JP2024008756A - In-situ photocatalyst system - Google Patents
In-situ photocatalyst system Download PDFInfo
- Publication number
- JP2024008756A JP2024008756A JP2022121153A JP2022121153A JP2024008756A JP 2024008756 A JP2024008756 A JP 2024008756A JP 2022121153 A JP2022121153 A JP 2022121153A JP 2022121153 A JP2022121153 A JP 2022121153A JP 2024008756 A JP2024008756 A JP 2024008756A
- Authority
- JP
- Japan
- Prior art keywords
- light source
- airbag
- housing
- water
- sets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 29
- 239000011941 photocatalyst Substances 0.000 title abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 76
- 239000010802 sludge Substances 0.000 claims abstract description 27
- 239000003054 catalyst Substances 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims description 53
- 230000005540 biological transmission Effects 0.000 claims description 51
- 239000013307 optical fiber Substances 0.000 claims description 37
- 230000001699 photocatalysis Effects 0.000 claims description 11
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 6
- 238000004891 communication Methods 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract 3
- 239000010866 blackwater Substances 0.000 abstract 2
- 238000010586 diagram Methods 0.000 description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 230000009471 action Effects 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 230000033001 locomotion Effects 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 238000005067 remediation Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/004—Seals, connections
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/008—Mobile apparatus and plants, e.g. mounted on a vehicle
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/009—Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/08—Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/14—NH3-N
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Abstract
Description
本発明は光触媒の技術分野に関し、具体的には、インサイチュ光触媒システムに関する。 The present invention relates to the technical field of photocatalysis, and specifically to in-situ photocatalyst systems.
水が黒くて臭くなることは、生化学的な現象で、水が深刻な有機汚染を受けた場合、有機
物の好気分解により水中の酸素消費速度が再酸素化速度より大きくなり、水の酸素欠乏が
発生し、その結果として、有機物の分解が不完全になり、速度が遅くなり、嫌気性生分解
の過程で硫化水素、アンモニア、メルカプタンなどの発臭物質が生成されるとともに、黒
色物質が形成され、これにより、水が黒くて臭くなる。
水が黒くて臭くなることは深刻な水質汚染現象であり、水の使用機能を完全に喪失させ、
景観や人間の生活と健康に悪影響を与える。黒臭水や汚泥を光触媒処理する場合、黒臭水
や汚泥への光の透過を解決できないため、光触媒処理が困難であり、一方、化学的に処理
すると、新たな汚染物質が発生しやすく、生態系に影響を与えやすい。
The black and smelly water is a biochemical phenomenon; when water is seriously contaminated with organic matter, the rate of oxygen consumption in the water is greater than the rate of reoxygenation due to aerobic decomposition of organic matter, and the oxygen in the water is Deficiency occurs, resulting in incomplete and slow decomposition of organic matter, and odorous substances such as hydrogen sulfide, ammonia, and mercaptans are produced in the process of anaerobic biodegradation, as well as black matter. formation, which causes the water to become black and smelly.
Water becoming black and smelly is a serious water pollution phenomenon, which can completely lose the ability to use water,
It has a negative impact on the landscape and human life and health. Photocatalytic treatment of black-smelling water and sludge is difficult because it cannot solve the problem of light passing through the black-smelling water and sludge.On the other hand, chemical treatment tends to generate new pollutants. Easy to affect the ecosystem.
上記の技術的課題を解决するために、本発明はインサイチュ光触媒システムを提供する。 In order to solve the above technical problems, the present invention provides an in-situ photocatalytic system.
本発明の技術的解決手段は以下のとおりである。インサイチュ光触媒システムであって、
光源を提供するための光源モジュールと、触媒を担持するための光ファイバとを含み、前
記光ファイバの一端は前記光源モジュールの出光口に突き合わされ、光ファイバの他端は
水中に入り、
前記触媒はＴｉＯ２、ＢｉＯ２のうちのいずれか１種であり、前記ＴｉＯ２は窒素ドープ
ＴｉＯ２を用い、
触媒は浸漬か焼(calcination）（ある物質を強く熱して脱水・分解などを起こさせ、揮発
成分を除くこと）、ゲル塗布法のうちのいずれか１種の方式で前記光ファイバ上に担持さ
れる。ＴｉＯ２は紫外線帯でしか励起できず、一方、窒素ドープＴｉＯ２は太陽光で励起
でき、このため、自然環境で使用される場合、窒素ドープＴｉＯ２の適用範囲がより広い
。
本発明の一態様によれば、前記水は黒臭水又は汚泥水である。
本発明の一態様によれば、前記光ファイバは、以下の２つの形態を採用する。
１）前記黒臭水の場合、光ファイバを水草を模倣した形状として黒臭水に配置させる。光
ファイバを水草を模倣した形状とすることにより、生態系への影響を低減させ、夜に発光
木とすることで、外観性や実用性を良好にする。
２）前記汚泥水の場合、光ファイバを汚泥水の汚泥にドットマトリックス状に分散させる
。金属ケーシングのようなものを利用して淤泥内に送り、次に金属ケーシングを取り出し
、光ファイバを淤泥に放射状に配置させることにより、日光が汚泥に直接当たらないとい
う問題を解決し、しかも、汚泥水の処理効率を向上させ、汚染物の光分解を促進する。
本発明の一態様によれば、前記光源モジュールは、近地光源装置又はフロート光源装置を
用い、前記フロート光源装置は光源ユニットとフロートスタビライザを含み、前記近地光
源装置、光源ユニットはいずれも自己発光光源又は集光器のうちのいずれか１種である。
インサイチュ光触媒システムは、黒臭水や汚泥水の実際の環境のニーズに応じて選択され
る。
本発明の一態様によれば、前記フロートスタビライザは、ハウジングと、２組の伝動リン
グと、中心棒とを含み、
前記ハウジングは、内部が中空であり、中心に前記中心棒が揺動するための中心筒体が設
けられ、２組の前記伝動リングはそれぞれハウジングの内天面、内底面に設けられ、かつ
２組の伝動リングはそれぞれ中心筒体に回動可能に套設され、
前記中心筒体内の中央部に載置板が設けられ、前記載置板の中心に、前記中心棒に設けら
れるボールに回動可能に嵌合されるソケットが設けられ、
前記中心棒の一端には光源ユニットに接続される接続台が設けられ、中心棒の他端には中
心棒にねじ接続されるカウンターウェイトが設けられ、かつ中心棒には光ファイバが中心
棒を貫通する連通孔が設けられ、
前記接続台は放射状に配置された複数組の第１エアバッグを介してハウジングに接続され
、複数組の前記第１エアバッグは、全て一端が接続台に接続され、他端がハウジングに接
続され、
２組の伝動リングの間に位置するハウジングの内側壁に少なくとも１組の駆動歯車が回動
可能に設けられ、かつ伝動リングには前記駆動歯車と噛み合う歯ディスクが設けられる。
上記フロートスタビライザの構成によれば、単一の駆動の下で、２組の伝動リングを利用
して時計回り及び反時計回りで回動することができ、これによって、２組の伝動リングが
回動することで安定的な動的バランスが取られ、フロート光源装置が横転するリスクが回
避される。
本発明の１つの好適な態様としては、前記ハウジングの側壁には、第１エアバッグに１対
１で対応する複数組の分流管が設けられ、前記分流管はチューブを介してその向かい側に
設けられる第１エアバッグに接続され、
前記伝動リングの側壁に環状溝が設けられ、前記分流管の上部と下部のそれぞれに、対応
する環状溝に入る１組の第２エアバッグが設けられ、
環状溝の内底部に位置する前記伝動リング内に、各第２エアバッグに１対１で対応する皿
穴が設けられ、前記皿穴内にカウンターウェイトスライダがスライド可能に設けられ、前
記カウンターウェイトスライダの一方の側面はばねを介して皿穴の内底部に接続され、カ
ウンターウェイトスライダの他方の側面に円弧状シートが設けられ、かつ前記皿穴の両側
の伝動リングに、円弧状シートの案内ロッドにスライド可能に接続される１組の案内溝が
それぞれ設けられ、
前記円弧状シートと第２エアバッグとの間にある環状溝内に弾性リングが設けられ、前記
弾性リングは第２エアバッグの端面にスライド可能に接続され、
前記ハウジングには、各チューブを覆うカバーが設けられ、かつ前記カバーの表面にソー
ラーパネル又は電池のうちの少なくとも１種が敷設され、かつハウジングには、前記駆動
歯車の軸棒に突き合わされる駆動モータが設けられ、前記駆動モータはリレーを介してソ
ーラーパネル又は電池に接続される。
フロートスタビライザを基にして、第１エアバッグと連携する分流管が複数組配置され、
伝動リングの内部構造を改良することにより、複数組のカウンターウェイトスライダなど
の部材を利用して、水面に大きな波動が発生したときに、伝動リングの重心を調整するこ
とで、フロートスタビライザが横転するリスクを大幅に低減させる。
本発明の別の好適な態様としては、前記ハウジングの側壁には、第１エアバッグに１対１
で対応する複数組のスタビライザが設けられ、
前記スタビライザは、回動ロッドと、回動ブッシュと、第３エアバッグとを含み、前記回
動ブッシュはハウジングの側壁に設けられる固定ブロックに回動可能に接続され、前記回
動ロッドの側壁に少なくとも１組の制限リブが設けられ、回動ロッドは前記回動ブッシュ
にスライド可能に係合され、前記回動ブッシュの内側壁に制限リブと嵌合する制限溝が設
けられ、
前記第３エアバッグの一端は回動ロッドの一端に回動可能に接続され、回動ロッドの他端
には少なくとも１組の円板が套設され、前記第３エアバッグの他端はチューブを介して対
応する第１エアバッグに接続され、
前記駆動歯車は複数組設けられ、かつ第１エアバッグに１対１で対応しており、駆動歯車
の出力軸はハウジングを貫通しており、第１傘歯車に接続され、前記回動ブッシュには、
第１傘歯車と噛み合って伝動する第２傘歯車が套設され、
少なくとも１組の前記固定ブロックには、回動ブッシュに接続されるリングモータが設け
られ、前記ハウジングにソーラーパネル又は電池のうちの少なくとも１種が敷設され、前
記リングモータはリレーを介してソーラーパネル又は電池に接続される。
フロートスタビライザを基に、第１エアバッグと連携する複数組のスタビライザが配置さ
れることによって、スタビライザと伝動リングとの連動により、駆動モータの配置数が大
幅に減少し、円板が水中で回動することで安定的な動的バランスが取られ、しかも、第３
エアバッグなどの部材が設けられることで、水面で大きな波動が発生したときに、水の深
さが小さすぎることによりスタビライザの円板が底部に接触したり水面から離れたりする
という問題を効果的に回避する。
The technical solutions of the present invention are as follows. An in-situ photocatalytic system,
a light source module for providing a light source; and an optical fiber for supporting a catalyst; one end of the optical fiber is butted against a light exit of the light source module, and the other end of the optical fiber is submerged in water;
The catalyst is one of TiO 2 and BiO 2 , and the TiO 2 is nitrogen-doped TiO 2 .
The catalyst is supported on the optical fiber by one of immersion calcination (strongly heating a substance to cause dehydration and decomposition to remove volatile components) and gel coating. Ru. TiO2 can only be excited in the ultraviolet range, while nitrogen-doped TiO2 can be excited in sunlight, so the scope of application of nitrogen-doped TiO2 is wider when used in natural environments.
According to one aspect of the present invention, the water is black-smelling water or sludge water.
According to one aspect of the present invention, the optical fiber adopts the following two forms.
1) In the case of the dark-smelling water, an optical fiber is placed in the dark-smelling water in a shape that imitates aquatic plants. By making the optical fiber into a shape that imitates aquatic plants, the impact on the ecosystem is reduced, and by making it a tree that emits light at night, it improves the appearance and practicality.
2) In the case of the sludge water, optical fibers are dispersed in the sludge of the sludge water in the form of a dot matrix. By using something like a metal casing to send it into the sludge, then taking out the metal casing and arranging the optical fibers radially in the sludge, we solved the problem of sunlight not directly hitting the sludge. Improve water treatment efficiency and promote photodegradation of pollutants.
According to one aspect of the present invention, the light source module uses a near-field light source device or a float light source device, the float light source device includes a light source unit and a float stabilizer, and the near-field light source device and the light source unit are both self-contained. It is either a light emitting source or a concentrator.
The in-situ photocatalytic system is selected according to the actual environmental needs of black-smelling water and sludge water.
According to one aspect of the present invention, the float stabilizer includes a housing, two sets of transmission rings, and a center rod,
The housing is hollow inside, and is provided with a central cylindrical body in the center for swinging the center rod, and the two sets of transmission rings are respectively provided on the inner top surface and the inner bottom surface of the housing, and two Each set of transmission rings is rotatably mounted on a central cylinder,
A mounting plate is provided at the center of the center cylinder, and a socket is provided at the center of the mounting plate, and is rotatably fitted to a ball provided on the center rod.
A connection stand connected to the light source unit is provided at one end of the center rod, a counterweight is provided at the other end of the center rod and screwed to the center rod, and an optical fiber is connected to the center rod. A penetrating communication hole is provided,
The connection base is connected to the housing via a plurality of sets of first airbags arranged radially, and each of the plurality of sets of first airbags has one end connected to the connection base and the other end connected to the housing. ,
At least one set of drive gears is rotatably mounted on the inner wall of the housing located between the two sets of transmission rings, and the transmission ring is provided with a toothed disc meshing with said drive gears.
According to the configuration of the float stabilizer, it is possible to rotate clockwise and counterclockwise using two sets of transmission rings under a single drive, and thereby the two sets of transmission rings rotate. By moving, a stable dynamic balance is achieved and the risk of the float light source device tipping over is avoided.
In one preferred aspect of the present invention, a plurality of sets of branch pipes are provided on the side wall of the housing and correspond to the first airbags on a one-to-one basis, and the branch pipes are provided on the opposite side of the first airbag via a tube. connected to the first airbag,
An annular groove is provided in the side wall of the transmission ring, and a pair of second air bags are provided in the upper and lower parts of the diverter pipe, respectively, and fit into the corresponding annular grooves;
A countersink is provided in the transmission ring located at the inner bottom of the annular groove and corresponds to each second airbag on a one-to-one basis, a counterweight slider is slidably provided in the countersink, and the counterweight slider One side of the counterweight slider is connected to the inner bottom of the countersink via a spring, an arc-shaped seat is provided on the other side of the counterweight slider, and a guide rod of the arc-shaped seat is provided in the transmission ring on both sides of the countersink. a pair of guide grooves each slidably connected to the guide grooves;
an elastic ring is provided in an annular groove between the arcuate seat and the second airbag, and the elastic ring is slidably connected to an end surface of the second airbag;
The housing is provided with a cover that covers each tube, and at least one of a solar panel or a battery is laid on the surface of the cover, and the housing is provided with a drive that is butted against the shaft of the drive gear. A motor is provided, said drive motor being connected to a solar panel or battery via a relay.
Based on the float stabilizer, multiple sets of diverter pipes are arranged to cooperate with the first airbag,
By improving the internal structure of the transmission ring, multiple sets of counterweight sliders and other members are used to adjust the center of gravity of the transmission ring when large waves occur on the water surface, thereby preventing the float stabilizer from overturning. Significantly reduce risk.
In another preferred aspect of the present invention, the side wall of the housing is provided with one-to-one support for the first airbag.
There are multiple sets of stabilizers that correspond to
The stabilizer includes a rotating rod, a rotating bush, and a third airbag, and the rotating bush is rotatably connected to a fixed block provided on a side wall of the housing, and the rotating bush is rotatably connected to a fixed block provided on a side wall of the housing. at least one set of restriction ribs are provided, a pivot rod is slidably engaged with the pivot bushing, and an inner wall of the pivot bush is provided with a limitation groove that engages with the limitation ribs;
One end of the third airbag is rotatably connected to one end of a rotating rod, the other end of the rotating rod is sheathed with at least one set of discs, and the other end of the third airbag is connected to a tube. connected to the corresponding first airbag via the
A plurality of sets of the drive gears are provided and correspond to the first airbag on a one-to-one basis, and an output shaft of the drive gear passes through the housing, is connected to the first bevel gear, and is connected to the rotation bush. teeth,
A second bevel gear that meshes with the first bevel gear to transmit transmission is provided,
At least one set of the fixed blocks is provided with a ring motor connected to a rotating bush, at least one of a solar panel or a battery is installed in the housing, and the ring motor is connected to the solar panel through a relay. Or connected to a battery.
By arranging multiple sets of stabilizers based on the float stabilizer that cooperate with the first airbag, the number of drive motors to be arranged is significantly reduced due to the interlocking of the stabilizer and the transmission ring, and the disc rotates underwater. By moving, a stable dynamic balance is achieved, and the third
By installing components such as airbags, it effectively solves the problem of the stabilizer disc touching the bottom or separating from the water surface due to the water depth being too small when large waves occur on the water surface. to avoid.
本発明の有益な効果は以下のとおりである。
（１）本発明のインサイチュ光触媒システムでは、光源モジュールと光ファイバとを組み
合わせて使用することにより、日光が黒臭水や汚泥に直接当たらないという問題を効果的
に解決し、汚染物を光分解するための新しい処理方式を提供し、インサイチュ汚染修復を
クリーンエネルギーで環境に優しく行うことができる。
（２）本発明のインサイチュ光触媒システムでは、複数の配置形態が提供されるので、イ
ンサイチュ光触媒システムは黒臭水や汚泥水の実際の環境のニーズに応じて選択され得る
。
（３）本発明のインサイチュ光触媒システムでは、フロートスタビライザが設けられるこ
とによって、フロート光源装置の水面への配置の安定性が向上し、水面の波動により搭載
された集光器の集光効率が影響を受けることが回避され、また、フロート光源装置が横転
するリスクも効果的に回避される。
The beneficial effects of the present invention are as follows.
(1) The in-situ photocatalyst system of the present invention uses a light source module and an optical fiber in combination to effectively solve the problem of sunlight not directly hitting dark-smelling water and sludge, and photodecomposes pollutants. In-situ pollution remediation can be done in an environmentally friendly manner using clean energy.
(2) The in-situ photocatalyst system of the present invention provides multiple configurations, so the in-situ photocatalyst system can be selected according to the actual environmental needs of black-smelling water and sludge water.
(3) In the in-situ photocatalyst system of the present invention, by providing a float stabilizer, the stability of the arrangement of the float light source device on the water surface is improved, and the light collection efficiency of the mounted light collector is affected by the wave motion of the water surface. In addition, the risk of the float light source device being overturned is also effectively avoided.
以下、本発明の優位性をよりよく示すために、特定実施方式を参照して本発明についてさ
らに説明する。
実施例１
図１に示すように、インサイチュ光触媒システムは、光源を提供するための光源モジュー
ルと、触媒を担持するための光ファイバとを含み、光ファイバの一端は光源モジュールの
出光口に突き合わされ、光ファイバの他端は水中に入り、
光源モジュールは近地光源装置１、具体的には自己発光光源を用い、触媒は窒素ドープＴ
ｉＯ２であり、窒素ドープＴｉＯ２はゲル塗布法で光ファイバ上に担持され、
水は汚泥水であり、汚泥水の場合、光ファイバは汚泥水の汚泥にドットマトリックス状に
分散しており、
上記ドットマトリックス状にする方法は以下のとおりである。光ファイバの一端を自己発
光光源に接続し、光ファイバの他端を金属ケーシング内に入れて汚泥内に送り、次に、金
属ケーシングを取り出し、このように、光ファイバを汚泥に放射状に配置させる。
Hereinafter, the present invention will be further described with reference to specific implementations, in order to better demonstrate the advantages of the present invention.
Example 1
As shown in FIG. 1, the in-situ photocatalyst system includes a light source module for providing a light source and an optical fiber for supporting a catalyst, one end of the optical fiber is butted against the light exit of the light source module, and the optical fiber The other end goes into the water,
The light source module uses a near-field light source device 1, specifically a self-luminous light source, and the catalyst is nitrogen-doped T.
iO2 , nitrogen-doped TiO2 is supported on the optical fiber by gel coating method,
The water is sludge water, and in the case of sludge water, optical fibers are dispersed in the sludge in the form of a dot matrix.
The method for forming the dot matrix is as follows. Connect one end of the optical fiber to a self-luminous light source, put the other end of the optical fiber inside the metal casing and send it into the sludge, then take out the metal casing and in this way, make the optical fibers radially arranged in the sludge. .
実施例２
本実施例は、図２に示すように、水は黒臭水であり、黒臭水の場合、光ファイバを水草を
模倣した形状として黒臭水に配置させる以外、実施例１と同様である。
Example 2
This example is the same as Example 1 except that, as shown in FIG. 2, the water is black-smelling water, and in the case of black-smelling water, the optical fiber is arranged in the dark-smelling water in a shape that imitates aquatic plants. .
実施例３
本実施例は、図３に示すように、光源モジュールは近地光源装置１、具体的には集光器を
用いる以外、実施例１と同様である。
Example 3
As shown in FIG. 3, this example is the same as Example 1 except that the light source module uses a nearby light source device 1, specifically a condenser.
実施例４
本実施例は、図４に示すように、光源モジュールは近地光源装置１、具体的には集光器を
用いる以外、実施例２と同様である。
Example 4
As shown in FIG. 4, this embodiment is the same as the second embodiment except that the light source module uses a near-field light source device 1, specifically a condenser.
実施例５
本実施例は、以下のこと以外、実施例３と同様である。図５、図９に示すように、光源モ
ジュールはフロート光源装置２を用い、フロート光源装置２は光源ユニット３とフロート
スタビライザ４とを含み、光源ユニット３は、具体的には集光器である。
図１０、図１１に示すように、フロートスタビライザ４はハウジング４１と、２組の伝動
リング４２と、中心棒４３とを含み、ハウジング４１は、内部が中空であり、中心に中心
棒４３が揺動するための中心筒体４１１が設けられ、２組の伝動リング４２はそれぞれハ
ウジング４１の内天面、内底面に設けられ、かつ２組の伝動リング４２はそれぞれその内
側壁を介して中心筒体４１１に回動可能に套設される。
図２２に示すように、中心筒体４１１内の中央部に載置板４４が設けられ、載置板４４の
中心に、中心棒４３に設けられるボール４３１に回動可能に嵌合されるソケット４４１が
設けられる。
図１１に示すように、中心棒４３の上端には光源ユニット３に接続される接続台４３２が
設けられ、中心棒４３の下端には中心棒４３にねじ接続されるカウンターウェイト４３３
が設けられ、カウンターウェイト４３３は、実際の使用のニーズに応じて複数の中心棒４
３に套設されてもよく、かつカウンターウェイト４３３は中心棒４３にねじ接続され、中
心棒４３に光ファイバが中心棒４３を貫通する連通孔が設けられる。
図１１に示すように、接続台４３２は、放射状に配置された１２組の第１エアバッグ４５
を介してハウジング４１に接続され、１２組の第１エアバッグ４５は、一端が接続台４３
２に接続され、他端がハウジング４１に接続される。
図１２に示すように、２組の伝動リング４２の間に位置するハウジング４１の内側壁に３
組の駆動歯車４６が設けられ、かつ３組の駆動歯車４６は互いに１２０°をなして設けら
れ、これによって、フロートスタビライザ４の重りの安定性が確保され、かつ伝動リング
４２には駆動歯車４６と噛み合う歯ディスク４２１が設けられる。
図１３、図１５に示すように、ハウジング４１の側壁には、第１エアバッグ４５に１対１
で対応する１２組の分流管４７が設けられ、各組の分流管４７はチューブを介してその向
かい側に設けられる第１エアバッグ４５に接続され、伝動リング４２の外側壁に環状溝４
２２が設けられ、分流管４７の上部と下部のそれぞれに、対応する環状溝４２２に入る１
組の第２エアバッグ４７１が設けられる。
図１３、図１４に示すように、環状溝４２２の内底部に位置する伝動リング４２内に、各
第２エアバッグ４７１に１対１で対応する皿穴４２３が設けられ、皿穴４２３内にカウン
ターウェイトスライダ４２４がスライド可能に設けられ、カウンターウェイトスライダ４
２４の一方の側面は２組のばね４２５を介して皿穴４２３の内底部に接続され、カウンタ
ーウェイトスライダ４２４の他方の側面に円弧状シート４２６が設けられ、かつ皿穴４２
３の両側の伝動リング４２に、円弧状シート４２６の案内ロッドにスライド可能に接続さ
れる１組の案内溝４２７がそれぞれ設けられる。
図１３に示すように、円弧状シート４２６と第２エアバッグ４７１との間にある環状溝４
２２内に弾性リング４２８が設けられ、弾性リング４２８は第２エアバッグ４７１の端面
にスライド可能に接続される。
図１０、図１１に示すように、ハウジング４１には、各チューブを覆うカバー４１２が設
けられ、かつカバー４１２の表面にソーラーパネル又は電池が間隔を空けて千鳥状に敷設
され、電池は表面に断熱板が覆われた市販のリチウム電池を用い、かつハウジング４１に
は、駆動歯車４６の軸棒に突き合わされる駆動モータが設けられ、駆動モータはリレーを
介してソーラーパネル又は電池に接続され、リレー及び駆動モータは、市販品、又は本装
置への装着に適するように市販の回動モータ、市販リレーの外形を調整したものを用い、
ハウジング４１、伝動リング４２はいずれも硬質フォームで製造されてもよく、これによ
り、フロートスタビライザ４の水面での浮力が確保される。
上記フロートスタビライザ４の作動原理は以下のとおりである。
集光器の底部を接続台４３２に係合して固定し、集光器が接続する光ファイバの他端を中
心棒４３に設けられた連通孔に通し、金属ケーシング内に入れて汚泥内に送り、次に、金
属ケーシングを取り出し、光ファイバを汚泥に放射状に配置させる。
駆動モータを起動して、駆動歯車４６を回動させ、駆動歯車４６と２組の伝動リング４２
の歯ディスク４２１による伝動の作用により、２組の伝動リング４２をそれぞれ時計回り
、反時計回りで回動させ、安定的な動的バランスを取る。
水面で大きな波動が発生したときに、中心棒４３の作用により集光器は常に重心方向に垂
直であり、このとき、ハウジング４１の関連部材は中心棒４３のボール４３１及び載置板
４４のソケット４４１による作用を受けて揺動し、揺動中、ハウジング４１と接続台４３
２との間の第１エアバッグ４５は押されたり引っ張らたりする。
分流管４７の第２エアバッグ４７１と第１エアバッグ４５とにより形成される動的バラン
スが取られたキャビティにおいて、例えば、第１エアバッグ４５が押された場合、第１エ
アバッグ４５に対して１８０°となるように設けられた第２エアバッグ４７１は延出し、
延出した状態で、第２エアバッグ４７１はカウンターウェイトスライダ４２４側へ弾性リ
ング４２８を押す。
よって、上記の作用により、伝動リング４２の重心がずれて、即ち、図１０に示すように
、ハウジング４１が左側へ下向きに傾斜すると、左側のカウンターウェイトスライダ４２
４は伝動リング４２の重心により接近し、右側のカウンターウェイトスライダ４２４は伝
動リング４２の重心からより離れ、このとき、伝動リング４２が回動すると、フロートス
タビライザ４が横転するリスクが大幅に低減される。
Example 5
This example is the same as Example 3 except for the following. As shown in FIGS. 5 and 9, the light source module uses a float light source device 2, and the float light source device 2 includes a light source unit 3 and a float stabilizer 4, and the light source unit 3 is specifically a light condenser. .
As shown in FIGS. 10 and 11, the float stabilizer 4 includes a housing 41, two sets of transmission rings 42, and a center rod 43. The housing 41 is hollow inside, and the center rod 43 swings in the center. A central cylindrical body 411 for movement is provided, two sets of transmission rings 42 are respectively provided on the inner top surface and the inner bottom surface of the housing 41, and the two sets of transmission rings 42 are connected to the center cylinder through their inner walls. It is rotatably mounted on the body 411.
As shown in FIG. 22, a mounting plate 44 is provided at the center of the central cylindrical body 411, and a socket rotatably fitted to a ball 431 provided on the center rod 43 at the center of the mounting plate 44. 441 is provided.
As shown in FIG. 11, a connection stand 432 connected to the light source unit 3 is provided at the upper end of the center rod 43, and a counterweight 433 is screwed to the center rod 43 at the lower end of the center rod 43.
is provided, and the counterweight 433 has a plurality of center rods 4 according to the needs of actual use.
3, the counterweight 433 is screwed to the center rod 43, and the center rod 43 is provided with a communication hole through which the optical fiber passes through the center rod 43.
As shown in FIG. 11, the connection stand 432 connects 12 sets of first airbags 45 arranged radially.
The 12 sets of first airbags 45 are connected to the housing 41 via the connecting base 43 at one end.
2, and the other end is connected to the housing 41.
As shown in FIG. 12, three
Three sets of drive gears 46 are provided, and the three sets of drive gears 46 are arranged at 120° to each other, thereby ensuring the stability of the weight of the float stabilizer 4, and the transmission ring 42 has two sets of drive gears 46. A toothed disc 421 is provided which meshes with.
As shown in FIGS. 13 and 15, on the side wall of the housing 41, there is a
12 sets of corresponding branch pipes 47 are provided, and each set of branch pipes 47 is connected to the first air bag 45 provided on the opposite side via a tube, and an annular groove 4 is formed in the outer wall of the transmission ring 42.
22 are provided in the upper and lower parts of the branch pipe 47, respectively, and a groove 1 that enters the corresponding annular groove 422 is provided.
A set of second airbags 471 is provided.
As shown in FIGS. 13 and 14, countersinks 423 are provided in the transmission ring 42 located at the inner bottom of the annular groove 422, and correspond to each second airbag 471 on a one-to-one basis. A counterweight slider 424 is slidably provided, and the counterweight slider 4
One side of the counterweight slider 424 is connected to the inner bottom of the countersink 423 via two sets of springs 425, and an arcuate sheet 426 is provided on the other side of the counterweight slider 424.
A pair of guide grooves 427 are respectively provided on the transmission rings 42 on both sides of the drive ring 3, which are slidably connected to the guide rods of the arcuate seat 426.
As shown in FIG. 13, the annular groove 4 between the arcuate seat 426 and the second airbag 471
An elastic ring 428 is provided within the second airbag 471, and the elastic ring 428 is slidably connected to the end surface of the second airbag 471.
As shown in FIGS. 10 and 11, the housing 41 is provided with a cover 412 that covers each tube, and solar panels or batteries are laid on the surface of the cover 412 in a staggered manner at intervals. A commercially available lithium battery covered with a heat insulating plate is used, and the housing 41 is provided with a drive motor that butts against the shaft of the drive gear 46, and the drive motor is connected to a solar panel or battery via a relay. The relay and drive motor are commercially available products, or commercially available rotary motors and commercially available relays with external shapes adjusted to suit installation on this device.
Both the housing 41 and the transmission ring 42 may be made of rigid foam, thereby ensuring the buoyancy of the float stabilizer 4 on the water surface.
The operating principle of the float stabilizer 4 is as follows.
The bottom of the condenser is engaged with and fixed to the connection base 432, and the other end of the optical fiber to which the condenser is connected is passed through the communication hole provided in the center rod 43, placed into the metal casing, and placed into the sludge. The metal casing is then removed and the optical fibers are placed radially into the sludge.
The drive motor is started to rotate the drive gear 46, and the drive gear 46 and the two sets of transmission rings 42 are connected to each other.
The two sets of transmission rings 42 are rotated clockwise and counterclockwise by the action of the transmission by the toothed disc 421, respectively, to maintain a stable dynamic balance.
When large waves occur on the water surface, the condenser is always perpendicular to the center of gravity due to the action of the center rod 43, and at this time, the related members of the housing 41 are the ball 431 of the center rod 43 and the socket of the mounting plate 44. 441, and during the swing, the housing 41 and the connection base 43
The first airbag 45 between the two is pushed or pulled.
In the dynamically balanced cavity formed by the second airbag 471 and the first airbag 45 of the diverter pipe 47, for example, when the first airbag 45 is pushed, The second airbag 471, which is provided at an angle of 180°, extends,
In the extended state, the second airbag 471 pushes the elastic ring 428 toward the counterweight slider 424.
Therefore, due to the above action, when the center of gravity of the transmission ring 42 shifts, that is, when the housing 41 tilts downward to the left as shown in FIG.
4 is closer to the center of gravity of the transmission ring 42, and the counterweight slider 424 on the right side is further away from the center of gravity of the transmission ring 42. At this time, when the transmission ring 42 rotates, the risk of the float stabilizer 4 overturning is greatly reduced. Ru.
実施例６
本実施例は、図６に示すように、水は黒臭水であり、黒臭水の場合、光ファイバを水草を
模倣した形状として黒臭水に配置させる以外、実施例５と同様である。
Example 6
This example is the same as Example 5 except that, as shown in FIG. 6, the water is black-smelling water, and in the case of black-smelling water, the optical fiber is arranged in the dark-smelling water in a shape that imitates aquatic plants. .
実施例７
本実施例は、以下のこと以下、実施例３と同様である。図７、図１６に示すように、光源
モジュールはフロート光源装置２を含み、フロート光源装置２は光源ユニット３と、フロ
ートスタビライザ４を含み、光源ユニット３は、具体的には、集光器である。
図１７に示すように、フロートスタビライザ４はハウジング４１と、２組の伝動リング４
２と、中心棒４３とを含み、ハウジング４１は、内部が中空であり、中心に中心棒４３が
揺動するための中心筒体４１１が設けられ、２組の伝動リング４２はそれぞれハウジング
４１の内天面、内底面に設けられ、かつ２組の伝動リング４２はそれぞれ中心筒体４１１
に回動可能に套設される。
図２２に示すように、中心筒体４１１の中央部に載置板４４が設けられ、載置板４４の中
心に、中心棒４３に設けられるボール４３１に回動可能に嵌合されるソケット４４１が設
けられる。
図１８に示すように、中心棒４３の上端には光源ユニット３に接続される接続台４３２が
設けられ、中心棒４３の下端には中心棒４３にねじ接続されるカウンターウェイト４３３
が設けられ、カウンターウェイト４３３は実際の使用ニーズに応じて複数の中心棒４３に
套設されてもよく、かつカウンターウェイト４３３は中心棒４３にねじ接続され、中心棒
４３には光ファイバが貫通する連通孔が設けられる。
図１７、図１８に示すように、接続台４３２は放射状に配置された１２組の第１エアバッ
グ４５を介してハウジング４１に接続され、１２組の第１エアバッグ４５は、一端が接続
台４３２に接続され、他端がハウジング４１に接続される。
図１８に示すように、２組の伝動リング４２の間に位置するハウジング４１の内側壁に１
２組の駆動歯車４６が設けられ、かつ第１エアバッグ４５に１対１で対応しており、伝動
リング４２には駆動歯車４６と噛み合う歯ディスク４２１が設けられ、ハウジング４１の
側壁には、第１エアバッグ４５に１対１で対応する１２組のスタビライザ４８が設けられ
る。
図１９、図２０に示すように、スタビライザ４８は、回動ロッド４８１と、回動ブッシュ
４８２と、第３エアバッグ４８４とを含み、回動ブッシュ４８２はハウジング４１の側壁
に設けられる固定ブロック４８３に回動可能に接続され、回動ロッド４８１の側壁に２組
の制限リブが設けられ、２組の制限リブは１８０°をなして設けられ、回動ロッド４８１
は回動ブッシュ４８２にスライド可能に係合され、回動ブッシュ４８２の内側壁に制限リ
ブと嵌合する制限溝が設けられる。
図１９に示すように、第３エアバッグ４８４の下端は回動ロッド４８１の上端に回動可能
に接続され、回動ロッド４８１の下端には２組の円板４８５が套設され、第３エアバッグ
４８４の上端はチューブを介して対応する第１エアバッグ４５に接続される。
図１８、図１９、図２１に示すように、駆動歯車４６の出力軸はハウジング４１を貫通し
ており、第１傘歯車４８６に接続され、回動ブッシュ４８２には、第１傘歯車４８６と噛
み合って伝動する第２傘歯車４８７が套設される。
図１８、図１９に示すように、３組の固定ブロック４８３のいずれにも、回動ブッシュ４
８２に接続されるリングモータが設けられ、かつ３組の固定ブロック４８３は互いに１２
０°を空けて設けられる３組の固定ブロック４８３であり、ハウジング４１にはソーラー
パネル又は電池が敷設され、リングモータはリレーを介してソーラーパネル又は電池に接
続され、電池は表面に断熱板が覆われた市販リチウム電池を用い、リングモータ、リレー
は、市販品、又は本装置への装着に適するように市販モータ、市販リレーの外形を調整し
たものを用い、ハウジング４１、伝動リング４２はいずれも硬質フォームで製造されても
よく、これにより、フロートスタビライザ４の水面での浮力が確保される。
上記フロートスタビライザ４の作動原理は以下のとおりである。
集光器の底部を接続台４３２に係合して固定し、集光器が接続する光ファイバの他端を中
心棒４３に設けられた連通孔に通し、金属ケーシング内に入れて汚泥内に送り、次に、金
属ケーシングを取り出し、光ファイバを汚泥に放射状に配置させる。
駆動モータを起動して、駆動歯車４６を回動させ、駆動歯車４６と２組の伝動リング４２
の歯ディスク４２１による伝動の作用により、２組の伝動リング４２をそれぞれ時計回り
、反時計回りで回動させ、安定的なバランスを取る。
水面で大きな波動が発生したときに、中心棒４３の作用により集光器は常に重力方向に向
かっており、即ち、垂直に維持され、このとき、ハウジング４１の関連部材は中心棒４３
のボール４３１及び載置板４４のソケット４４１による作用を受けて揺動し、揺動中、ハ
ウジング４１と接続台４３２との間の第１エアバッグ４５は押されたり引っ張られたりす
る。
スタビライザ４８の第３エアバッグ４８４と第１エアバッグ４５とにより形成される動的
バランスが取られたキャビティにおいて、例えば、第１エアバッグ４５が押された場合、
対応する第３エアバッグ４８４は下方へ延出し、延出した状態で、第３エアバッグ４８４
は水面側へ回動ロッド４８１を押す。
よって、上記の作用により、上昇したスタビライザ４８は円板４８５と水とが接触するこ
とを保持し、即ち、図１７に示すように、ハウジング４１が左側へ下向きに傾斜すると、
左側の第１エアバッグ４８４は引っ張られ、第３エアバッグ４８４と第１エアバッグ４５
とにより形成される動的バランスが取られたキャビティにおいて、第３エアバッグ４８４
は上方へ収縮され、円板４８５はハウジング４１に接近し、右側の第１エアバッグ４８４
は押され、対応する位置の第３エアバッグ４８４は下方へ延出し、円板４８５はハウジン
グ４１から離れ、このとき、伝動リング４２が回動するときに、駆動歯車４６及び第１傘
歯車４８６、第２傘歯車４８７による伝動作用により、各スタビライザ４８の回動ロッド
４８１及び回動ブッシュ４８２は回動し、２組の円板４８５が水中で安定的な動的バラン
スを取ることにより、フロートスタビライザ４が横転するリスクを大幅に低下させるとと
もに、水の深さが小さすぎることによりスタビライザ４８の円板４８５が底部に接触した
り水面から離れたりするという問題を効果的に回避する。
Example 7
This example is similar to Example 3 in the following points. As shown in FIGS. 7 and 16, the light source module includes a float light source device 2, the float light source device 2 includes a light source unit 3, and a float stabilizer 4, and the light source unit 3 is specifically a condenser. be.
As shown in FIG. 17, the float stabilizer 4 includes a housing 41 and two sets of transmission rings 4.
2 and a center rod 43, the housing 41 is hollow inside, and is provided with a center cylindrical body 411 in the center for swinging the center rod 43. The two sets of transmission rings 42 provided on the inner top surface and the inner bottom surface each have a central cylinder body 411.
It is rotatably mounted.
As shown in FIG. 22, a mounting plate 44 is provided at the center of the central cylindrical body 411, and a socket 441 is rotatably fitted to a ball 431 provided on the center rod 43 at the center of the mounting plate 44. will be provided.
As shown in FIG. 18, a connection stand 432 connected to the light source unit 3 is provided at the upper end of the center rod 43, and a counterweight 433 is screwed to the center rod 43 at the lower end of the center rod 43.
is provided, and the counterweight 433 may be mounted on a plurality of center rods 43 according to actual usage needs, and the counterweight 433 is screwed to the center rod 43, and an optical fiber is passed through the center rod 43. A communicating hole is provided for the purpose.
As shown in FIGS. 17 and 18, the connection base 432 is connected to the housing 41 via 12 sets of first airbags 45 arranged radially, and one end of each of the 12 sets of first airbags 45 is connected to the connection base. 432, and the other end is connected to the housing 41.
As shown in FIG. 18, one
Two sets of drive gears 46 are provided and correspond one-to-one to the first airbag 45, the transmission ring 42 is provided with a toothed disc 421 that meshes with the drive gear 46, and the side wall of the housing 41 includes: Twelve pairs of stabilizers 48 are provided that correspond to the first airbags 45 on a one-to-one basis.
As shown in FIGS. 19 and 20, the stabilizer 48 includes a rotating rod 481, a rotating bush 482, and a third airbag 484, and the rotating bush 482 is connected to a fixed block 483 provided on the side wall of the housing 41. Two sets of restriction ribs are provided on the side wall of the rotation rod 481, and the two sets of restriction ribs are provided at an angle of 180°.
is slidably engaged with the rotary bush 482, and the inner wall of the rotary bush 482 is provided with a restriction groove that fits with the restriction rib.
As shown in FIG. 19, the lower end of the third airbag 484 is rotatably connected to the upper end of a rotating rod 481, and two sets of discs 485 are installed at the lower end of the rotating rod 481, and the third airbag 484 is The upper end of the airbag 484 is connected to the corresponding first airbag 45 via a tube.
As shown in FIGS. 18, 19, and 21, the output shaft of the drive gear 46 passes through the housing 41 and is connected to the first bevel gear 486. A second bevel gear 487 is provided which meshes with each other for transmission.
As shown in FIGS. 18 and 19, there is no rotary bush 4 in any of the three sets of fixed blocks 483.
A ring motor connected to 82 is provided, and three sets of fixed blocks 483 are connected to each other by 12
There are three sets of fixed blocks 483 installed at 0° intervals, a solar panel or battery is installed in the housing 41, a ring motor is connected to the solar panel or battery via a relay, and the battery has a heat insulating plate on its surface. A covered commercially available lithium battery is used, the ring motor and the relay are commercially available products, or the external shapes of commercially available motors and commercially available relays are adjusted to suit installation in this device, and the housing 41 and the transmission ring 42 are The float stabilizer 4 may also be made of rigid foam, which ensures the buoyancy of the float stabilizer 4 on the water surface.
The operating principle of the float stabilizer 4 is as follows.
The bottom of the condenser is engaged with and fixed to the connection base 432, and the other end of the optical fiber to which the condenser is connected is passed through the communication hole provided in the center rod 43, placed into the metal casing, and placed into the sludge. The metal casing is then removed and the optical fibers are placed radially into the sludge.
The drive motor is started to rotate the drive gear 46, and the drive gear 46 and the two sets of transmission rings 42 are connected to each other.
Due to the transmission action of the toothed disc 421, the two sets of transmission rings 42 are rotated clockwise and counterclockwise, respectively, to maintain stable balance.
When large waves occur on the water surface, the action of the central rod 43 keeps the concentrator always facing the direction of gravity, i.e. vertically, and at this time, the associated parts of the housing 41 are connected to the central rod 43.
The first air bag 45 between the housing 41 and the connection base 432 is pushed or pulled during the swing.
For example, when the first airbag 45 is pushed in the dynamically balanced cavity formed by the third airbag 484 and the first airbag 45 of the stabilizer 48,
The corresponding third airbag 484 extends downward, and in the extended state, the third airbag 484
pushes the rotating rod 481 toward the water surface.
Therefore, due to the above action, the raised stabilizer 48 maintains contact between the disc 485 and the water, that is, as shown in FIG. 17, when the housing 41 tilts downward to the left,
The first airbag 484 on the left side is pulled, and the third airbag 484 and the first airbag 45
In the dynamically balanced cavity formed by the third airbag 484
is contracted upward, the disc 485 approaches the housing 41, and the first airbag 484 on the right side
is pushed, the third airbag 484 at the corresponding position extends downward, and the disc 485 separates from the housing 41. At this time, when the transmission ring 42 rotates, the drive gear 46 and the first bevel gear 486 , the rotation rod 481 and the rotation bush 482 of each stabilizer 48 rotate due to the transmission operation by the second bevel gear 487, and the two sets of discs 485 maintain stable dynamic balance in the water, so that the float The risk of the stabilizer 4 overturning is greatly reduced, and the problem of the disc 485 of the stabilizer 48 touching the bottom or leaving the water surface due to too small water depth is effectively avoided.
実施例８
本実施例は、水は黒臭水であり、黒臭水の場合、光ファイバを水草を模倣した形状として
黒臭水に配置させる以外、実施例７と同様である。
Example 8
This example is the same as Example 7, except that the water is black-smelling water, and in the case of black-smelling water, the optical fiber is placed in the dark-smelling water in a shape that imitates aquatic plants.
実験例
本発明の実施例１及び２、実施例３及び４、実施例５及び６、実施例７及び８はそれぞれ
黒臭水や汚泥水に対応する解決手段であるので、これらの１つを用いてインサイチュ光触
媒システムの処理効果を検討する実験を行う。
本都市のある黒臭水を本実施例２、４、６、８の試験対象として、実施例２、４、６、８
をそれぞれ実験群１、実験群２、実験群３、実験群４とし、それぞれ黒臭水を１０ｄ処理
し、自然環境が多く変化することを考慮して、この実験では、１０ｄ内に自然光照射を模
倣した条件で１日１４ｈ照射し、また、自己発光光源による光照射の強度について、模倣
した自然光照射の平均光照射強度及び光照射時間に相当するものとし、以下のように検討
する。
検討１、自己発光光源及び集光器がインサイチュ光触媒システムの効果に与える影響の測
定
実験群１及び２を比較実験とし、インサイチュ光触媒システムを使用していない対照群１
を１組設置し、１０ｄ後の黒臭水への処理効果を測定し、結果を以下の表１に示す。
表１ 黒臭水の処理パラメータの対照表
Experimental Examples Examples 1 and 2, Examples 3 and 4, Examples 5 and 6, and Examples 7 and 8 of the present invention are solutions for dealing with black-smelling water and sludge water, so one of them We will conduct experiments to examine the treatment effects of the in-situ photocatalytic system.
Examples 2, 4, 6, and 8 were conducted using dark-smelling water in this city as the test subject for Examples 2, 4, 6, and 8.
were treated as experimental group 1, experimental group 2, experimental group 3, and experimental group 4, respectively, and black-smelling water was treated for 10 d. Considering that the natural environment changes frequently, in this experiment, natural light was irradiated within 10 d. The light was irradiated for 14 hours a day under simulated conditions, and the intensity of the light irradiation from the self-luminous light source corresponded to the average light irradiation intensity and light irradiation time of the simulated natural light irradiation, and the following study was conducted.
Study 1: Measuring the influence of self-luminous light sources and concentrators on the effectiveness of the in-situ photocatalytic system Experimental groups 1 and 2 were used as comparison experiments, and control group 1 did not use the in-situ photocatalytic system.
One set was installed, and the treatment effect on black-smelling water was measured after 10 days, and the results are shown in Table 1 below.
Table 1 Comparison table of treatment parameters for black odor water
上記の表１の結果から分かるように、実験群１、２と対照群１の実験を比較したところ、
本発明のインサイチュ光触媒システムで黒臭水を処理した場合、使用効果が良好であり、
日光が黒臭水に直接当たらないという問題を効果的に解決し、インサイチュ汚染修復をク
リーンエネルギーで環境に優しく行うことができる。
一方、実験群１、２の実験を比較した結果、窒素ドープＴｉＯ２を塗布した光ファイバを
使用する場合、自己発光光源及び集光器の処理効果はほぼ同じであることが明らかになり
、周囲光が十分である場合、集光器を使用してもインサイチュ光触媒の処理効果が優れて
おり、そして、エネルギーがクリーンで、環境にやさしいような利点がある。
検討２、近地光源装置及びフロート光源装置がインサイチュ光触媒システムの効果に与え
る影響の測定
実験群２、３及び４を比較実験とし、フロートプレートに搭載された集光器を使用した対
照群２を１組設置し、１０ｄ後の黒臭水の処理効果を測定し、水面を１日の光照射時間内
で８ｈ波動させ、結果を以下の表２に示す。
表２ 黒臭水の処理パラメータの対照表
As can be seen from the results in Table 1 above, when comparing the experiments of experimental groups 1 and 2 and control group 1,
When black odor water is treated with the in-situ photocatalytic system of the present invention, the usage effect is good;
It can effectively solve the problem of sunlight not directly hitting the black-smelling water, and in-situ pollution remediation can be done in an environment-friendly manner with clean energy.
On the other hand, the results of comparing the experiments of experimental groups 1 and 2 revealed that when using the optical fiber coated with nitrogen-doped TiO2 , the processing effects of the self-luminous light source and the condenser are almost the same, and the When the light is sufficient, the treatment effect of in-situ photocatalysis is excellent even when using a condenser, and the energy is clean and has the advantages of being environmentally friendly.
Study 2: Measuring the effects of near-field light source devices and float light source devices on the effectiveness of in-situ photocatalyst systems Experimental groups 2, 3, and 4 were used as comparison experiments, and control group 2, which used a light concentrator mounted on a float plate, was used as a comparison experiment. One set was installed, and the treatment effect on black-smelling water was measured after 10 days, and the water surface was waved for 8 hours within the light irradiation time of one day.The results are shown in Table 2 below.
Table 2 Comparison table of treatment parameters for black odor water
上記の表２の結果から分かるように、実験群２、３、４の実験を比較した結果、本発明で
は、フロートスタビライザ４に集光器を搭載した場合、集光器の地面での使用効果はほぼ
同じである。
一方、実験群３、４及び対照群２の実験を比較した結果、水面の波動がある程度で集光器
の集光効率に影響を与えるので、本発明のフロートスタビライザ４によって、このような
問題を効果的に解決し、フロートスタビライザ４が横転するリスクを大幅に低減させるこ
とができる。
［符号の説明］
As can be seen from the results in Table 2 above, as a result of comparing the experiments of experimental groups 2, 3, and 4, in the present invention, when the float stabilizer 4 is equipped with a condenser, the effect of using the condenser on the ground are almost the same.
On the other hand, as a result of comparing the experiments of Experimental Groups 3 and 4 and Control Group 2, it was found that the wave motion on the water surface affects the light collection efficiency of the light collector to a certain extent, so the float stabilizer 4 of the present invention can solve this problem. This can be effectively solved and the risk of the float stabilizer 4 overturning can be significantly reduced.
[Explanation of symbols]
１－近地光源装置
２－フロート光源装置
３－光源ユニット
４－フロートスタビライザ
４１－ハウジング
４１１－中心筒体
４１２－カバー
４２－伝動リング
４２１－歯ディスク
４２２－環状溝
４２３－皿穴
４２４－カウンターウェイトスライダ
４２５－ばね
４２６－円弧状シート
４２７－案内溝
４２８－弾性リング
４３－中心棒
４３１－ボール
４３２－接続台
４３３－カウンターウェイト
４４－載置板
４４１－ソケット
４５－第１エアバッグ
４６－駆動歯車
４７－分流管
４７１－第２エアバッグ
４８－スタビライザ
４８１－回動ロッド
４８２－回動ブッシュ
４８３－固定ブロック
４８４－第３エアバッグ
４８５－円板
４８６－第１傘歯車
４８７－第２傘歯車
1 - Nearby light source device 2 - Float light source device 3 - Light source unit 4 - Float stabilizer 41 - Housing 411 - Center cylinder 412 - Cover 42 - Transmission ring 421 - Tooth disc 422 - Annular groove 423 - Countersink 424 - Counterweight Slider 425 - Spring 426 - Arc-shaped sheet 427 - Guide groove 428 - Elastic ring 43 - Center rod 431 - Ball 432 - Connection stand 433 - Counter weight 44 - Placement plate 441 - Socket 45 - First airbag 46 - Drive gear 47 - Diversion pipe 471 - Second airbag 48 - Stabilizer 481 - Rotating rod 482 - Rotating bush 483 - Fixed block 484 - Third airbag 485 - Disc 486 - First bevel gear 487 - Second bevel gear
Claims (7)
前記光ファイバの一端は前記光源モジュールの出光口に突き合わされ、光ファイバの他端
は水中に入り、
前記触媒はＴｉＯ２、ＢｉＯ２のうちのいずれか１種であり、前記ＴｉＯ２は窒素ドープ
ＴｉＯ２を用い、
前記触媒は浸漬か焼、ゲル塗布法のうちのいずれか１種の方式で前記光ファイバ上に担持
される、
ことを特徴とするインサイチュ光触媒システム。 including a light source module for providing a light source and an optical fiber for supporting a catalyst;
One end of the optical fiber is butted against the light exit of the light source module, the other end of the optical fiber is submerged in water,
The catalyst is one of TiO 2 and BiO 2 , and the TiO 2 is nitrogen-doped TiO 2 .
The catalyst is supported on the optical fiber by one of immersion calcination and gel coating.
An in-situ photocatalytic system characterized by:
１）前記黒臭水の場合、光ファイバを水草を模倣した形状として黒臭水に配置させる形態
と、
１）前記汚泥水の場合、光ファイバを汚泥水の汚泥にドットマトリックス状に分散させる
形態との２つの形態を採用する、
ことを特徴とする請求項２に記載のシステム。 The optical fiber is
1) In the case of the black-smelling water, an optical fiber is arranged in the black-smelling water in a shape imitating aquatic plants;
1) In the case of the sludge water, two forms are adopted: a form in which optical fibers are dispersed in the sludge in the form of a dot matrix;
3. The system of claim 2.
ート光源装置（２）は光源ユニット（３）とフロートスタビライザ（４）を含み、前記近
地光源装置（１）、光源ユニット（３）はいずれも自己発光光源又は集光器のうちのいず
れか１種である、ことを特徴とする請求項１に記載のシステム。 The light source module uses a near-field light source device (1) or a float light source device (2), the float light source device (2) includes a light source unit (3) and a float stabilizer (4), and the near-field light source device (1) includes a light source unit (3) and a float stabilizer (4). ), the light source unit (3) is one of a self-luminous light source or a concentrator.
と、中心棒（４３）とを含み、
前記ハウジング（４１）は、内部が中空であり、中心に前記中心棒（４３）が揺動するた
めの中心筒体（４１１）が設けられ、２組の前記伝動リング（４２）はそれぞれハウジン
グ（４１）の内天面、内底面に設けられ、かつ２組の伝動リング（４２）はそれぞれ中心
筒体（４１１）に回動可能に套設され、
前記中心筒体（４１１）内の中央部に載置板（４４）が設けられ、前記載置板（４４）の
中心に、前記中心棒（４３）に設けられるボール（４３１）に回動可能に嵌合されるソケ
ット（４４１）が設けられ、
前記中心棒（４３）の一端には光源ユニット（３）に接続される接続台（４３２）が設け
られ、中心棒（４３）の他端には中心棒（４３）にねじ接続されるカウンターウェイト（
４３３）が設けられ、かつ中心棒（４３）に光ファイバが中心棒（４３）を貫通する連通
孔が設けれ、
前記接続台（４３２）は放射状に配置された複数組の第１エアバッグ（４５）を介してハ
ウジング（４１）に接続され、複数組の前記第１エアバッグ（４５）は、全て一端が接続
台（４３２）に接続され、他端がハウジング（４１）に接続され、
２組の伝動リング（４２）の間に位置するハウジング（４１）の内側壁に少なくとも１組
の駆動歯車（４６）が回動可能に設けられ、かつ伝動リング（４２）には前記駆動歯車（
４６）と噛み合う歯ディスク（４２１）が設けられる、ことを特徴とする請求項４に記載
のシステム。 The float stabilizer (4) includes a housing (41) and two sets of transmission rings (42).
and a center rod (43),
The housing (41) is hollow inside, and is provided with a central cylindrical body (411) in the center of which the central rod (43) swings, and the two sets of transmission rings (42) are connected to the housing (41), respectively. 41), and two sets of transmission rings (42) are rotatably mounted on the central cylinder (411),
A mounting plate (44) is provided at the center of the center cylinder (411), and is rotatable at the center of the mounting plate (44) around a ball (431) provided on the center rod (43). A socket (441) is provided to be fitted into the
A connection stand (432) connected to the light source unit (3) is provided at one end of the center rod (43), and a counterweight screwed to the center rod (43) is provided at the other end of the center rod (43). (
433), and the center rod (43) is provided with a communication hole through which the optical fiber passes through the center rod (43),
The connection stand (432) is connected to the housing (41) via a plurality of sets of first airbags (45) arranged radially, and the plurality of sets of first airbags (45) are all connected at one end. connected to the stand (432), the other end connected to the housing (41),
At least one set of drive gears (46) is rotatably provided on the inner wall of the housing (41) located between the two sets of transmission rings (42), and the drive gears (46) are rotatably provided in the transmission ring (42).
5. System according to claim 4, characterized in that a toothed disc (421) is provided which meshes with the toothed disc (46).
の分流管（４７）が設けられ、前記分流管（４７）はチューブを介してその向かい側に設
けられる第１エアバッグ（４５）に接続され、
前記伝動リング（４２）の側壁に環状溝（４２２）が設けられ、前記分流管（４７）の上
部と下部のそれぞれに、対応する環状溝（４２２）に入る１組の第２エアバッグ（４７１
）が設けられ、
環状溝（４２２）の内底部に位置する前記伝動リング（４２）内に、各第２エアバッグ（
４７１）に１対１で対応する皿穴（４２３）が設けられ、前記皿穴（４２３）内にカウン
ターウェイトスライダ（４２４）がスライド可能に設けられ、前記カウンターウェイトス
ライダ（４２４）の一方の側面はばね（４２５）を介して皿穴（４２３）の内底部に接続
され、カウンターウェイトスライダ（４２４）の他方の側面に円弧状シート（４２６）が
設けられ、かつ前記皿穴（４２３）の両側の伝動リング（４２）に、円弧状シート（４２
６）の案内ロッドにスライド可能に接続される１組の案内溝（４２７）がそれぞれ設けら
れ、
前記円弧状シート（４２６）と第２エアバッグ（４７１）との間にある環状溝（４２２）
内に弾性リング（４２８）が設けられ、前記弾性リング（４２８）は第２エアバッグ（４
７１）の端面にスライド可能に接続され、
前記ハウジング（４１）には、各チューブを覆うカバー（４１２）が設けられ、かつ前記
カバー（４１２）の表面にソーラーパネル又は電池のうちの少なくとも１種が敷設され、
かつハウジング（４１）には、前記駆動歯車（４６）の軸棒に突き合わされる駆動モータ
が設けられ、前記駆動モータはリレーを介してソーラーパネル又は電池に接続される、こ
とを特徴とする請求項５に記載のシステム。 A plurality of sets of branch pipes (47) corresponding to the first airbag (45) on a one-to-one basis are provided on the side wall of the housing (41), and the branch pipes (47) are connected to the opposite side through a tube. connected to a first airbag (45) provided;
An annular groove (422) is provided on the side wall of the transmission ring (42), and a pair of second airbags (471) are provided in the upper and lower parts of the diverter pipe (47), respectively, entering the corresponding annular groove (422).
) is provided,
Each second airbag (
A countersink (423) corresponding to the countersink (471) on a one-to-one basis is provided, a counterweight slider (424) is slidably provided in the countersink (423), and one side of the counterweight slider (424) is provided. is connected to the inner bottom of the countersink (423) via a spring (425), and an arcuate sheet (426) is provided on the other side of the counterweight slider (424), and both sides of the countersink (423) An arc-shaped seat (42) is attached to the transmission ring (42) of
a set of guide grooves (427) slidably connected to the guide rods of 6);
An annular groove (422) between the arcuate seat (426) and the second airbag (471)
An elastic ring (428) is provided within the second airbag (428), and the elastic ring (428) is connected to the second airbag (428).
71) is slidably connected to the end face of the
The housing (41) is provided with a cover (412) that covers each tube, and at least one of a solar panel or a battery is laid on the surface of the cover (412),
Further, the housing (41) is provided with a drive motor that butts against the shaft of the drive gear (46), and the drive motor is connected to a solar panel or a battery via a relay. The system according to item 5.
のスタビライザ（４８）が設けられ、
前記スタビライザ（４８）は、回動ロッド（４８１）と、回動ブッシュ（４８２）と、第
３エアバッグ（４８４）とを含み、前記回動ブッシュ（４８２）はハウジング（４１）の
側壁に設けられる固定ブロック（４８３）に回動可能に接続され、前記回動ロッド（４８
１）の側壁に少なくとも１組の制限リブが設けられ、回動ロッド（４８１）は前記回動ブ
ッシュ（４８２）にスライド可能に係合され、前記回動ブッシュ（４８２）の内側壁に制
限リブと嵌合する制限溝が設けられ、
前記第３エアバッグ（４８４）の一端は回動ロッド（４８１）の一端に回動可能に接続さ
れ、回動ロッド（４８１）の他端には少なくとも１組の円板（４８５）が套設され、前記
第３エアバッグ（４８４）の他端はチューブを介して対応する第１エアバッグ（４５）に
接続され、
前記駆動歯車（４６）は複数組設けられ、かつ第１エアバッグ（４５）に１対１で対応し
ており、駆動歯車（４６）の出力軸はハウジング（４１）を貫通しており、第１傘歯車（
４８６）に接続され、前記回動ブッシュ（４８２）には、第１傘歯車（４８６）と噛み合
って伝動する第２傘歯車（４８７）が套設され、
少なくとも１組の前記固定ブロック（４８３）には、回動ブッシュ（４８２）に接続され
るリングモータが設けられ、前記ハウジング（４１）にソーラーパネル又は電池のうちの
少なくとも１種が敷設され、前記リングモータはリレーを介してソーラーパネル又は電池
に接続される、ことを特徴とする請求項５に記載のシステム。 A plurality of sets of stabilizers (48) are provided on the side wall of the housing (41) in one-to-one correspondence with the first airbag (45),
The stabilizer (48) includes a rotating rod (481), a rotating bush (482), and a third airbag (484), and the rotating bush (482) is provided on a side wall of the housing (41). The rotary rod (483) is rotatably connected to the fixed block (483)
1), the pivot rod (481) is slidably engaged with the pivot bush (482), and the inner wall of the pivot bush (482) is provided with at least one set of limitation ribs; A restriction groove is provided that fits with the
One end of the third airbag (484) is rotatably connected to one end of a rotating rod (481), and at least one set of discs (485) is provided at the other end of the rotating rod (481). and the other end of the third airbag (484) is connected to the corresponding first airbag (45) via a tube,
A plurality of sets of the drive gears (46) are provided and correspond to the first airbag (45) on a one-to-one basis, and the output shaft of the drive gear (46) passes through the housing (41). 1 bevel gear (
486), a second bevel gear (487) that meshes with the first bevel gear (486) and transmits transmission is disposed on the rotary bush (482),
At least one set of the fixed blocks (483) is provided with a ring motor connected to the rotary bush (482), at least one of a solar panel or a battery is installed in the housing (41), and the System according to claim 5, characterized in that the ring motor is connected to a solar panel or a battery via a relay.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210802623.5A CN115072829B (en) | 2022-07-07 | 2022-07-07 | In situ photocatalytic system |
| CN202210802623.5 | 2022-07-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP7193686B1 JP7193686B1 (en) | 2022-12-21 |
| JP2024008756A true JP2024008756A (en) | 2024-01-19 |
Family
ID=83257091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022121153A Active JP7193686B1 (en) | 2022-07-07 | 2022-07-29 | In-situ photocatalyst system |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP7193686B1 (en) |
| CN (1) | CN115072829B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007209841A (en) * | 2006-02-07 | 2007-08-23 | National Institute For Materials Science | Environmental purification system using light energy |
| JP2012020219A (en) * | 2010-07-13 | 2012-02-02 | Mitsubishi Heavy Ind Ltd | Wastewater treatment apparatus |
| JP2012091172A (en) * | 2011-12-19 | 2012-05-17 | National Institute Of Advanced Industrial Science & Technology | Visible light responsive photocatalyst and photolysis method of environmental pollutant |
| JP2015080772A (en) * | 2013-10-24 | 2015-04-27 | スタンレー電気株式会社 | Photocatalyst-supporting optical fiber and water treatment device using the same |
| JP2015199065A (en) * | 2014-03-31 | 2015-11-12 | 新日鉄住金化学株式会社 | Photocatalyst and production method therefor |
| JP2017104809A (en) * | 2015-12-10 | 2017-06-15 | 日本電気硝子株式会社 | Method for producing photocatalyst-silica composite molding |
| CN108147497A (en) * | 2018-03-01 | 2018-06-12 | 佛山市金净创环保技术有限公司 | A kind of ecosystem processing unit |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1230572C (en) * | 2002-10-23 | 2005-12-07 | 中国科学院化学研究所 | Method for forming heteronitrogen nano TiO2 light catalytic activity coating on substrate |
| CN201151472Y (en) * | 2007-12-07 | 2008-11-19 | 林婉旭 | Leak-quickly-repairing machine for ship |
| GB2494227B (en) * | 2012-04-10 | 2013-09-11 | Marine Specialised Technology Ltd | Righting device for a water vessel |
| CN203514277U (en) * | 2013-09-10 | 2014-04-02 | 岱山县科技开发中心 | Floating type tide power station structure |
| CN105709411A (en) * | 2016-03-22 | 2016-06-29 | 武汉东湖学院 | Intelligent fun water cannon toy |
| CN108529715B (en) * | 2018-03-30 | 2021-06-08 | 河海大学 | Self-luminous artificial aquatic plant photocatalytic purification box |
| CN109732475A (en) * | 2019-01-24 | 2019-05-10 | 华南理工大学 | Multi-direction floating executing agency |
| CN210555438U (en) * | 2019-07-04 | 2020-05-19 | 张良 | Modular combined hydrology and water resource surveying buoy |
| US11673831B2 (en) * | 2019-10-01 | 2023-06-13 | The Hong Kong University Of Science And Technology | Method for preparing optical fibers with high-particle-coated porous polymeric outer coating layers |
| CN211978882U (en) * | 2020-04-22 | 2020-11-20 | 嘉兴海慧环境科技有限公司 | Buoy type hydrology and water quality monitoring device |
| CN111573849A (en) * | 2020-04-27 | 2020-08-25 | 江苏双良环境科技有限公司 | Promote graphene photocatalysis net water treatment efficiency's device |
| CN111927698B (en) * | 2020-06-22 | 2023-12-19 | 山东中能华源海上风电集团有限公司 | Offshore floating type liftable wind generating set |
| CN112335601B (en) * | 2020-09-28 | 2022-11-15 | 泸溪县兄弟特种水产养殖有限公司 | Be used for aquaculture oxygen equipments |
| CN214356570U (en) * | 2020-12-08 | 2021-10-08 | 樊玉杰 | Boats and ships prevent device that topples |
| CN215554005U (en) * | 2021-08-25 | 2022-01-18 | 中国船级社 | Novel anti-overturning device for ship |
-
2022
- 2022-07-07 CN CN202210802623.5A patent/CN115072829B/en active Active
- 2022-07-29 JP JP2022121153A patent/JP7193686B1/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007209841A (en) * | 2006-02-07 | 2007-08-23 | National Institute For Materials Science | Environmental purification system using light energy |
| JP2012020219A (en) * | 2010-07-13 | 2012-02-02 | Mitsubishi Heavy Ind Ltd | Wastewater treatment apparatus |
| JP2012091172A (en) * | 2011-12-19 | 2012-05-17 | National Institute Of Advanced Industrial Science & Technology | Visible light responsive photocatalyst and photolysis method of environmental pollutant |
| JP2015080772A (en) * | 2013-10-24 | 2015-04-27 | スタンレー電気株式会社 | Photocatalyst-supporting optical fiber and water treatment device using the same |
| JP2015199065A (en) * | 2014-03-31 | 2015-11-12 | 新日鉄住金化学株式会社 | Photocatalyst and production method therefor |
| JP2017104809A (en) * | 2015-12-10 | 2017-06-15 | 日本電気硝子株式会社 | Method for producing photocatalyst-silica composite molding |
| CN108147497A (en) * | 2018-03-01 | 2018-06-12 | 佛山市金净创环保技术有限公司 | A kind of ecosystem processing unit |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115072829B (en) | 2023-07-18 |
| JP7193686B1 (en) | 2022-12-21 |
| CN115072829A (en) | 2022-09-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104058508B (en) | A kind of method for treating water utilizing microorganism to carry out sewage purification | |
| CN213506085U (en) | Water environment ecological restoration device | |
| CN204643970U (en) | A kind of ecological floating island of sun power pollution administration water body | |
| CN107129005A (en) | A kind of inner light source ball string data photocatalysis water quality purifying box | |
| CN204981237U (en) | Be used for prosthetic photocatalysis purifier of river course normal position | |
| CN104630816B (en) | Hydrogen production device and technology via photoelectric degradation of organic pollutant based on solar energy and sea water cell collaborative drive | |
| CN100554185C (en) | Utilize the solidified algae ball dispose of sewage in the method for organo-tin compound | |
| JP2024008756A (en) | In-situ photocatalyst system | |
| CN108178288B (en) | River pollutant biological treatment device | |
| CN208218634U (en) | A kind of black-odor riverway in-situ sediment remediation system | |
| CN207619194U (en) | A kind of automation oxidation ditch device for during tertiary sewage treatment | |
| CN209940779U (en) | River channel purification device | |
| WO2008136532A1 (en) | Method of improving quality of water in water tank and device for improving water quality therefor | |
| CN215208723U (en) | Porous aeration solar ecological floating bed | |
| CN205710114U (en) | Lake water disinfection layering oxygen increasing equipment | |
| CN210505776U (en) | Sewage purification device combining solar energy and waste beverage bottles | |
| CN114380387A (en) | Landscape water body restoration treatment method | |
| Lv et al. | A lotus leaf-inspired Janus dual-functional nanofiber evaporator for efficient water purification | |
| CN110054251B (en) | Ultraviolet light catalytic device for treating organic pollutants in river channel | |
| CN109052545B (en) | Portable photocatalytic reactor for treating organic wastewater | |
| CN204570054U (en) | Based on the device of the photoelectrochemical degradation organic pollutant hydrogen manufacturing of sun power and seawater cell coordinated drive | |
| CN220376492U (en) | Photocatalyst-coupled microorganism mobile water treatment device | |
| CN203999156U (en) | A kind of water treatment device that utilizes microorganism to carry out sewage purification | |
| CN110668564A (en) | Medium-grade sewage treatment tank with large-area contact with biological membrane | |
| CN108314194A (en) | A kind of efficiently oxygenation ecological treatment system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220729 |
|
| A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20220729 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20220906 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20220908 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20221018 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20221018 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20221101 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20221104 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7193686 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |