JP2562913C - - Google Patents
Info
- Publication number
- JP2562913C JP2562913C JP2562913C JP 2562913 C JP2562913 C JP 2562913C JP 2562913 C JP2562913 C JP 2562913C
- Authority
- JP
- Japan
- Prior art keywords
- deodorant
- fragrance
- gel
- added
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002781 deodorant agent Substances 0.000 claims description 19
- 239000003205 fragrance Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- 239000003349 gelling agent Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 150000004676 glycans Polymers 0.000 claims description 4
- 229920001282 polysaccharide Polymers 0.000 claims description 4
- 239000005017 polysaccharide Substances 0.000 claims description 4
- 150000004804 polysaccharides Polymers 0.000 claims description 4
- 230000003381 solubilizing Effects 0.000 claims description 2
- 239000000499 gel Substances 0.000 description 9
- 229920002148 Gellan gum Polymers 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000216 gellan gum Substances 0.000 description 6
- 235000010492 gellan gum Nutrition 0.000 description 6
- -1 vinyl alcohols Chemical class 0.000 description 5
- 229940113118 Carrageenan Drugs 0.000 description 4
- 239000000679 carrageenan Substances 0.000 description 4
- 235000010418 carrageenan Nutrition 0.000 description 4
- 229920001525 carrageenan Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 229920005615 natural polymer Polymers 0.000 description 3
- 230000002335 preservative Effects 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 229920001059 synthetic polymer Polymers 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N D-Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229940097043 Glucuronic Acid Drugs 0.000 description 1
- PNNNRSAQSRJVSB-BXKVDMCESA-N Rhamnose Chemical compound C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O PNNNRSAQSRJVSB-BXKVDMCESA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 230000000749 insecticidal Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- AEMOLEFTQBMNLQ-QIUUJYRFSA-N β-D-glucuronic acid Chemical compound O[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-QIUUJYRFSA-N 0.000 description 1
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、芳香剤及び／又は消臭剤の分野において使用される透明ゲル状芳
香及び／又は消臭組成物に関するものである。
〔従来の技術〕
従来の透明ゲル状組成物においては、ゲル化剤として一般にカラギーナン、寒
天等の天然高分子化合物が使用されており、又近年これらに代わるものとしてウ
レタン系、ビニルアルコール系等の合成高分子化合物が使用されている。
〔発明が解決しようとする問題点〕
しかしながら、上記カラギーナン、寒天等の天然高分子化合物は、凝固温度が
高いので、例えば透明ゲル状芳香剤への使用においては、香料を添加する場合に
その香料分の一部が揮散してしまうという問題点を有し、さらに離水防止やゲル
強度向上のために他の成分を添加しなければならず、そのため透明度が低下する
という問題点を有していた。
又、上記ウレタン系、ビニルアルコール系等の合成高分子化合物は、ゲル化剤
として使用する場合に５〜３０重量％の含有量を必要とするので、残査が多いと
いう問題点を有し、さらにゲル構造が天然高分子化合物を使用した場合に比べ強
固であり、水の揮散と共にゲル表面が乾燥する傾向にあり、透明ゲル状芳香剤へ
の使用においては、香料の持続力、強さ等を調節するのに問題があり、さらに又
これら合成高分子化合物は、ゲル化を阻害する物質に注意を要し、透明ゲル状芳
香剤への使用においては、添加する香料等に選択性があるという問題点を有して
いた。
〔問題点を解決するための手段〕
そのため、この発明の透明ゲル状芳香及び／又は消臭組成物は、ゲル化剤とし
て、下記の一般式で示される高分子多糖類を含有してなるものである。
上記一般式で示される高分子多糖類は、グルコース２分子と、ラムノース、グ
ルクロン酸１分子ずつを１単位とした直鎖の高分子であり、以下このものを単に
ジェランガムと称す。
この発明の透明ゲル状芳香及び／又は消臭組成物への前記ジェランガムの含有
量は０．１〜３．０重量％であり、好ましくは０．５〜１．５重量％である。０
．１重量％未満ではゲル化機能をほとんど有さず、又３．０重量％を越えると透
明度が低下する。
この発明の透明ゲル状芳香及び／又は消臭組成物の前記ゲル化剤以外並びに界
面活性剤に溶解した芳香剤及び／又は消臭剤以外の含有成分としては、色素、防
腐剤、防虫剤、殺虫剤、忌避剤等を挙げることができる。尚、界面活性剤は、香
料、消臭剤を効果的に可溶化できるものであれば何でもよく、例えばノニオン系
界面活性剤のうちポリオキシエチレンノニルフェニルエーテル系、ソルビタン脂
肪酸エステル系を単独又は混合して用いることができる。界面活性剤は香料及び
／又は消臭剤の可溶化に最適の量を使用するが、大量の使用は得られる透明ゲル
状芳香及び／又は消臭組成物からの香料及び／又は消臭剤の揮散を阻害するので
、なるべく使用量をおさえるのが好ましい。さらに、厳寒時のゲルの凍結防止の
ため、必要に応じ多価アルコール類、グリコールエーテル類を添加することもで
きる。
〔作用〕
この発明の透明ゲル状芳香及び／又は消臭組成物は、ゲル化剤としてジェラン
ガムを含有することにより、凝固温度を低くすることができるので香料等の揮散
性物質の添加は低温で可能となり、又高温下でもゲル状態がくずれず安定し、さ
らにゲル化剤そのものの使用量が少なくてすみ、さらに又ゲル化を阻害する物質
にさほど注意を要することはなくなった。
〔実施例〕
次に、この発明を実施例に基づきさらに詳細に説明する。
実施例１．
表Ｉに示す配合量（重量％）従い、第１過程として、ジェランガムを水に添加
し、９０℃以上になるまで、加熱攪拌する。次に、第２過程として、ジェランガ
ムが完全に溶解した後、約５０℃になるまで冷却する。それとは別に香料を界面
活性剤に溶解し、そしてさらに塩化カルシウム、防腐剤を加えて攪拌する。これ
を溶解したジェランガムに加え、その後、約４０℃になるまで放冷してから容器
へ充填し、室温になるまで放置した。
実施例２．
表Ｉに示す配合量（重量％）に従い、実施例１の第２過程において３−メチル
−３−メトキシ−１−ブタノール(グリコールエーテル類)を追添加する以外は、
実施例１と同様の操作によった。
実施例３．
表Ｉに示す配合量（重量％）に従い、実施例１の第２過程においてプロピレン
グリコール（多価アルコール）を追添加する以外は、実施例１と同様の操作によ
った。
比較例
表Ｉに示す配合量（重量％）に従い、カラギーナンを水に添加し、８０℃にな
るまで加熱攪拌する。カラギーナンが完全に溶解した後、香料、界面活性剤、防
腐剤を加え、さらに攪拌しながら、約６０℃になるまで冷却してから容器へ充填
し、室温になるまで放置した。 上記実施例１〜３と比較例について、凝固温度、ゲル溶解温度の測定を行った
。その結果を表II、IIIに示す。
上記表II、IIIから明らかなように、この発明の実施例では比較例より、凝固
温度において約２０℃低くなり、ゲル溶解温度においては約３５℃以上高くなる
という結果を得た。
〔発明の効果〕
この発明の透明ゲル状芳香及び／又は消臭組成物は、以上に述べたように構成
されており、凝固温度を低くすることができるので香料及び／又は消臭剤の添加
は比較的低温で可能となり、製造時に香料分等が揮散する量は極めて少なく香料
本来の香りが得られ、その消臭剤も無駄なく使用できる。又、高温下でもゲル状
態がくずれず安定しているので、広範囲の用途に使用できる。さらにゲル化剤そ
のものの使用量が少なくてすむので、残査が少なくなり、さらに又ゲル化を阻害
する物質にさほど注意を要することはなく、添加する香料及び／又は消臭剤にも
選択性がほとんどない等、優れた効果を有する。Description: TECHNICAL FIELD The present invention relates to a transparent gel-like fragrance and / or deodorant composition used in the field of fragrance and / or deodorant. [Prior art] In a conventional transparent gel composition, a natural polymer compound such as carrageenan or agar is generally used as a gelling agent, and in recent years, urethanes, vinyl alcohols, etc. Synthetic polymer compounds have been used. [Problems to be Solved by the Invention] However, the above-mentioned natural polymer compounds such as carrageenan and agar have a high coagulation temperature. In addition, there is a problem that a part of the fraction is volatilized, and further, it is necessary to add another component for preventing water separation and improving the gel strength, so that there is a problem that the transparency is reduced. . Further, the urethane-based and vinyl alcohol-based synthetic polymer compounds require a content of 5 to 30% by weight when used as a gelling agent, and thus have a problem that a large amount of residue remains. Furthermore, the gel structure is stronger than when a natural polymer compound is used, and the gel surface tends to dry with the volatilization of water. In addition, these synthetic polymer compounds require attention to substances that inhibit gelation, and when used in a transparent gel-like fragrance, there is a selectivity for a fragrance to be added. There was a problem that. [Means for Solving the Problems] Therefore, the transparent gel-like aroma and / or deodorant composition of the present invention contains, as a gelling agent, a polymer polysaccharide represented by the following general formula: It is. The high molecular polysaccharide represented by the above general formula is a linear polymer having two units of glucose, one unit of rhamnose and one unit of glucuronic acid, and this is hereinafter simply referred to as gellan gum. The content of the gellan gum in the transparent gel-like aroma and / or deodorant composition of the present invention is 0.1 to 3.0% by weight, preferably 0.5 to 1.5% by weight. 0
. If it is less than 1% by weight, it has almost no gelling function, and if it exceeds 3.0% by weight, the transparency is reduced. The components other than the gelling agent and the components other than the fragrance and / or deodorant dissolved in the surfactant of the transparent gel-like aroma and / or deodorant composition of the present invention include pigments, preservatives, insect repellents, Insecticides, repellents and the like can be mentioned. The surfactant is not particularly limited as long as it can effectively solubilize a fragrance and a deodorant. For example, among nonionic surfactants, polyoxyethylene nonylphenyl ether and sorbitan fatty acid ester can be used alone or in combination. Can be used. The surfactant is used in an amount that is optimal for solubilizing the fragrance and / or deodorant, but a large amount is used to remove the fragrance and / or deodorant from the resulting transparent gel-like aroma and / or deodorant composition. Since volatilization is inhibited, it is preferable to reduce the amount of use as much as possible. Furthermore, polyhydric alcohols and glycol ethers can be added as needed to prevent the gel from freezing during severe cold. [Action] The transparent gel-like aroma and / or deodorant composition of the present invention can reduce the coagulation temperature by containing gellan gum as a gelling agent, so that volatile substances such as fragrances can be added at a low temperature. It is possible to stabilize the gel state even at a high temperature, to reduce the amount of the gelling agent itself, and to be less careful with substances that inhibit gelation. EXAMPLES Next, the present invention will be described in more detail based on examples. Embodiment 1 FIG. According to the blending amount (% by weight) shown in Table I, as a first step, gellan gum is added to water and heated and stirred until the temperature becomes 90 ° C. or higher. Next, as a second step, after the gellan gum is completely dissolved, it is cooled to about 50 ° C. Separately, the perfume is dissolved in the surfactant, and further calcium chloride and preservative are added and stirred. This was added to the dissolved gellan gum, then allowed to cool to about 40 ° C., filled in a container, and left to reach room temperature. Embodiment 2. FIG. According to the compounding amount (% by weight) shown in Table I, except that 3-methyl-3-methoxy-1-butanol (glycol ethers) was additionally added in the second step of Example 1.
The same operation as in Example 1 was performed. Embodiment 3 FIG. According to the blending amount (% by weight) shown in Table I, the same operation as in Example 1 was performed, except that propylene glycol (polyhydric alcohol) was additionally added in the second step of Example 1. Comparative Example Carrageenan was added to water according to the amount (% by weight) shown in Table I, and the mixture was heated and stirred until the temperature reached 80 ° C. After the carrageenan was completely dissolved, a fragrance, a surfactant, and a preservative were added, and the mixture was cooled to about 60 ° C. with stirring, filled in a container, and left to reach room temperature. The solidification temperature and the gel dissolution temperature of the above Examples 1 to 3 and Comparative Example were measured. The results are shown in Tables II and III. As is clear from Tables II and III, in the examples of the present invention, the results were that the solidification temperature was lower by about 20 ° C. and the gel dissolution temperature was higher by about 35 ° C. or more than the comparative example. [Effects of the Invention] The transparent gel-like aroma and / or deodorant composition of the present invention is constituted as described above, and can reduce the coagulation temperature, so that a perfume and / or deodorant is added. Is possible at a relatively low temperature, the amount of the fragrance and the like volatilized during production is extremely small, the fragrance inherent in fragrance is obtained, and the deodorant can be used without waste. In addition, the gel state is stable even at high temperatures without breaking down, so that it can be used for a wide range of applications. Furthermore, since the amount of the gelling agent itself used is small, the amount of residue is small, and there is no need to pay much attention to the substance that inhibits gelation, and it is also selective for the added fragrance and / or deodorant. It has excellent effects such as almost no.
Claims (1)
子多糖類並びに前記香料及び／又は消臭剤を可溶化できる界面活性剤を含有して
なることを特徴とする透明ゲル状芳香及び／又は消臭組成物。 ２．前記高分子多糖類の含有量が０．１〜３．０重量％である請求項１記載の
透明ゲル状芳香及び／又は消臭組成物。[Claims] 1. It is characterized by comprising a high molecular weight polysaccharide represented by the following general formula as a fragrance and / or deodorant and a gelling agent, and a surfactant capable of solubilizing the fragrance and / or deodorant. A transparent gel-like aroma and / or deodorant composition. 2. The transparent gel-like aroma and / or deodorant composition according to claim 1, wherein the content of the high-molecular polysaccharide is 0.1 to 3.0% by weight.
Family
ID=
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