JP2022552939A - 洗浄ブースターを含む液体洗濯洗剤 - Google Patents
洗浄ブースターを含む液体洗濯洗剤 Download PDFInfo
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- JP2022552939A JP2022552939A JP2022515079A JP2022515079A JP2022552939A JP 2022552939 A JP2022552939 A JP 2022552939A JP 2022515079 A JP2022515079 A JP 2022515079A JP 2022515079 A JP2022515079 A JP 2022515079A JP 2022552939 A JP2022552939 A JP 2022552939A
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- laundry detergent
- liquid laundry
- detergent formulation
- liquid
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- 239000007788 liquid Substances 0.000 title claims abstract description 129
- 239000003599 detergent Substances 0.000 title claims abstract description 114
- 239000000203 mixture Substances 0.000 claims abstract description 128
- 238000009472 formulation Methods 0.000 claims abstract description 107
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims description 26
- 239000004744 fabric Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 150000004703 alkoxides Chemical group 0.000 claims description 11
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003752 hydrotrope Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract description 2
- 238000010586 diagram Methods 0.000 abstract 1
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
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- 239000002979 fabric softener Substances 0.000 description 4
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- 238000011056 performance test Methods 0.000 description 4
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- 239000001509 sodium citrate Substances 0.000 description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 3
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XRIBIDPMFSLGFS-UHFFFAOYSA-N 2-(dimethylamino)-2-methylpropan-1-ol Chemical compound CN(C)C(C)(C)CO XRIBIDPMFSLGFS-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
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- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
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- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
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- 125000002091 cationic group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical class OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
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- 235000010755 mineral Nutrition 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical class CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- OSPOJLWAJPWJTO-UHFFFAOYSA-N 3-[hexadecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O OSPOJLWAJPWJTO-UHFFFAOYSA-N 0.000 description 1
- TUBRCQBRKJXJEA-UHFFFAOYSA-N 3-[hexadecyl(dimethyl)azaniumyl]propane-1-sulfonate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O TUBRCQBRKJXJEA-UHFFFAOYSA-N 0.000 description 1
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical class CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 1
- BRIXOPDYGQCZFO-UHFFFAOYSA-N 4-ethylphenylsulfonic acid Chemical class CCC1=CC=C(S(O)(=O)=O)C=C1 BRIXOPDYGQCZFO-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
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- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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- KMBPCQSCMCEPMU-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCCN KMBPCQSCMCEPMU-UHFFFAOYSA-N 0.000 description 1
- HESSGHHCXGBPAJ-UHFFFAOYSA-N n-[3,5,6-trihydroxy-1-oxo-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexan-2-yl]acetamide Chemical compound CC(=O)NC(C=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O HESSGHHCXGBPAJ-UHFFFAOYSA-N 0.000 description 1
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- GHKGUEZUGFJUEJ-UHFFFAOYSA-M potassium;4-methylbenzenesulfonate Chemical compound [K+].CC1=CC=C(S([O-])(=O)=O)C=C1 GHKGUEZUGFJUEJ-UHFFFAOYSA-M 0.000 description 1
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- 229960005076 sodium hypochlorite Drugs 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- ASEFUFIKYOCPIJ-UHFFFAOYSA-M sodium;2-dodecoxyethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOS([O-])(=O)=O ASEFUFIKYOCPIJ-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical group [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
48(6×8)個の並列圧力反応器を備えた、プレートを収容するSymyx PPR(登録商標)セットアップを使用して、洗浄ブースターを調製した。ロボット制御針および圧縮ガスマイクロバルブを備えたISCOシリンジポンプを使用して、プロピレンオキシド(PO)およびエチレンオキシド(EO)を別個に送達した。Library Studio(登録商標)ソフトウェアを使用して、使用した反応器の各々のレイアウトを設計した。各反応器の取り外し可能なPEEK撹拌パドルと一緒にガラスインサートを125℃の真空オーブンで乾燥させた。
反応器に添加する原材料((ジアミン)(PO)8、PO、およびEO)の量を変更して、合成S1~S24と同様の様式で、合成S25を実施した。合成S25の生成物のNMRおよびGPC分析を、表2に報告する。
表4に記載の洗浄ブースターを含む、表3に記載の一般的な配合を有する、後の実施例の洗浄試験で使用した液体洗濯洗剤配合物を、標準的な液体洗濯配合物の調製手順によって調製した。
22℃の設定試験温度、各実験に使用する20個の1.2リットルキャニスターでの18分の洗浄サイクルを使用するLaunder-Ometer(SDL Atlas、モデルM228AA)で、比較例C1~C5の液体洗濯洗剤配合物の一次洗浄性能を評価した。洗浄した布地を、Eberbach E6000レシプロ式シェーカーで100ppm(2/1のCa/Mg)に硬度を調整した周囲温度の水300mLで、260osc/分で5分間すすいだ。試験で使用したシミの付いた布地および汚れたバラストは、PCS-S-132高識別皮脂BEY顔料、および収縮前の綿インターロック布地に縫い付けたTestfabricsからのPCS-S-94皮脂/埃ASTMシミであった。綿インターロックのサイズは、5×5cmであった。シミの付いた見本は、2.5×3cmであった。1つの5×5cmの切片のSBL-CFT汚れバラストを各キャニスターに添加して、洗浄溶液に対する汚れのベースラインを提供した。研究に使用した水の硬度は、CaCO3 (2:1のCa:Mgモル比)として100ppmに調整し、EDTA滴定によってチェックして確認した。洗浄液体中の総界面活性剤濃度は、200ppmであった。
上の試験1と同様の様式のLaunder-Ometer(SDL Atlas、モデルM228AA)で、比較例C6および実施例1~4の液体洗濯洗剤配合物の一次洗浄性能を評価した。
上の試験1と同様の様式のLaunder-Ometer(SDL Atlas、モデルM228AA)で、比較例C7~C8および実施例5~6の液体洗濯洗剤配合物の一次洗浄性能を評価した。
Claims (10)
- 前記液体洗濯洗剤配合物が、
前記液体洗濯洗剤配合物の重量に基づいて、25~97.9重量%の前記液体担体と、
前記液体洗濯洗剤配合物の重量に基づいて、2~60重量%の前記洗浄界面活性剤と、
前記液体洗濯洗剤配合物の重量に基づいて、0.1~15重量%の前記洗浄ブースターポリマーと、を含む、請求項1に記載の液体洗濯洗剤配合物。 - 前記液体担体が、水を含む、請求項1に記載の液体洗濯洗剤配合物。
- 前記洗浄ブースターが、1,750~9,000ダルトンの重量平均分子量MWを有する、請求項3に記載の液体洗濯洗剤配合物。
- 前記洗浄ブースターが、前記洗浄ブースターの重量に基づいて、90~99.5重量%のアルコキシド基を含有し、前記アルコキシド基が、-CH2CH2O-基および-CH2CH(CH3)O-基からなる群から選択され、前記洗浄ブースター中の前記アルコキシド基の≦70重量%が、-CH2CH(CH3)O-基である、請求項4に記載の液体洗濯洗剤配合物。
- 前記洗浄界面活性剤が、アニオン性界面活性剤を含む、請求項5に記載の液体洗濯洗剤配合物。
- 前記洗浄界面活性剤がまた、非イオン性界面活性剤を含む、請求項6に記載の液体洗濯洗剤配合物。
- 溶剤をさらに含む、請求項7に記載の液体洗濯洗剤配合物。
- ヒドロトロープおよびビルダーをさらに含む、請求項8に記載の液体洗濯洗剤配合物。
- 布地物品を洗浄する方法であって、汚れた布地物品を提供することと、請求項1に記載の液体洗濯洗剤配合物を提供することと、洗浄水を提供することと、前記洗浄水および前記液体洗濯洗剤配合物を前記汚れた布地物品に適用して、洗浄された布地物品を提供することと、を含む、方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US201962906915P | 2019-09-27 | 2019-09-27 | |
US62/906,915 | 2019-09-27 | ||
PCT/US2020/052218 WO2021061774A1 (en) | 2019-09-27 | 2020-09-23 | Liquid laundry detergent with cleaning booster |
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JP2022552939A true JP2022552939A (ja) | 2022-12-21 |
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JP2022515079A Pending JP2022552939A (ja) | 2019-09-27 | 2020-09-23 | 洗浄ブースターを含む液体洗濯洗剤 |
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US (1) | US20220315864A1 (ja) |
EP (1) | EP4034626A1 (ja) |
JP (1) | JP2022552939A (ja) |
CN (1) | CN114364781B (ja) |
AR (1) | AR119899A1 (ja) |
AU (1) | AU2020356460A1 (ja) |
BR (1) | BR112022004180A2 (ja) |
CA (1) | CA3151617A1 (ja) |
WO (1) | WO2021061774A1 (ja) |
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EP4321604A1 (en) | 2022-08-08 | 2024-02-14 | The Procter & Gamble Company | A fabric and home care composition comprising surfactant and a polyester |
WO2024094803A1 (en) | 2022-11-04 | 2024-05-10 | The Procter & Gamble Company | Fabric and home care composition |
WO2024094802A1 (en) | 2022-11-04 | 2024-05-10 | The Procter & Gamble Company | Fabric and home care composition |
WO2024094800A1 (en) | 2022-11-04 | 2024-05-10 | The Procter & Gamble Company | Fabric and home care composition |
WO2024119298A1 (en) | 2022-12-05 | 2024-06-13 | The Procter & Gamble Company | Fabric and home care composition comprising a polyalkylenecarbonate compound |
EP4386074A1 (en) | 2022-12-16 | 2024-06-19 | The Procter & Gamble Company | Fabric and home care composition |
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EP0794245B1 (en) * | 1996-03-04 | 2003-07-09 | The Procter & Gamble Company | Laundry pretreatment process and bleaching compositions |
US6075000A (en) * | 1997-07-02 | 2000-06-13 | The Procter & Gamble Company | Bleach compatible alkoxylated polyalkyleneimines |
MX2007012838A (es) * | 2005-04-15 | 2007-11-09 | Procter & Gamble | Composiciones de limpieza con polialquileniminas alcoxiladas. |
EP2139978B1 (en) * | 2007-04-24 | 2010-12-22 | Unilever PLC | Improvements relating to laundry cleaning compositions |
WO2009004555A1 (en) | 2007-06-29 | 2009-01-08 | The Procter & Gamble Company | Laundry detergent compositions comprising amphiphilic graft polymers based on polyalkylene oxides and vinyl esters |
BRPI0820306B1 (pt) * | 2007-11-09 | 2018-02-27 | The Procter & Gamble Company | Composições de limpeza com polialquileno iminas anfifílicas solúveis em água que têm um bloco de óxido de polietileno interno e um bloco de óxido de polipropileno externo. |
CN103415608A (zh) * | 2010-12-17 | 2013-11-27 | 宝洁公司 | 具有聚氧化烯氧化物封端的聚环氧烷-聚羧酸根接枝聚合物的清洁组合物 |
ES2718380T3 (es) * | 2015-10-29 | 2019-07-01 | Procter & Gamble | Composición detergente líquida |
EP3301159B1 (en) * | 2016-10-03 | 2023-08-02 | The Procter & Gamble Company | Laundry detergent composition |
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2020
- 2020-09-04 AR ARP200102476A patent/AR119899A1/es active IP Right Grant
- 2020-09-23 CN CN202080062695.XA patent/CN114364781B/zh active Active
- 2020-09-23 BR BR112022004180A patent/BR112022004180A2/pt unknown
- 2020-09-23 WO PCT/US2020/052218 patent/WO2021061774A1/en active Application Filing
- 2020-09-23 US US17/633,653 patent/US20220315864A1/en active Pending
- 2020-09-23 CA CA3151617A patent/CA3151617A1/en active Pending
- 2020-09-23 JP JP2022515079A patent/JP2022552939A/ja active Pending
- 2020-09-23 AU AU2020356460A patent/AU2020356460A1/en active Pending
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US20220315864A1 (en) | 2022-10-06 |
CN114364781B (zh) | 2024-03-19 |
EP4034626A1 (en) | 2022-08-03 |
WO2021061774A1 (en) | 2021-04-01 |
AU2020356460A1 (en) | 2022-04-14 |
BR112022004180A2 (pt) | 2022-05-31 |
CA3151617A1 (en) | 2021-04-01 |
CN114364781A (zh) | 2022-04-15 |
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