JP2636725B2 - Aggregation treatment method of dredged slurry - Google Patents

Aggregation treatment method of dredged slurry

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Publication number
JP2636725B2
JP2636725B2 JP6039458A JP3945894A JP2636725B2 JP 2636725 B2 JP2636725 B2 JP 2636725B2 JP 6039458 A JP6039458 A JP 6039458A JP 3945894 A JP3945894 A JP 3945894A JP 2636725 B2 JP2636725 B2 JP 2636725B2
Authority
JP
Japan
Prior art keywords
slurry
water
fluidized bed
soluble polymer
bed boiler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP6039458A
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Japanese (ja)
Other versions
JPH07246396A (en
Inventor
正康 山崎
要 三宅
弘幸 松田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
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Filing date
Publication date
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Priority to JP6039458A priority Critical patent/JP2636725B2/en
Publication of JPH07246396A publication Critical patent/JPH07246396A/en
Application granted granted Critical
Publication of JP2636725B2 publication Critical patent/JP2636725B2/en
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Expired - Lifetime legal-status Critical Current

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  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Treatment Of Sludge (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は浚渫スラリーの団粒化
理方法に係り、特に、固形分に対する含水率が100重
量%以上の高含水率浚渫スラリーを、低コストに、か
つ、効率的に団粒化処理する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for agglomerating dredged slurry, and more particularly to a method for producing a dredged slurry having a high water content of 100% by weight or more based on solid content at low cost. Also, the present invention relates to a method for efficiently performing agglomeration treatment.

【0002】[0002]

【従来の技術】浚渫工事では浚渫スラリーが大量に発生
するが、発生した浚渫スラリーは、廃棄する場合であっ
ても埋戻す場合であっても、ある程度固形化する必要が
ある。
2. Description of the Related Art In dredging work, a large amount of dredging slurry is generated, and it is necessary to solidify the generated dredging slurry to some extent, whether it is discarded or backfilled.

【0003】ところで、従来、粘土系スラリーの産業廃
土や建設廃土は、その含水率(本明細書において、含水
率とは固形分重量に対する水分重量の割合をさす。)に
応じて固化方法が異なり、含水率40%以下の比較的低
含水率のものは、生石灰(CaO)を添加して水分調整
及びポゾラン反応による固化処理がなされている。ま
た、含水率40〜100%のものは、セメント、或い
は、セメントと高分子吸収材及び/又は生石灰とを添加
することにより固化処理がなされている。
[0003] Conventionally, industrial waste soil or construction waste soil of clay-based slurry is solidified in accordance with the water content thereof (in this specification, the water content means the ratio of the weight of water to the weight of solids). However, for those having a relatively low water content of 40% or less, quick lime (CaO) is added and the water content is adjusted and the solidification treatment by the pozzolanic reaction is performed. Further, those having a water content of 40 to 100% are subjected to solidification treatment by adding cement or cement and a polymer absorbent and / or quicklime.

【0004】しかしながら、含水率100%以上の高含
水率スラリーは、上述のような方法では、固化材を多く
添加する必要があり、処理コストが高騰することから、
長期間天日乾燥して含水率を低下させた後処理している
のが現状である。
However, a slurry having a high water content of 100% or more requires a large amount of a solidifying material to be added by the above-described method, which increases the processing cost.
It is the present condition that after drying in the sun for a long period of time, the water content is reduced and then treated.

【0005】浚渫工事で発生する浚渫スラリーもまた、
含水率100%以上の高含水率スラリーであることか
ら、固化処理には長期間の天日乾燥を必要とする。
[0005] The dredging slurry generated during dredging is also
Since the slurry is a high water content slurry having a water content of 100% or more, solidification requires long-term solar drying.

【0006】[0006]

【発明が解決しようとする課題】上述の如く、浚渫スラ
リーは高含水率スラリーであるため、浚渫スラリーの固
化処理には次のような問題がある。
As described above, since the dredged slurry is a slurry having a high moisture content, the solidification of the dredged slurry has the following problems.

【0007】即ち、生石灰等の固化材の使用量の増大を
防いでコストの高騰を避けるためには、長期間天日乾燥
する必要があり、この場合には、処理に要する期間が長
くなる、天日乾燥のためのスペースを確保する必要があ
るなどの問題がある。
That is, in order to prevent an increase in the amount of solidified material such as quicklime and the like, and to avoid a rise in cost, it is necessary to dry in the sun for a long period of time. There are problems such as the need to secure space for solar drying.

【0008】一方、天日乾燥を行わず、処理効率を高め
ようとすると、固化材を多量に添加する必要があり、処
理コストの高騰を招く。
On the other hand, in order to increase the processing efficiency without performing sun drying, it is necessary to add a large amount of a solidifying material, resulting in an increase in processing cost.

【0009】本発明は上記従来の問題点を解決し、含水
率100%以上の高含水率浚渫スラリーを、低コスト
に、かつ効率的に団粒化処理する方法を提供することを
目的とする。
An object of the present invention is to solve the above-mentioned conventional problems and to provide a low-cost and efficient method for agglomerating a dredged slurry having a high water content of 100% or more. .

【0010】[0010]

【課題を解決するための手段】請求項1の浚渫スラリー
の団粒化処理方法は、固形分に対する含水率が100重
量%以上の浚渫スラリーに流動床ボイラー灰と水溶性高
分子吸収材とを添加して該浚渫スラリーを団粒化処理す
る方法であって、該浚渫スラリーに対して流動床ボイラ
ー灰を160〜20重量%、水溶性高分子吸収材を13
〜0.05重量%添加することを特徴とする。
According to a first aspect of the present invention, there is provided a method for agglomerating a dredged slurry, comprising: adding a fluidized bed boiler ash and a water-soluble polymer absorbent to a dredged slurry having a water content of 100% by weight or more based on solid content. and added a method for processing crumb of the dredging slurry, 160-20 wt% of a fluidized bed boiler ash to said dredging slurry, a water-soluble polymer absorber 13
0.050.05% by weight.

【0011】請求項2の浚渫スラリーの団粒化処理方法
は、固形分に対する含水率が100重量%以上の浚渫ス
ラリーに流動床ボイラー灰と、水溶性高分子吸収材と、
セメント又は生石灰とを添加して該浚渫スラリーを団粒
化処理する方法であって、該浚渫スラリーに対して流動
床ボイラー灰を160〜20重量%、水溶性高分子吸収
材を3〜0.05重量%、セメント又は生石灰を15重
量%以下添加することを特徴とする。
According to a second aspect of the present invention, there is provided a method for agglomerating dredged slurry, comprising: adding a fluidized bed boiler ash, a water-soluble polymer absorbent to a dredged slurry having a water content of not less than 100% by weight based on solid content;
Cement or a method by adding the lime to process crumb of the dredging slurry, a fluidized bed boiler ash 160-20 wt%, a water-soluble polymer absorbing material 3 against the dredged slurry 0.05 wt%, cement or is characterized by the addition of quick lime 15% by weight or less.

【0012】即ち、水溶性高分子吸収材は、浚渫スラリ
ー中の水を吸収してゲル化するため、浚渫スラリーの固
化に有効であるが、高含水率スラリーに対しては、多量
添加を必要とし、コスト高騰の原因となる。
That is, the water-soluble polymer absorbent material is effective for solidifying the dredged slurry because it absorbs water in the dredged slurry and gels. However, it is necessary to add a large amount to a high water content slurry. And cause a rise in cost.

【0013】本発明者は、高含水率浚渫スラリーへの水
溶性高分子吸収材添加量の低減について検討した結果、
浚渫スラリーに流動床ボイラー灰を添加して体積当りの
含水量を低減させることにより、水溶性高分子吸収材添
加量の低減が図れることを見出し、本発明を完成させ
た。
The present inventor studied the reduction of the amount of the water-soluble polymer absorbent added to the dredged slurry with a high water content, and as a result,
The present inventors have found that the amount of water-soluble polymer absorbent added can be reduced by adding a fluidized bed boiler ash to the dredged slurry to reduce the water content per volume, and completed the present invention.

【0014】以下に本発明を詳細に説明する。Hereinafter, the present invention will be described in detail.

【0015】本発明の方法においては、含水率100%
以上の高含水率浚渫スラリーに流動床ボイラー灰及び水
溶性高分子吸収材、或いは更にセメント又は生石灰を添
加する。
In the method of the present invention, the water content is 100%
More high water content dredged slurry to the fluidized bed boiler ash and the water-soluble polymer absorber, or even cement or the addition of quicklime.

【0016】本発明において、流動床ボイラー灰は、
動床ボイラー灰添加混合後の浚渫スラリーの含水率が1
00%以下、好ましくは40〜100%程度となるよう
に添加するのが好ましく、その添加量は処理する浚渫ス
ラリーの含水率に応じて適宜決定されるが、通常の場
合、各添加材の好適添加量は次の通りである。
[0016] In the present invention, a fluidized bed boiler ash, flow
The water content of the dredged slurry after adding and mixing the moving bed boiler ash is 1
It is preferably added so as to be not more than 00%, preferably about 40 to 100%, and the amount of addition is appropriately determined according to the water content of the dredging slurry to be treated. The addition amount is as follows.

【0017】浚渫スラリーに流動床ボイラー灰及び水溶
性高分子吸収材を添加する場合、その添加量は、浚渫ス
ラリーに対して流動床ボイラー灰を160〜20重量
%、水溶性高分子吸収材を13〜0.05重量%とす
る。
[0017] When adding a fluidized bed boiler ash and the water-soluble polymer absorbent material dredged slurry, its amount is 160 to 20 wt% of a fluidized bed boiler ash respect dredged slurry, a water-soluble polymer absorber 13-0.05% by weight
You.

【0018】また、浚渫スラリーに流動床ボイラー灰と
水溶性高分子吸収材とセメント又は生石灰とを添加する
場合には、浚渫スラリーに対して流動床ボイラー灰を1
60〜20重量%、水溶性高分子吸収材を3〜0.05
重量%、セメントを15重量%以下、好ましくは8〜4
重量%又は生石灰を15重量%以下、好ましくは8〜4
重量%添加する
When the fluidized bed boiler ash, the water-soluble polymer absorbent, cement or quick lime are added to the dredged slurry, the fluidized bed boiler ash is added to the dredged slurry in an amount of 1%.
60 to 20% by weight, water-soluble polymer absorbent is 3 to 0.05
Wt%, less than 15 wt% cement, preferably 8-4%
15% by weight or less, preferably 8 to 4% by weight
% By weight .

【0019】本発明において、浚渫スラリーへの流動床
ボイラー灰の添加量が上記範囲より少ないと流動床ボイ
ラー灰を添加したことによる水溶性高分子吸収材やセメ
ント、生石灰の必要添加量の低減効果が十分に得られ
ず、多いと所定の強度に団粒化することが困難となる場
合がある。水溶性高分子吸収材の割合が上記範囲より少
ないと十分に団粒化することができず、また、多いと水
溶性高分子吸収材の添加コストが高くつき好ましくな
い。
In the present invention, a fluidized bed to dredged slurry
And the addition amount of the boiler ash is smaller than the above range fluidized bed Boi
The effect of reducing the required amount of the water-soluble polymer absorbent, cement, and quick lime due to the addition of the ash cannot be sufficiently obtained, and if the amount is too large, it may be difficult to aggregate the particles to a predetermined strength. When the proportion of the water-soluble polymer absorbent is less than the above range, the particles cannot be sufficiently aggregated, and when the proportion is too large, the cost of adding the water-soluble polymer absorbent is undesirably high.

【0020】セメント又は生石灰は団粒化強度の増大の
ために添加するため、必要とされる強度に応じて決定さ
れるが、上記範囲より多く添加しても、強度の大幅な向
上は認められず、コストの高騰を招き、好ましくない。
[0020] For cement or quick lime is added for increased crumb intensity is determined in accordance with the strength required, be added more than the above range, the significant improvement in strength It is not admitted, and the cost rises, which is not preferable.

【0021】各添加材の添加割合は、上記範囲におい
て、浚渫スラリーの含水率の程度や団粒化後の処理方法
(廃棄するか、或いは埋立て等に再利用するか)等に応
じて適宜決定するのが好ましい。
In the above range, the proportion of each additive to be added is appropriately determined according to the degree of water content of the dredged slurry and the treatment method after agglomeration (whether discarded or reused for landfill). It is preferable to determine.

【0022】本発明の浚渫スラリーの処理方法におい
て、各添加材の添加順序には特に制限はなく、全添加材
を一度に同時添加することもできるが、好ましくは、次
の〜のいずれかの手順で行うのが望ましいが、下記
添加順序に何ら限定されるものではない。
In the method for treating a dredged slurry of the present invention, the order of addition of each additive is not particularly limited, and all the additives can be added simultaneously at the same time. It is desirable to carry out the procedure, but the order of addition is not limited at all.

【0023】 浚渫スラリーに所定量の流動床ボイラ
ー灰を添加混合した後、所定量の水溶性高分子吸収材を
添加混合する。 浚渫スラリーに所定量の流動床ボイラー灰を添加混
合した後、水溶性高分子吸収材を添加混合し、更にセメ
ト又は生石灰を添加混合する。 浚渫スラリーに流動床ボイラー灰の所定添加量の一
部を添加混合した後、水溶性高分子吸収材を添加混合
し、流動床ボイラー灰の残部とセメント又は生石灰とを
添加混合する。
After adding and mixing a predetermined amount of fluidized bed boiler ash to the dredged slurry, a predetermined amount of a water-soluble polymer absorbent is added and mixed. After adding and mixing a predetermined amount of the fluidized bed boiler ash dredging slurry, adding and mixing water-soluble polymer absorber, further cementite <br/> down bets or admixing quicklime. After adding and mixing a portion of the predetermined amount of the fluidized bed boiler ash dredging slurry, adding and mixing water-soluble polymer absorber, balance and cement the fluidized bed boiler ash or admixing the lime.

【0024】本発明で用いる流動床ボイラーの一般的な
組成は次の通りである。流動床ボイラー灰は、産業廃棄
物として各所で多量に発生するものであり、安価に入手
することができる。
The general composition of the fluidized-bed boiler used in the present invention is as follows. Fluidized bed boiler ash is industrial waste
It is generated in large quantities in various places as a product, and is available at low cost
can do.

【0025】[0025]

【表1】 [Table 1]

【0026】[0026]

【作用】動床ボイラー灰は、比重が軽く、吸水性が高
く、高含水率浚渫スラリーの体積当りの水分を有効に低
減することができる。特に流動床ボイラー灰は、CaO
を多量に含むため水分調整及びポゾラン反応による固化
に有効であり、また、CaSO4 を含むためエトリンガ
イトの生成による団粒化強度の発現に有効である。
[Action] flow fluidized bed boiler ash, low specific gravity, high water absorption, it is possible to effectively reduce the moisture per volume of the high water content dredging slurry. In particular, fluidized bed boiler ash contains CaO
Is contained in a large amount, which is effective for water content adjustment and solidification by the pozzolanic reaction, and contains CaSO 4 , which is effective for generating ettringite to develop agglomeration strength.

【0027】一方、前述の如く、水溶性高分子吸収材
は、浚渫スラリー中の水を吸収してゲル化して固化す
る。
On the other hand, as described above, the water-soluble polymer absorbent
Absorbs the water in the dredged slurry and gels and solidifies
You.

【0028】このような水溶性高分子吸収材と共に、流
動床ボイラー灰を添加することにより、浚渫スラリーの
含水率が低減し、適当量の水溶性高分子吸収材、或いは
水溶性高分子吸収材とセメント又は生石灰とにより、所
望の強度に団粒化することが可能となる。
By adding a fluidized bed boiler ash together with such a water-soluble polymer absorbent, the water content of the dredged slurry is reduced, and an appropriate amount of the water-soluble polymer absorbent or water-soluble polymer absorbent is added. cement by preparative or the quicklime, it is possible to crumb to the desired strength and.

【0029】請求項2の方法によれば、団粒化の強度を
高めることができ、埋立て等の再利用に有効である。
According to the method of claim 2, the strength of agglomeration can be increased, which is effective for reclaiming landfills.

【0030】[0030]

【実施例】以下に実施例を挙げて本発明をより具体的に
説明する。
The present invention will be described more specifically with reference to the following examples.

【0031】実施例1〜、比較例1〜4 含水率154%の高含水率浚渫スラリーに表3に示す割
合で各添加材を添加混合し、団粒化の可否を調べ、結果
を表3に示した。
Examples 1 to 3 and Comparative Examples 1 to 4 Each additive was added to a high water content dredging slurry having a water content of 154% at the ratio shown in Table 3 and mixed. 3 is shown.

【0032】なお、用いた流動床ボイラー灰の組成は表
2に示す通りである。また、添加順序は前記又はの
方法を採用した。
The composition of the fluidized bed boiler ash used is as shown in Table 2. The order of addition was the same as that described above.

【0033】団粒化強度は、比較例1で得られたものを
基準とし、相対評価により示した。
The agglomerated strength was shown by relative evaluation with reference to that obtained in Comparative Example 1.

【0034】[0034]

【表2】 [Table 2]

【0035】[0035]

【表3】 [Table 3]

【0036】表3より明らかなように、本発明の方法に
よれば、天日乾燥を行なうことなく、水溶性高分子吸収
材やセメント、生石灰の少ない添加量にて、安価に高含
水率浚渫スラリーの団粒化を行うことができる。
As is evident from Table 3, according to the method of the present invention, high-moisture-content dredging can be carried out at low cost with less addition of a water-soluble polymer absorbent, cement and quick lime without performing sun drying. Agglomeration of the slurry can be performed.

【0037】これに対して、流動床ボイラー灰を用いな
い比較例1,2では、団粒化のために多量の水溶性高分
子吸収材やセメントが必要とされる。また、流動床ボイ
ラー灰を用いず、実施例1,と同程度の水溶性高分子
吸収材やセメント添加量とした比較例3,4では団粒化
不可能であった。
On the other hand, in Comparative Examples 1 and 2 using no fluidized-bed boiler ash , a large amount of a water-soluble polymer absorbent or cement is required for agglomeration. Also, fluidized bed boiler
In Comparative Examples 3 and 4 in which the same amount of the water-soluble polymer absorbent and cement as in Examples 1 and 2 were used without using ash , it was impossible to aggregate.

【0038】[0038]

【発明の効果】以上詳述した通り、本発明の浚渫スラリ
ーの処理方法によれば、含水率100%以上の高含水率
浚渫スラリーを、安価にしかも容易に入手可能な流動床
ボイラー灰を用いることにより、高価な添加材を多量に
添加することなく、低コストに、効率的に団粒化処理す
ることができる。
As described above in detail, according to the method for treating a dredged slurry of the present invention, a dredged slurry having a high water content of 100% or more can be obtained at a low cost and easily available in a fluidized bed.
By using boiler ash , the agglomeration treatment can be performed efficiently at low cost without adding a large amount of expensive additives.

【0039】請求項2の方法によれば、団粒化強度を高
め、所望の強度を有する団粒を得ることができる。
According to the method of claim 2, it is possible to increase the agglomeration strength and to obtain the agglomerates having a desired strength.

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 固形分に対する含水率が100重量%以
上の浚渫スラリーに流動床ボイラー灰と水溶性高分子吸
収材とを添加して該浚渫スラリーを団粒化処理する方法
であって、該浚渫スラリーに対して流動床ボイラー灰を
160〜20重量%、水溶性高分子吸収材を13〜0.
05重量%添加することを特徴とする浚渫スラリーの団
粒化処理方法。
1. A method for adding a fluidized bed boiler ash and a water-soluble polymer absorbent to a dredged slurry having a water content of 100% by weight or more with respect to solid content, and subjecting the dredged slurry to an agglomeration treatment. 160 to 20% by weight of the fluidized bed boiler ash and 13 to 0.
A method for agglomerating dredged slurry, comprising adding 0.05% by weight.
【請求項2】 固形分に対する含水率が100重量%以
上の浚渫スラリーに流動床ボイラー灰と、水溶性高分子
吸収材と、セメント又は生石灰とを添加して該浚渫スラ
リーを団粒化処理する方法であって、該浚渫スラリーに
対して流動床ボイラー灰を160〜20重量%、水溶性
高分子吸収材を3〜0.05重量%、セメント又は生石
灰を15重量%以下添加することを特徴とする浚渫スラ
リーの処理方法。
2. A crumb of the water content fluidized bed boiler ash 100% or more by weight of dredging slurry, and a water-soluble polymer absorbing material, the dredging slurry cement or by adding the lime to the solid content adding a method of treating, 160-20 wt% of a fluidized bed boiler ash to said dredging slurry, a water-soluble polymer absorber 3 to 0.05% by weight, cement or 15% by weight of quicklime or less A method for treating dredged slurry.
JP6039458A 1994-03-10 1994-03-10 Aggregation treatment method of dredged slurry Expired - Lifetime JP2636725B2 (en)

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JPH11256154A (en) * 1998-03-10 1999-09-21 Oji Ryokka Kk Soil improvement
JP2001115158A (en) * 1999-10-15 2001-04-24 Shigenori Yamada Production method of granular soil using molten slag of refuse
JP2002273484A (en) * 2001-03-23 2002-09-24 Hitachi Constr Mach Co Ltd Treatment method of sludgy waste, treatment system and mixing treatment equipment
EP2825583B1 (en) 2012-03-15 2016-09-14 Huntsman P&A Uerdingen GmbH Method for granulating particle-containing material obtained from industrial processes, the granulate thus produced
DE102012102473A1 (en) * 2012-03-22 2013-09-26 Xtract Gmbh Treating sewage sludge, useful for improving its storage- and/or transport properties, comprises mechanically dewatering sludge, and mixing dewatered sludge with superabsorbent or hydrogel to obtain granules with specific moisture content

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JPS5342314B2 (en) * 1974-11-29 1978-11-10
JPS51141459A (en) * 1975-06-02 1976-12-06 Taisei Corp Method of solidifying dirty mud
JPS5325270A (en) * 1976-08-20 1978-03-08 Japan Exlan Co Ltd Solidifying method for sludgy substance
JPS54112553A (en) * 1978-02-20 1979-09-03 Japan Exlan Co Ltd Granular solidifying method of muddy matter
JPS62117698A (en) * 1985-11-15 1987-05-29 Mitsubishi Heavy Ind Ltd Solidifying method for sludge
JPS644969A (en) * 1987-06-26 1989-01-10 Nippon Electric Eng System for identifying data code system on magnetic tape and disk
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