JP2504525B2 - Grinding wheel for grinding aluminum materials - Google Patents

Grinding wheel for grinding aluminum materials

Info

Publication number
JP2504525B2
JP2504525B2 JP63161781A JP16178188A JP2504525B2 JP 2504525 B2 JP2504525 B2 JP 2504525B2 JP 63161781 A JP63161781 A JP 63161781A JP 16178188 A JP16178188 A JP 16178188A JP 2504525 B2 JP2504525 B2 JP 2504525B2
Authority
JP
Japan
Prior art keywords
grindstone
polishing
specific gravity
grinding
bulk specific
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP63161781A
Other languages
Japanese (ja)
Other versions
JPH029587A (en
Inventor
憲治 根尾
尚躬 川島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP63161781A priority Critical patent/JP2504525B2/en
Publication of JPH029587A publication Critical patent/JPH029587A/en
Application granted granted Critical
Publication of JP2504525B2 publication Critical patent/JP2504525B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は磁気ディスク用アルミニウム合金円板の研磨
加工に使用するのに好適であって、平坦度、微小変位、
板厚精度、粗度及び研磨模様の均一性等が優れたアルミ
ニウム材を得ることができるアルミニウム材研削用砥石
に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention is suitable for use in polishing an aluminum alloy disc for a magnetic disk, and has flatness, small displacement,
The present invention relates to a grindstone for grinding an aluminum material, which is capable of obtaining an aluminum material excellent in plate thickness accuracy, roughness and uniformity of polishing pattern.

[従来の技術] アルミニウム合金製磁気ディスク基盤であるグランド
サブストレートの製造工程においては、従来、ウレタン
系砥石をリング状に加工して、この1対の砥石でアルミ
ニウム合金円板をその両側から挾み込み、砥石を高速回
転させてアルミニウム合金円板を研磨している。
[Prior Art] In the manufacturing process of a ground substrate that is an aluminum alloy magnetic disk substrate, conventionally, a urethane-based grindstone is processed into a ring shape, and an aluminum alloy disc is sandwiched from both sides by this pair of grindstones. The aluminum alloy disc is polished by digging and rotating the grindstone at high speed.

而して、近時、3.5インチ又は5インチの小径ディス
クの需要が増大してきたが、それに伴い生産性が重視さ
れるようになると共に、品質の更に一層の向上が要望さ
れるようになってきた。
Therefore, recently, the demand for small diameter discs of 3.5 inches or 5 inches has increased, but along with this, the importance of productivity has come to a great extent and further improvement of quality has been demanded. It was

そこで、第6図に示すように、両面ラップ方式の研磨
装置が使用されるようになってきた。この研磨装置にお
いては、上定盤4及び下定盤7が夫々その中央にて垂直
軸5,8に固定されており、上定盤4及び下定盤7の対向
面には夫々上砥石3及び下砥石6が取付けられている。
そして、数十枚のディスク用アルミニウム合金円板1を
保持板2により一平面上に保持させた状態で、これらを
上砥石3と下砥石6との間に配置し、上砥石3と下砥石
6との間でディスク1を挾み込む。次いで、回転軸5,8
を回転駆動して砥石3,6を回転させ、複数枚のディスク
1の両面を同時に研磨加工する。
Therefore, as shown in FIG. 6, a double side lapping type polishing apparatus has come to be used. In this polishing apparatus, the upper surface plate 4 and the lower surface plate 7 are fixed to the vertical shafts 5 and 8 at the centers thereof, and the upper grindstone 3 and the lower surface plate 7 are provided on the facing surfaces of the upper surface plate 4 and the lower surface plate 7, respectively. The grindstone 6 is attached.
Then, while holding several tens of aluminum alloy discs 1 for discs on one plane by the holding plate 2, these are arranged between the upper grindstone 3 and the lower grindstone 6, and the upper grindstone 3 and the lower grindstone. The disc 1 is inserted between 6 and. Then the rotary shaft 5,8
Is rotated to rotate the grindstones 3 and 6, and both surfaces of the plurality of disks 1 are simultaneously polished.

ところで、この方法においては、砥石3,6を低速回転
させて、ディスク1を研磨するため、脆化しやすいウレ
タン系砥石は使用することができず、主としてPVA(ポ
リビニルアルコール)系砥石が使用されている。
By the way, in this method, since the grindstones 3 and 6 are rotated at a low speed to grind the disk 1, it is not possible to use a urethane grindstone that is easily embrittled, and a PVA (polyvinyl alcohol) grindstone is mainly used. There is.

[発明が解決しようとする課題] しかしながら、PVA系砥石は砥石の形状、研磨液の種
類及び量、並びに研磨圧力等の研磨機の条件を一定にし
ても、研磨品質上のバラツキが大きく、安定した品質の
ディスクを量産することが困難である。
[Problems to be Solved by the Invention] However, even if the conditions of the polishing machine such as the shape of the grinding stone, the type and amount of the polishing liquid, and the polishing pressure are constant, the PVA-based grinding stone has a large variation in polishing quality and is stable. It is difficult to mass produce discs of the desired quality.

つまり、PVA系砥石の特性としては、砥粒の種類(通
常、結合剤との相性が良いSiCが使用される)、砥石粒
度、砥石組成(砥粒率、結合剤率、気孔率)、硬度、及
び膨潤度等があるが、これらの各特性がディスク1の素
材であるアルミニウム−マグネシウム(Al−Mg)合金等
の研磨品質に与える影響については未だ解明されておら
ず、砥石の製造ロットによるディスクの品質上のバラツ
キが大きいという難点がある。このため、高品質のディ
スクを安定して量産することができない。
In other words, the characteristics of PVA-based grindstones include the type of abrasive grains (usually SiC, which has a good compatibility with the binder), the grain size of the stone, the composition of the stone (abrasive grain ratio, binder ratio, porosity), hardness , And the degree of swelling, etc., but the effect of each of these characteristics on the polishing quality of the aluminum-magnesium (Al-Mg) alloy, which is the material of the disk 1, has not yet been clarified, and it depends on the manufacturing lot of the grindstone. The problem is that the quality of the discs varies greatly. Therefore, high quality discs cannot be stably mass-produced.

本発明はかかる問題点に鑑みてなされたものであっ
て、安定して優れた研磨特性が得られ、砥石のドレッシ
ング回数を低減して研磨効率を向上させることができる
アルミニウム材研削用砥石を提供することを目的とす
る。
The present invention has been made in view of such problems, and provides a grindstone for grinding aluminum material, which can stably obtain excellent polishing characteristics, reduce the number of dressing of the grindstone, and improve the polishing efficiency. The purpose is to do.

[課題を解決するための手段] 本発明に係るアルミニウム材研削用砥石は、砥粒率が
6乃至12容量%、結合剤率が12乃至18容量%及び気孔率
が70乃至82容量%のPVA系砥石を複数個定盤に取り付
け、前記砥石はロックウエル硬度が−180乃至−250、膨
潤度が0.8乃至2.0%、かさ比重が0.465乃至0.485であ
り、前記複数個の砥石のうち、ロックウエル硬度の数値
が最大値をとる砥石と、ロックウエル硬度の数値が最小
値をとる砥石とのロックウエル硬度の差が60以下、かさ
比重の数値が最大値をとる砥石と、かさ比重の数値が最
小値をとる砥石とのかさ比重の差が0.03以下であること
を特徴とする。
[Means for Solving the Problems] The grinding wheel for grinding aluminum material according to the present invention is a PVA having an abrasive grain ratio of 6 to 12% by volume, a binder rate of 12 to 18% by volume, and a porosity of 70 to 82% by volume. A plurality of system grindstones are attached to the surface plate, the grindstone has a Rockwell hardness of -180 to -250, a swelling degree of 0.8 to 2.0%, and a bulk specific gravity of 0.465 to 0.485. The difference in the Rockwell hardness between the whetstone with the maximum value and the whetstone with the minimum Rockwell hardness value is 60 or less, and the whetstone with the maximum bulk specific gravity value is the minimum value, and the bulk specific gravity value is the minimum value. The difference in bulk specific gravity from the grindstone is 0.03 or less.

[作用] 本願発明者等は、一般的に最終仕上として使用される
2000番以上のPVA系砥石の特性値と、研磨によって得ら
れたディスクの表面品質との対応関係について実験研究
した結果、砥粒率、結合剤率、気孔率、硬度、一研磨面
内の硬度のバラツキ、膨潤度、かさ比重及び1セット内
のかさ比重のバラツキが夫々上記数値範囲内にある場合
に、ディスクの構成材料であるアルミニウム合金を安定
して高品質で研磨することができることを見い出した。
つまり、上記数値範囲のPVA系砥石を使用することによ
り、平坦度、微小変位、板厚精度、粗度及び研磨模様の
均一性等の研磨品質がいずれも優れたアルミニウム合金
板を安定して製造することができ、また、砥石のドレッ
シング回数が減少して生産性が向上すると共に、ディス
ク検査工程における歩留を上昇させることができる。
[Operation] The present inventors are generally used as a final finish.
As a result of experimental research on the correspondence between the characteristic values of PVA-based grindstones of 2000 or more and the surface quality of the disk obtained by polishing, the abrasive grain ratio, the binder ratio, the porosity, the hardness, the hardness within one polished surface It has been found that the aluminum alloy, which is a constituent material of the disk, can be stably and high quality polished when the dispersion of the disc, the swelling degree, the bulk specific gravity, and the variation of the bulk specific gravity within one set are within the above numerical ranges, respectively. It was
That is, by using a PVA-based grindstone in the above numerical range, it is possible to stably manufacture an aluminum alloy plate having excellent polishing quality such as flatness, minute displacement, plate thickness accuracy, roughness and uniformity of polishing pattern. In addition, the number of times of dressing the grindstone is reduced to improve the productivity, and the yield in the disc inspection process can be increased.

[実施例] 以下、本発明について更に具体的に説明する。[Examples] Hereinafter, the present invention will be described more specifically.

先ず、PVA系砥石の各特性と研磨品質との関係につい
て説明する。
First, the relationship between each characteristic of the PVA type grindstone and the polishing quality will be described.

砥石組成 PVA系砥石は、第5図に示すように、砥粒11、結合剤1
2及び気孔13で構成されており、これらの比率が研磨速
度及び研磨品質に影響を与える。
Whetstone composition PVA-based whetstone has abrasive grains 11 and binder 1 as shown in FIG.
2 and pores 13, the ratio of which affects the polishing rate and the polishing quality.

この場合に、両面ラップ方式においては、脱落砥粒及
び研削屑が一時的に気孔13内に保持されるので、研磨速
度及び研磨品質に及ぼす気孔率の影響が極めて大きい。
このため、気孔率がある程度高いことが必要であり、少
なくとも、70容量%以上の気孔率を確保する必要があ
る。
In this case, in the double-sided lapping method, the fallen abrasive grains and grinding debris are temporarily held in the pores 13, so that the effect of porosity on the polishing rate and the polishing quality is extremely large.
Therefore, it is necessary that the porosity is high to some extent, and it is necessary to secure the porosity of at least 70% by volume or more.

しかしながら、気孔13が多すぎて砥粒率及び結合剤率
が低くなりすぎても研磨速度が遅くなり、平坦度も悪化
する。この研磨速度及び平坦度を望ましいものにするた
め、砥粒率は6容量%以上、結合剤率は12容量%以上に
する。従って、気孔率は82容量%以下になる。また、気
孔率が70容量%以上であるから、砥粒率及び結合剤率は
総計で30容量%以下になる。そして、砥粒11と結合剤12
とは砥粒:結合剤=1:1.5〜2.0のように配合すべきであ
るから、砥粒率及び結合剤率は夫々12容量%以下及び18
容量%以下となる。
However, even if the number of pores 13 is too large and the abrasive grain ratio and the binder ratio are too low, the polishing rate becomes slow and the flatness also deteriorates. In order to obtain the desired polishing rate and flatness, the abrasive grain ratio is 6% by volume or more and the binder ratio is 12% by volume or more. Therefore, the porosity is 82% by volume or less. Further, since the porosity is 70% by volume or more, the total rate of the abrasive grains and the binder is 30% by volume or less. Then, the abrasive grains 11 and the binder 12
Should be compounded as follows: abrasive grain: binder = 1: 1.5 to 2.0, so the abrasive grain ratio and the binder ratio are 12% by volume or less and 18% respectively.
It will be less than the capacity%.

なお、砥石の粒度が細かくなるにつれて、即ち、番手
が高くなるにつれて、結合剤率を低くして気孔率を高め
る方が研磨速度上及び研磨品質上好ましい傾向になる。
It should be noted that as the grain size of the grindstone becomes finer, that is, as the count becomes higher, it tends to be preferable from the viewpoint of polishing rate and polishing quality to lower the binder ratio and increase the porosity.

硬度 硬度は砥石組成によって変化する。硬度が高く硬い
と、被研磨物のアルミニウム合金円板に砥粒による疵が
入り易く、逆に硬度が低く軟らかいと、研磨速度が遅く
研磨模様がきれいには揃いにくい。このため、最も適切
な硬度範囲はロックウエル硬度(スーパーフィッシャル
15Y)で−180乃至−250である。
Hardness Hardness changes with the composition of the grindstone. If the hardness is high and hard, the aluminum alloy disc to be polished is likely to be flawed by the abrasive grains. Conversely, if the hardness is low and the hardness is soft, the polishing rate is slow and the polishing pattern is not easily aligned. For this reason, the most suitable hardness range is Rockwell hardness (superficial
15Y) is -180 to -250.

第1図は横軸に硬度をとり、縦軸に砥石寿命をとって
両者の関係を示すグラフ図である。
FIG. 1 is a graph showing the relationship between the hardness of the abscissa and the life of the grindstone on the ordinate.

但し、砥石寿命は研磨及びドレッシングによって砥石
の厚さが減少していく場合の使用開始から研磨不能とな
るまでの研磨回数である。この場合に、1回の研磨代は
常に一定である。また、ドレッシングは、目詰まり等の
原因により所定の研磨代を得るために所定時間以上かか
るとき、又は砥粒による引っかき疵若しくは研磨模様の
不揃い等の表面品質上の欠陥が発生したときに行った。
However, the life of the grindstone is the number of times of polishing from the start of use until the grinding becomes impossible when the thickness of the grindstone is reduced by polishing and dressing. In this case, one polishing allowance is always constant. Further, dressing was performed when it took more than a predetermined time to obtain a predetermined polishing allowance due to a cause such as clogging, or when a defect in surface quality such as scratches due to abrasive grains or uneven polishing pattern occurred. .

この第1図から明らかなように、本発明のように、硬
度が−180以上であると、砥石寿命がそのバラツキを考
慮しても1000回以上に長くなる。
As is apparent from FIG. 1, when the hardness is −180 or more as in the present invention, the life of the grindstone becomes 1000 times or more even if the variation is taken into consideration.

また、両面ラップ方式では、最大約1m強の直径の定盤
に多数の砥石を張り付けるが、この場合に、各砥石につ
いて硬度のバラツキが大きいと、研磨面がマダラ模様と
なり、微小な変位が発生する。このため、一つの研磨面
内における硬度のバラツキを60以下にする。
Also, in the double-sided lapping method, a large number of grindstones are attached to a surface plate having a diameter of up to about 1 m, but in this case, if the hardness of each grindstone is large, the polishing surface becomes a coddle pattern, and minute displacement occurs. appear. Therefore, the variation in hardness within one polishing surface is set to 60 or less.

第2図は横軸の硬度のバラツキをとり、縦軸に砥石寿
命をとって両者の関係を示すグラフ図である。この図か
ら明らかなように、硬度のバラツキが60以下である場合
に、砥石寿命は1000回以上になる。
FIG. 2 is a graph showing the relationship between the hardness on the horizontal axis and the life of the grindstone on the vertical axis. As is clear from this figure, when the hardness variation is 60 or less, the life of the grindstone is 1000 times or more.

膨潤度 PVA系砥石の結合剤の一成分であるポリビニルアルコ
ールは、膨潤する性質を有する。通常、この膨潤する性
質をメラミン樹脂を添加することによって抑制してい
る。この膨潤度が大きい場合は、砥石中の水分量の僅か
の変化によって砥石の平面度が変化し、延いてはディス
クの平坦度も変化させる。逆に、膨潤度を抑制するため
に、メラミンの比率を多くすると、他の特性を劣化させ
るので、適度の膨潤性が必要である。このような理由で
膨潤度を0.8乃至2.0%にする。
Swelling degree Polyvinyl alcohol, which is a component of the PVA-based grindstone binder, has the property of swelling. Usually, this swelling property is suppressed by adding a melamine resin. When the degree of swelling is large, the flatness of the grindstone changes due to a slight change in the amount of water in the grindstone, which in turn changes the flatness of the disk. On the contrary, if the proportion of melamine is increased in order to suppress the degree of swelling, other properties are deteriorated, and therefore, appropriate swelling property is required. For this reason, the degree of swelling is 0.8 to 2.0%.

かさ比重 上述の各特性は相互に独立したものではなく、互いに
相関関数を有するものであると共に、砥石製造工程にお
ける熱処理条件によっても変化するものである。而し
て、本願発明者等はこれらの特性の相違が最終的に砥石
のかさ比重の変化に現れることを見い出した。このかさ
比重は、種々の実験研究の結果及び操業上の実績等を考
慮すると、本願発明の目的を達成するためには、0.465
乃至0.485にする必要がある。
Bulk Specific Gravity The above-mentioned characteristics are not independent of each other but have a correlation function with each other, and also change depending on heat treatment conditions in the grindstone manufacturing process. Then, the inventors of the present application found that the difference in these characteristics finally appears in the change in the bulk specific gravity of the grindstone. This bulk specific gravity is 0.465 in order to achieve the object of the present invention in consideration of the results of various experimental studies and operational results.
It is necessary to set to 0.485.

第3図は横軸にかさ比重をとり、縦軸に砥石寿命をと
って両者の関係を示すグラフ図である。この第3図から
明らかなように、かさ比重が0.465乃至0.485である場合
に、砥石寿命は略々1000回以上になる。
FIG. 3 is a graph showing the relationship between the two by taking the bulk specific gravity on the horizontal axis and the grindstone life on the vertical axis. As is clear from FIG. 3, when the bulk specific gravity is 0.465 to 0.485, the life of the grindstone is approximately 1000 times or more.

また、砥石は通常ラップ盤定盤に数十枚貼り付けて使
用するが、この1定盤内のかさ比重のバラツキは0.03以
下にすることが必要である。第4図は横軸にかさ比重の
バラツキをとり、縦軸に砥石寿命をとって両者の関係を
示すグラフ図である。この第4図から明らかなように、
かさ比重のバラツキが0.03以下の場合に、砥石寿命が略
々1000回以上になる。
Further, dozens of grindstones are usually attached to a lapping plate and used, but it is necessary that the variation of the bulk specific gravity in this one plate is 0.03 or less. FIG. 4 is a graph showing the relationship between the two, where the horizontal axis represents the variation of the bulk specific gravity and the vertical axis represents the life of the grindstone. As is clear from FIG. 4,
When the variation in bulk specific gravity is 0.03 or less, the grindstone life is approximately 1000 times or more.

[発明の効果] 本発明によれば、PVA系砥石により表面品質が優れた
アルミニウム材を安定して得ることができ、研磨性能の
向上により砥石のドレッシング回数を低減することがで
きる。このため、生産性が向上し、ディスク検査におけ
る歩留を著しく高めることができる。
[Effect of the Invention] According to the present invention, an aluminum material having excellent surface quality can be stably obtained by the PVA-based grindstone, and the number of dressing times of the grindstone can be reduced by improving the polishing performance. Therefore, the productivity is improved and the yield in the disc inspection can be remarkably increased.

【図面の簡単な説明】[Brief description of drawings]

第1図乃至第4図は種々の砥石特性と砥石寿命との関係
を示すグラフ図であり、第1図は硬度との関係、第2図
は面内硬度バラツキとの関係、第3図はかさ比重との関
係、第4図は1セット内かさ比重のバラツキとの関係を
示すグラフ図、第5図はPVA系砥石の構造を示す断面
図、第6図は両面研磨装置を示す断面図である。 1;ディスク、3;上砥石、4;上定盤、6;下砥石、7;下定
盤、11;砥粒、12;結合剤、13;気孔
1 to 4 are graphs showing the relationship between various grinding wheel characteristics and grinding wheel life. FIG. 1 shows the relationship with hardness, FIG. 2 shows the relationship with in-plane hardness variation, and FIG. 3 shows Fig. 4 is a graph showing the relationship with bulk specific gravity, Fig. 4 is a graph showing the relationship with variation in bulk specific gravity within one set, Fig. 5 is a sectional view showing the structure of a PVA-based grindstone, and Fig. 6 is a sectional view showing a double-side polishing machine. Is. 1; disk, 3; upper grindstone, 4; upper grindstone, 6; lower grindstone, 7; lower grindstone, 11; abrasive grains, 12; binder, 13; pores

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】砥粒率が6乃至12容量%、結合剤率が12乃
至18容量%及び気孔率が70乃至82容量%のPVA系砥石を
複数個定盤に取り付け、前記砥石はロックウエル硬度が
−180乃至−250、膨潤度が0.8乃至2.0%、かさ比重が0.
465乃至0.485であり、前記複数個の砥石のうち、ロック
ウエル硬度の数値が最大値をとる砥石と、ロックウエル
硬度の数値が最小値をとる砥石とのロックウエル硬度の
差が60以下、かさ比重の数値が最大値をとる砥石と、か
さ比重の数値が最小値をとる砥石とのかさ比重の差が0.
03以下であることを特徴とするアルミニウム材研削用砥
石。
1. A plurality of PVA-based grindstones having an abrasive grain ratio of 6 to 12% by volume, a binder ratio of 12 to 18% by volume, and a porosity of 70 to 82% by volume are mounted on a surface plate, the stones having Rockwell hardness. Is -180 to -250, swelling degree is 0.8 to 2.0%, and bulk specific gravity is 0.
465 to 0.485, among the plurality of whetstones, a stone having a maximum Rockwell hardness value, and a stone having a minimum Rockwell hardness value having a Rockwell hardness difference of 60 or less, a value of bulk specific gravity The difference in bulk specific gravity between the whetstone with maximum value and the whetstone with minimum numerical value is 0.
A grindstone for grinding aluminum materials, characterized by being 03 or less.
JP63161781A 1988-06-29 1988-06-29 Grinding wheel for grinding aluminum materials Expired - Fee Related JP2504525B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63161781A JP2504525B2 (en) 1988-06-29 1988-06-29 Grinding wheel for grinding aluminum materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63161781A JP2504525B2 (en) 1988-06-29 1988-06-29 Grinding wheel for grinding aluminum materials

Publications (2)

Publication Number Publication Date
JPH029587A JPH029587A (en) 1990-01-12
JP2504525B2 true JP2504525B2 (en) 1996-06-05

Family

ID=15741786

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63161781A Expired - Fee Related JP2504525B2 (en) 1988-06-29 1988-06-29 Grinding wheel for grinding aluminum materials

Country Status (1)

Country Link
JP (1) JP2504525B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2694705B2 (en) * 1991-02-08 1997-12-24 鐘紡株式会社 Synthetic grindstone for high-purity aluminum substrate polishing
US6437280B1 (en) * 1999-12-03 2002-08-20 Printronix, Inc. Printer hammer tip and method for making

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61192480A (en) * 1985-02-22 1986-08-27 Kanebo Ltd Synthetic grinding stone for soft metal

Also Published As

Publication number Publication date
JPH029587A (en) 1990-01-12

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