JP2022118198A - Terminal-equipped wire and manufacturing method thereof - Google Patents

Terminal-equipped wire and manufacturing method thereof Download PDF

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JP2022118198A
JP2022118198A JP2022100613A JP2022100613A JP2022118198A JP 2022118198 A JP2022118198 A JP 2022118198A JP 2022100613 A JP2022100613 A JP 2022100613A JP 2022100613 A JP2022100613 A JP 2022100613A JP 2022118198 A JP2022118198 A JP 2022118198A
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conductor
anticorrosion
terminal
corrosion
wire
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JP7421844B2 (en
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永吾 達川
Eigo Tatsukawa
良樹 生沼
Yoshiki Ikunuma
隆寛 今村
Takahiro Imamura
裕文 河中
Hirofumi Kawanaka
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Furukawa Electric Co Ltd
Furukawa Automotive Systems Inc
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Furukawa Electric Co Ltd
Furukawa Automotive Systems Inc
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Abstract

PROBLEM TO BE SOLVED: To provide a manufacturing method of a terminal-equipped wire capable of securely covering a conductive wire exposed from a conductive wire crimping portion with an anticorrosion material without impairing manufacturability and ensuring corrosion resistance.
SOLUTION: A first anticorrosion material 17a is applied to a protruding portion of a conductive wire 13 exposed from the tip of a conductive wire crimping portion 7 by, for example, a dispenser or the like (first anticorrosion material application step). At this time, the first anticorrosion material 17a is applied so as to avoid the conductive wire crimping portion 7. After the first anticorrosion material application step, the first anticorrosion material 17a in front of the protruding portion of the conductive wire 13 is temporarily hardened to form a temporary hardened portion 18 (anticorrosion material temporary hardening step). Thereafter, the first anticorrosion material 17a applied in the first anticorrosion material application step is made to penetrate into the vicinity of the tip of the conductive wire 13 (anticorrosion material permeation step). At this time, the first anticorrosion material 17a penetrates between the strands of the conductive wire 13 and a gap 12 between the conductive wire 13 and the tip of the conductor crimping portion 7.
SELECTED DRAWING: Figure 3
COPYRIGHT: (C)2022,JPO&INPIT

Description

本発明は例えば自動車等に用いられる端子付き電線およびその製造方法に関するものである。 TECHNICAL FIELD The present invention relates to a terminal-equipped electric wire for use in automobiles, etc., and a method for manufacturing the same.

従来、自動車、OA機器、家電製品等の分野では、電力線や信号線として、電気導電性に優れた銅系材料からなる電線が使用されている。特に、自動車分野においては、車両の高性能化、高機能化が急速に進められており、車載される各種電気機器や制御機器が増加している。したがって、これに伴い、使用される端子付き電線も増加する傾向にある。 2. Description of the Related Art Conventionally, in the fields of automobiles, OA equipment, home electric appliances, and the like, electric wires made of copper-based materials with excellent electrical conductivity have been used as power lines and signal lines. In particular, in the field of automobiles, the performance and functionality of vehicles are rapidly advancing, and the number of various electric devices and control devices to be mounted on vehicles is increasing. Therefore, along with this, the number of electric wires with terminals used tends to increase.

一方、環境問題が注目される中、自動車の軽量化が要求されている。したがって、ワイヤハーネスの使用量増加に伴う重量増加が問題となる。このため、従来使用されている銅線に代えて、軽量なアルミニウム電線が注目されている。 On the other hand, while environmental problems are attracting attention, there is a demand for weight reduction of automobiles. Therefore, an increase in weight due to an increase in the amount of use of the wire harness becomes a problem. For this reason, light weight aluminum wires have attracted attention in place of conventionally used copper wires.

ここで、このような電線同士を接続する際や機器類等の接続部においては、接続用端子が用いられる。しかし、アルミニウム電線を用いた端子付き電線であっても、接続部の信頼性等のため、端子部には、電気特性に優れる銅が使用される場合がある。このような場合には、アルミニウム電線と銅製の端子とが接合されて使用される。 Here, a connection terminal is used when connecting such electric wires or at a connection portion of equipment. However, even in an electric wire with a terminal using an aluminum electric wire, there are cases where copper, which has excellent electrical properties, is used for the terminal portion for the reliability of the connecting portion. In such a case, an aluminum electric wire and a copper terminal are joined and used.

しかし、異種金属を接触させると、標準電極電位の違いから、いわゆる電食が発生する恐れがある。特に、アルミニウムと銅との標準電極電位差は大きいため、接触部への水の飛散や結露等の影響により、電気的に卑であるアルミニウム側の腐食が進行する。このため、接続部における電線と端子との接続状態が不安定となり、接触抵抗の増加や線径の減少による電気抵抗の増大、更には断線が生じて電装部品の誤動作、機能停止に至る恐れがある。このため、電線と端子との接続部を防食材で被覆する方法が提案されている。 However, when dissimilar metals are brought into contact with each other, so-called electrolytic corrosion may occur due to the difference in standard electrode potential. In particular, since the standard electrode potential difference between aluminum and copper is large, corrosion on the electrically base aluminum side progresses due to the influence of water splashing and condensation on the contact portion. As a result, the connection between the wire and the terminal at the connection part becomes unstable, increasing the electrical resistance due to an increase in contact resistance and a decrease in the wire diameter. be. For this reason, a method has been proposed in which the connecting portion between the electric wire and the terminal is coated with an anticorrosion material.

例えば、防食材の粘度を下げることで、効率よく導線の素線間等に防食材を浸透させるために、製造工程において、樹脂を加温して一時的に低粘度として、防食材を塗布する方法が提案されている(特許文献1)。 For example, by lowering the viscosity of the anti-corrosion material, the anti-corrosion material is applied in the manufacturing process by heating the resin to temporarily lower the viscosity, in order to allow the anti-corrosion material to efficiently penetrate between the strands of the conductor wire. A method has been proposed (Patent Document 1).

特開2016-225171号公報JP 2016-225171 A

図5(a)は、導線圧着部107において、導線113を圧着した状態を示す概念図である。導線圧着部107を金型で圧縮して導線113を圧着すると、その先端部には、導線113との間に隙間101が生じる場合がある。 FIG. 5A is a conceptual diagram showing a state in which the conductor wire 113 is crimped in the conductor crimping portion 107. FIG. When the conductor wire crimping portion 107 is compressed with a mold and the conductor wire 113 is crimped, a gap 101 may be generated between the tip portion and the conductor wire 113 .

この状態で、図5(b)に示すように、導線圧着部107の先端から露出する導線113を覆うように防食材117を塗布すると、発明者らは、図5(c)に示すように、この隙間101や導線113の素線間に残っていた空気によって、気泡102が生じるおそれがあることを見出した。このような気泡102が生じると、この部位の防食材117の厚みが薄くなり、硬化時等において防食材117が破裂して導線113が露出するおそれがある。このため、防食性が低下するという問題がある。 In this state, as shown in FIG. 5(b), when the anti-corrosion 117 is applied so as to cover the conductor wire 113 exposed from the tip of the conductor crimping portion 107, the inventors found that as shown in FIG. 5(c), It has been found that the gap 101 and the air remaining between the strands of the conductor wire 113 may generate air bubbles 102 . When such air bubbles 102 are generated, the thickness of the anti-corrosion 117 at this portion is reduced, and there is a risk that the anti-corrosion 117 may burst during hardening or the like, exposing the conducting wire 113 . Therefore, there is a problem that the anticorrosion property is lowered.

これに対し、特許文献1のように防食材を低粘度とすることで、気泡を抜けやすくする方法はあるが、特許文献1のように粘度調整を行うためには、環境温度を調整する追加設備が必要となり、製造工程が長くなるなどコスト増を招く。 On the other hand, as in Patent Document 1, there is a method of making the anti-corrosion material have a low viscosity to make it easier for air bubbles to escape. Equipment is required, and the manufacturing process is lengthened, resulting in an increase in cost.

本発明は、このような問題に鑑みてなされたもので、製造性を損なうことなく、導線圧着部から露出する導線を確実に防食材で覆い、防食性を確保することが可能な端子付き電線及びその製造方法を提供することを目的とする。 The present invention has been made in view of such problems, and an electric wire with a terminal that can reliably cover the conductor exposed from the crimped portion of the conductor with an anti-corrosion property without impairing the manufacturability. and a manufacturing method thereof.

前述した目的を達するために第1の発明は、被覆導線と端子とが接続される端子付き電線であって、被覆導線の先端部の被覆部が除去された導線露出部が、前記端子の導線圧着部で圧着されており、前記導線圧着部の先端から露出する導線の出代部に対し、前記導線圧着部を避けるように設けられた第1防食材と、前記第1防食材の少なくとも一部を覆うように設けられた第2防食材と、を具備し、前記第1防食材が、前記導線と前記導線圧着部との隙間に浸透されていることを特徴とする端子付き電線
である。
In order to achieve the above object, a first invention provides an electric wire with a terminal to which a covered conductor and a terminal are connected, wherein the conductor exposed portion obtained by removing the covering at the tip of the covered conductor is the conductor of the terminal. and at least one of a first anti-corrosion protection provided so as to avoid the lead wire crimping part with respect to a protrusion portion of the conductor which is crimped by the crimping part and exposed from the tip of the lead wire crimping part. and a second anti-corrosion layer provided so as to cover a portion, wherein the first anti-corrosion layer permeates a gap between the conductor wire and the conductor crimping portion. .

前記導線の出代部以外の部位であって、前記導線圧着部の少なくとも一部を覆うように設けられる第3防食材をさらに有し、前記第2防食材が、前記第1防食材及び前記第3防食材の少なくとも一部を覆うように設けられてもよい。 It further has a third anti-corrosion part provided so as to cover at least a part of the crimped part of the conductor wire, the second anti-corrosion part being a portion other than the protruding margin part of the conductor wire, wherein the second anti-corrosion part comprises the first anti-corrosion part and the It may be provided so as to cover at least part of the third anticorrosion.

第2の発明は、覆導線と端子とが接続される端子付き電線の製造方法であって、被覆導線の先端部の被覆部を除去し、導線露出部を形成する電線加工工程と、
前記導線露出部を、端子の導線圧着部で圧着して、導線と前記端子とを接続する電線・端子接続工程と、前記導線圧着部の先端から露出する前記導線の出代部に対し、前記導線圧着部を避けるように防食材を塗布する第1防食材塗布工程と、前記導線圧着部の後端側に第3防食材を塗布する第3防食材塗布工程と、前記第1防食材塗布工程で塗布した防食材を、前記導線の先端部近傍に浸透させる防食材浸透工程と、前記導線の出代部に防食材を浸透させた後、前記第1防食材塗布工程及び前記第3防食材塗布工程で塗布した防食材の少なくとも一部を覆うようにさらに防食材を塗布する第2防食材塗布工程と、塗布された防食材を硬化させる樹脂硬化工程と、を具備し、前記防食材浸透工程では、所定時間の浸透時間によって、前記第1防食材塗布工程で塗布した防食材を前記導線と前記導線圧着部の先端部との隙間に浸透させるとともに、前記第3防食材塗布工程で塗布した防食材を前記導線と前記導線圧着部の後端部との隙間に浸透させることを特徴とする端子付き電線の製造方法である。
A second invention is a method for manufacturing an electric wire with a terminal in which a covered conductor and a terminal are connected, the electric wire processing step of removing the covering portion of the tip portion of the covered conductor to form an exposed conductor portion;
A wire/terminal connecting step of crimping the exposed conductor portion with a conductor crimping portion of a terminal to connect the conductor and the terminal; A first anti-corrosion coating step of applying anti-corrosion so as to avoid the crimped portion of the conductor, a third anti-corrosion coating step of applying a third anti-corrosion to the rear end side of the crimped portion of the conductor, and the first anti-corrosion coating. Anticorrosion penetrating step for penetrating the anticorrosion coating applied in the step to the vicinity of the tip of the conductor wire; a second anti-corrosion coating step of further coating the anti-corrosion so as to cover at least a part of the anti-corrosion applied in the food coating step; and a resin curing step of curing the applied anti-corrosion, wherein the anti-corrosion In the permeation step, the anticorrosion applied in the first anticorrosion application step is permeated into the gap between the conductor wire and the tip portion of the conductor crimped portion for a predetermined permeation time, and in the third anticorrosion application step, The method of manufacturing an electric wire with a terminal is characterized in that the coated anti-corrosion material is allowed to permeate into a gap between the conductive wire and the rear end portion of the crimped portion of the conductive wire.

第1、第2の発明によれば、導線圧着部の先端から露出する導線の出代部に対し、導線圧着部を避けるように防食材を塗布するため、導線と導線圧着部との隙間が防食材で覆われることがない。また、導線の素線間等に防食材を浸透させることで、導線の素線間や隙間を防食材で埋めることができるため、気泡が生じることを抑制することができる。このため、気泡に起因した防食性の低下を抑制することができる。 According to the first and second inventions, since the anti-corrosion material is applied to the protruded portion of the conductor exposed from the tip of the conductor crimping part so as to avoid the conductor crimping part, a gap between the conductor and the conductor crimping part is formed. Not covered with anti-corrosion material. In addition, by infiltrating the anti-corrosion material between the strands of the conducting wire, it is possible to fill the spaces between the strands of the conducting wire and gaps with the anti-corrosion material, thereby suppressing the formation of air bubbles. Therefore, it is possible to suppress the deterioration of the anticorrosiveness caused by the air bubbles.

また、防食材を浸透させている間に、導線の出代部以外の部位であって、導線圧着部を覆うように、防食材を塗布することで、防食材の塗布時間を短縮することができる。 In addition, while the anti-corrosion material is infiltrated, the anti-corrosion material is applied so as to cover the crimped portion of the conductive wire other than the protruding portion of the conductor, thereby shortening the application time of the anti-corrosion material. can.

本発明によれば、製造性を損なうことなく、導線圧着部から露出する導線を確実に防食材で覆い、防食性を確保することが可能な端子付き電線及びその製造方法を提供することができる。 ADVANTAGE OF THE INVENTION According to the present invention, it is possible to provide an electric wire with a terminal and a method for manufacturing the same, which can reliably cover the conductor exposed from the conductor crimping part with an anticorrosive and ensure anticorrosion without impairing manufacturability. .

端子付き電線10を示す斜視図。The perspective view which shows the electric wire 10 with a terminal. 端子付き電線10を示す断面図。Sectional drawing which shows the electric wire 10 with a terminal. (a)~(c)は、第1防食材17aを塗布する工程を示す断面拡大図。4(a) to 4(c) are cross-sectional enlarged views showing a step of applying a first anti-corrosion layer 17a; (a)、(b)は、第2防食材17b、第3防食材17cを塗布する方法を示す断面図。(a), (b) is sectional drawing which shows the method of apply|coating the 2nd anti-corrosion 17b and the 3rd anti-corrosion 17c. (a)~(c)は、従来の導線圧着部107への防食材117を塗布する工程を示す図。4(a) to 4(c) are diagrams showing a conventional process of applying anti-corrosion material 117 to a crimped portion 107 of a conductor wire.

以下、図面を参照しながら、本発明の実施形態について説明する。図1は、端子付き電線10を示す斜視図であり、図2は断面図である。なお、図1は、防食材17を透視した図である。なお、防食材17は、後述する第1防食材17a、第2防食材17b、第3防食材17cの総称である。端子付き電線10は、端子1と被覆導線11が接続されて構成される。 Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 1 is a perspective view showing an electric wire 10 with a terminal, and FIG. 2 is a cross-sectional view. In addition, FIG. 1 is a perspective view of the anticorrosion 17 . The anti-corrosion 17 is a general term for the first anti-corrosion 17a, the second anti-corrosion 17b, and the third anti-corrosion 17c, which will be described later. An electric wire 10 with a terminal is configured by connecting a terminal 1 and a covered conductor 11 .

被覆導線11は、アルミニウムまたはアルミニウム合金製である導線13と、導線13を被覆する被覆部15からなる。すなわち、被覆導線11は、被覆部15と、その先端から露出する導線13とを具備する。導線13は、例えば、複数の素線が撚り合わせられた撚り線である。 Covered lead wire 11 includes lead wire 13 made of aluminum or an aluminum alloy and cover portion 15 covering lead wire 13 . That is, the covered conductor 11 has a covered portion 15 and the conductor 13 exposed from the tip thereof. The conducting wire 13 is, for example, a twisted wire in which a plurality of strands are twisted together.

端子1は、オープンバレル型であり、銅または銅合金製である。端子1には被覆導線11が接続される。端子1は、端子本体3と圧着部5とがトランジション部4を介して連結されて構成される。圧着部5と端子本体3の間に位置するトランジション部4は、上方が開口する。 The terminal 1 is of open barrel type and made of copper or copper alloy. A coated conductor 11 is connected to the terminal 1 . The terminal 1 is configured by connecting a terminal main body 3 and a crimping portion 5 via a transition portion 4 . The transition portion 4 positioned between the crimping portion 5 and the terminal body 3 is open at the top.

端子本体3は、所定の形状の板状素材を、断面が矩形の筒体に形成したものである。端子本体3は、内部に、板状素材を矩形の筒体内に折り込んで形成される弾性接触片を有する。端子本体3は、前端部から雄型端子などが挿入されて接続される。なお、以下の説明では、端子本体3が、雄型端子等の挿入タブ(図示省略)の挿入を許容する雌型端子である例を示すが、本発明において、この端子本体3の細部の形状は特に限定されない。例えば、雌型の端子本体3に代えて例えば雄型端子の挿入タブを設けてもよい。また、端子本体3は、雄雌の嵌合タイプではなく、一般的な丸形端子や先開形端子であってもよい。 The terminal main body 3 is formed by forming a plate-shaped material having a predetermined shape into a tubular body having a rectangular cross section. The terminal body 3 has an elastic contact piece inside which is formed by folding a plate-like material into a rectangular cylindrical body. The terminal body 3 is connected by inserting a male terminal or the like from the front end portion. In the following description, an example in which the terminal body 3 is a female terminal that allows insertion of an insertion tab (not shown) of a male terminal or the like will be shown. is not particularly limited. For example, instead of the female terminal main body 3, for example, an insertion tab for a male terminal may be provided. Further, the terminal body 3 may be a general round terminal or a tip-open terminal instead of a male-female fitting type.

圧着部5は、被覆導線11と圧着される部位であり、圧着前においては、端子1の長手方向に垂直な断面形状が略U字状のバレル形状を有する。端子1の圧着部5は、被覆導線11の先端側に被覆部15から露出する導線13を圧着する導線圧着部7と、被覆導線11の被覆部15を圧着する被覆圧着部9と、導線圧着部7と被覆圧着部9の間のバレル間部8からなる。 The crimping part 5 is a part to be crimped with the coated conductor 11, and has a substantially U-shaped cross-sectional shape perpendicular to the longitudinal direction of the terminal 1 before crimping. The crimping portion 5 of the terminal 1 includes a conductor crimping portion 7 for crimping the conductor wire 13 exposed from the covering portion 15 to the distal end side of the covered conductor 11, a covering crimping portion 9 for crimping the covering portion 15 of the covered conductor 11, and a conductor crimping portion. It consists of an inter-barrel portion 8 between the portion 7 and the covering crimp portion 9 .

導線圧着部7の内面の一部には、幅方向(長手方向に垂直な方向)に、図示を省略したセレーションが設けられる。このようにセレーションを形成することで、導線13を圧着した際に、導線13の表面の酸化膜を破壊しやすく、また、導線13との接触面積を増加させることができる。 A portion of the inner surface of the conductor crimping portion 7 is provided with serrations (not shown) in the width direction (direction perpendicular to the longitudinal direction). By forming the serrations in this manner, the oxide film on the surface of the conductor 13 is easily destroyed when the conductor 13 is crimped, and the contact area with the conductor 13 can be increased.

被覆導線11の先端は、被覆部15が剥離され、内部の導線13が露出する。被覆導線11の被覆部15は、端子1の被覆圧着部9によって圧着される。また、被覆部15が剥離されて露出する導線13は、導線圧着部7により圧着される。導線圧着部7において、導線13と端子1とが電気的に接続される。なお、被覆部15の端面は、被覆圧着部9と導線圧着部7の間のバレル間部8に位置する。 At the tip of the covered conductor 11, the covering portion 15 is peeled off, and the conductor 13 inside is exposed. The covering portion 15 of the covered conductor wire 11 is crimped by the covering crimping portion 9 of the terminal 1 . Further, the conductor wire 13 exposed by peeling off the covering portion 15 is crimped by the conductor crimping portion 7 . The conductor wire 13 and the terminal 1 are electrically connected at the conductor crimping portion 7 . The end face of the covering portion 15 is located in the inter-barrel portion 8 between the covering crimping portion 9 and the conductor crimping portion 7 .

本発明では、少なくとも、バレル間部8から導線圧着部7の先端の導線13が露出する部位までが防食材17で覆われている。したがって、導線13は、防食材17によって外部に露出しない。なお、防食材17は、例えば、アクリレート系の光硬化樹脂である。 In the present invention, at least the portion from the inter-barrel portion 8 to the portion where the conductor wire 13 at the tip of the conductor crimping portion 7 is exposed is covered with the anti-corrosion layer 17 . Therefore, the conductive wire 13 is not exposed to the outside due to the anticorrosion 17 . The anti-corrosion material 17 is, for example, an acrylate-based photo-curing resin.

次に、端子付き電線10の製造方法について説明する。まず、被覆導線11の先端部の被覆部15を除去し、導線露出部を形成する(電線加工工程)。次に、導線露出部を、端子1の導線圧着部7で圧着して、導線13と端子1とを接続する(電線・端子接続工程)。 Next, a method for manufacturing the electric wire with terminal 10 will be described. First, the covering portion 15 of the tip portion of the covering conductor 11 is removed to form the conductor exposed portion (electric wire processing step). Next, the exposed wire portion is crimped by the wire crimping portion 7 of the terminal 1 to connect the wire 13 and the terminal 1 (wire/terminal connecting step).

次に、図3(a)に示すように、導線圧着部7の先端から端子本体3側に露出する導線13の出代部に対して、例えばディスペンサ等によって第1防食材17aを塗布する(第1防食材塗布工程)。この際、第1防食材17aは、導線圧着部7を避けるように塗布される。すなわち、導線圧着部7の先端部の上面には、第1防食材17aは付着せず、導線13の出代部のみに接触するように第1防食材17aが塗布される。 Next, as shown in FIG. 3(a), a first anti-corrosion material 17a is applied by, for example, a dispenser to the protruding portion of the conductor 13 exposed from the tip of the conductor crimping portion 7 toward the terminal body 3 ( first anti-corrosion coating step). At this time, the first anti-corrosion layer 17 a is applied so as to avoid the wire crimping portion 7 . That is, the first anti-corrosion layer 17 a is applied to the upper surface of the leading end portion of the wire crimping portion 7 so as to contact only the protruded portion of the lead wire 13 without adhering to the first anti-corrosion layer 17 a.

第1防食材塗布工程の後に、図3(b)に示すように、導線13の出代部の前方の第1防食材17aを部分的に仮硬化させ、仮硬化部18を形成する(防食材仮硬化工程)。仮硬化部18は、第1防食材17aの端子本体3側の一部に部分的に光を照射することで形成することができる。なお、仮硬化部18は、完全に硬化していてもよく、完全に硬化していなくてもよい。いずれにせよ、導線13と付着している部分の第1防食材17aに流動性が残ればよい。 After the first anti-corrosion coating step, as shown in FIG. 3B, the first anti-corrosion portion 17a in front of the protruding portion of the conductor 13 is partially pre-cured to form a pre-cured portion 18 (pre-hardening portion 18). material temporary hardening process). The temporary hardened portion 18 can be formed by partially irradiating a portion of the first anticorrosion 17a on the terminal main body 3 side with light. In addition, the temporary hardening part 18 may be completely hardened or may not be completely hardened. In any case, the fluidity should remain in the portion of the first anti-corrosion material 17a adhering to the conducting wire 13 .

また、防食材仮硬化工程は、必要に応じ行えばよく、後述する防食材浸透工程において、第1防食材17aの端子本体3への流出が少ない場合には不要である。例えば、第1防食材17aの塗布時の粘度が1000mPa・s以下である場合に、防食材仮硬化工程を行うことが効果的である。 Further, the anticorrosion temporary hardening step may be performed as necessary, and is not necessary when the first anticorrosion 17a flows into the terminal main body 3 in a small amount in the anticorrosion permeation step to be described later. For example, when the viscosity of the first anticorrosion 17a when applied is 1000 mPa·s or less, it is effective to perform the anticorrosion temporary hardening step.

その後、図3(c)に示すように、第1防食材塗布工程で塗布した第1防食材17aを、導線13の先端部近傍に浸透させる(防食材浸透工程)。この際、第1防食材17aは、導線13の素線間と、導線13と導線圧着部7の先端部の隙間12に浸透する。なお、浸透時間は、例えば0.3~2.4秒が望ましく、より望ましくは1~2.4秒とする。浸透時間が十分でないと、隙間12が埋まらずに気泡が生成され、浸透時間が長すぎると、サイクルタイムが長くなりすぎて生産性が悪化する。 After that, as shown in FIG. 3(c), the first anticorrosion 17a applied in the first anticorrosion coating step is allowed to permeate the vicinity of the tip portion of the lead wire 13 (anticorrosion permeation step). At this time, the first anti-corrosion material 17 a penetrates into the gaps 12 between the strands of the conductor wire 13 and between the conductor wire 13 and the tip of the conductor crimping portion 7 . The permeation time is desirably 0.3 to 2.4 seconds, more desirably 1 to 2.4 seconds. If the permeation time is not enough, air bubbles are generated without filling the gaps 12, and if the permeation time is too long, the cycle time becomes too long and the productivity deteriorates.

防食材浸透工程おいて、導線13の出代部に第1防食材17aを浸透させた後、第1防食材17aを覆うようにさらに第2防食材を塗布し(第2防食材塗布工程)、導線圧着部7の先端部において、十分な防食材の厚みを確保する。この際、第2防食材は、第1防食材17aと同一の粘度の樹脂を用いてもよいが、第1防食材17aよりも粘度の高い樹脂を用いてもよい。 In the anti-corrosion penetration step, after the first anti-corrosion 17a is permeated into the protruding portion of the conductor 13, the second anti-corrosion is applied so as to cover the first anti-corrosion 17a (second anti-corrosion coating step). , ensure a sufficient anti-corrosion thickness at the leading end of the wire crimping portion 7; In this case, the second anti-corrosion resin may be made of a resin having the same viscosity as that of the first anti-corrosion layer 17a, or may be a resin having a higher viscosity than that of the first anti-corrosion layer 17a.

なお、前述したように、防食材浸透工程が完了しないと、第2防食材を塗布することができないため、その間は手待ち時間となる。このため、図4(a)に示すように、防食材浸透工程と並行して、導線13の出代部以外の部位であって、バレル間部8から導線圧着部7を覆うように、第3防食材17cを塗布してもよい(第3防食材塗布工程)。このようにすることで、防食材浸透工程における待ち時間を有効に利用して他の部位に防食材を塗布することができる。 As described above, the second anticorrosion agent cannot be applied until the permeation step of the anticorrosion agent is completed. For this reason, as shown in FIG. 4( a ), in parallel with the anti-corrosion permeation step, a portion other than the protruded portion of the conductor 13 , so as to cover the conductor crimping portion 7 from the inter-barrel portion 8 . 3 Anticorrosion 17c may be applied (third anticorrosion application step). By doing so, it is possible to effectively utilize the waiting time in the anticorrosion permeation step to apply the anticorrosion to other parts.

この場合には、図4(b)に示すように、第3防食材17cを塗布した後であって、防食材浸透工程が完了した後に第2防食材17bを導線圧着部7の先端部近傍に塗布し、導線圧着部7の先端部近傍の防食材17の厚みを確保する。 In this case, as shown in FIG. 4(b), after the third anti-corrosion layer 17c has been applied and the step of penetrating the anti-corrosion layer is completed, the second anti-corrosion layer 17b is applied to the vicinity of the tip portion of the lead wire crimping portion 7. to ensure the thickness of the anti-corrosion 17 near the tip of the wire crimping portion 7 .

最後に、塗布された防食材17(第1防食材17a、第2防食材17b、第3防食材17c)に光を照射して完全に硬化させる(樹脂硬化工程)。以上により、端子付き電線10を得ることができる。 Finally, the applied anticorrosion 17 (the first anticorrosion 17a, the second anticorrosion 17b, and the third anticorrosion 17c) is irradiated with light to be completely cured (resin curing step). The electric wire 10 with a terminal can be obtained by the above.

なお、本発明において、防食材17を塗布するとは、防食材17の液滴を対象部に接触させる方法や、防食材17の液滴を供給部から打ち出して(滴下させて)対象部に付着させる方法など、対象部に防食材17が付着した状態を得る方法の全てを含むものとする。例えば、防食材17の液滴を対象部に対して、メカニカルディスペンサで接触させて塗布してもよく、ジェットディスペンサで供給部から打ち出して塗布してもよい。 In the present invention, the application of the anticorrosion 17 means a method of bringing droplets of the anticorrosion 17 into contact with the target area, or ejecting (dripping) droplets of the anticorrosion 17 from the supply unit and adhering to the target area. It includes all methods for obtaining a state in which the anti-corrosion 17 is adhered to the target portion, such as a method for For example, droplets of the anti-corrosion 17 may be applied to the target area by contacting them with a mechanical dispenser, or may be applied by ejecting them from a supply unit with a jet dispenser.

また、各工程における防食材17の塗布は、一か所ではなく、複数個所であってもよい。例えば、第1防食材塗布工程において、導線圧着部7の上部にかからず、導線13の先端部にかかるように複数個所に第1防食材17aを塗布してもよい。 Also, the anti-corrosion 17 may be applied at a plurality of locations instead of at one location in each step. For example, in the first anti-corrosion coating step, the first anti-corrosion coating 17 a may be applied to a plurality of locations so as not to cover the upper portion of the wire crimping portion 7 but to cover the tip of the lead wire 13 .

なお、第1防食材17a、第2防食材17b及び第3防食材17cは、それぞれの形成タイミングが異なるため、その境界を、断面研磨後に光学顕微鏡や偏光顕微鏡で識別が可能である。 Since the first anti-corrosion layer 17a, the second anti-corrosion layer 17b, and the third anti-corrosion layer 17c are formed at different timings, their boundaries can be identified with an optical microscope or a polarizing microscope after cross-sectional polishing.

以上説明したように、本実施形態によれば、第1防食材17aを導線圧着部7の上部にかからないように塗布するため、導線圧着部7と導線13との隙間12に溜まっていた空気による気泡の発生を抑制することができる。また、第2防食材17bを塗布する前に十分に浸透時間を確保するため、第2防食材17bを塗布した際の気泡の発生も抑制することができるとともに、第2防食材17bによって導線圧着部7の先端部近傍の防食材17の厚みを確保することができる。 As described above, according to the present embodiment, since the first anti-corrosion layer 17 a is applied so as not to cover the upper portion of the wire crimping portion 7 , the air accumulated in the gap 12 between the wire crimping portion 7 and the wire 13 is applied. It is possible to suppress the generation of air bubbles. In addition, since sufficient penetration time is ensured before applying the second anti-corrosion layer 17b, it is possible to suppress the generation of air bubbles when the second anti-corrosion layer 17b is applied, and the lead wires are crimped by the second anti-corrosion layer 17b. The thickness of the anticorrosion 17 near the tip of the portion 7 can be ensured.

なお、このような効果は、特に、電線径の小さい場合に有効である。例えば、0.3sq~2.5sqの電線の場合には、隙間12に樹脂が浸透しにくく、気泡も抜けにくいが、上記の方法によれば、気泡の発生を抑制することができる。 Such an effect is particularly effective when the wire diameter is small. For example, in the case of an electric wire of 0.3 sq to 2.5 sq, it is difficult for the resin to permeate the gap 12 and it is difficult for air bubbles to escape.

また、第1防食材塗布工程の後に、第1防食材17aを仮硬化させることで、第1防食材17aが端子本体3側に流れてしまい、十分に第1防食材17aを導線13側に浸透させることができなくなることを抑制することができる。 Further, after the first anticorrosion coating step, the first anticorrosion 17a is temporarily hardened, so that the first anticorrosion 17a flows toward the terminal main body 3, and the first anticorrosion 17a is sufficiently moved toward the conductor 13. It is possible to suppress the impossibility of infiltration.

また、防食材浸透工程と並行して、第3防食材17cを塗布することで、浸透時間を有効に利用し、タクトタイムを短縮することができる。 By applying the third anti-corrosion layer 17c in parallel with the anti-corrosion permeation step, the permeation time can be effectively used and the tact time can be shortened.

浸透時間と防食材の粘度等の条件を調整して、各種の端子付き電線を製造し、各種の評価を行った。防食材としては、紫外線硬化性のアクリレート系樹脂を用いた。第1防食材塗布工程→第2防食材塗布工程→樹脂硬化工程を行い、硬化後の浸透性(気泡の有無)と、膜厚について外観を確認し、導線部分の樹脂の膜厚が50μm以上のものを合格とした。また、製造にかかる時間について評価した。 Various types of electric wires with terminals were manufactured by adjusting conditions such as permeation time and viscosity of anticorrosion, and various evaluations were performed. An ultraviolet curable acrylate resin was used as the anti-corrosion material. Perform the first anticorrosion coating process → second anticorrosion coating process → resin curing process, check the permeability after curing (whether or not there are bubbles) and the appearance of the film thickness, and the resin film thickness of the conductor part is 50 μm or more. Those with . Also, the time required for manufacturing was evaluated.

各条件において、10個のサンプルを作成し、上記の評価を行った。この際、10個全てが基準をクリアしたものを○とし、合格数が1~9個であったものを△とし、全て不合格であった物を×とした。浸透性、膜厚および目標タクトの全てについて評価し、その最低の評価を当該条件の評価として表1に示した。 For each condition, 10 samples were prepared and evaluated as described above. At this time, ◯ indicates that all 10 samples cleared the criteria, Δ indicates that the number of acceptable samples was 1 to 9, and x indicates that all failed samples. All of the permeability, film thickness and target takt time were evaluated, and the lowest evaluation was shown in Table 1 as the evaluation of the conditions.

Figure 2022118198000002
Figure 2022118198000002

浸透時間を2.5秒以上とすると、目標とするタクトタイムを超えてしまうため全て不合格となった。一方、浸透時間が0.1秒では、十分に樹脂が浸透せずに気泡が確認された。このため、浸透時間は、0.3~2.4秒であることが望ましい。 If the permeation time was set to 2.5 seconds or longer, the target tact time was exceeded, and all were rejected. On the other hand, when the permeation time was 0.1 second, the resin did not permeate sufficiently and air bubbles were observed. Therefore, it is desirable that the permeation time is 0.3 to 2.4 seconds.

また、粘度によっては、浸透時間を長くすることで膜厚不足が見られた。これに対しては、第1防食材の仮硬化工程を追加することで膜厚不足が解消された。 In addition, depending on the viscosity, insufficient film thickness was observed by lengthening the permeation time. To solve this problem, the lack of film thickness was resolved by adding a temporary hardening step for the first anti-corrosion layer.

以上、添付図を参照しながら、本発明の実施の形態を説明したが、本発明の技術的範囲は、前述した実施の形態に左右されない。当業者であれば、特許請求の範囲に記載された技術的思想の範疇内において各種の変更例または修正例に想到し得ることは明らかであり、それらについても当然に本発明の技術的範囲に属するものと了解される。 Although the embodiments of the present invention have been described above with reference to the accompanying drawings, the technical scope of the present invention is not influenced by the above-described embodiments. It is obvious that a person skilled in the art can conceive various modifications or modifications within the scope of the technical idea described in the claims, and these are naturally within the technical scope of the present invention. be understood to belong to

1………端子
3………端子本体
4………トランジション部
5………圧着部
7………導線圧着部
8………バレル間部
9………被覆圧着部
10………端子付き電線
11………被覆導線
12………隙間
13………導線
15………被覆部
17………防食材
17a………第1防食材
17b………第2防食材
17c………第2防食材
18………仮硬化部
101………隙間
102………気泡
107………導線圧着部
113………導線
117………防食材
1 Terminal 3 Terminal main body 4 Transition portion 5 Crimping portion 7 Lead wire crimping portion 8 Inter-barrel portion 9 Insulated crimping portion 10 With terminal Electric wire 11 Covered conductor wire 12 Gap 13 Conductor wire 15 Covered portion 17 Anti-corrosion part 17 a First anti-corrosion part 17 b Second anti-corrosion part 17 c Second 2 Anti-corrosion part 18 Temporary hardening part 101 Gap 102 Air bubble 107 Lead wire crimping part 113 Lead wire 117 Anti-corrosion part

Claims (3)

被覆導線と端子とが接続される端子付き電線であって、
被覆導線の先端部の被覆部が除去された導線露出部が、前記端子の導線圧着部で圧着されており、
前記導線圧着部の先端から露出する導線の出代部に対し、前記導線圧着部を避けるように設けられた第1防食材と、
前記第1防食材の少なくとも一部を覆うように設けられた第2防食材と、
を具備し、
前記第1防食材が、前記導線と前記導線圧着部との隙間に浸透されていることを特徴とする端子付き電線。
An electric wire with a terminal in which a coated conductor and a terminal are connected,
The conductor exposed portion from which the covering portion of the tip portion of the covered conductor is removed is crimped by the conductor crimping portion of the terminal,
a first anti-corrosion material provided so as to avoid the conductor crimping portion with respect to the protrusion portion of the conductor exposed from the tip of the conductor crimping portion;
a second anticorrosion provided to cover at least a portion of the first anticorrosion;
and
An electric wire with a terminal, wherein the first anti-corrosion material permeates a gap between the conductor wire and the conductor crimping portion.
前記導線の出代部以外の部位であって、前記導線圧着部の少なくとも一部を覆うように設けられる第3防食材をさらに有し、
前記第2防食材が、前記第1防食材及び前記第3防食材の少なくとも一部を覆うように設けられたことを特徴とする請求項1記載の端子付き電線。
further comprising a third anti-corrosion material provided so as to cover at least a portion of the conductor crimping portion at a portion other than the protrusion portion of the conductor;
2. The electric wire with a terminal according to claim 1, wherein said second anticorrosive material is provided so as to cover at least part of said first anticorrosive material and said third anticorrosive material.
被覆導線と端子とが接続される端子付き電線の製造方法であって、
被覆導線の先端部の被覆部を除去し、導線露出部を形成する電線加工工程と、
前記導線露出部を、端子の導線圧着部で圧着して、導線と前記端子とを接続する電線・端子接続工程と、
前記導線圧着部の先端から露出する前記導線の出代部に対し、前記導線圧着部を避けるように防食材を塗布する第1防食材塗布工程と、
前記導線圧着部の後端側に第3防食材を塗布する第3防食材塗布工程と、
前記第1防食材塗布工程で塗布した防食材を、前記導線の先端部近傍に浸透させる防食材浸透工程と、
前記導線の出代部に防食材を浸透させた後、前記第1防食材塗布工程及び前記第3防食材塗布工程で塗布した防食材の少なくとも一部を覆うようにさらに防食材を塗布する第2防食材塗布工程と、
塗布された防食材を硬化させる樹脂硬化工程と、
を具備し、
前記防食材浸透工程では、所定時間の浸透時間によって、前記第1防食材塗布工程で塗布した防食材を前記導線と前記導線圧着部の先端部との隙間に浸透させるとともに、前記第3防食材塗布工程で塗布した防食材を前記導線と前記導線圧着部の後端部との隙間に浸透させることを特徴とする端子付き電線の製造方法。
A method for manufacturing an electric wire with a terminal in which a coated conductor and a terminal are connected,
A wire processing step of removing the covering of the tip of the covered conductor to form an exposed conductor;
A wire/terminal connection step of crimping the exposed conductor portion with a conductor crimping portion of a terminal to connect the conductor wire and the terminal;
a first anti-corrosion coating step of applying an anti-corrosion material to the projection portion of the conductor exposed from the tip of the crimped conductor so as to avoid the crimped conductor;
a third anticorrosion applying step of applying a third anticorrosion to the rear end side of the conductor crimping portion;
an anticorrosion impregnation step of penetrating the anticorrosion applied in the first anticorrosion coating step into the vicinity of the tip of the conductor;
After infiltrating the anticorrosion into the protruding portion of the conductor, the anticorrosion is further applied so as to cover at least a part of the anticorrosion applied in the first anticorrosion application step and the third anticorrosion application step. 2 anti-corrosion coating step;
a resin curing step of curing the applied anticorrosion;
and
In the anti-corrosion permeation step, the anti-corrosion coating applied in the first anti-corrosion coating step is permeated into the gap between the conductor wire and the tip portion of the crimped portion of the conductor wire for a predetermined permeation time, and the third anti-corrosion insulation step is performed. A method for manufacturing an electric wire with a terminal, wherein the anticorrosive material applied in the coating step is allowed to permeate into a gap between the conductor wire and the rear end portion of the crimped portion of the conductor wire.
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JP2012028021A (en) * 2010-07-20 2012-02-09 Auto Network Gijutsu Kenkyusho:Kk Electric wire with terminal
JP2016225171A (en) * 2015-06-01 2016-12-28 株式会社フジクラ Manufacturing method of wire with terminal, and wire with terminal
JP2017212089A (en) * 2016-05-25 2017-11-30 古河電気工業株式会社 Wire with terminal
JP2018077949A (en) * 2016-11-07 2018-05-17 古河電気工業株式会社 Method for manufacturing terminal-attached electric wire

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JP2016225171A (en) * 2015-06-01 2016-12-28 株式会社フジクラ Manufacturing method of wire with terminal, and wire with terminal
JP2017212089A (en) * 2016-05-25 2017-11-30 古河電気工業株式会社 Wire with terminal
JP2018077949A (en) * 2016-11-07 2018-05-17 古河電気工業株式会社 Method for manufacturing terminal-attached electric wire

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