JP2552806B2 - Coal gasifier - Google Patents

Description

Detailed Description of the Invention

[0001]

FIELD OF THE INVENTION This invention relates to improvements in spouted bed coal gasifiers.

[0002]

2. Description of the Related Art The development of coal gasification technology is currently being actively promoted as part of so-called coal conversion and utilization, in which coal is converted into a fluid fuel that is clean and easy to handle. Among them, the gasification method characterized by separating the ash of coal as molten slag from the produced gas and discharging it out of the furnace is also called slagging gasification.In particular, the spouted bed gasification method is highly efficient in ash treatment. Because of their excellent environmental friendliness, various types of coal gasifiers are currently proposed and being developed.

In a slugging furnace, coal and a gasifying agent such as oxygen are reacted at a high temperature to produce useful gases such as carbon monoxide (CO) and hydrogen (H ₂ ), and the ash content of coal is melted. The reaction in the gasification chamber is controlled so that the liquid slag having fluidity can be discharged to the outside of the gasification chamber. Therefore, the operating temperature of the slagging furnace is generally extremely high, and when the coal having a high melting point of ash is gasified, it is not uncommon for the atmospheric temperature in the gasification chamber to exceed 1500 ° C. Further, the gasification chamber is mainly composed of coal slag, which is a melt of coal ash composed of a reducing crude gas containing CO and H ₂ as main components and a multi-component oxide, and char and unmelted or semi-molten coal. An environment where powders such as ash, vapors of substances with high vapor pressure such as alkali metal elements and SiO, hydrogen sulfide, hydrogen chloride, etc. coexist at high temperatures, and in some cases jet these substances at high speed. Therefore, the corrosion / wear effect on the material is generally very large.

Under such a high temperature and highly corrosive environment, there is currently no constituent material of the gasification chamber that can withstand long-term use without any trouble without any measures. Therefore, in a slagging furnace of the type that enables gasification of coal whose ash melting temperature is not low, it is possible to cool the furnace wall of the gasification chamber and the non-operating side of the hearth refractory material by lowering the material temperature. A method that allows high temperature operation of the furnace is often adopted by providing a lining water cooling wall.

On the other hand, in the slagging furnace, an opening (hereinafter referred to as a slag tap) for flowing / discharging the slag to the outside of the gasification reaction chamber has a high temperature so that the slag tap hole is not clogged due to cooling and solidification of the slag. At the same time, as a slag tap constituent member, it is necessary to configure the member so as to withstand the corrosive action of highly corrosive gas or molten slag.

As the slag tap, an uncooled slag tap made of a ceramic material such as refractory brick, a refractory lining water-cooled slag tap having the same construction as the refractory lining water-cooled wall, or JP-A-56-47488. A metal casting slag tap with a water-cooled pipe as disclosed in the publication, or the cooling type slag tap is lifted to a high temperature part in a gasification chamber to form a slag pool, thereby trying to maintain a necessary temperature under the slag flow. Known slag taps, slag taps formed by combining these slag taps with a burner for heating, or slag taps that can be said to be a self-heating type disclosed in JP-A-62-236891. .

[0007]

In the construction of these slag taps, when a non-cooling type slag tap is constructed by using a ceramic material such as refractory bricks, the tap holes are hard to be cooled, so that a stable slag It is effective in facilitating one of the most important functions in the slagging furnace, which is the flow-down and discharge. On the other hand, ceramic-based materials such as refractory bricks are in a severe wear environment due to consumption by high temperature process atmosphere or permeation / erosion / erosion of molten coal slag, and it is difficult to maintain component life for a long period of time. It has the drawback of shortening the repair cycle of the gasification chamber.

On the other hand, in order to maintain the life of the slag tap member, in a slag tap of a system provided with some cooling means, the reaction heat in the gasification chamber or heating of the slag tap by an auxiliary burner and the slag tap by the forced cooling means are used. It is not always easy to maintain the balance of the temperature drop of, and there is a drawback that the slag tap is likely to be clogged with the change of the reaction condition in the gasification chamber.

Further, the partial oxidation gasification method in this type of coal gasification furnace is characterized in that the gasification temperature is eventually determined by the ratio of the supplied gasifying agent and coal, and the gasification chamber is characterized. The temperature measurement of the gasification is not always essential in the operation of the coal gasification furnace, but by knowing the temperature of the gasification chamber internal points such as the vicinity of the slag tap and the gas outlet, the gasification status and slag fluidity can be measured. It becomes possible to accurately grasp. Therefore, being able to appropriately measure the temperature in the gasification chamber is very convenient for the purpose of selecting the optimum gasification conditions depending on the type of coal or continuing stable operation of the furnace.

In order to measure the temperature in the gasification chamber with high sensitivity, generally, a high temperature type thermocouple covered with a sheath is protruded into the gasification chamber through a protective tube and sufficiently exposed to the atmosphere in the chamber. Need to let. Regarding the material of the thermocouple protection tube, the proposal of the ceramic material disclosed in Japanese Patent Publication No. 2-46549 or the reference (RYYoung: "
Recent Developments in High Pressure, Entrained Fl
ow Slagging Gasification of Coal ", 8th Intern. Con
f. on Coal Gasification, Liquefaction and Conversio
n to Electricity, or DOE Report No.ET/14705-1
A thermocouple protection tube formed by coating the surface of the molybdenum base material described in 3) with chromium oxide (Cr ₂ O ₃ ) is known. As is obvious from the function required for the member, the protection tube cannot be used by lowering the material temperature by means such as cooling, so it is directly hit by the high temperature and highly corrosive gas and slag in the gasification chamber. In addition, since it is exposed to a very rapid temperature change, it has a problem that it generally has an extremely short life.Therefore, a thermocouple protection tube for a coal gasifier with a significantly improved service life is required. There is.

An object of the present invention is to solve these problems in a slugging coal gasification furnace. That is, the slag discharge hole (slag tap) provided in the gasification chamber is liable to be clogged by cooling and solidification of the slag, and as a means for solving the problem, a type of coal in which the slag tap member is not cooled in order to prevent clogging easily. In gasification furnaces, the main components such as slag taps in the gasification chamber are prone to wear in a relatively short time, and the thermocouple protection tube installed in the gasification chamber generally has a short life. It is difficult to understand the status of the gasification reaction in the gasification chamber, and as a result, various obstacles due to excessive temperature rise in the gasification chamber, or too low temperature leading to slag tap blockage, etc. Solved the operational or equipment problem in the slagging coal gasification furnace that it is difficult to operate the gasification furnace stably over a long period of time.
Another object of the present invention is to propose a novel configuration of a slugging type coal gasification furnace which is suitable for significantly extending one operation life or one operation time in coal gasification furnace operation.

[0012]

[Means for Solving the Problems] The present inventors have conducted many studies and experiments in order to solve the above problems and achieve the objects. In the process, first, the idea of applying Ir, which is a refractory metal, to the main members in the gasification chamber of the slugging coal gasification furnace was conceived. According to the literature (Noboru Ishiguro et al., Industrial Rare Metals, No.91, 1987, p.50, etc.), Ir is a white metal element with a melting point of 2447 ° C and relatively difficult to process, and its chemical stability at high temperatures. For, the volatile oxide forms slowly in an oxidizing atmosphere and is consumed, does not react with graphite and specific metal elements, and is industrially used as a reaction catalyst in petrochemistry and a melting crucible material for oxide single crystal production. It is known that it has been used as a prize. However, to date, there is no known possibility of the usefulness of Ir in the environment of the gasification chamber in which the strongly reducing and corrosive high temperature gas-melting coal slag is swirled. In order to achieve the above object, the present inventors have conducted experiments as described below regarding durability or corrosion resistance in an Ir gasification environment.

[Experiment I: Corrosion Test in Laboratory Simulated Environment] A corrosion test in a simulated environment was conducted for the purpose of evaluating the durability of Ir under a wider environmental condition. The experimental procedure is as follows. In order to simulate the main environment in a spouted bed coal gasification furnace, an Ir test piece with a purity of 99.9% (Dimension: 1
(0 mm x 20 mm x 1 mm) is sandwiched with refractory containing Cr ₂ O ₃ as a main component and placed in a platinum or graphite crucible, and the void in the crucible is filled with ash of Pacific coal (weight: about 20 g ). The reason why the Ir test piece was sandwiched with the refractory was that the refractory was usually used as the lining material of the gasification chamber, and it was necessary to examine the reaction between the refractory component and Ir.

The amount of coal ash filled was determined in consideration of the fact that when the ash was heated and melted, both the Ir test piece and the sandwich of the refractory sample were in contact with both the molten slag and the atmospheric gas in the crucible. This crucible was installed in an externally heated tubular electric furnace,
12 liters of air, nitrogen, or carbon monoxide gas
The mixture was heated and maintained at 1650 ° C to 1600 ° C for 5 hours while flowing for h. Table 1 shows the combination of the four test conditions tested and the situation of the Ir test piece as the test result.

[0015]

[Table 1]

Po ₂ shown in the table is a value estimated by thermodynamic examination based on the type and purity of the atmosphere gas used in the experiment or the substance deposited or remaining in the crucible after the heating test is completed. As shown in the table, in the experiment numbers 1 and 2, that is, in the atmosphere of Po ₂ > 10 ⁻⁴ atm, Ir was
The test piece retained the same metallic luster as before the test, and there was no sign of damage such as increase or decrease in weight or formation of corrosive substances. In Experiment No. 3, although a slightly greenish black deposit was observed on the surface of the Ir test piece, the Ir test piece after removing the deposit had almost no abnormal appearance. On the other hand, there was partial melting loss of the refractory material, and a thin metallic coating was formed macroscopically continuously on the inner wall of the graphite crucible. As a result of the analytical investigation, elements other than Ir were not detected inside the test piece, most of the deposit on the Ir test piece surface was Cr ₂ O ₃ , and the thin film-like precipitate on the inner wall of the crucible was Cr.
_{With 23} C ₆ and Cr ₇ C ₃ , the slag remaining in the crucible contained Cr ₂ O ₃ eluted from the refractory and a small amount of ZrO ₂ in the slag composition before the test, and the iron oxide was reduced to Fe. It was found that they existed as slag components without any.

The above results are considered as follows. Decrease in melting point of Cr ₂ O ₃ under low oxygen partial pressure atmosphere, melting into slag, formation of chromium carbide (Cr _x C _y ) by reaction of Cr ₂ O ₃ and graphite (C) in molten slag / inner wall of crucible Precipitation. On the other hand, the oxygen partial pressure of the atmosphere is not so low as to reduce the most easily dissociated iron oxide among the substances existing in the system, and therefore it is estimated that Po ₂ was 10 ⁻⁸ atm or more. Further, the reason why iron carbide (Fe ₃ C) is not detected while chromium carbide is formed is considered to be because a large amount of Cr ₂ O ₃ was present with respect to FeO.

In Experiment No. 4, the Ir test piece and the refractory sample that were set had almost no original shape, and a non-metallic reaction product with a whitish gray color was spilled from the crucible, and the same reaction product was found on the bottom of the crucible. At the same time, the metal phase melted and solidified was present, and also in the spilled non-metallic reactant, the metal phase was present. This is due to the excessive reducibility of the test environment,
A metal element reduced and produced from the oxide in the crucible and Ir are mutually alloyed, have a low melting point, or form an intermetallic compound / carbide. In any case, experiment number 4
It is speculated that Ir cannot be expected to be applied to members that need to maintain their shape under the conditions where various types of oxides coexist in a strong reducing environment such as The slacking furnace is not operated under such a strong reducing environment.

[Experiment II: Actual Plant Test] Since the effectiveness of Ir could be recognized by the corrosion test under the above-mentioned laboratory simulated environment, the present inventors next conducted a test in an actual plant. This is described below. Two plate-shaped test pieces (dimensions: 5 mm × 95 mm × 1 mm, mass: about 11 g) having an Ir purity of 99.9% grade were subjected to an exposure test in an environment in the gasification chamber of the actual plant. One of them (TP No. 1) was placed in contact with the refractory hearth floor surface of the gasification chamber. This site is primarily the environment in which molten coal slag flows over the surface of the specimen during the gasification test run of the plant. Other test pieces (TP
No. 2) is about 40 at one end of the test piece at the thermocouple protection tube attachment part provided on the refractory lining water cooling wall of the gasification chamber.
It was installed in the form of inserting mm. Therefore, TP N
o. No. 2 is an atmosphere environment in which the gas and slag / char in the gasification chamber scatter about 55 mm of the test piece length.

The operating conditions of the gasification test of the plant in the exposure test were pressure: 30 atm, cumulative test time: a little over 100 hours, and cumulative coal input: a little over 120 t. Although the details of the environmental temperature to which each test piece was exposed during the operation of the plant cannot be specified, TP No. According to the measurement value by the thermocouple with the protective tube made of ceramics, which is installed in a tie with 2, the maximum temperature of 1750 ° C. is detected for a short time. Each test piece was collected after the plant operation was completed. Table 2 shows the results of a detailed survey of their usefulness / damage conditions.

[0021]

[Table 2]

As shown in the table, the test piece of TP No. 1 presumed that slag mainly flowed on the surface of the test piece had metallic luster, but part of the surface in contact with the hearth It was in a molten state and glass-like deposits had adhered. The comparatively sound part of the test piece, the part that was in a molten state, and the deposits were analyzed by energy dispersive X-ray analysis (hereinafter referred to as EDX) and X-ray diffraction (hereinafter referred to as XRD). As a result, Fe was alloyed with Ir in the molten state, no components other than Ir were detected in the sound part, and the deposit was solidified matter of coal slag or hearth refractory (main component). : Cr ₂ O ₃ ) was identified. Further, the formation of a corrosive product containing Ir could not be found in any part of the test piece.

The alloying of Fe with Ir and the formation of a partially molten appearance are considered as follows. As a result of investigating the operation status of the plant where the exposure test was conducted, the slag was not discharged from the gasification chamber during the very limited time during operation, and during the period during which molten slag was accumulated in the gasification chamber In the environment where coal is gasified at high temperature, iron oxide in coal slag is probably FeO, which is the most easily reduced oxide among slag components, and equilibrium dissociation pressure of FeO (oxygen partial pressure). : Po ₂ ) and the equilibrium dissociation pressure of the atmospheric gas in the gasification chamber is 160
Approximately equivalent level at 0 ° C (Po ₂ ≈ 10 ^-8 a
tm), the atmosphere gas may reduce FeO and produce Fe while the slag is accumulated and accumulated in the gasification chamber. Phase equilibrium diagram of Ir-Fe system
sed Fe-Ir Phase Diagram, in Binary AlloyPhase Diag
rams: ed by TBMassalski, et al, 1 (1986), 1072, A
According to (SM), the melting point of pure Ir is 2447 ° C., whereas the melting temperature of the Ir—Fe alloy is drastically lowered by the alloying of Fe, and about 1800 ° C. at Ir-25% Fe,
It is shown that the temperature is about 1600 ° C. for Ir-70% Fe.

Next, TP No. On the surface of No. 2, a blackish brown deposit that was easily peeled off was observed. As a result of the investigation, it was found that this deposit was the one to which coal slag was fixed and did not contain Ir at all. Further, the mass of the test piece after removing the adhered matter was not different from that before the test. From the above consideration, the cause of damage to the hearth exposure test piece can be almost explained. Also, by considering the soundness of the furnace wall exposure test piece together, even in the environment of the gasification chamber hearth where slag continuously flows down, even in the environment where the gas phase in the gasification chamber is the main, Ir maintains its high melting point unless slag is retained, and
It is concluded that there is little danger of reacting with slag and refractory components and suffering damage such as corrosion.

The above field tests and simulated tests in a laboratory environment have demonstrated that Ir has very good durability in a spouted bed gasification chamber environment.
The excellent durability of Ir in the gasification environment as described above allows the inclusion of inevitable impurities, so to speak, substantially pure I.
However, the durability of Ir described here is about 2000 ° C. depending on the composition ratio such as Ir-Rh alloy, Ir alloy having a high melting point such as Ir-Re alloy, or Ir-Pt alloy. It would be obvious to those skilled in the art that the same thing would be shown even in the case of an Ir alloy having a melting point above. Pt is preferably 40% by weight or less (preferably 1 to 20%), and Rh and Re form a solid solution at all ratios, and any composition has a melting point of 2000 ° C. or higher. High alloy strength can be obtained by alloying. Both Rh and Re are 40% or less, and particularly preferably 1 to 20%.

The present invention is based on the knowledge obtained from the above experiments and experience. Basically, coal is reacted with a gasifying agent such as oxygen at a high temperature, and the ash content of the coal is melted into slag. In a coal gasification furnace of a type that discharges to the outside of the gasification chamber, all or part of the members formed in the portion exposed to the environment of the gasification chamber is substantially covered with Ir or Ir. Achieved by

The object can also be achieved by an Ir alloy having a melting point higher than the atmospheric temperature in the coal gasification furnace, and as an example, an Ir-Rh alloy, an Ir-Re alloy, or an Ir-Pt.
An alloy having a composition whose melting point is equal to or higher than the atmospheric temperature in the coal gasification furnace can be mentioned. Since the atmospheric temperature in the coal gasification furnace is about 1500 ° C to 1600 ° C, it is a preferable embodiment to use an Ir-Pt alloy having a composition with a melting point of 2000 ° C or higher.

Further, the member formed or coated with Ir or Ir alloy may be any member formed in the portion exposed to the gasification chamber environment, but in the operation of the actual machine, the thermocouple protection tube, the slag tab, etc. It is preferable to apply to a member in which the gas / slag environment in the gasification chamber is harsh, and the structure of the gas flow path where scattered slag tends to adhere in a jet bed coal gasification furnace such as the gas outlet of the gasification chamber It is also preferable to use it as a member. Especially, in the latter case, since the member is made of Ir, the setting limit of the member temperature at the relevant portion is greatly expanded, and slag is less likely to adhere to the material as compared with a material such as a refractory lining, so that adhesion of scattered slag is reduced. A new effect of broadening the selection range of measures for the process can be expected.

[0029]

EXAMPLES The present invention will be described in more detail with reference to some examples. FIG. 1 is a partial conceptual diagram of an embodiment of a spouted bed coal gasification furnace to which the present invention is applied. The coal gasification furnace has a gasification chamber 1 and a slag cooling chamber 6 located below the gasification chamber 1 via a hearth portion, and the gasification chamber 1 has a gas outlet 2 at its upper part and a furnace. The floor has a slag extraction port (referred to as a slag tap) member 3. Further, a coal and gasifying agent supply burner 4 and a thermocouple 5 as a means for detecting the temperature in the gasification chamber are installed in the furnace wall portion of the gasification chamber 1, and the thermocouple 5 is protected by a protective tube 5a. It projects into the gasification chamber 1 in a protected state. Note that this configuration is the same as in the case of a conventionally known spouted bed coal gasification furnace and will not be described in detail.

In this embodiment, the slag tap member 3
Further, it differs from the conventional one in that the protective tube 5a of the thermocouple is made of Ir. Also in this jet bed coal gasification furnace, as in the conventional one, the coal and the gasifying agent supplied from the burner are jetted while being accompanied by the gasification reaction and sent from the gas outlet 2 to the downstream equipment, The ash content of the slag is converted to molten slag and flows down to the slag cooling chamber 6 through the portion of the slag tap member 3. On the other hand, the temperature detected by the thermocouple 5 is used for monitoring the temperature in the gasification chamber, determining the slag flowability, and the like.

In the above embodiment, the thermocouple protection tube 5a
Also, since the members constituting the slag tap member 3 are made of Ir and substantial wear does not occur in the high temperature and highly corrosive environment inside the gasification chamber 1, the temperature measurement by the thermocouple 5 is stably performed for a long time. Therefore, it is possible to appropriately monitor and control the reaction in the gasification chamber 1. Also,
Since the cooling for extending the life of the slag tap member 3 is not required unlike the conventional case, the clogging trouble of the slag tap is remarkably reduced, the operation of the coal gasifier is facilitated, and the continuous operation is maintained for a long time. Obstacles are removed.

In the above embodiment, all the members constituting the thermocouple protection tube 5a and the slag tap member 3 are made of Ir, but the thermocouple protection tube 5a and the slag tap member 3 are exposed to the gasification chamber environment. Ir only the part to be
It may be manufactured, or the part may be covered with a covering material made of Ir. The latter case will be described with reference to FIG. 2, in which a different type of spouted bed coal gasification furnace is applied.

The jet-bed coal gasification furnace shown in FIG. 2 has a gas return port (referred to as a gas tap member) 3b in addition to a slag tap member 3a in the hearth, and a mixed fluid of coal and a gasifying agent swirls. Burners 4a and 4b that eject as if to
Are arranged in two stages in the height direction of the gasification chamber, the upper burner 4a of the burners is above ½ in the height direction of the gasification chamber, and the lower burner 4b is 1 in the height direction of the gasification chamber. / 2 as a means for detecting the temperature in the gasification chamber by making the swirl circle diameter of the mixed fluid ejected from the upper burner larger than the swirl circle diameter of the mixed fluid ejected from the lower burner. The thermocouple 5 is arranged between the upper burner 4a and the lower burner 4b. And
In this embodiment, the slag tap member 3a and the gas tap member 3b are made of refractory bricks, and the thermocouple protection tube 5a is made of a ceramic member.

In this embodiment, the thermocouple protection tube 5
a, the thickness of the refractory brick slag tap member 3a and the gas tap member 3b that is exposed to the environment in the gasification chamber is 1
Caps 7, 8 and 9 made of ~ 2 mm Ir sheet
The coal gasification furnace is covered by. Under the configuration of this embodiment, the coal gasification reaction proceeds while the mixed fluid of coal and the gasifying agent supplied from the upper and lower burners 4a and 4b forms a swirling downward flow. Part of the high-temperature gas forms a gas flow system from the slag tap member 3a to the slag cooling chamber 6 and from the slag cooling chamber 6 to the gas tap member 3b and back to the gasification chamber, whereby the slag tap is heated and the molten coal slag Easier to discharge. The gasified gas is finally sent from the gas outlet 2 to the downstream equipment.

As a result of applying this embodiment to a coal gasification plant under operational research, the life of the ceramic thermocouple protection tube 5a was about 20 hours in the past, but the life of the Ir cap 7 was at least 100 hours or more. Was still healthy after being prolonged by. Further, the caps 8 and 9 of the refractory brick slag tap and the gas tap member have no apparent wear due to high-temperature gas / slag, and the remarkable effect that the wear of the refractory brick slag tap members 3a and 3b does not occur. Was confirmed.

FIG. 3 is a partial conceptual view of a coal gasification furnace showing still another embodiment of the present invention, in which the gas outlet 2 and the gas outlet 2 in the upper part of the gasification chamber 1 in the coal gasification furnace shown in FIG. The gas flow pipe portion 21 on the downstream side is lined with an Ir-made member 11, and the liner 11 is somewhat extended from the gas outlet 2 into the coal gasification chamber 1. Is. Reference numeral 10 denotes a gas cooling means, which causes water (steam) or the generated gas after heat exchange to be ejected to the gas flow path piping portion 21.

According to the present embodiment, compared with the case where the gas outlet port 2 and the gas passage pipe portion 21 on the downstream side thereof are made of a material such as a refractory lining, the life is extended and the gas is accompanied. There is an effect that the scattered slag is unlikely to adhere to the flow path system and the flow path is unlikely to be blocked. It should be noted that the above examples are just some examples of the coal gasification furnace according to the present invention, and there are many other modified examples. For example, in the coal gasification furnace of the type shown in FIG. 1 or 3, the thermocouple protection tube 5a and the slag tap member 3 are made of ceramic or refractory brick, respectively, and the portion exposed to the environment in the gasification chamber is shown in FIG. In the case of applying the cap made of the Ir thin plate described in 1 above to cover, and also when applying the configuration having the Ir lining 11 described in FIG. 3 to the coal gasification furnace of the type shown in FIG. It will be readily understood that the objects of the invention can be achieved. Also,
As described above, it will be easily understood that the object can be achieved even if the alloy is not substantially made of Ir but made of an Ir alloy satisfying certain conditions.

[0038]

EFFECTS OF THE INVENTION According to the present invention, the durability and service life of the members placed in the atmosphere in the coal gasification furnace, for example, the main constituent members in the gasification chamber such as the thermocouple protection tube and the slag tap member are remarkable. As a result, it is possible to accurately grasp the gasification reaction status in the gasification chamber such as the slag flow-down status and reflect it in the optimal control of the coal gasification furnace. In addition, since a non-cooling type (in other words, adiabatic type) slag tap can be configured, the clogging of the slag discharge hole due to the cooling and solidification of the slag is reduced, and the excessive temperature rise in the gasification chamber becomes unnecessary. As a result, it is expected that the coal gasification furnace will operate stably over a long period of time, such as the improvement of the gasification efficiency, and that one operation life or one operation time can be remarkably extended.

[Brief description of drawings]

FIG. 1 is a partial conceptual view showing an embodiment of a spouted bed coal gasification furnace according to the present invention.

FIG. 2 is a partial conceptual diagram showing another embodiment of the spouted bed coal gasification furnace according to the present invention.

FIG. 3 is a partial conceptual view showing still another embodiment of the spouted bed coal gasification furnace according to the present invention.

[Explanation of symbols]

1 ... Gasification chamber, 2 ... Gas outlet, 3 ... Slag tap, 4 ... Burner, 5 ... Thermocouple, 5a ... Thermocouple protection tube, 6
… Slag cooling room

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Shigeyoshi Nakamura Inventor Shigayoshi, Ichiro, Hitachi City, Omika Town, 7-1, 1-1 Hitachi Research Laboratory, Hitachi, Ltd. (72) Inventor, Hiroshi Fukui 7-1, Omika-cho, Hitachi City Hitachi Ltd. Hitachi Research Laboratory (72) Inventor Eiji Kida 6-9 Takaracho, Kure-shi, Hiroshima Prefecture Babcock Hiritsu Co., Ltd. Kure Factory (72) Inventor Shuichi Matsuoka 3-chome, Nakasode, Sodegaura-shi, Chiba

Claims (5)

(57) [Claims] 1. A coal gasification furnace in which coal and a gasifying agent such as oxygen are reacted at a high temperature to melt and slag the ash of the coal and discharge it to the outside of the gasification chamber, which is exposed to the environment of the gasification chamber. A coal gasification furnace, characterized in that all or part of the members constituting the part are substantially covered with Ir or Ir. 2. In a coal gasification furnace of a system in which coal and a gasifying agent such as oxygen are reacted at a high temperature to melt and slag the ash content of the coal and discharge it to the outside of the gasification chamber, exposed to the environment of the gasification chamber. A coal gasification furnace, characterized in that all or a part of the members formed in the part is made of an Ir alloy having a melting point equal to or higher than the atmospheric temperature in the coal gasification furnace or coated with the alloy. 3. The Ir alloy is an Ir—Rh alloy, Ir
3. The coal gasification furnace according to claim 2, which is a -Re alloy or an Ir-Pt alloy, the melting point of which is equal to or higher than the atmospheric temperature in the coal gasification furnace. 4. The Ir—Pt alloy is of a composition having a melting point of 2000 ° C. or higher.
The described coal gasifier. 5. A member formed in a portion exposed to the environment of the gasification chamber is an opening member of the gasification chamber for circulating gas or molten slag, or a thermocouple protection installed inside the gasification chamber. The coal gasification furnace according to any one of claims 1 to 4, which is a pipe member.