JP2562064C - - Google Patents

Info

Publication number

JP2562064C

JP2562064C JP2562064C JP 2562064 C JP2562064 C JP 2562064C JP 2562064 C JP2562064 C JP 2562064C

Authority

JP

Japan

Prior art keywords

weight

hydrogen peroxide

stabilizer

surfactant

viscosity

Prior art date

1999-02-10

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

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• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 43
• 239000000203 mixture Substances 0.000 claims description 32
• 239000003381 stabilizer Substances 0.000 claims description 18
• 239000004094 surface-active agent Substances 0.000 claims description 18
• 239000003792 electrolyte Substances 0.000 claims description 15
• XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 8
• 239000007788 liquid Substances 0.000 claims description 6
• -1 alcohol sulfates Chemical class 0.000 claims description 5
• 239000012670 alkaline solution Substances 0.000 claims description 5
• 238000004061 bleaching Methods 0.000 claims description 5
• 239000003945 anionic surfactant Substances 0.000 claims description 3
• 150000001875 compounds Chemical class 0.000 claims description 3
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
• 229910052783 alkali metal Inorganic materials 0.000 claims description 2
• 150000001340 alkali metals Chemical class 0.000 claims description 2
• 229910052784 alkaline earth metal Chemical class 0.000 claims description 2
• 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
• 150000003863 ammonium salts Chemical class 0.000 claims description 2
• 150000001768 cations Chemical class 0.000 claims description 2
• 239000000243 solution Substances 0.000 description 10
• DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 8
• 235000019333 sodium laurylsulphate Nutrition 0.000 description 8
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
• 229910021538 borax Inorganic materials 0.000 description 6
• 239000004328 sodium tetraborate Substances 0.000 description 6
• 235000010339 sodium tetraborate Nutrition 0.000 description 6
• 150000003606 tin compounds Chemical class 0.000 description 6
• 239000007844 bleaching agent Substances 0.000 description 5
• 238000000354 decomposition reaction Methods 0.000 description 5
• 238000009472 formulation Methods 0.000 description 5
• UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 5
• 239000000047 product Substances 0.000 description 5
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
• 229910052748 manganese Inorganic materials 0.000 description 4
• 239000011572 manganese Substances 0.000 description 4
• 150000003839 salts Chemical class 0.000 description 4
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 150000001412 amines Chemical class 0.000 description 3
• 150000002978 peroxides Chemical class 0.000 description 3
• 239000011734 sodium Substances 0.000 description 3
• 239000011780 sodium chloride Substances 0.000 description 3
• 238000003860 storage Methods 0.000 description 3
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
• 229910019142 PO4 Inorganic materials 0.000 description 2
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
• 150000001335 aliphatic alkanes Chemical class 0.000 description 2
• 125000000217 alkyl group Chemical group 0.000 description 2
• 239000002280 amphoteric surfactant Substances 0.000 description 2
• 150000008064 anhydrides Chemical class 0.000 description 2
• 125000004432 carbon atom Chemical group C* 0.000 description 2
• 230000015556 catabolic process Effects 0.000 description 2
• 239000012141 concentrate Substances 0.000 description 2
• 238000006731 degradation reaction Methods 0.000 description 2
• 230000000694 effects Effects 0.000 description 2
• 239000003205 fragrance Substances 0.000 description 2
• WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
• 239000010452 phosphate Substances 0.000 description 2
• 229910052708 sodium Inorganic materials 0.000 description 2
• FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
• 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• 229940120146 EDTMP Drugs 0.000 description 1
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
• 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
• 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
• 230000002378 acidificating effect Effects 0.000 description 1
• JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
• 230000009286 beneficial effect Effects 0.000 description 1
• 239000000872 buffer Substances 0.000 description 1
• 230000003139 buffering effect Effects 0.000 description 1
• 238000011109 contamination Methods 0.000 description 1
• 230000001934 delay Effects 0.000 description 1
• CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 1
• TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 description 1
• 239000006185 dispersion Substances 0.000 description 1
• 239000000975 dye Substances 0.000 description 1
• NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
• 239000012467 final product Substances 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• 230000005484 gravity Effects 0.000 description 1
• 230000007062 hydrolysis Effects 0.000 description 1
• 238000006460 hydrolysis reaction Methods 0.000 description 1
• 238000011065 in-situ storage Methods 0.000 description 1
• 230000002401 inhibitory effect Effects 0.000 description 1
• 150000002500 ions Chemical class 0.000 description 1
• 229910052742 iron Inorganic materials 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
• 239000012286 potassium permanganate Substances 0.000 description 1
• 239000002994 raw material Substances 0.000 description 1
• 239000003352 sequestering agent Substances 0.000 description 1
• 230000009919 sequestration Effects 0.000 description 1
• 229940079864 sodium stannate Drugs 0.000 description 1
• 235000019832 sodium triphosphate Nutrition 0.000 description 1
• 230000006641 stabilisation Effects 0.000 description 1
• 238000011105 stabilization Methods 0.000 description 1
• 230000000087 stabilizing effect Effects 0.000 description 1
• 235000011150 stannous chloride Nutrition 0.000 description 1
• BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
• 239000003760 tallow Substances 0.000 description 1
• 230000008719 thickening Effects 0.000 description 1
• FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 1
• AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
• HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
• 229910052723 transition metal Inorganic materials 0.000 description 1
• 229910001428 transition metal ion Inorganic materials 0.000 description 1
• 150000003624 transition metals Chemical class 0.000 description 1
• 125000005270 trialkylamine group Chemical group 0.000 description 1