A (en) | 1995-10-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3775165A (en) | Polymers of improved flame retardance | |
| EP0248553B1 (en) | Process for imparting flame resistance to a polyester/cotton blend fabric | |
| EP0249375A2 (en) | A process of dyeing and flame retarding an aramid fibre or fabric | |
| US4794037A (en) | Flame-proof fiber product | |
| US4842609A (en) | Flame retardant treatments for polyester/cotton fabrics | |
| US7588802B2 (en) | Agent and method for flame-retardant processing of polyester-based fiber products | |
| US4750911A (en) | Flame-resistant nylon/cotton fabrics | |
| US3480582A (en) | Fire-resistant fiber blends | |
| JPH0995870A (en) | Aromatic polyamide-containing dyed textile fabric and dyeing of aromatic polyamide-containing textile fabric | |
| US3764374A (en) | Process for placing modifiers within polyester fibers and films | |
| US6719810B1 (en) | Method for providing protective treatment to nylon fibers | |
| JP2873138B2 (en) | Dyeing method of polyester fiber material with excellent flameproofing and lightfastness for washing durability | |
| JP2003239136A (en) | Highly light resistant wholly aromatic polyamide fibrous structural material | |
| JP2004332187A (en) | Flame-retardant polyester-based synthetic fiber structure and method for producing the same | |
| JPH0299674A (en) | Dyed polyester imide fiber and method for dyeing thereof | |
| JP2006070417A (en) | Flame retardant for polyester-based fiber and method for flame proof finish | |
| US7196125B2 (en) | Poly(trimethylene terephthalate) fibers useful in high-UV exposure end uses | |
| US5211720A (en) | Dyeing and flame-retardant treatment for synthetic textiles | |
| JPS6364544B2 (en) | ||
| JP4624542B2 (en) | Dyeing method for wholly aromatic polyamide fiber | |
| JPS6359475A (en) | Fire retardant polyester cloth | |
| WO2007086594A1 (en) | Flameproofing agent for polyester textile and flameproofing method | |
| JP3862063B2 (en) | Method for dyeing polyester fabric having flame retardancy and antibacterial properties | |
| EP0733638B1 (en) | Use of phosphoryl compounds for the flame retardant finishing of polyester-based synthetic fibre materials | |
| EP0400018B1 (en) | Simultaneously dyeing and flame-retardant treating aramids |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 19981201 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313115 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |