JP2024523384A - 高温の化学プロセスのための触媒の製造方法及び得られる触媒 - Google Patents

高温の化学プロセスのための触媒の製造方法及び得られる触媒 Download PDF

Info

Publication number
JP2024523384A
JP2024523384A JP2023577782A JP2023577782A JP2024523384A JP 2024523384 A JP2024523384 A JP 2024523384A JP 2023577782 A JP2023577782 A JP 2023577782A JP 2023577782 A JP2023577782 A JP 2023577782A JP 2024523384 A JP2024523384 A JP 2024523384A
Authority
JP
Japan
Prior art keywords
support
transition metal
solution
organometallic compound
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2023577782A
Other languages
English (en)
Japanese (ja)
Other versions
JP2024523384A5 (https=
Inventor
エウジェーニオ リッカルド バシーニ,ルカ
イカニエッロ,ガエターノ
サッラディーニ,アンナリタ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NextChem SpA
Original Assignee
NextChem Tech SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NextChem Tech SpA filed Critical NextChem Tech SpA
Publication of JP2024523384A publication Critical patent/JP2024523384A/ja
Publication of JP2024523384A5 publication Critical patent/JP2024523384A5/ja
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/464Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/468Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892Nickel and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0213Preparation of the impregnating solution
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1023Catalysts in the form of a monolith or honeycomb
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
JP2023577782A 2021-06-14 2022-06-14 高温の化学プロセスのための触媒の製造方法及び得られる触媒 Pending JP2024523384A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT102021000015473 2021-06-14
IT102021000015473A IT202100015473A1 (it) 2021-06-14 2021-06-14 Metodo di produzione di catalizzatori per processi chimici ad alta temperatura e catalizzatori cosi' ottenuti
PCT/EP2022/066105 WO2022263409A1 (en) 2021-06-14 2022-06-14 Method for producing catalysts for high temperature chemical processes and catalysts thus obtained.

Publications (2)

Publication Number Publication Date
JP2024523384A true JP2024523384A (ja) 2024-06-28
JP2024523384A5 JP2024523384A5 (https=) 2025-05-23

Family

ID=79018675

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2023577782A Pending JP2024523384A (ja) 2021-06-14 2022-06-14 高温の化学プロセスのための触媒の製造方法及び得られる触媒

Country Status (9)

Country Link
US (1) US20240286115A1 (https=)
EP (1) EP4355480A1 (https=)
JP (1) JP2024523384A (https=)
KR (1) KR20240037945A (https=)
AU (1) AU2022293970A1 (https=)
BR (1) BR112023026438A2 (https=)
CA (1) CA3223343A1 (https=)
IT (1) IT202100015473A1 (https=)
WO (1) WO2022263409A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024165142A1 (en) * 2023-02-07 2024-08-15 NextChem S.p.A. Process of direct reduction of iron ores by means of synthesis gas produced with catalytic partial oxidation
WO2024245538A1 (en) 2023-05-30 2024-12-05 Nextchem Tech S.P.A. Process for the production of synthetic hydrocarbons compounds by utilizing carbon dioxide-rich feedstock
WO2024245540A1 (en) * 2023-05-30 2024-12-05 Nextchem Tech S.P.A. Process for the production of carboxylic acids and carbonyl compounds by utilizing carbon dioxide-rich feedstock
WO2025021301A1 (en) 2023-07-26 2025-01-30 NextChem S.p.A. Improved process for the smelting reduction of iron ores
US20250333301A1 (en) * 2024-04-29 2025-10-30 Saudi Arabian Oil Company Methods of producing hydrogen

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050211604A1 (en) * 2002-05-24 2005-09-29 Snamprogetti S.P.A. Process for catalytic partial oxidation reactions
JP2007090241A (ja) * 2005-09-29 2007-04-12 Toshiba Corp 燃料電池システム用触媒構造体および燃料電池システム
US20070105962A1 (en) * 2003-09-11 2007-05-10 Eni S.P.A. Catalytic partial oxidation process for producing synthesis gas
JP2008132458A (ja) * 2006-11-29 2008-06-12 Nippon Steel Corp 炭素質原料の熱分解タールを改質してガス化するタールガス化用触媒、タールガス化方法、タールガス化ガスの利用方法、及びタールガス化用触媒の再生方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1238676B (it) 1990-01-26 1993-09-01 Snam Progetti Sistema catalitico e procedimento per la produzione di gas di sintesi mediante reazione di reforming di idrocarubri leggeri con co2
IT1272532B (it) 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
IT1273491B (it) 1995-02-03 1997-07-08 Snam Progetti Materiale avente struttura a strati tipo idrotalcite e relativi usi
IT1283585B1 (it) 1996-04-11 1998-04-22 Snam Progetti Apparecchiatura per effettuare reazioni di ossidazione parziale
DE69808521T2 (de) 1998-07-21 2003-01-30 Haldor Topsoee A/S, Lyngby Synthesegasherstellung durch dampfreformierung
US20060024347A1 (en) 2004-02-10 2006-02-02 Biosurface Engineering Technologies, Inc. Bioactive peptide coatings
ITMI20041860A1 (it) 2004-09-30 2004-12-30 Eni Spa Apparecchiatura per nebulizzare una corrente liquida con una corrente disperdente gassosa e miscelare il prodotto nebulizzato con un'ulteriore corrente gassosa adatta in apparecchiature per effettuare ossidazioni parziali catalitiche e relativo proce
ITMI20052002A1 (it) 2005-10-21 2007-04-22 Eni Spa Dispositivo per miscelare fluidi inserito o combinato ad un reattore
ITMI20072209A1 (it) 2007-11-21 2009-05-22 Eni Spa Procedimento migliorato per la produzione di gas di sintesi a partire da idrocarburi ossigenati ricavati da biomasse
ITMI20072228A1 (it) 2007-11-23 2009-05-24 Eni Spa Procedimento per produrre gas di sintesi e idrogeno a partire da idrocarburi liquidi e gassosi
IT1398292B1 (it) 2009-12-16 2013-02-22 Eni Spa Processo per la produzione di idrogeno a partire da idrocarburi liquidi, idrocarburi gassosi e/o composti ossigenati anche derivanti da biomasse
IT1400492B1 (it) 2010-06-03 2013-06-11 Eni Spa Sistema catalitico per processi di ossidazione parziale catalitica a basso tempo di contatto
WO2016016253A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated short contact time catalytic partial oxidation/gas heated reforming process for the production of synthesis gas
WO2016016256A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/atr process for the production of synthesis gas
WO2016016257A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/pox process for producing synthesis gas
WO2016016251A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/sr process for producing synthesis gas

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050211604A1 (en) * 2002-05-24 2005-09-29 Snamprogetti S.P.A. Process for catalytic partial oxidation reactions
US20070105962A1 (en) * 2003-09-11 2007-05-10 Eni S.P.A. Catalytic partial oxidation process for producing synthesis gas
JP2007090241A (ja) * 2005-09-29 2007-04-12 Toshiba Corp 燃料電池システム用触媒構造体および燃料電池システム
JP2008132458A (ja) * 2006-11-29 2008-06-12 Nippon Steel Corp 炭素質原料の熱分解タールを改質してガス化するタールガス化用触媒、タールガス化方法、タールガス化ガスの利用方法、及びタールガス化用触媒の再生方法

Also Published As

Publication number Publication date
US20240286115A1 (en) 2024-08-29
WO2022263409A1 (en) 2022-12-22
KR20240037945A (ko) 2024-03-22
IT202100015473A1 (it) 2022-12-14
BR112023026438A2 (pt) 2024-03-05
EP4355480A1 (en) 2024-04-24
AU2022293970A1 (en) 2024-01-18
CA3223343A1 (en) 2022-12-22

Similar Documents

Publication Publication Date Title
JP2024523384A (ja) 高温の化学プロセスのための触媒の製造方法及び得られる触媒
Al-Fatesh et al. CO2 reforming of CH4: Effect of Gd as promoter for Ni supported over MCM-41 as catalyst
Tomishige et al. Nickel–iron alloy catalysts for reforming of hydrocarbons: preparation, structure, and catalytic properties
CN105188915B (zh) 碱土金属/金属氧化物负载型催化剂
CN106362735B (zh) 用于蒸汽重整过程的催化剂
Hafizi et al. Calcium promoted Fe/Al2O3 oxygen carrier for hydrogen production via cyclic chemical looping steam methane reforming process
KR101994152B1 (ko) 탄소 침적의 감소를 위해, 금속이온이 치환된 페로브스카이트 금속산화물 촉매 및 이의 제조 방법, 그리고 이를 이용한 메탄 개질 반응 방법
Modafferi et al. Propane reforming on Ni–Ru/GDC catalyst: H2 production for IT-SOFCs under SR and ATR conditions
JP5327323B2 (ja) 炭化水素系ガス改質用触媒、その製造方法、および合成ガスの製造方法
WO2001028678A1 (en) Nickel-rhodium based catalysts and process for preparing synthesis gas
CN113747972A (zh) 钌促催化剂组合物
De Vasconcelos et al. Catalytic transformation of carbon dioxide and methane into syngas over ruthenium and platinum supported hydroxyapatites
Sajjadi et al. Combustion vs. hybrid sol-gel-plasma surface design of coke-resistant Co-promoted Ni-spinel nanocatalyst used in combined reforming of CH4/CO2/O2 for hydrogen production
WO2003039740A1 (en) Combustion deposited metal-metal oxide catalysts and process for producing synthesis gas
WO2004073855A1 (en) Sulfur-tolerant catalysts and related precursors and processes
Ibrahim et al. Influence of promoted 5% Ni/MCM‐41 catalysts on hydrogen yield in CO2 reforming of CH4
Silva et al. Partial oxidation of methane using Pt/CeZrO2/Al2O3 catalysts–effect of preparation methods
KR101432621B1 (ko) 합성가스 제조용 개질 촉매, 이를 이용한 합성가스 제조 방법 및 합성가스 제조 반응기
WO2007029862A1 (ja) 炭化水素の接触部分酸化用の触媒及び合成ガスの製造方法
Chen et al. Low temperature synthesis of metal doped perovskites catalyst for hydrogen production by autothermal reforming of methane
JPWO2020175558A1 (ja) 酸窒素水素化物、酸窒素水素化物を含む金属担持物、及びアンモニア合成用触媒
JP4211900B2 (ja) 金属微粒子担持炭化水素改質用触媒及びその製造方法
Spretz et al. Fe/MgO formulations for the catalytic combustion of methane
Phan et al. Insights on the highly stable and coke-resistant nickel/zirconia nanocatalyst for the methanation of carbon dioxide
KR102092736B1 (ko) 탄소 침적을 감소시킬 수 있는, 금속이온이 치환된 페로브스카이트 금속산화물 촉매의 제조 방법 및 이를 이용한 메탄 개질 반응 방법

Legal Events

Date Code Title Description
A529 Written submission of copy of amendment under article 34 pct

Free format text: JAPANESE INTERMEDIATE CODE: A529

Effective date: 20240213

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20250515

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20250515

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20260305

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20260317