JP2774555B2 - Method of forming antimicrobial agent layer and processing tool - Google Patents
Method of forming antimicrobial agent layer and processing toolInfo
- Publication number
- JP2774555B2 JP2774555B2 JP6389689A JP6389689A JP2774555B2 JP 2774555 B2 JP2774555 B2 JP 2774555B2 JP 6389689 A JP6389689 A JP 6389689A JP 6389689 A JP6389689 A JP 6389689A JP 2774555 B2 JP2774555 B2 JP 2774555B2
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial agent
- processing tool
- agent layer
- binder
- resin film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- Apparatus For Disinfection Or Sterilisation (AREA)
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、膜状あるいは成形体状に形成される抗菌剤
層の形成方法ならびに処理用具に係り、例えば抗菌作用
を有する金属イオンを担持したゼオライト微粒子とバイ
ンダーとからなる抗菌剤層の形成方法ならびに処理用具
に関するものである。The present invention relates to a method for forming an antimicrobial agent layer formed in the form of a film or a molded article and a processing tool, for example, carrying metal ions having an antimicrobial action. The present invention relates to a method for forming an antimicrobial agent layer comprising zeolite fine particles and a binder, and a processing tool.
従来、大腸菌，バクテリア真菌，酵母などの雑菌によ
る汚染，変質，腐敗を防止するため、抗菌性を有する被
膜を必要個所に形成する方法がとられている。2. Description of the Related Art Conventionally, in order to prevent contamination, alteration, and decay by various bacteria such as Escherichia coli, bacterial fungi, and yeast, a method of forming a coating having antibacterial properties at necessary places has been adopted.
この抗菌剤被膜の形成方法として、例えば抗菌作用を
有する金属イオンを担持したゼオライト微粒子をバイン
ダー樹脂溶液と混合し、これを必要個所に塗布し嵌装し
て抗菌剤被膜を形成していた。As a method of forming the antibacterial agent coating, for example, zeolite fine particles carrying metal ions having an antibacterial action are mixed with a binder resin solution, and the mixture is applied to necessary portions and fitted to form an antibacterial agent coating.
第12図はこのようにして形成した抗菌剤被膜の拡大断
面図で、図中の51は基材、52は抗菌作用を有する金属イ
オンをイオン交換によつて担持したゼオライト微粒子、
53はバインダー樹脂である。FIG. 12 is an enlarged cross-sectional view of the antibacterial agent film formed in this manner. In the figure, 51 is a substrate, 52 is zeolite fine particles carrying metal ions having an antibacterial action by ion exchange,
53 is a binder resin.
ところで、このようにして形成した抗菌剤被膜は同図
に示すように、ゼオライト微粒子52がバインダー樹脂53
中に封じ込まれたり、ゼオライト微粒子52の表面が樹脂
膜で覆われたりする。そのため抗菌効果が十分に発揮さ
れず、抗菌剤の利用効率が悪い。By the way, as shown in the figure, the antibacterial agent film thus formed has
It is sealed inside, or the surface of the zeolite fine particles 52 is covered with a resin film. Therefore, the antibacterial effect is not sufficiently exhibited, and the use efficiency of the antibacterial agent is poor.
これを解決するため、バインダー溶液中の樹脂濃度を
極めて低くすることが考えられる。このようにして形成
した抗菌剤被膜の拡大断面図を第13図に示すが、同図の
ようにバンイダー樹脂53の膜厚が極めて薄くなり、その
ためゼオライト微粒子52の決着力が弱く、ゼオライト微
粒子52が基剤51から脱落するなどの欠点を有している。In order to solve this, it is conceivable to make the resin concentration in the binder solution extremely low. FIG. 13 shows an enlarged cross-sectional view of the antibacterial agent film formed in this manner. As shown in FIG. 13, the film thickness of the vanider resin 53 is extremely thin, so that the setting force of the zeolite fine particles 52 is weak, and the zeolite fine particles 52 However, they have a drawback such as falling off from the base material 51.
本発明の目的は、このような従来技術の欠点を解消
し、抗菌剤の利用効率が高く、しかも抗菌剤微粒子が脱
落しない抗菌剤層の形成方法ならびに処理用具を提供す
るにある。An object of the present invention is to provide a method and a processing tool for forming an antibacterial agent layer which solves the above-mentioned drawbacks of the prior art, has high utilization efficiency of the antibacterial agent, and does not cause the antibacterial agent fine particles to fall off.
前述の目的を達成するため、本発明は、例えば抗菌性
を有する銀，銅，亜鉛などを金属を担持したゼオライト
からなる抗菌剤とバインダーとの混合物を、膜状あるい
は成形体状などの所定の形状に形成した後、前記バイン
ダーよりも硬度の高い処理用具で表面をこすつて抗菌剤
を露出せしめることを特徴とするものである。In order to achieve the above-mentioned object, the present invention provides a mixture of an antibacterial agent composed of zeolite carrying a metal such as silver, copper, zinc or the like having antibacterial properties and a binder, in a predetermined form such as a film or molded article. After being formed into a shape, the surface is rubbed with a processing tool having a hardness higher than that of the binder to expose the antibacterial agent.
前述の目的を達成するため、さらに本発明は、抗菌剤
層を形成するためのバインダーよりも硬度の高い、例え
ば砥粒を混入した弾性体などからなる樹脂膜除去部を有
することを特徴とするものである。In order to achieve the above object, the present invention is further characterized in that it has a resin film removing portion having a higher hardness than a binder for forming an antibacterial agent layer, for example, an elastic body mixed with abrasive grains. Things.
本発明は前述のような構成になつているから、所定量
のバインダーを使用しても後処理によつて抗菌剤の露出
面積が増大し、その結果、優れた抗菌効果が長期間にわ
たつて発揮できる。Since the present invention is configured as described above, even if a predetermined amount of binder is used, the exposed area of the antibacterial agent is increased by post-treatment, and as a result, excellent antibacterial effect is obtained over a long period of time. Can demonstrate.
また、バインダーよりも硬度の高い、例えば砥粒を含
有した弾性体などからなる樹脂膜除去部を設けた処理用
具を用いることにより、抗菌剤を覆う樹脂膜あるいは表
面に付着しているゴミ類や油類を有効に除去して、抗菌
効果を十分にかつ長期間にわたつて発揮することができ
る。Also, by using a processing tool provided with a resin film removing portion having a hardness higher than that of the binder, for example, an elastic body containing abrasive grains, dust or the like adhering to the resin film or surface covering the antibacterial agent can be removed. By effectively removing oils, the antibacterial effect can be sufficiently exhibited over a long period of time.
次に本発明の実施例を図面とともに説明する。 Next, embodiments of the present invention will be described with reference to the drawings.
第１図は本発明の実施例で使用する処理用具の斜視
図、第２図は抗菌剤被膜を形成した電気かみそりの一部
断面図、第３図ならびに第４図は毛受皿の処理状態を説
明するための一部を断面にした側面図、第５図は抗菌剤
被膜の拡大断面図である。FIG. 1 is a perspective view of a processing tool used in an embodiment of the present invention, FIG. 2 is a partial cross-sectional view of an electric shaver having an antibacterial agent film formed thereon, and FIGS. FIG. 5 is an enlarged cross-sectional view of the antimicrobial agent coating, with a partial cross-sectional view for explanation.
回転式電気かみそりは第２図に示すように、かみそり
本体１の頭部には固定リング２によつてドーム状の外刃
３が所定の張力をもつて固定されている。この外刃３の
下面には回転刃４が摺接するように配置され、回転刃４
の下方に毛受皿５が設けられている。この毛受皿５の上
面には、第３図ならびに第４図に示すように抗菌剤被膜
６が形成されている。電気かみそりを使用してひげをそ
つた際、毛くずとともに角質，脂肪ならびに皮膚に付着
していたボツリヌス菌，変性菌，大腸菌などの雑菌が毛
受皿５に留まる。そして大気中の水分によつて雑菌の繁
殖が助長され、毛受皿５の内側が非衛生的になりがちで
ある。この雑菌の繁殖を抑制したりあるいは積極的に殺
菌して、毛受皿５の内側を衛生的に維持するために、抗
菌剤被膜６が形成されている。As shown in FIG. 2, the rotary electric shaver has a dome-shaped outer blade 3 fixed to a head of a razor body 1 by a fixing ring 2 with a predetermined tension. A rotary blade 4 is disposed on the lower surface of the outer blade 3 so as to be in sliding contact therewith.
A hair receiving tray 5 is provided below the bottom. An antimicrobial coating 6 is formed on the upper surface of the bristle tray 5, as shown in FIGS. When shaving is performed using an electric razor, germs, fats, and various germs such as botulinum bacteria, denaturing bacteria, and Escherichia coli that have adhered to the skin together with hair filings remain in the hair receiving tray 5. The propagation of various bacteria is promoted by the moisture in the atmosphere, and the inside of the hair receiving tray 5 tends to be unsanitary. An antimicrobial coating 6 is formed to suppress or actively sterilize the germs and maintain the inside of the hair receiving tray 5 in a hygienic manner.
この抗菌剤被膜６は、銀イオン，銅イオン，亜鉛イオ
ンなどの抗菌作用を有する金属イオンをイオン交換によ
つて担持したゼオライト微粒子７とその微粒子を決着し
て被膜を形成するためのバインダー８とから構成されて
いる（第５図参照）。The antimicrobial agent coating 6 includes zeolite fine particles 7 carrying metal ions having antimicrobial activity such as silver ions, copper ions, and zinc ions by ion exchange, and a binder 8 for fixing the fine particles to form a coating. (See FIG. 5).
前述のゼオライトとしては、合成ゼオライトが賞用さ
れる。この合成ゼオライトは三次元的に発達した骨格構
造を有し、化学組成は、一般にはAl2O3を基準にしてxM2
/nO・Al2O3・ySiO2・zH2Oで表され、Ｍはイオン交換可
能な金属イオンを表し、ｎはその原子価である。そして
ケイ素の一部を配位数４の正四面体形アルミニウムで置
換しているため、正電荷が不足し、その不足を補うため
銀イオン，銅イオン，亜鉛イオンなどの抗菌性のある金
属イオンを結晶内に良好に保持することができる。また
合成ゼオライトは、10オングストローム以下の細孔を三
次元的に有し、150m2/gの比表面積を有し、特にゼオラ
イトA,ゼオライトＸならびにゼオライトＹが好適であ
る。As the above-mentioned zeolite, a synthetic zeolite is awarded. This synthetic zeolite has a three-dimensionally developed framework structure, and its chemical composition is generally xM 2 based on Al 2 O 3.
/ nO · Al 2 O 3 · ySiO represented by 2 · zH 2 O, M represents an ion exchangeable metal ion, n represents its valence. And since a part of silicon is replaced by tetrahedral aluminum having a coordination number of 4, the positive charge is insufficient. To compensate for the lack, antibacterial metal ions such as silver ion, copper ion and zinc ion are used. It can be well retained in the crystal. The synthetic zeolite has pores of 10 Å or less three-dimensionally and has a specific surface area of 150 m 2 / g. Zeolite A, zeolite X and zeolite Y are particularly suitable.
また前記金属イオンの代わりに、安息香酸，サリチル
酸，パラクロロメタクレゾール，グルコン酸クロルヘキ
ジン，レゾルシンなどの有機化合物をゼオライト微粒子
中に担持することもできる。Instead of the metal ion, an organic compound such as benzoic acid, salicylic acid, parachlorometacresol, chlorhexidine gluconate, or resorcinol can be carried in the zeolite fine particles.
被膜形成のためのバインダーとしては、例えばエポキ
シ樹脂，ポリアミド，ポリエステル，合成ゴム，紫外線
硬化樹脂など通常使用されている水不溶性の有機化合物
が使用できる。As a binder for forming a film, a water-insoluble organic compound which is generally used such as an epoxy resin, a polyamide, a polyester, a synthetic rubber, and an ultraviolet curable resin can be used.
ゼオライト微粒子７とバインダー８の樹脂溶液との混
合物を基材である毛受皿５の表面に塗布し乾燥した状態
では、バインダー８の層は第５図に破線で示すようにほ
とんどのゼオライト微粒子７を覆つた状態で、ゼオライ
ト微粒子７どうしならびにゼオライト微粒子７と毛受皿
５とをしつかりと結着する。In a state where a mixture of the zeolite fine particles 7 and the resin solution of the binder 8 is applied to the surface of the bristle tray 5 as a base material and dried, the layer of the binder 8 removes most of the zeolite fine particles 7 as shown by a broken line in FIG. In the covered state, the zeolite fine particles 7 and the zeolite fine particles 7 and the hair receiving tray 5 are tightly bound.
次にバインダー８の上層部を機械的に除去して、ゼオ
ライト微粒子７の表面を露出する。この露出処理に第１
図で示す処理用具９が使用される。この処理用具９は、
指で持つ合成樹脂製の板状挟持部10と、それの一端に植
設された例えば硬質塩化ビニールやポリアミドなどから
なるブラシ11と、他端に連結された板状の弾性部12とか
ら構成されている。この弾性部12は、シリコンゴムなど
のゴム質（ゴム硬度が45〜65度）に、シリコンカーバイ
ト，ホワイトアランダム,Al2O3,SiO2などの番数が400〜
1000の砥粒を混合したものから構成されている。従つて
この弾性部12は前述したバインダー８よりも硬度が高
く、第４図に示すようにこの弾性部12によつて抗菌剤被
膜６の表面を軽くこすることにより、ゼオライト微粒子
７の表面にある樹脂膜（バインダー８）を除去して、ゼ
オライト微粒子７を第５図に示すように部分的に露出す
る。Next, the upper layer of the binder 8 is mechanically removed to expose the surface of the zeolite fine particles 7. The first in this exposure process
The processing tool 9 shown in the figure is used. This processing tool 9
It is composed of a synthetic resin plate-like holding portion 10 held by a finger, a brush 11 made of, for example, hard vinyl chloride or polyamide, implanted at one end of the holding portion 10, and a plate-like elastic portion 12 connected to the other end. Have been. The elastic portion 12 is made of rubber such as silicon rubber (rubber hardness is 45 to 65 degrees), and the number of silicon carbide, white alundum, Al 2 O 3 , SiO 2 is 400 to
It is composed of a mixture of 1000 abrasive grains. Accordingly, the elastic portion 12 has a higher hardness than the binder 8 described above, and the surface of the antibacterial agent coating 6 is lightly rubbed by the elastic portion 12 as shown in FIG. After removing a certain resin film (binder 8), the zeolite fine particles 7 are partially exposed as shown in FIG.
このようにし露出処理された毛受皿５が電気かみそり
に装着されて、使用に供せられる。電気かみそりを使用
すると毛くずや角質，脂肪などと混じつて雑菌が溜まる
が、抗菌剤被膜６の存在により雑菌の繁殖が抑制された
り殺菌が行われ、毛受皿５の内側が常に衛生的に維持で
きる。毛受皿５に溜まつた毛くずなどの除去は第３図に
示すように処理用具９に付いているブラシ11によつて除
去し、さらにその後第４図に示すように弾性部12で毛受
皿５の内面をこすることにより、ゼオライト微粒子７の
表面に付着している脂肪，油分などブラシ11では除去し
難い付着物の除去が行え、抗菌効果の維持に役立つ。The hair tray 5 thus exposed is mounted on an electric razor and used. When an electric razor is used, germs accumulate by mixing with shavings, keratin, fat, and the like. However, the presence of the antibacterial agent coating 6 suppresses the growth of germs and sterilizes the bacteria. it can. As shown in FIG. 3, the removal of the lint collected on the bristle tray 5 is removed by a brush 11 attached to the processing tool 9, and then the bristle pan is elastically deformed by an elastic part 12 as shown in FIG. By rubbing the inner surface of 5, it is possible to remove deposits such as fats and oils adhering to the surface of the zeolite fine particles 7 which are difficult to remove with the brush 11, and to maintain the antibacterial effect.
第６図は処理用具９の第１変形例を示す図で、この例
の場合、弾性部12は複数に分割され、被処理体の形状に
沿い易くなつている。FIG. 6 is a view showing a first modified example of the processing tool 9. In this example, the elastic portion 12 is divided into a plurality of parts, so that the elastic part 12 can easily follow the shape of the object to be processed.
第７図は処理用具９の第２変形例を示す図で、この例
の場合は弾性部12がワイヤブラシから構成されている。FIG. 7 is a view showing a second modification of the processing tool 9, in which the elastic portion 12 is formed of a wire brush.
第８図は処理用具９の第３変形例を示すとともに被処
理体の変形例も示している。この例の場合、電気そうじ
機の集塵ケース13の内面に前述と同様にして抗菌剤被膜
６が形成され、へら状の処理用具９によつて処理され
る。この例では、処理用具９の先端部に弾性部12が一体
に設けられている。FIG. 8 shows a third modification of the processing tool 9 and also shows a modification of the object to be processed. In the case of this example, the antibacterial agent film 6 is formed on the inner surface of the dust collecting case 13 of the electric cleaning machine in the same manner as described above, and is processed by the processing tool 9 having a spatula shape. In this example, an elastic portion 12 is integrally provided at the tip of the processing tool 9.
第９図，第10図は、処理用具９の第４変形例を示す図
である。この例の場合へら状の処理用具９は硬質の合成
樹脂，金属薄板あるいはセラミツクス薄板などからな
り、折り取りが容易にできるように複数本の溝14が形成
されている。9 and 10 are views showing a fourth modification of the processing tool 9. FIG. In this example, the spatula-like processing tool 9 is made of a hard synthetic resin, a thin metal plate, a thin ceramic plate, or the like, and has a plurality of grooves 14 so as to be easily cut off.
第10図は処理用具９の第５変形例を示す図で、この例
では両端にそれぞれ異形の弾性部12a,12bが設けられ、
例えば円錐状の弾性部12aは被処理体の隅部や溝部など
を処理したり清掃するときに、また平板状の弾性部12b
は被処理体の平面部などを処理したり清掃するときに使
用される。FIG. 10 is a view showing a fifth modification of the processing tool 9. In this example, deformed elastic portions 12a and 12b are provided at both ends, respectively.
For example, the conical elastic portion 12a is used when processing or cleaning a corner or a groove portion of the object to be processed, or when the flat elastic portion 12b is used.
Is used when processing or cleaning a flat portion of the object to be processed.
前記実施例では、抗菌剤を担持したゼオライト微粒子
とバインダーとの混合物を基材に塗布した例について説
明したが、前記ゼオライト微粒子と例えばABS樹脂やア
ミド樹脂などの合成樹脂（バインダーとしても機能す
る）の混合物を成形したものにも本発明は適用される。
またこの際ゼオライトの代わりに１〜４μｍ程度の粒径
を有する例えば銀，銅，亜鉛，カドミウム，水銀，ス
ズ，ビスマス，クロムなどの金属微粒子を10〜60重量％
練り込んで成形体にすることもできる。In the above-described embodiment, an example was described in which a mixture of zeolite fine particles carrying an antimicrobial agent and a binder was applied to a substrate, but the zeolite fine particles and a synthetic resin such as an ABS resin or an amide resin (also functioning as a binder) were used. The present invention is also applied to a molded product of the above mixture.
In this case, instead of zeolite, metal particles having a particle diameter of about 1 to 4 μm, such as silver, copper, zinc, cadmium, mercury, tin, bismuth, and chromium, are added in an amount of 10 to 60 wt%
It can also be kneaded into a molded article.
なお前記第１図，第５図ならびに第６図に示した処理
用具９において、ブラシ11として抗菌剤（例えば抗菌作
用を有する金属微粒子、その金属微粒子を担持したゼオ
ライト微粒子あるいは有機化合物など）を一緒に練り込
んだブラシを使用することも可能である。In the processing tool 9 shown in FIGS. 1, 5, and 6, an antibacterial agent (for example, metal fine particles having an antibacterial action, zeolite fine particles or an organic compound carrying the metal fine particles) is used as the brush 11 together. It is also possible to use a brush kneaded in the brush.
本発明は前述のような構成になつており、抗菌剤の利
用効率が高く、しかも所望の決着強度を有し抗菌剤微粒
子が脱落しない抗菌剤層を得ることができる。The present invention has the above-described structure, and can provide an antibacterial agent layer having high utilization efficiency of the antibacterial agent, having a desired fixing strength, and preventing the antibacterial agent fine particles from falling off.
第１図は本発明の実施例で使用する処理用具の斜視図、
第２図は抗菌剤被膜を形成した電気かみそりの一部断面
図、第３図ならびに第４図は毛受皿の処理状態を説明す
るための一部を断面した側面図、第５図は抗菌剤被膜の
拡大断面図である。第６図ならびに第７図は処理用具の
変形例を示す平面図ならびに斜視図、第８図は処理用具
のさらに他の変形例を示す使用状態での斜視図、第９図
図ならびに第10図は処理用具のさらに他の変形例を示す
平面図ならびに側面図、第11図は処理用具のさらに他の
変形例を示す斜視図である。第12図ならびに第13図は、
従来の抗菌剤被膜の拡大断面図である。 ５……毛受皿、６……抗菌剤被膜、７……ゼオライト微
粒子、８……バインダー、９……処理用具、10……挟持
部、11……ブラシ、12,12a,12b……弾性部、13……集塵
ケース、14……溝。FIG. 1 is a perspective view of a processing tool used in an embodiment of the present invention,
FIG. 2 is a partial cross-sectional view of an electric razor having an antibacterial agent film formed thereon, FIG. 3 and FIG. 4 are side cross-sectional views for explaining a part of a processing state of a hair receiving tray, and FIG. It is an expanded sectional view of a coating. 6 and 7 are a plan view and a perspective view showing a modification of the processing tool, and FIG. 8 is a perspective view showing a further modification of the processing tool in a use state, FIG. 9 and FIG. Is a plan view and a side view showing still another modification of the processing tool, and FIG. 11 is a perspective view showing still another modification of the processing tool. FIG. 12 and FIG. 13
It is an expanded sectional view of the conventional antimicrobial agent film. 5 hair receiving tray, 6 antimicrobial coating, 7 fine zeolite particles, 8 binder, 9 processing tool, 10 clamping section, 11 brush, 12, 12a, 12b elastic section , 13 ... dust collecting case, 14 ... groove.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6，ＤＢ名) A61L 2/16 B05D 3/12 B32B 1/00 - 35/00──────────────────────────────────────────────────続 き Continued on the front page (58) Fields surveyed (Int. Cl. 6 , DB name) A61L 2/16 B05D 3/12 B32B 1/00-35/00
Claims (12)
状に形成した後、前記バインダーよりも硬度の高い処理
用具で表面をこすつて抗菌剤を露出せしめることを特徴
とする抗菌剤層の形成方法。An antibacterial agent layer is formed by forming a mixture of an antibacterial agent and a binder into a predetermined shape and then rubbing the surface with a processing tool having a hardness higher than that of the binder to expose the antibacterial agent. Method.
抗菌作用を有する金属を担持したゼオライト微粒子であ
ることを特徴とする抗菌剤層の形成方法。2. The method for forming an antibacterial agent layer according to claim 1, wherein said antibacterial agent is zeolite fine particles carrying a metal having an antibacterial action.
抗菌作用を有する金属粒子であることを特徴とする抗菌
剤層の形成方法。3. The method for forming an antibacterial agent layer according to claim 1, wherein said antibacterial agent is a metal particle having an antibacterial action.
バインダーとの混合物が基材に塗布された被膜であるこ
とを特徴とする抗菌剤層の形成方法。4. The method for forming an antimicrobial agent layer according to claim 1, wherein the mixture of the antimicrobial agent and the binder is a coating applied to a substrate.
バインダーとの混合物が成形体であることを特徴とする
抗菌剤層の形成方法。5. The method according to claim 1, wherein the mixture of the antibacterial agent and the binder is a molded article.
も硬度の高い樹脂膜除去部を有することを特徴とする抗
菌剤層の処理用具。6. An antibacterial agent layer processing tool having a resin film removing portion having a higher hardness than a bander for forming an antibacterial agent layer.
去部が砥粒を含有した弾性体から構成されていることを
特徴とする抗菌剤層の処理用具。7. The antibacterial agent layer processing tool according to claim 6, wherein said resin film removing portion is made of an elastic body containing abrasive grains.
去部の他に清掃部を一体に設けたことを特徴とする抗菌
剤層の処理用具。8. The antibacterial agent layer processing tool according to claim 6, wherein a cleaning unit is provided integrally with the resin film removing unit.
去部が縦割り状に複数分割されていることを特徴とする
抗菌剤層の処理用具。9. An antibacterial agent layer processing tool according to claim 6, wherein said resin film removing portion is divided into a plurality of vertically divided portions.
除去部が先端部に設けられてへら状になつていることを
特徴とする抗菌剤層の処理用具。10. An antibacterial agent layer processing tool according to claim 6, wherein said resin film removing portion is provided at a tip portion and has a spatula shape.
れぞれ異形の樹脂膜除去部が設けられていることを特徴
とする抗菌剤層の処理用具。11. The antibacterial agent layer processing tool according to claim 6, wherein the resin film removing portions having different shapes are provided at both ends.
除去部が複数段にわたつて折り取り可能になつているこ
とを特徴とする抗菌剤層の処理用具。12. The antibacterial agent layer processing tool according to claim 6, wherein said resin film removing portion is capable of being folded over a plurality of steps.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6389689A JP2774555B2 (en) | 1989-03-17 | 1989-03-17 | Method of forming antimicrobial agent layer and processing tool |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6389689A JP2774555B2 (en) | 1989-03-17 | 1989-03-17 | Method of forming antimicrobial agent layer and processing tool |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02243159A JPH02243159A (en) | 1990-09-27 |
| JP2774555B2 true JP2774555B2 (en) | 1998-07-09 |
Family
ID=13242525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6389689A Expired - Fee Related JP2774555B2 (en) | 1989-03-17 | 1989-03-17 | Method of forming antimicrobial agent layer and processing tool |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2774555B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102525091A (en) * | 2010-11-18 | 2012-07-04 | 株式会社大利鸭 | Mixing tool for hair cosmetics, hair cosmetic kit and hair cosmetic preparation method |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3192606B2 (en) * | 1997-04-03 | 2001-07-30 | 四国化成工業株式会社 | Wall coating method |
| KR100828153B1 (en) * | 2007-03-06 | 2008-05-07 | (주)아이탑 | A portable antimicrobial applicator |
| JP5266517B2 (en) * | 2008-02-29 | 2013-08-21 | 東洋製罐グループホールディングス株式会社 | Molded body containing ultrafine metal particles |
| JP5266516B2 (en) * | 2008-02-29 | 2013-08-21 | 東洋製罐グループホールディングス株式会社 | Resin molded body |
-
1989
- 1989-03-17 JP JP6389689A patent/JP2774555B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102525091A (en) * | 2010-11-18 | 2012-07-04 | 株式会社大利鸭 | Mixing tool for hair cosmetics, hair cosmetic kit and hair cosmetic preparation method |
| CN102525091B (en) * | 2010-11-18 | 2016-08-17 | 株式会社大利鸭 | Hybrid instrument, the hair generation method of cosmetic external member and hair cosmetic for hair cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02243159A (en) | 1990-09-27 |
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