JP2024046026A - Texture improver for minced meat processed foods or meat substitute foods - Google Patents

Texture improver for minced meat processed foods or meat substitute foods Download PDF

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JP2024046026A
JP2024046026A JP2022151164A JP2022151164A JP2024046026A JP 2024046026 A JP2024046026 A JP 2024046026A JP 2022151164 A JP2022151164 A JP 2022151164A JP 2022151164 A JP2022151164 A JP 2022151164A JP 2024046026 A JP2024046026 A JP 2024046026A
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protein
lipid
texture
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mass
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伸介 城島
祐太 小林
隆 鈴木
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Adeka Corp
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Abstract

【課題】挽肉加工食品及び畜肉代替食品のいずれの製造であっても用いることができ、且つ作業性が良好であり、挽肉加工食品等を製造する際の油脂や水分の流出を抑制し、ジューシーな食感を有する食感改良剤を提供すること。【解決手段】本発明は、変性脂質蛋白質複合体を含有する、挽肉加工食品又は畜肉代替食品の食感改良剤及びその製造方法、該食感改良剤を含有する、挽肉加工食品又は畜肉代替食品、並びに該食感改良剤を含有させる、挽肉加工食品又は畜肉代替食品の食感改良方法である。【選択図】なし[Problem] To provide a texture improver that can be used in the production of both processed minced meat foods and meat substitute foods, has good workability, inhibits the outflow of oils and fats and water when producing processed minced meat foods, etc., and has a juicy texture. [Solution] The present invention provides a texture improver for processed minced meat foods or meat substitute foods that contains a denatured lipid protein complex and a method for producing the same, processed minced meat foods or meat substitute foods that contain the texture improver, and a method for improving the texture of processed minced meat foods or meat substitute foods that contain the texture improver. [Selected Figures] None

Description

本発明は、挽肉加工食品又は畜肉代替食品を製造する際に用いられる食感改良剤に関する。 The present invention relates to a texture improver used in producing ground meat processed foods or livestock meat substitute foods.

一般に、牛肉や豚肉、鶏肉等の畜肉に対して、焼成や油ちょう等の加熱処理を施すと、加熱によって畜肉の中の油脂や水分が流出し、ジューシーな食感やコク味が乏しくなる他、蛋白質が加熱変性を受け、硬い食感となったり、パサついた食感となったりする問題が生じることが知られており、特に挽肉を用いた食品(以下、「挽肉加工食品」という。)でより顕著に生じることが知られている。
他方、健康志向や倫理的な観点、宗教上の観点等から、畜肉や動物油脂等の動物性原料を、植物性蛋白質素材やその加工品(例えば豆腐等)を用いて一部又は全量置換して製造された、畜肉代替食品が増加しているが、これらの畜肉代替食品においては上記のような問題が顕著に生じることが知られている。
このため、従前より、挽肉加工食品や畜肉代替食品(以下、これらをまとめて「挽肉加工食品等」ともいう。)の加熱に伴う食味や食感の低下、具体的にはジューシーな食感の低下を抑制し、又は改善する方法について検討されてきた。
Generally, when meat such as beef, pork, or chicken is subjected to heat treatments such as baking or frying, the oil and moisture in the meat leak out due to the heating, resulting in a lack of juicy texture and rich flavor. It is known that proteins undergo heat denaturation, causing problems such as a hard or dry texture, especially in foods using ground meat (hereinafter referred to as ``ground meat processed foods''). ) is known to occur more markedly.
On the other hand, from health-conscious, ethical, and religious viewpoints, animal raw materials such as meat and animal fats and oils are partially or completely replaced with vegetable protein materials and their processed products (e.g. tofu, etc.). Although the number of meat substitute foods manufactured using traditional methods is increasing, it is known that the above-mentioned problems occur significantly in these meat substitute foods.
For this reason, it has long been reported that heating ground meat processed foods and meat substitute foods (hereinafter collectively referred to as "ground meat processed foods, etc.") causes a decrease in taste and texture, and specifically, a decrease in juicy texture. Methods to suppress or improve the decline have been studied.

例えば、加熱に伴って流出する油脂や水分を、乳化物を加えることにより補う方法が報告されている(例えば特許文献1~3)。
また、乳化剤やゲル化剤を加えることにより加熱に伴って流出する油脂や水分を少なくする方法が報告されている(例えば特許文献4~6)。
さらに、酵素を加えることにより、挽肉加工食品等をジューシーな食感とする方法が報告されている(例えば特許文献7~9)。
さらにまた、各種塩類を加えることにより、挽肉加工食品等をジューシーな食感とする方法が報告されている(例えば特許文献10~12)。
なお、本出願人も挽肉加工食品等の製造に用いられる、畜肉加工品用固形状水中油型乳化脂について検討し、出願を行っている(特許文献13)。
For example, methods have been reported in which an emulsion is added to compensate for the loss of oil and water that occurs during heating (for example, Patent Documents 1 to 3).
In addition, methods have been reported in which an emulsifier or gelling agent is added to reduce the amount of oil and water that flows out when heated (for example, Patent Documents 4 to 6).
Furthermore, methods have been reported for imparting a juicy texture to processed minced meat foods and the like by adding enzymes (for example, Patent Documents 7 to 9).
Furthermore, methods have been reported for imparting a juicy texture to processed minced meat foods and the like by adding various salts (for example, Patent Documents 10 to 12).
The present applicant has also studied and filed an application for a solid oil-in-water type emulsified fat for processed meat products, which is used in the production of processed minced meat foods and the like (Patent Document 13).

特開2021-069332号公報JP 2021-069332 A 特開2019-115339号公報JP 2019-115339 A 国際公開第2020/004058号International Publication No. 2020/004058 特開2019-083826号公報JP2019-083826A 特開2002-000231号公報Japanese Patent Application Publication No. 2002-000231 特開2016-067338号公報JP 2016-067338 A 国際公開第2008/156126号International Publication No. WO 2008/156126 国際公開第2010/140708号International Publication No. 2010/140708 特開2017-209052号公報JP 2017-209052 A 特開2007-274999号公報Japanese Patent Application Publication No. 2007-274999 国際公開第2020/066844号International Publication No. 2020/066844 特開2004-242674号公報JP 2004-242674 A 特開2017-051156号公報Japanese Patent Application Publication No. 2017-051156

従来検討されてきた手法には以下のような問題があった。
乳化物を加える方法では、挽肉加工食品等の生地が緩くなりやすく、挽肉加工食品等を製造する際の作業性に改善の余地があった。
また、乳化剤やゲル化剤を加える方法では、油脂や水分の流出を十分に抑制しようとすると、多くの乳化剤やゲル化剤を含有させる必要が生じ、風味発現性が損なわれやすい他、得られる挽肉加工食品等が弾力の強い食感となる場合があった。
さらに、酵素を加える方法では、その処理温度や時間により得られる挽肉加工食品等の生地や挽肉加工食品等の品質、及びその作業性がばらつきやすかった。
さらにまた、各種塩類を加える方法では、塩類特有のえぐみが挽肉加工食品等に付与される場合があった。
なお、特許文献13の発明は加熱調理時に生じる油脂や水分の流出を抑制することが可能であるが、畜肉代替食品ではその効果が得られにくかった。
The methods that have been considered so far have the following problems.
In the method of adding an emulsion, the dough of ground meat processed foods, etc. tends to become loose, and there is room for improvement in workability when producing ground meat processed foods, etc.
In addition, in the method of adding an emulsifier or gelling agent, if you try to sufficiently suppress the outflow of oils, fats, and water, it becomes necessary to include a large amount of emulsifying agent or gelling agent, which tends to impair flavor development and reduce the amount of oil that can be obtained. In some cases, ground meat processed foods had a chewy texture.
Furthermore, in the method of adding enzymes, the quality of the resulting ground meat processed food, etc., and the quality of the dough and the workability of the ground meat processed food vary depending on the processing temperature and time.
Furthermore, in the method of adding various salts, the harsh taste peculiar to salts may be imparted to ground meat processed foods.
In addition, although the invention of Patent Document 13 can suppress the outflow of oil, fat, and moisture generated during cooking, it is difficult to obtain this effect with livestock meat substitute foods.

したがって、本発明の課題は、以下の(1)及び(2)を達成することのできる食感改良剤を提供することにある。
(1)挽肉加工食品及び畜肉代替食品のいずれの製造であっても用いることができ、且つ作業性が良好である。
(2)挽肉加工食品等を製造する際の油脂や水分の流出を抑制し、ジューシーな食感を有するものとする。
Therefore, an object of the present invention is to provide a texture improving agent that can achieve the following (1) and (2).
(1) It can be used in the production of both ground meat processed foods and livestock meat substitute foods, and has good workability.
(2) The outflow of oil, fat and water during the production of ground meat processed foods, etc. is suppressed, and the food has a juicy texture.

本発明者による鋭意検討により、挽肉加工食品等を製造する際に、変性脂質蛋白質複合体を挽肉加工食品等の生地に含有させることで、上記課題を解決しうることが見出された。 Through intensive research by the present inventors, it was discovered that the above problems can be solved by adding a denatured lipid-protein complex to the dough of a minced meat processed food or the like when producing the food.

本発明は以下の内容を含む。
本発明は、変性脂質蛋白質複合体を含有する、挽肉加工食品又は畜肉代替食品の食感改良剤である。
また、本発明は、脂質及び蛋白質を含有する水溶液を均質化する工程を経た後に、均質化された水溶液を緩慢冷凍する工程、又は120~150℃の加熱温度で1~20秒の間加熱する工程のいずれか1つ以上の工程を経る、上記食感改良剤の製造方法である。
更に、本発明は、上記食感改良剤を含有する、挽肉加工食品又は畜肉代替食品である。
また、食感改良剤を含有させる、挽肉加工食品又は畜肉代替食品の食感改良方法である。
The present invention includes the following contents.
The present invention is a texture improving agent for processed ground meat foods or meat substitute foods, which contains a modified lipid protein complex.
The present invention also provides a step of homogenizing an aqueous solution containing lipids and proteins, followed by a step of slowly freezing the homogenized aqueous solution, or heating the homogenized aqueous solution for 1 to 20 seconds at a heating temperature of 120 to 150°C. This is a method for producing the above-mentioned food texture improver, which includes any one or more of the following steps.
Furthermore, the present invention is a ground meat processed food or a meat substitute food containing the above-mentioned texture improving agent.
It is also a method for improving the texture of a ground meat processed food or a meat substitute food, which comprises incorporating a texture improver.

本発明によれば、以下の(1)及び(2)を達成することのできる食感改良剤を提供することができる。
(1)挽肉加工食品及び畜肉代替食品のいずれの製造であっても用いることができ、且つ作業性が良好である。
(2)挽肉加工食品等を製造する際の油脂や水分の流出を抑制し、ジューシーな食感を有するものとする。
According to the present invention, it is possible to provide a food texture improver that can achieve the following (1) and (2).
(1) It can be used in the production of both ground meat processed foods and livestock meat substitute foods, and has good workability.
(2) The outflow of oil, fat, and water during the production of ground meat processed foods, etc. is suppressed, and the food has a juicy texture.

以下、本発明の挽肉加工食品又は畜肉代替食品の食感改良剤(以下、本発明の挽肉加工食品等食感改良剤と記載)について、好ましい実施形態に基づき詳述する。
なお、本発明における脂質蛋白質複合体とは、蛋白質と脂質とを含有し、且つ蛋白質と脂質との間に働く強い親和力により形成される高次構造を持つものを意味する。単に蛋白質と脂質とを含有するだけのものは本発明の脂質蛋白質複合体には包含されない。
また、本発明における凍結変性脂質蛋白質複合体とは、脂質蛋白質複合体を凍結させることにより得られるものを意味し、好ましくは後述する緩慢冷凍処理が施されたものであり、本発明における加熱変性脂質蛋白質複合体とは、脂質蛋白質複合体を加熱することにより得られるものを意味し、好ましくは後述するとおり120℃以上の液温となるように加熱されたものである。
Hereinafter, the texture improving agent for ground meat processed foods or livestock meat substitute foods of the present invention (hereinafter referred to as the texture improving agent for ground meat processed foods, etc. of the present invention) will be described in detail based on preferred embodiments.
Note that the lipid-protein complex in the present invention refers to one containing a protein and a lipid and having a higher-order structure formed by strong affinity between the protein and the lipid. Lipid-protein complexes of the present invention do not include those that simply contain protein and lipid.
In addition, the freeze-denatured lipid-protein complex in the present invention means one obtained by freezing a lipid-protein complex, and is preferably one that has been subjected to the slow freezing treatment described below. The term "lipid-protein complex" refers to one obtained by heating a lipid-protein complex, preferably one heated to a liquid temperature of 120° C. or higher, as described later.

以下、本発明における脂質蛋白質複合体(以下、単に「複合体」ということがある。)の構成成分である脂質及び蛋白質、脂質蛋白質複合体の製造方法について述べた後、本発明の挽肉加工食品等食感改良剤が好ましく含有する凍結変性脂質蛋白質複合体、及び加熱変性脂質蛋白質複合体について述べる。 Hereinafter, after describing the lipids and proteins that are constituent components of the lipid-protein complex of the present invention (hereinafter sometimes simply referred to as "complex") and the method for producing the lipid-protein complex, the ground meat processed food of the present invention will be described. A freeze-denatured lipid-protein complex and a heat-denatured lipid-protein complex preferably contained in the food texture improving agent will be described.

[脂質について]
上記複合体を構成する脂質としては、特に限定されず、任意の脂質を使用することが可能である。脂質の具体例としては、例えば、トリグリセリド、ジグリセリド、モノグリセリド、リン脂質、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ショ糖脂肪酸エステル及びポリグリセリン脂肪酸エステルなどが挙げられる。
本発明の効果が一層顕著になることから、脂質として、モノグリセリド、リン脂質、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ショ糖脂肪酸エステル及びポリグリセリン脂肪酸エステルからなる群から選択される1種又は2種以上を使用することが好ましく、リン脂質を使用することが風味の面からも機能の面からも特に好ましい。
すなわち、本発明に用いる脂質は、一部又は全部がリン脂質であることが特に好ましい。
[About lipids]
The lipid constituting the complex is not particularly limited, and any lipid can be used. Specific examples of lipids include triglycerides, diglycerides, monoglycerides, phospholipids, sorbitan fatty acid esters, propylene glycol fatty acid esters, sucrose fatty acid esters, and polyglycerin fatty acid esters.
Since the effects of the present invention become more pronounced, it is preferable to use, as the lipid, one or more selected from the group consisting of monoglycerides, phospholipids, sorbitan fatty acid esters, propylene glycol fatty acid esters, sucrose fatty acid esters, and polyglycerin fatty acid esters, and the use of phospholipids is particularly preferable from the standpoint of both flavor and functionality.
That is, it is particularly preferred that the lipids used in the present invention are partially or entirely phospholipids.

上記脂質におけるリン脂質の含有量は、リン脂質とリン脂質以外の脂質との質量比率が、前者:後者で、30:70~100:0の範囲が好ましく、60:40~100:0の範囲がより好ましく、80:20~100:0の範囲が最も好ましい。本発明においては、目的に応じて、上記脂質の1種を単独で用いてもよく、2種以上を組合わせて用いてもよい。
なお、リン脂質をレシチンの形で使用する場合は、リン脂質と、レシチンに含有されるその他の脂質との質量比率が、前者:後者で、30:70~100:0の範囲にある任意のレシチンを使用することができ、好ましくは60:40~100:0のレシチンを、より好ましくは80:20~100:0のレシチンを使用するとよい。
The content of phospholipids in the above lipids is such that the mass ratio of phospholipids to lipids other than phospholipids is preferably in the range of 30:70 to 100:0, and in the range of 60:40 to 100:0. is more preferable, and the range of 80:20 to 100:0 is most preferable. In the present invention, one type of the above-mentioned lipids may be used alone or two or more types may be used in combination depending on the purpose.
In addition, when using phospholipids in the form of lecithin, the mass ratio of phospholipids and other lipids contained in lecithin is in the range of 30:70 to 100:0 (former:latter). Lecithin can be used, preferably 60:40 to 100:0 lecithin, more preferably 80:20 to 100:0 lecithin.

本発明においては、上記リン脂質の由来は特に限定されるものではなく、大豆由来リン脂質、ヒマワリ由来リン脂質、紅花由来リン脂質及び菜種由来リン脂質等の植物由来の植物性リン脂質、卵黄由来リン脂質、魚卵由来リン脂質及び乳由来リン脂質等の動物由来の動物性リン脂質、並びに微生物由来の微生物性リン脂質を使用することができる。また、これらの抽出物、精製物あるいは酵素処理品等を使用することも可能である。
具体的なリン脂質としてはホスファチジン酸、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルイノシトール、ホスファチジルセリン、スフィンゴミエリン等が挙げられ、これらの1種を単独で用いてもよく、2種以上を組合わせて用いてもよい。
本発明ではいずれのリン脂質も用いることができるが、少量の添加で挽肉加工食品等に対して十分な改良効果を得る点や、蛋白質との複合体生成能が高い点から、大豆由来、ヒマワリ由来、紅花由来、菜種由来などの植物由来の植物性リン脂質又は微生物由来の微生物性リン脂質を使用することが好ましく、大豆由来リン脂質及び/又はヒマワリ由来リン脂質を使用することがより好ましい。
In the present invention, the origin of the above-mentioned phospholipids is not particularly limited, and includes vegetable phospholipids derived from plants such as soybean-derived phospholipids, sunflower-derived phospholipids, safflower-derived phospholipids, and rapeseed-derived phospholipids, and egg yolk-derived phospholipids. Animal phospholipids derived from animals such as phospholipids, phospholipids derived from fish eggs and phospholipids derived from milk, and microbial phospholipids derived from microorganisms can be used. It is also possible to use extracts, purified products, enzyme-treated products, etc. of these.
Specific phospholipids include phosphatidic acid, phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidylserine, sphingomyelin, etc., and one type of these may be used alone, or two or more types may be used in combination. Good too.
Although any phospholipid can be used in the present invention, soybean-derived, sunflower-derived, It is preferable to use vegetable phospholipids derived from plants such as safflower, rapeseed, etc., or microbial phospholipids derived from microorganisms, and it is more preferable to use soybean-derived phospholipids and/or sunflower-derived phospholipids.

[蛋白質について]
上記複合体を構成する蛋白質としては、特に限定されず、任意の蛋白質を使用することが可能である。蛋白質の具体例としては、例えば、動物性蛋白質、微生物性蛋白質及び植物性蛋白質等が挙げられる。動物性蛋白質としては、例えば、ホエイ蛋白質及びカゼイン蛋白質等の乳蛋白質;並びに低密度リポ蛋白質、高密度リポ蛋白質、ホスビチン、リベチン、リン糖蛋白質、オボアルブミン、コンアルブミン及びオボムコイド等の卵蛋白質等が挙げられる。植物性蛋白質としては、グリアジン、グルテニン、プロラミン及びグルテリン等の小麦蛋白質;大豆蛋白質、エンドウ豆蛋白質、そら豆蛋白質、緑豆蛋白質、ひよこ豆蛋白質及びレンズ豆蛋白質等の豆類蛋白質、並びに米蛋白質等のその他穀類蛋白質が挙げられる。これらの蛋白質は、目的に応じて、1種を単独で使用してもよく、2種以上を組合わせて用いてもよい。
[About protein]
The protein constituting the above complex is not particularly limited, and any protein can be used. Specific examples of proteins include animal proteins, microbial proteins, vegetable proteins, and the like. Examples of animal proteins include milk proteins such as whey protein and casein protein; and egg proteins such as low-density lipoprotein, high-density lipoprotein, phosvitin, livetin, phosphoglycoprotein, ovalbumin, conalbumin, and ovomucoid. Can be mentioned. Examples of vegetable proteins include wheat proteins such as gliadin, glutenin, prolamin, and glutelin; legume proteins such as soybean protein, pea protein, broad bean protein, mung bean protein, chickpea protein, and lentil protein; and other cereals such as rice protein. Examples include proteins. These proteins may be used singly or in combination of two or more, depending on the purpose.

本発明では、少量の添加で高い品質改良効果が得られる挽肉加工食品等食感改良剤とすることができる点や、脂質との複合体生成能が高い点で、豆類蛋白質を選択すること好ましい。
豆類蛋白質としては、いっそう高い効果を得る点や、水溶性が高いことから後述する製造方法をとることが容易である点で、大豆蛋白質、エンドウ豆蛋白質、そら豆蛋白質、緑豆蛋白質、ひよこ豆蛋白質及びレンズ豆蛋白質からなる群から選択される1種又は2種以上を使用すること好ましく、大豆蛋白質、エンドウ豆蛋白質、そら豆蛋白質のうちいずれか1種以上を使用することがより好ましい。
In the present invention, it is preferable to select legume protein because it can be used as a texture improver for minced meat processed foods and the like, which can provide a high quality improving effect with the addition of a small amount, and because it has a high ability to form a complex with lipids.
As the legume protein, it is preferable to use one or more types selected from the group consisting of soybean protein, pea protein, fava bean protein, mung bean protein, chickpea protein and lentil protein, in terms of obtaining a higher effect and of facilitating the production method described below due to high water solubility, and it is more preferable to use one or more types of soybean protein, pea protein and fava bean protein.

本発明に含まれる複合体における、蛋白質と脂質との質量比は、蛋白質100質量部に対し脂質が10~250質量部であることが好ましく、20~130質量部であることがより好ましく、80~130質量部であることが更に好ましく、100~130質量部であることが最も好ましい。蛋白質100質量部に対する脂質の質量比を上述の範囲とすることで、挽肉加工食品等を得る際の作業性が向上しやすく、得られる挽肉加工食品等のジューシーな食感も向上しやすい。また、複合体を製造する際に蛋白質と脂質とを含有する水溶液の粘度が高くならないので、該水溶液がゲル状になりにくくなり、その結果複合体の製造が容易となるため好ましい。 The mass ratio of protein to lipid in the complex included in the present invention is preferably 10 to 250 parts by mass of lipid per 100 parts by mass of protein, more preferably 20 to 130 parts by mass, even more preferably 80 to 130 parts by mass, and most preferably 100 to 130 parts by mass. By setting the mass ratio of lipid to 100 parts by mass of protein in the above-mentioned range, the workability when obtaining minced meat processed foods and the like is easily improved, and the juicy texture of the obtained minced meat processed foods and the like is also easily improved. In addition, since the viscosity of the aqueous solution containing protein and lipid does not increase when the complex is produced, the aqueous solution is less likely to become gel-like, which is preferable as a result, making it easier to produce the complex.

[脂質と蛋白質以外のその他の成分について]
本発明における脂質蛋白質複合体は、本発明の効果を阻害しない範囲内で、必要に応じ、その製造の際に、上記の脂質と蛋白質以外のその他の成分を用いることができる。該その他の成分としては、アルコール類、ゲル化剤や安定剤、乳化剤、金属イオン封鎖剤、糖類・甘味料、糖アルコール、澱粉類、無機塩、有機酸塩、酵素、香辛料、香辛料抽出物、ハーブ、直鎖デキストリン・分枝デキストン・環状デキストン等のデキストリン類、その他各種食品素材、微粒二酸化ケイ素・炭酸マグネシウム・リン酸二ナトリウム・酸化マグネシウム等の固結防止剤、ビタミン類、光沢剤、着香料、苦味料、調味料等の呈味成分、着色料、保存料、酸化防止剤、pH調整剤、有機酸、重炭安等のアルカリ剤、強化剤等が挙げられる。
[About other components other than lipids and proteins]
In the lipid-protein complex of the present invention, other components other than the above-mentioned lipids and proteins can be used in the production of the complex, if necessary, within a range that does not impede the effects of the present invention. Other ingredients include alcohols, gelling agents and stabilizers, emulsifiers, sequestering agents, sugars and sweeteners, sugar alcohols, starches, inorganic salts, organic acid salts, enzymes, spices, spice extracts, Herbs, dextrins such as linear dextrin, branched dextone, and cyclic dextone, various other food materials, anti-caking agents such as fine silicon dioxide, magnesium carbonate, disodium phosphate, and magnesium oxide, vitamins, brighteners, and adhesives. Examples include flavor components such as fragrances, bittering agents, and seasonings, coloring agents, preservatives, antioxidants, pH adjusters, organic acids, alkali agents such as ammonium carbonate, and reinforcing agents.

[脂質蛋白質複合体の製造方法について]
脂質蛋白質複合体の製造方法について述べる。
本発明における脂質蛋白質複合体は、例えば、蛋白質や蛋白質を含有する食品素材、及び脂質や脂質を含有する食品素材を水に添加し、更に必要により上述のその他の成分を水に添加して蛋白質と脂質とを含有する水溶液を調製し、調製した水溶液を均質化することによって得ることができる。この場合、得られる水溶液は脂質蛋白質複合体を含有するものとなる。
この際、蛋白質及び/又は蛋白質を含有する食品素材の使用量、並びに脂質及び/又は脂質を含有する食品素材の使用量を、得られる脂質蛋白質複合体における脂質と蛋白質との比が上述の範囲となるように適切に設定することが好ましい。
なお、上記蛋白質として、蛋白質を含有する食品素材を使用した場合、また、脂質として、脂質を含有する食品素材を使用した場合、複合体における脂質の含有量及び蛋白質の含有量は、それぞれの食品素材に含まれる純蛋白質含有量及び純脂質含有量を用いて算出するものとする。
[About the production method of lipid protein complex]
A method for producing a lipid-protein complex will be described.
The lipid-protein complex in the present invention can be prepared by, for example, adding a protein, a food material containing protein, a lipid or a food material containing lipid to water, and further adding the above-mentioned other components to water as necessary. It can be obtained by preparing an aqueous solution containing the lipid and the lipid, and homogenizing the prepared aqueous solution. In this case, the resulting aqueous solution will contain a lipid-protein complex.
At this time, the amount of protein and/or protein-containing food material used, and the amount of lipid and/or lipid-containing food material used, should be adjusted so that the ratio of lipid to protein in the resulting lipid-protein complex is within the above-mentioned range. It is preferable to set it appropriately so that
In addition, when a food material containing protein is used as the above-mentioned protein, and when a food material containing lipid is used as the lipid, the lipid content and protein content in the complex will vary depending on the respective food. It shall be calculated using the pure protein content and pure lipid content contained in the material.

上記の蛋白質と脂質とを含有する水溶液中における蛋白質の含有量は、好ましくは1~25質量%、より好ましくは5~25質量%、更に好ましくは5~20質量%であり、脂質の含有量は、好ましくは1~25質量%、より好ましくは5~25質量%、更に好ましくは5~20質量%である。
上記の蛋白質と脂質とを含有する水溶液中の蛋白質及び脂質の含有量を上記の量範囲を満たすものとすることで、混合・撹拌によりダマを解消・分散させることができ、且つ十分に均質化を行うことができ、効率よく脂質蛋白質複合体を製造できるため好ましい。
上述したとおり、脂質蛋白質複合体の製造時に、水溶液中に蛋白質及び脂質以外のその他の成分を含有させることができるが、蛋白質及び脂質を高効率で複合化させる観点から、その他の成分を含有させないことが好ましい。
The protein content in the aqueous solution containing the above protein and lipid is preferably 1 to 25 mass%, more preferably 5 to 25 mass%, and even more preferably 5 to 20 mass%, and the lipid content is preferably 1 to 25 mass%, more preferably 5 to 25 mass%, and even more preferably 5 to 20 mass%.
By setting the protein and lipid contents in the aqueous solution containing the above-mentioned protein and lipid to fall within the above-mentioned ranges, lumps can be eliminated and dispersed by mixing and stirring, and sufficient homogenization can be achieved, which is preferable because it allows the efficient production of lipid-protein complexes.
As described above, when producing a lipid-protein complex, other components besides protein and lipid can be contained in the aqueous solution. However, from the viewpoint of highly efficient complexation of protein and lipid, it is preferable not to contain other components.

脂質蛋白質複合体を製造する際、蛋白質と脂質とを含有する水溶液を均質化する前又は均質化した後に加熱殺菌することが好ましい。均質化の後に加熱殺菌する場合は、加熱殺菌の後に再度均質化することができる。
上記均質化に用いる装置としては、ケトル型チーズ乳化釜、ステファンミキサーのような高速せん断乳化釜、コミットロールやマスコロイダーのような高速せん断ミキサー、スタティックミキサー、インラインミキサー、ホモジナイザー、コロイドミル、ディスパーミル等が挙げられる。この均質化処理は、2段式ホモジナイザーを用いて、例えば、1段目3~100mpa、2段目0~5mpaの均質化圧力にて行えばよい。
上記加熱殺菌の方法としては、インジェクション式、インフュージョン式、マイクロ波等の直接加熱方式、又は、バッチ式、プレート式、チューブラー式、掻き取り式等の間接加熱方式があり、UHT、HTST、LTLT等の60~160℃の加熱処理を行えばよい。
なお、後述するとおり、本発明における変性脂質蛋白質複合体が加熱変性脂質蛋白質複合体である場合には、この殺菌に伴う加熱によって加熱変性脂質蛋白質複合体を製造してもよい。
In producing lipid-protein complexes, it is preferred to heat sterilize the aqueous solution containing the protein and lipid before or after homogenization. If heat sterilization is performed after homogenization, it can be homogenized again after heat sterilization.
Examples of the apparatus used for the homogenization include a kettle-type cheese emulsification kettle, a high-speed shear emulsification kettle such as a Stephan mixer, a high-speed shear mixer such as a commit roll or a mass colloider, a static mixer, an in-line mixer, a homogenizer, a colloid mill, a disper mill, etc. This homogenization treatment may be carried out using a two-stage homogenizer, for example, at a homogenization pressure of 3 to 100 MPa in the first stage and 0 to 5 MPa in the second stage.
The above-mentioned heat sterilization method includes direct heating methods such as injection type, infusion type, and microwave type, and indirect heating methods such as batch type, plate type, tubular type, and scraping type. Heat treatment at 60 to 160 ° C. such as UHT, HTST, and LTLT may be performed.
As described below, when the denatured lipid-protein complex of the present invention is a heat-denatured lipid-protein complex, the heat-denatured lipid-protein complex may be produced by heating accompanying the sterilization.

[凍結変性脂質蛋白質複合体について]
本発明の挽肉加工食品等食感改良剤は、その好ましい一態様が、上記の脂質蛋白質複合体を凍結変性させた凍結変性脂質蛋白質複合体を含有するものである。溶剤変性された脂質蛋白質複合体等、加熱や凍結以外の手法により得られる脂質蛋白質複合体では本発明の効果は得られない。
本発明の挽肉加工食品等食感改良剤に含まれる凍結変性脂質蛋白質複合体は、粉体、顆粒、錠剤等の固形状や、液状、ペースト等の流動状の何れの形態であってもよいが、他の成分との混合性が高い点、そのまま食感改良剤として用いた際の食品への混合性が良好である点で、粉体、液状及びペースト状の何れかの形態であることが好ましい。
粉体とする場合は、脂質蛋白質複合体を冷凍した後そのまま凍結乾燥して粉末化してもよく、また、脂質蛋白質複合体を冷凍した後に解凍して凍結変性脂質蛋白質複合体を含む水溶液とし、その水溶液をスプレードライして粉末化してもよい。
また液剤、ペースト等の流動状の形態とする場合は、脂質蛋白質複合体を冷凍後に解凍して凍結変性脂質蛋白質複合体を含む水溶液をそのまま用いることができる。
[About freeze-denatured lipid protein complex]
A preferable embodiment of the texture improving agent for ground meat processed foods of the present invention contains a freeze-denatured lipid-protein complex obtained by freeze-denaturing the above-mentioned lipid-protein complex. The effects of the present invention cannot be obtained with lipid-protein complexes obtained by methods other than heating or freezing, such as solvent-denatured lipid-protein complexes.
The freeze-denatured lipid-protein complex contained in the texture improver for ground meat processed foods of the present invention may be in any solid form such as powder, granules, or tablets, or in a fluid form such as liquid or paste. However, it should be in the form of powder, liquid, or paste because it is highly miscible with other ingredients and has good miscibility with food when used as a texture improver. is preferred.
In the case of powder, the lipid-protein complex may be frozen and then lyophilized to form a powder, or the lipid-protein complex may be frozen and then thawed to form an aqueous solution containing the freeze-denatured lipid-protein complex. The aqueous solution may be spray-dried to form a powder.
In addition, in the case of preparing a fluid form such as a liquid or paste, the lipid-protein complex can be frozen and then thawed, and the aqueous solution containing the freeze-denatured lipid-protein complex can be used as it is.

[加熱変性脂質蛋白質複合体について]
本発明の挽肉加工食品等食感改良剤は、その好ましい一態様が、上記の脂質蛋白質複合体を加熱変性させた凍結変性脂質蛋白質複合体を含有するものである。溶剤変性された脂質蛋白質複合体等、加熱や凍結以外の手法により得られる脂質蛋白質複合体では本発明の効果は得られない。
本発明の挽肉加工食品等食感改良剤に含まれる加熱変性脂質蛋白質複合体は、粉体、顆粒、錠剤等の固形状や、液状、ペースト等の流動状の何れの形態であってもよいが、他の成分との混合性が高い点、そのまま食感改良剤として用いた際の食品への混合性が良好である点で、粉体、液状及びペースト状の何れかの形態であることが好ましい。
粉体とする場合は、脂質蛋白質複合体を加熱した後に凍結乾燥して粉末化してもよく、また、加熱脂質蛋白質複合体を含む水溶液をスプレードライして粉末化してもよい。
また液剤、ペースト等の流動状の形態とする場合は、脂質蛋白質複合体を加熱後に、加熱変性脂質蛋白質複合体を含む水溶液をそのまま用いることができる。
[Heat-denatured lipid-protein complexes]
A preferred embodiment of the texture improver for processed minced meat foods and the like of the present invention contains a frozen denatured lipid-protein complex obtained by heat-denaturing the lipid-protein complex described above. The effects of the present invention cannot be obtained with lipid-protein complexes obtained by methods other than heating or freezing, such as solvent-denatured lipid-protein complexes.
The heat-denatured lipid protein complex contained in the texture improver for minced meat processed foods, etc. of the present invention may be in any form, such as a solid form such as powder, granules, or tablets, or a fluid form such as a liquid or paste. However, it is preferable that the complex be in any of the powder, liquid, or paste forms, in view of its high mixability with other ingredients and its good mixability with foods when used as a texture improver as is.
When preparing a powder, the lipid-protein complex may be heated and then freeze-dried to obtain a powder, or an aqueous solution containing the heated lipid-protein complex may be spray-dried to obtain a powder.
When the lipid-protein complex is in the form of a fluid such as a liquid or paste, the aqueous solution containing the heat-denatured lipid-protein complex can be used as it is after heating the lipid-protein complex.

[凍結変性脂質蛋白質複合体及び加熱変性脂質蛋白質複合体の製造方法について]
以下、本発明における変性脂質蛋白質複合体の好ましい態様である、凍結変性脂質蛋白質複合体及び加熱変性脂質蛋白質複合体の製造方法について述べる。
まず、凍結変性脂質蛋白質複合体の製造方法について述べる。
本発明における凍結変性脂質蛋白質複合体は、上述の通り脂質蛋白質複合体を冷凍工程に付し、凍結変性させることで得られる。
脂質蛋白質複合体を冷凍する際には、急速冷凍であってもよく、緩慢冷凍であっても良いが、本発明においては緩慢冷凍を行う事が好ましい。
複合体を急速冷凍した場合、凍結変性がおこりにくく、本発明の効果が得られにくい。
本発明における緩慢冷凍とは、緩慢な冷却速度での冷凍を意味し、具体的には、温度変化が2.0℃/h未満、好ましくは0.1~1.5℃/hの冷却速度で冷凍処理することを意味する。急速冷凍とは2.0℃/h超の冷却速度で冷凍処理することを意味する。
[About the manufacturing method of freeze-denatured lipid protein complex and heat-denatured lipid protein complex]
Hereinafter, methods for producing freeze-denatured lipid-protein complexes and heat-denatured lipid-protein complexes, which are preferred embodiments of the denatured lipid-protein complexes of the present invention, will be described.
First, a method for producing a freeze-denatured lipid protein complex will be described.
The freeze-denatured lipid-protein complex in the present invention can be obtained by subjecting the lipid-protein complex to a freezing process and freeze-denaturing it as described above.
When freezing the lipid-protein complex, rapid freezing or slow freezing may be used, but in the present invention slow freezing is preferably performed.
When the complex is rapidly frozen, freeze denaturation is less likely to occur, making it difficult to obtain the effects of the present invention.
Slow freezing in the present invention means freezing at a slow cooling rate, specifically, the temperature change is less than 2.0°C/h, preferably at a cooling rate of 0.1 to 1.5°C/h. This means that it is frozen. Rapid freezing means freezing treatment at a cooling rate of more than 2.0°C/h.

本発明においては、脂質蛋白質複合体を含有する水溶液を冷凍する際、最大氷結晶生成温度帯(-1~-5℃)を2時間以上かけて通過することが好ましい。
冷凍工程の始点温度は水溶液が凍結しない温度であればいいが、好ましくは0℃~10℃、より好ましくは1~10℃、最も好ましくは3~7℃である。
また、冷凍工程の終点温度は水溶液が凍結する温度であればいいが、好ましくは-5℃以下、より好ましくは-10℃以下、最も好ましくは-18℃以下である。
冷凍工程の終点温度の下限は特に制限されないが、本発明においては緩慢冷凍が好ましく採用されるため、設定された終点温度が過度に低いと凍結変性脂質蛋白質複合体の製造に時間がかかり生産性が悪化するため、好ましくは-40℃以上、より好ましくは-30℃以上、最も好ましくは-25℃以上である。
冷凍工程の始点温度に至るまでの冷却や、冷凍工程における冷却は、例えば、チューブラー式、掻取式等の熱交換機によって冷却する方法が挙げられる。また、別の方法として、適当な容器に充填した後に、冷凍庫等で冷却する方法も挙げられる。
なお、冷却に要する時間としては30分以上であることが好ましく、より好ましくは3時間以上とする。
In the present invention, when freezing the aqueous solution containing the lipid-protein complex, it is preferable that the aqueous solution containing the lipid-protein complex be passed through the maximum ice crystal formation temperature range (-1 to -5°C) for 2 hours or more.
The starting point temperature of the freezing step may be any temperature at which the aqueous solution does not freeze, but is preferably 0°C to 10°C, more preferably 1 to 10°C, and most preferably 3 to 7°C.
Further, the end point temperature of the freezing step may be any temperature at which the aqueous solution freezes, but is preferably -5°C or lower, more preferably -10°C or lower, and most preferably -18°C or lower.
The lower limit of the end point temperature of the freezing process is not particularly limited, but since slow freezing is preferably employed in the present invention, if the set end point temperature is too low, it will take time to produce the freeze-denatured lipid-protein complex, resulting in reduced productivity. The temperature is preferably -40°C or higher, more preferably -30°C or higher, and most preferably -25°C or higher.
Cooling up to the starting point temperature of the freezing process and cooling in the freezing process include, for example, a method of cooling using a tubular type, scraping type, etc. heat exchanger. Another method is to fill an appropriate container and then cool it in a freezer or the like.
Note that the time required for cooling is preferably 30 minutes or more, more preferably 3 hours or more.

脂質蛋白質複合体が凍結変性しているか否か(すなわち凍結変性脂質蛋白質複合体が得られたか否か)については、以下のようにして判断することができる。
まず、脂質蛋白質複合体の製造における均質化後、その一部を冷凍しないものとして取り置き、残りを冷凍工程に供する。
冷凍工程後、脂質蛋白質複合体を含有する水溶液を-20℃で20時間保管した後、1℃/hの速度で解凍し、水溶液が25℃の温度に達したのち10時間置き、その水溶液の25℃の粘度を、回転式粘度計を用いて測定したとき、冷凍しなかった場合と比べて粘度が高い場合、好ましくは1.5倍以上、より好ましくは2倍以上、更に好ましくは3倍以上、最も好ましくは4倍以上の粘度になっていることで、凍結変性しているとみなすことができる。
なお、この判定方法は、脂質蛋白質複合体が凍結により変性し、部分的にゲルを形成することを利用するものである。
Whether or not the lipid-protein complex has been freeze-denatured (that is, whether a freeze-denatured lipid-protein complex has been obtained) can be determined as follows.
First, after homogenization in the production of a lipid-protein complex, a part of it is set aside as not to be frozen, and the rest is subjected to a freezing process.
After the freezing process, the aqueous solution containing the lipid-protein complex was stored at -20°C for 20 hours, then thawed at a rate of 1°C/h, and after the aqueous solution reached a temperature of 25°C, it was left for 10 hours and the aqueous solution was stored at -20°C for 20 hours. When the viscosity at 25°C is measured using a rotational viscometer, if the viscosity is higher than that without freezing, it is preferably 1.5 times or more, more preferably 2 times or more, and even more preferably 3 times. As mentioned above, if the viscosity is most preferably four times or more, it can be considered that freeze denaturation has occurred.
Note that this determination method utilizes the fact that the lipid-protein complex is denatured by freezing and partially forms a gel.

次に、加熱変性脂質蛋白質複合体の製造方法について述べる。
本発明における加熱変性脂質蛋白質複合体は、脂質蛋白質複合体を加熱工程に付し、加熱変性させることで得られる。
脂質蛋白質複合体の加熱工程は、上記殺菌工程を行う場合にはその前後のいずれに行ってもよく、上記殺菌工程そのものを加熱工程として採用してもよいが、本発明においては上記殺菌工程そのものを加熱工程として採用する事が好ましい。
上記殺菌工程を加熱工程として採用する場合、過剰な加熱がなされることがなく、風味の変質が生じにくくなる。
Next, a method for producing a heat-denatured lipid-protein complex will be described.
The heat-denatured lipid-protein complex in the present invention can be obtained by subjecting the lipid-protein complex to a heating step and denaturing it by heat.
The heating step of the lipid protein complex may be performed either before or after the sterilization step, or the sterilization step itself may be employed as the heating step, but in the present invention, the sterilization step itself may be performed. It is preferable to employ this as a heating step.
When the above-mentioned sterilization step is employed as a heating step, excessive heating is not performed, and flavor deterioration is less likely to occur.

上記加熱工程を行う際の加熱殺菌の方法としては、インジェクション式、インフュージョン式、マイクロ波等の直接加熱方式、又は、バッチ式、プレート式、チューブラー式、掻き取り式等の間接加熱方式があり、UHT、HTST、LTLT等の60~160℃の加熱処理を行えばよいが、好ましくは120~150℃の加熱温度で1~20秒の間加熱することが好ましく、130~150℃の加熱温度で4~15秒加熱することがより好ましく、140~150℃の加熱温度で7~12秒加熱することがさらに好ましい。
加熱を終えた後は、加熱工程に付された脂質蛋白質複合体を適宜冷却することが好ましく、その手法は任意であり、放冷や水冷、氷冷等のいずれの手法であってもよいが、その冷却が急冷であることが好ましい。なお、急冷とは2.0℃/h超の冷却速度で冷却することを意味する。
Heat sterilization methods used in the above heating process include direct heating methods such as injection type, infusion type, and microwave, and indirect heating methods such as batch type, plate type, tubular type, and scraping type. Yes, heat treatment at 60 to 160°C such as UHT, HTST, or LTLT may be performed, but it is preferable to heat at a heating temperature of 120 to 150°C for 1 to 20 seconds, and heating at 130 to 150°C. It is more preferable to heat at a temperature of 4 to 15 seconds, and even more preferably to heat at a heating temperature of 140 to 150° C. for 7 to 12 seconds.
After heating, it is preferable to appropriately cool the lipid protein complex that has been subjected to the heating process, and the method is arbitrary, and may be any method such as standing cooling, water cooling, ice cooling, etc. Preferably, the cooling is rapid cooling. Note that quenching means cooling at a cooling rate of more than 2.0° C./h.

脂質蛋白質複合体が加熱変性しているか否か(すなわち加熱変性脂質蛋白質複合体が得られたか否か)については、以下のようにして判断することができる。
まず、脂質蛋白質複合体の製造における均質化後、その一部を加熱しないものとして取り置き、残りを加熱工程に供する。
加熱工程後、脂質蛋白質複合体を含有する水溶液を、2℃/hの速度で冷却し、水溶液が25℃の温度に達したのち10時間置き、その水溶液の25℃の粘度を、回転式粘度計を用いて測定したとき、冷凍しなかった場合と比べて粘度が高い場合、好ましくは1.5倍以上、より好ましくは2倍以上、更に好ましくは3倍以上、最も好ましくは4倍以上の粘度になっていることで、加熱変性しているとみなすことができる。
なお、この判定方法は、脂質蛋白質複合体が加熱により変性し、部分的にゲルを形成することを利用するものである。
Whether or not the lipid-protein complex has been heat-denatured (that is, whether a heat-denatured lipid-protein complex has been obtained) can be determined as follows.
First, after homogenization in the production of a lipid-protein complex, a part of it is set aside as not to be heated, and the rest is subjected to a heating process.
After the heating step, the aqueous solution containing the lipid protein complex is cooled at a rate of 2°C/h, and after the aqueous solution reaches a temperature of 25°C, it is left for 10 hours, and the viscosity of the aqueous solution at 25°C is determined by rotational viscosity. When measured using a meter, if the viscosity is higher than that without freezing, it is preferably 1.5 times or more, more preferably 2 times or more, still more preferably 3 times or more, and most preferably 4 times or more. If it becomes viscous, it can be considered that it has been denatured by heat.
Note that this determination method utilizes the fact that the lipid-protein complex is denatured by heating and partially forms a gel.

[本発明の挽肉加工食品等食感改良剤について]
本発明の挽肉加工食品等食感改良剤は、上記の変性脂質蛋白質複合体を含有するものである。
本発明の挽肉加工食品等食感改良剤は、粉体、顆粒、錠剤等の固形状や、液状、ペースト等の流動状のいずれの形態にも常法によりすることができるが、食品への混合性が良好である点で、粉体、液状及びペースト状の何れかの形態であることが好ましい。
本発明の挽肉加工食品等食感改良剤中の変性脂質蛋白質複合体の含有量は、本発明における変性脂質蛋白質複合体の形態や、本発明の挽肉加工食品等食感改良剤の形態によっても異なるが、本発明の挽肉加工食品等食感改良剤が粉体、顆粒、錠剤等の固形状の形態である場合、本発明の食品の品質改良剤における上記変性脂質蛋白質複合体の含有量は、少量の添加で効果を得るという目的のため、変性脂質蛋白質複合体の固形分として50~100質量%であることが好ましく、より好ましくは70~100質量%であり、最も好ましくは85~100質量%である。
[Regarding the texture improver for minced meat processed foods etc. of the present invention]
The texture improver for processed minced meat foods and the like of the present invention contains the above-mentioned denatured lipid-protein complex.
The texture improver for minced meat processed foods, etc. of the present invention can be made in a conventional manner into any solid form such as powder, granules, tablets, etc., or into a fluid form such as liquid or paste, but in terms of good mixability with foods, it is preferable for it to be in any of the powder, liquid, and paste forms.
The content of the denatured lipid-protein complex in the texture improver for minced meat processed foods, etc. of the present invention will vary depending on the form of the denatured lipid-protein complex in the present invention and the form of the texture improver for minced meat processed foods, etc. of the present invention. However, when the texture improver for minced meat processed foods, etc. of the present invention is in the form of a solid such as powder, granules, or tablets, the content of the denatured lipid-protein complex in the food quality improver of the present invention is preferably 50 to 100% by mass, more preferably 70 to 100% by mass, and most preferably 85 to 100% by mass, in terms of the solid content of the denatured lipid-protein complex, for the purpose of obtaining the desired effect with the addition of a small amount.

また、本発明の挽肉加工食品等食感改良剤が液剤、ペースト等の流動状の形態である場合、本発明の挽肉加工食品等食感改良剤における上記変性脂質蛋白質複合体の含有量は、少量の添加で効果を得るという目的、粘度が高すぎず使用しやすいこと、及び保存中の沈殿の生成を避けるため、変性脂質蛋白質複合体の固形分として1~30質量%であることが好ましく、より好ましくは5~20質量%である。
なお、本発明においては、各種形態をとる変性脂質蛋白質複合体をそのまま本発明の挽肉加工食品等食感改良剤として使用することもでき、変性脂質蛋白質複合体と下記のその他の成分とを必要に応じて混合したものを、本発明の挽肉加工食品等食感改良剤として使用することもできる。
Furthermore, when the texture improver for minced meat processed foods, etc. of the present invention is in a fluid form such as a liquid or paste, the content of the above-mentioned denatured lipid-protein complex in the texture improver for minced meat processed foods, etc. of the present invention is preferably 1 to 30% by mass, more preferably 5 to 20% by mass, in terms of the solid content of the denatured lipid-protein complex, for the purpose of obtaining the desired effect with the addition of a small amount, for ease of use as the viscosity is not too high, and for preventing the formation of precipitation during storage.
In the present invention, the modified lipid-protein complex in various forms can be used as it is as a texture improver for minced meat processed foods, etc. of the present invention, or a mixture of the modified lipid-protein complex and other ingredients described below as necessary can be used as a texture improver for minced meat processed foods, etc. of the present invention.

該その他の成分としては、水、アルコール類、油脂、ゲル化剤や安定剤、乳化剤、金属イオン封鎖剤、糖類・甘味料、糖アルコール、澱粉類、乳や乳製品、卵製品、穀類、無機塩、有機酸塩、酵素、ジグリセライド、香辛料、香辛料抽出物、ハーブ、直鎖デキストリン・分枝デキストリン・環状デキストン等のデキストリン類、その他各種食品素材、微粒二酸化ケイ素・炭酸マグネシウム・リン酸二ナトリウム・酸化マグネシウム等の固結防止剤、ビタミン類、光沢剤、着香料、苦味料、調味料等の呈味成分、着色料、保存料、酸化防止剤、ph調整剤、有機酸、重炭安等のアルカリ剤、強化剤等が挙げられる。
本発明の挽肉加工食品等食感改良剤は、本発明の効果を阻害しない範囲内で変性脂質蛋白質複合体以外のその他の成分を含有することができるが、本発明の挽肉加工食品等食感改良剤中10質量%以下であることが好ましく、8質量%以下であることがより好ましく、5質量%以下であることがさらに好ましく、下限は0質量%である。
Examples of such other ingredients include water, alcohols, oils and fats, gelling agents and stabilizers, emulsifiers, sequestering agents, sugars and sweeteners, sugar alcohols, starches, milk and dairy products, egg products, grains, inorganic salts, organic acid salts, enzymes, diglycerides, spices, spice extracts, herbs, dextrins such as linear dextrin, branched dextrin, and cyclic dextrin, various other food ingredients, anti-caking agents such as fine silicon dioxide, magnesium carbonate, disodium phosphate, and magnesium oxide, vitamins, gloss agents, flavorings, bittering agents, seasonings, and other taste components, colorants, preservatives, antioxidants, pH adjusters, organic acids, alkaline agents such as ammonium bicarbonate, and strengthening agents.
The texture improver for minced meat processed foods, etc. of the present invention may contain other ingredients other than the denatured lipid-protein complex within a range that does not inhibit the effects of the present invention, but it is preferable that the amount of other ingredients in the texture improver for minced meat processed foods, etc. of the present invention is 10% by mass or less, more preferably 8% by mass or less, and even more preferably 5% by mass or less, with the lower limit being 0% by mass.

[本発明の挽肉加工食品等食感改良剤の製造方法について]
本発明の挽肉加工食品等食感改良剤の製造方法は、好ましくは脂質と蛋白質を含有する水溶液を均質化する工程と、均質化された水溶液を緩慢冷凍する工程、又は120~150℃の加熱温度で1~20秒の間加熱する工程のいずれか1つ以上の工程を経る。
脂質と蛋白質を含有する水溶液の調製にかかる要件、該水溶液の均質化にかかる要件、均質化した水溶液の冷凍及び加熱を行う際の要件については、それぞれ上述のとおりである。
脂質と蛋白質を含有する水溶液を均質化する工程と、均質化した水溶液の冷凍又は加熱の工程のいずれか1つ以上との間では、本発明の挽肉加工食品等食感改良剤の効果を損ねない範囲で任意の工程をとることができ、例えば、冷却工程、追加の均質化工程、濾過工程、水分の除去等による濃縮工程、本発明の挽肉加工食品等食感改良剤が含有しうるその他成分を含有させる工程等のいずれか1つ以上をとることができる。
[About the method for producing the texture improver for ground meat processed foods, etc. of the present invention]
The method for producing the texture improver for ground meat processed foods of the present invention preferably includes a step of homogenizing an aqueous solution containing lipids and proteins, and a step of slowly freezing the homogenized aqueous solution, or heating at 120 to 150°C. One or more steps of heating at a temperature of 1 to 20 seconds are performed.
The requirements for preparing an aqueous solution containing lipids and proteins, the requirements for homogenizing the aqueous solution, and the requirements for freezing and heating the homogenized aqueous solution are as described above.
The effect of the texture improving agent for ground meat processed foods, etc. of the present invention may be impaired between the step of homogenizing the aqueous solution containing lipids and proteins and the step of freezing or heating the homogenized aqueous solution. For example, a cooling step, an additional homogenization step, a filtration step, a concentration step by removing moisture, etc., and other steps that may be contained in the texture improver of the ground meat processed food of the present invention. Any one or more of the steps of incorporating components can be taken.

また、均質化した水溶液の冷凍又は加熱の工程のいずれか1つ以上のあとにおいても、本発明の挽肉加工食品等食感改良剤の効果を損ねない範囲で任意の工程をとることができ、例えば、冷却工程、均質化工程、濾過工程、水分の除去等による濃縮工程(粉末化等、固形状の形態にすることを含む)、本発明の挽肉加工食品等食感改良剤が含有しうるその他成分を含有させる工程等のいずれか1つ以上をとることができる。
なお、均質化した水溶液の冷凍又は加熱の工程をいずれも経る場合には、冷凍工程よりも先に加熱工程を経ることが好ましい。
Furthermore, after any one or more of the steps of freezing or heating the homogenized aqueous solution, any step can be taken as long as it does not impair the effect of the texture improving agent for ground meat processed foods, etc. of the present invention. For example, a cooling process, a homogenization process, a filtration process, a concentration process by removing moisture (including powdering, etc., into a solid form), a texture improving agent for ground meat processed foods, etc. of the present invention may contain Any one or more of the steps of incorporating other components can be taken.
In addition, when the homogenized aqueous solution undergoes both freezing and heating steps, it is preferable to go through the heating step before the freezing step.

[本発明の挽肉加工食品又は畜肉代替食品について]
本発明の挽肉加工食品等食感改良剤を用いて挽肉加工食品等を製造することができる。本発明は、斯かる挽肉加工食品等も提供する。以下、本発明の挽肉加工食品等について述べる。
本発明における挽肉加工食品とは牛肉や豚肉、鶏肉等の挽肉、及び植物性蛋白質素材からなる群より選ばれた1種又は2種以上を含む挽肉加工食品生地を加熱処理して得られるものを指し、具体例としては、ハンバーグ、メンチカツ、肉団子、コロッケ、餃子、しゅうまい、肉まん、ソーセージ、ミートボール、つくね、ミートローフ、春巻き、肉入りオムレツ、ロールキャベツ、小籠包等が挙げられ、ハンバーグ、メンチカツ、肉団子、コロッケ、餃子、しゅうまい、肉まん及びソーセージ等からなる群より選ばれた1種が好ましく挙げられる。
[About the ground meat processed food or meat substitute food of the present invention]
Processed ground meat foods, etc. can be produced using the texture improving agent for processed ground meat foods, etc. of the present invention. The present invention also provides such ground meat processed foods. The ground meat processed food and the like of the present invention will be described below.
The ground meat processed food in the present invention refers to one obtained by heat-treating ground meat processed food dough containing one or more selected from the group consisting of ground meat such as beef, pork, and chicken, and vegetable protein materials. Specific examples include hamburgers, minced meat cutlets, meatballs, croquettes, gyoza, shumai, steamed buns, sausages, meatballs, meatballs, meatloaf, spring rolls, meat-filled omelets, cabbage rolls, xiao long bao, etc. Preferably, one type selected from the group consisting of minced meat cutlets, meat balls, croquettes, gyoza, shumai, meat buns, sausages, etc.

また、本発明における畜肉代替食品は、後述する植物性蛋白質素材を用いて、例えばブロック肉やスライス肉、こま切れ肉、成形肉、挽肉等の各種形態をとる畜肉を模して製造された畜肉代替食品材料を、さらに調理加工して製造されるものであり、その具体例としては、焼き肉やステーキ、ハンバーグ、煮込み料理、照り焼き又は炭火焼きなどの肉料理に用いられる畜肉を畜肉代替食品材料で一部または全部置換したものが挙げられる。
本発明の挽肉加工食品等は、例えば、上に例示したような挽肉加工食品等を製造する際に、後述する挽肉にした食肉、及び植物性蛋白質素材のうちから選ばれた1種以上と、上記の本発明の挽肉加工食品等食感改良剤とを含有し、混ぜ合わせて得られる挽肉加工食品等の生地(以下、単に「本発明の挽肉加工食品等生地」ともいう。)を加熱することで得られるものである。
好適な一実施形態において、本発明の挽肉加工食品等は、(1)後述する挽肉にした食肉、及び植物性蛋白質素材のうちから選ばれた1種以上と、上記の本発明の挽肉加工食品等食感改良剤を含む原料を混錬し挽肉加工食品等生地を調製する生地調製工程と、(2)調製された挽肉加工食品等生地を加熱する加熱工程とを含む方法にて製造することができる。
In addition, the meat substitute food of the present invention is produced by further cooking and processing meat substitute food materials produced to imitate meat in various forms such as block meat, sliced meat, minced meat, formed meat, minced meat, etc., using the vegetable protein material described below. Specific examples include meat used in meat dishes such as grilled meat, steak, hamburger, stews, teriyaki or charcoal grilled dishes, which are partially or completely replaced with the meat substitute food materials.
The minced meat processed food, etc. of the present invention can be obtained, for example, when producing the minced meat processed food, etc. exemplified above, by heating a dough for the minced meat processed food, etc. (hereinafter also referred to simply as "dough for the minced meat processed food, etc. of the present invention") obtained by mixing one or more selected from the minced meat and vegetable protein materials described below with the texture improver for the minced meat processed food, etc. of the present invention.
In a preferred embodiment, the minced meat processed food, etc. of the present invention can be produced by a method including: (1) a dough preparation step in which a dough is prepared for the minced meat processed food, etc. by kneading a raw material containing one or more selected from the minced meat and vegetable protein materials described below and the texture improver for the minced meat processed food, etc. of the present invention described above; and (2) a heating step in which the prepared dough for the minced meat processed food, etc. is heated.

以下、本発明の挽肉加工食品等の製造方法の各工程について述べる。 Each step of the method for producing ground meat processed foods, etc. of the present invention will be described below.

-工程(1)-
工程(1)は、後述する挽肉にした食肉、及び植物性蛋白質素材のうちから選ばれた1種以上と、上記の本発明の挽肉加工食品等食感改良剤を含む原料を混錬し挽肉加工食品等生地を調製する生地調製工程である。
上記のとおり、本発明の挽肉加工食品等生地は、挽肉にした食肉及び植物性蛋白質素材のうちから選ばれた1種以上を含むものである。
本発明に用いられる食肉としては、例えば牛肉、豚肉、鶏肉、羊肉、馬肉、鹿肉、猪肉、山羊肉、七面鳥肉等を挙げることができ、これら食肉の部位、グレード等に限定なく適用できる。
また、本発明に用いられる植物性蛋白質素材は、精製や分離等の処理により、蛋白質含有量が40質量%以上となるように高められたものであり、例えば大豆蛋白質、エンドウ豆蛋白質、そら豆蛋白質、緑豆蛋白質、ひよこ豆蛋白質、及びレンズ豆蛋白質からなる豆類蛋白質、小麦蛋白質等を挙げることができ、好ましくは大豆蛋白質、ひよこ豆蛋白質を挙げることができる。
-Process (1)-
Step (1) involves kneading the ground meat described below, one or more selected from vegetable protein materials, and the raw material containing the texture improver such as the ground meat processed food of the present invention described above to produce ground meat. This is a dough preparation process for preparing dough for processed foods.
As described above, the ground meat processed food dough of the present invention contains one or more selected from ground meat and vegetable protein materials.
Examples of the meat used in the present invention include beef, pork, chicken, mutton, horse meat, venison, boar meat, goat meat, turkey meat, etc., and the invention can be applied to any part, grade, etc. of these meats without limitation.
Furthermore, the vegetable protein material used in the present invention is one whose protein content has been increased to 40% by mass or more through processing such as purification and separation, and includes, for example, soybean protein, pea protein, and broad bean protein. Examples include legume proteins such as , mung bean protein, chickpea protein, and lentil protein, wheat protein, etc., and preferred examples include soybean protein and chickpea protein.

本発明の挽肉加工食品等生地中の、上記食肉や上記植物性蛋白質素材の含量は特に限定されないが、本発明の挽肉加工食品においては、少なくともいずれか1つ以上を含有する。
なお、植物性蛋白質素材を用いて本発明の挽肉加工食品等、特に畜肉代替食品を製造する場合には、植物性蛋白質素材を水戻ししてから用いることがパサつきの無い食感を得る観点から好ましく、植物性蛋白質素材を水戻ししたものと、水戻ししていないものとを併用することが、畜肉様の食感を得る観点から好ましい。
本発明の挽肉加工食品等には、本発明の効果を抑制しない範囲で、本発明の挽肉加工食品等食感改良剤や上記食肉、植物性蛋白質素材とは別に、適宜、乳化剤、ph調整剤、食塩やリン酸塩、グルタミン酸塩等の塩類、糖質、食物繊維、アミノ酸、トランスグルタミナーゼやプロテアーゼ等の酵素、ペッパーやスパイスミックス等の香辛料、ビーフエキスやベジタブルエキス等のエキス類、セロリやパセリ等のハーブ類、各種野菜や果実、香料、色素、酸化防止剤、水等の1種又は2種以上を含有させてもよい。
The contents of the above-mentioned meat and vegetable protein materials in the dough of the minced meat processed food, etc. of the present invention are not particularly limited, but the minced meat processed food of the present invention contains at least one of them.
When producing the minced meat processed food of the present invention, particularly a meat substitute food, using a vegetable protein material, it is preferable to reconstitute the vegetable protein material with water before use in order to obtain a texture that is not dry, and it is preferable to use a combination of vegetable protein material that has been reconstituted with water and that has not been reconstituted with water in order to obtain a texture similar to that of meat.
The minced meat processed food, etc. of the present invention may contain, in addition to the texture improving agent for minced meat processed food, etc. of the present invention and the above-mentioned meat and vegetable protein materials, as appropriate, one or more of the following: emulsifiers, pH adjusters, salts such as salt, phosphates, glutamates, etc., carbohydrates, dietary fiber, amino acids, enzymes such as transglutaminase and protease, spices such as pepper and spice mix, extracts such as beef extract and vegetable extract, herbs such as celery and parsley, various vegetables and fruits, flavorings, colorants, antioxidants, water, etc., within a range that does not inhibit the effects of the present invention.

本発明の挽肉加工食品等生地中の、本発明の挽肉加工食品等食感改良剤の含量は、求める作業性や食感によっても異なるが、良好な作業性やジューシー感を得る観点から、0.01~3質量%が好ましく、0.03~2質量%がより好ましく、0.05~1質量%がさらに好ましい。
上記範囲で本発明の挽肉加工食品等生地に、本発明の挽肉加工食品等食感改良剤が含有されていることで、挽肉加工食品類を製造する際の作業性が良く、また、喫食時のコク味やジューシーな食感が良好なものとなりやすい。
本発明の挽肉加工食品等生地は、上記原料をミキサーボール等にとり、混練することにより調製してよい。ここで、混練する方法は特に限定されず、ヘラやミキサー、エクストルーダを用いた混練等、任意の手法で混練してよい。
なお、エクストルーダで混錬する際には同時に加圧加熱を行ってもよく、この際に挽肉加工食品等生地の膨化を伴うものであってもよい。この加熱は工程(2)の加熱として扱わない。
The content of the texture improving agent for ground meat processed food, etc. of the present invention in the dough for ground meat processed food, etc. of the present invention varies depending on the desired workability and texture, but from the viewpoint of obtaining good workability and juicy feeling, the content is 0. It is preferably .01 to 3% by weight, more preferably 0.03 to 2% by weight, and even more preferably 0.05 to 1% by weight.
By containing the texture improving agent for ground meat processed foods, etc. of the present invention in the dough for ground meat processed foods, etc. of the present invention within the above range, workability when producing ground meat processed foods, etc. is good, and further, when eating. It tends to have a good rich flavor and juicy texture.
The dough of the ground meat processed food of the present invention may be prepared by placing the above-mentioned raw materials in a mixer ball or the like and kneading them. Here, the kneading method is not particularly limited, and any method such as kneading using a spatula, mixer, or extruder may be used.
Note that when kneading with an extruder, pressurization and heating may be performed at the same time, and at this time, the dough may be expanded, such as a ground meat processed food. This heating is not treated as heating in step (2).

-工程(2)-
工程(2)は、調製された挽肉加工食品等生地を加熱する加熱工程である。
本発明の挽肉加工食品等は、上記のようにして調製された挽肉加工食品等生地を、必要に応じて野菜や卵等のその他食材と共に、加熱することで製造される。
加熱方法は特に制限されず、例えば、焼成、油ちょう、ボイル、蒸し、過熱水蒸気加熱、電子レンジ加熱等の公知の方法で加熱してよく、加熱の途中又は加熱前後に調味してもよい。
加熱温度及び加熱時間等の各条件は、選択した原料の種類や挽肉加工食品等生地の配合、加熱方法等に応じて適宜調整し得るが、加熱温度は通常50~300℃であり、加熱時間は通常30秒間~3時間である。
なお、上記加熱に供する前に、挽肉加工食品等生地に対し成形や包餡を行ってもよい。
成形する際の形状は、板状や小判状、俵状や球状等の任意の形状としてよい。成形の手法は特に問わず、手技による成形であっても、型による成形であってもよい。また、押出成形であってもよい。
-Process (2)-
Step (2) is a heating step of heating the prepared dough for ground meat processed food or the like.
The ground meat processed food etc. of the present invention is produced by heating the ground meat processed food etc. dough prepared as described above together with other ingredients such as vegetables and eggs as necessary.
The heating method is not particularly limited, and for example, it may be heated by known methods such as baking, frying, boiling, steaming, heating with superheated steam, heating in a microwave oven, etc., and it may be seasoned during or before or after heating.
Conditions such as heating temperature and heating time can be adjusted as appropriate depending on the type of raw materials selected, the formulation of the dough such as ground meat processed food, the heating method, etc., but the heating temperature is usually 50 to 300°C, and the heating time is usually 30 seconds to 3 hours.
In addition, before being subjected to the above-mentioned heating, the dough, such as ground meat processed food, may be shaped or wrapped.
The shape at the time of molding may be any shape such as a plate, an oval shape, a bale shape, or a spherical shape. The molding method is not particularly limited, and may be manually molded or molded. Alternatively, extrusion molding may be used.

[本発明の挽肉加工食品等の食感改良方法について]
次に、本発明の挽肉加工食品等の食感改良方法について述べる。
本発明の挽肉加工食品等の食感改良方法は、挽肉加工食品等の製造時に本発明の挽肉加工食品等食感改良剤を挽肉加工食品等生地に含有させる工程を含むものである。
挽肉加工食品等の製造方法や本発明の挽肉加工食品等食感改良剤の添加方法や添加量については、上述のとおりである。
[Method for improving the texture of processed minced meat foods and the like according to the present invention]
Next, the method for improving the texture of processed minced meat foods and the like according to the present invention will be described.
The method for improving the texture of processed minced meat foods and the like of the present invention comprises the step of incorporating the texture improver for processed minced meat foods and the like of the present invention into dough for processed minced meat foods and the like during production of the processed minced meat foods and the like.
The method for producing processed minced meat foods and the like and the method and amount of addition of the texture improver for processed minced meat foods and the like of the present invention are as described above.

本発明の内容を以下の実施例、比較例等を用いて具体的に説明するが、本発明はこれらに何ら限定されるものではない。 The content of the present invention will be specifically explained using the following Examples, Comparative Examples, etc., but the present invention is not limited thereto.

<挽肉加工食品等食感改良剤の製造>
〔製造例1〕
大豆蛋白質(「profam(登録商標)974」:ADM社製)(蛋白質含有量85.0質量%、脂質含有量3.0質量%、水分含量6質量%)6質量部を、60℃に加温した水88質量部に加え、スリーワンモーターを使用して撹拌して十分に分散させた。
ここに粉末状大豆レシチン(脂質含有量99質量%、リン脂質含有量90質量%)を6質量部添加し、よく撹拌して十分に分散・乳化させ、予備乳化液を得た。
この予備乳化液をバルブ式ホモジナイザー(アルファラバル社製:ホモジナイザー)を用いて、30mpaの圧力で均質化した後、VTIS殺菌機(アルファラバル社製UHT殺菌機)で139℃・4秒間殺菌した後、5℃まで冷却した。
これを0.5℃/hの徐冷により、50時間かけて-20℃まで冷却し、凍結変性させた。これを凍結乾燥し、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Aを得た。
得られた挽肉加工食品等食感改良剤A中の複合体の含有量、挽肉加工食品等食感改良剤Aの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
<Production of texture improver for minced meat processed foods, etc.>
[Production Example 1]
Six parts by mass of soy protein ("Profam (registered trademark) 974" manufactured by ADM) (protein content 85.0% by mass, lipid content 3.0% by mass, moisture content 6% by mass) was added to 88 parts by mass of water heated to 60°C, and thoroughly dispersed by stirring using a three-one motor.
To this was added 6 parts by mass of powdered soybean lecithin (lipid content 99% by mass, phospholipid content 90% by mass), and thoroughly stirred to thoroughly disperse and emulsify, thereby obtaining a preliminary emulsion.
This preliminary emulsion was homogenized at a pressure of 30 MPa using a valve-type homogenizer (Alfa Laval homogenizer), then sterilized at 139°C for 4 seconds in a VTIS sterilizer (Alfa Laval UHT sterilizer), and then cooled to 5°C.
This was cooled slowly at 0.5°C/h to -20°C over 50 hours for freeze-denaturation, and then freeze-dried to obtain a powdered texture improver A for minced meat processed foods, etc., containing a frozen-denatured lipid-protein complex with a water content of 3% by mass.
The content of the complex in the obtained texture improver A for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver A for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例2〕
大豆蛋白質に代えてエンドウ豆蛋白質(「NUTRALYS(登録商標)S85F」:ロケット社製)(蛋白質含有量85.0質量%、脂質含有量7.0質量%、水分含量4質量%)を使用した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Bを得た。
得られた挽肉加工食品等食感改良剤B中の複合体の含有量、挽肉加工食品等食感改良剤Bの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 2]
A powdered texture improver B for processed minced meat foods, etc., containing a frozen-denatured lipid protein complex and having a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that pea protein ("NUTRALYS (registered trademark) S85F" manufactured by Roquette) (protein content 85.0% by mass, lipid content 7.0% by mass, moisture content 4% by mass) was used instead of soy protein.
The content of the complex in the obtained texture improver B for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver B for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例3〕
大豆蛋白質6質量部に代えて、そら豆蛋白質(「オルプロテインFP-AC」:オルガノフードテック株式会社製)(蛋白質含有量84.0質量%、脂質含有量5.0質量%、水分含量6質量%)6.3質量部を使用し、水88質量部を87.7質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Cを得た。
得られた挽肉加工食品等食感改良剤C中の複合体の含有量、挽肉加工食品等食感改良剤Cの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 3]
A powdered texture improver C for processed minced meat foods, etc. containing a frozen-denatured lipid protein complex with a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that 6.3 parts by mass of fava bean protein ("Orprotein FP-AC": manufactured by Organo Food Tech Co., Ltd.) (protein content 84.0% by mass, lipid content 5.0% by mass, moisture content 6% by mass) was used instead of 6 parts by mass of soy protein, and the water was changed from 88 parts by mass to 87.7 parts by mass.
The content of the complex in the obtained texture improver C for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver C for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例4〕
大豆蛋白質6質量部に代えて、緑豆蛋白質(「オルプロテインMP-AC」:オルガノフードテック株式会社製)(蛋白質含有量75.0質量%、脂質含有量6.0質量%、水分含量7質量%)7質量部を使用し、水88質量部を87質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Dを得た。
得られた挽肉加工食品等食感改良剤D中の複合体の含有量、挽肉加工食品等食感改良剤Dの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Manufacture example 4]
Instead of 6 parts by mass of soybean protein, mung bean protein ("Or Protein MP-AC", manufactured by Organo Food Tech Co., Ltd.) (protein content 75.0% by mass, lipid content 6.0% by mass, water content 7% by mass) Contains a freeze-denatured lipid-protein complex with a moisture content of 3% by mass, using the same formulation and manufacturing method as Production Example 1, except that 7 parts by mass (%) was used and 88 parts by mass of water was changed to 87 parts by mass. A powdered food texture improver D for ground meat processed foods was obtained.
The content of the complex in the obtained texture improving agent D for ground meat processed foods, the content of the complex in the solid content of the texture improving agent D for ground meat processed foods, and the content of the complex between protein and lipid in the complex. The mass ratios are listed in [Table 1].

〔製造例5〕
大豆蛋白質6質量部に代えて、ひよこ豆蛋白質(「オルプロテインCP-AC」:オルガノフードテック株式会社製)(蛋白質含有量63.0質量%、脂質含有量22質量%、水分含量7質量%)8.4質量部を使用し、水88質量部を85.6質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Eを得た。
得られた挽肉加工食品等食感改良剤E中の複合体の含有量、品質改良剤Eの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Manufacture example 5]
Instead of 6 parts by mass of soybean protein, chickpea protein ("Or Protein CP-AC": manufactured by Organo Food Tech Co., Ltd.) (protein content 63.0 mass%, lipid content 22 mass%, water content 7 mass%) ) 8.4 parts by mass was used, and the formulation and manufacturing method were the same as in Production Example 1, except that 88 parts by mass of water was changed to 85.6 parts by mass, and the water content was 3% by mass. A powdered texture improving agent E for ground meat processed foods containing minced meat was obtained.
Regarding the content of the complex in the obtained texture improver E for ground meat processed foods, the content of the complex in the solid content of the quality improver E, and the mass ratio of protein and lipid in the complex [Table 1].

〔製造例6〕
大豆蛋白質に代えて、ミルクプロテインコンセントレート(MPC)(「Promilk85」:イングレディア社製)(蛋白質含有量81.0質量%、脂質含有量1.0質量%、水分含量5質量%)を使用した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Fを得た。
得られた挽肉加工食品等食感改良剤F中の複合体の含有量、挽肉加工食品等食感改良剤Fの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 6]
A powdered texture improver F for processed minced meat foods, etc., containing a frozen denatured lipid protein complex with a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that milk protein concentrate (MPC) ("Promilk 85": manufactured by Ingredia) (protein content 81.0% by mass, lipid content 1.0% by mass, moisture content 5% by mass) was used instead of soy protein.
The content of the complex in the obtained texture improver F for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver F for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例7〕
粉末状大豆レシチンに代えて粉末状ヒマワリレシチン(脂質含有量100質量%、リン脂質含有量90質量%)を使用した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Gを得た。
得られた挽肉加工食品等食感改良剤G中の複合体の含有量、挽肉加工食品等食感改良剤Gの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 7]
A powdered texture improver G for processed minced meat foods, etc., containing a frozen denatured lipid protein complex having a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that powdered sunflower lecithin (lipid content 100% by mass, phospholipid content 90% by mass) was used instead of powdered soybean lecithin.
The content of the complex in the obtained texture improver G for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver G for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例8〕
粉末状大豆レシチン(脂質含有量100質量%、リン脂質含有量90質量%)を添加せず、且つ水88質量部を94質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、粉末状の挽肉加工食品等食感改良剤Hを得た。
得られた挽肉加工食品等食感改良剤H中の複合体の含有量、挽肉加工食品等食感改良剤Hの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production example 8]
With the same formulation and manufacturing method as Production Example 1, except that powdered soybean lecithin (lipid content 100% by mass, phospholipid content 90% by mass) was not added and 88 parts by mass of water was changed to 94 parts by mass. A powdered food texture improver H for ground meat processed foods, etc., having a water content of 3% by mass was obtained.
The content of the complex in the obtained texture improving agent H for ground meat processed foods, the content of the complex in the solid content of the texture improving agent H for ground meat processed foods, and the content of the complex between protein and lipid in the complex. The mass ratios are listed in [Table 1].

〔製造例9〕
製造例1における大豆蛋白質6質量部を11質量部に変更し、粉末状大豆レシチン6質量部を1質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Iを得た。
得られた挽肉加工食品等食感改良剤I中の複合体の含有量、挽肉加工食品等食感改良剤Iの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 9]
A powdered texture improver I for processed minced meat foods, etc., containing a frozen denatured lipid protein complex having a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that the amount of soy protein in Production Example 1 was changed from 6 parts by mass to 11 parts by mass and the amount of powdered soy lecithin in Production Example 1 was changed from 6 parts by mass to 1 part by mass.
The content of the complex in the obtained texture improver I for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver I for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例10〕
製造例1における大豆蛋白質6質量部を9.6質量部に変更し、粉末状大豆レシチン6質量部を2.4質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Jを得た。
得られた挽肉加工食品等食感改良剤J中の複合体の含有量、挽肉加工食品等食感改良剤Jの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 10]
A powdered texture improver J for processed minced meat foods, etc., containing a frozen denatured lipid protein complex having a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that the 6 parts by mass of soy protein in Production Example 1 was changed to 9.6 parts by mass and the 6 parts by mass of powdered soy lecithin was changed to 2.4 parts by mass.
The content of the complex in the obtained texture improver J for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver J for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例11〕
製造例1における大豆蛋白質6質量部を8質量部に変更し、粉末状大豆レシチン6質量部を4質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Kを得た。
得られた挽肉加工食品等食感改良剤K中の複合体の含有量、挽肉加工食品等食感Kの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 11]
A powdered texture improver K for processed minced meat foods, etc., containing a frozen denatured lipid protein complex having a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that the soy protein in Production Example 1 was changed from 6 parts by mass to 8 parts by mass and the powdered soy lecithin in Production Example 1 was changed from 6 parts by mass to 4 parts by mass.
The content of the complex in the obtained texture improver K for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver K for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例12〕
製造例1における大豆蛋白質6質量部を4質量部に変更し、粉末状大豆レシチン6質量部を8質量部に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Lを得た。
得られた挽肉加工食品等食感改良剤L中の複合体の含有量、挽肉加工食品等食感改良剤Lの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Production Example 12]
A powdered texture improver L for minced meat processed foods, etc., containing a frozen denatured lipid protein complex having a moisture content of 3% by mass was obtained using the same formulation and manufacturing method as in Production Example 1, except that the soy protein in Production Example 1 was changed from 6 parts by mass to 4 parts by mass and the powdered soy lecithin in Production Example 1 was changed from 6 parts by mass to 8 parts by mass.
The content of the complex in the obtained texture improver L for minced meat processed foods, etc., the content of the complex in the solid content of the texture improver L for minced meat processed foods, etc., and the mass ratio of protein to lipid in the complex are shown in Table 1.

〔製造例13〕
製造例1における冷却条件を0.5℃/hで25時間の徐冷から、5℃/hで2.5時間の急冷に変更した以外は製造例1と同様の配合及び製法で、水分含量が3質量%である、凍結変性脂質蛋白質複合体を含有する粉末状の挽肉加工食品等食感改良剤Mを得た。
得られた挽肉加工食品等食感改良剤M中の複合体の含有量、挽肉加工食品等食感改良剤Mの固形分中における複合体の含有量、及び、複合体における蛋白質と脂質との質量比について〔表1〕に記載した。
[Manufacture example 13]
The water content was A powdered texture improver M for ground meat processed foods containing a freeze-denatured lipid-protein complex having a content of 3% by mass was obtained.
The content of the complex in the obtained texture improving agent M for ground meat processed foods, the content of the complex in the solid content of the texture improving agent M for ground meat processed foods, and the content of the complex between protein and lipid in the complex. The mass ratios are listed in [Table 1].

<粘度測定試験>
製造例1~13で脂質蛋白質複合体製造時に、均質化後、冷凍するものと冷凍しないものに分け、冷凍工程後、-20℃に20時間保管後に、1℃/hの速度で解凍し、25℃の温度に達してのち10時間置き、この水溶液の25℃の粘度を、回転式粘度計を用いて測定した。
そして、冷凍しなかった場合の水溶液の粘度と比べて、粘度が低い場合を--、粘度が同一~1.5倍未満高かった場合を-、粘度が1.5倍以上2倍未満高かった場合を±、2倍以上3倍未満高かった場合を+、3倍以上4倍未満高かった場合を++、4倍以上高かった場合を+++とし、その結果を表2に記載した。
<Viscosity measurement test>
In production examples 1 to 13, when producing lipid protein complexes, after homogenization, divide into those to be frozen and those not to be frozen, and after the freezing process, store at -20 ° C. for 20 hours, then thaw at a rate of 1 ° C. / h, After reaching a temperature of 25°C, the solution was allowed to stand for 10 hours, and the viscosity of this aqueous solution at 25°C was measured using a rotational viscometer.
And, compared to the viscosity of the aqueous solution without freezing, if the viscosity is lower -, if the viscosity is the same to less than 1.5 times higher -, if the viscosity is 1.5 times or more and less than 2 times higher The results are shown in Table 2. The results are shown in Table 2. The results are shown in Table 2.

<検討:挽肉加工食品等であるハンバーグの製造>
本検討では、製造例1~13で製造された挽肉加工食品等食感改良剤のうち、挽肉加工食品等食感改良剤A,B,F,H,Mを抜粋して、これらを用いたハンバーグの製造を行い、その評価を行った。検討の際のハンバーグの配合は表3のとおりである。
<Study: Manufacture of hamburgers, which are ground meat processed foods, etc.>
In this study, among the texture improvers for ground meat processed foods manufactured in Production Examples 1 to 13, texture improvers A, B, F, H, and M for ground meat processed foods were selected and used. We manufactured hamburger steaks and evaluated them. The composition of the hamburger steak used in the study is shown in Table 3.

〔ハンバーグの製造〕
まず、ラードに挽肉加工食品等食感改良剤を充分に混合および分散させた。次に、合挽き肉(牛豚比7:3)、食塩、ソテーオニオン、全卵、パン粉、牛乳、水、粉末大豆たんぱく、および、上記で得たラードをミキサーボウルに投入し、卓上ミキサーを使用して充分に混合することにより、畜肉生地を得た。
上記で得られた畜肉生地を50g/個となるように成形し、オーブン(設定温度190℃)で10分間焼成することにより、ハンバーグを得た。ここで、上記のソテーオニオン(※1)は、キユーピー社製「オニオンアッセ60」であり、上記の粉末大豆たんぱく(※2)は、昭和産業社製「フレッシュCXフレーク」を事前に水で戻し、茹でこぼしたものである。
なお、表3に示すように、各畜肉生地の配合において、挽肉加工食品等食感改良剤を、同量のラードで置換した配合で同様に製造したハンバーグを、比較対象品(コントロール)とした。
[Production of hamburger steak]
First, the texture improver such as ground meat processed food was thoroughly mixed and dispersed in the lard. Next, the mixed ground meat (beef/pork ratio 7:3), salt, sauteed onion, whole egg, bread crumbs, milk, water, powdered soy protein, and the lard obtained above were put into a mixer bowl and thoroughly mixed using a tabletop mixer to obtain a meat dough.
The meat dough obtained above was molded into 50 g pieces and baked in an oven (set temperature 190° C.) for 10 minutes to obtain a hamburger steak. Here, the sauteed onion (*1) was "Onion Asse 60" manufactured by Kewpie Corporation, and the powdered soy protein (*2) was "Fresh CX Flakes" manufactured by Showa Sangyo Co., Ltd., which had been rehydrated in water and boiled.
As shown in Table 3, the texture improver for each meat dough was replaced with the same amount of lard to produce a hamburger steak similarly, which was used as a comparison product (control).

<評価方法>
上記のようにして製造された畜肉生地を成形するまでの作業性を下記評価基準に基づいて評価を行った。また、得られたハンバーグを食し、コントロールと比較した場合におけるジューシーな食感について官能評価を行い、各加工油脂が食品に与える効果を評価した。官能評価は、下記評価基準に基づき、12名のパネラーにより実施した。官能評価に先立ち、事前にパネラー間で各点数に対応する官能の程度をすり合わせた。
<Evaluation method>
The workability of the meat dough produced as described above until it was shaped was evaluated based on the following evaluation criteria. In addition, the resulting hamburger steaks were eaten and a sensory evaluation was performed on the juicy texture when compared with a control to evaluate the effects of each processed fat and oil on the food. The sensory evaluation was performed by 12 panelists based on the following evaluation criteria. Prior to the sensory evaluation, the panelists agreed on the sensory level corresponding to each score in advance.

<<評価基準:ハンバーグ生地の作業性>>
5点:コントロールと同等の作業性を有する生地である。
3点:コントロールと比較してややべたつく、あるいはやや緩い生地であるが問題にならない範囲である。
1点:コントロールと比較して、べたつく、あるいは緩い生地であり作業性が低い。
0点:コントロールと比較して、強くべたつく、過度に緩い生地であり、作業性が低い。
<<Evaluation criteria: Workability of hamburger dough>>
5 points: The fabric has workability equivalent to that of the control.
3 points: The dough is slightly sticky or slightly loose compared to the control, but it is within a range that does not pose a problem.
1 point: Compared to the control, the dough is sticky or loose and has low workability.
0 point: Compared to the control, the dough is strongly sticky and excessively loose, and the workability is low.

<<評価基準:ジューシーな食感>>
5点:コントロールと比較して、ジューシーな食感が非常に強い。
3点:コントロールと比較して、ジューシーな食感が強い。
1点:コントロールと比較して、ジューシーな食感が同等である。
0点:コントロールと比較して、ジューシーな食感が弱い。
評価結果は表4のとおりである。ジューシーな食感の評価の結果は、全パネラーの合計点に応じて、[54~60点:+++、44~53点:++、36~43点:+、28~35点:±、18~27点:-、0~17点:--]として表記した。ハンバーグ生地の作業性およびジューシーな食感のいずれにおいても、プラスマイナス記号「±」が1つ以上であれば、本発明の課題達成レベルと言える。
<<Evaluation criteria: Juicy texture>>
5 points: Very strong juicy texture compared to the control.
3 points: Strong juicy texture compared to the control.
1 point: Juicy texture is equivalent to the control.
0 points: Less juicy texture compared to the control.
The evaluation results are shown in Table 4. The evaluation results for juicy texture were expressed according to the total points of all panelists as follows: 54-60 points: +++, 44-53 points: ++, 36-43 points: +, 28-35 points: ±, 18-27 points: -, 0-17 points: --. In both the workability of the hamburger dough and the juicy texture, if there is one or more plus-minus signs "±", it can be said that the objective of the present invention is achieved.

Claims (7)

変性脂質蛋白質複合体を含有する、挽肉加工食品又は畜肉代替食品の食感改良剤。 A texture improver for processed minced meat foods or meat substitute foods, containing a modified lipid protein complex. 変性脂質蛋白質複合体が凍結変性脂質蛋白質複合体、又は加熱変性脂質蛋白質複合体である、請求項1記載の食感改良剤。 The texture improver according to claim 1, wherein the denatured lipid-protein complex is a frozen denatured lipid-protein complex or a heat denatured lipid-protein complex. 上記変性脂質蛋白質複合体を構成する脂質及び蛋白質が、以下の群から選択される1種又は2種以上である、請求項1又は2記載の食感改良剤。
[脂質]
トリグリセリド、ジグリセリド、モノグリセリド、リン脂質、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、及びポリグリセリン脂肪酸エステルからなる群
[蛋白質]
大豆蛋白質、エンドウ豆蛋白質、そら豆蛋白質、緑豆蛋白質、ひよこ豆蛋白質、及びレンズ豆蛋白質からなる豆類蛋白質の群
3. The texture improver according to claim 1, wherein the lipid and protein constituting the denatured lipid-protein complex are one or more types selected from the following group:
[Lipids]
The group consisting of triglycerides, diglycerides, monoglycerides, phospholipids, sorbitan fatty acid esters, propylene glycol fatty acid esters, sucrose fatty acid esters, and polyglycerol fatty acid esters [proteins]
The group of legume proteins consists of soybean protein, pea protein, fava bean protein, mung bean protein, chickpea protein, and lentil protein.
上記変性脂質蛋白質複合体を構成する脂質及び蛋白質の質量比が、蛋白質100質量部に対し脂質が10~250質量部である、請求項1に記載の食感改良剤。 The texture improving agent according to claim 1, wherein the mass ratio of lipid and protein constituting the modified lipid-protein complex is 10 to 250 parts by mass of lipid to 100 parts by mass of protein. 脂質及び蛋白質を含有する水溶液を均質化する工程を経た後に、均質化された水溶液を緩慢冷凍する工程、又は120~150℃の加熱温度で1~20秒の間加熱する工程のいずれか1つ以上の工程を経る、請求項1記載の食感改良剤の製造方法。 After passing through the step of homogenizing the aqueous solution containing lipids and proteins, either a step of slowly freezing the homogenized aqueous solution, or a step of heating the homogenized aqueous solution for 1 to 20 seconds at a heating temperature of 120 to 150 ° C. The method for producing a texture improver according to claim 1, which comprises the above steps. 請求項1記載の食感改良剤を含有する、挽肉加工食品又は畜肉代替食品。 A processed minced meat food or meat substitute food containing the texture improver according to claim 1. 請求項1記載の食感改良剤を含有させる、挽肉加工食品又は畜肉代替食品の食感改良方法。 A method for improving the texture of a ground meat processed food or a meat substitute food, which comprises containing the texture improving agent according to claim 1.
JP2022151164A 2022-09-22 2022-09-22 Texture improver for minced meat processed foods or meat substitute foods Pending JP2024046026A (en)

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