JP2023130988A - Functional liquid carrier, functional sustained-release formulation, and molded article - Google Patents

Abstract

To provide a functional liquid carrier that can maintain an excellent sustained-release effect for a long time, a functional sustained-release formulation, and a molded article.SOLUTION: A functional liquid carrier includes a porous coordination polymer including an organic ligand and a metal ion, and function sustained-release liquid. The organic ligand includes at least one kind selected from a group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole. If the organic ligand includes the fumaric acid, an amount of free fumaric acid in the porous coordination polymer is 0.7 mass% or less relative to 100 mass% of the porous coordination polymer; if the organic ligand includes the terephthalic acid, an amount of free terephthalic acid in the porous coordination polymer is 0.5 mass% or less relative to 100 mass% of the porous coordination polymer; if the organic ligand includes benzenetricarboxylic acid, an amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.6 mass% or less relative to 100 mass% of the porous coordination polymer; and if the organic ligand includes methylimidazole, an amount of free methylimidazole in the porous coordination polymer is 0.7 mass% or less relative to 100 mass% of the porous coordination polymer.SELECTED DRAWING: None

Description

The present invention relates to a functional liquid carrier, a functional sustained release composition, and a molded article.

In a molded product containing a functional component for controlling small animals, by releasing a predetermined amount of the functional component from the molded product over a long period of time, it is expected that the sustainability of the effect will be improved. As a method for increasing the sustainability of the effect of small animal control functional components, molded bodies using small animal control composite materials in which small animal control functional components are developed in a matrix resin have been devised (for example, Patent Documents 1 to 4). The molded bodies described in Patent Documents 1 to 4 gradually release a small animal control functional component onto the surface of the molded body (hereinafter referred to as "sustained release"), thereby reducing the amount of damage on the surface of the molded body that comes into contact with small animals such as pests. Can maintain small animal control function. In order to maintain such sustained release properties for a long period of time, it is conceivable to increase the amount of functional sustained release components developed in the matrix resin. Increasing the amount of the functional sustained release component is also effective from the viewpoint of further strengthening the function.

Japanese Patent Application Publication No. 2001-73886 Japanese Patent Application Publication No. 2000-212005 Japanese Patent Application Publication No. 2008-206492 Japanese Patent Application Publication No. 2012-6868

However, porous coordination polymers that hold functional sustained-release components have a problem in that the amount of functional sustained-release liquid adsorbed varies within or between lots during the manufacturing process.
Therefore, even if a fixed amount of functional sustained-release liquid is blended into a porous coordination polymer for the purpose of functional expression, the amount of functional sustained-release liquid adsorbed by the porous coordination polymer varies, resulting in Variations also occur in the functions of the molded bodies. Similarly, even if a molded product is manufactured with a constant blending amount of porous coordination polymer, there is a problem that the functionality of the molded product will vary due to variations in the adsorption amount of the functional sustained release liquid. has.

Therefore, an object of the present invention is to provide a functional liquid carrier, a functional sustained release composition, and a molded article that can maintain an excellent sustained release effect over a long period of time.

As a result of extensive research to solve the above problems, the present inventors found that a porous coordination polymer having a specific organic ligand and a metal ion, and a specific functional sustained release liquid, The above problem is solved by using a functional liquid carrier containing a free organic ligand derived from a specific organic ligand in a porous coordination polymer in a specific amount or less as a functional sustained release component. We have discovered that this can be done, and have completed the present invention.

That is, the present invention includes the following contents.
[1] A porous coordination polymer having an organic ligand and a metal ion, and a functional sustained release liquid, wherein the organic ligand is fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methyl imidazole, and when the organic ligand contains fumaric acid, the amount of free fumaric acid in the porous coordination polymer is 100% by mass of the porous coordination polymer. %, and when the organic ligand contains terephthalic acid, the amount of free terephthalic acid in the porous coordination polymer is 0.7% by mass or less % by mass, and when the organic ligand contains benzenetricarboxylic acid, the amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.5% by mass or less with respect to the porous coordination polymer. When the amount of free methylimidazole in the porous coordination polymer is 0.6% by mass or less based on 100% by mass of the polymer, and the organic ligand contains methylimidazole, the amount of free methylimidazole in the porous coordination polymer is A functional liquid carrier having an amount of 0.7% by mass or less based on 100% by mass of the polymer.

[2] The functional liquid carrier according to [1], wherein the metal ion includes one or more selected from the group consisting of aluminum ions, zirconium ions, chromium ions, copper ions, iron ions, and zinc ions.

[3] The functional liquid carrier according to [1] or [2], wherein the functional sustained-release liquid has a molecular weight of 600 or less.

[4] The functional liquid carrier according to any one of [1] to [3], wherein the average pore diameter of the porous coordination polymer is equal to or larger than the molecular diameter of the functional sustained-release liquid.

[5] A functional sustained release composition comprising the functional liquid carrier according to any one of [1] to [4] and a matrix resin.

[6] The functional sustained release composition according to [5], wherein the surface concentration of the liquid component when compressed at 10 MPa or more is less than 1.0 mg/cm ² .

[7] A molded article comprising the functional sustained release composition according to [5] or [6].

According to the present invention, it is an object of the present invention to provide a functional liquid carrier, a functional sustained release composition, and a molded body that can maintain an excellent sustained release effect over a long period of time.

DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, a mode for carrying out the present invention (hereinafter simply referred to as "the present embodiment") will be described with reference to the drawings as necessary. This embodiment is an illustration for explaining the present invention, and the present invention is not limited only to the embodiment.

[Functional liquid carrier]
The functional liquid carrier of the present embodiment includes a porous coordination polymer having an organic ligand and a metal ion, and a functional sustained release liquid, wherein the organic ligand is fumaric acid or terephthalic acid. , benzenetricarboxylic acid, and methylimidazole, and when the organic ligand contains fumaric acid, the amount of free fumaric acid in the porous coordination polymer When the amount of free terephthalic acid in the porous coordination polymer is 0.7% by mass or less based on 100% by mass of the polymer, and the organic ligand contains terephthalic acid, the amount of free terephthalic acid in the porous coordination polymer When the amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.5% by mass or less based on 100% by mass and the organic ligand contains benzenetricarboxylic acid, the amount of free benzenetricarboxylic acid in the porous coordination polymer When the organic ligand contains methylimidazole, the amount of free methylimidazole in the porous coordination polymer is 0.6% by mass or less based on 100% by mass of the porous coordination polymer. %, it is 0.7% by mass or less.

Since the functional liquid carrier of the present embodiment is configured in this way, the functional sustained release composition and molded body containing the functional liquid carrier as a functional sustained release component exhibit an excellent sustained release effect. Can last for a long time. Therefore, the functional sustained release composition of this embodiment has advantages such as improved product performance and cost reduction due to reduced maintenance frequency.

In this embodiment, it is not clear why a functional sustained release composition and a molded article containing a functional liquid carrier as a functional sustained release component that can maintain an excellent sustained release effect for a long period of time can be obtained, but the present invention The inventors estimate as follows.
First, in the porous coordination polymer according to this embodiment, an organic ligand is adsorbed on the surface of the porous coordination polymer even if the same washing step is performed in the manufacturing process. Therefore, free substances derived from organic ligands that are not bonded to metal ions may exist on the surface of the porous coordination polymer. In this case, the free organic ligands close the pores of the porous coordination polymer, which reduces the adsorption power of the functional sustained release liquid to the porous coordination polymer. It is thought that the amount of liquid adsorption is also a cause of the decrease.
When the adsorption amount of the functional sustained release liquid in the porous coordination polymer decreases, it is necessary to increase the amount of the porous coordination polymer blended into the resin composition and molded body in order to compensate for the adsorption amount. be. As a result, the concentration of the porous coordination polymer in the resin composition and the molded body becomes apparently higher, which increases the amount of functional sustained-release liquid released from the molded body and also increases the rate of sustained release. It gets faster. As a result, the sustained release effect and lifespan of the molded product are significantly reduced.
Therefore, in order to maintain an excellent sustained release effect over a long period of time, it is necessary to keep the concentration of free substances derived from organic ligands below a certain level, and to use porous coordination polymers with less attachment of free substances for functional sustained release. It is estimated that it is necessary to use it as a sex liquid. However, the presumed reason is not limited to this.

The functional liquid carrier is preferably a porous material because it can maintain superior sustained release effects over a long period of time.

[Porous coordination polymer]
The functional sustained release carrier of this embodiment includes a porous coordination polymer. The porous coordination polymer according to this embodiment has an organic ligand and a metal ion.

The porous coordination polymer has, for example, a form in which metal ions are adsorbed to organic ligands. The porous coordination polymer is also called MOF (Metal-Organic Framework) or PCP (Porous Coordination Polymer).

Porous coordination polymers, for example, have a large number of pores in the macropore or mesopore region, and have a uniform pore diameter because the pore diameter (diameter of the pores) is determined based on the crystal structure. .

By controlling the length of the organic ligand and the affinity due to the chemical structure, the porous coordination polymer can increase the holding power of the functional sustained release liquid and can be packed closely. From the same viewpoint, the average pore diameter of the porous coordination polymer is preferably equal to or larger than the molecular diameter of the functional sustained release liquid described below.

The average pore diameter of the porous coordination polymer is preferably 0.1 nm or more and 5.0 nm or less, from the viewpoint of effectively developing the functional sustained release liquid with the matrix resin and further improving long-term sustained release properties. , more preferably 0.5 nm or more and 3.0 nm or less. Note that in this specification, the average pore diameter is measured using the MP (micropore anaylsis) method. For specific measurement methods, refer to Examples.

The molecular diameter of the functional sustained release liquid is preferably 0.1 nm or more and 5.0 nm or less, from the viewpoint of being able to effectively develop the functional sustained release liquid with a matrix resin and further improving long-term sustained release properties. More preferably, the thickness is .5 nm or more and 3.0 nm or less. In this specification, the molecular diameter of the functional sustained release liquid is determined by the following procedure using open source "Mol-view". First, a molecule is drawn and the major and minor axes of the molecule are measured within the software. Here, the major axis is the intermolecular distance in the long part when the molecules are stretched linearly, and the minor axis is the intermolecular distance in the short part when the molecules are stretched in the same way. Here, the above-mentioned "molecular diameter" corresponds to the above-mentioned short axis.

The specific surface area of the porous coordination polymer is preferably 900 m ² /g or more and 10400 m ² /g or less, more preferably 900 m ² /g or more and 9000 m ² /g or less, and 900 m ² /g or more and 7000 m ² /g or less is more preferable, and it is even more preferable that it is 900 m ² /g or more and 5000 m ² /g or less. If the specific surface area is 900 m ² /g or more, the porous coordination polymer will be able to incorporate the functional sustained-release liquid into the matrix, compared to the case where the functional sustained-release liquid is directly kneaded into the matrix resin to form a composite molded body. It tends to be more effectively developed by resin. Note that in this specification, the specific surface area is measured by the Brunauer-Emmett-Teller method (BET method). For specific measurement methods, refer to Examples.

Since a sufficient pore volume is required to adsorb the functional sustained release liquid, the gas adsorption amount of the porous coordination polymer is preferably 50 cm ³ /g or more and 5000 cm ³ /g or less, and 100 cm ³ /g or more and 4000 cm ³ /g or less, more preferably 150 cm ³ /g or more and 3000 cm ³ /g or less. In this specification, the amount of gas adsorption is determined by creating an isothermal adsorption curve and determining the amount of nitrogen adsorption at 0.99P/ _P in the curve. For specific measurement methods, refer to Examples.

From the viewpoint of sustained release properties in the resin composition and molded product, the content of the porous coordination polymer in the functional sustained release carrier should be 10 parts by mass or more in 100 parts by mass of the functional sustained release carrier. It is preferably at most 20 parts by mass and at most 50 parts by mass.

(organic ligand)
The porous coordination polymer of this embodiment includes an organic ligand. The organic ligand includes one or more selected from the group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole, since it can easily bind to metal salts and metal ions.
In this specification, these compounds include various isomers, such as stereoisomers (geometric isomers, enantiomers, diastereoisomers, etc.), structural isomers (positional isomers, etc.), and , solvates (hydrates, etc.) are also included. The same applies to other compounds described in this specification.

The porous coordination polymer may contain two or more of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole as organic ligands, but these compounds are preferred from the viewpoint of easier pore control. Among them, it is preferable to include only one type.

As the benzenetricarboxylic acid, 1,3,5-benzenetricarboxylic acid is preferable since the structure of the porous coordination polymer can be more easily constructed.

As the methylimidazole, 2-methylimidazole is preferable since the structure of the porous coordination polymer can be more easily constructed.

From the standpoint of being able to control the amount of functional sustained-release liquid adsorbed onto the porous coordination polymer, when the porous coordination polymer contains fumaric acid as an organic ligand, it is preferable that the porous coordination polymer binds to metal ions derived from fumaric acid. The amount of free fumaric acid (educt) is 0.7% by mass or less based on 100% by mass of the porous coordination polymer. The amount of free fumaric acid is preferably 0.5% by mass or less based on 100% by mass of the porous coordination polymer. The lower limit of the amount of free fumaric acid is 0% by mass or more, since it is preferable that free fumaric acid is not contained in the porous coordination polymer from the viewpoint of being able to control the amount of adsorption of the functional sustained release liquid. Considering the manufacturing process of the porous coordination polymer, the content may be 0.1% by mass or more.

From the standpoint of being able to control the amount of functional sustained-release liquid adsorbed onto the porous coordination polymer, when the porous coordination polymer contains terephthalic acid as an organic ligand, it is preferable that the porous coordination polymer binds to metal ions derived from terephthalic acid. The amount of free terephthalic acid (educt) is 0.5% by mass or less based on 100% by mass of the porous coordination polymer. The amount of free terephthalic acid is preferably 0.3% by mass or less based on 100% by mass of the porous coordination polymer. The lower limit of the amount of free terephthalic acid is 0% by mass or more, since it is preferable that the porous coordination polymer does not contain free terephthalic acid from the viewpoint of controlling the amount of adsorption of the functional sustained release liquid. Considering the manufacturing process of the porous coordination polymer, the content may be 0.1% by mass or more.

From the viewpoint of controlling the adsorption of the functional sustained-release liquid to the porous coordination polymer, when the porous coordination polymer contains benzenetricarboxylic acid as an organic ligand, it is possible to bind to metal ions derived from benzenetricarboxylic acid. The amount of free benzenetricarboxylic acid (educt) that is not present is 0.6% by mass or less based on 100% by mass of the porous coordination polymer. The amount of free benzenetricarboxylic acid is preferably 0.3% by mass or less based on 100% by mass of the porous coordination polymer. The lower limit of the amount of free benzenetricarboxylic acid is 0% by mass or more since it is preferable that the porous coordination polymer does not contain free benzenetricarboxylic acid from the viewpoint of controlling the adsorption amount of the functional sustained release liquid. In consideration of the manufacturing process of the porous coordination polymer, the content may be 0.1% by mass or more.

From the standpoint of being able to control the amount of functional sustained-release liquid adsorbed onto the porous coordination polymer, when the porous coordination polymer contains methylimidazole as an organic ligand, it is preferable that the porous coordination polymer binds to metal ions derived from methylimidazole. The amount of free methylimidazole (educt) is 0.7% by mass or less based on 100% by mass of the porous coordination polymer. The amount of free methylimidazole is preferably 0.5% by mass or less based on 100% by mass of the porous coordination polymer. The lower limit of the amount of free methylimidazole is 0% by mass or more, since it is preferable that the porous coordination polymer does not contain free methylimidazole, from the viewpoint of being able to control the amount of adsorption of the functional sustained release liquid. Considering the manufacturing process of the porous coordination polymer, the content may be 0.1% by mass or more.

In terms of adsorption amount of the functional sustained release liquid, the total content of organic ligands in the porous coordination polymer is 60% by mass or more and 90% by mass in 100% by mass of the porous coordination polymer. It is preferably at most 70% by mass and at most 85% by mass.

(Other organic ligands)
The porous coordination polymer of this embodiment does not contain any other organic ligands other than fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole as long as the effects of the present invention are achieved. But that's fine.

It is preferable that the other organic ligands include a crosslinking ligand capable of crosslinking to a metal ion. Examples of such bridging ligands include 2,5-dihydroxyterephthalic acid, 1,4-naphthalenedicarboxylic acid, 4,4'-biphenyldicarboxylic acid, 4,4''-p-terphenyldicarboxylic acid, Isophthalic acid, 1,3,5-tri-4-carboxylphenylbenzene, 4,4'-biphenyldicarboxylic acid, naphthalene dicarboxylic acid, hexaazatriphenylene, 2,5-dihydroxybenzoic acid, 5-cyano-benzenedicarboxylic acid , 5-ethyl-1,3-benzodicarboxylic acid, terephenyl-3,3',5,5'-tetracarboxylic acid, 9,10-anthracenedicarboxylic acid, imidazole, 2,2'-diamino-4,4 '-Stilbene dicarboxylic acid, 2,2'-dinitro-stilbene dicarboxylic acid, 2,5-dihydroxyterephthalic acid, 3,3',5,5'-tetracarboxydiphenylmethane, 1,2,4,5-tetrakis(4 -carboxyphenyl)benzene, 4,4',4''-s-triazine-2,4,6-trail-tribenzoic acid, 2-hydroxyterephthalic acid, biphenyl-3,3',5,5'-tetracarboxylic acid acid, biphenyl-3,4,5-tricarboxylic acid, 5-bromoisophthalic acid, and malonic acid. These organic ligands may be used alone or in combination of two or more.

When the porous coordination polymer contains other organic ligands, the amount of free other organic ligands (free substances) that are not bound to metal ions derived from the other organic ligands is The total amount is preferably 1.0% by mass or less based on 100% by mass of the coordination polymer. The lower limit of the amount of other free organic ligands is determined by the fact that no other free organic ligands are contained in the porous coordination polymer, from the viewpoint of controlling the adsorption amount of the functional sustained-release liquid. The content is preferably 0% by mass or more, but in consideration of the manufacturing process of the porous coordination polymer, the content may be 0.1% by mass or more.

(Metal ions)
The porous coordination polymer of this embodiment contains metal ions. The metal ion is not particularly limited as long as it can be bonded suitably to the organic ligand. The metal ions may be used alone or in combination of two or more. The metal ion may be present in the porous coordination polymer in the form of a compound such as a salt.

The metal ion is preferably a metal ion other than an alkali metal ion, since it can bond more suitably to an organic ligand. In addition, in this specification, the alkali metal ion refers to a lithium ion, a sodium ion, a potassium ion, a rubidium ion, a cesium ion, and a francium ion.

Metal ions include silver ions, aluminum ions, beryllium ions, calcium ions, cadmium ions, cerium ions, cobalt ions, chromium ions, copper ions, dysprosium ions, and erbium ions because they can bond more favorably with organic ligands. , europium ion, iron ion, gallium ion, gadolinium ion, holmium ion, indium ion, magnesium ion, manganese ion, molybten ion, neodymium ion, nickel ion, scandium ion, samarium ion, strontium ion, terbium ion, thulium ion, vanadium More preferred are ion, tungsten ion, yttrium ion, ytterbium ion, zinc ion, and zirconium ion.

The metal ion preferably contains one or more selected from the group consisting of aluminum ion, zirconium ion, chromium ion, copper ion, iron ion, and zinc ion, since it can more easily bind to an organic ligand. More preferred.

When the porous coordination polymer contains fumaric acid as an organic ligand, metal ions include aluminum ions, iron ions, copper ions, and magnesium ions because they can more easily bond with organic ligands. It is preferable that aluminum ions are included, and it is more preferable that aluminum ions are included.

When the porous coordination polymer contains terephthalic acid as an organic ligand, metal ions such as zirconium ions, chromium ions, aluminum ions, iron ions, and magnesium ions can be used because they can bond more easily with the organic ligands. ion, zinc ion, and more preferably zirconium ion and/or chromium ion.

When the porous coordination polymer contains benzenetricarboxylic acid as an organic ligand, metal ions such as iron ions, copper ions, chromium ions, iron ions, It preferably contains molybdenum ions and zinc ions, and more preferably contains iron ions and/or copper ions.

When the porous coordination polymer contains methylimidazole as an organic ligand, it is preferable that the metal ion contains a zinc ion or a cobalt ion, since it can more easily bond with the organic ligand. It is more preferable to include.

Since the structure of the porous coordination polymer can be more easily constructed, the total content of metal ions in the porous coordination polymer is 10% by mass or more in 100% by mass of the porous coordination polymer. It is preferably 40% by mass or less, and more preferably 15% by mass or more and 30% by mass or less.

[Method for producing porous coordination polymer]
The method for producing the porous coordination polymer is not particularly limited, and any known method can be employed as appropriate. Such manufacturing methods include, for example, solvent mixing methods such as normal temperature and normal pressure mixing, high temperature and normal pressure mixing, high temperature and high pressure mixing, microwave, ultrasonic, and electrochemical synthesis methods, as well as flow reactions such as column reactors, Examples include methods using a countercurrent mixing reactor, a continuous stirred tank reactor, a tubular flow reactor, microfluidic synthesis, and the like. Furthermore, mechanochemical synthesis methods include methods using mortar mixing, ball mill mixing, twin screw extruder, and the like.

[Functional sustained release liquid]
The functional sustained release carrier of this embodiment includes a functional sustained release liquid.
Functional sustained release properties in functional sustained release liquids include, for example, small animal control function, plant growth control function, antibacterial function, antifungal function, function of imparting plasticity to resin, sliding function, and self-sustaining function. It has functions such as repair function, catalytic function, medical function, antiviral function, self-cleaning function, fragrance function, etc., and has sustained release properties. The functional sustained release liquid may be a liquid component that has functional sustained release properties, or may be in the form of a liquefied solid component that has functional sustained release properties, or a solid component that has functional sustained release properties in a solvent. It may also be in a liquefied form by dissolving it in.

Functional sustained-release liquids that have a function of controlling small animals include, for example, drugs or drugs that have a control activity against small animals such as various agricultural pests, sanitary pests, other insects, spiders, mites, and rats, dissolved in a solvent. For example, compounds with small animal repellent activity, insecticidal activity, acaricidal activity, spidericidal activity, rodenticidal activity, etc. , compounds with anti-feeding activity in small animals, and compounds with growth control activity in small animals.

Specific examples of small animal control agents include metadiamide insecticides such as brofuranilide, piperidine insecticides such as icaridine, chloronicotinyl insecticides such as imidacloprid, compounds consisting of neophyll radicals containing silicon atoms such as silafluofen, and benfuracarb. , aranicarb, methoxydiazone, carbosphan, fenobucarb, carbaryl, methomyl, propoxar, carbamate compounds such as phenoxycarb, pyrethrin, allethrin, dl, d-T80-allethrin, d-T80-resmethrin, bioallethrin, d-T80 - Pyrethroid compounds such as phthalthrin, phthalthrin, resmethrin, flamethrin, propathrin, permethrin, acrinathrin, etofenprox, tralomethrin, phenothrin, d-phenothrin, fenvalerate, empenthrin, pralethrin, tefluthrin, benfluthrin, transfluthrin, methofluthrin, dichloro Organophosphorus compounds such as Bosu, fenitrothion, diazinon, marathon, promophos, fenthion, trichlorfon, naled, temefos, fenclofos, chlorpyrifos-methyl, siafos, calcrofos, azamethyphos, pyridafenthione, propetanphos, chlorpyrifos, and their isomers, derivatives, and analogs etc.

Examples of compounds having growth control activity in small animals include methoprene, pyriproxyfen, quinoprene, hydroprene, deohenolan, NC-170, flufenoloxuron, diflubenzuron, lufenuron, and chlorazuron.

Compounds having small animalicidal activity include, for example, acaricides such as kersen, chlorfenavir, debufenpyradopyridaben, milbemectin, and fenpyroximate, silyloside, norbomide, zinc phosphide, thallium sulfate, yellow phosphorus, antu, warfarin, and endo. Examples include rodenticides such as side, coumarin, comatetralin, promadiolone, and difethialone.

Examples of small animal control agents include hinokitiol contained in Taiwanese cypress, Asunaro, Hinoki Asunaro (Aomori Hiba), casinol derivatives (α-casinol, T-casinol) contained in herbs and cypress, cloves, nutmeg, coriander, and cumin. Naturally derived agents such as geraniol, pinene, caryophyllene, borneol, eugenol, and cedar, which are abundantly contained in perfume oil plants, include known perfume oils that have small animal repellent properties.

Pheromone agents for insects and the like that have an attracting effect, a communication inhibiting effect, etc. are also used as small animal control agents. Examples of pheromone agents include Shin-Etsu Chemical's "Confuser R", "Confuser AA", "Confuser N", "Confuser MM", "Hamakicon-N", "Sukashibacon-L", "Shinquicon-L", and " Pheromone agents used for fruit trees such as 'Nashihimekon', 'Bokutokon-H', 'Hetumshikon', etc., Shin-Etsu Chemical products' 'Confuser V', 'Yotoukon-H', 'Yotoukon-S', 'Konagakon-Plus', Pheromone agents used for vegetables such as "Shin-Etsu Konagakon", pheromone agents used for tea such as Shin-Etsu Chemical's "Hamakikon-N", Shin-Etsu Chemical's "Ochimeracon", "Yotoukon-I", " Examples include pheromone agents used for sugarcane such as "Kebukakon".

The small animal control agent may be a repellent for wasps of the family Waspsidae, and the repellent for wasps of the family Waspsidae, for example, contains a compound represented by the following general formula (I) as an active ingredient.

In formula (I), R ¹ is a hydrogen atom, a C _1-4 alkyl group that may have a substituent β, a C _2-4 alkenyl group that may have a substituent β, or a substituent Represents a C _1-4 alkyl-carbonyl group which may have β, and X is a C 1-4 alkylene group which may have a substituent γ, or a C _1-4 alkylene group which may have a substituent γ represents a C _2-4 alkenylene group, α represents a C _{1-4 alkyl group which may have a substituent δ, a C 2-4} alkenyl group which may have a substituent δ, and α represents a C _2-4 alkenyl group which may have a substituent δ; C _1-4 alkoxy group which may have a substituent δ, C _1-4 alkyl-carbonyl group which may have a substituent δ, C _1-4 alkyl-carbonyloxy which may have a substituent δ represents one or more substituents selected from a group, a halogeno group, and a hydroxyl group. The substituents β, γ and δ are each independently selected from the group consisting of a C _1-4 alkoxy group, a C _1-4 alkyl-carbonyl group, a C _1-4 alkyl-carbonyloxy group, a halogeno group and a hydroxyl group. represents one or more substituents, and n represents an integer of 0 or more and 5 or less.

Further specific examples of the repellent for the family Wasps include, for example, the repellent described in JP 2017-88548A.

Examples of functional sustained-release liquids that control plant growth include plant hormones. Examples of plant hormones include natural or synthetic auxins such as indole-3-acetic acid, 2,4-dichlorophenoxyacetic acid, 2,6-dichlorobenzoic acid, naphthaleneacetic acid, zeatin, kinetin, 4-benzylaminobenzimidazole, Natural or synthetic cytokinins such as benzyladenine; gibberellins; brassinosteroids such as brassinolide and castasterone; abscisic acid and the like. These plant hormones may be used singly or in combination of two or more.

Examples of the functional sustained release liquid having an antibacterial function and an antifungal function include known antibacterial agents having a sustained release property and antifungal agents having a sustained release property. Examples of antibacterial agents and antifungal agents include natural organic compounds such as hinokitiol compounds, chitosan compounds, mustard extract compounds, and eucalyptus compounds, synthetic organic compounds, and organic composite agents. These compounds may be used alone or in combination of two or more. Among these, synthetic organic compounds are preferred from the viewpoint of effectively acting on both bacteria and mold.

Examples of synthetic organic compounds include nitrogen-containing heterocyclic compounds, aldehyde compounds, phenol compounds, biguanide compounds, nitrile compounds, halogen compounds, anilide compounds, disulfide compounds, thiocarbamate compounds, and organic compounds. Examples include silicon quaternary ammonium salt compounds, quaternary ammonium salt compounds, amino acid compounds, organometallic compounds, alcohol compounds, carboxylic acid compounds, ester compounds, thiazoline compounds, and cationic polymers. These synthetic organic compounds may be used alone or in combination of two or more.

Examples of functional sustained release liquids that have the function of imparting plasticity to resins include carboxylic acid ester derivatives, phosphoric acid ester derivatives, phosphazene derivatives, carboxylic acid amide derivatives, sulfonic acid ester derivatives, sulfonic acid amide derivatives, and sulfones. Amide derivatives may be mentioned. The plasticizers may be used alone or in combination of two or more.

Examples of carboxylic acid ester derivatives include alkyl esters of various carboxylic acids that may be substituted with hydroxyl groups, nitro groups, amino groups, epoxy groups, halogens, etc., and aromatic esters. Specific examples of carboxylic acid ester derivatives include dimethyl phthalate, diethyl phthalate, di-n-octyl phthalate, diphenyl phthalate, benzyl phthalate, dimethoxyethyl phthalate, and di(2-ethylhexyl 4,5-epoxyhexahydrophthalate). , 4,5-epoxycyclohexahydrophthalate di(7,8-epoxy-2-octenyl), 4,5-epoxycyclohexahydrophthalate di(9,10-epoxyoctadecyl), 4,5-epoxycyclohexyl Phthalate ester derivatives, isophthalate ester derivatives such as di(10,11-epoxyundecyl sahydrophthalate), di(tetrahydrofurfuryloxyethyl) phthalate, various phthalic acid mixed esters, and ethylene oxide adducts of phthalic acid mixed esters. , tetrahydrophthalic acid ester derivatives, butoxyethyl para-hydroxybenzoate, cyclohexyloxyethoxyethoxyethyl para-hydroxybenzoate, 2-ethylhexyl para-hydroxybenzoate, hydroxybenzoic acid ester of ω-alkyl oligoethylene oxide, para-hydroxy undecyl glycidyl ether Benzoic acid ester derivatives such as benzoic acid adducts, propionic acid ester derivatives such as di(tetrahydrofurfuryloxyethyl) thiodipropionate, adipate ester derivatives, azelaic acid ester derivatives, sebacic acid ester derivatives, dodecane-2-acid ester Derivatives, maleate ester derivatives, fumarate ester derivatives, trimetate ester derivatives, tris(2-ethylhexyl) trimellitate, tri(butoxyethoxyethyl) citrate, di-n-octyl-mono(nonylphenoxyethyl) citrate, citric acid Citric acid ester derivatives such as tri-n-octyl, dioctyl citrate (tetrahydrofurfuryloxyethyl), trimyristyl citrate, triethyl citrate, itaconic acid ester derivatives, oleic acid ester derivatives such as tetrahydrofurfuryl oleate, ricinoleic acid ester derivatives, lactic acid ester derivatives such as lactic acid (n-butyl), lactic acid (2-ethylhexyl), lactic acid (n-butoxyethoxyethyl), lactic acid (n-octoxyethoxyethyl), lactic acid (n-decyloxyethoxyethyl), Tartrate ester derivatives such as di(octoxyethoxyethyl) tartrate, (n-octyl) tartrate (nonylphenoxyethyl), di(octoxyethoxyethyl) tartrate, dibutoxyethyl malate, di(n-butoxyethoxyethyl malate) ), malic acid ester derivatives such as distearyl malate and octadecenylisononyl malate, and salicylic acid ester derivatives such as a salicylic acid adduct of benzyl glycidyl ether.

Examples of phosphate ester derivatives include trimethyl phosphate, triethyl phosphate, tributyl phosphate, tri-(2-ethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, tributoxyethyl phosphate, triphenyl phosphate, cresyl diphenyl phosphate, isodecyl - Diphenyl phosphate, tricresyl phosphate, tricylenyl phosphate, tri(chloroethyl) phosphate, xylenyl diphenyl phosphate, and tetrakis(2,4-di-tert-butylphenyl) 4,4'-biphenylene diphosphonate. .

Examples of phosphazene derivatives include cyclic phosphazene compounds represented by the following general formula (1).

In the formula, m represents an integer of 3 to 25, and R ¹ and R ² may be the same or different, and are an alkyl group having 1 to 8 carbon atoms, or an alkyl group having 1 to 8 carbon atoms. It shows a phenyl group which may be substituted with the following alkyl group and/or allyl group. The phosphazene derivative may be composed of one type of cyclic phosphazene compound represented by formula (1), or may be composed of a mixture of two or more types.

Examples of phosphazene derivatives include linear phosphazene compounds represented by the following general formula (2).

In the formula, n represents an integer of 3 or more and 1000 or less, and R ³ and R ⁴ may be the same or different, and are an alkyl group having 1 to 8 carbon atoms, or an alkyl group having 1 to 8 carbon atoms. It represents a phenyl group which may be substituted with the following alkyl group and/or allyl group, and X is a group -N=P(OR ³ ) ₃ , a group -N=P(OR ⁴ ) ₃ , a group -N= P(O)(OR ³ ) or a group -N=P(O)(OR ⁴ ), and Y represents a group -P(OR ³ ) ₄ , a group -P(OR ⁴ ) ₄ , a group -P(O )(OR ³ ) ₂ or the group -P(O)(OR ⁴ ) ₂ . The phosphazene derivative may be composed of one type of linear phosphazene compound represented by formula (2), or may be composed of a mixture of two or more types.

As a phosphazene derivative, an alkyl group is removed from R ¹ , R ² , R ³ , and R ⁴ in formula (1) or formula (2) by a crosslinking group represented by the following formula (3), and two oxygen It may also be a phosphazene compound in which atoms are crosslinked.

In the formula, r represents 0 or 1, and A represents a group -SO ₂ -, -S-, -O- or -C(CH ₃ ) ₂ -.

Specific examples of the cyclic phosphazene compound represented by formula (1) include hexaphenoxycyclotriphosphazene, octaphenoxycyclotetraphosphazene, decaffenoxycyclopentaphosphazene, hexapropoxycyclotriphosphazene, octapropoxycyclotetraphosphazene, and decapropoxycyclotriphosphazene. Examples include cyclopentaphosphazene.

Specific examples of the linear phosphazene compound represented by formula (2) include linear phosphazene compounds obtained by substituting a propoxy group and/or a phenoxy group on a linear dichlorophosphazene.

Specific examples of the crosslinked structure represented by formula (3) include 4,4'-sulfonyldiphenylene (bisphenol-S residue), 4,4'-oxydiphenylene group, 4,4'-thiodiphenylene and 4,4'-diphenylene groups.

These phosphazene derivatives may be substituted with an amino group and/or a phenylamino group at any position. These phosphazene derivatives may be used alone or in combination of two or more.

Examples of the carboxylic acid amide derivative include N-cyclohexylbenzoic acid amide.

Sulfonamide derivatives include N-methyl-benzenesulfonamide, N-ethyl-benzenesulfonamide, N-butyl-benzenesulfonamide, N-cyclohexyl-benzenesulfonamide, N-ethyl-P-toluenesulfonamide, N- Examples include butyl-toluenesulfonamide and N-cyclohexyl-toluenesulfonamide.

Examples of sulfonic acid ester derivatives include ethyl benzenesulfonate.

Examples of sulfonic acid amide derivatives include 2-methoxyethyl methanesulfonate, 2,2,2-trifluoroethyl methanesulfonate, methyl p-toluenesulfonate, ethyl p-toluenesulfonate, n-p-toluenesulfonate. - Examples include propyl.

Examples of the functional sustained release liquid having a sliding function include known sliding agents having sustained release properties. Examples of known sliding agents include mineral oil, synthetic oil, wax, paraffin, and the like.

Examples of the functional sustained release liquid having a self-healing function include known self-healing agents having sustained release properties. Known self-healing agents include polyrotaxane, self-healing clear (manufactured by Natco Shoji Co., Ltd.), and the like.

Examples of the functional sustained release liquid having a catalytic function include known catalysts having sustained release properties. Known catalysts include ionic liquids, tertiary amines (for example, "PZETA" manufactured by Tosoh Corporation, etc.), organic titanium compounds (for example, tetra-i-propoxytitanium, tetra-n-butoxytitanium, tetrakis(2- ethylhexyloxine) titanium (for example, manufactured by Nippon Soda Co., Ltd.).

Examples of the functional sustained release liquid having medical functions include known medical products having sustained release properties.

Functional sustained release liquids having antiviral functions include, for example, aromatic compounds (Amolden V-1000HP, manufactured by Daiwa Chemical Industries), cationic polymer systems (Amolden D-CL50, D-CLH, manufactured by Daiwa Chemical Industries), etc. Can be mentioned.

Examples of functional sustained release liquids having a self-cleaning function include ionic surfactants (Amino Ion AS200, AS400, manufactured by Nippon Nyukazai), nonionic surfactants (Amit 102, 105, manufactured by Kao), and fluorine-based surfactants. Examples include surfactants (Surflon S-242, S-243, S-386, manufactured by AGC Sei Chemical).

It is preferable that the solvent contains a solvent that has high compatibility with the matrix resin and has a small effect on the shape stability of the molded article. Examples of the solvent include water, methanol, ethanol, dimethyl sulfoxide, polyethylene glycol, sulfonamide derivatives, sulfonic acid ester derivatives, carboxylic acid amide derivatives, carboxylic acid ester derivatives, phosphate ester derivatives, hydrocarbon compounds, and silicone compounds. It will be done.

Examples of sulfonamide derivatives include N-methyl-benzenesulfonamide, N-ethyl-benzenesulfonamide, N-butyl-benzenesulfonamide, N-cyclohexyl-benzenesulfonamide, N-ethyl-P-toluenesulfonamide, N-butyl-toluenesulfonamide and N-cyclohexyl-toluenesulfonamide are mentioned. Examples of sulfonic acid ester derivatives include 2-methoxyethyl methanesulfonate, 2,2,2-trifluoroethyl methanesulfonate, methyl p-toluenesulfonate, ethyl p-toluenesulfonate, n-p-toluenesulfonate. - Examples include propyl.

Examples of carboxylic acid amide derivatives include N-cyclohexylbenzoic acid amide.

Examples of carboxylic acid ester derivatives include dimethyl phthalate, diethyl phthalate, di-n-octyl phthalate, diphenyl phthalate, benzyl phthalate, dimethoxyethyl phthalate, di(2-ethylhexyl) 4,5-epoxyhexahydrophthalate, 4, 5-epoxycyclohexahydrophthalate di(7,8-epoxy-2-octenyl), 4,5-epoxycyclohexahydrophthalate di(9,10-epoxyoctadecyl), 4,5-epoxycyclohexahydrophthalate Di(10,11-epoxyundecyl) acid, di(tetrahydrofurfuryloxyethyl) phthalate, various phthalic acid mixed esters, phthalic acid ester derivatives such as ethylene oxide adducts of phthalic acid mixed esters, isophthalic acid ester derivatives, tetrahydrophthalic acid. Acid ester derivatives, butoxyethyl para-hydroxybenzoate, cyclohexyloxyethoxyethoxyethyl para-hydroxybenzoate, 2-ethylhexyl para-hydroxybenzoate, hydroxybenzoic acid ester of ω-alkyl oligoethylene oxide, addition of para-hydroxybenzoic acid to undecyl glycidyl ether benzoic acid ester derivatives such as di(tetrahydrofurfuryloxyethyl) thiodipropionate, adipic acid ester derivatives, azelaic acid ester derivatives, sebacic acid ester derivatives, dodecane-2-acid ester derivatives, maleic acid ester derivatives, etc. Acid ester derivatives, fumaric acid ester derivatives, trimetic acid ester derivatives, tri(butoxyethoxyethyl) citrate, di-n-octyl-mono(nonylphenoxyethyl) citrate, tri-n-octyl citrate, dioctyl citrate (tetrahydrofurfurin) citric acid ester derivatives such as trimyristyl citrate and triethyl citrate, itaconic acid ester derivatives, oleic acid ester derivatives such as tetrahydrofurfuryl oleate, ricinoleic acid ester derivatives, lactic acid (n-butyl), lactic acid ( lactic acid ester derivatives such as lactic acid (n-butoxyethoxyethyl), lactic acid (n-octoxyethoxyethyl), lactic acid (n-decyloxyethoxyethyl), di(octoxyethoxyethyl) tartrate, tartaric acid ( n-octyl) (nonylphenoxyethyl), tartrate derivatives such as di(octoxyethoxyethyl) tartrate, dibutoxyethyl malate, di(n-butoxyethoxyethyl) malate, distearyl malate, octade malate Examples include malic acid ester derivatives such as senylisononyl, and salicylic acid ester derivatives such as a salicylic acid adduct of benzyl glycidyl ether.

Examples of phosphate ester derivatives include trimethyl phosphate, triethyl phosphate, tributyl phosphate, tri-(2-ethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, tributoxyethyl phosphate, triphenyl phosphate, cresyl diphenyl phosphate, isodecyl - Diphenyl phosphate, tricresyl phosphate, tricylenyl phosphate, tri(chloroethyl) phosphate, xylenyl diphenyl phosphate, and tetrakis(2,4-di-tert-butylphenyl)4,4'-biphenylene diphosphonate.

Examples of hydrocarbon compounds include chain saturated hydrocarbon compounds (paraffins), chain unsaturated hydrocarbon compounds (olefins), alicyclic hydrocarbon compounds (cycloalkanes, cycloalkenes, cycloalkynes, etc.), and Examples include aromatic hydrocarbon compounds. Among these hydrocarbon compounds, paraffin oil having a molecular weight of 330 to 530 and a kinematic viscosity of 10 to 120 cSt is particularly preferably used. A hydrocarbon compound having a molecular weight of 330 or more and 530 or less is preferable from the viewpoint of easily penetrating into the body of a small animal through its body pore. Further, a hydrocarbon compound having a kinematic viscosity of 10 cSt or more and 120 cSt or less is preferable from the viewpoint of easily adhering to the body surface of a small animal. Further, it is preferable to use paraffin oil because it is inexpensive and easily available. Examples of silicone compounds include dimethyl silicone, methylphenyl silicone, polyether-modified silicone, long-chain alkyl-modified silicone, and higher fatty acid ester-modified silicone.

Examples of flame retardants include non-halogen flame retardants such as trimethyl phosphate, triethyl phosphate, triphenyl phosphate, tricresyl phosphate, tricylenyl phosphate, cresyl diphenyl phosphate, cresyl di-2,6-xylenyl phosphate, and aromatic condensed phosphorus. Acid ester, aliphatic phosphoric acid amide, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, melamine cyanurate, Adekastab FP-600 (product name, manufactured by ADEKA), Adekastab PFR (product name) , manufactured by ADEKA), ADEKA STAB FP-900L (trade name, manufactured by ADEKA), halogen-based flame retardants include tris (chloropropyl) phosphate, tris (tribromoneopentyl) phosphate, halogen-containing condensed phosphate ester, tribromoneopentyl Examples include alcohol, dibromoneopentyl glycol, tribromophenol, pentabromobenzyl polyacrylate, decabromodiphenyl oxide, tetrabromobisphenol-A, and brominated epoxy.

Flavors include isothiocyanates, indoles and their derivatives, ethers, esters, ketones, fatty acids, aliphatic higher alcohols, aliphatic higher aldehydes, aliphatic higher hydrocarbons, thioethers, thiols, Examples include terpene hydrocarbons, phenol ethers, phenols, furfural and its derivatives, aromatic alcohols, aromatic aldehydes, lactones, and 4-nonanolide. These fragrances may be used alone or in combination of two or more.

When compounded with a resin, a functional sustained release liquid is gradually released onto the surface of a molded product and can maintain an excellent sustained release effect over a long period of time. It is preferable that there be. The lower limit of the molecular weight is not particularly limited, but is, for example, 30 or more.

The acid dissociation constant of the functional sustained release liquid is preferably in the range of -10 or more and 40 or less, since it is a condition that it is a liquid. The acid dissociation constant of the functional sustained-release liquid can be determined using the Henderson-Hasselbalch equation, a collection of known literature, neutralization titration, spectrophotometry, capillary electrophoresis, and the like.

In order to facilitate the compounding of the resin, the content of the functional sustained release liquid in the functional sustained release carrier is 10 parts by mass or more and 90 parts by mass or less in 100 parts by mass of the functional sustained release carrier. It is preferable that it is, and it is more preferable that it is 25 parts by mass or more and 80 parts by mass or less.

The ratio of the content of the functional sustained release liquid to the content of the porous coordination polymer is, for example, 0.10 or more and 9.00 or less, from the viewpoint of achieving the effects of the present invention more effectively and reliably. It is preferably 0.25 or more and 3.00 or less.

[Method for manufacturing functional liquid carrier]
The method for producing the functional sustained release carrier is not particularly limited, and any known method can be employed as appropriate. Examples of such manufacturing methods include, for example, Pigment Test Methods - Part 13: Oil Absorption JISK5101-13-1 (2004) Section 1: Refined Linseed Oil Method, and JISK5101-13-2 (2004) Section 2. :You may refer to the boiled linseed oil method.

In this embodiment, in the production of a functional liquid carrier, free substances derived from organic ligands that are attached to or present on the surface and/or inside the pores of a porous coordination polymer are removed. After that, it is desirable to allow the porous coordination polymer to retain the functional sustained release liquid. If free substances exist, when the porous coordination polymer and functional sustained-release liquid are combined, the free substances will narrow or completely block the pores, making the functional sustained-release liquid porous. It becomes difficult to inject into the pores of the coordination polymer. Furthermore, since the free substances are mixed into the functional sustained-release liquid as impurities, the physical properties of the functional sustained-release liquid change, making it impossible to obtain the desired effect.

The method for removing free substances is not particularly limited, and any known method can be employed as appropriate. Examples of such methods include, for example, a method of washing the porous coordination polymer with a solvent. Examples of the solvent used for cleaning include water, methanol, THF (tetrahydrofuran), and DMF (dimethylformamide). Among these solvents, water and/or methanol are preferred. When the solvent is water and/or methanol, since the molecular diameter of the solvent is small, the solvent easily enters the pores of the porous coordination polymer, and free substances in the pores can be easily removed. Alternatively, free substances may be removed by immersing the porous coordination polymer in a solvent for a long time. The immersion time is preferably 12 hours or more, more preferably 24 hours or more. After cleaning with a solvent, it is preferable to perform a heat treatment to completely remove the solvent.

As a method for removing free substances, heat treatment may be used to remove free substances. Since the free substances are derived from organic ligands and are organic substances, they can be easily removed by heat treatment in air or an oxygen atmosphere. If the free substance is a volatile substance, it can also be removed by vacuum heat treatment. The heating temperature is preferably 100°C or more and 300°C or less.

In the production of a functional liquid carrier, if impurities other than free substances are contained, it is preferable to remove them, for example, by the above-mentioned washing and heat treatment.

[Functional sustained release composition]
The functional sustained release composition of this embodiment includes a functional liquid carrier and a matrix resin. In the functional sustained release composition, the functional liquid carrier may be used alone or in combination of two or more, as long as the effects of the present invention are achieved.

The functional sustained release composition preferably has a surface concentration of the liquid component of less than 1.0 mg/cm ² when compressed at 10 MPa or more. If the surface concentration is 1.0 mg/cm ² or more, when the functional sustained release composition is processed by injection molding or the like, problems such as clogging of the material pellets may occur due to the sticky surface.

(matrix resin)
The functional sustained release composition of this embodiment includes a matrix resin. Examples of the matrix resin include thermoplastic resins and thermosetting resins. The matrix resin may be used alone or in combination of two or more.

Examples of thermoplastic resins include polyethylene resin, polypropylene resin, polyvinyl chloride resin, polyvinylidene chloride resin, polyvinyl acetate resin, polystyrene resin, AS resin, ABS resin, methacrylic resin, polyvinyl alcohol resin, EVA resin, and polyamide resin. , polyacetal resin, polycarbonate resin, polyphenylene ether resin, polyethylene terephthalate resin, polybutylene terephthalate resin, fluororesin, polyphenylene sulfide resin, polysulfone resin, polyarylate resin, polyetherimide resin, polyether sulfone resin, polyether ketone resin, Examples include liquid crystal polyester resin, thermoplastic polyimide resin, and thermoplastic polyurethane resin.

Thermosetting resins include epoxy resin, unsaturated polyester resin, phenol resin, urea resin, melamine resin, alkyd resin, silicone resin, polyimide resin, polyurethane resin, vinyl ester resin, diallyl phthalate resin, furan resin, and polyamino bismaleimide. resins, casein resins, epoxy acrylate resins, urethane acrylate resins, polyurea resins, benzoxazine resins, oxetane resins, xylene resins, dicyclopentadiene resins, and episulfide resins.

From the viewpoint of easy processing, the content of the functional liquid carrier in the functional sustained release composition should be 1% by mass or more and 95% by mass or less in 100% by mass of the functional sustained release composition. is preferred. In the functional sustained release composition, the total content of the matrix resin is preferably 5% by mass or more and 99% by mass or less in 100% by mass of the functional sustained release composition.

(Inorganic filler)
The functional sustained release composition may contain an inorganic filler from the viewpoint of improving mechanical properties.
As such an inorganic filler, a known inorganic filler is used. Examples include particulate inorganic fillers, fibrous inorganic fillers, and scale-like or plate-like inorganic fillers. The inorganic fillers may be used alone or in combination of two or more.

The particulate inorganic filler may be, for example, a particulate inorganic filler having a micron size or a particulate inorganic filler having a nano size.

Examples of the particulate inorganic filler having a micron size include calcium carbonate particles, silica particles, glass beads, titanium oxide particles, zinc oxide particles, potassium titanate particles, titania particles, monoclinic titania particles, calcium phosphate particles, Examples include wollastonite, vermiculite, shirasu balloon, glass balloon, etc.

Examples of the nano-sized particulate inorganic filler include nano titanium oxide, nano silica, carbon black, and carbon filler.

Among these, it is preferable that the particulate inorganic filler contains potassium titanate particles from the viewpoint of further excellent sustained release properties of functional sustained release liquids (particularly small animal control agents).

The fibrous inorganic filler may include a fibrous inorganic filler having an average fiber diameter of 0.05 μm or more and 10 μm or less and an average fiber length of 3 μm or more and 150 μm or less, from the viewpoint of not adversely affecting the appearance of the molded product. Preferably, it includes a fibrous inorganic filler having an average fiber diameter of 0.1 μm or more and 7 μm or less, and an average fiber length of 5 μm or more and 50 μm or less.

The fibrous inorganic filler may be, for example, a micron-sized fibrous inorganic filler or a nano-sized fibrous inorganic filler.

Examples of the fibrous inorganic filler having a micron size include glass fiber, carbon fiber, graphite fiber, aramid fiber, vinylon fiber, polyamide fiber, polyester fiber, cotton, hemp fiber, kenaf fiber, bamboo fiber, rayon, and steel fiber. , aluminum fiber, gypsum fiber, potassium tetratitanate fiber, potassium hexatitanate fiber, potassium octitanate fiber, titania fiber, monoclinic titania fiber, silica fiber, wollastonite, xonotrite, and the like.

Examples of the nano-sized fibrous inorganic filler include carbon fibers, carbon nanotubes, fullerenes, cotton fibrils, silicon nitride whiskers, alumina whiskers, silicon carbide whiskers, and nickel whiskers.

These fibrous inorganic fillers may be used alone or in combination of two or more.

The scale-like or plate-like inorganic filler may be, for example, a scale-like or plate-like inorganic filler having a micron size, or a scale-like or plate-like inorganic filler having a nano size.

Examples of scale-like or plate-like inorganic fillers having a micron size include talc, kaolin clay, mica (synthetic mica or natural mica), glass flakes, aragonite, calcium sulfate, aluminum hydroxide, potassium titanate, potassium titanate. Examples include lithium, potassium magnesium titanate, sericite, plate-like alumina, and boron nitride.

Examples of the nano-sized scale-like or plate-like inorganic filler include organic montmorillonite, swellable synthetic mica, graphite, and graphite.

The scale-like inorganic fillers may be used alone or in combination of two or more.

The inorganic filler may be used as it is, or from the viewpoint of improving the interfacial adhesion with the resin and further improving the mechanical properties, a silane coupling agent such as aminosilane, epoxysilane, acrylic silane or a titanate cup may be used as the inorganic filler. It may also be used in the form of a surface treatment with a surface treatment agent such as a ring agent.

When the functional sustained release composition contains an inorganic filler, the content of the inorganic filler is usually 0.01% by mass or more and 70% by mass or less in 100% by mass of the functional sustained release composition.

(Weather resistance imparting additive)
The functional sustained release composition may contain a weather resistance imparting additive from the viewpoint of further improving weather resistance when left outdoors.
Examples of such weather resistance imparting additives include hindered phenolic antioxidants, phosphorus antioxidants, ultraviolet absorbing light stabilizers, hindered amine light stabilizers, and carbon. The weather resistance imparting additives may be used alone or in combination of two or more.

Examples of hindered phenolic antioxidants include pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], N,N'-hexane-1,6-diylbis[ 3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)], bis-[3,3-bis-(4'-hydroxy-3'-tert-butylphenyl)-butanoic acid ]-glycol ester, tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, thiodiethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], Octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 3,3',3'',5,5',5''-hexa-tert-butyl-a,a' , a''-(methylene-2,4,6-triyl)tri-p-cresol, hexamethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], tetrakis[methylene -3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]methane, and methylene-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate.

Examples of phosphorus antioxidants include tris(2,4-di-tert-butylphenyl)phosphite, tris[2-[[2,4,8,10-tetra-tert-butylbenzo[d,f] [1,3,2]dioxaphosphefin-6-yl]oxy]ethyl]amine, tetrakis(2,4-di-tert-butylphenyl)[1,1-biphenyl]-4,4'-diyl Bisphosphonite, distearyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol phosphite, bis(2,6-di-tert-butyl-4-phenyl) pentaerythritol phosphite and bis(2,4-di-tert-butylphenyl)pentaerythol diphosphite.

Examples of the ultraviolet absorber include 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, 2-(2H-benzotriazol-2-yl) -4,6-di-tert-pentylphenol, propanedioc acid, and [(4-methoxyphenyl)-methylene]-dimethyl ester.

Examples of hindered amine light stabilizers include N,N',N'',N'''-tetrakis-(4,6-bis-(butyl-(N-methyl-2,2,6,6-tetramethyl) piperidin-4-yl)amino)-triazin-2-yl)-4,7-diazadecane-1,10-diamine, poly[(6-(1,1,3,3-tetramethylbutyl)amino-1, 3,5-triazine-2,4-diyl)(2,2,6,6-tetramethyl-4-piperidyl)imino]hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino )), bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, 2,2,4,4-tetramethyl-7-oxa-3,20-diaza-dispiro-[5.1. 11.2]-heneicosan-21-one, propanedioic acid, [(4-methoxyphenyl)-methylene]-, bis(1,2,2,6,6-pentamethyl-4-piperidinyl) ester, 1,3 -benzenedicarboxamide, N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl), and 2-ethyl,2'-ethoxy-oxalanilide.

Among these, weatherability imparting additives include pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], N,N'-hexane-1,6-diylbis[3 -(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)], tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, tris(2,4-di-tert-butyl-4-hydroxybenzyl) -butylphenyl) phosphite, tetrakis(2,4-di-tert-butylphenyl)[1,1-biphenyl]-4,4'-diylbisphosphonite, bis(2,4-di-tert-butyl) phenyl)pentaerythritol phosphite, 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, 2-ethyl,2'-ethoxy-oxalanilide, N, N',N'',N'''-tetrakis-(4,6-bis-(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)-triazine-2 -yl)-4,7-diazadecane-1,10-diamine, poly[(6-(1,1,3,3-tetramethylbutyl)amino-1,3,5-triazine-2,4-diyl) (2,2,6,6-tetramethyl-4-piperidyl)imino]hexamethylene ((2,2,6,6-tetramethyl-4-piperidyl)imino)), 1,3-benzenedicarboxamide, and N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl) are preferred.

When the functional sustained release composition contains a weather resistance imparting additive, the content of the weather resistance imparting additive is usually 0.01 mass% or more and 20 mass% or less in 100 mass% of the functional sustained release composition. It is.

[Method for producing functional sustained release composition]
The method for producing the functional sustained release composition is not particularly limited, and any known method can be employed as appropriate. Such manufacturing methods include, for example, batch kneading using rolls, banburys, kneaders, etc., screw kneading using single screw extruders, twin screw extruders, multi-screw extruders, etc., single screw kneading machines, multi-screw kneading machines, etc. There are methods using a rotor type kneading machine such as a shaft kneading machine, and a stone mill type kneading machine such as a KCK kneading extruder.

[Molded body]
The molded article of this embodiment contains a functional sustained release composition.
The functional sustained release composition can be used as it is, for example, as a paint, a sealant, a cushioning material, or a filler, or it can be processed into a molded product having a predetermined shape and used.

The molded body can be made into a molded body having fluidity, semi-fluidity, or rubber-like elasticity by, for example, selecting an appropriate functional liquid carrier and matrix resin and adjusting them appropriately in the functional sustained release composition. can be manufactured.

Examples of fluid molded bodies include paints.

An example of a semi-fluid molded product is a sealant.

Examples of molded bodies having rubber-like elasticity include cushioning materials and stuffing.

When the functional sustained-release composition is used as a paint, a sealant, a cushioning material, or a filling material, a colorant such as a colorant or a pigment can be added to the matrix resin, if necessary.

For example, injection molding, compression molding, transfer molding, extrusion molding, blow molding, calendar molding, FRP molding, lamination molding, cast molding, solution casting, vacuum/pressure molding, etc. Appropriate known molding methods such as molding, extrusion composite molding, foam molding, thermoforming, insert molding, melt impregnation, and melt spinning can be applied.
Further, the shape of the molded product is not particularly limited, and can be any shape such as a flat plate, a rod, a cylinder, a comb, and a sphere. In addition to molding the functional sustained release composition alone, it can also be molded into two-color or multi-color molds in combination with metals or the like.

Hereinafter, the present invention will be explained in more detail using Examples and Comparative Examples, but the present invention is not limited by these Examples. Furthermore, "parts" and "%" are based on mass unless otherwise specified.

[Amount of free organic ligand]
The amounts of free fumaric acid, free terephthalic acid, free 1,3,5-benzenetricarboxylic acid, and free 2-methylimidazole in the porous coordination polymer were measured by the following method.
That is, 1 g of each of the porous coordination polymers obtained in the synthesis examples and 20 ml of the solvent were added to a 100 ml Erlenmeyer flask. Next, extraction was performed for 30 minutes at 50° C. and 120 rpm using a constant temperature shaker (manufactured by Tokyo Rikakikai Co., Ltd.). The obtained extract was filtered through a 0.2 μm filter, and measured using a high performance liquid chromatograph (manufactured by GL Science, SH-Stabilwax 30 m x 0.25 mm ID x 0.25 μm). From the measurement results, the amount of free organic ligand was calculated as the amount (mass %) relative to 100 mass % of the porous coordination polymer.

[Specific surface area]
The specific surface area (m ² /g) of the porous coordination polymer was measured by the following method. That is, for each of the porous coordination polymers obtained in Examples and Comparative Examples, using a specific surface area/pore size distribution measuring device (BELSORP-max II (trade name) manufactured by Microtrac Bell Co., Ltd.), Nitrogen adsorption and desorption was performed. The adsorption temperature was liquid nitrogen temperature (-196°C, 77K). The pretreatment was performed under the conditions of vacuum, 200° C., and 5 hours. The measurement range was 5×10 ⁻⁵ P/P ₀ or more and 0.995 P/P ₀ or less (relative pressure).

[Average pore diameter]
The average pore diameter (nm) of the porous coordination polymer was measured by the following method. That is, for each of the porous coordination polymers obtained in Examples and Comparative Examples, using a specific surface area/pore size distribution measuring device (BELSORP-max II (trade name) manufactured by Microtrac Bell Co., Ltd.), Nitrogen adsorption and desorption was performed. The adsorption temperature was liquid nitrogen temperature (-196°C, 77K). The pretreatment was performed under the conditions of vacuum, 200° C., and 5 hours. The measurement range was 5×10 ⁻⁵ P/P ₀ or more and 0.995 P/P ₀ or less (relative pressure). The MP method was used for the analysis.

[Gas adsorption amount]
The amount of gas adsorption was determined from the amount of nitrogen adsorbed _at 0.99P/P from the isothermal adsorption curve. Specifically, for each of the porous coordination polymers obtained in Examples and Comparative Examples, a specific surface area/pore size distribution measuring device (BELSORP-max II (trade name) manufactured by Microtrac Bell Co., Ltd.) was used. The gas adsorption amount (cm ³ /g-STP (standard state)) of the porous coordination polymer was measured by adsorbing and desorbing nitrogen using the method. The adsorption temperature was set to liquid nitrogen temperature (-196°C, 77K). The pretreatment was performed under the conditions of vacuum, 200° C., and 5 hours. The measurement range was 5×10 ⁻⁵ P/P ₀ or more and 0.995 P/P ₀ or less (relative pressure).

[Adsorption amount of functional sustained release liquid in functional liquid carrier]
The amount of adsorption (mass%) of etofenprox, 2-n-octyl-4-isothiazolin-3-one, 4-nonanoid, and trimellitic acid ester in the functional liquid carrier was measured by the following method. did.
That is, 1 g of the porous coordination polymer obtained in Synthesis Examples 1 to 30 was weighed into a glass petri dish, and one drop of the functional sustained release liquid was added to the porous coordination polymer. A functional liquid-carrying material was prepared by kneading and dropping the functional sustained-release liquid with a glass rod so that it was absorbed. At this time, it was visually confirmed that the functional liquid carrier could no longer maintain a lumpy state and became slurry-like, and the amount of dripping at that time was defined as the adsorption amount of the functional sustained-release liquid. From the measurement results, the adsorption amount of the functional sustained release liquid in the functional liquid carrier was calculated as the amount (mass %) relative to 100 mass % of the porous coordination polymer.

[Measurement of surface amount of functional sustained release liquid in molded body]
The amounts of etofenprox, 2-n-octyl-4-isothiazolin-3-one, 4-nonanoid, and trimellitic acid ester in the molded body were measured by the following method. That is, for each of the molded bodies produced in Examples and Comparative Examples, the following method was used to determine the concentration of etofenprox, 2-n-octyl-4-isothiazolin-3-one, 4-nonanoid, and trimellitic acid ester. The surface amount (functional sustained release liquid surface concentration) in the molded body was measured.
First, each molded body was immersed in 50 mL of tetrahydrofuran in an environment of 20° C. to wash away the functional sustained release liquid deposited on the surface. Next, using a high performance liquid chromatograph (manufactured by LUNA, column: Luna (registered trademark) 3 μm C18 (2) 100 Å, LC Column 150 x 4.6 mm, Ea), the amount per unit area of the molded body in the washed solution was determined. The surface amount (surface concentration) (μg/cm ² ) of the functional sustained release liquid was measured.

[Synthesis Examples 1 to 5] Synthesis of porous coordination polymers A1 to A5 Aluminum sulfate/18 hydrated water (Al ₂ (SO ₄ ) _{3.18H 2} O), fumaric acid, and sodium hydroxide were combined into 1 :3:6 (mass ratio) into a Henschel mixer and blended. Thereafter, the blend was put into a twin-screw extruder (HAAKE Process 11 (trade name), Thermo Fisher Scientific Co., Ltd.), the temperature of the cylinder and die was set to 150°C, and the extrusion rate was set to 0.6 kg/hour. A powder sample was obtained by extrusion while kneading. 1 g of the powder sample and 10 mL of pure water were added to a 100 mL Erlenmeyer flask, and the mixture was washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (manufactured by AS ONE). By vacuum drying the washed powder sample at 200° C., a porous coordination polymer A1 having aluminum ions as metal ions and fumaric acid as an organic ligand was obtained.
Porous coordination polymers A2 to A5 were obtained by synthesis using the same method as the synthesis method for porous coordination polymer A1 described above.

[Synthesis Examples 6 to 10] Synthesis of porous coordination polymers B1 to B5 In a Teflon (registered trademark) container, 1 mmol of chromium nitrate _{/ 9H 2} O and nitric acid were added. 1 mmol of terephthalic acid, 1 mmol of terephthalic acid, and 5 mL of ultrapure water were added and dissolved.Then, the resulting solution was heated at 220°C for 8 hours and cooled to room temperature (25°C) over 6 hours. Thereafter, a product (filtrate) was obtained by filtering the solution. 1 g of the product (filtrate) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask, and the mixture was stirred using a magnetic stirrer (AS ONE). The product was washed by stirring at 120 rpm for 20 hours.The washed product was vacuum dried at 200°C to remove chromium ions as metal ions and terephthalic acid as an organic ligand. A porous coordination polymer B1 having the following properties was obtained.
The porous coordination polymers B2 to B5 were synthesized in the same manner as the synthesis method of the porous coordination polymer B1 described above, respectively.

[Synthesis Examples 11 to 15] Synthesis of porous coordination polymers C1 to C5 In a Teflon container, 0.2 mmol of zirconium chloride (ZrCl ₄ ), 0.4 mmol of terephthalic acid, 0.2 mmol of hydrochloric acid, and N , N-dimethylformaldehyde (DMF) (25 mL) were added thereto, and the mixture was stirred and mixed at 120° C. for 24 hours. Thereafter, the mixture was filtered to obtain a product (filtrate). 1 g of the product (filtrate) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask, and the flask was washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (manufactured by AS ONE). The washed product was vacuum dried at 200° C. to obtain a porous coordination polymer C1 having zirconium ions as metal ions and terephthalic acid as an organic ligand.
Porous coordination polymers C2 to C5 were synthesized in the same manner as the above-mentioned synthesis method of porous coordination polymer C1, respectively.

[Synthesis Examples 16 to 20] Synthesis of porous coordination polymers D1 to D5 In a 100 ml round bottom flask, iron nitrate/9-hydrate water ([Fe(H ₂ O) ₆ ] (NO ₃ ) _{3.3H 2} O), 1,3,5-benzenetricarboxylic acid, hydrogen fluoride, nitric acid, and ultrapure water at a ratio (mass ratio) of 1:1:2:0.5:100, The mixture was refluxed at 95°C for 12 hours. Thereafter, it was left to stand at room temperature. Thereafter, the solution was filtered to obtain a product (filtrate). 1 g of the product (filtrate) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask, and the mixture was washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (manufactured by AS ONE). By vacuum drying the product after washing at 200°C, a porous coordination polymer D1 having iron ions as metal ions and 1,3,5-benzenetricarboxylic acid as an organic ligand is obtained. I got it.
Porous coordination polymers D2 to D5 were obtained by synthesizing in the same manner as the above-mentioned synthesis method of porous coordination polymer D1.

[Synthesis Examples 21 to 25] Synthesis of porous coordination polymers E1 to E5 In a 200 ml Erlenmeyer flask, add copper nitrate (Cu(NO ₃ ) ₂ ), 1,3,5-benzenetricarboxylic acid, and ultrapure water. were added at a ratio (mass ratio) of 1:2:2222, and the mixture was stirred and mixed at room temperature for 1 hour. Thereafter, it was left at room temperature for 23 hours. Thereafter, the solution was filtered to obtain a product (filtrate). 1 g of the product (filtrate) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask, and the mixture was washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (manufactured by AS ONE). By vacuum drying the product after washing at 200 ° C., a porous coordination polymer E1 having copper ions as metal ions and 1,3,5-benzenetricarboxylic acid as an organic ligand was obtained. Ta.
The porous coordination polymers E2 to E5 were synthesized in the same manner as the synthesis method of the porous coordination polymer E1 described above, respectively.

[Synthesis Examples 26 to 30] Synthesis of porous coordination polymers F1 to F5 In a 200 ml Erlenmeyer flask, add zinc nitrate (Zn(NO ₃ ) ₂ ), 2-methylimidazole, triethylamine, and ultrapure water. The mixture was added at a ratio (mass ratio) of 1:6:2.5:500 and mixed for 30 minutes at room temperature. A product (filtrate) was obtained by filtering the solution. 1 g of the product (filtrate) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask, and the flask was washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (manufactured by AS ONE). The washed product was vacuum dried at 200° C. to obtain a porous coordination polymer F1 having zinc ions as metal ions and 2-methylimidazole as an organic ligand.
The porous coordination polymers F2 to F5 were synthesized in the same manner as the synthesis method of the porous coordination polymer F1 described above, respectively.

[Example 1-A1]
When the amount of free fumaric acid was measured using the above method with respect to the porous coordination polymer A1 (W), it was found that it was 0.4% by mass with respect to 100% by mass of the porous coordination polymer A1 (W). there were. Further, the specific surface area of the porous coordination polymer A1 (W) by the BET method was 904 m ² /g, the average pore diameter was 0.6 nm, and the amount of gas adsorption was 451 cm ³ /g.
Next, etofenprox (melting point 37°C, boiling point 200°C, molecular weight 376.49, molecular diameter (longer axis) 1.748 nm, molecular diameter (shorter axis)) was added to the porous coordination polymer A1 (W) as a functional sustained release liquid. (diameter) 0.5 nm, Mitsui Chemicals Agro Co., Ltd.) was adsorbed, and etofenprox was adsorbed to obtain a functional liquid carrier 1-A1. In addition, as for the adsorption method, porous coordination polymer A1 is placed in a vacuum bell jar, and etofenprox is dropped onto the porous coordination polymer A1 under reduced pressure of 0.01 MPa or less. We used a method of adsorbing . When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-A1 was 100% by mass of the porous coordination polymer A1 (W). , 300% by mass.
Next, the functional liquid carrier 1-A1 was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). In addition, the mixing was carried out so that the functional liquid carrier 1-A1 was 6.7% by mass and the matrix resin (polyethylene resin) was 93.3% by mass based on 100% by mass of the functional sustained release composition. did. Further, as a method for compounding, a method was used in which a Labo Plastomill device (manufactured by Toyo Seiki Seisakusho) was used and compounding was performed at a processing temperature of 120° C. for 10 minutes. Next, using a heating press machine (IMC180C model (trade name), Imoto Seisakusho Co., Ltd.), 10 tons of the functional sustained-release composition was pressed at 120°C to form a 50 mm x 50 mm, 1.0 mm thick sheet. A plate-shaped molded body was produced. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Example 1-A2]
When the amount of free fumaric acid was measured with respect to the porous coordination polymer A2 (W) by the above method, it was found that it was 0.7% by mass with respect to 100% by mass of the porous coordination polymer A2 (W). there were. Further, the specific surface area of the porous coordination polymer A2 (W) by the BET method was 903 m ² /g, the average pore diameter was 0.6 nm, and the amount of gas adsorption was 452 cm ³ /g.
Next, in the same manner as in Example 1-A1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer A2 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-A2 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-A2 was 100% by mass of the porous coordination polymer A2 (W). , 250% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A2 is 7.0% by mass and the matrix resin (polyethylene resin) is 93.0% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Comparative example 1-A3]
When the amount of free fumaric acid was measured with respect to the porous coordination polymer A3 (W) by the above method, it was found that it was 0.9% by mass with respect to 100% by mass of the porous coordination polymer A3 (W). there were. Further, the specific surface area of the porous coordination polymer A3 (W) by the BET method was 907 m ² /g, the average pore diameter was 0.6 nm, and the amount of gas adsorption was 449 cm ³ /g.
Next, in the same manner as in Example 1-A1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer A3 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-A3 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-A3 was 100% by mass of the porous coordination polymer A3 (W). , 200% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A3 is 7.5% by mass and the matrix resin (polyethylene resin) is 92.5% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 23 μg/cm ² .

[Comparative example 1-A4]
When the amount of free fumaric acid was measured using the above method with respect to the porous coordination polymer A4 (W), it was found that it was 1.1% by mass based on 100% by mass of the porous coordination polymer A4 (W). there were. Further, the specific surface area of the porous coordination polymer A4 (W) by the BET method was 908 m ² /g, the average pore diameter was 0.6 nm, and the amount of gas adsorption was 453 cm ³ /g.
Next, in the same manner as in Example 1-A1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer A4 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-A4 was obtained. When the amount of etofenprox adsorbed was measured by the above measurement method, the amount of etofenprox adsorbed in the functional liquid carrier 1-A4 was 100% by mass of the porous coordination polymer A4 (W). , 180% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A4 is 7.8% by mass and the matrix resin (polyethylene resin) is 92.2% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 28 μg/cm ² .

[Comparative example 1-A5]
When the amount of free fumaric acid was measured using the above method with respect to the porous coordination polymer A5 (W), it was found that it was 1.2% by mass based on 100% by mass of the porous coordination polymer A5 (W). there were. Further, the specific surface area of the porous coordination polymer A5 (W) by the BET method was 904 m ² /g, the average pore diameter was 0.6 nm, and the amount of gas adsorption was 454 cm ³ /g.
Next, in the same manner as in Example 1-A1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer A5 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-A5 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-A5 was 100% by mass of the porous coordination polymer A5 (W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A5 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 31 μg/cm ² .

[Comparative example 1-6]
Etofenprox as a functional sustained release liquid was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). Next, a plate-shaped molded body was produced in the same manner as in Example 1A-1. The mixture was such that the functional sustained release liquid was 5.0% by mass and the matrix resin (polyethylene resin) was 95.0% by mass. The surface amount of the functional sustained release liquid of the produced plate-shaped molded product was measured and found to be 21 μg/cm ² .

Table 1 shows the adsorption amount of etofenprox in the functional liquid carriers 1-A1 to 1-A5 and the amount of etofenprox on the surface of the plate-shaped molded body. In Table 1, the amount of adsorption of etofenprox in functional liquid carrier 1-A1 is assumed to be 100, and the amount of relative change is also shown assuming that the amount of adsorption of etofenprox in functional liquid carrier 1-A5 is 0. show. In addition, the relative change in the functional liquid carriers 1-A2 to 1-A4 is from the adsorption amount of etofenprox in functional liquid carrier 1-A5 to 0 in the functional liquid carrier 1-A1. It is shown as a relative amount when the adsorption amount is set to 100. For example, the relative change amount in the functional liquid carrier 1-A2 is calculated as 62 (≈(250-170)/(300-170)×100). In Table 1, EP represents etofenprox.

[Example 2-A1]
For the porous coordination polymer A1 (W) in Example 1-A1, 2-n-octyl-4-isothiazolin-3-one (molecular weight 213, A functional liquid carrier 2-A1 on which Tokyo Chemical Industry Co., Ltd. was adsorbed was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-A1. The amount was 210% by weight based on 100% by weight of the porous coordination polymer A1(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A1 is 3.0% by mass and the matrix resin (polyethylene resin) is 97.0% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 2-A2]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer A2 (W) in Example 1-A2 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-A2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-A2. The amount was 160% by weight based on 100% by weight of the porous coordination polymer A2(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A2 is 3.3% by mass and the matrix resin (polyethylene resin) is 96.7% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 11 μg/cm ² .

[Comparative example 2-A3]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer A3 (W) in Example 1-A3 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-A3 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-A3. The amount was 140% by weight based on 100% by weight of the porous coordination polymer A3(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A3 is 3.4% by mass and the matrix resin (polyethylene resin) is 96.6% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Comparative example 2-A4]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer A4 (W) in Example 1-A4 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-A4 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-A4. The amount was 110% by weight based on 100% by weight of the porous coordination polymer A4(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A4 is 3.8% by mass and the matrix resin (polyethylene resin) is 96.2% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 17 μg/cm ² .

[Comparative example 2-A5]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer A5 (W) in Example 1-A5 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-A5 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-A5. The amount was 107% by weight based on 100% by weight of the porous coordination polymer A5(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 1-A5 is 3.9% by mass and the matrix resin (polyethylene resin) is 96.1% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 18 μg/cm ² .

[Comparative example 2-6]
A functional sustained release composition is obtained by compounding and mixing 2-n-octyl-4-isothiazolin-3-one as a functional sustained release liquid with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin. A product (molded body material) was produced. Next, a plate-shaped molded body was produced in the same manner as in Example 2A-1. The mixture was such that the functional sustained release liquid was 2.0% by mass and the matrix resin (polyethylene resin) was 98.0% by mass. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 12 μg/cm ² .

Adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-A1 to 2-A5 and the surface of 2-n-octyl-4-isothiazolin-3-one on the plate-shaped molded body The amounts are shown in Table 2. In addition, in Table 2, the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-A1 is assumed to be 100, and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-A5 is assumed to be 100. The relative change amount with the amount of 4-isothiazolin-3-one adsorbed as 0 is also shown. In addition, the relative change amount in functional liquid carriers 2-A2 to 2-A4 is from 0 adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A5 to functional liquid carrier 2-A5. It is shown as a relative amount when the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in support material 2-A1 is taken as 100. In Table 2, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[Example 3-A1]
For porous coordination polymer A1 (W) in Example 1-A1, 4-nonanolide (molecular weight 156, Fuji Film Wako Pure Chemical Industries, Ltd.) was used instead of etofenprox as a functional sustained release liquid. A functional liquid carrier 3-A1 on which 4-nonanolide was adsorbed was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A1 was 100% by mass of the porous coordination polymer A1 (W). , 220% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixture was such that 7.3% by mass of the functional sustained-release liquid carrier 3-A1 and 92.7% by mass of the matrix resin (polyethylene resin) were based on 100% by mass of the functional sustained-release composition. It was blended into. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 5 μg/cm ² .

[Example 3-A2]
Functional liquid carrier 3-A2 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to porous coordination polymer A2 (W) in Example 1-A2. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid support 3-A2 was 100% by mass of the porous coordination polymer A2 (W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 3-A2 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 6 μg/cm ² .

[Comparative Example 3-A3]
Functional liquid carrier 3-A3 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid for porous coordination polymer A3 (W) in Example 1-A3. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A3 was 100% by mass of the porous coordination polymer A3 (W). , 140% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 3-A3 is 8.6% by mass and the matrix resin (polyethylene resin) is 91.4% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Comparative example 3-A4]
Functional liquid carrier 3-A4 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid to porous coordination polymer A4 (W) in Example 1-A4. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, it was found that the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A4 was 100% by mass of the porous coordination polymer A4 (W). , 120% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 4-A4 is 9.2% by mass and the matrix resin (polyethylene resin) is 90.8% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Comparative Example 3-A5]
Functional liquid support 3-A5 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for porous coordination polymer A5 (W) in Example 1-A5. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A5 was 100% by mass of the porous coordination polymer A5 (W). , 90% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing was carried out so that the functional liquid carrier 3-A5 was 10.6% by mass and the matrix resin (polyethylene resin) was 89.4% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Comparative example 3-6]
A functional sustained release composition (molded body material) was prepared by compounding and mixing 4-nonanolide as a functional sustained release liquid with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin. Next, a plate-shaped molded body was produced in the same manner as in Example 3A-1. The mixture was such that the functional sustained release liquid was 5.0% by mass and the matrix resin (polyethylene resin) was 95.0% by mass. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

Table 3 shows the adsorption amount of 4-nonanolide in the functional liquid carriers 3-A1 to 3-A5 and the surface amount of 4-nonanolide in the plate-shaped molded body. In addition, in Table 3, the relative change amount is also shown when the adsorption amount of 4-nonanolide in functional liquid carrier 3-A1 is 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-A5 is 0. show. In addition, the relative change in the functional liquid carriers 3-A2 to 3-A4 is from the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A5 to 4-nonanolide in the functional liquid carrier 3-A1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 4-A1]
In place of etofenprox, trimellitic acid ester (molecular weight 547, Tokyo Chemical Industry Co., Ltd.) was adsorbed to the porous coordination polymer A1 (W) in Example 1-A1 as a functional sustained release liquid. A functional liquid-supported material 4-A1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A1 was 100% by mass of the porous coordination polymer A1 (W). On the other hand, it was 290% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 4-A1 is 6.7% by mass and the matrix resin (polyethylene resin) is 92.3% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 11 μg/cm ² .

[Example 4-A2]
For the porous coordination polymer A2 (W) in Example 1-A2, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-A2 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A2 was 100% by mass of the porous coordination polymer A2 (W). On the other hand, it was 250% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 4-A2 is 7.0% by mass and the matrix resin (polyethylene resin) is 93.0% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 15 μg/cm ² .

[Comparative example 4-A3]
For the porous coordination polymer A3 (W) in Example 1-A3, functional liquid support 4-A3 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A3 was 100% by mass of the porous coordination polymer A3 (W). On the other hand, it was 210% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 4-A3 is 7.4% by mass and the matrix resin (polyethylene resin) is 92.6% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 21 μg/cm ² .

[Comparative example 4-A4]
For the porous coordination polymer A4 (W) in Example 1-A4, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-A4 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A4 was 100% by mass of the porous coordination polymer A4 (W). On the other hand, it was 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 4-A4 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 36 μg/cm ² .

[Comparative example 4-A5]
For the porous coordination polymer A5 (W) in Example 1-A5, functional liquid support 4-A5 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A5 was 100% by mass of the porous coordination polymer A5 (W). On the other hand, it was 140% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. In addition, the mixing is such that the functional liquid carrier 4-A5 is 8.6% by mass and the matrix resin (polyethylene resin) is 91.4% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 47 μg/cm ² .

[Comparative example 4-6]
A functional sustained release composition (molded body material) was prepared by compounding and mixing trimellitic acid ester as a functional sustained release liquid with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin. . Next, a plate-shaped molded body was produced in the same manner as in Example 4A-1. The mixture was such that the functional sustained release liquid was 5% by mass and the matrix resin (polyethylene resin) was 95% by mass. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 18 μg/cm ² .

Table 4 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-A1 to 4-A5 and the surface amount in the plate-shaped molded body. In addition, in Table 4, the relative change amount is also given when the adsorption amount of trimellitic acid ester in functional liquid carrier 4-A1 is 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-A5 is 0. Also shown. In addition, the relative change in the functional liquid carriers 4-A2 to 4-A4 is from 0 adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A5 to trimellitic acid ester adsorption amount in the functional liquid carrier 4-A1. It is shown as a relative amount when the adsorption amount of ester up to 100 is set as 100. In Table 4, TOTM indicates trimellitic acid ester.

[Example 1-B1]
When the amount of free terephthalic acid was measured using the above method with respect to the porous coordination polymer B1 (W), it was found that it was 0.1% by mass with respect to 100% by mass of the porous coordination polymer B1 (W). there were. Further, the specific surface area of the porous coordination polymer B1 (W) by the BET method was 2210 m ² /g, the average pore diameter was 2.5 nm, and the amount of gas adsorption was 1001 cm ³ /g.
Next, a functional liquid-supported material 1-B1 was obtained in which etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer B1 (W). Note that the same adsorption method as in Example 1-A1 was used. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in the functional liquid carrier 1-B1 was 100% by mass of the porous coordination polymer B1 (W). , 320% by mass.
Next, the functional liquid carrier 1-B1 was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). In addition, the mixing is such that the functional liquid carrier 1-B1 is 6.6% by mass and the matrix resin (polyethylene resin) is 93.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 1-B2]
When the amount of free terephthalic acid was measured using the above method with respect to porous coordination polymer B2 (W), it was found that it was 0.3% by mass with respect to 100% by mass of porous coordination polymer B2 (W). there were. Further, the specific surface area of the porous coordination polymer B2 (W) by the BET method was 2220 m ² /g, the average pore diameter was 2.5 nm, and the gas adsorption amount was 1010 cm ³ /g, STP.
Next, in the same manner as in Example 1-B1, etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer B2 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-B2 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-B2 was 100% by mass of the porous coordination polymer B2 (W). , 260% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 1-B2 is 6.9% by mass and the matrix resin (polyethylene resin) is 93.1% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 15 μg/cm ² .

[Example 1-B3]
When the amount of free terephthalic acid was measured using the above method with respect to porous coordination polymer B3 (W), it was found to be 0.6% by mass with respect to 100% by mass of porous coordination polymer B3 (W). there were. Further, the specific surface area of the porous coordination polymer B3 (W) by the BET method was 2214 m ² /g, the average pore diameter was 2.5 nm, and the amount of gas adsorption was 990 cm ³ /g.
Next, in the same manner as in Example 1-B1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer B3 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-B3 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-B3 was 100% by mass of the porous coordination polymer B3 (W). , 240% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 1-B3 is 7.1% by mass and the matrix resin (polyethylene resin) is 92.9% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 18 μg/cm ² .

[Comparative example 1-B4]
When the amount of free terephthalic acid was measured using the above method with respect to porous coordination polymer B4 (W), it was found that it was 0.8% by mass with respect to 100% by mass of porous coordination polymer B4 (W). there were. Further, the specific surface area of the porous coordination polymer B4 (W) by the BET method was 2221 m ² /g, the average pore diameter was 2.5 nm, and the amount of gas adsorption was 995 cm ³ /g.
Next, in the same manner as in Example 1-B1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer B4 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-B4 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-B4 was 100% by mass of the porous coordination polymer B4 (W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 1-B4 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 24 μg/cm ² .

[Comparative Example 1-B5]
When the amount of free terephthalic acid was measured using the above method with respect to porous coordination polymer B5 (W), it was found that it was 0.9% by mass with respect to 100% by mass of porous coordination polymer B5 (W). there were. Further, the specific surface area of the porous coordination polymer B5 (W) by the BET method was 2224 m ² /g, the average pore diameter was 2.5 nm, and the amount of gas adsorption was 1003 cm ³ /g.
Next, in the same manner as in Example 1-B1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer B5 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-B5 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in functional liquid carrier 1-B5 was 100% by mass of porous coordination polymer B5 (W). , 130% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing was carried out so that the functional liquid carrier 1-B5 was 8.8% by mass and the matrix resin (polyethylene resin) was 91.2% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 33 μg/cm ² .

Table 5 shows the adsorption amount of etofenprox in the functional liquid carriers 1-B1 to 1-B5 and the surface amount of etofenprox in the sheet-like molded product. In addition, Table 5 also shows the relative change amount when the adsorption amount of etofenprox in functional liquid carrier 1-B1 is 100 and the adsorption amount of etofenprox in functional liquid carrier 1-B5 is 0. show. In addition, the relative change in the functional liquid carriers 1-B2 to 1-B4 is from the adsorption amount of etofenprox in the functional liquid carrier 1-B5 to 0 in the functional liquid carrier 1-B1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 2-B1]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer B1 (W) in Example 1-B1 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-B1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-B1. The amount was 280% by weight based on 100% by weight of the porous coordination polymer B1(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 2-B1 is 2.7% by mass and the matrix resin (polyethylene resin) is 97.3% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Example 2-B2]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer B2 (W) in Example 1-B2 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-B2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-B2. The amount was 240% by weight based on 100% by weight of the porous coordination polymer B2(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 2-B2 is 2.8% by mass and the matrix resin (polyethylene resin) is 97.2% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Example 2-B3]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer B3 (W) in Example 1-B3 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-B3 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-B3. The amount was 210% by weight based on 100% by weight of the porous coordination polymer B3(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 2-B3 is 3.0% by mass and the matrix resin (polyethylene resin) is 97.0% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Comparative example 2-B4]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer B4 (W) in Example 1-B4 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-B4 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-B4. The amount was 150% by weight based on 100% by weight of the porous coordination polymer B4(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 2-B4 is 3.3% by mass and the matrix resin (polyethylene resin) is 96.7% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 13 μg/cm ² .

[Comparative Example 2-B5]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer B5 (W) in Example 1-B5 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-B5 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-B5. The amount was 120% by weight based on 100% by weight of the porous coordination polymer B5(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing was carried out so that the functional liquid carrier 2-B5 was 3.7% by mass and the matrix resin (polyethylene resin) was 96.3% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 16 μg/cm ² .

Table 6 shows the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carriers 2-B1 to 2-B5 and the OIT surface amount of the plate-shaped molded body. In addition, in Table 6, the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B1 is assumed to be 100, and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B5 is assumed to be 100. The relative change amount with the amount of 4-isothiazolin-3-one adsorbed as 0 is also shown. In addition, the relative change amount in functional liquid carriers 2-B2 to 2-B4 is from 0 adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B5 to functional liquid carrier 2-B5. It is shown as a relative amount when the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in support material 2-B1 is taken as 100. In Table 6, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[Example 3-B1]
A functional liquid carrier 3-B1 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer B1 (W) in Example 1-B1. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-B1 was 100% by mass of the porous coordination polymer B1 (W). , 210% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 3-B1 is 7.4% by mass and the matrix resin (polyethylene resin) is 92.6% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 7 μg/cm ² .

[Example 3-B2]
A functional liquid carrier 3-B2 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer B2 (W) in Example 1-B2. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-B2 was 100% by mass of the porous coordination polymer B2 (W). , 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 3-B2 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Example 3-B3]
Functional liquid support 3-B3 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for porous coordination polymer B3 (W) in Example 1-B3. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-B3 was 100% by mass of the porous coordination polymer B3 (W). , 150% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 3-B3 is 8.8% by mass and the matrix resin (polyethylene resin) is 91.2% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Comparative Example 3-B4]
Functional liquid support 3-B4 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for porous coordination polymer B4 (W) in Example 1-B4. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid support 3-B4 was 100% by mass of the porous coordination polymer B4 (W). , 120% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 3-B4 is 9.2% by mass and the matrix resin (polyethylene resin) is 90.8% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Comparative Example 3-B5]
A functional liquid carrier 3-B5 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid for the porous coordination polymer B5 (W) in Example 1-B5. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-B5 was 100% by mass of the porous coordination polymer B5 (W). , 90% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 3-B5 is 10.6% by mass and the matrix resin (polyethylene resin) is 89.4% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 12 g/cm ² .

Table 7 shows the amount of 4-nonanolide adsorbed in the functional liquid carriers 3-B1 to 3-B5 and the amount of OIT surface in the plate-shaped molded body. In addition, Table 7 also shows the relative change amount when the amount of adsorption of 4-nonanolide in functional liquid carrier 3-B1 is 100 and the amount of adsorption of 4-nonanolide in functional liquid carrier 3-B5 is 0. show. In addition, the relative change in the functional liquid carriers 3-B2 to 3-B4 is from the adsorption amount of 4-nonanolide in the functional liquid carrier 3-B5 to 4-nonanolide in the functional liquid carrier 3-B1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 4-B1]
For the porous coordination polymer B1 (W) in Example 1-B1, functional liquid carrier 4-B1 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-B1 was 100% by mass of the porous coordination polymer B1 (W). On the other hand, it was 280% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 4-B1 is 6.8% by mass and the matrix resin (polyethylene resin) is 93.2% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 13 g/cm ² .

[Example 4-B2]
For the porous coordination polymer B2 (W) in Example 1-B2, functional liquid support 4-B2 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-B2 was 100% by mass of the porous coordination polymer B2 (W). On the other hand, it was 230% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 4-B2 is 7.2% by mass and the matrix resin (polyethylene resin) is 92.8% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 15 g/cm ² .

[Example 4-B3]
For the porous coordination polymer B3 (W) in Example 1-B3, functional liquid support 4-B3 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-B3 was 100% by mass of the porous coordination polymer B3 (W). On the other hand, it was 200% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 4-B3 is 7.5% by mass and the matrix resin (polyethylene resin) is 92.5% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 16 g/cm ² .

[Comparative Example 4-B4]
For the porous coordination polymer B4 (W) in Example 1-B4, functional liquid support 4-B4 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-B4 was 100% by mass of the porous coordination polymer B4 (W). On the other hand, it was 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 4-B4 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 19 g/cm ² .

[Comparative Example 4-B5]
For the porous coordination polymer B5 (W) in Example 1-B5, functional liquid support 4-B5 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-B5 was 100% by mass of the porous coordination polymer B5 (W). In contrast, it was 110% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In addition, the mixing is such that the functional liquid carrier 4-B5 is 9.5% by mass and the matrix resin (polyethylene resin) is 90.5% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 25 g/cm ² .

Table 8 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-B1 to 4-B5 and the surface amount of trimellitic acid ester on the plate-shaped molded body. In addition, in Table 8, the relative change amount is also given when the adsorption amount of trimellitic acid ester in functional liquid carrier 4-B1 is 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-B5 is 0. Also shown. In addition, the relative change in the functional liquid carriers 4-B2 to 4-B4 is from the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-B5 to 0, to the trimellitic acid ester adsorption amount in the functional liquid carrier 4-B1. It is shown as a relative amount when the adsorption amount of ester up to 100 is set as 100. In Table 8, TOTM indicates trimellitic acid ester.

[Example 1-C1]
When the amount of free terephthalic acid was measured by the above method with respect to the porous coordination polymer C1 (W), it was found that it was 0.1% by mass with respect to 100% by mass of the porous coordination polymer C1 (W). there were. Further, the specific surface area of the porous coordination polymer C1(W) by the BET method was 1004 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 644 cm ³ /g.
Next, a functional liquid carrier 1-C1 was obtained in which etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer C1 (W). Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-C1 was 100% by mass of the porous coordination polymer C1 (W). , 280% by mass.
Next, the functional liquid carrier 1-C1 was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). In addition, the mixing is such that the functional liquid carrier 1-C1 is 6.8% by mass and the matrix resin (polyethylene resin) is 93.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Example 1-C2]
When the amount of free terephthalic acid was measured using the above method with respect to the porous coordination polymer C2 (W), it was found that it was 0.3% by mass with respect to 100% by mass of the porous coordination polymer C2 (W). there were. Further, the specific surface area of the porous coordination polymer C2(W) by the BET method was 1006 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 656 cm ³ /g.
Next, in the same manner as in Example 1-C1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer C2 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-C2 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-C2 was 100% by mass of the porous coordination polymer C2 (W). , 270% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 1-C2 is 6.9% by mass and the matrix resin (polyethylene resin) is 93.1% by mass based on 100% by mass of the functional sustained release composition. did. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 13 μg/cm ² .

[Example 1-C3]
When the amount of free terephthalic acid was measured using the above method with respect to the porous coordination polymer C3 (W), it was found that it was 0.5% by mass based on 100% by mass of the porous coordination polymer C3 (W). there were. Further, the specific surface area of the porous coordination polymer C3(W) by the BET method was 1043 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 643 cm ³ /g.
Next, in the same manner as in Example 1-C1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer C3 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-C3 was obtained. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in the functional liquid support 1-C3 was 100% by mass of the porous coordination polymer C3(W). , 240% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 1-C3 is 7.1% by mass and the matrix resin (polyethylene resin) is 92.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 16 μg/cm ² .

[Comparative Example 1-C4]
When the amount of free terephthalic acid was measured using the above method with respect to the porous coordination polymer C4 (W), it was found to be 0.8% by mass based on 100% by mass of the porous coordination polymer C4 (W). there were. Further, the specific surface area of the porous coordination polymer C4(W) by the BET method was 1050 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 650 cm ³ /g.
Next, in the same manner as in Example 1-C1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer C4 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-C4 was obtained. When the adsorption amount of etofenprox was measured using the above measurement method, it was found that the adsorption amount of etofenprox in the functional liquid carrier 1-C4 was 100% by mass of the porous coordination polymer C4 (W). , 190% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 1-C4 is 7.6% by mass and the matrix resin (polyethylene resin) is 92.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded product was measured and found to be 26 μg/cm ² .

[Comparative Example 1-C5]
When the amount of free terephthalic acid was measured using the above method with respect to the porous coordination polymer C5(W), it was found to be 0.9% by mass based on 100% by mass of the porous coordination polymer C5(W). there were. Further, the specific surface area of the porous coordination polymer C5(W) by the BET method was 1051 m ² /g, the average pore diameter was 0.9 nm, and the gas adsorption amount was 651 cm ³ /g.
Next, in the same manner as in Example 1-C1, etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer C5 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-C5 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-C5 was 100% by mass of the porous coordination polymer C5 (W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 1-C5 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 33 μg/cm ² .

Table 9 shows the adsorption amount of etofenprox in the functional liquid carriers 1-C1 to 1-C5 and the amount of etofenprox on the surface of the plate-shaped molded body. In addition, Table 9 also shows the relative change amount when the adsorption amount of etofenprox in functional liquid carrier 1-C1 is 100 and the adsorption amount of etofenprox in functional liquid carrier 1-C5 is 0. show. In addition, the relative change in the functional liquid carriers 1-C2 to 1-C4 is from the adsorption amount of etofenprox in the functional liquid carrier 1-C5 to 0 in the functional liquid carrier 1-C1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 2-C1]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer C1 (W) in Example 1-C1 instead of etofenprox as a functional sustained release liquid. A functional liquid carrier 2-C1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-C1. The amount was 200% by weight relative to 100% by weight of the porous coordination polymer C1(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 2-C1 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Example 2-C2]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer C2 (W) in Example 1-C2 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-C2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-C2. The amount was 190% by weight relative to 100% by weight of the porous coordination polymer C2(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 2-C2 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Example 2-C3]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer C3 (W) in Example 1-C3 instead of etofenprox as a functional sustained release liquid. A functional liquid carrier 2-C3 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-C3. The amount was 160% by weight relative to 100% by weight of the porous coordination polymer C3(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 2-C3 is 3.3% by mass and the matrix resin (polyethylene resin) is 96.7% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 11 μg/cm ² .

[Comparative Example 2-C4]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer C4 (W) in Example 1-C4 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-C4 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-C4. The amount was 140% by weight relative to 100% by weight of the porous coordination polymer C4(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 2-C4 is 3.4% by mass and the matrix resin (polyethylene resin) is 96.6% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 13 μg/cm ² .

[Comparative Example 2-C5]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer C5 (W) in Example 1-C5 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-C5 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-C5. The amount was 120% by weight relative to 100% by weight of the porous coordination polymer C5(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 2-C5 is 3.7% by mass and the matrix resin (polyethylene resin) is 96.3% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 15 μg/cm ² .

Adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-C1 to 2-C5 and surface amount of 2-n-octyl-4-isothiazolin-3-one in the plate-shaped molded product are shown in Table 10. In addition, in Table 10, the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-C1 is assumed to be 100, and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-C5 is assumed to be 100. The relative change amount with the amount of 4-isothiazolin-3-one adsorbed as 0 is also shown. In addition, the relative change in the functional liquid carriers 2-C2 to 2-C4 is from 0 adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-C5 to the functional liquid carrier 2-C5. It is shown as a relative amount when the amount of adsorption of 2-n-octyl-4-isothiazolin-3-one in support material 2-C1 is taken as 100. In Table 10, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[Example 3-C1]
A functional liquid in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer C1 (W) in Example 1-C1, and 4-nonanolide was adsorbed. Support material 3-C1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-C1 was 100% by mass of the porous coordination polymer C1 (W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 3-C1 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded product was measured and found to be 7 μg/cm ² .

[Example 3-C2]
A functional liquid in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer C2 (W) in Example 1-C2, and 4-nonanolide was adsorbed. Support material 3-C2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-C2 was 100% by mass of the porous coordination polymer C2 (W). , 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 3-C2 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 7 μg/cm ² .

[Example 3-C3]
A functional liquid carrier 3-C3 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer C3 (W) in Example 1-C3. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-C3 was 100% by mass of the porous coordination polymer C3(W). , 140% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 3-C3 is 8.6% by mass and the matrix resin (polyethylene resin) is 91.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded product was measured and found to be 7 μg/cm ² .

[Comparative Example 3-C4]
A functional liquid carrier 3-C4 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid to the porous coordination polymer C4 (W) in Example 1-C4. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-C4 was 100% by mass of the porous coordination polymer C4 (W). , 120% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 3-C4 is 9.2% by mass and the matrix resin (polyethylene resin) is 90.8% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Comparative Example 3-C5]
A functional liquid carrier 3-C5 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid for the porous coordination polymer C5 (W) in Example 1-C5. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-C5 was 100% by mass of the porous coordination polymer C5(W). , 100% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 3-C5 is 10.0% by mass and the matrix resin (polyethylene resin) is 90.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

Table 11 shows the amount of 4-nonanolide adsorbed in the functional liquid carriers 3-C1 to 3-C5 and the amount of 4-nonanolide on the surface of the plate-shaped molded article. In addition, Table 11 also shows the relative change amount when the adsorption amount of 4-nonanolide in functional liquid carrier 3-C1 is 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-C5 is 0. show. In addition, the relative change in the functional liquid carriers 3-C2 to 3-C4 is from the adsorption amount of 4-nonanolide in the functional liquid carrier 3-C5 to 4-nonanolide in the functional liquid carrier 3-C1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 4-C1]
For the porous coordination polymer C1 (W) in Example 1-C1, functional liquid carrier 4-C1 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-C1 was 100% by mass of the porous coordination polymer C1 (W). On the other hand, it was 240% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 4-C1 is 7.1% by mass and the matrix resin (polyethylene resin) is 92.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Example 4-C2]
For the porous coordination polymer C2 (W) in Example 1-C2, functional liquid carrier 4-C2 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-C2 was 100% by mass of the porous coordination polymer C2 (W). On the other hand, it was 220% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 4-C2 is 7.3% by mass and the matrix resin (polyethylene resin) is 92.7% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 14 μg/cm ² .

[Example 4-C3]
For porous coordination polymer C3 (W) in Example 1-C3, functional liquid support 4-C3 on which trimellitic acid ester was adsorbed was used instead of etofenprox as a functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-C3 was 100% by mass of the porous coordination polymer C3 (W). On the other hand, it was 200% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 4-C3 is 7.5% by mass and the matrix resin (polyethylene resin) is 92.5% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 17 μg/cm ² .

[Comparative Example 4-C4]
For porous coordination polymer C4 (W) in Example 1-C4, functional liquid support 4-C4 on which trimellitic acid ester was adsorbed was used instead of etofenprox as a functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-C4 was 100% by mass of the porous coordination polymer C4 (W). On the other hand, it was 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 4-C4 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 22 μg/cm ² .

[Comparative Example 4-C5]
For the porous coordination polymer C5 (W) in Example 1-C5, functional liquid carrier 4-C5 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-C5 was 100% by mass of the porous coordination polymer C5 (W). On the other hand, it was 150% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-C1. In addition, the mixing is such that the functional liquid carrier 4-C5 is 8.8% by mass and the matrix resin (polyethylene resin) is 91.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 27 μg/cm ² .

Table 12 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-C1 to 4-C5 and the surface amount of trimellitic acid ester in the plate-shaped molded product. In addition, in Table 12, the relative change amount is also given when the adsorption amount of trimellitic acid ester in functional liquid carrier 4-C1 is 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-C5 is 0. Also shown. In addition, the relative change in the functional liquid carriers 4-C2 to 4-C4 is from the adsorption amount of trimellitic acid ester of 0 in the functional liquid carrier 4-C5 to the trimellitic acid ester adsorption amount in the functional liquid carrier 4-C1. It is shown as a relative amount when the adsorption amount of ester up to 100 is set as 100. In Table 12, TOTM indicates trimellitic acid ester.

[Example 1-D1]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to the porous coordination polymer D1 (W) by the above method, it was found that it was 100% by mass of the porous coordination polymer D1 (W). , 0.2% by mass. Further, the specific surface area of the porous coordination polymer D1 (W) by the BET method was 1607 m ² /g, the average pore diameter was 2.6 nm, and the amount of gas adsorption was 703 cm ³ /g.
Next, a functional liquid-supported material 1-D1 was obtained in which etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer D1 (W). Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-D1 was 100% by mass of the porous coordination polymer D1 (W). , 320% by mass.
Next, the functional liquid carrier 1-D1 was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). In addition, the mixing is such that the functional liquid carrier 1-D1 is 6.6% by mass and the matrix resin (polyethylene resin) is 93.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 1-D2]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer D2 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer D2 (W). , 0.3% by mass. Further, the specific surface area of the porous coordination polymer D2 (W) by the BET method was 1610 m ² /g, the average pore diameter was 2.6 nm, and the amount of gas adsorption was 710 cm ³ /g.
Next, in the same manner as in Example 1-D1, a functional liquid-supported material 1-D2 in which etofenprox was adsorbed onto the porous coordination polymer D2 (W) was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-D2 was 100% by mass of the porous coordination polymer D2 (W). , 280% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 1-D2 is 6.6% by mass and the matrix resin (polyethylene resin) is 93.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 14 μg/cm ² .

[Example 1-D3]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer D3 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer D3 (W). , 0.6% by mass. Further, the specific surface area of the porous coordination polymer D3 (W) by the BET method was 1619 m ² /g, the average pore diameter was 2.6 nm, and the amount of gas adsorption was 689 cm ³ /g.
Next, in the same manner as in Example 1-D1, etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer D3 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-D3 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-D3 was 100% by mass of the porous coordination polymer D3 (W). , 250% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 1-D3 is 6.8% by mass and the matrix resin (polyethylene resin) is 93.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 14 μg/cm ² .

[Comparative Example 1-D4]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer D4 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer D4 (W). , 0.8% by mass. Further, the specific surface area of the porous coordination polymer D4 (W) by the BET method was 1625 m ² /g, the average pore diameter was 2.6 nm, and the amount of gas adsorption was 695 cm ³ /g.
Next, a functional liquid carrier 1-D4 in which etofenprox was adsorbed onto the porous coordination polymer D4 (W) was obtained in the same manner as in Example 1-D1. When the adsorption amount of etofenprox was measured using the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-D4 was 100% by mass of the porous coordination polymer D4 (W). , 180% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 1-D4 is 7.0% by mass and the matrix resin (polyethylene resin) is 93.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and was found to be 23 μg/cm ² .

[Comparative Example 1-D5]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer D5 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer D5 (W). , 0.9% by mass. Further, the specific surface area of the porous coordination polymer D5 (W) by the BET method was 1624 m ² /g, the average pore diameter was 2.6 nm, and the amount of gas adsorption was 694 cm ³ /g.
Next, in the same manner as in Example 1-D1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer D5 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-D5 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-D5 was 100% by mass of the porous coordination polymer D5 (W). , 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 1-D5 is 7.8% by mass and the matrix resin (polyethylene resin) is 92.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 37 μg/cm ² .

Table 13 shows the adsorption amount of etofenprox in the functional liquid carriers 1-D1 to 1-D5 and the surface amount of the plate-shaped molding composition. In addition, Table 13 also includes the relative change amount when the adsorption amount of etofenprox in functional liquid carrier 1-D1 is 100 and the adsorption amount of etofenprox in functional liquid carrier 1-D5 is 0. show. In addition, the relative change in the functional liquid carriers 1-D2 to 1-D4 is from the adsorption amount of etofenprox in the functional liquid carrier 1-D5 to 0, to the adsorption amount of etofenprox in the functional liquid carrier 1-D1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 2-D1]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer D1 (W) in Example 1-D1 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-D1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-D1. The amount was 240% by weight based on 100% by weight of the porous coordination polymer D1(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 2-D1 is 2.8% by mass and the matrix resin (polyethylene resin) is 97.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Example 2-D2]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer D2 (W) in Example 1-D2 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-D2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-D2. The amount was 220% by weight based on 100% by weight of the porous coordination polymer D2(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 2-D2 is 3.0% by mass and the matrix resin (polyethylene resin) is 97.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Example 2-D3]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer D3 (W) in Example 1-D3 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-D3 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-D3. The amount was 180% by weight based on 100% by weight of the porous coordination polymer D3(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 2-D3 is 3.1% by mass and the matrix resin (polyethylene resin) is 96.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Comparative Example 2-D4]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer D4 (W) in Example 1-D4 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-D4 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-D4. The amount was 120% by weight based on 100% by weight of the porous coordination polymer D4(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 2-D4 is 3.7% by mass and the matrix resin (polyethylene resin) is 96.3% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 15 μg/cm ² .

[Comparative Example 2-D5]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer D5 (W) in Example 1-D5 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-D5 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-D5. The amount was 110% by weight based on 100% by weight of the porous coordination polymer D5(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 2-D5 is 3.8% by mass and the matrix resin (polyethylene resin) is 96.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 18 μg/cm ² .

Adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-D1 to 2-D5 and surface amount of 2-n-octyl-4-isothiazolin-3-one in the plate-shaped molded product are shown in Table 14. In addition, in Table 14, the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D1 is assumed to be 100, and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D5 is assumed to be 100. The relative change amount with the amount of 4-isothiazolin-3-one adsorbed as 0 is also shown. In addition, the relative change in the functional liquid carriers 2-D2 to 2-D4 is from the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-D5 to 0. It is shown as a relative amount when the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in support material 2-D1 is taken as 100. In Table 14, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[Example 3-D1]
Functional liquid carrier 3- in which 4-nonanolide 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid to the porous coordination polymer D1 (W) in Example 1-D1. I got D1. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D1 was 100% by mass of the porous coordination polymer D1 (W). , 230% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 3-D1 is 7.2% by mass and the matrix resin (polyethylene resin) is 92.8% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 6 μg/cm ² .

[Example 3-D2]
A functional liquid carrier 3-D2 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer D2 (W) in Example 1-D2. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D2 was 100% by mass of the porous coordination polymer D2 (W). , 210% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 3-D2 is 7.4% by mass and the matrix resin (polyethylene resin) is 92.6% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 6 μg/cm ² .

[Example 3-D3]
A functional liquid support 3-D3 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid for the porous coordination polymer D3 (W) in Example 1-D3. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D3 was 100% by mass of the porous coordination polymer D3 (W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 3-D3 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Comparative Example 3-D4]
A functional liquid carrier 3-D4 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer D4 (W) in Example 1-D4. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D4 was 100% by mass of the porous coordination polymer D4 (W). , 130% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 3-D4 is 8.8% by mass and the matrix resin (polyethylene resin) is 91.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Comparative Example 3-D5]
A functional liquid carrier 3-D5 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for the porous coordination polymer D5 (W) in Example 1-D5. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D5 was 100% by mass of the porous coordination polymer D5 (W). , 110% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 3-D5 is 9.5% by mass and the matrix resin (polyethylene resin) is 90.5% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

Table 15 shows the adsorption amount of 4-nonanolide in the functional liquid carriers 3-D1 to 3-D5 and the surface amount of the plate-shaped molded product. In addition, Table 15 also includes the relative change amount when the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D1 is 100 and the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D5 is 0. show. In addition, the relative change in the functional liquid carriers 3-D2 to 3-D4 is from the adsorption amount of 4-nonanolide in the functional liquid carrier 3-D5 to 4-nonanolide in the functional liquid carrier 3-D1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 4-D1]
For porous coordination polymer D1 (W) in Example 1-D1, instead of etofenprox as a functional sustained release liquid, functional liquid carrier 4-D1 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-D1 was 100% by mass of the porous coordination polymer D1 (W). On the other hand, it was 330% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 4-D1 is 6.5% by mass and the matrix resin (polyethylene resin) is 93.5% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Example 4-D2]
For the porous coordination polymer D2 (W) in Example 1-D2, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-D2 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-D2 was 100% by mass of the porous coordination polymer D2 (W). On the other hand, it was 310% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing was such that the functional liquid carrier 4-D2 was 6.6% by mass and the matrix resin (polyethylene resin) was 93.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Example 4-D3]
For the porous coordination polymer D3 (W) in Example 1-D3, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-D3 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-D3 was 100% by mass of the porous coordination polymer D3 (W). On the other hand, it was 260% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 4-D3 is 6.9% by mass and the matrix resin (polyethylene resin) is 93.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 18 μg/cm ² .

[Comparative Example 4-D4]
For the porous coordination polymer D4 (W) in Example 1-D4, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-D4 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-D4 was 100% by mass of the porous coordination polymer D4 (W). On the other hand, it was 190% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 4-D4 is 7.6% by mass and the matrix resin (polyethylene resin) is 92.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 33 μg/cm ² .

[Comparative Example 4-D5]
For the porous coordination polymer D5 (W) in Example 1-D5, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-D5 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-D5 was 100% by mass of the porous coordination polymer D5 (W). On the other hand, it was 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-D1. In addition, the mixing is such that the functional liquid carrier 4-D5 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 58 μg/cm ² .

Table 16 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-D1 to 4-D5 and the surface amount of the plate-shaped molded product. In addition, in Table 16, the relative change amount is also given when the adsorption amount of trimellitic acid ester in functional liquid carrier 4-D1 is 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-D5 is 0. Also shown. In addition, the relative change in the functional liquid carriers 4-D2 to 4-D4 is from the adsorption amount of trimellitic acid ester of 0 in the functional liquid carrier 4-D5 to the trimellitic acid ester adsorption amount in the functional liquid carrier 4-D1. It is shown as a relative amount when the adsorption amount of ester up to 100 is set as 100. In Table 16, TOTM indicates trimellitic acid ester.

[Example 1-E1]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to the porous coordination polymer E1 (W) by the above method, it was found that it was 100% by mass of the porous coordination polymer E1 (W). , 0.1% by mass. Further, the specific surface area of the porous coordination polymer E1 (W) by the BET method was 1534 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 346 cm ³ /g.
Next, a functional liquid-supported material 1-E1 was obtained in which etofenprox was adsorbed onto the porous coordination polymer E1 (W). Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-E1 was 100% by mass of the porous coordination polymer E1 (W). , 270% by mass.
Next, the functional liquid carrier 1-E1 was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). In addition, the mixing is such that the functional liquid carrier 1-E1 is 6.9% by mass and the matrix resin (polyethylene resin) is 93.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 1-E2]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer E2 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer E2 (W). , 0.3% by mass. Further, the specific surface area of the porous coordination polymer E2 (W) by the BET method was 1531 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 361 cm ³ /g.
Next, in the same manner as in Example 1-E1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer E2 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-E2 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-E2 was 100% by mass of the porous coordination polymer E2 (W). , 230% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 1-E2 is 7.2% by mass and the matrix resin (polyethylene resin) is 92.8% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 14 μg/cm ² .

[Example 1-E3]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer E3 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer E3 (W). , 0.6% by mass. Further, the specific surface area of the porous coordination polymer E3 (W) by the BET method was 1623 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 352 cm ³ /g.
Next, in the same manner as in Example 1-E1, etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer E3 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-E3 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-E3 was 100% by mass of the porous coordination polymer E3 (W). , 210% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 1-E3 is 7.4% by mass and the matrix resin (polyethylene resin) is 92.6% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 17 μg/cm ² .

[Comparative Example 1-E4]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer E4 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer E4 (W). , 0.7% by mass. Further, the specific surface area of the porous coordination polymer E4 (W) by the BET method was 1536 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 356 cm ³ /g.
Next, in the same manner as in Example 1-E1, a functional liquid-supported material 1-E4 in which etofenprox was adsorbed onto the porous coordination polymer E4 (W) was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-E4 was 100% by mass of the porous coordination polymer E4 (W). , 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 1-E4 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 28 μg/cm ² .

[Comparative Example 1-E5]
When the amount of free 1,3,5-benzenetricarboxylic acid was measured with respect to porous coordination polymer E5 (W) by the above method, it was found that it was 100% by mass of porous coordination polymer E5 (W). , 0.9% by mass. Further, the specific surface area of the porous coordination polymer E5 (W) by the BET method was 1534 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 349 cm ³ /g.
Next, in the same manner as in Example 1-E1, etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer E5 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-E5 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-E5 was 100% by mass of the porous coordination polymer E5 (W). , 150% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 1-E5 is 8.3% by mass and the matrix resin (polyethylene resin) is 91.7% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 32 μg/cm ² .

Table 17 shows the adsorption amount of etofenprox in the functional liquid carriers 1-E1 to 1-E5 and the amount of etofenprox on the surface of the plate-shaped molded body. In addition, Table 17 also shows the relative change amount when the adsorption amount of etofenprox in functional liquid carrier 1-E1 is 100 and the adsorption amount of etofenprox in functional liquid carrier 1-E5 is 0. show. In addition, the relative change in the functional liquid carriers 1-E2 to 1-E4 is from the adsorption amount of etofenprox in functional liquid carrier 1-E5 to 0 in the functional liquid carrier 1-E1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 2-E1]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer E1 (W) in Example 1-E1 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-E1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-E1. The amount was 230% by weight based on 100% by weight of the porous coordination polymer E1(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 2-E1 is 2.9% by mass and the matrix resin (polyethylene resin) is 97.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 2-E2]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer E2 (W) in Example 1-E2 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-E2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-E2. The amount was 210% by weight based on 100% by weight of the porous coordination polymer E2(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 2-E2 is 3.0% by mass and the matrix resin (polyethylene resin) is 97.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 2-E3]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer E3 (W) in Example 1-E3 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-E3 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-E3. The amount was 180% by weight based on 100% by weight of the porous coordination polymer E3(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 2-E3 is 3.3% by mass and the matrix resin (polyethylene resin) is 96.7% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 11 μg/cm ² .

[Comparative example 2-E4]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer E4 (W) in Example 1-E4 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-E4 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-E4. The amount was 130% by weight based on 100% by weight of the porous coordination polymer E4(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 2-E4 is 3.5% by mass and the matrix resin (polyethylene resin) is 96.5% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 14 μg/cm ² .

[Comparative Example 2-E5]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer E5 (W) in Example 1-E5 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-E5 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-E5. The amount was 120% by weight based on 100% by weight of the porous coordination polymer E5(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing was carried out so that the functional liquid carrier 2-E5 was 3.7% by mass and the matrix resin (polyethylene resin) was 96.3% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 16 μg/cm ² .

Table 18 shows the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carriers 2-E1 to 2-E5 and the surface amount in the plate-shaped molded product. In addition, in Table 18, the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E1 is assumed to be 100, and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E5 is assumed to be 100. The relative change amount with the amount of 4-isothiazolin-3-one adsorbed as 0 is also shown. In addition, the relative change amount in functional liquid carriers 2-E2 to 2-E4 is from 0 adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E5 to functional liquid carrier 2-E5. It is shown as a relative amount when the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in support material 2-E1 is taken as 100. In Table 18, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[Example 3-E1]
Functional liquid support 3-E1 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer E1 (W) in Example 1-E1. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-E1 was 100% by mass of the porous coordination polymer E1 (W). , 210% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 3-E1 is 7.4% by mass and the matrix resin (polyethylene resin) is 92.6% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 6 μg/cm ² .

[Example 3-E2]
Functional liquid support 3-E2 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid for porous coordination polymer E2 (W) in Example 1-E2. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid support 3-E2 was 100% by mass of the porous coordination polymer E2 (W). , 180% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 3-E2 is 7.8% by mass and the matrix resin (polyethylene resin) is 92.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded product was measured and found to be 7 μg/cm ² .

[Example 3-E3]
A functional liquid carrier 3-E3 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for the porous coordination polymer E3 (W) in Example 1-E3. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-E3 was 100% by mass of the porous coordination polymer E3 (W). , 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 3-E3 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compounding process and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Comparative Example 3-E4]
Functional liquid carrier 3-E4 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for porous coordination polymer E4 (W) in Example 1-E4. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-E4 was 100% by mass of the porous coordination polymer E4 (W). , 130% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 3-E4 is 8.8% by mass and the matrix resin (polyethylene resin) is 91.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Comparative Example 3-E5]
A functional liquid support 3-E5 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid for the porous coordination polymer E5 (W) in Example 1-E5. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-E5 was 100% by mass of the porous coordination polymer E5 (W). , 100% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 3-E5 is 10.0% by mass and the matrix resin (polyethylene resin) is 90.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

Table 19 shows the adsorption amount of 4-nonanolide in the functional liquid carriers 3-E1 to 3-E5 and the surface amount of the plate-shaped molded product. In Table 19, the amount of adsorption of 4-nonanolide in functional liquid carrier 3-E1 is set to 100, and the amount of relative change is also shown, assuming that the amount of adsorption of 4-nonanolide in functional liquid carrier 3-E5 is 0. show. In addition, the relative change in the functional liquid carriers 3-E2 to 3-E4 is from the adsorption amount of 4-nonanolide in the functional liquid carrier 3-E5 to 4-nonanolide in the functional liquid carrier 3-E1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 4-E1]
For the porous coordination polymer E1 (W) in Example 1-E1, functional liquid support 4-E1 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-E1 was 100% by mass of the porous coordination polymer E1 (W). On the other hand, it was 250% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 4-E1 is 7.0% by mass and the matrix resin (polyethylene resin) is 93.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 4-E2]
For the porous coordination polymer E2 (W) in Example 1-E2, functional liquid support 4-E2 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-E2 was 100% by mass of the porous coordination polymer E2 (W). On the other hand, it was 210% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 4-E2 is 7.4% by mass and the matrix resin (polyethylene resin) is 92.6% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 14 μg/cm ² .

[Example 4-E3]
For the porous coordination polymer E3 (W) in Example 1-E3, functional liquid support 4-E3 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured by the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-E3 was 100% by mass of the porous coordination polymer E3 (W). On the other hand, it was 200% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 4-E3 is 7.5% by mass and the matrix resin (polyethylene resin) is 92.5% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 16 μg/cm ² .

[Comparative example 4-E4]
For the porous coordination polymer E4 (W) in Example 1-E4, functional liquid support 4-E4 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-E4 was 100% by mass of the porous coordination polymer E4 (W). On the other hand, it was 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 4-E4 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 22 μg/cm ² .

[Comparative Example 4-E5]
For porous coordination polymer E5 (W) in Example 1-E5, functional liquid carrier 4-E5 on which trimellitic acid ester was adsorbed was used instead of etofenprox as a functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-E5 was 100% by mass of the porous coordination polymer E5 (W). On the other hand, it was 130% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-E1. In addition, the mixing is such that the functional liquid carrier 4-E5 is 8.8% by mass and the matrix resin (polyethylene resin) is 91.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 46 μg/cm ² .

Table 20 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-E1 to 4-E5 and the surface amount of the plate-shaped molded body. In addition, in Table 20, the relative change amount is also given when the adsorption amount of trimellitic acid ester in functional liquid carrier 4-E1 is 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-E5 is 0. Also shown. In addition, the relative change in the functional liquid carriers 4-E2 to 4-E4 is from 0 adsorption amount of trimellitic acid ester in the functional liquid carrier 4-E5 to trimellitic acid ester adsorption amount in the functional liquid carrier 4-E1. It is shown as a relative amount when the adsorption amount of ester up to 100 is set as 100. In Table 20, TOTM indicates trimellitic acid ester.

[Example 1-F1]
When the amount of free 2-methylimidazole was measured by the above method with respect to the porous coordination polymer F1 (W), it was found that it was 0.3 mass % with respect to 100 mass% of the porous coordination polymer F1 (W). %Met. Further, the specific surface area of the porous coordination polymer F1(W) by the BET method was 1404 m ² /g, the average pore diameter was 0.8 nm, and the amount of gas adsorption was 170 cm ³ /g.
Next, a functional liquid-supported material 1-F1 was obtained in which etofenprox was adsorbed as a functional sustained-release liquid onto the porous coordination polymer F1 (W). Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-F1 was 100% by mass of the porous coordination polymer F1 (W). , 260% by mass.
Next, the functional liquid carrier 1-F1 was compounded and mixed with a polyethylene resin (Novatic UJ310 manufactured by Nippon Polyethylene Products) as a matrix resin to prepare a functional sustained release composition (molded body material). In addition, the mixing is such that the functional liquid carrier 1-F1 is 6.9% by mass and the matrix resin (polyethylene resin) is 93.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 11 μg/cm ² .

[Example 1-F2]
When the amount of free 2-methylimidazole was measured using the above method with respect to the porous coordination polymer F2(W), it was found that 0.5 mass% was determined based on 100% by mass of the porous coordination polymer F2(W). %Met. Further, the specific surface area of the porous coordination polymer F2(W) by the BET method was 1410 m ² /g, the average pore diameter was 0.8 nm, and the amount of gas adsorption was 171 cm ³ /g.
Next, in the same manner as in Example 1-F1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer F2 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-F2 was obtained. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in the functional liquid carrier 1-F2 was 100% by mass of the porous coordination polymer F2 (W). , 240% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 1-F2 is 7.1% by mass and the matrix resin (polyethylene resin) is 92.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 12 μg/cm ² .

[Example 1-F3]
When the amount of free 2-methylimidazole was measured by the above method with respect to the porous coordination polymer F3 (W), it was found that it was 0.7 mass % with respect to 100 mass% of the porous coordination polymer F3 (W). %Met. Further, the specific surface area of the porous coordination polymer F3(W) by the BET method was 1413 m ² /g, the average pore diameter was 0.9 nm, and the amount of gas adsorption was 173 cm ³ /g.
Next, in the same manner as in Example 1-F1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer F3 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-F3 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-F3 was 100% by mass of the porous coordination polymer F3 (W). , 190% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 1-F3 is 7.6% by mass and the matrix resin (polyethylene resin) is 92.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 20 μg/cm ² .

[Comparative Example 1-F4]
When the amount of free 2-methylimidazole was measured by the above method with respect to the porous coordination polymer F4 (W), it was found that it was 0.9 mass % with respect to 100 mass% of the porous coordination polymer F4 (W). %Met. Further, the specific surface area of the porous coordination polymer F4(W) by the BET method was 1404 m ² /g, the average pore diameter was 0.8 nm, and the amount of gas adsorption was 174 cm ³ /g.
Next, in the same manner as in Example 1-F1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer F4 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-F4 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid support 1-F4 was 100% by mass of the porous coordination polymer F4 (W). , 110% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 1-F4 is 9.5% by mass and the matrix resin (polyethylene resin) is 90.5% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 59 μg/cm ² .

[Comparative Example 1-F5]
When the amount of free 2-methylimidazole was measured with respect to the porous coordination polymer F5 (W) by the above method, it was found that 1.0 mass % with respect to 100 mass% of the porous coordination polymer F5 (W). %Met. Further, the specific surface area of the porous coordination polymer F5(W) by the BET method was 1412 m ² /g, the average pore diameter was 0.8 nm, and the amount of gas adsorption was 162 cm ³ /g.
Next, in the same manner as in Example 1-F1, etofenprox was adsorbed as a functional sustained release liquid onto the porous coordination polymer F5 (W), and the functional liquid carrying etofenprox was adsorbed. Product 1-F5 was obtained. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-F5 was 100% by mass of the porous coordination polymer F5 (W). , 100% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 1-F5 is 10.0% by mass and the matrix resin (polyethylene resin) is 90.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 37 μg/cm ² .

Table 21 shows the adsorption amount of etofenprox in the functional liquid carriers 1-F1 to 1-F5 and the surface amount of the plate-shaped molded body. In addition, Table 21 also shows the relative change amount when the adsorption amount of etofenprox in functional liquid carrier 1-F1 is 100 and the adsorption amount of etofenprox in functional liquid carrier 1-F5 is 0. show. In addition, the relative change in the functional liquid carriers 1-F2 to 1-F4 is from the adsorption amount of etofenprox in the functional liquid carrier 1-F5 to 0 in the functional liquid carrier 1-F1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 2-F1]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer F1 (W) in Example 1-F1 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-F1 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-F1. The amount was 230% by weight based on 100% by weight of the porous coordination polymer F1(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 2-F1 is 2.9% by mass and the matrix resin (polyethylene resin) is 97.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded product was measured and found to be 7 μg/cm ² .

[Example 2-F2]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer F2 (W) in Example 1-F2 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-F2 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-F2. The amount was 210% by weight based on 100% by weight of the porous coordination polymer F2(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 2-F2 is 3.0% by mass and the matrix resin (polyethylene resin) is 97.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded product was measured and found to be 7 μg/cm ² .

[Example 2-F3]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer F3 (W) in Example 1-F3 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-F3 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-F3. The amount was 170% by weight based on 100% by weight of the porous coordination polymer F3(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 2-F3 is 3.2% by mass and the matrix resin (polyethylene resin) is 96.8% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Comparative Example 2-F4]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer F4 (W) in Example 1-F4 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-F4 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-F4. The amount was 100% by weight relative to 100% by weight of the porous coordination polymer F4(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 2-F4 is 4.0% by mass and the matrix resin (polyethylene resin) is 96.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 16 μg/cm ² .

[Comparative Example 2-F5]
2-n-octyl-4-isothiazolin-3-one was adsorbed to the porous coordination polymer F5 (W) in Example 1-F5 instead of etofenprox as a functional sustained release liquid. Functional liquid carrier 2-F5 was obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, it was found that 2-n-octyl-4-isothiazolin-3-one was adsorbed on the functional liquid carrier 2-F5. The amount was 90% by weight based on 100% by weight of the porous coordination polymer F5(W).
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 2-F5 is 4.2% by mass and the matrix resin (polyethylene resin) is 95.8% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 20 μg/cm ² .

Table 22 shows the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carriers 2-F1 to 2-F5 and the surface amount of the plate-shaped molded body. In addition, in Table 22, the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-F1 is assumed to be 100, and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-F5 is assumed to be 100. The relative change amount with the amount of 4-isothiazolin-3-one adsorbed as 0 is also shown. In addition, the relative change in the functional liquid carriers 2-F2 to 2-F4 is from 0 adsorption amount of 2-n-octyl-4-isothiazolin-3-one in the functional liquid carrier 2-F5 to the functional liquid carrier 2-F5. It is shown as a relative amount when the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in support material 2-F1 is taken as 100. In Table 22, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[Example 3-F1]
A functional liquid support 3-F1 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer F1 (W) in Example 1-F1. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-F1 was 100% by mass of the porous coordination polymer F1(W). , 170% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 3-F1 is 7.9% by mass and the matrix resin (polyethylene resin) is 92.1% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 6 μg/cm ² .

[Example 3-F2]
A functional liquid carrier 3-F2 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid to the porous coordination polymer F2 (W) in Example 1-F2. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid support 3-F2 was 100% by mass of the porous coordination polymer F2 (W). , 160% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 3-F2 is 8.1% by mass and the matrix resin (polyethylene resin) is 91.9% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional liquid in the produced plate-shaped molded body was measured and found to be 6 μg/cm ² .

[Example 3-F3]
A functional liquid carrier 3-F3 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained-release liquid for the porous coordination polymer F3 (W) in Example 1-F3. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-F3 was 100% by mass of the porous coordination polymer F3(W). , 140% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 3-F3 is 8.6% by mass and the matrix resin (polyethylene resin) is 91.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded product was measured and found to be 7 μg/cm ² .

[Comparative Example 3-F4]
A functional liquid carrier 3-F4 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid to the porous coordination polymer F4 (W) in Example 1-F4. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured by the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-F4 was 100% by mass of the porous coordination polymer F4 (W). , 120% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 3-F4 is 9.2% by mass and the matrix resin (polyethylene resin) is 90.8% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the prepared plate-shaped molded body was measured and found to be 9 μg/cm ² .

[Comparative Example 3-F5]
A functional liquid support 3-F5 was obtained in which 4-nonanolide was adsorbed instead of etofenprox as a functional sustained release liquid to the porous coordination polymer F5 (W) in Example 1-F5. Ta. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of 4-nonanolide was measured using the above measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-F5 was 100% by mass of the porous coordination polymer F5(W). , 100% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 3-F5 is 10.0% by mass and the matrix resin (polyethylene resin) is 90.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

Table 23 shows the adsorption amount of 4-nonanolide in the functional liquid carriers 3-F1 to 3-F5 and the surface amount of the plate-shaped molded body. In addition, Table 23 also shows the relative change amount when the adsorption amount of 4-nonanolide in functional liquid carrier 3-F1 is 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-F5 is 0. show. In addition, the relative change in the functional liquid carriers 3-F2 to 3-F4 is from 0 adsorption amount of 4-nonanolide in the functional liquid carrier 3-F5 to 4-nonanolide in the functional liquid carrier 3-F1. It is shown as a relative amount when the adsorption amount up to 100 is set as 100.

[Example 4-F1]
For porous coordination polymer F1 (W) in Example 1-F1, functional liquid support 4-F1 on which trimellitic acid ester was adsorbed was used instead of etofenprox as a functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-F1 was 100% by mass of the porous coordination polymer F1 (W). On the other hand, it was 250% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 4-F1 is 7.0% by mass and the matrix resin (polyethylene resin) is 93.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 8 μg/cm ² .

[Example 4-F2]
For the porous coordination polymer F2 (W) in Example 1-F2, functional liquid carrier 4-F2 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-F2 was 100% by mass of the porous coordination polymer F2 (W). On the other hand, it was 220% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 4-F2 is 7.3% by mass and the matrix resin (polyethylene resin) is 92.7% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 10 μg/cm ² .

[Example 4-F3]
For the porous coordination polymer F3 (W) in Example 1-F3, functional liquid carrier 4-F3 on which trimellitic acid ester was adsorbed was used instead of etofenprox as the functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-F3 was 100% by mass of the porous coordination polymer F3 (W). In contrast, it was 180% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 4-F3 is 7.8% by mass and the matrix resin (polyethylene resin) is 92.2% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 15 μg/cm ² .

[Comparative Example 4-F4]
For the porous coordination polymer F4 (W) in Example 1-F4, instead of etofenprox as the functional sustained release liquid, functional liquid carrier 4-F4 on which trimellitic acid ester was adsorbed was used. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-F4 was 100% by mass of the porous coordination polymer F4 (W). In contrast, it was 100% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 4-F4 is 10.0% by mass and the matrix resin (polyethylene resin) is 90.0% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 26 μg/cm ² .

[Comparative Example 4-F5]
For porous coordination polymer F5 (W) in Example 1-F5, functional liquid carrier 4-F5 on which trimellitic acid ester was adsorbed was used instead of etofenprox as a functional sustained release liquid. Obtained. Note that the same adsorption method as in Example 1-A1 was used. When the adsorption amount of trimellitic acid ester was measured using the above measurement method, it was found that the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-F5 was 100% by mass of the porous coordination polymer F5 (W). On the other hand, it was 90% by mass.
Next, a plate-shaped molded body was produced in the same manner as in Example 1-F1. In addition, the mixing is such that the functional liquid carrier 4-F5 is 10.6% by mass and the matrix resin (polyethylene resin) is 89.4% by mass based on 100% by mass of the functional sustained release composition. did. Further, the compound processing and the method for producing the plate-shaped molded body were performed in the same manner as in A-1. The surface amount of the functional sustained release liquid of the produced plate-shaped molded body was measured and found to be 37 μg/cm ² .

Table 24 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-F1 to 4-F5 and the surface amount of the plate-shaped molded body. In addition, in Table 24, the relative change amount is also given when the adsorption amount of trimellitic acid ester in functional liquid carrier 4-F1 is 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-F5 is 0. Also shown. In addition, the relative change in the functional liquid carriers 4-F2 to 4-F4 is from the adsorption amount of trimellitic acid ester of 0 in the functional liquid carrier 4-F5 to the trimellitic acid ester adsorption amount in the functional liquid carrier 4-F1. It is shown as a relative amount when the adsorption amount of ester up to 100 is set as 100. In Table 24, TOTM indicates trimellitic acid ester.

The functional liquid carrier of this embodiment is a functional sustained-release material that has functional components such as small animal control function, sliding function, antibacterial function, antifungal function, self-repair function, catalytic function, and medical function. It can be used in compositions and molded bodies. Specifically, the functional liquid carrier of this embodiment can be used in industrial fields such as automobiles and electrical appliances, amenity fields such as sanitary services, and medical fields such as pharmaceuticals.

Claims (7)

a porous coordination polymer having an organic ligand and a metal ion;
and a functional sustained release liquid;
The organic ligand includes one or more selected from the group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole,
When the organic ligand contains fumaric acid, the amount of free fumaric acid in the porous coordination polymer is 0.7% by mass or less based on 100% by mass of the porous coordination polymer. ,
When the organic ligand contains terephthalic acid, the amount of free terephthalic acid in the porous coordination polymer is 0.5% by mass or less based on 100% by mass of the porous coordination polymer. ,
When the organic ligand contains benzenetricarboxylic acid, the amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.6% by mass or less based on 100% by mass of the porous coordination polymer. and
When the organic ligand contains methylimidazole, the amount of free methylimidazole in the porous coordination polymer is 0.7% by mass or less with respect to 100% by mass of the porous coordination polymer. ,
Functional liquid carrier. The functional liquid carrier according to claim 1, wherein the metal ions include one or more selected from the group consisting of aluminum ions, zirconium ions, chromium ions, copper ions, iron ions, and zinc ions. The functional liquid carrier according to claim 1 or 2, wherein the functional sustained release liquid has a molecular weight of 600 or less. The functional liquid carrier according to any one of claims 1 to 3, wherein the average pore diameter of the porous coordination polymer is greater than or equal to the molecular diameter of the functional sustained release liquid. The functional liquid carrier according to any one of claims 1 to 4,
A functional sustained release composition comprising: a matrix resin; The functional sustained release composition according to claim 5, wherein the surface concentration of the liquid component when compressed at 10 MPa or more is less than 1.0 mg/cm ² . A molded article comprising the functional sustained release composition according to claim 5 or 6.