JP2868565B2 - Manufacturing method of cosmetic materials - Google Patents
Manufacturing method of cosmetic materialsInfo
- Publication number
- JP2868565B2 JP2868565B2 JP1245990A JP1245990A JP2868565B2 JP 2868565 B2 JP2868565 B2 JP 2868565B2 JP 1245990 A JP1245990 A JP 1245990A JP 1245990 A JP1245990 A JP 1245990A JP 2868565 B2 JP2868565 B2 JP 2868565B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- thermoplastic resin
- layer
- decorative material
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、家具や建材等の表面仕上げ材として使用さ
れる化粧材の製造方法に関し、さらに詳しくは、熱可塑
性樹脂と熱硬化性樹脂の複合化粧材の製造方法に関する
ものである。The present invention relates to a method for producing a decorative material used as a surface finishing material such as furniture and building materials, and more particularly to a method for producing a thermoplastic resin and a thermosetting resin. The present invention relates to a method for manufacturing a composite decorative material.
化粧板の製造方法において、熱可塑性樹脂化粧板（塩
ビ化粧板など）と熱硬化性樹脂化粧板（メラミン化粧
板、ダップ化粧板、不飽和ポリエステル樹脂化粧板な
ど）は、それぞれ実用化されているが、両者の複合化粧
材の製造についてはわずかに開示されているにすぎな
い。例えば、基材上に熱硬化性樹脂含浸紙およびプライ
マー層を有する合成樹脂フィルムを順次積層した化粧材
の製造方法（特開昭60−122149号公報）や、基材上に接
着剤を介して、硬化処理した含浸紙と透明熱可塑性樹脂
からなるラミネート用化粧シートを積層した化粧材の製
造方法（特公昭62−54674号公報）が提案されている。In the method of manufacturing decorative boards, thermoplastic resin decorative boards (PVC decorative boards, etc.) and thermosetting resin decorative boards (melamine decorative boards, dup decorative boards, unsaturated polyester resin decorative boards, etc.) have each been put to practical use. However, the production of both composite cosmetics is only slightly disclosed. For example, a method for manufacturing a decorative material in which a thermosetting resin-impregnated paper and a synthetic resin film having a primer layer are sequentially laminated on a substrate (Japanese Patent Laid-Open No. 60-122149), There has been proposed a method for producing a decorative material in which a laminated decorative sheet comprising a cured impregnated paper and a transparent thermoplastic resin is laminated (Japanese Patent Publication No. 62-54674).
しかしながら、従来の、上記のプライマー層を有する
合成樹脂フィルムを積層する方法（特開昭60−122149
号）では、実用上プライマー層の選定および塗布に困難
をきたすとともに、得られた化粧材の表面硬度が不充分
である。また、予め硬化処理した含浸紙の上に透明熱可
塑性樹脂の表面層を形成（特公昭62−54674号公報）す
ることは、製造上複雑かつ困難であり、得られた化粧材
の表面硬度も不十分であった。However, a conventional method of laminating a synthetic resin film having the above-mentioned primer layer (JP-A-60-122149)
No. 2), practically, it is difficult to select and apply the primer layer, and the surface hardness of the obtained decorative material is insufficient. Also, forming a surface layer of a transparent thermoplastic resin on impregnated paper that has been cured in advance (Japanese Patent Publication No. 62-54674) is complicated and difficult in production, and the surface hardness of the obtained decorative material is also low. It was not enough.
そこで、本発明者等は工程が容易で、得られる製品表
面の硬度も十分な化粧材の製造方法の必要性に鑑み、鋭
意検討の結果、本発明を完成するに至った。In view of the necessity of a method for producing a cosmetic material which is easy in process and has sufficient hardness on the surface of the obtained product, the present inventors have made intensive studies and completed the present invention.
本発明は上記のような問題点を解決するためのもので
あり、熱可塑性樹脂材料と熱硬化性樹脂材料の複合化の
手段として熱接着性シートを用い、且つ表面に電離放射
線硬化性樹脂層を設けたフィルムを化粧材の最上層に用
いることにより、従来の方法に比し、工程が容易で、得
られる製品表面の硬度も十分であり、しかも熱可塑性樹
脂材料の一部として絵柄層を熱可塑性樹脂フィルムに印
刷したものを使用したときは、紙に印刷したものでは表
現できない美しい絵柄表現を可能とする製造方法に関す
る。The present invention is intended to solve the above-mentioned problems, and uses a thermo-adhesive sheet as a means for compounding a thermoplastic resin material and a thermosetting resin material, and uses an ionizing radiation-curable resin layer on the surface. By using the film provided with as the uppermost layer of the decorative material, the process is easier than in the conventional method, the hardness of the obtained product surface is sufficient, and the pattern layer is used as a part of the thermoplastic resin material. The present invention relates to a manufacturing method that enables a beautiful picture expression that cannot be expressed by printing on a paper when a product printed on a thermoplastic resin film is used.
具体的には、本発明は、熱硬化性樹脂を成分とする基
材上に、順次、熱接着性シート、必要に応じて絵柄層を
設けた着色熱可塑性樹脂フィルム及び表面に電離放射線
硬化性樹脂層を設けた透明または着色透明熱可塑性組成
樹脂フィルムを重ね合せ、熱圧成型することを特徴とす
る化粧材の製造法に関する。Specifically, the present invention provides, on a base material containing a thermosetting resin, a thermo-adhesive sheet, a colored thermoplastic resin film provided with a picture layer as necessary, and an ionizing radiation-curable The present invention relates to a method for producing a decorative material, which comprises laminating a transparent or colored transparent thermoplastic composition resin film provided with a resin layer and hot-press molding.
以下、図面を参照しつつ本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail with reference to the drawings.
本発明にかかる熱可塑性樹脂と熱硬化性樹脂との複合
化粧材の製造法は、第１図a,bに示すごとく、熱硬化性
樹脂を成分とする基材（１）上に、順次、熱接着性シー
ト（２）、必要に応じて絵柄層（３′）を設けた着色熱
可塑性樹脂フィルム（３）及び表面に電離放射線硬化型
樹脂層（５）を設けた透明または着色透明熱可塑性樹脂
フィルム（４）を重ね合せ、これを熱盤間に挟んで、加
熱圧締して熱圧成型することにより行われる。The method for producing a composite decorative material of a thermoplastic resin and a thermosetting resin according to the present invention comprises, as shown in FIGS. 1a and 1b, a base material (1) containing a thermosetting resin as a component. Transparent or colored transparent thermoplastic having a heat-adhesive sheet (2), a colored thermoplastic resin film (3) provided with a picture layer (3 ') if necessary, and an ionizing radiation-curable resin layer (5) provided on the surface. This is performed by laminating resin films (4), sandwiching the resin films between hot plates, heating and pressing, and hot pressing.
熱圧成型条件としては、温度120〜180℃、圧力10〜80
kg/cm2、時間10〜60分の範囲で、熱硬化性樹脂、熱接着
性シートの接着性、熱可塑性樹脂フィルムの接着性等に
応じて適宜選択される。The hot-press molding conditions include a temperature of 120 to 180 ° C and a pressure of 10 to 80.
It is appropriately selected according to the thermosetting resin, the adhesiveness of the thermoadhesive sheet, the adhesiveness of the thermoplastic resin film, and the like in the range of 10 kg / cm 2 and 10 to 60 minutes.
熱圧成型に際しては、一般に当板が用いられるが、当
板としては光沢、半光沢、艶消し等の鏡面盤あるいはエ
ンボス板が使用される。In hot-press molding, generally, a contact plate is used, and as the contact plate, a mirror surface plate such as gloss, semi-gloss, matte or an emboss plate is used.
また、熱圧後、圧力をかけたままで常温まで冷却した
ほうが、エアーのパンク、エアー噛みによる脹れ等が発
生し難い。Further, it is less likely that air puncture or swelling due to air bite will occur when cooling to room temperature while applying pressure after applying heat and pressure.
本発明の製造法に用いられる熱硬化性樹脂を成分とす
る基材（１）は、例えば、繊維状基材に熱硬化性樹脂を
塗布、混抄または含浸せしめたものである。The base material (1) containing a thermosetting resin as a component used in the production method of the present invention is, for example, a fibrous base material coated, mixed or impregnated with a thermosetting resin.
繊維状基材としては含浸紙、含浸布等である。 Examples of the fibrous base material include impregnated paper and impregnated cloth.
基材（１）は、好ましくは熱硬化性樹脂が未硬化のも
のを用いることにより熱接着性シートの選択巾が広が
る、熱接着性シートとの密着性が向上する、熱圧成型時
硬化と各層の接着を一度に行えるため工程が簡素化でき
る等の利点がある。As the base material (1), it is preferable to use an uncured thermosetting resin so that the selection range of the thermoadhesive sheet is widened, the adhesiveness with the thermoadhesive sheet is improved, Since the bonding of each layer can be performed at once, there is an advantage that the process can be simplified.
熱硬化性樹脂としてはメラミン樹脂、フェノール樹
脂、ジアリルフタレート系樹脂、不飽和ポリエステル樹
脂、熱硬化型アクリル樹脂、ベンゾグアナミン樹脂等で
ある。Examples of the thermosetting resin include a melamine resin, a phenol resin, a diallyl phthalate resin, an unsaturated polyester resin, a thermosetting acrylic resin, and a benzoguanamine resin.
本発明の製造法に用いられる熱接着性シート（２）と
しては、公知の熱接着性フィルムを用いることができ
る。As the thermal adhesive sheet (2) used in the production method of the present invention, a known thermal adhesive film can be used.
例えば、ポリエステル系樹脂、ナイロン系樹脂、ポリ
酢酸ビニル系樹脂、アクリル系樹脂等の熱接着性フィル
ムである。For example, it is a heat-adhesive film of a polyester resin, a nylon resin, a polyvinyl acetate resin, an acrylic resin, or the like.
更に、本発明の製造法に用いられる熱接着性シート
（２）としては、繊維質シートに熱可塑性樹脂若しくは
熱硬化性樹脂を含浸、混抄または塗布したものが用いら
れる。Further, as the heat-adhesive sheet (2) used in the production method of the present invention, a sheet obtained by impregnating, mixing or coating a fibrous sheet with a thermoplastic resin or a thermosetting resin is used.
繊維質シートとしては、含浸性の紙、不織布等であ
る。Examples of the fibrous sheet include impregnated paper and nonwoven fabric.
熱可塑性樹脂としては、ポリエチレン酢酸ビニル系、
ポリ酢酸ビニル系、オレフィン系、ポリエステル系、ア
クリル系、アルキッド系等の樹脂が単独または混合で用
いることができる。As the thermoplastic resin, polyethylene vinyl acetate,
Resins such as polyvinyl acetate, olefin, polyester, acrylic, and alkyd resins can be used alone or in combination.
例えば、含浸用紙にポリエチレン酢酸ビニルを含浸し
たものは、基材と着色熱可塑性樹脂フィルムの選択巾が
広がるという点で好ましい。For example, impregnated paper impregnated with polyethylene vinyl acetate is preferable in that the range of choice between the base material and the colored thermoplastic resin film is widened.
熱硬化性樹脂としては、ジアリルフタレート、不飽和
ポリエステル、熱硬化型アクリル等の樹脂が単独または
混合で用いることができる。As the thermosetting resin, resins such as diallyl phthalate, unsaturated polyester, and thermosetting acrylic can be used alone or in combination.
この熱接着性シート（２）の厚さは、特に限定されな
いが、例えば20〜100μである。The thickness of the heat adhesive sheet (2) is not particularly limited, but is, for example, 20 to 100 μm.
本発明の製造法に用いられる、必要に応じて表面に絵
柄層が設けられる着色熱可塑性樹脂フィルム（３）は、
アクリルフィルム、ポリエチレンフィルム、ポリプロピ
レンフィルム、ポリ塩化ビニルフィルム、ポリ塩化ビニ
リデンフィルム、ポリビニルアルコールフィルム、エチ
レン酢酸ビニル共重合体フィルム、エチレンビニルアル
コール共重合体フィルム、アイオノマー等のプラスチッ
クフィルムから適宜選ばれる。The colored thermoplastic resin film (3) used in the production method of the present invention, which is provided with a pattern layer on the surface as necessary,
It is appropriately selected from acrylic films, polyethylene films, polypropylene films, polyvinyl chloride films, polyvinylidene chloride films, polyvinyl alcohol films, ethylene vinyl acetate copolymer films, ethylene vinyl alcohol copolymer films, and plastic films such as ionomers.
この着色熱可塑性樹脂フィルム（３）の厚さは、特に
限定されないが、例えば40〜200μである。The thickness of the colored thermoplastic resin film (3) is not particularly limited, but is, for example, 40 to 200 μ.
本発明の製造法に用いられる、必要に応じて上記の着
色熱可塑性樹脂フィルム表面に設けられる絵柄層
（３′）は、従来一般に熱可塑性樹脂化粧板製造に用い
られる公知の方法、インキを用いることができる。The pattern layer (3 ') provided on the surface of the colored thermoplastic resin film as needed, which is used in the production method of the present invention, uses a known method and ink conventionally used in the production of a thermoplastic resin decorative board. be able to.
本発明の製造法に用いられる、表面に電離放射線硬化
性樹脂層が設けられる透明または着色透明熱可塑性樹脂
フィルム（４）は、上記の着色熱可塑性樹脂フィルム
（３）の樹脂と同様の樹脂に必要に応じ着色した樹脂の
透明なフィルムである。The transparent or colored transparent thermoplastic resin film (4) having a surface provided with an ionizing radiation-curable resin layer used in the production method of the present invention is a resin similar to the resin of the above-mentioned colored thermoplastic resin film (3). It is a transparent film of resin colored as necessary.
この透明熱可塑性樹脂フィルム（４）は、上記の必要
に応じて表面に絵柄層が設けられる着色熱可塑性樹脂フ
ィルム層を保護し、且つ意匠効果の主体である該層が透
視されるように透明なものである。This transparent thermoplastic resin film (4) protects the colored thermoplastic resin film layer provided with a pattern layer on the surface as required, and is transparent so that the layer, which is the main subject of the design effect, can be seen through. It is something.
この透明熱可塑性樹脂フィルム（４）の厚さは、特に
限定されないが、例えば70〜300μである。The thickness of the transparent thermoplastic resin film (4) is not particularly limited, but is, for example, 70 to 300 μm.
本発明の製造法に用いられる、上記の透明熱可塑性樹
脂フィルムの表面に設けられる電離放射線硬化性樹脂層
（５）は、本発明の化粧材の表面に十分な硬度を賦与す
る働きをするものである。The ionizing radiation-curable resin layer (5) provided on the surface of the transparent thermoplastic resin film used in the production method of the present invention functions to impart sufficient hardness to the surface of the decorative material of the present invention. It is.
本発明の製造法に用いられる電離放射線硬化性樹脂層
（５）は、一般に用いられる電離放射線硬化性樹脂層を
用いることができ、分子中に重合性不飽和結合または、
エポキシ基を有するプレポリマー、オリゴマー及び／又
は単量体を適宜混合した組成物を、上記の透明熱可塑性
樹脂フィルム（４）の表面に塗工し、電離放射線を照射
して硬化させることにより形成される。As the ionizing radiation-curable resin layer (5) used in the production method of the present invention, a generally used ionizing radiation-curable resin layer can be used, and a polymerizable unsaturated bond or
A composition obtained by appropriately mixing a prepolymer, an oligomer and / or a monomer having an epoxy group onto the surface of the transparent thermoplastic resin film (4) and irradiating with ionizing radiation to cure the composition. Is done.
プレポリマー、オリゴマーとしては、例えば不飽和ジ
カルボン酸と多価アルコールの縮合物等の不飽和ポリエ
ステル類、各種メタクリレート類、各種アクリレート類
等である。Examples of the prepolymer and oligomer include unsaturated polyesters such as a condensate of an unsaturated dicarboxylic acid and a polyhydric alcohol, various methacrylates, and various acrylates.
例えば、ウレタンアクリレートは、樹脂に可とう性を
与えやすく、熱圧成型時のクラック等が発生しにくい点
で好ましい。For example, urethane acrylate is preferable because it easily imparts flexibility to the resin and hardly causes cracks or the like during hot pressing.
電離放射線とは、電磁波又は荷電粒子線のうち分子を
重合、架橋し得るエネルギー量子を有するものを意味
し、通常紫外線、電子線が用いられる。Ionizing radiation means an electromagnetic wave or a charged particle beam having energy quanta capable of polymerizing and cross-linking molecules, and usually ultraviolet rays and electron beams are used.
電離放射線硬化性樹脂層（５）の厚さは１〜50μであ
り、好ましくは10〜15μである。The thickness of the ionizing radiation-curable resin layer (5) is 1 to 50 µ, preferably 10 to 15 µ.
以下、実施例により更に具体的に説明するが、本発明
はこれにより限定されるものではない。Hereinafter, the present invention will be described more specifically with reference to Examples, but the present invention is not limited thereto.
第１図,a,bに示すごとく、下記の４層の材料を重ね
て、ジュラルミン製光沢成型板に挟み、140℃、20kg/cm
2の条件で10分間熱圧成型後冷却し、本発明にかかる化
粧材を得た。As shown in FIG. 1, a and b, the following four layers of material are stacked, sandwiched between duralumin gloss molded plates, and at 140 ° C. and 20 kg / cm.
After hot-press molding for 10 minutes under the conditions of 2 , cooling was performed to obtain a decorative material according to the present invention.
基材;140g/m2クラフト紙にフェノール樹脂を140g/m2
（固型分）の割合に含浸させたもの。Base material: 140 g / m 2 phenolic resin on kraft paper 140 g / m 2
(Solid component) impregnated.
熱接着性シート;30g/m2含浸用紙にポリエチレン酢酸
ビニル樹脂を30g/m2（固型分）の割合に含浸させたも
の。Thermal adhesive sheet: 30 g / m 2 impregnated paper impregnated with polyethylene vinyl acetate resin at a rate of 30 g / m 2 (solid content).
着色熱可塑性樹脂フィルム;100μ厚の着色塩化ビニル
フィルム（理研ビニル社製、Ｗ−500）に塩ビ系インキ
（昭和インク工業所製、化Ｘ）でグラビア印刷により絵
柄を設けたもの。Colored thermoplastic resin film: 100 μm thick colored vinyl chloride film (manufactured by Riken Vinyl Co., Ltd., W-500) provided with a pattern by gravure printing with a PVC-based ink (manufactured by Showa Ink Industries, Ltd., Chemical X).
透明熱可塑性樹脂フィルム;200μ厚の透明塩化ビニル
フィルム（理研ビニル社製、Ｗ−500）に、ウレタンア
クリレート系の紫外線硬化性樹脂（大日精化社製、PT
C）を、膜厚15μ塗布し、160w/cmの紫外線ランプ下を10
m/minの速度で通して硬化させたもの。Transparent thermoplastic resin film; 200μ thick transparent vinyl chloride film (manufactured by Riken Vinyl Co., W-500) and urethane acrylate UV curable resin (manufactured by Dainichi Seika Co., Ltd., PT
C) is applied in a thickness of 15 μm, and is applied under an ultraviolet lamp of 160 w / cm to 10 μm.
Cured at a speed of m / min.
工程の作業性は容易であり、得られた化粧材は表面物
性良好で硬度も十分であり、塗装感に深みがあり、印刷
が美しい高級感のあるものであった。The workability of the process was easy, and the obtained decorative material had good surface physical properties and sufficient hardness, had a deep painting feeling, and had a high-quality feel with beautiful printing.
以上から明らかな如く、本発明によれば熱接着性シー
トおよび表面に電離放射線硬化性樹脂層が塗布された透
明フィルムを使用し、熱圧成型時に同時積層することに
より、製造が容易となり、且つ実用上十分な表面硬度が
得られると共に、外観の深みが一層増大した化粧板を製
造することができる。As is clear from the above, according to the present invention, using a heat-adhesive sheet and a transparent film having a surface coated with an ionizing radiation-curable resin layer, and simultaneously laminating during hot-press molding, the production becomes easy, and A practically sufficient surface hardness can be obtained, and a decorative plate with further increased appearance can be manufactured.
また、絵柄層を着色フィルムに設けることにより、紙
等では表現できない美しい柄表現ができる優れた複合化
粧材の製造法を提供することができる。In addition, by providing a pattern layer on a colored film, it is possible to provide a method for producing an excellent composite decorative material capable of expressing beautiful patterns that cannot be expressed with paper or the like.
第１図,a,bは本発明の製造法の工程を表す化粧材の模式
断面図である。 １…熱硬化性樹脂を成分とする基材 ２…熱接着性シート ３…着色熱可塑性樹脂フィルム ３′…絵柄層 ４…透明熱可塑性組成樹脂フィルム ５…電離放射線硬化性樹脂層FIGS. 1, a and b are schematic sectional views of a decorative material showing the steps of the production method of the present invention. DESCRIPTION OF SYMBOLS 1 ... Substrate containing thermosetting resin as a component 2 ... Heat-adhesive sheet 3 ... Colored thermoplastic resin film 3 '... Picture layer 4 ... Transparent thermoplastic composition resin film 5 ... Ionizing radiation curable resin layer
Claims (4)
次、含浸用紙にポリエチレン酢酸ビニルを含浸してなる
熱接着性シート、必要に応じて絵柄層を設けた着色熱可
塑性樹脂フィルム及び表面にウレタンアクリレートから
なる電離放射線硬化性樹脂の硬化物層を設けた透明また
は着色透明熱可塑性樹脂フィルムを重ね合せ、熱圧成型
することを特徴とする化粧材の製造法。1. A thermo-adhesive sheet obtained by sequentially impregnating a paper impregnated with polyethylene vinyl acetate on a base material containing a thermosetting resin as a component, and a colored thermoplastic resin film provided with a picture layer if necessary. And a transparent or colored transparent thermoplastic resin film provided with a cured layer of an ionizing radiation-curable resin made of urethane acrylate on the surface thereof, and laminating and hot-pressing.
なるものである請求項１記載の化粧材の製造法。2. The method for producing a decorative material according to claim 1, wherein the substrate comprises a fibrous sheet and a thermosetting resin.
は２記載の化粧材の製造法。3. The method for producing a decorative material according to claim 1, wherein the thermosetting resin is uncured.
は３記載の化粧材の製造法。4. The method for producing a decorative material according to claim 2, wherein the fibrous sheet is an impregnated paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1245990A JP2868565B2 (en) | 1990-01-24 | 1990-01-24 | Manufacturing method of cosmetic materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1245990A JP2868565B2 (en) | 1990-01-24 | 1990-01-24 | Manufacturing method of cosmetic materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03218832A JPH03218832A (en) | 1991-09-26 |
| JP2868565B2 true JP2868565B2 (en) | 1999-03-10 |
Family
ID=11805933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1245990A Expired - Fee Related JP2868565B2 (en) | 1990-01-24 | 1990-01-24 | Manufacturing method of cosmetic materials |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2868565B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101189424B1 (en) * | 2003-12-18 | 2012-10-10 | 다이니폰 인사츠 가부시키가이샤 | Decorative material |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0735109B2 (en) * | 1990-12-25 | 1995-04-19 | 東海ケミカル株式会社 | Manufacturing method of composite board |
| JP6162425B2 (en) * | 2013-02-25 | 2017-07-12 | アイカ工業株式会社 | Metal decorative veneer |
-
1990
- 1990-01-24 JP JP1245990A patent/JP2868565B2/en not_active Expired - Fee Related
Non-Patent Citations (2)
| Title |
|---|
| Ｂ３２Ｂ ２７／００ |
| Ｂ３２Ｂ ３３／００ |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101189424B1 (en) * | 2003-12-18 | 2012-10-10 | 다이니폰 인사츠 가부시키가이샤 | Decorative material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03218832A (en) | 1991-09-26 |
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