JP2023142449A - Substrate processing apparatus - Google Patents

Substrate processing apparatus Download PDF

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JP2023142449A
JP2023142449A JP2022049369A JP2022049369A JP2023142449A JP 2023142449 A JP2023142449 A JP 2023142449A JP 2022049369 A JP2022049369 A JP 2022049369A JP 2022049369 A JP2022049369 A JP 2022049369A JP 2023142449 A JP2023142449 A JP 2023142449A
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substrate
frame member
wafer
processing liquid
processing
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博 横田
Hiroshi Yokota
慎 立花
Shin Tachibana
タン ザン グエン
Tan Dan Nguyen
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Kurabo Industries Ltd
Kurashiki Spinning Co Ltd
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Kurabo Industries Ltd
Kurashiki Spinning Co Ltd
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Abstract

To provide a substrate processing apparatus in which a substrate can be rotated while a processing liquid is stored on the substrate.SOLUTION: A substrate processing apparatus 10 for processing a substrate using a processing liquid includes a substrate holding portion 11 that holds a substrate W, substrate rotation means 12 that rotates the substrate holding portion, a processing liquid supply portion 13 that discharges the processing liquid onto the substrate, a frame member 20 whose inner enclosing shape is smaller than the outer shape of the substrate in a plan view, and which can be placed on the outer periphery of the substrate to form a reservoir for the processing liquid together with the substrate, and frame member holding means 30 capable of holding or releasing the frame member and movable vertically relative to the substrate holding portion.SELECTED DRAWING: Figure 1

Description

本発明は、処理液を用いて半導体ウェハ等の基板を処理する装置に関する。 The present invention relates to an apparatus for processing a substrate such as a semiconductor wafer using a processing liquid.

半導体工業における枚葉式プロセスでは、半導体ウェハを略水平に保持して回転させながら、その表面に処理液を供給することにより、エッチングや洗浄などの各種の処理が実施される。ウェハ上に供給された処理液は遠心力によってウェハの外縁に向かって移動してウェハ外縁から排出され、ウェハ表面には、供給量と排出量が釣り合う厚さの処理液膜が形成される。このように、従来の枚葉式処理方法では、処理液を掛け流しながら基板を処理するので、多量の処理液を使用する必要があった。 In single-wafer processing in the semiconductor industry, various treatments such as etching and cleaning are performed by supplying a processing liquid to the surface of a semiconductor wafer while holding it approximately horizontally and rotating it. The processing liquid supplied onto the wafer moves toward the outer edge of the wafer due to centrifugal force and is discharged from the outer edge of the wafer, and a processing liquid film is formed on the wafer surface with a thickness such that the amount of supply and the amount of discharge are balanced. As described above, in the conventional single-wafer processing method, the substrate is processed while the processing liquid is being poured over the substrate, so it is necessary to use a large amount of the processing liquid.

これに対して、特許文献1には、半導体ウェハ径の大きさでリング状の薬液ストッパーをウェハに密着させて、薬液をウェハ上に溜め、マイクロ波発生器や昇温ランプで薬液を昇温する半導体ウェハ洗浄装置が記載されている。また、特許文献2には、液溜まり部形成部材を設け、当該液溜まり部の底部を基板の表面にて形成した状態で、液溜まり部に溜められた液体で基板の表面を処理する方法が開示されている。 On the other hand, Patent Document 1 discloses that a ring-shaped chemical stopper with the diameter of the semiconductor wafer is brought into close contact with the wafer, the chemical is stored on the wafer, and the temperature of the chemical is raised using a microwave generator or a heating lamp. A semiconductor wafer cleaning apparatus is described. Further, Patent Document 2 discloses a method in which a liquid pool forming member is provided, the bottom of the liquid pool is formed on the surface of the substrate, and the surface of the substrate is treated with the liquid stored in the liquid pool. Disclosed.

特開平4-357836号公報Japanese Patent Application Publication No. 4-357836 特開平9-162153号公報Japanese Patent Application Publication No. 9-162153

特許文献1または2に記載された装置または方法によれば、基板上に処理液を溜めて基板を処理するため、処理液の使用量を低減できる。しかし、特許文献1および2に記載された装置または方法では、基板上に処理液を貯留させる段階で、基板を回転させることができないため、処理液に泡を巻き込む恐れもあり、処理液の拡がりが好ましくない。また、ウェハ表面状態にムラがある場合、その部分で処理液の拡がりが悪くなる場合がある。さらに、基板上に処理液を溜めた状態で基板を回転させることができないため、基板処理時の反応速度が低いという問題があった。 According to the apparatus or method described in Patent Document 1 or 2, since the processing liquid is stored on the substrate and the substrate is processed, the amount of processing liquid used can be reduced. However, in the apparatuses or methods described in Patent Documents 1 and 2, the substrate cannot be rotated at the stage of storing the processing liquid on the substrate, so there is a risk that bubbles may be drawn into the processing liquid, causing the processing liquid to spread. is not desirable. Further, if there is unevenness in the wafer surface condition, the processing liquid may not spread well in that area. Furthermore, since the substrate cannot be rotated with the processing liquid stored on the substrate, there is a problem that the reaction rate during substrate processing is low.

本発明は、上記を考慮してなされたものであり、基板上に処理液を溜めて基板を処理する装置であって、処理液を溜めた状態で基板が回転可能な基板処理装置を提供することを課題とする。 The present invention has been made in consideration of the above, and provides a substrate processing apparatus that processes a substrate by storing a processing liquid on the substrate, and in which the substrate can be rotated while the processing liquid is stored. That is the issue.

本発明の基板処理装置は、処理液を用いて基板を処理するための基板処理装置であって、前記基板を保持する基板保持部と、前記基板保持部を回転させる基板回転手段と、前記基板上に前記処理液を吐出する処理液供給部と、平面視において内側に囲む形状が前記基板の外形より小さく、前記基板の外周部に載置して、前記基板とともに前記処理液の貯留部を形成可能な枠部材と、前記枠部材を保持または開放可能で、前記基板保持部と上下方向に相対的に可動な枠部材保持手段とを有する。 A substrate processing apparatus of the present invention is a substrate processing apparatus for processing a substrate using a processing liquid, and includes a substrate holding part for holding the substrate, a substrate rotation means for rotating the substrate holding part, and a substrate processing apparatus for processing a substrate using a processing liquid. a processing liquid supply unit that discharges the processing liquid onto the top; and a processing liquid supply unit that has an inner enclosing shape smaller than the outer shape of the substrate in plan view, and is placed on the outer periphery of the substrate to store the processing liquid together with the substrate. It has a frame member that can be formed, and a frame member holding means that can hold or open the frame member and is movable vertically relative to the substrate holding part.

本発明の他の基板処理装置は、処理液を用いて円板状の基板を処理するための基板処理装置であって、前記基板を保持する基板保持部と、前記基板保持部を回転させる基板回転手段と、前記基板上に前記処理液を吐出する処理液供給部と、前記基板とともに前記処理液の貯留部を形成する枠部材と、前記枠部材を支持し、前記枠部材を回転させる枠部材回転手段を備え、前記枠部材の内径が前記基板の直径より小さい場合は、該枠部材の下面が前記基板の上面に近接する位置を少なくとも含む範囲で、前記枠部材の内径が前記基板の直径より大きい場合は、該枠部材の内壁面が前記基板の外周端面に近接する位置を少なくとも含む範囲で、前記基板保持部と上下方向に相対的に可動な枠部材支持手段とを有する。 Another substrate processing apparatus of the present invention is a substrate processing apparatus for processing a disk-shaped substrate using a processing liquid, the apparatus comprising: a substrate holder for holding the substrate; and a substrate for rotating the substrate holder. a rotating means, a processing liquid supply section that discharges the processing liquid onto the substrate, a frame member that forms a storage section for the processing liquid together with the substrate, and a frame that supports the frame member and rotates the frame member. If the inner diameter of the frame member is smaller than the diameter of the substrate, the inner diameter of the frame member is smaller than that of the substrate in a range that includes at least a position where the lower surface of the frame member is close to the upper surface of the substrate. If the frame member is larger than the diameter, the inner wall surface of the frame member includes a frame member supporting means that is movable in the vertical direction relative to the substrate holding portion in a range that includes at least a position close to the outer peripheral end surface of the substrate.

本発明の基板処理装置によれば、枠部材によって基板上に処理液を溜めて基板を処理することによって処理液の使用量を削減できる。また、処理液を溜めた状態で基板が回転可能である。 According to the substrate processing apparatus of the present invention, the amount of processing liquid used can be reduced by storing the processing liquid on the substrate using the frame member and processing the substrate. Further, the substrate can be rotated with the processing liquid stored therein.

第1実施形態の基板処理装置の構成を示す図である。FIG. 1 is a diagram showing the configuration of a substrate processing apparatus according to a first embodiment. 第1実施形態の枠部材の形状を示す図である。A:平面図、B:図2AのXX断面図、C:図2Bの破線円に囲まれた部分の拡大図。It is a figure which shows the shape of the frame member of 1st Embodiment. A: Plan view, B: XX sectional view of FIG. 2A, C: Enlarged view of the part surrounded by the broken line circle of FIG. 2B. 第1実施形態の枠部材保持手段の構成を示す図である。A:平面図、B:側面図。It is a figure showing the composition of frame member holding means of a 1st embodiment. A: Top view, B: Side view. 第1実施形態の基板処理装置の使用方法の工程フロー図である。FIG. 3 is a process flow diagram of a method of using the substrate processing apparatus of the first embodiment. A~F:第1実施形態の基板処理装置の使用方法を説明するための図である。A to F: Diagrams for explaining how to use the substrate processing apparatus of the first embodiment. 第2実施形態の基板処理装置の構成を示す図である。FIG. 3 is a diagram showing the configuration of a substrate processing apparatus according to a second embodiment. 第2実施形態の枠部材の形状を示す図である。A:平面図、B:図2AのXX断面図(内径がウェハより小さい場合)、C:図2AのXX断面図(内径がウェハより大きい場合)、D:図2CのY矢視図。It is a figure which shows the shape of the frame member of 2nd Embodiment. A: Plan view, B: XX cross-sectional view of FIG. 2A (when the inner diameter is smaller than the wafer), C: XX cross-sectional view of FIG. 2A (when the inner diameter is larger than the wafer), D: Y-arrow view of FIG. 2C. 第2実施形態の枠部材支持手段の構成を示す図である。A:ケース内部の平面図、B:一部の断面を示す側面図。It is a figure which shows the structure of the frame member support means of 2nd Embodiment. A: A plan view of the inside of the case, B: A side view showing a partial cross section. 第2実施形態の基板処理装置の使用方法の工程フロー図である。FIG. 7 is a process flow diagram of a method of using the substrate processing apparatus of the second embodiment. A~F:第2実施形態の基板処理装置の使用方法を説明するための図である。A to F: Diagrams for explaining how to use the substrate processing apparatus of the second embodiment.

基板処理装置の第1実施形態を図1~5に基づいて説明する。 A first embodiment of the substrate processing apparatus will be described based on FIGS. 1 to 5.

図1を参照して、本実施形態の基板処理装置10は、ウェハ(基板)Wを保持する基板保持部11と、基板保持部11を回転させる基板回転手段12と、ウェハW上に処理液を吐出する複数のノズル(処理液供給部)13と、枠部材20と、枠部材保持手段30とを有する。 Referring to FIG. 1, a substrate processing apparatus 10 according to the present embodiment includes a substrate holder 11 that holds a wafer (substrate) W, a substrate rotation means 12 that rotates the substrate holder 11, and a processing liquid that is placed on the wafer W. It has a plurality of nozzles (processing liquid supply section) 13 for discharging liquid, a frame member 20, and a frame member holding means 30.

基板保持部11は、ウェハWを真空吸着することや、外周数か所を保持ピンで支持することによって、ウェハを略水平に保持する。基板保持部は、ウェハを水平に保持するだけでなく、水平からわずかに傾いた角度、例えば水平から10度以内の範囲の角度で保持できることが好ましい。基板回転手段12は、ウェハがその面内で中心の周りに自転するように、基板保持部を回転させる。ノズル13は、ウェハ上に処理液を吐出する。ノズルの数は特に限定されない。 The substrate holding unit 11 holds the wafer W substantially horizontally by vacuum suctioning the wafer W or by supporting the wafer W at several locations around the periphery with holding pins. It is preferable that the substrate holder not only hold the wafer horizontally, but also be able to hold the wafer at a slightly inclined angle from the horizontal, for example within a range of 10 degrees from the horizontal. The substrate rotation means 12 rotates the substrate holder so that the wafer rotates around the center within its plane. The nozzle 13 discharges the processing liquid onto the wafer. The number of nozzles is not particularly limited.

ノズル13からウェハW上に供給される処理液の種類は特に限定されない。処理液の例としては、各種洗浄処理に用いられるアンモニア過酸化水素水混合液、硫酸過酸化水素水混合液、塩酸過酸化水素水混合液、希フッ酸やオゾン水、各種エッチング処理に用いられるフッ酸、硝酸、酢酸、リン酸及びそれらを混合した混酸、リンス処理に用いられる純水、乾燥処理に用いられるIPAなどが挙げられる。処理液ごとにノズルを設けることによって、異なる処理液を用いる一連の処理、例えば、薬液による洗浄処理、純水によるリンス処理およびIPAによる乾燥処理を連続して行うことができる。 The type of processing liquid supplied onto the wafer W from the nozzle 13 is not particularly limited. Examples of processing liquids include ammonia/hydrogen peroxide mixtures used in various cleaning treatments, sulfuric acid/hydrogen peroxide mixtures, hydrochloric acid/hydrogen peroxide mixtures, dilute hydrofluoric acid and ozone water, and ozone water used in various etching treatments. Examples include hydrofluoric acid, nitric acid, acetic acid, phosphoric acid, and mixed acids of these acids, pure water used for rinsing, and IPA used for drying. By providing a nozzle for each treatment liquid, a series of treatments using different treatment liquids, such as a cleaning treatment with a chemical solution, a rinsing treatment with pure water, and a drying treatment with IPA, can be performed continuously.

図2を参照して、枠部材20はリング状の部材である。枠部材の内径はウェハWの直径よりわずかに小さい。枠部材20の下部には、下面の内壁面21側に凹部22が形成され、ウェハWの外周と凹部22が嵌合可能であり、これにより、枠部材をウェハの外周部に載置できる。枠部材をウェハの外周部に載置した状態では、枠部材の内壁面21とウェハWの上面とで、処理液を溜めることができる貯留部24が形成される。また、枠部材の外周にはつば部23が形成され、枠部材保持手段30がつば部を把持することで枠部材20を保持できる。 Referring to FIG. 2, frame member 20 is a ring-shaped member. The inner diameter of the frame member is slightly smaller than the diameter of the wafer W. A recess 22 is formed in the lower part of the frame member 20 on the inner wall surface 21 side of the lower surface, and the recess 22 can be fitted to the outer periphery of the wafer W, so that the frame member can be placed on the outer periphery of the wafer. When the frame member is placed on the outer periphery of the wafer, the inner wall surface 21 of the frame member and the upper surface of the wafer W form a reservoir 24 in which processing liquid can be stored. Further, a flange portion 23 is formed on the outer periphery of the frame member, and the frame member 20 can be held by the frame member holding means 30 gripping the flange portion.

枠部材20の内径は、ウェハWの直径をdとして、好ましくはd-20mm以上、より好ましくはd-6mm以上であって、d未満である。ウェハに結晶方位を示すための切り欠き(オリエンテーションフラットやノッチ)がある場合は、枠部材の平面視における形状をウェハの外形に合わせる。基板が長方形などで円形でない場合は、平面視において枠部材内側に囲む形状を基板の外形より小さくする。言い換えると、枠部材の大きさは、枠部材を基板の外周部に重ねたときに、平面視において基板の輪郭が枠の内部に現れない大きさとする。このとき、枠部材が隠す基板外周部の領域が、基板の外周から10mm以内の領域であることが好ましく、3mm以内の領域であることがより好ましい。 The inner diameter of the frame member 20 is preferably d-20 mm or more, more preferably d-6 mm or more, and less than d, where d is the diameter of the wafer W. If the wafer has a notch (orientation flat or notch) for indicating the crystal orientation, the shape of the frame member in plan view is matched to the outer shape of the wafer. If the substrate is rectangular or otherwise non-circular, the shape enclosed inside the frame member is made smaller than the outer shape of the substrate in plan view. In other words, the size of the frame member is such that when the frame member is stacked on the outer periphery of the substrate, the outline of the substrate does not appear inside the frame in plan view. At this time, the area of the outer periphery of the substrate that is hidden by the frame member is preferably within 10 mm from the outer periphery of the substrate, and more preferably within 3 mm.

枠部材20は、耐薬品性のあるPFA/PTFE等のフッ素樹脂、寸法精度のよいPEEKなどのエンジニアリングプラスチック、溶出/パーティクルの少ない石英などのガラス材、サファイヤなどの結晶材等を用いて作製することができる。枠部材は、好ましくはフッ素樹脂、石英を用いて作製される。 The frame member 20 is manufactured using a fluororesin such as PFA/PTFE that has chemical resistance, an engineering plastic such as PEEK that has good dimensional accuracy, a glass material such as quartz that has little elution/particles, a crystalline material such as sapphire, etc. be able to. The frame member is preferably made using fluororesin or quartz.

図3を参照して、枠部材保持手段30は、垂直に立つ旋回軸31と、旋回軸31の周りに旋回可能なアーム32と、アーム32の先端に設けられた保持部33を有する。保持部33は枠部材20を保持し、開放することが可能である。アーム32は、旋回軸31の周りに旋回することによって、枠部材を、側方の待機位置(図2Aの破線の位置)と基板保持部11の真上との間で往復させることができる。アーム32は旋回軸31に沿って昇降可能で、枠部材20をウェハW上に置いたり、ウェハ上から持ち上げたりすることができる。あるいは、アーム32と旋回軸31が一体となって昇降可能であってもよい。なお、枠部材保持手段30と基板保持部11は上下方向に相対的に可動であればよいので、基板保持部を昇降可能としてもよい。旋回軸31は、基板保持部11からの距離を変えられるように水平方向(図3AおよびBの左右方向)にも移動可能である。 Referring to FIG. 3, the frame member holding means 30 has a vertically standing pivot shaft 31, an arm 32 that can pivot around the pivot shaft 31, and a holding portion 33 provided at the tip of the arm 32. The holding part 33 can hold the frame member 20 and open it. By pivoting around the pivot shaft 31, the arm 32 can reciprocate the frame member between a side standby position (the position indicated by the broken line in FIG. 2A) and a position directly above the substrate holder 11. The arm 32 can move up and down along the rotation axis 31, and can place the frame member 20 on the wafer W or lift it off the wafer. Alternatively, the arm 32 and the pivot shaft 31 may be able to move up and down integrally. Note that since it is sufficient that the frame member holding means 30 and the substrate holding section 11 are relatively movable in the vertical direction, the substrate holding section may be capable of being raised and lowered. The pivot shaft 31 is also movable in the horizontal direction (left and right directions in FIGS. 3A and 3B) so that the distance from the substrate holding part 11 can be changed.

次に、本実施形態の基板処理装置の使用方法を、半導体ウェハのRCA洗浄処理を例に、図4の工程の流れに沿って、図5を参照して説明する。 Next, a method of using the substrate processing apparatus of this embodiment will be described with reference to FIG. 5, using RCA cleaning processing of a semiconductor wafer as an example, along the process flow of FIG. 4.

(S1)ウェハWが基板保持部11に固定され、回転していない状態で、枠部材保持手段30によって、枠部材20をウェハW上にセットする(図5A)。詳しくは、枠部材保持手段30の保持部33で待機位置にある枠部材20を保持し、アーム32を旋回軸31の周りに旋回させて枠部材20をウェハWの直上まで移動させ、アーム32を降下させて枠部材20をウェハ外周に嵌合させてウェハの外周部に載置し、保持部33が枠部材を開放してアームを上昇させることで、枠部材のセットが完了する。枠部材20がウェハWに正しく載置されたかどうかは、例えば位置センサによって確認できる。 (S1) With the wafer W fixed to the substrate holding part 11 and not rotating, the frame member 20 is set on the wafer W by the frame member holding means 30 (FIG. 5A). Specifically, the holding portion 33 of the frame member holding means 30 holds the frame member 20 at the standby position, the arm 32 is rotated around the pivot shaft 31, the frame member 20 is moved to directly above the wafer W, and the arm 32 is lowered to fit the frame member 20 to the outer periphery of the wafer and place it on the outer periphery of the wafer, and the holding section 33 releases the frame member and raises the arm, thereby completing the setting of the frame member. Whether or not the frame member 20 is correctly placed on the wafer W can be confirmed by, for example, a position sensor.

(S2)ノズル13aからウェハ上に、70℃のSC-1液(アンモニア過酸化水素水混合液)を0.9L/分で20秒間、所定の量(0.3L)を吐出する(S2a、図5B)。SC-1液の吐出を停止した後、ウェハWを30rpm程度の低速で約10秒間回転させて、SC-1液を貯留部24の全体にまんべんなく行きわたらせる。なお、SC-1液の吐出は、ウェハを回転させながら行ってもよい。 (S2) A predetermined amount (0.3 L) of SC-1 liquid (ammonia hydrogen peroxide water mixture) at 70° C. is discharged onto the wafer from the nozzle 13a at 0.9 L/min for 20 seconds (S2a, Figure 5B). After stopping the discharge of the SC-1 liquid, the wafer W is rotated at a low speed of about 30 rpm for about 10 seconds to spread the SC-1 liquid evenly throughout the storage section 24. Note that the SC-1 liquid may be discharged while rotating the wafer.

SC-1液の供給を止めた状態で、ウェハWの回転を止めて、あるいはウェハWを回転させながら120秒程度洗浄処理を行う(S2b、図5C)。好ましくは、ウェハを低速回転させながら洗浄処理を行うことによって、処理液の循環性が高まり、洗浄処理時の反応速度を高くすることができる。SC-1液を基板上に溜めて処理を行うことで、処理液を掛け流して処理を行う従来の方法と比べて、SC-1液の使用量を大幅に低減できる。 With the supply of the SC-1 liquid stopped, the cleaning process is performed for about 120 seconds with the rotation of the wafer W stopped or while the wafer W is rotated (S2b, FIG. 5C). Preferably, by performing the cleaning process while rotating the wafer at a low speed, the circulation of the treatment liquid can be improved and the reaction rate during the cleaning process can be increased. By storing the SC-1 liquid on the substrate and performing the process, the amount of SC-1 liquid used can be significantly reduced compared to the conventional method of pouring the process liquid over the substrate.

洗浄処理が完了したら、枠部材20を枠部材保持手段30で保持して、50mm程度持ち上げる。ウェハWを600rpmで回転させて、SC-1液をウェハ外周からふり払う(S2c、図5D)。 After the cleaning process is completed, the frame member 20 is held by the frame member holding means 30 and lifted by about 50 mm. The wafer W is rotated at 600 rpm to shake off the SC-1 liquid from the outer periphery of the wafer (S2c, FIG. 5D).

(S3)ウェハWの回転数を30rpmに下げ、枠部材20を、ウェハとの距離が約1mmになるまで降下させる。ノズル13bからウェハ上に、25℃の純水(DIW)を例えば1L/分で60秒吐出する(S3a、図5E)。純水はウェハ表面をリンスするとともに、枠部材表面に残留するSC-1液を洗い流す。純水の供給量は、好ましくは、純水が枠部材上端を超えてあふれ出すほどの大きさとする。これにより、枠部材の表面全体をまんべんなく洗うことができる。枠部材20の全体をウェハの上面より高い位置に上げることで、枠部材の表面全体を容易に洗浄できる。 (S3) The rotational speed of the wafer W is lowered to 30 rpm, and the frame member 20 is lowered until the distance from the wafer is approximately 1 mm. Pure water (DIW) at 25° C. is discharged onto the wafer from the nozzle 13b at, for example, 1 L/min for 60 seconds (S3a, FIG. 5E). The pure water not only rinses the wafer surface, but also washes away the SC-1 liquid remaining on the frame member surface. The amount of pure water supplied is preferably large enough that the pure water overflows over the upper end of the frame member. This allows the entire surface of the frame member to be evenly washed. By raising the entire frame member 20 to a higher position than the upper surface of the wafer, the entire surface of the frame member can be easily cleaned.

リンス処理が完了したら、枠部材20を枠部材保持手段30で保持して50mm程度持ち上げ、ウェハWを600rpmで回転させて、純水をウェハ外周からふり払う(S3b、図5F)。 When the rinsing process is completed, the frame member 20 is held by the frame member holding means 30 and lifted by about 50 mm, and the wafer W is rotated at 600 rpm to shake off the pure water from the outer periphery of the wafer (S3b, FIG. 5F).

(S4)ウェハWの回転を止めて、工程S1と同様に、再度枠部材20をセットする。なお、枠部材20はSC-1洗浄で用いた枠部材と同じものを用いても良いが、枠部材の汚染を考慮して、別の枠部材を用いることが好ましい。
(S5)ノズル13aからウェハ上にSC-2液(塩酸過酸化水素水混合液)を吐出し、以後工程S2と同様にSC-2洗浄を行う。
(S6)工程S3と同様にリンス処理を行う。
(S7)リンス処理の完了後に乾燥処理を行って、RCA洗浄を終了する。
(S4) Stop the rotation of the wafer W, and set the frame member 20 again in the same manner as in step S1. Note that the same frame member used in the SC-1 cleaning may be used as the frame member 20, but in consideration of contamination of the frame member, it is preferable to use a different frame member.
(S5) SC-2 liquid (hydrochloric acid/hydrogen peroxide mixed solution) is discharged onto the wafer from the nozzle 13a, and thereafter SC-2 cleaning is performed in the same manner as in step S2.
(S6) Perform rinsing treatment in the same manner as step S3.
(S7) After the rinsing process is completed, a drying process is performed to complete the RCA cleaning.

基板処理装置の第2実施形態を図6~10に基づいて説明する。本実施形態の基板処理装置は円板状の基板を処理するための装置であって、第1実施形態が枠部材を基板上に載置するのに対して、枠部材を基板に近接させた状態で基板を処理する。 A second embodiment of the substrate processing apparatus will be described based on FIGS. 6 to 10. The substrate processing apparatus of this embodiment is an apparatus for processing a disk-shaped substrate, and unlike the first embodiment in which the frame member is placed on the substrate, the frame member is placed close to the substrate. Process the substrate in the correct condition.

図6を参照して、本実施形態の基板処理装置40は、ウェハ(基板)Wを保持する基板保持部11と、基板保持部11を回転させる基板回転手段12と、ウェハW上に処理液を吐出する複数のノズル(処理液供給部)13と、枠部材50と、枠部材支持手段60とを有する。 Referring to FIG. 6, the substrate processing apparatus 40 of the present embodiment includes a substrate holding section 11 that holds a wafer (substrate) W, a substrate rotation means 12 that rotates the substrate holding section 11, and a processing liquid on the wafer W. It has a plurality of nozzles (processing liquid supply section) 13 for discharging the liquid, a frame member 50, and a frame member support means 60.

基板保持部11は第1実施形態と同じである。ただし、ウェハWに結晶方位を示すための切り欠きがある場合は、基板保持部11としてウェハと同じ直径の円形の真空吸着テーブルであって、ウェハの切り欠かれた部分に吸引孔が現れないものを用いる。基板回転手段12およびノズル13は第1実施形態と同じである。また、処理液の種類も第1実施形態と同じく、特に限定されない。 The substrate holder 11 is the same as in the first embodiment. However, if the wafer W has a notch to indicate the crystal orientation, the substrate holder 11 should be a circular vacuum suction table with the same diameter as the wafer, so that no suction holes appear in the notched part of the wafer. use something The substrate rotation means 12 and nozzle 13 are the same as in the first embodiment. Furthermore, the type of treatment liquid is not particularly limited, as in the first embodiment.

図7を参照して、枠部材50はリング状の部材である。枠部材の内径はウェハWの直径とほぼ同じである。枠部材50の外周にはつば部53が形成され、つば部が枠部材支持手段60に連結されることで、枠部材が支持される。 Referring to FIG. 7, frame member 50 is a ring-shaped member. The inner diameter of the frame member is approximately the same as the diameter of the wafer W. A flange portion 53 is formed on the outer periphery of the frame member 50, and the frame member is supported by connecting the flange portion to the frame member support means 60.

図7Bを参照して、枠部材50の内径がウェハWの直径より小さい場合は、枠部材の下面52を、ウェハWの上面との間に隙間Gを残して、ウェハの上面に近接させることによって、枠部材の内壁面51とウェハの上面とで処理液を溜める貯留部54を形成できる。このときの隙間Gの大きさは、処理液の供給量や粘度、さらにはウェハの回転数によって選択されるが、好ましくは1mm以下、より好ましくは0.1mm以下である。隙間Gが狭いほど、貯留部から処理液が漏れる量を少なくできるからである。一方、後述するように、本実施形態の枠部材50はウェハとは独立して回転可能であるので、枠部材を回転させる場合、隙間Gの大きさは、好ましくは1μm以上である。枠部材を回転させたときにウェハとの干渉を避けるためである。また、枠部材50の内径は、ウェハWの直径をdとすると、好ましくはd-20mm以上、より好ましくはd-6mm以上であって、d未満である。なお、ウェハに結晶方位を示すための切り欠きがある場合は、基板保持部11としてウェハと同じ直径の円形の真空吸着テーブルであって、ウェハの切り欠かれた部分に吸引孔が現れないものを用いる。これにより、ウェハ上面および基板保持部のテーブル上面が貯留部54の底面を構成する。 Referring to FIG. 7B, if the inner diameter of the frame member 50 is smaller than the diameter of the wafer W, the lower surface 52 of the frame member should be brought close to the upper surface of the wafer W, leaving a gap G between the frame member 50 and the upper surface of the wafer W. Accordingly, a reservoir 54 for storing the processing liquid can be formed between the inner wall surface 51 of the frame member and the upper surface of the wafer. The size of the gap G at this time is selected depending on the supply amount and viscosity of the processing liquid and the rotational speed of the wafer, but is preferably 1 mm or less, more preferably 0.1 mm or less. This is because the narrower the gap G, the smaller the amount of processing liquid leaking from the reservoir. On the other hand, as will be described later, the frame member 50 of this embodiment is rotatable independently of the wafer, so when rotating the frame member, the size of the gap G is preferably 1 μm or more. This is to avoid interference with the wafer when the frame member is rotated. Further, the inner diameter of the frame member 50 is preferably d-20 mm or more, more preferably d-6 mm or more, and less than d, where d is the diameter of the wafer W. If the wafer has a notch to indicate the crystal orientation, the substrate holder 11 should be a circular vacuum suction table with the same diameter as the wafer, and no suction holes will appear in the notched part of the wafer. Use. As a result, the top surface of the wafer and the top surface of the table of the substrate holding section constitute the bottom surface of the storage section 54 .

図7Cを参照して、枠部材50の内径がウェハWの直径より大きい場合は、枠部材の内壁面51を、ウェハの外周端面との間に隙間Hを残して、ウェハの外周端面に近接させることによって、枠部材の内壁面51とウェハの上面とで処理液を溜める貯留部54を形成できる。このときの隙間Hの大きさは、図7Bの場合と同じ理由から、好ましくは1mm以下、より好ましくは0.1mm以下であり、好ましくは1μm以上である。枠部材50の内径は、ウェハWの直径をdとすると、dに隙間Hの2倍を足した大きさであるから、枠部材50の内径の好ましい範囲は、隙間Hの好ましい範囲に応じて定まる。なお、ウェハに結晶方位を示すための切り欠きがある場合は、基板保持部11としてウェハと同じ直径の円形の真空吸着テーブルであって、ウェハの切り欠かれた部分に吸引孔が現れないものを用いる。これにより、ウェハ上面および基板保持部のテーブル上面が貯留部54の底面を構成する。 Referring to FIG. 7C, when the inner diameter of the frame member 50 is larger than the diameter of the wafer W, the inner wall surface 51 of the frame member is moved close to the outer circumferential end surface of the wafer, leaving a gap H between the frame member 50 and the outer circumferential edge surface of the wafer. By doing so, a reservoir 54 for storing the processing liquid can be formed between the inner wall surface 51 of the frame member and the upper surface of the wafer. The size of the gap H at this time is preferably 1 mm or less, more preferably 0.1 mm or less, and preferably 1 μm or more for the same reason as in the case of FIG. 7B. The inner diameter of the frame member 50 is the sum of d and twice the gap H, where d is the diameter of the wafer W. Therefore, the preferable range of the inner diameter of the frame member 50 depends on the preferable range of the gap H. Determined. If the wafer has a notch to indicate the crystal orientation, the substrate holder 11 should be a circular vacuum suction table with the same diameter as the wafer, and no suction holes will appear in the notched part of the wafer. Use. As a result, the top surface of the wafer and the top surface of the table of the substrate holding section constitute the bottom surface of the storage section 54 .

また、図7Dを参照して、枠部材50の内径がウェハWの直径より大きい場合は、枠部材に、貯留部54から処理液が流れ出るための流出孔55が形成されていることが好ましい。後述するように、基板処理時の処理液の流れを安定させるためである。 Further, referring to FIG. 7D, when the inner diameter of the frame member 50 is larger than the diameter of the wafer W, it is preferable that the frame member is formed with an outflow hole 55 through which the processing liquid flows out from the storage section 54. As will be described later, this is to stabilize the flow of the processing liquid during substrate processing.

図8を参照して、枠部材支持手段60は、垂直に立つ2本の支柱61と、ケース62と、支持部材65とを有する。ケース62は、2本の支柱に対応する2か所に、天面と底面にガイド穴が設けられており、支柱をガイド穴に挿通することで支柱によって支持される。ケース62のウェハW上方にあたる部分には、ウェハとほぼ同じ大きさの穴63が上下に貫通し、穴63の内壁面にはボールベアリング64が装着されている。ボールベアリング64としては、耐酸性、耐薬品性に優れるセラミックボールベアリングを好適に用いることができる。 Referring to FIG. 8, frame member support means 60 includes two vertically standing columns 61, a case 62, and a support member 65. The case 62 is provided with guide holes on the top and bottom surfaces at two locations corresponding to the two pillars, and is supported by the pillars by inserting the pillars into the guide holes. A hole 63 of approximately the same size as the wafer vertically passes through a portion of the case 62 above the wafer W, and a ball bearing 64 is mounted on the inner wall surface of the hole 63. As the ball bearing 64, a ceramic ball bearing having excellent acid resistance and chemical resistance can be suitably used.

支持部材65は略円筒形で、上部がボールベアリング64に内接して、ケースから吊り下げられている。支持部材の下端部には、支持部材と枠部材50が同心になるように、枠部材50のつば部53が連結されている。支持部材65の略円筒形の内部には、処理液を供給するためのノズル13や、各種センサの配線などを挿通させることができる。 The support member 65 has a substantially cylindrical shape, has an upper portion inscribed in the ball bearing 64, and is suspended from the case. A collar portion 53 of the frame member 50 is connected to the lower end of the support member so that the support member and the frame member 50 are concentric. The nozzle 13 for supplying the processing liquid, wiring for various sensors, and the like can be inserted into the substantially cylindrical interior of the support member 65.

ケース62の内部にはモーター66が設置され、モーターの軸と支持部材上部に掛けまわされたベルト67によって、支持部材がその中心軸の周りに回転可能となっている。支持部材を回転させることによって、支持部材下端部に連結された枠部材50が回転する。本実施形態では、モーター66が枠部材回転手段である。 A motor 66 is installed inside the case 62, and the support member can be rotated around its central axis by a belt 67 wrapped around the shaft of the motor and the upper part of the support member. By rotating the support member, the frame member 50 connected to the lower end of the support member rotates. In this embodiment, the motor 66 is a frame member rotating means.

また、モーター66やベルト67がケース62内に収容されることによって、ベルト等からの発塵によるウェハの汚染を防止することができる。好ましくは、ケース62に設けられた排気口68から内部の空気を吸引して、ケース内部を負圧にすることで、ケース外に塵やパーティクルが漏れることをより確実に防止できる。 Further, by housing the motor 66 and the belt 67 in the case 62, contamination of the wafer due to dust generated from the belt or the like can be prevented. Preferably, internal air is sucked through an exhaust port 68 provided in the case 62 to create a negative pressure inside the case, thereby more reliably preventing dust and particles from leaking out of the case.

ケース62、支持部材65および枠部材50は、支柱61に沿って昇降可能である。あるいは、ケース62、支持部材65、枠部材50および支柱61の全体が昇降可能であってもよい。枠部材50の内径がウェハWの直径より小さい場合は(図7B)、枠部材50の下面52がウェハ上面に近接する位置を少なくとも含む範囲で、枠部材を昇降可能とする。枠部材50の内径がウェハWの直径より大きい場合は(図7C)、枠部材50の内壁面51がウェハの外周端面に近接する位置を少なくとも含む範囲で、枠部材を昇降可能とする。なお、枠部材支持手段60と基板保持部11は上下方向に相対的に可動であればよいので、基板保持部11を昇降可能としてもよい。 The case 62, the support member 65, and the frame member 50 can be moved up and down along the support column 61. Alternatively, the entire case 62, support member 65, frame member 50, and support column 61 may be movable up and down. When the inner diameter of the frame member 50 is smaller than the diameter of the wafer W (FIG. 7B), the frame member can be raised and lowered within a range that includes at least a position where the lower surface 52 of the frame member 50 is close to the upper surface of the wafer. When the inner diameter of the frame member 50 is larger than the diameter of the wafer W (FIG. 7C), the frame member can be moved up and down within a range that includes at least a position where the inner wall surface 51 of the frame member 50 is close to the outer peripheral end surface of the wafer. Incidentally, since it is sufficient that the frame member support means 60 and the substrate holding section 11 are relatively movable in the vertical direction, the substrate holding section 11 may be able to be moved up and down.

基板保持部11がウェハWを水平から傾斜させて保持可能な場合は、枠部材支持手段60も、例えば支柱61を傾けることによって、支持部材65を基板保持部11と同軸に保ちながら、基板保持部11の傾きに合わせて傾斜可能とする。 When the substrate holder 11 can hold the wafer W at an angle from the horizontal, the frame member support means 60 can also hold the wafer W while keeping the support member 65 coaxial with the substrate holder 11 by, for example, tilting the support 61. It can be tilted according to the inclination of the portion 11.

次に、本実施形態の基板処理装置の使用方法を、シリコンウェハのフッ酸エッチングを例に、図9の工程の流れに沿って、図10を参照して説明する。以下においては、枠部材の内径がウェハの直径より大きい場合(図7C)を例に説明する。 Next, a method of using the substrate processing apparatus of this embodiment will be described with reference to FIG. 10, using hydrofluoric acid etching of a silicon wafer as an example, along the process flow of FIG. 9. In the following, a case where the inner diameter of the frame member is larger than the diameter of the wafer (FIG. 7C) will be explained as an example.

(S8)ウェハWが基板保持部11に固定され、回転していない状態で、枠部材50の内壁面51とウェハの外周端面が近接する位置まで枠部材50を降下させる(図10A)。このとき、枠部材50に形成された流出孔55がウェハの上面より下に隠れる位置まで枠部材を降下させる(図10B)。 (S8) With the wafer W fixed to the substrate holder 11 and not rotating, the frame member 50 is lowered to a position where the inner wall surface 51 of the frame member 50 and the outer peripheral end surface of the wafer are close to each other (FIG. 10A). At this time, the frame member 50 is lowered to a position where the outflow hole 55 formed in the frame member 50 is hidden below the upper surface of the wafer (FIG. 10B).

(S9)ノズル13aからウェハ上に、HF液を所定の流量で吐出する(S9a、図10C)。ウェハWと枠部材50を、同方向に30rpm程度の低速で約10秒間回転させて、HF液を貯留部54の全体にまんべんなく行きわたらせる。 (S9) The HF liquid is discharged onto the wafer from the nozzle 13a at a predetermined flow rate (S9a, FIG. 10C). The wafer W and the frame member 50 are rotated in the same direction at a low speed of about 30 rpm for about 10 seconds to spread the HF liquid evenly throughout the storage section 54.

ウェハWと枠部材50の回転を止めて、そのまま60秒程度停止させてエッチング処理を行う(S9b)。ウェハWと枠部材50を約60rpmで回転させ、ノズル13aからHF液を所定の流量で供給しながら、枠部材50を少し上昇させて、流出孔55がウェハの上面より上に出す(図10D)。これにより、貯留部54のHF液は、隙間Hに加えて流出孔55からもウェハ外へ流れ出す。HF液を流出孔55からも流出させる理由は、処理液の流れを安定させるためである。また、枠部材50の高さ方向の位置を数十μm単位で制御することで、流出孔55がウェハより上に出る量に応じて貯留部54からのHF液の流出量を調節できる。HF液供給量と流出量が釣り合って、ウェハ面上のHF液の膜厚が一定になった状態でさらに60秒間エッチング処理を行う(S9b)。 The rotation of the wafer W and the frame member 50 is stopped, and the etching process is performed while the rotation is stopped for about 60 seconds (S9b). The wafer W and the frame member 50 are rotated at about 60 rpm, and the frame member 50 is slightly raised while supplying the HF liquid from the nozzle 13a at a predetermined flow rate, so that the outflow hole 55 is exposed above the upper surface of the wafer (FIG. 10D). ). As a result, the HF liquid in the reservoir 54 flows out of the wafer from the outflow hole 55 in addition to the gap H. The reason why the HF liquid is also allowed to flow out from the outflow hole 55 is to stabilize the flow of the processing liquid. Furthermore, by controlling the position of the frame member 50 in the height direction in units of several tens of micrometers, the amount of HF liquid flowing out from the storage section 54 can be adjusted depending on the amount by which the outflow hole 55 protrudes above the wafer. When the HF liquid supply amount and outflow amount are balanced and the film thickness of the HF liquid on the wafer surface becomes constant, etching processing is performed for another 60 seconds (S9b).

エッチング処理が完了したら、HF液の供給を停止する(S9c)。なお、エッチング処理中に、液温、液膜厚、液のHF濃度、ケイフッ化水素酸濃度、ウェハのシリコン酸化膜の膜厚などをウェハ上部に設置しているセンサで測定して、所定の値を閾値として、回転とHF液吐出の時間を延長または停止してもよく、回転数を変更してもよく、センサの値に応じた制御を実施してもよい。 When the etching process is completed, the supply of the HF liquid is stopped (S9c). During the etching process, the temperature of the liquid, the thickness of the liquid film, the HF concentration of the liquid, the concentration of hydrofluorosilicic acid, the thickness of the silicon oxide film on the wafer, etc. are measured by sensors installed above the wafer, and the specified values are measured. Using the value as a threshold, the time of rotation and HF liquid discharge may be extended or stopped, the rotation speed may be changed, or control may be performed according to the sensor value.

(S10)HF液の供給を停止すると同時に、ノズル13bから純水の吐出を開始して、ウェハおよび枠部材50を洗浄する(S10a、図10E)。次いで、枠部材50をウェハ上面から50mmの高さまで上昇させて枠部材の回転を停止し、ウェハを約500rpmで回転させて、純水をウェハ外周からふり払う(S10b、図10F)。 (S10) At the same time as stopping the supply of the HF liquid, discharge of pure water is started from the nozzle 13b to clean the wafer and the frame member 50 (S10a, FIG. 10E). Next, the frame member 50 is raised to a height of 50 mm from the top surface of the wafer, the rotation of the frame member is stopped, and the wafer is rotated at about 500 rpm to shake off the pure water from the outer periphery of the wafer (S10b, FIG. 10F).

(S11)リンス処理の完了後に乾燥処理を行って、HFエッチング処理を終了する。 (S11) After the rinsing process is completed, a drying process is performed to complete the HF etching process.

本実施形態ではHF液の供給を続けながら基板の処理を行うが、枠部材50によってウェハの外周から排出されるHF液の流量が従来の掛け流し方式より少ないので、HF液の使用量を低減できる。 In this embodiment, the substrate is processed while continuing to supply the HF liquid, but since the flow rate of the HF liquid discharged from the outer periphery of the wafer by the frame member 50 is lower than that of the conventional continuous flow method, the amount of HF liquid used is reduced. can.

なお、上記方法では、ウェハWと枠部材50を常に同方向に同速度で回転させたが、ウェハと枠部材の回転方向および回転速度は同じであっても異なっていてもよい。 Note that in the above method, the wafer W and the frame member 50 are always rotated in the same direction and at the same speed, but the rotation direction and rotation speed of the wafer and the frame member may be the same or different.

また、上記方法では、枠部材50の内径がウェハWの直径より大きい場合について説明したが、枠部材50の内径がウェハWの直径より小さい場合も同様に行うことができる。 Moreover, although the above method has been described for the case where the inner diameter of the frame member 50 is larger than the diameter of the wafer W, the same method can be performed when the inner diameter of the frame member 50 is smaller than the diameter of the wafer W.

本発明は、上記の実施形態や実施例に限定されるものではなく、その技術的思想の範囲内で種々の変形が可能である。 The present invention is not limited to the above-described embodiments and examples, and various modifications can be made within the scope of the technical idea.

例えば、上記実施形態では、ウェハを水平に保持して処理を行ったが、ウェハを水平からわずかに傾斜させて処理を行ってもよい。その場合は、貯留部24、54内に、ウェハ上に液がある状態とない状態を回転周期毎に作り出すことができるので、洗浄条件を多様にすることができる。また、ウェハの傾斜角度を変えながら処理を行うこともできる。 For example, in the above embodiment, the wafer is held horizontally and processed, but the wafer may be slightly tilted from the horizontal and processed. In this case, it is possible to create a state in which the liquid is present on the wafer and a state in which it is not present in the reservoirs 24 and 54 for each rotation period, so that the cleaning conditions can be varied. Furthermore, processing can be performed while changing the inclination angle of the wafer.

10 基板処理装置
11 基板保持部
12 基板回転手段
13 ノズル(処理液供給部)
20 枠部材
21 内壁面
22 凹部
23 つば部
24 貯留部
30 枠部材保持手段
31 旋回軸
32 アーム
33 保持部
40 基板処理装置
50 枠部材
51 内壁面
52 下面
53 つば部
54 貯留部
55 流出孔
60 枠部材支持手段
61 支柱
62 ケース
63 穴
64 ボールベアリング
65 支持部材
66 モーター
67 ベルト
68 排気口
G、H 隙間
W ウェハ(基板)
10 Substrate processing apparatus 11 Substrate holding section 12 Substrate rotation means 13 Nozzle (processing liquid supply section)
20 Frame member 21 Inner wall surface 22 Recessed portion 23 Flange portion 24 Storage portion 30 Frame member holding means 31 Rotating shaft 32 Arm 33 Holding portion 40 Substrate processing apparatus 50 Frame member 51 Inner wall surface 52 Lower surface 53 Flange portion 54 Storage portion 55 Outflow hole 60 Frame Member support means 61 Support column 62 Case 63 Hole 64 Ball bearing 65 Support member 66 Motor 67 Belt 68 Exhaust port G, H Gap W Wafer (substrate)

Claims (2)

処理液を用いて基板を処理するための基板処理装置であって、
前記基板を保持する基板保持部と、
前記基板保持部を回転させる基板回転手段と、
前記基板上に前記処理液を吐出する処理液供給部と、
平面視において内側に囲む形状が前記基板の外形より小さく、前記基板の外周部に載置して、前記基板とともに前記処理液の貯留部を形成可能な枠部材と、
前記枠部材を保持または開放可能で、前記基板保持部と上下方向に相対的に可動な枠部材保持手段と、
を有する基板処理装置。
A substrate processing apparatus for processing a substrate using a processing liquid,
a substrate holding part that holds the substrate;
substrate rotation means for rotating the substrate holding section;
a processing liquid supply unit that discharges the processing liquid onto the substrate;
a frame member whose inner enclosing shape is smaller than the outer shape of the substrate in a plan view, and which can be placed on the outer periphery of the substrate to form a reservoir for the processing liquid together with the substrate;
a frame member holding means capable of holding or opening the frame member and movable vertically relative to the substrate holding section;
A substrate processing apparatus having:
処理液を用いて円板状の基板を処理するための基板処理装置であって、
前記基板を保持する基板保持部と、
前記基板保持部を回転させる基板回転手段と、
前記基板上に前記処理液を吐出する処理液供給部と、
前記基板とともに前記処理液の貯留部を形成する枠部材と、
前記枠部材を支持し、前記枠部材を回転させる枠部材回転手段を備え、前記枠部材の内径が前記基板の直径より小さい場合は、該枠部材の下面が前記基板の上面に近接する位置を少なくとも含む範囲で、前記枠部材の内径が前記基板の直径より大きい場合は、該枠部材の内壁面が前記基板の外周端面に近接する位置を少なくとも含む範囲で、前記基板保持部と上下方向に相対的に可動な枠部材支持手段と、
を有する基板処理装置。
A substrate processing apparatus for processing a disk-shaped substrate using a processing liquid,
a substrate holding part that holds the substrate;
substrate rotation means for rotating the substrate holding section;
a processing liquid supply unit that discharges the processing liquid onto the substrate;
a frame member that forms a reservoir for the processing liquid together with the substrate;
A frame member rotating means for supporting the frame member and rotating the frame member is provided, and when the inner diameter of the frame member is smaller than the diameter of the substrate, the lower surface of the frame member is positioned close to the upper surface of the substrate. If the inner diameter of the frame member is larger than the diameter of the substrate, the inner wall surface of the frame member is vertically connected to the substrate holder at least in a range that includes at least a position close to the outer peripheral end surface of the substrate. a relatively movable frame member support means;
A substrate processing apparatus having:
JP2022049369A 2022-03-25 2022-03-25 Substrate processing apparatus Pending JP2023142449A (en)

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